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Wednesday, June 14, 2017

Brønsted–Lowry acid–base theory

    The Brønsted–Lowry theory is an acid–base reaction theory which was proposed independently by Johannes Nicolaus Brønsted and Thomas Martin Lowry in 1923.[1][2] The fundamental concept of this theory is that when an acid and a base react with each other, the acid forms its conjugate base, and the base forms its conjugate acid by exchange of a proton (the hydrogen cation, or H+). This theory is a generalization of the Arrhenius theory.

    Definitions of acids and bases

    Johannes Nicolaus Brønsted and Thomas Martin Lowry, independently, formulated the idea that acids are proton (H+) donors while bases are proton acceptors.

    In the Arrhenius theory acids are defined as substances which dissociate in aqueous solution to give H+ (hydrogen ions). Bases are defined as substances which dissociate in aqueous solution to give OH (hydroxide ions).[3]

    In 1923 physical chemists Johannes Nicolaus Brønsted in Denmark and Thomas Martin Lowry in England independently proposed the theory that carries their names.[4][5][6] In the Brønsted–Lowry theory acids and bases are defined by the way they react with each other, which allows for greater generality. The definition is expressed in terms of an equilibrium expression

    acid + base ⇌ conjugate base + conjugate acid.

    With an acid, HA, the equation can be written symbolically as:
     
    HA + B ⇌ A + HB+

    The equilibrium sign, ⇌, is used because the reaction can occur in both forward and backward directions. The acid, HA, can lose a proton to become its conjugate base, A. The base, B, can accept a proton to become its conjugate acid, HB+. Most acid-base reactions are fast so that the components of the reaction are usually in dynamic equilibrium with each other.[7]

    Aqueous solutions

    Acetic acid, CH3COOH, is composed of a methyl group, CH3, bound chemically to a carboxylate group, COOH. The carboxylate group can lose a proton and donate it to a water molecule, H2O, leaving behind an acetate anion CH3COO− and creating a hydronium cation H3O+. This is an equilibrium reaction, so the reverse process can also take place.
    Acetic acid, a weak acid, donates a proton (hydrogen ion, highlighted in green) to water in an equilibrium reaction to give the acetate ion and the hydronium ion. Red: oxygen, black: carbon, white: hydrogen.

    Consider the following acid–base reaction:
     
    CH3COOH + H2O ⇌ CH3COO + H3O+

    Acetic acid, CH3COOH, is an acid because it donates a proton to water (H2O) and becomes its conjugate base, the acetate ion (CH3COO). H2O is a base because it accepts a proton from CH3COOH and becomes its conjugate acid, the hydronium ion, (H3O+).[8]

    The reverse of an acid-base reaction is also an acid-base reaction, between the conjugate acid of the base in the first reaction and the conjugate base of the acid. In the above example, acetate is the base of the reverse reaction and hydronium ion is the acid.
     
    H3O+ + CH3COO ⇌ CH3COOH + H2O

    The power of the Brønsted–Lowry theory is that, in contrast to Arrhenius theory, it does not require an acid to dissociate.

    Amphoteric substances

    The amphoteric nature of water

    The essence of Brønsted–Lowry theory is that an acid only exists as such in relation to a base, and vice versa. Water is amphoteric as it can act as an acid or as a base. In the image shown at the right one molecule of H2O acts as a base and gains H+ to become H3O+while the other acts as an acid and loses H+ to become OH.

    Another example is furnished by substances like aluminium hydroxide, Al(OH)3.
     
    Al(OH)3 + OHAl(OH)
    4
    , acting as an acid
    3H+ + Al(OH)3 ⇌ 3H2O + Al3+(aq), acting as a base

    Non-aqueous solutions

    The hydrogen ion, or hydronium ion, is a Brønsted–Lowry acid in aqueous solutions, and the hydroxide ion is a base, by virtue of the self-dissociation reaction
     
    H2O + H2O ⇌ H3O+ + OH

    An analogous reaction occurs in liquid ammonia
     
    NH3 + NH3NH+
    4
    + NH
    2

    Thus, the ammonium ion, NH+
    4
    , plays the same role in liquid ammonia as does the hydronium ion in water and the amide ion, NH
    2
    , is analogous to the hydroxide ion. Ammonium salts behave as acids, and amides behave as bases.[9]

    Some non-aqueous solvents can behave as bases, that is, proton acceptors, in relation to Brønsted–Lowry acids.
     
    HA + S ⇌ A + SH+

    where S stands for a solvent molecule. The most important such solvents are dimethylsulfoxide, DMSO, and acetonitrile, CH3CN, as these solvents has been widely used to measure the acid dissociation constants of organic molecules. Because DMSO is a stronger proton acceptor than H2O the acid becomes a stronger acid in this solvent than in water.[10] Indeed, many molecules behave as acids in non-aqueous solution that do not do so in aqueous solution. An extreme case occurs with carbon acids, where a proton is extracted from a C-H bond.

    Some non-aqueous solvents can behave as acids. An acidic solvent will increase basicity of substances dissolved in it. For example, the compound CH3COOH is known as acetic acid because of its acidic behaviour in water. However it behaves as a base in liquid hydrogen chloride, a much more acidic solvent.[11]
     
    HCl + CH3COOH ⇌ Cl + CH
    3
    C(OH)+
    2

    Comparison with Lewis acid–base theory

    In the same year that Brønsted and Lowry published their theory, G. N. Lewis proposed an alternative theory of acid–base reactions. The Lewis theory is based on electronic structure. A Lewis base is defined as a compound that can donate an electron pair to a Lewis acid, a compound that can accept an electron pair.[12][13] Lewis's proposal gives an explanation to the Brønsted–Lowry classification in terms of electronic structure.

    HA + B: ⇌ A: + BH+

    In this representation both the base, B, and the conjugate base, A, are shown carrying a lone pair of electrons and the proton, which is a Lewis acid, is transferred between them.
    Adduct of ammonia and boron trifluoride

    Lewis later wrote in "To restrict the group of acids to those substances that contain hydrogen interferes as seriously with the systematic understanding of chemistry as would the restriction of the term oxidizing agent to substances containing oxygen."[13] In Lewis theory an acid, A, and a base, B:, form an adduct, AB, in which the electron pair is used to form a dative covalent bond between A and B. This is illustrated with the formation of the adduct H3N−BF3 from ammonia and boron trifluoride, a reaction that cannot occur in aqueous solution because boron trifluoride reacts violently with water in a hydrolysis reaction.

    BF3 + 3H2O → B(OH)3 + 3HF
    HF ⇌ H+ + F

    These reactions illustrate that BF3 is an acid in both Lewis and Brønsted–Lowry classifications and emphasizes the consistency between both theories.[citation needed]

    Boric acid is recognized as a Lewis acid by virtue of the reaction

    B(OH)3 + H2O ⇌ B(OH)
    4
    + H+

    In this case the acid does not dissociate, it is the base, H2O that dissociates. A solution of B(OH)3 is acidic because hydrogen ions are liberated in this reaction.

    There is strong evidence that dilute aqueous solutions of ammonia contain negligible amounts of the ammonium ion

    H2O + NH3 ⥇ OH + NH+
    4

    and that, when dissolved in water, ammonia functions as a Lewis base.[14]

    Comparison with the Lux-Flood theory

    The reactions between certain oxides in non-aqueous media cannot be explained on the basis of Brønsted–Lowry theory. For example, the reaction
     
    2MgO + SiO2 → Mg2SiO4

    does not fall within the scope of the Brønsted–Lowry definition of acids and bases. On the other hand, MgO is basic and SiO2 is acidic in the Brønsted–Lowry sense, referring to mixtures in water.
     
    2H+ + MgO(s) → Mg2+(aq) + 2H2O
    SiO2(s) + 2H2O → SiO4−
    4
    + 4H+ (≡ Si(OH)4(aq))

    Lux-Flood theory also classifies magnesium oxide as a base in non-aqueous circumstances. This classification is important in geochemistry. Minerals such as olivine, (Mg,Fe)SiO4 are classed as ultramafic; olivine is a compound of a very basic oxide, MgO, with an acidic oxide, silica, SiO2.

Thursday, June 8, 2017

Clive James: Climate Alarmists Won’t Admit They Are Wrong

Date: 04/06/17
Clive James, The Australia
From:  https://www.thegwpf.com/clive-james-climate-alarmists-wont-admit-they-are-wrong/

When you tell people once too often that the missing extra heat is hiding in the ocean, they will switch over to watch Game of Thrones, where the dialogue is less ridiculous and all the threats come true. The proponents of man-made climate catastrophe asked us for so many leaps of faith that they were bound to run out of credibility in the end.














 Author Clive James at his home in London.

Now that they finally seem to be doing so, it could be a good time for those of us who have never been convinced by all those urgent warnings to start warning each other that we might be making a comparably senseless tactical error if we expect the elastic cause of the catastrophists, and all of its exponents, to go away in a hurry.

I speak as one who knows nothing about the mathematics involved in modelling non-linear systems. But I do know quite a lot about the mass media, and far too much about the abuse of language. So I feel qualified to advise against any triumphalist urge to compare the apparently imminent disintegration of the alarmist cause to the collapse of a house of cards. Devotees of that fond idea haven’t thought hard enough about their metaphor. A house of cards collapses only with a sigh, and when it has finished collapsing all the cards are still there.
Although the alarmists might finally have to face that they will not get much more of what they want on a policy level, they will surely, on the level of their own employment, go on wanting their salaries and prestige.

Illustration: Eric Lobbecke
Illustration: Eric Lobbecke
To take a conspicuous if ludicrous case, Australian climate star Tim Flannery will probably not, of his own free will, shrink back to the position conferred by his original metier, as an expert on the extinction of the giant wombat. He is far more likely to go on being, and wishing to be, one of the mass media’s mobile oracles about climate. While that possibility continues, it will go on being danger­ous to stand between him and a television camera. If the giant wombat could have moved at that speed, it would still be with us.

The mere fact that few of Flannery’s predictions have ever come true need not be enough to discredit him, just as American professor Paul Ehrlich has been left untouched since he predicted that the world would soon run out of copper. In those days, when our current phase of the long discussion about man’s attack on nature was just beginning, he predicted mass death by extreme cold. Lately he predicts mass death by extreme heat. But he has always predicted mass death by extreme something.

Actually, a more illustrative starting point for the theme of the permanently imminent climatic apocalypse might be taken as August 3, 1971, when The Sydney Morning Herald announced that the Great Barrier Reef would be dead in six months.

After six months the reef had not died, but it has been going to die almost as soon as that ever since, making it a strangely durable emblem for all those who have wedded themselves to the notion of climate catastrophe.

The most exalted of all the world’s predictors of reef death, former US president Barack Obama, has still not seen the reef; but he promises to go there one day when it is well again.

In his acceptance speech at the 2008 Democratic convention, Obama said — and I truly wish that this were an inaccurate paraphrase — that people should vote for him if they wanted to stop the ocean rising. He got elected, and it didn’t rise.

The notion of a countdown or a tipping point is very dear to both wings of this deaf shouting match, and really is of small use to either. On the catastrophist wing, whose “narrative”, as they might put it, would so often seem to be a synthesised film script left over from the era of surround-sound disaster movies, there is always a countdown to the tipping point.

When the scientists are the main contributors to the script, the tipping point will be something like the forever forthcoming moment when the Gulf Stream turns upside down or the Antarctic ice sheet comes off its hinges, or any other extreme event which, although it persists in not happening, could happen sooner than we think. (Science correspondents who can write a phrase like “sooner than we think” seldom realise that they might have already lost you with the word “could”.)

When the politicians join in the writing, the dramatic language declines to the infantile. There are only 50 days (former British PM Gordon Brown) or 100 months (Prince Charles wearing his political hat) left for mankind to “do something” about “the greatest moral challenge … of our generation” (Kevin Rudd, before he arrived at the Copenhagen climate shindig in 2009).

When he left Copenhagen, Rudd scarcely mentioned the greatest moral challenge again. Perhaps he had deduced, from the confusion prevailing throughout the conference, that the chances of the world ever uniting its efforts to “do something” were very small. Whatever his motives for backing out of the climate chorus, his subsequent career was an early demonstration that to cease being a chorister would be no easy retreat because it would be a clear indication that everything you had said on the subject up to then had been said in either bad faith or ­ignorance. It would not be enough merely to fall silent. You would have to travel back in time, run for office in the Czech Republic ­instead of Australia, and call yourself Vaclav Klaus.

Australia, unlike Rudd, has a globally popular role in the ­climate movie because it looks the part.
Common reason might tell you that a country whose contribution to the world’s emissions is only 1.4 per cent can do very little about the biggest moral challenge even if it manages to reduce that contribution to zero; but your eyes tell you that Australia is burning up. On the classic alarmist principle of “just stick your head out of the window and look around you”, Australia always looks like Overwhelming Evidence that the alarmists must be right.

<i>Climate Change: The Facts 2017</i> edited by Jennifer Marohasy
Climate Change: The Facts 2017 edited by Jennifer Marohasy
Even now that the global warming scare has completed its transformation into the climate change scare so that any kind of event at either end of the scale of temperature can qualify as a crisis, Australia remains the top area of interest, still up there ahead of even the melting North Pole, ­despite the Arctic’s miraculous ­capacity to go on producing ice in defiance of all instructions from Al Gore. A C-student to his marrow, and thus never quick to pick up any reading matter at all, Gore has evidently never seen the Life magazine photographs of America’s nuclear submarine Skate surfacing through the North Pole in 1959. The ice up there is often thin, and sometimes vanishes.

But it comes back, especially when some­one sufficiently illustrious confidently predicts that it will go away for good.

After 4.5 billion years of changing, the climate that made outback Australia ready for Baz Luhrmann’s viewfinder looked all set to end the world tomorrow. History has already forgotten that the schedule for one of the big drought sequences in his movie Australia was wrecked by rain, and certainly history will never be reminded by the mass media, which loves a picture that fits the story.

In this way, the polar bear balancing on the Photoshopped shrinking ice floe will always have a future in show business, and the cooling towers spilling steam will always be up there in the background of the TV picture.

The full 97 per cent of all satirists who dealt themselves out of the climate subject back at the start look like staying out of it until the end, even if they get satirised in their turn. One could blame them for their pusillanimity, but it would be useless, and perhaps unfair. Nobody will be able plausibly to call actress Emma Thompson dumb for spreading gloom and doom about the climate: she’s too clever and too creative. And anyway, she might be right. Cases like Leonardo DiCaprio and Cate Blanchett are rare enough to be called brave. Otherwise, the consensus of silence from the wits and thespians continues to be impressive.

If they did wish to speak up for scepticism, however, they wouldn’t find it easy when the people who run the big TV outlets forbid the wrong kind of humour.

On Saturday Night Live back there in 2007, Will Ferrell, brilliantly pretending to be George W. Bush, was allowed to get every word of the global warming message wrong but he wasn’t allowed to disbelieve it. Just as all branches of the modern media love a picture of something that might be part of the Overwhelming Evidence for climate change even if it is really a picture of something else, they all love a clock ticking down to zero, and if the clock never quite gets there then the motif can be exploited forever.

But the editors and producers must face the drawback of such perpetual excitement: it gets perpetually less exciting. Numbness sets in, and there is time to think after all. Some of the customers might even start asking where this language of rubber numbers has been heard before.

It was heard from Swift. In Gulliver’s Travels he populated his flying island of Laputa with scientists busily using rubber numbers to predict dire events. He called these scientists “projectors”. At the basis of all the predictions of the projectors was the prediction that the Earth was in danger from a Great Comet whose tail was “ten hundred thousand and fourteen” miles long. I should concede at this point that a sardonic parody is not necessarily pertinent just because it is funny; and that although it might be unlikely that the Earth will soon be threatened by man-made climate change, it might be less unlikely that the Earth will be threatened eventually by an asteroid, or let it be a Great Comet; after all, the Earth has been hit before.

That being said, however, we can note that Swift has got the language of artificial crisis exactly right, to the point that we might have trouble deciding whether he invented it or merely copied it from scientific voices surrounding him. James Hansen is a Swiftian figure. Blithely equating trains full of coal to trains full of people on their way to Auschwitz, the Columbia University climatologist is utterly unaware that he has not only turned the stomachs of the informed audience he was out to impress, he has lost their attention.

Paleoclimatologist Chris Turney, from the University of NSW, who led a ship full of climate change enthusiasts into the Antarctic to see how the ice was doing under the influence of climate change and found it was doing well enough to trap the ship, could have been invented by Swift. (Turney’s subsequent Guardian article, in which he explained how this embarrassment was due only to a quirk of the weather and had nothing to do with a possible mistake about the climate, was a Swiftian lampoon in all respects.)

Compulsorily retired now from the climate scene, Rajendra Pachauri, formerly chairman of the Intergovernmental Panel on Clim­ate Change, was a zany straight from Swift, by way of a Bollywood remake of The Party starring the local imitator of Peter Sellers; if Dr Johnson could have thought of Pachauri, Rasselas would be much more entertaining than it is. Finally, and supremely, Flannery could have been invented by Swift after 10 cups of coffee too many with Stella. He wanted to keep her laughing. Swift projected the projectors who now surround us.

They came out of the grant-hungry fringe of semi-science to infect the heart of the mass media, where a whole generation of commentators taught each other to speak and write a hyperbolic doom-language (“unprecedent­ed”, “irreversible”, et cetera), which you might have thought was sure to doom them in their turn. After all, nobody with an intact pair of ears really listens for long to anyone who talks about “the planet” or “carbon” or “climate denial” or “the science”. But for now — and it could be a long now — the advocates of drastic action are still armed with a theory that no fact doesn’t fit.

The theory has always been manifestly unfalsifiable, but there are few science pundits in the mass media who could tell Karl Popper from Mary Poppins. More startling than their ignorance, however, is their defiance of logic. You can just about see how a bunch of grant-dependent climate scientists might go on saying that there was never a Medieval Warm Period even after it has been pointed out to them that any old corpse dug up from the permafrost could never have been buried in it. But how can a bunch of supposedly enlightened writers go on saying that? Their answer, if pressed, is usually to say that the question is too elementary to be considered.

Alarmists have always profited from their insistence that climate change is such a complex issue that no “science denier” can have an opinion about it worth hearing. For most areas of science such an insistence would be true. But this particular area has a knack of raising questions that get more and more complicated in the absence of an answer to the elementary ones. One of those elementary questions is about how man-made carbon dioxide can be a driver of climate change if the global temperature has not gone up by much over the past 20 years but the amount of man-made carbon dioxide has. If we go on to ask a supplementary question — say, how could carbon dioxide raise temperature when the evidence of the ice cores indicates that temperature has always raised carbon dioxide — we will be given complicated answers, but we still haven’t had an answer to the first question, except for the suggestion that the temperature, despite the observations, really has gone up, but that the extra heat is hiding in the ocean.

It is not necessarily science denial to propose that this long professional habit of postponing an answer to the first and most elementary question is bizarre. American physicist Richard Feynman said that if a fact doesn’t fit the theory, the theory has to go. Feynman was a scientist. Einstein realised that the Michelson-Morley experiment hinted at a possible fact that might not fit Newton’s theory of celestial mechanics. Einstein was a scientist, too. Those of us who are not scientists, but who are sceptical about the validity of this whole issue — who suspect that the alleged problem might be less of a problem than is made out — have plenty of great scientific names to point to for exemplars, and it could even be said that we could point to the whole of science itself. Being resistant to the force of its own inertia is one of the things that science does.

When the climatologists upgraded their frame of certainty from global warming to climate change, the bet-hedging man­oeuvre was so blatant that some of the sceptics started predicting in their turn: the alarmist cause must surely now collapse, like a house of cards. A tipping point had been reached.

Unfortunately for the cause of rational critical inquiry, the campaign for immediate action against climate doom reaches a tipping point every few minutes, because the observations, if not the calculations, never cease exposing it as a fantasy.

I myself, after I observed journalist Andrew Neil on BBC TV wiping the floor with the then secretary for energy and climate change Ed Davey, thought that the British government’s energy policy could not survive, and that the mad work that had begun with the 2008 Climate Change Act of Labour’s Ed Miliband must now surely begin to come undone. Neil’s well-inform­ed list of questions had been a tipping point. But it changed nothing in the short term. It didn’t even change the BBC, which continued uninterrupted with its determination that the alarmist view should not be questioned.

How did the upmarket mass media get themselves into such a condition of servility? One is reminded of that fine old historian George Grote when he said that he had taken his A History of Greece only to the point where the Greeks failed to realise they were slaves. The BBC’s monotonous plugging of the climate theme in its science documentaries is too obvious to need remarking, but it’s what the science programs never say that really does the damage.

Even the news programs get “smoothed” to ensure that nothing interferes with the constant business of protecting the climate change theme’s dogmatic status.

To take a simple but telling example: when Sigmar Gabriel, Germany’s Vice-Chancellor and man in charge of the Energiewende (energy transition), talked rings around Greenpeace hecklers with nothing on their minds but renouncing coal, or told executives of the renewable energy companies that they could no longer take unlimited subsidies for granted, these instructive moments could be seen on German TV but were not excerpted and subtitled for British TV even briefly, despite Gabriel’s accomplishments as a natural TV star, and despite the fact he himself was no sceptic.

Wrong message: easier to leave him out. And if American climate scientist Judith Curry appears before a US Senate com­mittee and manages to defend her anti-alarmist position against concentrated harassment from a senator whose only qualification for the discussion is that he can impugn her integrity with a rhetorical contempt of which she is too polite to be capable? Leave it to YouTube. In this way, the BBC has spent 10 years unplugged from a vital part of the global intellectual discussion, with an increasing air of provincialism as the inevitable result. As the UK now begins the long process of exiting the EU, we can reflect that the departing nation’s most important broadcasting institution has been behaving, for several years, as if its true aim were to reproduce the thought control that prevailed in the Soviet Union.

As for the print media, it’s no mystery why the upmarket newspapers do an even more thorough job than the downmarket newspapers of suppressing any dissenting opinion on the climate.

In Britain, The Telegraph sensibly gives a column to the diligently sceptical Christopher Booker, and Matt Rid­ley has recently been able to get a few rational articles into The Times, but a more usual arrangement is exemplified by my own newspaper, The Guardian, which entrusts all aspects of the subject to George Monbiot, who once informed his green readership that there was only one reason I could presume to disagree with him, and them: I was an old man, soon to be dead, and thus with no concern for the future of “the planet”.

I would have damned his impertinence, but it would have been like getting annoyed with a wheelbarrow full of freshly cut grass.

These byline names are stars committed to their opinion, but what’s missing from the posh press is the non-star name committed to the job of building a fact file and extracting a reasoned article from it. Further down the market, when The Daily Mail put its no-frills newshound David Rose on the case after Climategate, his admirable competence immediately got him labelled as a “climate change denier”: one of the first people to be awarded that badge of honour.

The other tactic used to discredit him was the standard one of calling his paper a disreputable publication. It might be — having been a victim of its prurience myself, I have no inclination to revere it — but it hasn’t forgotten what objective reporting is supposed to be. Most of the British papers have, and the reason is no mystery.

They can’t afford to remember. The print media, with notable exceptions, is on its way down the drain. With almost no personnel left to do the writing, the urge at editorial level is to give all the science stuff to one bloke. The print edition of The Independent bored its way out of business when its resident climate nag was allowed to write half the paper.

In its last year, when the doomwatch journalists were threatened by the climate industry with a newly revised consensus opinion that a mere 2C increase in world temperature might be not only acceptable but likely, The Independent’s chap retaliated by writing stories about how the real likelihood was an increase of 5C, and in a kind of frenzied crescendo he wrote a whole front page saying that the global temperature was “on track” for an increase of 6C. Not long after, the Indy’s print edition closed down.

At The New York Times, Andrew Revkin, star colour-piece writer on the climate beat, makes the whole subject no less predictable than his prose style: a cruel restriction.

In Australia, the Fairfax papers, which by now have almost as few writers as readers, reprint Revkin’s summaries as if they were the voice of authority, and will probably go on doing so until the waters close overhead. On the ABC, house science pundit Robyn Williams famously predicted that the rising of the waters “could” amount to 100m in the next century. But not even he predicted that it could happen next week. At The Sydney Morning Herald, it could happen next week. The only remaining journalists could look out of the window and see fish.

Bending its efforts to sensationalise the news on a scale previously unknown even in its scrappy history, the mass media has helped to consolidate a pernicious myth. But it could not have done this so thoroughly without the accident that it is the main source of information and opinion for people in the academic world and in the scientific institutions. Few of those people have been reading the sceptical blogs: they have no time. If I myself had not been so ill during the relevant time span, I might not have been reading it either, and might have remained confined within the misinformation system where any assertion of forthcoming disaster counts as evidence.

The effect of this mountainous accumulation of sanctified alarmism on the academic world is another subject. Some of the universities deserve to be closed down, but I expect they will muddle through, if only because the liberal spirit, when it regains its strength, is likely to be less vengeful than the dogmatists were when they ruled. Finding that the power of inertia blesses their security as once it blessed their influence, the enthusiasts might have the sense to throttle back on their certitude, huddle under the blanket cover provided by the concept of “post-normal science”, and wait in comfort to be forgotten.

As for the learned societies and professional institutions, it was never a puzzle that so many of them became instruments of obfuscation instead of enlightenment. Totalitarianism takes over a state at the moment when the ruling party is taken over by its secretariat; the tipping point is when Stalin, with his lists of names, offers to stay late after the meeting and take care of business.

The same vulnerability applies to any learned institution. Rule by bureaucracy favours mediocrity, and in no time at all you are in a world where the British Met Office’s (former) chief scientist Julia Slingo is a figure of authority and Curry is fighting to breathe.

On a smaller scale of influential prestige, Nicholas Stern lends the Royal Society the honour of his presence. For those of us who regard him as a vocalised stuffed shirt, it is no use saying that his confident pronouncements about the future are only those of an economist. Klaus was only an economist when he tried to remind us that Malthusian clairvoyance is invariably a harbinger of totalitarianism. But Klaus was a true figure of authority. Alas, true figures of authority are in short supply, and tend not to have much influence when they get to speak.

All too often, this is because they care more about science than about the media. As recently as 2015, after a full 10 years of nightly proof that this particular scientific dispute was a media event before it was anything, Freeman Dyson was persuaded to go on television. He was up there just long enough to say that the small proportion of carbon dioxide that was man-made could only add to the world’s supply of plant food. The world’s mass media outlets ignored the footage, mainly because they didn’t know who he was.

I might not have known either if I hadn’t spent, in these past few years, enough time in hospitals to have it proved to me on a personal basis that real science is as indispensable for modern medicine as cheap power. Among his many achievements, to none of which he has ever cared about drawing attention, Dyson designed the TRIGA reactor. The TRIGA ­ensures that the world’s hospitals get a reliable supply of isotopes.

Dyson served science. Except for the few holdouts who go on fighting to defend the objective ­nature of truth, most of the climate scientists who get famous are serving themselves.

There was a time when the journalists could have pointed out the difference, but now they have no idea. Instead, they are so celebrity-conscious that they would supply Flannery with a new clown suit if he wore out the one he is wearing now.

A bad era for science has been a worse one for the mass media, the field in which, despite the usual blunders and misjudgments, I was once proud to earn my living. But I have spent too much time, in these past few years, being ashamed of my profession: hence the note of anger which, I can now see, has crept into this essay even though I was determined to keep it out. As my retirement changed to illness and then to dotage, I would have preferred to sit back and write poems than to be known for taking a position in what is, despite the colossal scale of its foolish waste, a very petty quarrel.

But it was time to stand up and fight, if only because so many of the advocates, though they must know by now that they are professing a belief they no longer hold, will continue to profess it anyway.

Back in the day, when I was starting off in journalism — on The Sydney Morning Herald, as it happens — the one thing we all learned early from our veteran colleagues was never to improve the truth for the sake of the story. If they caught us doing so, it was the end of the world.

But here we are, and the world hasn’t ended after all. Though some governments might not yet have fully returned to the principle of evidence-based policy, most of them have learned to be wary of policy-based evidence. They have learned to spot it coming, not because the real virtues of critical inquiry have been well argued by scientists but because the false claims of abracadabra have been asserted too often by people who, though they might have started out as scientists of a kind, have found their true purpose in life as ideologists.

Modern history since World War II has shown us that it is unwise to predict what will happen to ideologists after their citadel of power has been brought low. It was feared that the remaining Nazis would fight on, as werewolves. Actually, only a few days had to pass before there were no Nazis to be found anywhere except in Argentina, boring one another to death at the world’s worst dinner parties.

After the collapse of the Soviet Union, on the other hand, when it was thought that no apologists for Marxist collectivism could possibly keep their credibility in the universities of the West, they not only failed to lose heart, they gained strength.

Some critics would say that the climate change fad itself is an offshoot of this ­lingering revolutionary animus against liberal democracy, and that the true purpose of the climatologists is to bring about a world government that will ensure what no less a philanthropist than Robert Mugabe calls “climate justice”, in which capitalism is replaced by something more altruistic.

I prefer to blame mankind’s inherent capacity for raising opportunism to a principle: the enabling condition for fascism in all its varieties, and often an imperative mindset among high-end frauds.[…]
This is an exclusive extract from the essay Mass Death Dies Hard by Clive James in Climate Change: The Facts 2017 edited by Jennifer Marohasy, published next month by the Institute of Public Affairs.

Monday, June 5, 2017

Future of Earth

From Wikipedia, the free encyclopedia

A dark gray and red sphere representing the scorched Earth lies against a black background to the right of an orange circular object representing the Sun
Conjectured illustration of the scorched Earth after the Sun has entered the red giant phase, about 7 billion years from now.[1]

The biological and geological future of Earth can be extrapolated based upon the estimated effects of several long-term influences. These include the chemistry at Earth's surface, the rate of cooling of the planet's interior, the gravitational interactions with other objects in the Solar System, and a steady increase in the Sun's luminosity. An uncertain factor in this extrapolation is the ongoing influence of technology introduced by humans, such as climate engineering,[2] which could cause significant changes to the planet.[3][4] The current Holocene extinction[5] is being caused by technology[6] and the effects may last for up to five million years.[7] In turn, technology may result in the extinction of humanity, leaving the planet to gradually return to a slower evolutionary pace resulting solely from long-term natural processes.[8][9]

Over time intervals of hundreds of millions of years, random celestial events pose a global risk to the biosphere, which can result in mass extinctions. These include impacts by comets or asteroids with diameters of 5–10 km (3.1–6.2 mi) or more, and the possibility of a massive stellar explosion, called a supernova, within a 100-light-year radius of the Sun, called a Near-Earth supernova. Other large-scale geological events are more predictable. If the long-term effects of global warming are disregarded, Milankovitch theory predicts that the planet will continue to undergo glacial periods at least until the Quaternary glaciation comes to an end. These periods are caused by variations in eccentricity, axial tilt, and precession of the Earth's orbit.[10] As part of the ongoing supercontinent cycle, plate tectonics will probably result in a supercontinent in 250–350 million years. Some time in the next 1.5–4.5 billion years, the axial tilt of the Earth may begin to undergo chaotic variations, with changes in the axial tilt of up to 90°.

During the next four billion years, the luminosity of the Sun will steadily increase, resulting in a rise in the solar radiation reaching the Earth. This will result in a higher rate of weathering of silicate minerals, which will cause a decrease in the level of carbon dioxide in the atmosphere. In about 600 million years from now, the level of CO2 will fall below the level needed to sustain C3 carbon fixation photosynthesis used by trees. Some plants use the C4 carbon fixation method, allowing them to persist at CO
2
concentrations as low as 10 parts per million. However, the long-term trend is for plant life to die off altogether. The extinction of plants will be the demise of almost all animal life, since plants are the base of the food chain on Earth.[11]

In about one billion years, the solar luminosity will be 10% higher than at present. This will cause the atmosphere to become a "moist greenhouse", resulting in a runaway evaporation of the oceans. As a likely consequence, plate tectonics will come to an end, and with them the entire carbon cycle.[12] Following this event, in about 2−3 billion years, the planet's magnetic dynamo may cease, causing the magnetosphere to decay and leading to an accelerated loss of volatiles from the outer atmosphere. Four billion years from now, the increase in the Earth's surface temperature will cause a runaway greenhouse effect, heating the surface enough to melt it. By that point, all life on the Earth will be extinct.[13][14] The most probable fate of the planet is absorption by the Sun in about 7.5 billion years, after the star has entered the red giant phase and expanded to cross the planet's current orbit.

Human influence

Humans play a key role in the biosphere, with the large human population dominating many of Earth's ecosystems.[3] This has resulted in a widespread, ongoing mass extinction of other species during the present geological epoch, now known as the Holocene extinction. The large-scale loss of species caused by human influence since the 1950s has been called a biotic crisis, with an estimated 10% of the total species lost as of 2007.[6] At current rates, about 30% of species are at risk of extinction in the next hundred years.[15] The Holocene extinction event is the result of habitat destruction, the widespread distribution of invasive species, hunting, and climate change.[16][17] In the present day, human activity has had a significant impact on the surface of the planet. More than a third of the land surface has been modified by human actions, and humans use about 20% of global primary production.[4] The concentration of carbon dioxide in the atmosphere has increased by close to 30% since the start of the Industrial Revolution.[3]
The consequences of a persistent biotic crisis have been predicted to last for at least five million years.[7] It could result in a decline in biodiversity and homogenization of biotas, accompanied by a proliferation of species that are opportunistic, such as pests and weeds. Novel species may also emerge; in particular taxa that prosper in human-dominated ecosystems may rapidly diversify into many new species. Microbes are likely to benefit from the increase in nutrient-enriched environmental niches. No new species of existing large vertebrates are likely to arise and food chains will probably be shortened.[5][18]

There are multiple scenarios for known risks that can have a global impact on the planet. From the perspective of humanity, these can be subdivided into survivable risks and terminal risks. Risks that humanity pose to itself include climate change, the misuse of nanotechnology, a nuclear holocaust, warfare with a programmed superintelligence, a genetically engineered disease, or a disaster caused by a physics experiment. Similarly, several natural events may pose a doomsday threat, including a highly virulent disease, the impact of an asteroid or comet, runaway greenhouse effect, and resource depletion. There may also be the possibility of an infestation by an extraterrestrial lifeform.[19] The actual odds of these scenarios are difficult if not impossible to deduce.[8][9]

Should the human race become extinct, then the various features assembled by humanity will begin to decay. The largest structures have an estimated decay half-life of about 1,000 years. The last surviving structures would most likely be open pit mines, large landfills, major highways, wide canal cuts, and earth-fill flank dams. A few massive stone monuments like the pyramids at the Giza Necropolis or the sculptures at Mount Rushmore may still survive in some form after a million years.[9][a]

Random events

The Barringer Meteorite Crater in Flagstaff, Arizona, showing evidence of the impact of celestial objects upon the Earth

As the Sun orbits the Milky Way, wandering stars may approach close enough to have a disruptive influence on the Solar System.[20] A close stellar encounter may cause a significant reduction in the perihelion distances of comets in the Oort cloud—a spherical region of icy bodies orbiting within half a light year of the Sun.[21] Such an encounter can trigger a 40-fold increase in the number of comets reaching the inner Solar System. Impacts from these comets can trigger a mass extinction of life on Earth. These disruptive encounters occur at an average of once every 45 million years.[22] The mean time for the Sun to collide with another star in the solar neighborhood is approximately 3 × 1013 years, which is much longer than the estimated age of the Milky Way galaxy, at ~1.3 × 1010 years. This can be taken as an indication of the low likelihood of such an event occurring during the lifetime of the Earth.[23]

The energy release from the impact of an asteroid or comet with a diameter of 5–10 km (3.1–6.2 mi) or larger is sufficient to create a global environmental disaster and cause a statistically significant increase in the number of species extinctions. Among the deleterious effects resulting from a major impact event is a cloud of fine dust ejecta blanketing the planet, which lowers land temperatures by about 15 °C (27 °F) within a week and halts photosynthesis for several months. The mean time between major impacts is estimated to be at least 100 million years. During the last 540 million years, simulations demonstrated that such an impact rate is sufficient to cause 5–6 mass extinctions and 20–30 lower severity events. This matches the geologic record of significant extinctions during the Phanerozoic Eon. Such events can be expected to continue into the future.[24]

A supernova is a cataclysmic explosion of a star. Within the Milky Way galaxy, supernova explosions occur on average once every 40 years.[25] During the history of the Earth, multiple such events have likely occurred within a distance of 100 light years. Explosions inside this distance can contaminate the planet with radioisotopes and possibly impact the biosphere.[26] Gamma rays emitted by a supernova react with nitrogen in the atmosphere, producing nitrous oxides. These molecules cause a depletion of the ozone layer that protects the surface from ultraviolet radiation from the Sun. An increase in UV-B radiation of only 10–30% is sufficient to cause a significant impact to life; particularly to the phytoplankton that form the base of the oceanic food chain. A supernova explosion at a distance of 26 light years will reduce the ozone column density by half. On average, a supernova explosion occurs within 32 light years once every few hundred million years, resulting in a depletion of the ozone layer lasting several centuries.[27] Over the next two billion years, there will be about 20 supernova explosions and one gamma ray burst that will have a significant impact on the planet's biosphere.[28]

The incremental effect of gravitational perturbations between the planets causes the inner Solar System as a whole to behave chaotically over long time periods. This does not significantly affect the stability of the Solar System over intervals of a few million years or less, but over billions of years the orbits of the planets become unpredictable. Computer simulations of the Solar System's evolution over the next five billion years suggest that there is a small (less than 1%) chance that a collision could occur between Earth and either Mercury, Venus, or Mars.[29][30] During the same interval, the odds that the Earth will be scattered out of the Solar System by a passing star are on the order of one part in 105. In such a scenario, the oceans would freeze solid within several million years, leaving only a few pockets of liquid water about 14 km (8.7 mi) underground. There is a remote chance that the Earth will instead be captured by a passing binary star system, allowing the planet's biosphere to remain intact. The odds of this happening are about one chance in three million.[31]

Orbit and rotation

The gravitational perturbations of the other planets in the Solar System combine to modify the orbit of the Earth and the orientation of its spin axis. These changes can influence the planetary climate.[10][32][33][34]

Glaciation

Historically, there have been cyclical ice ages in which glacial sheets periodically covered the higher latitudes of the continents. Ice ages may occur because of changes in ocean circulation and continentality induced by plate tectonics.[35] The Milankovitch theory predicts that glacial periods occur during ice ages because of astronomical factors in combination with climate feedback mechanisms. The primary astronomical drivers are a higher than normal orbital eccentricity, a low axial tilt (or obliquity), and the alignment of summer solstice with the aphelion.[10] Each of these effects occur cyclically. For example, the eccentricity changes over time cycles of about 100,000 and 400,000 years, with the value ranging from less than 0.01 up to 0.05.[36][37] This is equivalent to a change of the semiminor axis of the planet's orbit from 99.95% of the semimajor axis to 99.88%, respectively.[38]

The Earth is passing through an ice age known as the quaternary glaciation, and is presently in the Holocene interglacial period. This period would normally be expected to end in about 25,000 years.[34] However, the increased rate of carbon dioxide release into the atmosphere by humans may delay the onset of the next glacial period until at least 50,000–130,000 years from now. On the other hand, a global warming period of finite duration (based on the assumption that fossil fuel use will cease by the year 2200) will probably only impact the glacial period for about 5,000 years. Thus, a brief period of global warming induced through a few centuries worth of greenhouse gas emission would only have a limited impact in the long term.[10]

Obliquity

A small gray circle at the top represents the Moon. A green circle centered in a blue ellipse represents the Earth and its oceans. A curved arrow shows the counterclockwise direction of the Earth's rotation, resulting in the long axis of the ellipse being slightly out of alignment with the Moon.
The rotational offset of the tidal bulge exerts a net torque on the Moon, boosting it while slowing the Earth's rotation. This image is not to scale.

The tidal acceleration of the Moon slows the rotation rate of the Earth and increases the Earth-Moon distance. Friction effects—between the core and mantle and between the atmosphere and surface—can dissipate the Earth's rotational energy. These combined effects are expected to increase the length of the day by more than 1.5 hours over the next 250 million years, and to increase the obliquity by about a half degree. The distance to the Moon will increase by about 1.5 Earth radii during the same period.[39]

Based on computer models, the presence of the Moon appears to stabilize the obliquity of the Earth, which may help the planet to avoid dramatic climate changes.[40] This stability is achieved because the Moon increases the precession rate of the Earth's spin axis (that is, the precession motion of the ecliptic), thereby avoiding resonances between the precession of the spin and precession of the planet's orbital plane relative to that of Jupiter.[41] However, as the semimajor axis of the Moon's orbit continues to increase, this stabilizing effect will diminish. At some point, perturbation effects will probably cause chaotic variations in the obliquity of the Earth, and the axial tilt may change by angles as high as 90° from the plane of the orbit. This is expected to occur between 1.5 and 4.5 billion years from now.[42]

A high obliquity would probably result in dramatic changes in the climate and may destroy the planet's habitability.[33] When the axial tilt of the Earth exceeds 54°, the yearly insolation at the equator is less than that at the poles. The planet could remain at an obliquity of 60° to 90° for periods as long as 10 million years.[43]

Geodynamics

An irregular green shape against a blue background represents Pangaea.
Pangaea was the last supercontinent to form before the present.

Tectonics-based events will continue to occur well into the future and the surface will be steadily reshaped by tectonic uplift, extrusions, and erosion. Mount Vesuvius can be expected to erupt about 40 times over the next 1,000 years. During the same period, about five to seven earthquakes of magnitude 8 or greater should occur along the San Andreas Fault, while about 50 magnitude 9 events may be expected worldwide. Mauna Loa should experience about 200 eruptions over the next 1,000 years, and the Old Faithful Geyser will likely cease to operate. The Niagara Falls will continue to retreat upstream, reaching Buffalo in about 30,000–50,000 years.[9]

In 10,000 years, the post-glacial rebound of the Baltic Sea will have reduced the depth by about 90 m (300 ft). The Hudson Bay will decrease in depth by 100 m over the same period.[30] After 100,000 years, the island of Hawaii will have shifted about 9 km (5.6 mi) to the northwest. The planet may be entering another glacial period by this time.[9]

Continental drift

The theory of plate tectonics demonstrates that the continents of the Earth are moving across the surface at the rate of a few centimeters per year. This is expected to continue, causing the plates to relocate and collide. Continental drift is facilitated by two factors: the energy generation within the planet and the presence of a hydrosphere. With the loss of either of these, continental drift will come to a halt.[44] The production of heat through radiogenic processes is sufficient to maintain mantle convection and plate subduction for at least the next 1.1 billion years.[45]

At present, the continents of North and South America are moving westward from Africa and Europe. Researchers have produced several scenarios about how this will continue in the future.[46] These geodynamic models can be distinguished by the subduction flux, whereby the oceanic crust moves under a continent. In the introversion model, the younger, interior, Atlantic ocean becomes preferentially subducted and the current migration of North and South America is reversed. In the extroversion model, the older, exterior, Pacific ocean remains preferentially subducted and North and South America migrate toward eastern Asia.[47][48]

As the understanding of geodynamics improves, these models will be subject to revision. In 2008, for example, a computer simulation was used to predict that a reorganization of the mantle convection will occur over the next 100 million years, causing a supercontinent composed of Africa, Eurasia, Australia, Antarctica and South America to form around Antarctica.[49]

Regardless of the outcome of the continental migration, the continued subduction process causes water to be transported to the mantle. After a billion years from the present, a geophysical model gives an estimate that 27% of the current ocean mass will have been subducted. If this process were to continue unmodified into the future, the subduction and release would reach an equilibrium after 65% of the current ocean mass has been subducted.[50]

Introversion

A rough approximation of Pangaea Ultima, one of the three models for a future supercontinent.

Christopher Scotese and his colleagues have mapped out the predicted motions several hundred million years into the future as part of the Paleomap Project.[46] In their scenario, 50 million years from now the Mediterranean sea may vanish and the collision between Europe and Africa will create a long mountain range extending to the current location of the Persian Gulf. Australia will merge with Indonesia, and Baja California will slide northward along the coast. New subduction zones may appear off the eastern coast of North and South America, and mountain chains will form along those coastlines. To the south, the migration of Antarctica to the north will cause all of its ice sheets to melt. This, along with the melting of the Greenland ice sheets, will raise the average ocean level by 90 m (300 ft). The inland flooding of the continents will result in climate changes.[46]

As this scenario continues, by 100 million years from the present the continental spreading will have reached its maximum extent and the continents will then begin to coalesce. In 250 million years, North America will collide with Africa while South America will wrap around the southern tip of Africa. The result will be the formation of a new supercontinent (sometimes called Pangaea Ultima), with the Pacific Ocean stretching across half the planet. The continent of Antarctica will reverse direction and return to the South Pole, building up a new ice cap.[51]

Extroversion

The first scientist to extrapolate the current motions of the continents was Canadian geologist Paul F. Hoffman of Harvard University. In 1992, Hoffman predicted that the continents of North and South America would continue to advance across the Pacific Ocean, pivoting about Siberia until they begin to merge with Asia. He dubbed the resulting supercontinent, Amasia.[52][53] Later, in the 1990s, Roy Livermore calculated a similar scenario. He predicted that Antarctica would start to migrate northward, and east Africa and Madagascar would move across the Indian Ocean to collide with Asia.[54]

In an extroversion model, the closure of the Pacific Ocean would be complete in about 350 million years.[55] This marks the completion of the current supercontinent cycle, wherein the continents split apart and then rejoin each other about every 400–500 million years.[56] Once the supercontinent is built, plate tectonics may enter a period of inactivity as the rate of subduction drops by an order of magnitude. This period of stability could cause an increase in the mantle temperature at the rate of 30–100 °C (54–180 °F) every 100 million years, which is the minimum lifetime of past supercontinents. As a consequence, volcanic activity may increase.[48][55]

Supercontinent

The formation of a supercontinent can dramatically affect the environment. The collision of plates will result in mountain building, thereby shifting weather patterns. Sea levels may fall because of increased glaciation.[57] The rate of surface weathering can rise, resulting in an increase in the rate that organic material is buried. Supercontinents can cause a drop in global temperatures and an increase in atmospheric oxygen. This, in turn, can affect the climate, further lowering temperatures. All of these changes can result in more rapid biological evolution as new niches emerge.[58]

The formation of a supercontinent insulates the mantle. The flow of heat will be concentrated, resulting in volcanism and the flooding of large areas with basalt. Rifts will form and the supercontinent will split up once more.[59] The planet may then experience a warming period, as occurred during the Cretaceous period.[58]

Solidification of the outer core

The iron-rich core region of the Earth is divided into a 1,220 km (760 mi) radius solid inner core and a 3,480 km (2,160 mi) radius liquid outer core.[60] The rotation of the Earth creates convective eddies in the outer core region that cause it to function as a dynamo.[61] This generates a magnetosphere about the Earth that deflects particles from the solar wind, which prevents significant erosion of the atmosphere from sputtering. As heat from the core is transferred outward toward the mantle, the net trend is for the inner boundary of the liquid outer core region to freeze, thereby releasing thermal energy and causing the solid inner core to grow.[62] This iron crystallization process has been ongoing for about a billion years. In the modern era, the radius of the inner core is expanding at an average rate of roughly 0.5 mm (0.02 in) per year, at the expense of the outer core.[63] Nearly all of the energy needed to power the dynamo is being supplied by this process of inner core formation.[64]
The growth of the inner core may be expected to consume most of the outer core by some 3–4 billion years from now, resulting in a nearly solid core composed of iron and other heavy elements. The surviving liquid envelope will mainly consist of lighter elements that will undergo less mixing.[65] Alternatively, if at some point plate tectonics comes to an end, the interior will cool less efficiently, which may end the growth of the inner core. In either case, this can result in the loss of the magnetic dynamo. Without a functioning dynamo, the magnetic field of the Earth will decay in a geologically short time period of roughly 10,000 years.[66] The loss of the magnetosphere will cause an increase in erosion of light elements, particularly hydrogen, from the Earth's outer atmosphere into space, resulting in less favorable conditions for life.[67]

Solar evolution

The energy generation of the Sun is based upon thermonuclear fusion of hydrogen into helium. This occurs in the core region of the star using the proton–proton chain reaction process. Because there is no convection in the solar core, the helium concentration builds up in that region without being distributed throughout the star. The temperature at the core of the Sun is too low for nuclear fusion of helium atoms through the triple-alpha process, so these atoms do not contribute to the net energy generation that is needed to maintain hydrostatic equilibrium of the Sun.[68]
At present, nearly half the hydrogen at the core has been consumed, with the remainder of the atoms consisting primarily of helium. As the number of hydrogen atoms per unit mass decreases, so too does their energy output provided through nuclear fusion. This results in a decrease in pressure support, which causes the core to contract until the increased density and temperature bring the core pressure into equilibrium with the layers above. The higher temperature causes the remaining hydrogen to undergo fusion at a more rapid rate, thereby generating the energy needed to maintain the equilibrium.[68]
Evolution of the Sun's luminosity, radius and effective temperature compared to the present Sun. After Ribas (2010).[69]

The result of this process has been a steady increase in the energy output of the Sun. When the Sun first became a main sequence star, it radiated only 70% of the current luminosity. The luminosity has increased in a nearly linear fashion to the present, rising by 1% every 110 million years.[70] Likewise, in three billion years the Sun is expected to be 33% more luminous. The hydrogen fuel at the core will finally be exhausted in five billion years, when the Sun will be 67% more luminous than at present. Thereafter the Sun will continue to burn hydrogen in a shell surrounding its core, until the luminosity reaches 121% above the present value. This marks the end of the Sun's main sequence lifetime, and thereafter it will pass through the subgiant stage and evolve into a red giant.[1]

By this time, the collision of the Milky Way and Andromeda galaxies should be underway. Although this could result in the Solar System being ejected from the newly combined galaxy, it is considered unlikely to have any adverse effect on the Sun or planets.[71][72]

Climate impact

The rate of weathering of silicate minerals will increase as rising temperatures speed up chemical processes. This in turn will decrease the level of carbon dioxide in the atmosphere, as these weathering processes convert carbon dioxide gas into solid carbonates. Within the next 600 million years from the present, the concentration of CO
2
will fall below the critical threshold needed to sustain C3 photosynthesis: about 50 parts per million. At this point, trees and forests in their current forms will no longer be able to survive,[73] the last living trees being evergreen conifers.[74] However, C4 carbon fixation can continue at much lower concentrations, down to above 10 parts per million. Thus plants using C4 photosynthesis may be able to survive for at least 0.8 billion years and possibly as long as 1.2 billion years from now, after which rising temperatures will make the biosphere unsustainable.[75][76][77] Currently, C4 plants represent about 5% of Earth's plant biomass and 1% of its known plant species.[78] For example, about 50% of all grass species (Poaceae) use the C4 photosynthetic pathway,[79] as do many species in the herbaceous family Amaranthaceae.[80]

When the levels of carbon dioxide fall to the limit where photosynthesis is barely sustainable, the proportion of carbon dioxide in the atmosphere is expected to oscillate up and down. This will allow land vegetation to flourish each time the level of carbon dioxide rises due to tectonic activity and animal life. However, the long term trend is for the plant life on land to die off altogether as most of the remaining carbon in the atmosphere becomes sequestered in the Earth.[81] Some microbes are capable of photosynthesis at concentrations of CO
2
of a few parts per million, so these life forms would probably disappear only because of rising temperatures and the loss of the biosphere.[75]

Plants—and, by extension, animals—could survive longer by evolving other strategies such as requiring less CO
2
for photosynthetic processes, becoming carnivorous, adapting to desiccation, or associating with fungi. These adaptations are likely to appear near the beginning of the moist greenhouse (see further).[74]

The loss of plant life will also result in the eventual loss of oxygen as well as ozone due to the respiration of animals, chemical reactions in the atmosphere, and volcanic eruptions, meaning less attenuation of DNA-damaging ultraviolet radiation,[74] as well as the death of animals; the first animals to disappear would be large mammals, followed by small mammals, birds, amphibians and large fish, reptiles and small fish, and finally invertebrates. Before this happened it's expected that life would concentrate at refugia of lower temperature such as high elevations where less land surface area is available, thus restricting population sizes. Smaller animals would survive better than larger ones because of lesser oxygen requirements, while birds would fare better than mammals thanks to their ability to travel large distances looking for colder temperatures.[11]

In their work The Life and Death of Planet Earth, authors Peter D. Ward and Donald Brownlee have argued that some form of animal life may continue even after most of the Earth's plant life has disappeared. Ward and Brownlee use fossil evidence from the Burgess Shale in British Columbia, Canada, to determine the climate of the Cambrian Explosion, and use it to predict the climate of the future when rising global temperatures caused by a warming Sun and declining oxygen levels result in the final extinction of animal life. Initially, they expect that some insects, lizards, birds and small mammals may persist, along with sea life. However, without oxygen replenishment by plant life, they believe that animals would probably die off from asphyxiation within a few million years. Even if sufficient oxygen were to remain in the atmosphere through the persistence of some form of photosynthesis, the steady rise in global temperature would result in a gradual loss of biodiversity.[81]

As temperatures continue to rise, the last animal life will be driven back toward the poles, and possibly underground. They would become primarily active during the polar night, aestivating during the polar day due to the intense heat. Much of the surface would become a barren desert and life would primarily be found in the oceans.[81] However, due to a decrease of the amount or organic matter coming to the oceans from the land as well as oxygen in the water,[74] life would disappear there too following a similar path to that on Earth's surface. This process would start with the loss of freshwater species and conclude with invertebrates,[11] particularly those that do not depend on living plants such as termites or those near hydrothermal vents such as worms of the genus Riftia.[74] As a result of these processes, multi-cellular lifeforms may be extinct in about 800 million years, and eukaryotes in 1.3 billion years, leaving only the prokaryotes.[82]

Loss of oceans

Light brown clouds wrap around a planet, as seen from space.
The atmosphere of Venus is in a "supergreenhouse" state.

One billion years from now, about 27% of the modern ocean will have been subducted into the mantle. If this process were allowed to continue uninterrupted, it would reach an equilibrium state where 65% of the current surface reservoir would remain at the surface.[50] Once the solar luminosity is 10% higher than its current value, the average global surface temperature will rise to 320 K (47 °C; 116 °F). The atmosphere will become a "moist greenhouse" leading to a runaway evaporation of the oceans.[83][84] At this point, models of the Earth's future environment demonstrate that the stratosphere would contain increasing levels of water. These water molecules will be broken down through photodissociation by solar ultraviolet radiation, allowing hydrogen to escape the atmosphere. The net result would be a loss of the world's sea water by about 1.1 billion years from the present.[85][86] This will be a simple dramatic step in annihilating all life on Earth.

There will be two variations of this future warming feedback: the "moist greenhouse" where water vapor dominates the troposphere while water vapor starts to accumulate in the stratosphere (if the oceans evaporate very quickly), and the "runaway greenhouse" where water vapor becomes a dominant component of the atmosphere (if the oceans evaporate too slowly). The Earth will undergo rapid warming that could send its surface temperature to over 900 °C (1,650 °F) as the atmosphere will be totally overwhelmed by water vapor, causing its entire surface to melt and killing all life, perhaps in about three billion years. In this ocean-free era, there will continue to be surface reservoirs as water is steadily released from the deep crust and mantle,[50] where it is estimated there is an amount of water equivalent to several times that currently present in the Earth's oceans.[87] Some water may be retained at the poles and there may be occasional rainstorms, but for the most part the planet would be a dry desert with large dunefields covering its equator, and a few salt flats on what was once the ocean floor, similar to the ones in the Atacama Desert in Chile.[12]

With no water to lubricate them, plate tectonics would very likely stop and the most visible signs of geological activity would be shield volcanoes located above mantle hotspots.[74] In these arid conditions the planet may retain some microbial and possibly even multi-cellular life.[84] Most of these microbes will be halophiles and life could find too refuge in the atmosphere as has been proposed that could have happened on Venus.[74] However, the increasingly extreme conditions will likely lead to the extinction of the prokaryotes between 1.6 billion years[82] and 2.8 billion years from now, with the last of them living in residual ponds of water at high latitudes and heights or in caverns with trapped ice; underground life, however, could last longer.[11] What happens next depends on the level of tectonic activity. A steady release of carbon dioxide by volcanic eruption could cause the atmosphere to enter a "supergreenhouse" state like that of the planet Venus. But as stated above without surface water, plate tectonics would probably come to a halt and most of the carbonates would remain securely buried[12] until the Sun became a red giant and its increased luminosity heated the rock to the point of releasing the carbon dioxide.[87]

The loss of the oceans could be delayed until two billion years in the future if the total atmospheric pressure were to decline. A lower atmospheric pressure would reduce the greenhouse effect, thereby lowering the surface temperature. This could occur if natural processes were to remove the nitrogen from the atmosphere. Studies of organic sediments has shown that at least 100 kilopascals (0.99 atm) of nitrogen has been removed from the atmosphere over the past four billion years; enough to effectively double the current atmospheric pressure if it were to be released. This rate of removal would be sufficient to counter the effects of increasing solar luminosity for the next two billion years.[88]

By 2.8 billion years from now, the surface temperature of the Earth will have reached 422 K (149 °C; 300 °F), even at the poles. At this point, any remaining life will be extinguished due to the extreme conditions. If the Earth loses its surface water by this point, the planet will stay in the same conditions until the Sun becomes a red giant.[84] If this scenario doesn't happen, then in about 3–4 billion years the amount of water vapour in the lower atmosphere will rise to 40% and a moist greenhouse effect will commence[88] once the luminosity from the Sun reaches 35–40% more than its present-day value.[85] A "runaway greenhouse" effect will ensue, causing the atmosphere to heat up and raising the surface temperature to around 1,600 K (1,330 °C; 2,420 °F). This is sufficient to melt the surface of the planet.[86][84] However, most of the atmosphere will be retained until the Sun has entered the red giant stage.[89]

With the extinction of life, 2.8 billion years from now, it is also expected that Earth biosignatures will disappear, to be replaced by signatures caused by non-biological processes.[74]

Red giant stage

A large red disk represents the Sun as a red giant. An inset box shows the current Sun as a yellow dot.
The size of the current Sun (now in the main sequence) compared to its estimated size during its red giant phase

Once the Sun changes from burning hydrogen at its core to burning hydrogen around its shell, the core will start to contract and the outer envelope will expand. The total luminosity will steadily increase over the following billion years until it reaches 2,730 times the Sun's current luminosity at the age of 12.167 billion years. Most of Earth's atmosphere will be lost to space and its surface will consist of a lava ocean with floating continents of metals and metal oxides as well as icebergs of refractory materials, with its surface temperature reaching more than 2,400 K (2,130 °C; 3,860 °F).[90] The Sun will experience more rapid mass loss, with about 33% of its total mass shed with the solar wind. The loss of mass will mean that the orbits of the planets will expand. The orbital distance of the Earth will increase to at most 150% of its current value.[70]

The most rapid part of the Sun's expansion into a red giant will occur during the final stages, when the Sun will be about 12 billion years old. It is likely to expand to swallow both Mercury and Venus, reaching a maximum radius of 1.2 AU (180,000,000 km). The Earth will interact tidally with the Sun's outer atmosphere, which would serve to decrease Earth's orbital radius. Drag from the chromosphere of the Sun would also reduce the Earth's orbit. These effects will act to counterbalance the effect of mass loss by the Sun, and the Earth will probably be engulfed by the Sun.[70]

The drag from the solar atmosphere may cause the orbit of the Moon to decay. Once the orbit of the Moon closes to a distance of 18,470 km (11,480 mi), it will cross the Earth's Roche limit. This means that tidal interaction with the Earth would break apart the Moon, turning it into a ring system. Most of the orbiting ring will then begin to decay, and the debris will impact the Earth. Hence, even if the Earth is not swallowed up by the Sun, the planet may be left moonless.[91] The ablation and vaporization caused by its fall on a decaying trajectory towards the Sun may remove Earth's crust and mantle, then finally destroy it after at most 200 years.[92][93] Following this event, Earth's sole legacy will be a very slight increase (0.01%) of the solar metallicity.[94]§IIC

Alternatively, should the Earth survive being engulfed to the Sun, the ablation and vaporization mentioned before may strip both its crust and mantle leaving just its core.[93]

Post red-giant stage

The Helix nebula, a planetary nebula similar to what the Sun will produce in 8 billion years.

After fusing helium in its core to carbon, the Sun will begin to collapse again, evolving into a compact white dwarf star after ejecting its outer atmosphere as a planetary nebula. In 50 billion years, if the Earth and Moon are not engulfed by the Sun, they will become tidelocked, with each showing only one face to the other.[95][96] Thereafter, the tidal action of the Sun will extract angular momentum from the system, causing the lunar orbit to decay and the Earth's spin to accelerate.[97]

In about 65 billion years, it estimated that the Moon may end up colliding with the Earth, assuming they are not destroyed by the red giant Sun, due to the remaining energy of the Earth–Moon system being sapped by the remnant Sun, causing the Moon to slowly move inwards toward the Earth.[98]

Over time intervals of around 30 trillion years, the Sun will undergo a close encounter with another star. As a consequence, the orbits of their planets can become disrupted, potentially ejecting them from the system entirely.[99] If Earth is not destroyed by the expanding red giant Sun in 7.6 billion years and not ejected from its orbit by a stellar encounter, its ultimate fate will be that it collides with the black dwarf Sun due to the decay of its orbit via gravitational radiation, in 1020 (100 quintillion) years.[100]

Proto-metabolism

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