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Monday, December 7, 2020

Bhopal disaster

From Wikipedia, the free encyclopedia
 
Bhopal disaster
Bhopal-Union Carbide 1 crop memorial.jpg
Memorial by Dutch artist Ruth Kupferschmidt for those killed and disabled by the 1984 toxic gas release
Date2 December 1984 – 3 December 1984
LocationBhopal, Madhya Pradesh, India
Coordinates23°16′51″N 77°24′38″ECoordinates: 23°16′51″N 77°24′38″E
Also known asBhopal gas tragedy
CauseMethyl isocyanate leak from Union Carbide India Limited plant
DeathsAt least 3,787; over 16,000 claimed
Non-fatal injuriesAt least 558,125

The Bhopal disaster, also referred to as the Bhopal gas tragedy, was a gas leak incident on the night of 2–3 December 1984 at the Union Carbide India Limited (UCIL) pesticide plant in Bhopal, Madhya Pradesh, India. It is considered among the world's worst industrial disasters. Over 500,000 people were exposed to methyl isocyanate (MIC) gas. The highly toxic substance made its way into and around the small towns located near the plant.

Estimates vary on the death toll. The official immediate death toll was 2,259. In 2008, the Government of Madhya Pradesh had paid compensation to the family members of 3,787 victims killed in the gas release, and to 574,366 injured victims. A government affidavit in 2006 stated that the leak caused 558,125 injuries, including 38,478 temporary partial injuries and approximately 3,900 severely and permanently disabling injuries. Others estimate that 8,000 died within two weeks, and another 8,000 or more have since died from gas-related diseases. The cause of the disaster remains under debate. The Indian government and local activists argue that slack management and deferred maintenance created a situation where routine pipe maintenance caused a backflow of water into a MIC tank, triggering the disaster. Union Carbide Corporation (UCC) argues that water entered the tank through an act of sabotage.

The owner of the factory, UCIL, was majority owned by UCC, with Indian Government-controlled banks and the Indian public holding a 49.1 percent stake. In 1989, UCC paid $470 million (equivalent to $860 million in 2019) to settle litigation stemming from the disaster. In 1994, UCC sold its stake in UCIL to Eveready Industries India Limited (EIIL), which subsequently merged with McLeod Russel (India) Ltd. Eveready ended clean-up on the site in 1998, when it terminated its 99-year lease and turned over control of the site to the state government of Madhya Pradesh. Dow Chemical Company purchased UCC in 2001, seventeen years after the disaster.

Civil and criminal cases filed in the United States against UCC and Warren Anderson, UCC CEO at the time of the disaster, were dismissed and redirected to Indian courts on multiple occasions between 1986 and 2012, as the US courts focused on UCIL being a standalone entity of India. Civil and criminal cases were also filed in the District Court of Bhopal, India, involving UCC, UCIL and UCC CEO Anderson. In June 2010, seven Indian nationals who were UCIL employees in 1984, including the former UCIL chairman, were convicted in Bhopal of causing death by negligence and sentenced to two years imprisonment and a fine of about $2,000 each, the maximum punishment allowed by Indian law. All were released on bail shortly after the verdict. An eighth former employee was also convicted, but died before the judgement was passed.

Background

The UCIL factory was built in 1969 to produce the pesticide Sevin (UCC's brand name for carbaryl) using methyl isocyanate (MIC) as an intermediate. An MIC production plant was added to the UCIL site in 1979. The chemical process employed in the Bhopal plant had methylamine reacting with phosgene to form MIC, which was then reacted with 1-naphthol to form the final product, carbaryl. Another manufacturer, Bayer, also used this MIC-intermediate process at the chemical plant once owned by UCC at Institute, West Virginia, in the United States.

After the Bhopal plant was built, other manufacturers (including Bayer) produced carbaryl without MIC, though at a greater manufacturing cost. This "route" differed from the MIC-free routes used elsewhere, in which the same raw materials were combined in a different manufacturing order, with phosgene first reacting with naphthol to form a chloroformate ester, which was, in turn, reacted with methylamine. In the early 1980s, the demand for pesticides had fallen, but production continued regardless, leading to an accumulation of stores of unused MIC where that method was used.

Earlier leaks

In 1976, two local trade unions complained of pollution within the plant. In 1981, a worker was accidentally splashed with phosgene as he was carrying out a maintenance job of the plant's pipes. In a panic, he removed his gas mask and inhaled a large amount of toxic phosgene gas, leading to his death 72 hours later. Following these events, journalist Rajkumar Keswani began investigating and published his findings in Bhopal's local paper Rapat, in which he urged "Wake up, people of Bhopal, you are on the edge of a volcano."

In January 1982, a phosgene leak exposed 24 workers, all of whom were admitted to a hospital. None of the workers had been ordered to wear protective equipment. One month later, in February 1982, a MIC leak affected 18 workers. In August 1982, a chemical engineer came into contact with liquid MIC, resulting in burns over 30% of his body. In October 1982, there was another MIC leak. In attempting to stop the leak, the MIC supervisor suffered severe chemical burns and two other workers were severely exposed to the gases. During 1983 and 1984, there were leaks of MIC, chlorine, monomethylamine, phosgene, and carbon tetrachloride, sometimes in combination.

Leakage and its effects

Liquid MIC storage

The Bhopal UCIL facility housed three underground 68,000-litre (~18,000 gals) liquid MIC storage tanks: E610, E611, and E619. In the months leading up to the December leak, liquid MIC production was in progress and being used to fill these tanks. UCC safety regulations specified that no one tank should be filled more than 50% (here, 30 tons) with liquid MIC. Each tank was pressurized with inert nitrogen gas. This pressurization allowed liquid MIC to be pumped out of each tank as needed, and also kept impurities out of the tanks.

In late October 1984, tank E610 lost the ability to effectively contain most of its nitrogen gas pressure, which meant that the liquid MIC contained within could not be pumped out. At the time of this failure, tank E610 contained 42 tons of liquid MIC. Shortly after this failure, MIC production was halted at the Bhopal facility, and parts of the plant were shut down for maintenance. Maintenance included the shutdown of the plant's flare tower so that a corroded pipe could be repaired. With the flare tower still out of service, production of carbaryl was resumed in late November, using MIC stored in the two tanks still in service. An attempt to re-establish pressure in tank E610 on 1 December failed, so the 42 tons of liquid MIC contained within still could not be pumped out of it.

The release

Tank 610 in 2010. During decontamination of the plant, tank 610 was removed from its foundation and left aside.
 
Methylamine (1) reacts with phosgene (2) producing methyl isocyanate (3) which reacts with 1-naphthol (4) to yield carbaryl (5).

By early December 1984, most of the plant's MIC related safety systems were malfunctioning and many valves and lines were in poor condition. In addition, several vent gas scrubbers had been out of service as well as the steam boiler, intended to clean the pipes. During the late evening hours of 2 December 1984, water was believed to have entered a side pipe and into Tank E610 whilst trying to unclog it, which contained 42 tons of MIC that had been there since late October. The introduction of water into the tank subsequently resulted in a runaway exothermic reaction, which was accelerated by contaminants, high ambient temperatures and various other factors, such as the presence of iron from corroding non-stainless steel pipelines. The pressure in tank E610, although initially nominal at 2 psi at 10:30 p.m., it had reached 10 psi by 11 p.m. Two different senior refinery employees assumed the reading was instrumentation malfunction. By 11:30 p.m., workers in the MIC area were feeling the effects of minor exposure to MIC gas, and began to look for a leak. One was found by 11:45 p.m., and reported to the MIC supervisor on duty at the time. The decision was made to address the problem after a 12:15 a.m. tea break, and in the meantime, employees were instructed to continue looking for leaks. The incident was discussed by MIC area employees during the break.

In the five minutes after the tea break ended at 12:40 a.m., the reaction in tank E610 reached a critical state at an alarming speed. Temperatures in the tank were off the scale, maxed out beyond 25 °C (77 °F), and the pressure in the tank was indicated at 40 psi (275.8 kPa). One employee witnessed a concrete slab above tank E610 crack as the emergency relief valve burst open, and pressure in the tank continued to increase to 55 psi (379.2 kPa); this despite the fact that atmospheric venting of toxic MIC gas had already begun. Direct atmospheric venting should have been prevented or at least partially mitigated by at least three safety devices which were malfunctioning, not in use, insufficiently sized or otherwise rendered inoperable:

  • A refrigeration system meant to cool tanks containing liquid MIC, shut down in January 1982, and whose freon had been removed in June 1984. Since the MIC storage system assumed refrigeration, its high temperature alarm, set to sound at 11 °C (52 °F) had long since been disconnected, and tank storage temperatures ranged between 15 °C (59 °F) and 40 °C (104 °F)
  • A flare tower, to burn the MIC gas as it escaped, which had had a connecting pipe removed for maintenance, and was improperly sized to neutralise a leak of the size produced by tank E610
  • A vent gas scrubber, which had been deactivated at the time and was in 'standby' mode, and similarly had insufficient caustic soda and power to safely stop a leak of the magnitude produced

About 30 tonnes of MIC escaped from the tank into the atmosphere in 45 to 60 minutes. This would increase to 40 tonnes within two hours. The gases were blown in a southeasterly direction over Bhopal.

A UCIL employee triggered the plant's alarm system at 12:50 a.m. as the concentration of gas in and around the plant became difficult to tolerate. Activation of the system triggered two siren alarms: one that sounded inside the UCIL plant itself, and a second directed to the exterior, which would alert the public and the city of Bhopal. The two siren systems had been decoupled from one another in 1982, so that it was possible to leave the factory warning siren on while turning off the public one, and this is exactly what was done: the public siren briefly sounded at 12:50 a.m. and was quickly turned off, as per company procedure meant to avoid alarming the public around the factory over tiny leaks. Workers, meanwhile, evacuated the UCIL plant, travelling upwind.

Bhopal's superintendent of police was informed by telephone, by a town inspector, that residents of the neighbourhood of Chola (about 2 km from the plant) were fleeing a gas leak at approximately 1 a.m. Calls to the UCIL plant by police between 1:25 and 2:10 a.m. gave assurances twice that "everything is OK", and on the last attempt made, "we don't know what has happened, sir". With the lack of timely information exchange between UCIL and Bhopal authorities, the city's Hamidia Hospital was first told that the gas leak was suspected to be ammonia, then phosgene. Finally, they received an updated report that it was "MIC" (rather than "methyl isocyanate"), of which hospital staff had never heard of and had no antidote for, nor did they receive any immediate information about it.

The MIC gas leak emanating from tank E610 petered out at approximately 2:00 a.m. Fifteen minutes later, the plant's public siren was sounded for an extended period of time, after first having been quickly silenced an hour and a half earlier. Some minutes after the public siren sounded, a UCIL employee walked to a police control room to both inform them of the leak (their first acknowledgement that one had occurred at all), and that "the leak had been plugged." Most city residents who were exposed to the MIC gas were first made aware of the leak by exposure to the gas itself, or by opening their doors to investigate commotion, rather than having been instructed to shelter in place, or to evacuate before the arrival of the gas in the first place.

Acute effects

Reversible reaction of glutathione (top) with methyl isocyanate (MIC, middle) allows the MIC to be transported into the body.

The initial effects of exposure were coughing, severe eye irritation and a feeling of suffocation, burning in the respiratory tract, blepharospasm, breathlessness, stomach pains and vomiting. People awakened by these symptoms fled away from the plant. Those who ran inhaled more than those who had a vehicle to ride. Owing to their height, children and other residents of shorter stature inhaled higher concentrations, as methyl isocyanate gas is approximately twice as dense as air and, therefore, in an open environment has a tendency to fall toward the ground.

Thousands of people had died by the following morning. Primary causes of deaths were choking, reflexogenic circulatory collapse and pulmonary oedema. Findings during autopsies revealed changes not only in the lungs but also cerebral oedema, tubular necrosis of the kidneys, fatty degeneration of the liver and necrotising enteritis. The stillbirth rate increased by up to 300% and neonatal mortality rate by around 200%.

Gas cloud composition

Apart from MIC, based on laboratory simulation conditions, the gas cloud most likely also contained chloroform, dichloromethane, hydrogen chloride, methylamine, dimethylamine, trimethylamine and carbon dioxide, that was either present in the tank or was produced in the storage tank when MIC, chloroform and water reacted. The gas cloud, composed mainly of materials denser than air, stayed close to the ground and spread in the southeasterly direction affecting the nearby communities. The chemical reactions may have produced a liquid or solid aerosol. Laboratory investigations by CSIR and UCC scientists failed to demonstrate the presence of hydrogen cyanide.

Immediate aftermath

In the immediate aftermath, the plant was closed to outsiders (including UCC) by the Indian government, which subsequently failed to make data public, contributing to the confusion. The initial investigation was conducted entirely by the Council of Scientific and Industrial Research (CSIR) and the Central Bureau of Investigation. The UCC chairman and CEO Warren Anderson, together with a technical team, immediately travelled to India. Upon arrival Anderson was placed under house arrest and urged by the Indian government to leave the country within 24 hours. Union Carbide organized a team of international medical experts, as well as supplies and equipment, to work with the local Bhopal medical community, and the UCC technical team began assessing the cause of the gas leak.

The health care system immediately became overloaded. In the severely affected areas, nearly 70% were under-qualified doctors. Medical staff were unprepared for the thousands of casualties. Doctors and hospitals were not aware of proper treatment methods for MIC gas inhalation.

There were mass funerals and cremations. Photographer Pablo Bartholemew, on commission with press agency Rapho, took an iconic color photograph of a burial on 4 December, Bhopal gas disaster girl. Another photographer present, Raghu Rai, took a black and white photo. The photographers did not ask for the identity of the father or child as she was buried, and no relative has since confirmed it. As such, the identity of the girl remains unknown. Both photos became symbolic of the suffering of victims of the Bhopal disaster, and Bartholomew's went on to win the 1984 World Press Photo of the Year.

Within a few days, trees in the vicinity became barren and bloated animal carcasses had to be disposed of. 170,000 people were treated at hospitals and temporary dispensaries, and 2,000 buffalo, goats, and other animals were collected and buried. Supplies, including food, became scarce owing to suppliers' safety fears. Fishing was prohibited causing further supply shortages.

Lacking any safe alternative, on 16 December, tanks 611 and 619 were emptied of the remaining MIC by reactivating the plant and continuing the manufacture of pesticide. Despite safety precautions such as having water-carrying helicopters continually overflying the plant, this led to a second mass evacuation from Bhopal. The Government of India passed the "Bhopal Gas Leak Disaster Act" that gave the government rights to represent all victims, whether or not in India. Complaints of lack of information or misinformation were widespread. An Indian government spokesman said, "Carbide is more interested in getting information from us than in helping our relief work".

Formal statements were issued that air, water, vegetation and foodstuffs were safe, but warned not to consume fish. The number of children exposed to the gases was at least 200,000. Within weeks, the State Government established a number of hospitals, clinics and mobile units in the gas-affected area to treat the victims.

Subsequent legal action

Number of women pictured in black and white colour, sitting and protesting against Anderson and the company.
Victims of Bhopal disaster march in September 2006 demanding the extradition of American Warren Anderson from the United States.

Legal proceedings involving UCC, the United States and Indian governments, local Bhopal authorities, and the disaster victims started immediately after the catastrophe. The Indian Government passed the Bhopal Gas Leak Act in March 1985, allowing the Government of India to act as the legal representative for victims of the disaster, leading to the beginning of legal proceedings. Initial lawsuits were generated in the United States federal court system. On 17 April 1985, Federal District court judge John F. Keenan (overseeing one lawsuit) suggested that "'fundamental human decency' required Union Carbide to provide between $5 million and $10 million to immediately help the injured" and suggested the money could be quickly distributed through the International Red Cross. UCC, on the notion that doing so did not constitute an admission of liability and the figure could be credited toward any future settlement or judgement, offered a $5 million relief fund two days later. The Indian government turned down the offer.

In March 1986, UCC proposed a settlement figure, endorsed by plaintiffs' U.S. attorneys, of $350 million that would, according to the company, "generate a fund for Bhopal victims of between $500–600 million over 20 years". In May, litigation was transferred from the United States to Indian courts by a U.S. District Court ruling. Following an appeal of this decision, the U.S. Court of Appeals affirmed the transfer, judging, in January 1987, that UCIL was a "separate entity, owned, managed and operated exclusively by Indian citizens in India".

The Government of India refused the offer from Union Carbide and claimed US$3.3 billion. The Indian Supreme Court told both sides to come to an agreement and "start with a clean slate" in November 1988. Eventually, in an out-of-court settlement reached in February 1989, Union Carbide agreed to pay US$470 million for damages caused in the Bhopal disaster. The amount was immediately paid.

Throughout 1990, the Indian Supreme Court heard appeals against the settlement. In October 1991, the Supreme Court upheld the original $470 million, dismissing any other outstanding petitions that challenged the original decision. The Court ordered the Indian government "to purchase, out of settlement fund, a group medical insurance policy to cover 100,000 persons who may later develop symptoms" and cover any shortfall in the settlement fund. It also requested UCC and its subsidiary UCIL "voluntarily" fund a hospital in Bhopal, at an estimated $17 million, to specifically treat victims of the Bhopal disaster. The company agreed to this.

Post-settlement activity

In 1991, the local Bhopal authorities charged Anderson, who had retired in 1986, with manslaughter, a crime that carries a maximum penalty of 10 years in prison. He was declared a fugitive from justice by the Chief Judicial Magistrate of Bhopal on 1 February 1992 for failing to appear at the court hearings in a culpable homicide case in which he was named the chief defendant. Orders were passed to the Government of India to press for an extradition from the United States. The U.S. Supreme Court refused to hear an appeal of the decision of the lower federal courts in October 1993, meaning that victims of the Bhopal disaster could not seek damages in a U.S. court.

In 2004, the Indian Supreme Court ordered the Indian government to release any remaining settlement funds to victims. And in September 2006, the Welfare Commission for Bhopal Gas Victims announced that all original compensation claims and revised petitions had been "cleared". The Second Circuit Court of Appeals in New York City upheld the dismissal of remaining claims in the case of Bano v. Union Carbide Corporation in 2006. This move blocked plaintiffs' motions for class certification and claims for property damages and remediation. In the view of UCC, "the ruling reaffirms UCC's long-held positions and finally puts to rest—both procedurally and substantively—the issues raised in the class action complaint first filed against Union Carbide in 1999 by Haseena Bi and several organisations representing the residents of Bhopal".

In June 2010, seven former employees of UCIL, all Indian nationals and many in their 70s, were convicted of causing death by negligence: Keshub Mahindra, former non-executive chairman of Union Carbide India Limited; V. P. Gokhale, managing director; Kishore Kamdar, vice-president; J. Mukund, works manager; S. P. Chowdhury, production manager; K. V. Shetty, plant superintendent; and S. I. Qureshi, production assistant. They were each sentenced to two years’ imprisonment and fined 100,000 (equivalent to 180,000 or US$2,500 in 2019). All were released on bail shortly after the verdict.

US federal class action litigation, Sahu v. Union Carbide and Warren Anderson, was filed in 1999 under the U.S. Alien Torts Claims Act (ATCA), which provides for civil remedies for "crimes against humanity." It sought damages for personal injury, medical monitoring and injunctive relief in the form of clean-up of the drinking water supplies for residential areas near the Bhopal plant. The lawsuit was dismissed in 2012 and the subsequent appeal was denied. Former UCC CEO Anderson, then 92 years old, died on 29 September 2014.

Long-term effects

In 2018, The Atlantic called it the "world’s worst industrial disaster."

Long-term health effects

Some data about the health effects are still not available. The Indian Council of Medical Research (ICMR) was forbidden to publish health effect data until 1994.

A total of 36 wards were marked by the authorities as being "gas affected," affecting a population of 520,000. Of these, 200,000 were below 15 years of age, and 3,000 were pregnant women. The official immediate death toll was 2,259, and in 1991, 3,928 deaths had been officially certified. Ingrid Eckerman estimated 8,000 died within two weeks.

The government of Madhya Pradesh confirmed a total of 3,787 deaths related to the gas release.

Later, the affected area was expanded to include 700,000 citizens. A government affidavit in 2006 stated the leak caused 558,125 injuries including 38,478 temporary partial injuries and approximately 3,900 severely and permanently disabling injuries.

A cohort of 80,021 exposed people was registered, along with a control group, a cohort of 15,931 people from areas not exposed to MIC. Nearly every year since 1986, they have answered the same questionnaire. It shows overmortality and overmorbidity in the exposed group. Bias and confounding factors cannot be excluded from the study. Because of migration and other factors, 75% of the cohort is lost, as the ones who moved out are not followed.

A number of clinical studies are performed. The quality varies, but the different reports support each other. Studied and reported long-term health effects are:

Missing or insufficient fields for research are female reproduction, chromosomal aberrations, cancer, immune deficiency, neurological sequelae, post traumatic stress disorder (PTSD) and children born after the disaster. Late cases that might never be highlighted are respiratory insufficiency, cardiac insufficiency (cor pulmonale), cancer and tuberculosis. Bhopal now has high rates of birth defects and records a miscarriage rate 7x higher than the national average.

A 2014 report in Mother Jones quotes a "spokesperson for the Bhopal Medical Appeal, which runs free health clinics for survivors" as saying "An estimated 120,000 to 150,000 survivors still struggle with serious medical conditions including nerve damage, growth problems, gynecological disorders, respiratory issues, birth defects, and elevated rates of cancer and tuberculosis."

Health care

The Government of India had focused primarily on increasing the hospital-based services for gas victims thus hospitals had been built after the disaster. When UCC wanted to sell its shares in UCIL, it was directed by the Supreme Court to finance a 500-bed hospital for the medical care of the survivors. Thus, Bhopal Memorial Hospital and Research Centre (BMHRC) was inaugurated in 1998 and was obliged to give free care for survivors for eight years. BMHRC was a 350-bedded super speciality hospital where heart surgery and hemodialysis were done. There was a dearth of gynaecology, obstetrics and paediatrics. Eight mini-units (outreach health centres) were started and free health care for gas victims were to be offered until 2006. The management had also faced problems with strikes, and the quality of the health care being disputed. Sambhavna Trust is a charitable trust, registered in 1995, that gives modern as well as ayurvedic treatments to gas victims, free of charge.

Environmental rehabilitation

When the factory was closed in 1986, pipes, drums and tanks were sold. The MIC and the Sevin plants are still there, as are storages of different residues. Isolation material is falling down and spreading. The area around the plant was used as a dumping area for hazardous chemicals. In 1982 tubewells in the vicinity of the UCIL factory had to be abandoned and tests in 1989 performed by UCC's laboratory revealed that soil and water samples collected from near the factory and inside the plant were toxic to fish. Several other studies had also shown polluted soil and groundwater in the area. Reported polluting compounds include 1-naphthol, naphthalene, Sevin, tarry residue, mercury, toxic organochlorines, volatile organochlorine compounds, chromium, copper, nickel, lead, hexachloroethane, hexachlorobutadiene, and the pesticide HCH.

In order to provide safe drinking water to the population around the UCIL factory, Government of Madhya Pradesh presented a scheme for improvement of water supply. In December 2008, the Madhya Pradesh High Court decided that the toxic waste should be incinerated at Ankleshwar in Gujarat, which was met by protests from activists all over India. On 8 June 2012, the Centre for incineration of toxic Bhopal waste agreed to pay 250 million (US$3.5 million) to dispose of UCIL chemical plants waste in Germany. On 9 August 2012, Supreme court directed the Union and Madhya Pradesh Governments to take immediate steps for disposal of toxic waste lying around and inside the factory within six months.

A U.S. court rejected the lawsuit blaming UCC for causing soil and water pollution around the site of the plant and ruled that responsibility for remedial measures or related claims rested with the State Government and not with UCC. In 2005, the state government invited various Indian architects to enter their "concept for development of a memorial complex for Bhopal gas tragedy victims at the site of Union Carbide". In 2011, a conference was held on the site, with participants from European universities which was aimed for the same.

Occupational and habitation rehabilitation

33 of the 50 planned work-sheds for gas victims started. All except one was closed down by 1992. 1986, the MP government invested in the Special Industrial Area Bhopal. 152 of the planned 200 work sheds were built and in 2000, 16 were partially functioning. It was estimated that 50,000 persons need alternative jobs, and that less than 100 gas victims had found regular employment under the government's scheme. The government also planned 2,486 flats in two- and four-story buildings in what is called the "widow's colony" outside Bhopal. The water did not reach the upper floors and it was not possible to keep cattle which were their primary occupation. Infrastructure like buses, schools, etc. were missing for at least a decade.

Economic rehabilitation

Immediate relieves were decided two days after the tragedy. Relief measures commenced in 1985 when food was distributed for a short period along with ration cards. Madhya Pradesh government's finance department allocated 874 million (US$12 million) for victim relief in July 1985. Widow pension of 200 (US$2.80)/per month (later 750 (US$11)) were provided. The government also decided to pay 1,500 (US$21) to families with monthly income 500 (US$7.00) or less. As a result of the interim relief, more children were able to attend school, more money was spent on treatment and food, and housing also eventually improved. From 1990 interim relief of 200 (US$2.80) was paid to everyone in the family who was born before the disaster.

The final compensation, including interim relief for personal injury was for the majority 25,000 (US$350). For death claim, the average sum paid out was 62,000 (US$870). Each claimant were to be categorised by a doctor. In court, the claimants were expected to prove "beyond reasonable doubt" that death or injury in each case was attributable to exposure. In 1992, 44 percent of the claimants still had to be medically examined.

By the end of October 2003, according to the Bhopal Gas Tragedy Relief and Rehabilitation Department, compensation had been awarded to 554,895 people for injuries received and 15,310 survivors of those killed. The average amount to families of the dead was $2,200.

In 2007, 1,029,517 cases were registered and decided. Number of awarded cases were 574,304 and number of rejected cases 455,213. Total compensation awarded was 15,465 million (US$220 million). On 24 June 2010, the Union Cabinet of the Government of India approved a 12,650 million (US$180 million) aid package which would be funded by Indian taxpayers through the government.

Other impacts

In 1985, Henry Waxman, a California Democrat, called for a U.S. government inquiry into the Bhopal disaster, which resulted in U.S. legislation regarding the accidental release of toxic chemicals in the United States.

Causes

There are two main lines of argument involving the disaster. The "Corporate Negligence" point of view argues that the disaster was caused by a potent combination of under-maintained and decaying facilities, a weak attitude towards safety, and an undertrained workforce, culminating in worker actions that inadvertently enabled water to penetrate the MIC tanks in the absence of properly working safeguards.

The "Worker Sabotage" point of view, held by Union Carbide, argues that it was not physically possible for the water to enter the tank without concerted human effort, and that extensive testimony and engineering analysis leads to a conclusion that water entered the tank when a rogue individual employee hooked a water hose directly to an empty valve on the side of the tank. This point of view further argues that the Indian government took extensive actions to hide this possibility in order to attach blame to UCC.

Theories differ as to how the water entered the tank. At the time, workers were cleaning out a clogged pipe with water about 400 feet from the tank. They claimed that they were not told to isolate the tank with a pipe slip-blind plate. The operators assumed that owing to bad maintenance and leaking valves, it was possible for the water to leak into the tank.

This water entry route could not be reproduced despite strenuous efforts by motivated parties. UCC claims that a "disgruntled worker" deliberately connecting a hose to a pressure gauge connection was the real cause.

Early the next morning, a UCIL manager asked the instrument engineer to replace the gauge. UCIL's investigation team found no evidence of the necessary connection; the investigation was totally controlled by the government, denying UCC investigators access to the tank or interviews with the operators.

Corporate negligence

This point of view argues that management (and to some extent, local government) underinvested in safety, which allowed for a dangerous working environment to develop. Factors cited include the filling of the MIC tanks beyond recommended levels, poor maintenance after the plant ceased MIC production at the end of 1984, allowing several safety systems to be inoperable due to poor maintenance, and switching off safety systems to save money— including the MIC tank refrigeration system which could have mitigated the disaster severity, and non-existent catastrophe management plans. Other factors identified by government inquiries included undersized safety devices and the dependence on manual operations. Specific plant management deficiencies that were identified include the lack of skilled operators, reduction of safety management, insufficient maintenance, and inadequate emergency action plans.

Underinvestment

Underinvestment is cited as contributing to an environment. In attempts to reduce expenses, $1.25 million of cuts were placed upon the plant which affected the factory's employees and their conditions. Kurzman argues that "cuts ... meant less stringent quality control and thus looser safety rules. A pipe leaked? Don't replace it, employees said they were told ... MIC workers needed more training? They could do with less. Promotions were halted, seriously affecting employee morale and driving some of the most skilled ... elsewhere". Workers were forced to use English manuals, even though only a few had a grasp of the language.

Subsequent research highlights a gradual deterioration of safety practices in regard to the MIC, which had become less relevant to plant operations. By 1984, only six of the original twelve operators were still working with MIC and the number of supervisory personnel had also been halved. No maintenance supervisor was placed on the night shift and instrument readings were taken every two hours, rather than the previous and required one-hour readings. Workers made complaints about the cuts through their union but were ignored. One employee was fired after going on a 15-day hunger strike. 70% of the plant's employees were fined before the disaster for refusing to deviate from the proper safety regulations under pressure from the management.

In addition, some observers, such as those writing in the Trade Environmental Database (TED) Case Studies as part of the Mandala Project from American University, have pointed to "serious communication problems and management gaps between Union Carbide and its Indian operation", characterised by "the parent companies [sic] hands-off approach to its overseas operation" and "cross-cultural barriers".

Adequacy of equipment and regulations

The factory was not well equipped to handle the gas created by the sudden addition of water to the MIC tank. The MIC tank alarms had not been working for four years and there was only one manual back-up system, compared to a four-stage system used in the United States. The flare tower and several vent gas scrubbers had been out of service for five months before the disaster. Only one gas scrubber was operating: it could not treat such a large amount of MIC with sodium hydroxide (caustic soda), which would have brought the concentration down to a safe level. The flare tower could only handle a quarter of the gas that leaked in 1984, and moreover it was out of order at the time of the incident. To reduce energy costs, the refrigeration system was idle. The MIC was kept at 20 degrees Celsius, not the 4.5 degrees advised by the manual. Even the steam boiler, intended to clean the pipes, was non-operational for unknown reasons. Slip-blind plates that would have prevented water from pipes being cleaned from leaking into the MIC tanks, had the valves been faulty, were not installed and their installation had been omitted from the cleaning checklist. As MIC is water-soluble, deluge guns were in place to contain escaping gases from the stack. The water pressure was too weak for the guns to spray high enough to reach the gas which would have reduced the concentration of escaping gas significantly. In addition to it, carbon steel valves were used at the factory, even though they were known to corrode when exposed to acid.

According to the operators, the MIC tank pressure gauge had been malfunctioning for roughly a week. Other tanks were used, rather than repairing the gauge. The build-up in temperature and pressure is believed to have affected the magnitude of the gas release. UCC admitted in their own investigation report that most of the safety systems were not functioning on the night of 3 December 1984. The design of the MIC plant, following government guidelines, was "Indianized" by UCIL engineers to maximise the use of indigenous materials and products. Mumbai-based Humphreys and Glasgow Consultants Pvt. Ltd., were the main consultants, Larsen & Toubro fabricated the MIC storage tanks, and Taylor of India Ltd. provided the instrumentation. In 1998, during civil action suits in India, it emerged that the plant was not prepared for problems. No action plans had been established to cope with incidents of this magnitude. This included not informing local authorities of the quantities or dangers of chemicals used and manufactured at Bhopal.

Safety audits

Safety audits were done every year in the US and European UCC plants, but only every two years in other parts of the world. Before a "Business Confidential" safety audit by UCC in May 1982, the senior officials of the corporation were well aware of "a total of 61 hazards, 30 of them major and 11 minor in the dangerous phosgene/methyl isocyanate units" in Bhopal. In the audit 1982, it was indicated that worker performance was below standards. Ten major concerns were listed. UCIL prepared an action plan, but UCC never sent a follow-up team to Bhopal. Many of the items in the 1982 report were temporarily fixed, but by 1984, conditions had again deteriorated. In September 1984, an internal UCC report on the West Virginia plant in the United States revealed a number of defects and malfunctions. It warned that "a runaway reaction could occur in the MIC unit storage tanks, and that the planned response would not be timely or effective enough to prevent catastrophic failure of the tanks". This report was never forwarded to the Bhopal plant, although the main design was the same.

Impossibility of the "negligence"

According to the "Corporate Negligence" argument, workers had been cleaning out pipes with water nearby. This water was diverted due to a combination of improper maintenance, leaking and clogging, and eventually ended up in the MIC storage tank. Indian scientists also suggested that additional water might have been introduced as a "back-flow" from a defectively designed vent-gas scrubber. None of these theoretical routes of entry were ever successfully demonstrated during tests by the Central Bureau of Investigation (CBI) and UCIL engineers.

A Union Carbide commissioned analysis conducted by Arthur D. Little claims that the Negligence argument was impossible for several tangible reasons:

  1. The pipes being used by the nearby workers were only 1/2 inch in diameter and were physically incapable of producing enough hydraulic pressure to raise water the more than 10 feet that would have been necessary to enable the water to "backflow" into the MIC tank.
  2. A key intermediate valve would have had to be open for the Negligence argument to apply. This valve was "tagged" closed, meaning that it had been inspected and found to be closed. While it is possible for open valves to clog over time, the only way a closed valve allows penetration is if there is leakage, and 1985 tests carried out by the government of India found this valve to be non-leaking.
  3. In order for water to have reached the MIC tank from the pipe-cleaning area, it would have had to flow through a significant network of pipes ranging from 6 to 8 inches in diameter, before rising ten feet and flowing into the MIC tank. Had this occurred, most of the water that was in those pipes at the time the tank had its critical reaction would have remained in those pipes, as there was no drain for them. Investigation by the Indian government in 1985 revealed that the pipes were bone dry.

Employee sabotage

Now owned by Dow Chemical Company, Union Carbide maintains a website dedicated to the tragedy and claims that the incident was the result of sabotage, stating that sufficient safety systems were in place and operative to prevent the intrusion of water.

The Union Carbide-commissioned Arthur D. Little report concluded that it was likely that a single employee secretly and deliberately introduced a large amount of water into the MIC tank by removing a meter and connecting a water hose directly to the tank through the metering port.

UCC claims the plant staff falsified numerous records to distance themselves from the incident and absolve themselves of blame, and that the Indian government impeded its investigation and declined to prosecute the employee responsible, presumably because it would weaken its allegations of negligence by Union Carbide.

The evidence advanced by UCC, alleged to support this hypothesis:

  1. A key witness testified that when he entered the control room at 12:15 am, prior to the disaster, the "atmosphere was tense and quiet".
  2. Another key witness (the "instrument supervisor") testified that when he arrived at the scene immediately following the incident, he noticed that the local pressure indicator on the critical Tank 610 was missing, and that he had found a hose lying next to the empty manhead created by the missing pressure indicator, and that the hose had had water running out of it. (This testimony was corroborated by other witnesses.)
  3. Graphological analysis revealed major attempts to alter logfiles and destroy log evidence.
  4. Other logfiles show that the control team had attempted to purge 1 ton of material out of Tank 610 immediately prior to the disaster. An attempt was then made to cover up this transfer via log alteration. Water is heavier than MIC, and the transfer line is attached to the bottom of the tank. The Arthur D. Little report concludes from this that the transfer was an effort to transfer water out of Tank 610 that had been discovered there.
  5. Second-hand and third-hand recounting of events yielded two accounts that corroborated UCC's conspiracy hypothesis; an operator from a different unit stated that after the release, two MIC operators had told him that water had entered the tank through a pressure gauge. One employee from stated that "he had been told by a close friend of one of the MIC operators that water had entered through a tube that had been connected to the tank." This had been allegedly discovered by the other MIC operators who then tried to open and close valves to prevent the release.

The Little report argues that this evidence demonstrates that the following chronology took place:

  • At 10:20pm, the tank was at normal pressure, indicating the absence of water.
  • At 10:45pm, a shift change took place, after which the MIC storage area "would be completely deserted". During this period, a "disgruntled operator entered the storage area and hooked up one of the readily available rubber water hoses to Tank 610, with the intention of contaminating and spoiling the tank's contents."
  • Water began to flow, beginning the chemical reaction that caused the disaster.
  • After midnight, control room operators noticed the pressure rising and realized there was a problem with Tank 610. They discovered the water connection, and decided to transfer one ton of the contents out to try and remove the water. The MIC release then occurred.
  • The cover-up activities discovered during the investigation then took place.
  • After over 30 years, in November 2017, S. P. Choudhary, former MIC production manager, claimed in court that the disaster was not an accident but the result of a sabotage that claimed thousands of lives.

Chaudry's counsel, Anirban Roy, argued that the theory of design defects was floated by the central government in its endeavour to protect the victims of the tragedy. Everyone else who was part of investigations into the case "just toed the line of the central government.... The government and the CBI suppressed the actual truth and saved the real perpetrators of the crime."

Roy argued to the district court that disgruntled plant operator M. L. Verma was behind the sabotage because he was unhappy with senior management. The counsel argued that there were discrepancies in the statements given by persons who were operating the plant at that time but the central agency chose not to investigate the case properly because it always wanted to prove that it was a mishap, and not sabotage. He alleged that Verma was unhappy with Chaudhary and Mukund.

Additional Union Carbide actions

The corporation denied the claim that the valves on the tank were malfunctioning, and claimed that the documented evidence gathered after the incident showed that the valve close to the plant's water-washing operation was closed and was leak-tight. Furthermore, process safety systems had prevented water from entering the tank by accident. Carbide states that the safety concerns identified in 1982 were all allayed before 1984 and had nothing to do with the incident.

The company admitted that the safety systems in place would not have been able to prevent a chemical reaction of that magnitude from causing a leak. According to Carbide, "in designing the plant's safety systems, a chemical reaction of this magnitude was not factored in" because "the tank's gas storage system was designed to automatically prevent such a large amount of water from being inadvertently introduced into the system" and "process safety systems—in place and operational—would have prevented water from entering the tank by accident". Instead, they claim that "employee sabotage—not faulty design or operation—was the cause of the tragedy".

Tactical response

The company stresses the immediate action taken after the disaster and its continued commitment to helping the victims. On 4 December, the day following the leak, Union Carbide sent material aid and several international medical experts to assist the medical facilities in Bhopal.

Financial response

The primary financial restitution paid by UCC was negotiated in 1989, when the Indian Supreme Court approved a settlement of US$470 million (₹1,055 crore; equivalent to $860 million in 2019). This amount was immediately paid by UCC to the Indian government. The company states that the restitution paid "was $120 million more than plaintiffs' lawyers had told U.S. courts was fair" and that the Indian Supreme Court stated in its opinion that "compensation levels under the settlement were far greater than would normally be payable under Indian law."

In the immediate aftermath of the disaster, Union Carbide states on its website that it put $2 million into the Indian prime minister's immediate disaster relief fund on 11 December 1984. The corporation established the Employees' Bhopal Relief Fund in February 1985, which raised more than $5 million for immediate relief. According to Union Carbide, in August 1987, they made an additional $4.6 million in humanitarian interim relief available.

Union Carbide stated that it also undertook several steps to provide continuing aid to the victims of the Bhopal disaster. The sale of its 50.9 percent interest in UCIL in April 1992 and establishment of a charitable trust to contribute to the building of a local hospital. The sale was finalised in November 1994. The hospital was begun in October 1995 and was opened in 2001. The company provided a fund with around $90 million from sale of its UCIL stock. In 1991, the trust had amounted approximately $100 million. The hospital catered for the treatment of heart, lung and eye problems. UCC also provided a $2.2 million grant to Arizona State University to establish a vocational-technical center in Bhopal, which was opened, but was later closed by the state government. They also donated $5 million to the Indian Red Cross after the disaster. They also developed a Responsible Care system with other members of the chemical industry as a response to the Bhopal crisis, which was designed to help prevent such an event in the future.

Charges against UCC and UCIL employees

UCC chairman and CEO Warren Anderson was arrested and released on bail by the Madhya Pradesh Police in Bhopal on 7 December 1984. Anderson was taken to UCC's house after which he was released six hours later on $2,100 bail and flown out on a government plane. These actions were allegedly taken under the direction of then chief secretary of the state, who was possibly instructed from chief minister's office, who himself flew out of Bhopal immediately. Later in 1987, the Indian government summoned Anderson, eight other executives and two company affiliates with homicide charges to appear in Indian court. In response, Union Carbide said the company is not under Indian jurisdiction.

From 2014, Dow is a named respondent in a number of ongoing cases arising from Union Carbide's business in Bhopal.

Ongoing contamination

A view of MIC plant surrounded by few metal pipes
Deteriorating section of the MIC plant in 2008, decades after the gas leak.

Chemicals abandoned at the plant continue to leak and pollute the groundwater. Whether the chemicals pose a health hazard is disputed. Contamination at the site and surrounding area was not caused by the gas leakage. The area around the plant was used as a dumping ground for hazardous chemicals and by 1982 water wells in the vicinity of the UCIL factory had to be abandoned. UCC states that "after the incident, UCIL began clean-up work at the site under the direction of Indian central and state government authorities". The work was continued from 1994 by Eveready Industries India, Limited (EIIL) who was UCIL's successor. In 1998, the Madhya Pradesh State Government, which owned and had been leasing the property to EIIL, cancelled the lease, took over the facility and assumed all accountability for the site, including the completion of any remediation.

UCC's laboratory tests in 1989 revealed that soil and water samples collected from near the factory were toxic to fish. Twenty-one areas inside the plant were reported to be highly polluted. In 1991 the municipal authorities declared that water from over 100 wells was hazardous for health if used for drinking. In 1994 it was reported that 21% of the factory premises were seriously contaminated with chemicals. Beginning in 1999, studies made by Greenpeace and others from soil, groundwater, well water and vegetables from the residential areas around UCIL and from the UCIL factory area show contamination with a range of toxic heavy metals and chemical compounds. Substances found, according to the reports, are naphthol, naphthalene, Sevin, tarry residues, alpha naphthol, mercury, organochlorines, chromium, copper, nickel, lead, hexachlorethane, hexachlorobutadiene, pesticide HCH (BHC), volatile organic compounds and halo-organics. Many of these contaminants were also found in breast milk of women living near the area. Soil tests were conducted by Greenpeace in 1999. One sample (IT9012) from "sediment collected from drain under former Sevin plant" showed mercury levels to be at "20,000 and 6 million times" higher than expected levels. Organochlorine compounds at elevated levels were also present in groundwater collected from (sample IT9040) a 4.4 meter depth "bore-hole within the former UCIL site". This sample was obtained from a source posted with a warning sign which read "Water unfit for consumption". Chemicals that have been linked to various forms of cancer were also discovered, as well as trichloroethylene, known to impair fetal development, at 50 times above safety limits specified by the U.S. Environmental Protection Agency (EPA). In 2002, an inquiry by Fact-Finding Mission on Bhopal found a number of toxins, including mercury, lead, 1,3,5 trichlorobenzene, dichloromethane and chloroform, in nursing women's breast milk.

A 2004 BBC Radio 5 broadcast reported the site is contaminated with toxic chemicals including benzene hexachloride and mercury, held in open containers or loose on the ground. A drinking water sample from a well near the site had levels of contamination 500 times higher than the maximum limits recommended by the World Health Organization. In 2009, the Centre for Science and Environment, a Delhi-based pollution monitoring lab, released test results showing pesticide groundwater contamination up to three kilometres from the factory. Also in 2009, the BBC took a water sample from a frequently used hand pump, located just north of the plant. The sample, tested in UK, was found to contain 1,000 times the World Health Organization's recommended maximum amount of carbon tetrachloride, a carcinogenic toxin.

In 2010, a British photojournalist ventured into the abandoned UCIL factory to investigate allegations of abandoned, leaking toxins. He was hospitalized in Bhopal for a week after he was exposed to chemicals. Doctors at the Sambhavna Clinic treated him with oxygen, painkillers and anti-inflammatories following a severe respiratory reaction to toxic dust inside the factory.

In October 2011, the Institute of Environmental Management and Assessment published an article and video by two British environmental scientists, showing the current state of the plant, landfill and solar evaporation ponds and calling for renewed international efforts to provide the necessary skills to clean up the site and contaminated groundwater.

Popular culture

Novels

Amulya Malladi's 2002 novel A Breath of Fresh Air relates the story of a mother and son who develop health issues as a result of exposure to gas at Bhopal. The book is based on Malladi's recollections of Bhopal during the incident.

Indra Sinha released Animal's People in 2007. The novel tells the story of a boy who is born with a spinal condition due to effects of the gas. The book was shortlisted for the Man Booker Prize.

Arundhati Roy's 2017 novel The Ministry of Utmost Happiness which deals with many contemporary political issues in India, also features several characters still dealing with the aftermath of the gas leak.

Annie Murray's novel Mother and Child (2019) is partly set in post-disaster Bhopal.

Music

Film

In 1999, a Hindi film dealing with the tragedy, Bhopal Express, was released. The film stars Kay Kay Menon and Naseeruddin Shah.

In 2014, to coincide with the 30th anniversary of the disaster, historical-drama Bhopal: A Prayer for Rain was released, starring Martin Sheen as Union Carbide CEO Warren Anderson, Kal Penn, and Mischa Barton.

Activism

Local activism

Protest in Bhopal in 2010

Since 1984, individual activists have played a role in the aftermath of the tragedy. The best-known is Satinath Sarangi (Sathyu), a metallurgic engineer who arrived at Bhopal the day after the leakage. He founded several activist groups, as well as Sambhavna Trust, the clinic for gas affected patients, where he is the manager. Other activists include Rashida Bee and Champa Devi Shukla, who received the Goldman Prize in 2004, Abdul Jabbar and Rachna Dhingra. Soon after the accident, other representatives from different activist groups arrived. The activists worked on organising the gas victims, which led to violent repression from the police and the government.

Numerous actions have been performed: demonstrations, sit-ins, hunger strikes, marches combined with pamphlets, books, and articles. Every anniversary, actions are performed. Often these include marches around Old Bhopal, ending with burning an effigy of Warren Anderson.

International activism

Cooperation with international NGOs including Pesticide Action Network UK and Greenpeace started soon after the tragedy. One of the earliest reports is the Trade Union report from ILO 1985.

In 1992, a session of the Permanent Peoples' Tribunal on Industrial Hazards and Human Rights took place in Bhopal, and in 1996, the "Charter on Industrial Hazards and Human Rights" was adopted.

In 1994, the International Medical Commission on Bhopal (IMCB) met in Bhopal. Their work contributed to long-term health effects being officially recognised.

Activist organisations

Bhopal People's Health and Documentation Clinic

More than 14 different NGOs were immediately engaged and 15 international, national and local organisations have been engaged including:

  • International Campaign for Justice in Bhopal (ICJB), coordinates international activities
  • Bhopal Medical Appeal, collects funds for the Sambhavna Trust
  • Sambhavna Trust or Bhopal People's Health and Documentation Clinic. Provides medical care for gas affected patients and those living in water-contaminated area
  • Chingari Trust, provides medical care for children being born in Bhopal with malformations and brain damages
  • Students for Bhopal, based in the United States
  • International Medical Commission on Bhopal, provided medical information 1994–2000
  • Bhopal Gas Peedit Mahila-Stationery Karmachari Sangh
  • Bhopal Gas Peedit Mahila Udyog Sangthan

Settlement fund hoax

On 3 December 2004, the twentieth anniversary of the disaster, a man falsely claiming to be a Dow representative named Jude Finisterra was interviewed on BBC World News. He claimed that the company had agreed to clean up the site and compensate those harmed in the incident, by liquidating Union Carbide for US$12 billion. Dow quickly issued a statement saying that they had no employee by that name—that he was an impostor, not affiliated with Dow, and that his claims were a hoax. The BBC later broadcast a correction and an apology.

Jude Finisterra was actually Andy Bichlbaum, a member of the activist prankster group The Yes Men. In 2002, The Yes Men issued a fake press release explaining why Dow refused to take responsibility for the disaster and started up a website, at "DowEthics.com", designed to look like the real Dow website, but containing hoax information.

Monitoring of activists

The release of an email cache related to intelligence research organisation Stratfor was leaked by WikiLeaks on 27 February 2012. It revealed that Dow Chemical had engaged Stratfor to spy on the public and personal lives of activists involved in the Bhopal disaster, including the Yes Men. E-mails to Dow representatives from hired security analysts list the YouTube videos liked, Twitter and Facebook posts made and the public appearances of these activists. Journalists, film-makers and authors who were investigating Bhopal and covering the issue of ongoing contamination, such as Jack Laurenson and Max Carlson, were also placed under surveillance. Stratfor released a statement condemning the revelation by Wikileaks while neither confirming nor denying the accuracy of the reports, and would only state that it had acted within the bounds of the law. Dow Chemical also refrained to comment on the matter.

Ingrid Eckerman, a member of the International Medical Commission on Bhopal, has been denied a visa to visit India.

 

Phosgene

From Wikipedia, the free encyclopedia
Phosgene
Full structural formula with dimensions
Space-filling model
A bag of toxic gases use in chemical warfare; the leftmost one is phosgene
Names
Preferred IUPAC name
Carbonyl dichloride
Other names
Carbonyl chloride
CG
Carbon dichloride oxide
Carbon oxychloride
Chloroformyl chloride
Dichloroformaldehyde
Dichloromethanone
Dichloromethanal
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.000.792 Edit this at Wikidata
EC Number
  • 200-870-3
RTECS number
  • SY5600000
UNII
UN number 1076
Properties
COCl2, also CCl2O
Molar mass 98.92 g/mol
Appearance Colorless gas
Odor Suffocating, like musty hay
Density 4.248 g/L (15 °C, gas)
1.432 g/cm3 (0 °C, liquid)
Melting point −118 °C (−180 °F; 155 K)
Boiling point 8.3 °C (46.9 °F; 281.4 K)
Insoluble, reacts
Solubility Soluble in benzene, toluene, acetic acid
Decomposes in alcohol and acid
Vapor pressure 1.6 atm (20°C)
−48·10−6 cm3/mol
Structure
Planar, trigonal
1.17 D
Hazards
Safety data sheet ICSC 0007
Very Toxic T+
R-phrases (outdated) R26 R34
S-phrases (outdated) (S1/2) S9 S26 S36/37/39 S45
NFPA 704 (fire diamond)
Flammability code 0: Will not burn. E.g. waterHealth code 4: Very short exposure could cause death or major residual injury. E.g. VX gasReactivity code 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no codeNFPA 704 four-colored diamond
0
4
1
Flash point Non-flammable
0.1 ppm
Lethal dose or concentration (LD, LC):
500 ppm (human, 1 min)
340 ppm (rat, 30 min)
438 ppm (mouse, 30 min)
243 ppm (rabbit, 30 min)
316 ppm (guinea pig, 30 min)
1022 ppm (dog, 20 min)
145 ppm (monkey, 1 min)
3 ppm (human, 2.83 h)
30 ppm (human, 17 min)
50 ppm (mammal, 5 min)
88 ppm (human, 30 min)
46 ppm (cat, 15 min)
50 ppm (human, 5 min)
2.7 ppm (mammal, 30 min)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.1 ppm (0.4 mg/m3)
REL (Recommended)
TWA 0.1 ppm (0.4 mg/m3) C 0.2 ppm (0.8 mg/m3) [15-minute]
IDLH (Immediate danger)
2 ppm
Related compounds
Related compounds
Thiophosgene
Formaldehyde
Carbonic acid
Urea
Carbon monoxide
Chloroformic acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
check verify (what is check☒ ?)
Infobox references


Phosgene is the organic chemical compound with the formula COCl2. It is a colorless gas; in low concentrations, its odor resembles that of freshly cut hay or grass. Phosgene is a valued industrial building block, especially for the production of urethanes and polycarbonate plastics.

It is very poisonous and was used as a chemical weapon during World War I, when it was responsible for 85,000 deaths.

In addition to its industrial production, small amounts occur from the breakdown and the combustion of organochlorine compounds.

Structure and basic properties

Phosgene is a planar molecule as predicted by VSEPR theory. The C=O distance is 1.18 Å, the C−Cl distance is 1.74 Å and the Cl−C−Cl angle is 111.8°. It is one of the simplest acyl chlorides, being formally derived from carbonic acid.

Production

Industrially, phosgene is produced by passing purified carbon monoxide and chlorine gas through a bed of porous activated carbon, which serves as a catalyst:

CO + Cl2 → COCl2Hrxn = −107.6 kJ/mol)

The reaction is exothermic, therefore the reactor must be cooled. Typically, the reaction is conducted between 50 and 150 °C. Above 200 °C, phosgene reverts to carbon monoxide and chlorine, Keq(300 K) = 0.05. World production of this compound was estimated to be 2.74 million tonnes in 1989.

Because of safety issues, phosgene is often produced and consumed within the same plant, and extraordinary measures are made to contain it. It is listed on Schedule 3 of the Chemical Weapons Convention: All production sites manufacturing more than 30 tonnes per year must be declared to the OPCW. Although less dangerous than many other chemical weapons such as sarin, phosgene is still regarded as a viable chemical warfare agent because it is so easy to manufacture when compared to the production requirements of more technically advanced chemical weapons such as the first-generation nerve agent tabun.

Inadvertent generation

Upon ultraviolet (UV) radiation in the presence of oxygen, chloroform slowly converts into phosgene by a radical reaction. To suppress this photodegradation, chloroform is often stored in brown-tinted glass containers and with a small percentage of ethanol added. Chlorinated solvents used to remove oil from metals, such as automotive brake cleaners, are converted to phosgene by the UV rays of arc welding processes.

Phosgene may also be produced during testing for leaks of older-style refrigerant gases.

 Chloromethanes (R12, R22 and others) were formerly leak-tested in situ by employing a small gas torch (propane, butane, or propylene gas) with a sniffer tube and a copper reaction plate in the flame nozzle of the torch. If any refrigerant gas was leaking from a pipe or joint, the gas would be sucked into the flame through the sniffer tube and would cause a colour change of the gas flame to a bright greenish blue. In the process, phosgene gas would be created due to the thermal reaction. No valid statistics are available, but anecdotal reports suggest that numerous refrigeration technicians suffered the effects of phosgene poisoning due to their ignorance of the toxicity of phosgene, produced during such leak testing.

Electronic sensing of refrigerant gases phased out the use of flame testing for leaks in the 1980s. Similarly, phosgene poisoning is a possibility for people fighting fires that occur in the vicinity of refrigerant leaks from air-conditioning systems or refrigeration equipment, smoking in the vicinity of a freon refrigerant leak, or fighting fires using halon or halotron.

Phosgene can be released during building fires. In one instance, a deputy fire chief died ten days after inhaling fumes that wafted down outside a burning restaurant. After a two-day hospitalization he had appeared to recover, but ultimately suffered cardiac arrest at home following tracheobronchial inflammation, alveolar hemorrhage, and pulmonary edema. The phosgene was produced by decomposing Freon 22 after flames ducted up from a grease fire heated an air-conditioning unit on the roof and ruptured a hose.

History

Phosgene was synthesized by the Cornish chemist John Davy (1790–1868) in 1812 by exposing a mixture of carbon monoxide and chlorine to sunlight. He named it "phosgene" in reference of the use of light to promote the reaction; from Greek, phos (light) and gene (born). It gradually became important in the chemical industry as the 19th century progressed, particularly in dye manufacturing.

Reactions and uses

The great majority of phosgene is used in the production of isocyanates, the most important being toluene diisocyanate (TDI) and methylene diphenyl diisocyanate (MDI). These two isocyanates are precursors to polyurethanes. The reaction of an organic substrate with phosgene is called phosgenation.

Synthesis of carbonates

Significant amounts are also used in the production of polycarbonates by its reaction with bisphenol A. Polycarbonates are an important class of engineering thermoplastic found, for example, in lenses in eyeglasses. Diols react with phosgene to give either linear or cyclic carbonates (R = H, alkyl, aryl):

HOCR2−X−CR2OH + COCl2 → ​1n [OCR2−X−CR2OC(O)−]n + 2 HCl

Phosgenation of hydroxamic acids gives dioxazolone, a class of cyclic carbonate esters:

RC(O)NHOH + COCl2 → RC=NOCO2 + 2 HCl

Synthesis of isocyanates

The synthesis of isocyanates from amines illustrates the electrophilic character of this reagent and its use in introducing the equivalent of "CO2+":

RNH2 + COCl2 → RN=C=O + 2 HCl (R = alkyl, aryl)

Such reactions are conducted in the presence of a base such as pyridine that absorbs the hydrogen chloride.

Laboratory uses

In the research laboratory phosgene still finds limited use in organic synthesis. A variety of substitutes have been developed, notably trichloromethyl chloroformate ("diphosgene"), a liquid at room temperature, and bis(trichloromethyl) carbonate ("triphosgene"), a crystalline substance. Aside from the above reactions that are widely practiced industrially, phosgene is also used to produce acyl chlorides and carbon dioxide from carboxylic acids:

RCO2H + COCl2 → RC(O)Cl + HCl + CO2

Such acid chlorides react with amines and alcohols to give, respectively, amides and esters, which are commonly used intermediates. Thionyl chloride is more commonly and more safely employed for this application. A specific application for phosgene is the production of chloroformic esters:

ROH + COCl2 → ROC(O)Cl + HCl

Phosgene is stored in metal cylinders. The outlet is always standard, a tapered thread that is known as CGA 160

Other chemistry

Although it is somewhat hydrophobic, phosgene reacts with water to release hydrogen chloride and carbon dioxide:

COCl2 + H2O → CO2 + 2 HCl

Analogously, with ammonia, one obtains urea:

COCl2 + 4 NH3 → CO(NH2)2 + 2 NH4Cl

Halide exchange with nitrogen trifluoride and aluminium tribromide gives COF2 and COBr2, respectively.

Chemical warfare

US Army phosgene identification poster from World War II

The collapse of international conventions against chemical weapons led to the widespread use of chlorine gas in World War I, but its lethal concentration of 0.1% was visible as a green cloud in the air, allowing troops to take readily available countermeasures. Phosgene, colorless with a more subtle "moldy hay" odor, was introduced by a group of French chemists led by Victor Grignard and first used by the French in 1915. It was also used in a mixture with an equal volume of chlorine, with the chlorine helping to spread the denser phosgene.  Phosgene was more potent than chlorine, though some of the symptoms of exposure took 24 hours or more to manifest, meaning the victims were initially still capable of putting up a fight.

Following the extensive use of phosgene gas in combat during World War I, it was stockpiled by various countries as part of their secret chemical weapons programs.

In May 1928, eleven tons of phosgene escaped from a war surplus store in central Hamburg. Three hundred people were poisoned, of whom 10 died.

Phosgene was then only infrequently used by the Imperial Japanese Army against the Chinese during the Second Sino-Japanese War. Gas weapons, such as phosgene, were produced by Unit 731 and authorized by specific orders given by Hirohito (Emperor Showa) himself, transmitted by the chief of staff of the army. For example, the Emperor authorized the use of toxic gas on 375 separate occasions during the Battle of Wuhan from August to October 1938.

Safety

Phosgene is an insidious poison as the odor may not be noticed and symptoms may be slow to appear.

The odor detection threshold for phosgene is 0.4 ppm, four times the threshold limit value. Its high toxicity arises from the action of the phosgene on the proteins in the pulmonary alveoli, the site of gas exchange: their damage disrupts the blood–air barrier, causing suffocation. It reacts with the amines of the proteins, causing crosslinking by formation of urea-like linkages, in accord with the reactions discussed above. Phosgene detection badges are worn by those at risk of exposure.

Sodium bicarbonate may be used to neutralise liquid spills of phosgene. Gaseous spills may be mitigated with ammonia.

Accidents

  • On January 23, 2010, an accidental release of phosgene gas at a DuPont facility in West Virginia killed one employee.

Chemical weapons and the United Kingdom

From Wikipedia, the free encyclopedia

Chemical weapons were widely used by the United Kingdom in World War I, and while the use of tear gas was suggested by Churchill and others postwar in Mesopotamia and in World War II, it appears that they were not actually used, although some historians disagree. While the UK was a signatory of the Hague Conventions of 1899 and 1907 which outlawed the use of poison gas shells, the conventions omitted mention of deployment from cylinders, probably because that had not been considered.

The United Kingdom ratified the Geneva Protocol on 9 April 1930. The UK signed the Chemical Weapons Convention on 13 January 1993 and ratified it on 13 May 1996.

Use in World War I

A World War I-era British gas bomb

During the First World War, in retaliation to the use of chlorine by Germany against British troops from April 1915 onwards, the British Army deployed chlorine themselves for the first time during the Battle of Loos on 25 September 1915. By the end of the war, poison gas use had become widespread on both sides and by 1918 a quarter of artillery shells were filled with gas and Britain had produced around 25,400 tons of toxic chemicals.

Britain used a range of poison gases, originally chlorine and later phosgene, diphosgene and mustard gas. They also used relatively small amounts of the irritant gases chloromethyl chloroformate, chloropicrin, bromacetone and ethyl iodoacetate. Gases were frequently mixed, for example white star was the name given to a mixture of equal volumes of chlorine and phosgene, the chlorine helping to spread the denser but more toxic phosgene. Despite the technical developments, chemical weapons suffered from diminishing effectiveness as the war progressed because of the protective equipment and training which the use engendered on both sides.

Mustard gas was first used effectively in World War I by the Imperial German Army against Commonwealth soldiers in the Battle of Passchendaele near Ypres, Belgium, in 1917 and later also against the French Second Army. The name Yprite comes from its usage by the German army near the town of Ypres. The Allies did not use mustard gas until November 1917 at the Battle of Cambrai after the armies had captured a stockpile of German mustard-gas shells. It took the British more than a year to develop their own mustard gas weapon, with production of the chemicals centred on Avonmouth Docks. (The only option available to the British was the Despretz–Niemann–Guthrie process). This was used first in September 1918 during the breaking of the Hindenburg Line with the Hundred Days' Offensive.

The use of chemical weapons in warfare during the Great War was in violation of the 1899 Hague Declaration Concerning Asphyxiating Gases and the 1907 Hague Convention on Land Warfare, which explicitly forbade the use of "poison or poisoned weapons" in warfare.

Between the wars

To maintain a stockpile of Adamsite, the British Ministry of Munitions established Sutton Oak Chemical Defence Research Establishment (CDRE) in 1919. The plant was able to manufacture up to 20 tons of mustard gas per week in the late 1920s.

After the war, the Royal Air Force dropped diphenylchloroarsine, an irritant agent designed to cause uncontrollable coughing, on Bolshevik troops in 1919, and Winston Churchill, secretary of state for war and air, suggested that the RAF use tear gas in Iraq in 1920 during a major revolt there. However, historians are divided as to whether or not gas was actually used.

It is sheer affectation to lacerate a man with the poisonous fragment of a bursting shell and to boggle at making his eyes water by means of lachrymatory gas. I am strongly in favour of using poisoned gas against uncivilised tribes. The moral effect should be so good that the loss of life should be reduced to a minimum. It is not necessary to use only the most deadly gasses: gasses can be used which cause great inconvenience and would spread a lively terror and yet would leave no serious permanent effects on most of those affected.

— Winston Churchill, Departmental minute (1919)

Usage of the term "poisoned gas" by Churchill in a way suggesting he promoted lethal chemical warfare was circulated in 2000's in response to British criticism of the use of chemical weapons in the Syrian Civil War.

In 1937 ICI began to build a new factory for Mustard Gas at their Randle plant on Wigg Island, Runcorn, Cheshire.

Britain signed and ratified the Geneva Protocol in 1930, which banned the use of toxic gases and bacteria in war but not the development and production of such weapons. Britain carried out extensive testing of chemical weapons from the early 1930s onwards. In the Rawalpindi experiments, hundreds of Indian soldiers were exposed to mustard gas in an attempt to determine the appropriate dosage to use on battlefields. Many of the subjects suffered severe burns from their exposure to the gas.

Proposed use in World War II

In the late 1930s the Chamberlain Government planned that the United Kingdom should be in a position at the beginning of any war to retaliate in kind if the Germans, as expected, used mustard gas and phosgene. to help repel a German invasion in 1940–1941, and had there been an invasion may have also deployed it against German cities. General Brooke, in command of British anti-invasion preparations of World War II said that he "...had every intention of using sprayed mustard gas on the beaches" in an annotation in his diary. The British manufactured mustard, chlorine, lewisite, phosgene and Paris Green and stored it at airfields and depots for use on the beaches.

M. S. Factory, Valley

In the late 1930s the Chamberlain Government planned that the United Kingdom should be in a position at the beginning of any war to retaliate in kind if the Germans, as expected, used mustard gas. In April/June 1939 the Alyn Valley in Rhydymwyn was surveyed by the Department of Industrial Planning on behalf of the Ministry of Supply and Imperial Chemical Industries (ICI) who were tasked with managing this programme. This resulted in M. S. Factory, Valley as United Kingdoms main chemical weapons plant.

Forward Filling Depots

To able to retaliate quickly if Nazi Germany used chemical weapons, a number of Forward Filling Depots were built so that the mustard gas stockpile was dispersed and ready to use.

  • FFD 1 RAF Barnham, Heath Site. Under the control of 94 Maintenance Unit
  • FFD 2 RAF RiselyLake Site. American FFD - Station 572
  • FFD 3 RAF Station Swinderby Under the control of 93 Maintenance Unit
  • FFD 4 Bridge Site. Under the control of 95 Maintenance Unit
  • FFD 5 Station Site. Under the control of 80 Sub Maintenance Unit

Later plans

The mustard gas stockpile was enlarged in 1940-1941 to help repel a possible Nazi German invasion in 1940–1941, and had there been an invasion may have also deployed it against German cities. General Alan Brooke, in command of British anti-invasion preparations of World War II said that he "...had every intention of using sprayed mustard gas on the beaches" in an annotation in his diary. The British manufactured mustard, chlorine, lewisite, phosgene and Paris Green and stored it at airfields and depots for use on the beaches.

Winston Churchill issued a memorandum advocating a chemical strike on German cities using poison gas and possibly anthrax. Although the idea was rejected, it has provoked debate. In July 1944, fearing that rocket attacks on London would get even worse and that he only use it if it was "life or death for us" or would "shorten the war by a year", Churchill wrote a secret memorandum asking his military chiefs to "think very seriously over this question of using poison gas." He said "it is absurd to consider morality on this topic when everybody used it in the last war without a word of complaint..." and that:

I should be prepared to do anything [Churchill's emphasis] that would hit the enemy in a murderous place. I may certainly have to ask you to support me in using poison gas. We could drench the cities of the Ruhr and many other cities in Germany ..., We could stop all work at the flying bombs starting points.... and if we do it, let us do it one hundred per cent.

— Winston Churchill, 'Most Secret' PRIME MINISTER'S PERSONAL MINUTE to the Chiefs of Staff, 6 July 1944

The Joint Planning Staff (JPS), however, advised against the use of gas because it would inevitably provoke Germany to retaliate with gas. They argued that this would be to the Allies' disadvantage in France both for military reasons and because it might "seriously impair our relations with the civilian population when it became generally known that chemical warfare was first employed by us." The JPS had similar concerns about public morale in Britain, fearing that people might become resentful if they felt a gas war could have been avoided. The Chiefs of Staff also warned that the Nazis would have no particular "difficulty in holding down the cowed German population, if they were subjected to gas attack," whereas the British population "are in no such inarticulate condition." Also that the German might also use Allied prisoners as workers in contaminated areas causing "great public concern".

Churchill responded to this advice by saying:

I am not at all convinced by this negative report. But clearly I cannot make head against the parsons and the warriors at the same time. The matter should be kept under review and brought up again when things get worse.

At the same time, the JPS examined the case of using anthrax bioweapons against six large German cities but only ruled this out on the grounds that the anthrax bombs were not yet available. A large batch of aerial bombs were ordered, but by the time the US factory was ready to produce them, they were deemed unnecessary since the war in Europe was almost over.

Novelist Robert Harris and broadcaster Jeremy Paxman argue that as soon as another weapon of mass destruction – the atomic bomb – became available, and offered a chance to shorten the war, the Americans used it. "Why, from an ethical or political point of view, should germ warfare have been regarded any differently? [by British]."

As the end of the war was sufficiently in sight, British poison gas production was terminated following a request from the Chiefs of Staff Committee in February 1945.

Post-World War II

From 1939 to 1989 experiments on chemical weapons including nerve agents and countermeasures were carried out at the Porton Down research establishment. Although volunteers were used, many ex-servicemen complained about suffering long term illnesses after taking part in the tests. It was alleged that before volunteering they were not provided with adequate information about the experiments and the risk, in breach of the Nuremberg Code of 1947. This became the subject of a lengthy police investigation called Operation Antler.

From 1950, a Chemical Defence Establishment was established as CDE Nancekuke for small-scale chemical agent production. A pilot production facility for Sarin was built, which produced about 20 tons of the nerve agent from 1954 until 1956. A full-scale production plant was planned, but with the 1956 decision to end the United Kingdom's offensive chemical weapons programme it was never built. Nancekuke was mothballed, but was maintained through the 1960s and 1970s in a state whereby production of chemical weapons could easily re-commence if required.

In the early 1980s the government took the view that the lack of a European chemical weapons retaliatory capability was a "major gap in NATO's armoury". However the political difficulties of addressing this prevented any redevelopment of a British chemical weapons capability.

An inquest was opened on 5 May 2004 into the death on 6 May 1953 of a serviceman, Ronald Maddison, during an experiment using sarin. His death had earlier been found by a private Ministry of Defence inquest to have been as a result of "misadventure" but this was quashed by the High Court in 2002. The 2004 hearing closed on 15 November, after a jury found that the cause of Maddison's death was "application of a nerve agent in a non-therapeutic experiment".

Butane

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