El Niño–Southern Oscillation

From Wikipedia, the free encyclopedia

https://en.wikipedia.org/wiki/El_Ni%C3%B1o%E2%80%93Southern_Oscillation

Southern Oscillation Index timeseries from 1876 to 2023. The Southern Oscillation is the atmospheric component of El Niño. This component is an oscillation in surface air pressure between the tropical eastern and the western Pacific Ocean waters.

El Niño–Southern Oscillation (ENSO) is an irregular periodic variation in winds and sea surface temperatures over the tropical eastern Pacific Ocean, affecting the climate of much of the tropics and subtropics. The warming phase of the sea temperature is known as El Niño and the cooling phase as La Niña. The Southern Oscillation is the accompanying atmospheric component, coupled with the sea temperature change: El Niño is accompanied by high air surface pressure in the tropical western Pacific and La Niña with low air surface pressure there. The two periods last several months each and typically occur every few years with varying intensity per period.

The two phases relate to the Walker circulation, which was discovered by Gilbert Walker during the early twentieth century. The Walker circulation is caused by the pressure gradient force that results from a high-pressure area over the eastern Pacific Ocean, and a low-pressure system over Indonesia. Weakening or reversal of the Walker circulation (which includes the trade winds) decreases or eliminates the upwelling of cold deep sea water, thus creating El Niño by causing the ocean surface to reach above average temperatures. An especially strong Walker circulation causes La Niña, resulting in cooler ocean temperatures due to increased upwelling.

Mechanisms that cause the oscillation remain under study. The extremes of this climate pattern's oscillations cause extreme weather (such as floods and droughts) in many regions of the world. Developing countries dependent upon agriculture and fishing, particularly those bordering the Pacific Ocean, are the most affected.

In climate change science, ENSO is known as one of the internal climate variability phenomena. The other two main ones are Pacific Decadal Variability (or oscillation) and Atlantic Multi-decadal Variability (or oscillation).

Terminology

An early recorded mention of the term "El Niño" ("The Boy" in Spanish) to refer to climate occurred in 1892, when Captain Camilo Carrillo told the geographical society congress in Lima that Peruvian sailors named the warm south-flowing current "El Niño" because it was most noticeable around Christmas. Although pre-Columbian societies were certainly aware of the phenomenon, the indigenous names for it have been lost to history.

Originally, the term El Niño applied to an annual weak warm ocean current that ran southwards along the coast of Peru and Ecuador at about Christmas time. However, over time the term has evolved and now refers to the warm and negative phase of the El Niño–Southern Oscillation (ENSO). La Niña ("The Girl" in Spanish) is the colder counterpart of El Niño, as part of the broader El Niño–Southern Oscillation (ENSO) climate pattern.

Outline

The El Niño–Southern Oscillation is a single climate phenomenon that periodically fluctuates between three phases: Neutral, La Niña or El Niño. La Niña and El Niño are opposite phases which require certain changes to take place in both the ocean and the atmosphere before an event is declared.

Normally the northward flowing Humboldt Current brings relatively cold water from the Southern Ocean northwards along South America's west coast to the tropics, where it is enhanced by up-welling taking place along the coast of Peru. Along the equator, trade winds cause the ocean currents in the eastern Pacific to draw water from the deeper ocean to the surface, thus cooling the ocean surface. Under the influence of the equatorial trade winds, this cold water flows westwards along the equator where it is slowly heated by the sun. As a direct result sea surface temperatures in the western Pacific are generally warmer, by about 8–10 °C (14–18 °F) than those in the Eastern Pacific. This warmer area of ocean is a source for convection and is associated with cloudiness and rainfall. During El Niño years the cold water weakens or disappears completely as the water in the Central and Eastern Pacific becomes as warm as the Western Pacific.

Walker circulation

Main article: Walker circulation

Diagram of the quasi-equilibrium and La Niña phase of the Southern Oscillation. The Walker circulation is seen at the surface as easterly trade winds which move water and air warmed by the sun towards the west. The western side of the equatorial Pacific is characterized by warm, wet low pressure weather as the collected moisture is dumped in the form of typhoons and thunderstorms. The ocean is some 60 centimetres (24 in) higher in the western Pacific as the result of this motion. The water and air are returned to the east. Both are now much cooler, and the air is much drier. An El Niño episode is characterised by a breakdown of this water and air cycle, resulting in relatively warm water and moist air in the eastern Pacific.

The Walker circulation is caused by the pressure gradient force that results from a high pressure system over the eastern Pacific Ocean, and a low pressure system over Indonesia. The Walker circulations of the tropical Indian, Pacific, and Atlantic basins result in westerly surface winds in northern summer in the first basin and easterly winds in the second and third basins. As a result, the temperature structure of the three oceans display dramatic asymmetries. The equatorial Pacific and Atlantic both have cool surface temperatures in northern summer in the east, while cooler surface temperatures prevail only in the western Indian Ocean. These changes in surface temperature reflect changes in the depth of the thermocline.

Changes in the Walker circulation with time occur in conjunction with changes in surface temperature. Some of these changes are forced externally, such as the seasonal shift of the sun into the Northern Hemisphere in summer. Other changes appear to be the result of coupled ocean-atmosphere feedback in which, for example, easterly winds cause the sea surface temperature to fall in the east, enhancing the zonal heat contrast and hence intensifying easterly winds across the basin. These anomalous easterlies induce more equatorial upwelling and raise the thermocline in the east, amplifying the initial cooling by the southerlies. This coupled ocean-atmosphere feedback was originally proposed by Bjerknes. From an oceanographic point of view, the equatorial cold tongue is caused by easterly winds. Were the Earth climate symmetric about the equator, cross-equatorial wind would vanish, and the cold tongue would be much weaker and have a very different zonal structure than is observed today.

During non-El Niño conditions, the Walker circulation is seen at the surface as easterly trade winds that move water and air warmed by the sun toward the west. This also creates ocean upwelling off the coasts of Peru and Ecuador and brings nutrient-rich cold water to the surface, increasing fishing stocks. The western side of the equatorial Pacific is characterized by warm, wet, low-pressure weather as the collected moisture is dumped in the form of typhoons and thunderstorms. The ocean is some 60 cm (24 in) higher in the western Pacific as the result of this motion.

Sea surface temperature oscillation

The various "Niño regions" where sea surface temperatures are monitored to determine the current ENSO phase (warm or cold)

Within the National Oceanic and Atmospheric Administration in the United States, sea surface temperatures in the Niño 3.4 region, which stretches from the 120th to 170th meridians west longitude astride the equator five degrees of latitude on either side, are monitored. This region is approximately 3,000 kilometres (1,900 mi) to the southeast of Hawaii. The most recent three-month average for the area is computed, and if the region is more than 0.5 °C (0.9 °F) above (or below) normal for that period, then an El Niño (or La Niña) is considered in progress. The United Kingdom's Met Office also uses a several month period to determine ENSO state. When this warming or cooling occurs for only seven to nine months, it is classified as El Niño/La Niña "conditions"; when it occurs for more than that period, it is classified as El Niño/La Niña "episodes".

Normal Pacific pattern: Equatorial winds gather warm water pool toward the west. Cold water upwells along South American coast. (NOAA / PMEL / TAO)

 

El Niño conditions: Warm water pool approaches the South American coast. The absence of cold upwelling increases warming.

 

La Niña conditions: Warm water is farther west than usual.

Neutral phase

Average equatorial Pacific temperatures

If the temperature variation from climatology is within 0.5 °C (0.9 °F), ENSO conditions are described as neutral. Neutral conditions are the transition between warm and cold phases of ENSO. Ocean temperatures (by definition), tropical precipitation, and wind patterns are near average conditions during this phase. Close to half of all years are within neutral periods. During the neutral ENSO phase, other climate anomalies/patterns such as the sign of the North Atlantic Oscillation or the Pacific–North American teleconnection pattern exert more influence.

The 1997 El Niño observed by TOPEX/Poseidon

Warm phase

Main article: El Niño

When the Walker circulation weakens or reverses and the Hadley circulation strengthens an El Niño results, causing the ocean surface to be warmer than average, as upwelling of cold water occurs less or not at all offshore northwestern South America. El Niño (/ɛlˈniːnjoʊ/, /-ˈnɪn-/, Spanish pronunciation: [el ˈniɲo]) is associated with a band of warmer than average ocean water temperatures that periodically develops off the Pacific coast of South America. El niño is Spanish for "the child boy", and the capitalized term El Niño refers to the Christ child, Jesus, because periodic warming in the Pacific near South America is usually noticed around Christmas. El Niño accompanies high air surface pressure in the western Pacific. Mechanisms that cause the oscillation remain under study.

Cold phase

Main article: La Niña

An especially strong Walker circulation causes La Niña, resulting in cooler ocean temperatures in the central and eastern tropical Pacific Ocean due to increased upwelling. La Niña (/lɑːˈniːnjə/, Spanish pronunciation: [la ˈniɲa]) is a coupled ocean-atmosphere phenomenon that is the counterpart of El Niño as part of the broader El Niño Southern Oscillation climate pattern. The name La Niña originates from Spanish, meaning "the child girl", analogous to El Niño meaning "the child boy". During a period of La Niña the sea surface temperature across the equatorial eastern central Pacific will be lower than normal by 3–5 °C. In the United States, an appearance of La Niña happens for at least five months of La Niña conditions. However, each country and island nation has a different threshold for what constitutes a La Niña event, which is tailored to their specific interests. The Japan Meteorological Agency for example, declares that a La Niña event has started when the average five month sea surface temperature deviation for the NINO.3 region, is over 0.5 °C (0.90 °F) cooler for 6 consecutive months or longer.

Transitional phases

Transitional phases at the onset or departure of El Niño or La Niña can also be important factors on global weather by affecting teleconnections. Significant episodes, known as Trans-Niño, are measured by the Trans-Niño index (TNI). Examples of affected short-time climate in North America include precipitation in the Northwest US and intense tornado activity in the contiguous US.

Southern Oscillation

The regions where the air pressure are measured and compared to generate the Southern Oscillation Index

Southern Oscillation Index correlated with mean sea level pressure.

The Southern Oscillation is the atmospheric component of El Niño. This component is an oscillation in surface air pressure between the tropical eastern and the western Pacific Ocean waters. The strength of the Southern Oscillation is measured by the Southern Oscillation Index (SOI). The SOI is computed from fluctuations in the surface air pressure difference between Tahiti (in the Pacific) and Darwin, Australia (on the Indian Ocean).

• El Niño episodes have negative SOI, meaning there is lower pressure over Tahiti and higher pressure in Darwin.
• La Niña episodes have positive SOI, meaning there is higher pressure in Tahiti and lower in Darwin.

Low atmospheric pressure tends to occur over warm water and high pressure occurs over cold water, in part because of deep convection over the warm water. El Niño episodes are defined as sustained warming of the central and eastern tropical Pacific Ocean, thus resulting in a decrease in the strength of the Pacific trade winds, and a reduction in rainfall over eastern and northern Australia. La Niña episodes are defined as sustained cooling of the central and eastern tropical Pacific Ocean, thus resulting in an increase in the strength of the Pacific trade winds, and the opposite effects in Australia when compared to El Niño.

Although the Southern Oscillation Index has a long station record going back to the 1800s, its reliability is limited due to the presence of both Darwin and Tahiti well south of the Equator, resulting in the surface air pressure at both locations being less directly related to ENSO. To overcome this question, a new index was created, being named the Equatorial Southern Oscillation Index (EQSOI). To generate this index data, two new regions, centered on the Equator, were delimited to create a new index: The western one is located over Indonesia and the eastern one is located over equatorial Pacific, close to the South American coast. However, data on EQSOI goes back only to 1949.

Related patterns

Madden–Julian oscillation

A Hovmöller diagram of the 5-day running mean of outgoing longwave radiation showing the MJO. Time increases from top to bottom in the figure, so contours that are oriented from upper-left to lower-right represent movement from west to east.

The Madden–Julian oscillation (MJO) is the largest element of the intraseasonal (30- to 90-day) variability in the tropical atmosphere. It was discovered in 1971 by Roland Madden and Paul Julian of the American National Center for Atmospheric Research (NCAR). It is a large-scale coupling between atmospheric circulation and tropical deep atmospheric convection. Unlike a standing pattern like the El Niño–Southern Oscillation (ENSO), the Madden–Julian oscillation is a traveling pattern that propagates eastward, at approximately 4 to 8 m/s (14 to 29 km/h; 9 to 18 mph), through the atmosphere above the warm parts of the Indian and Pacific oceans. This overall circulation pattern manifests itself most clearly as anomalous rainfall.

Interactions with global warming

Colored bars show how El Niño years (red, regional warming) and La Niña years (blue, regional cooling) relate to overall global warming. The El Niño–Southern Oscillation has been linked to variability in longer-term global average temperature increase.

In climate change science, ENSO is known as one of the internal climate variability phenomena. The other two main ones are Pacific Decadal Variability (or oscillation) and Atlantic Multi-decadal Variability (or oscillation).

El Niño events cause short-term (approximately 1 year in length) spikes in global average surface temperature while La Niña events cause short term cooling. Therefore, the relative frequency of El Niño compared to La Niña events can affect global temperature trends on decadal timescales. Over the last several decades, the number of El Niño events increased, and the number of La Niña events decreased, although observation of ENSO for much longer is needed to detect robust changes.

The studies of historical data show the recent El Niño variation is most likely linked to global warming. For example, one of the most recent results, even after subtracting the positive influence of decadal variation, is shown to be possibly present in the ENSO trend, the amplitude of the ENSO variability in the observed data still increases, by as much as 60% in the last 50 years. A study published in 2023 by CSIRO researchers found that climate change may have increased by two times the likelihood of strong El Niño events and nine times the likelihood of strong La Niña events. The study claims it found a consensus between different models and experiments.

Future trends in ENSO are uncertain as different models make different predictions. It may be that the observed phenomenon of more frequent and stronger El Niño events occurs only in the initial phase of the global warming, and then (e.g., after the lower layers of the ocean get warmer, as well), El Niño will become weaker. It may also be that the stabilizing and destabilizing forces influencing the phenomenon will eventually compensate for each other. More research is needed to provide a better answer to that question. The ENSO is considered to be a potential tipping element in Earth's climate and, under the global warming, can enhance or alternate regional climate extreme events through a strengthened teleconnection. For example, an increase in the frequency and magnitude of El Niño events have triggered warmer than usual temperatures over the Indian Ocean, by modulating the Walker circulation. This has resulted in a rapid warming of the Indian Ocean, and consequently a weakening of the Asian Monsoon.

The IPCC Sixth Assessment Report summarized the state of the art of research in 2021 into the future of ENSO as follows:

• "In the long term, it is very likely that the precipitation variance related to El Niño–Southern Oscillation will increase" and
• "It is very likely that rainfall variability related to changes in the strength and spatial extent of ENSO teleconnections will lead to significant changes at regional scale". and
• "There is medium confidence that both ENSO amplitude and the frequency of high-magnitude events since 1950 are higher than over the period from 1850 and possibly as far back as 1400".

Impacts

On precipitation

Regional impacts of El Niño

 

Regional impacts of La Niña.

Developing countries dependent upon agriculture and fishing, particularly those bordering the Pacific Ocean, are the most affected by ENSO. The effects of El Niño in South America are direct and strong. An El Niño is associated with warm and very wet weather months in April–October along the coasts of northern Peru and Ecuador, causing major flooding whenever the event is strong or extreme. La Niña causes a drop in sea surface temperatures over Southeast Asia and heavy rains over Malaysia, the Philippines, and Indonesia.

To the north across Alaska, La Niña events lead to drier than normal conditions, while El Niño events do not have a correlation towards dry or wet conditions. During El Niño events, increased precipitation is expected in California due to a more southerly, zonal, storm track. During La Niña, increased precipitation is diverted into the Pacific Northwest due to a more northerly storm track. During La Niña events, the storm track shifts far enough northward to bring wetter than normal winter conditions (in the form of increased snowfall) to the Midwestern states, as well as hot and dry summers. During the El Niño portion of ENSO, increased precipitation falls along the Gulf coast and Southeast due to a stronger than normal, and more southerly, polar jet stream.

In the late winter and spring during El Niño events, drier than average conditions can be expected in Hawaii. On Guam during El Niño years, dry season precipitation averages below normal. However, the threat of a tropical cyclone is over triple what is normal during El Niño years, so extreme shorter duration rainfall events are possible. On American Samoa during El Niño events, precipitation averages about 10 percent above normal, while La Niña events lead to precipitation amounts which average close to 10 percent below normal. ENSO is linked to rainfall over Puerto Rico. During an El Niño, snowfall is greater than average across the southern Rockies and Sierra Nevada mountain range, and is well-below normal across the Upper Midwest and Great Lakes states. During a La Niña, snowfall is above normal across the Pacific Northwest and western Great Lakes. In Western Asia, during the region's November–April rainy season, it was discovered that in the El Niño phase there was increased precipitation, and in the La Niña phase there was a reduced amount of precipitation on average.

Although ENSO can dramatically affect precipitation, even severe droughts and rainstorms in ENSO areas are not always deadly. Scholar Mike Davis cites ENSO as responsible for droughts in India and China in the late nineteenth century, but argues that nations in these areas avoided devastating famine during these droughts with institutional preparation and organized relief efforts.

On Tehuantepecers

Main article: Tehuantepecer

The synoptic condition for the Tehuantepecer, a violent mountain-gap wind in between the mountains of Mexico and Guatemala, is associated with high-pressure system forming in Sierra Madre of Mexico in the wake of an advancing cold front, which causes winds to accelerate through the Isthmus of Tehuantepec. Tehuantepecers primarily occur during the cold season months for the region in the wake of cold fronts, between October and February, with a summer maximum in July caused by the westward extension of the Azores-Bermuda high pressure system. Wind magnitude is greater during El Niño years than during La Niña years, due to the more frequent cold frontal incursions during El Niño winters. Tehuantepec winds reach 20 knots (40 km/h) to 45 knots (80 km/h), and on rare occasions 100 knots (190 km/h). The wind's direction is from the north to north-northeast. It leads to a localized acceleration of the trade winds in the region, and can enhance thunderstorm activity when it interacts with the Intertropical Convergence Zone. The effects can last from a few hours to six days.

On coral bleaching

Main article: Coral bleaching

Following the El Nino event in 1997 – 1998, the Pacific Marine Environmental Laboratory attributes the first large-scale coral bleaching event to the warming waters.

On hurricanes

See also: Hurricanes and climate change

Based on modeled and observed accumulated cyclone energy (ACE), El Niño years usually result in less active hurricane seasons in the Atlantic Ocean, but instead favor a shift of tropical cyclone activity in the Pacific Ocean, compared to La Niña years favoring above average hurricane development in the Atlantic and less so in the Pacific basin.

Variations

See also: El Niño § Variations, and La Niña § Variations

The traditional ENSO (El Niño Southern Oscillation), also called Eastern Pacific (EP) ENSO, involves temperature anomalies in the eastern Pacific. However, in the 1990s and 2000s, nontraditional ENSO conditions were observed, in which the usual place of the temperature anomaly (Niño 1 and 2) is not affected, but an anomaly arises in the central Pacific (Niño 3.4). The phenomenon is called Central Pacific (CP) ENSO, "dateline" ENSO (because the anomaly arises near the dateline), or ENSO "Modoki" (Modoki is Japanese for "similar, but different"). There are flavors of ENSO additional to EP and CP types and some scientists argue that ENSO exists as a continuum often with hybrid types.

The effects of the CP ENSO are different from those of the traditional EP ENSO. The El Niño Modoki leads to more hurricanes more frequently making landfall in the Atlantic. La Niña Modoki leads to a rainfall increase over northwestern Australia and northern Murray–Darling basin, rather than over the east as in a conventional La Niña. Also, La Niña Modoki increases the frequency of cyclonic storms over Bay of Bengal, but decreases the occurrence of severe storms in the Indian Ocean.

The recent discovery of ENSO Modoki has some scientists believing it to be linked to global warming. However, comprehensive satellite data go back only to 1979. More research must be done to find the correlation and study past El Niño episodes. More generally, there is no scientific consensus on how/if climate change might affect ENSO.

There is also a scientific debate on the very existence of this "new" ENSO. Indeed, a number of studies dispute the reality of this statistical distinction or its increasing occurrence, or both, either arguing the reliable record is too short to detect such a distinction, finding no distinction or trend using other statistical approaches, or that other types should be distinguished, such as standard and extreme ENSO.

Following the asymmetric nature of the warm and cold phases of ENSO, some studies could not identify such distinctions for La Niña, both in observations and in the climate models, but some sources indicate that there is a variation on La Niña with cooler waters on central Pacific and average or warmer water temperatures on both eastern and western Pacific, also showing eastern Pacific Ocean currents going to the opposite direction compared to the currents in traditional La Niñas.

Magnetic refrigeration

From Wikipedia, the free encyclopedia

https://en.wikipedia.org/wiki/Magnetic_refrigeration

Gadolinium alloy heats up inside the magnetic field and loses thermal energy to the environment, so it exits the field and becomes cooler than when it entered.

Magnetic refrigeration is a cooling technology based on the magnetocaloric effect. This technique can be used to attain extremely low temperatures, as well as the ranges used in common refrigerators.

A magnetocaloric material warms up when a magnetic field is applied. The warming is due to changes in the internal state of the material releasing heat. When the magnetic field is removed, the material returns to its original state, reabsorbing the heat, and returning to original temperature. To achieve refrigeration, the material is allowed to radiate away its heat while in the magnetized hot state. Removing the magnetism, the material then cools to below its original temperature.

The effect was first observed in 1881 by a German physicist Emil Warburg, followed by French physicist P. Weiss and Swiss physicist A. Piccard in 1917. The fundamental principle was suggested by P. Debye (1926) and W. Giauque (1927). The first working magnetic refrigerators were constructed by several groups beginning in 1933. Magnetic refrigeration was the first method developed for cooling below about 0.3 K (a temperature attainable by pumping on ³
He vapors).

Magnetocaloric effect

The magnetocaloric effect (MCE, from magnet and calorie) is a magneto-thermodynamic phenomenon in which a temperature change of a suitable material is caused by exposing the material to a changing magnetic field. This is also known by low temperature physicists as adiabatic demagnetization. In that part of the refrigeration process, a decrease in the strength of an externally applied magnetic field allows the magnetic domains of a magnetocaloric material to become disoriented from the magnetic field by the agitating action of the thermal energy (phonons) present in the material. If the material is isolated so that no energy is allowed to (re)migrate into the material during this time, (i.e., an adiabatic process) the temperature drops as the domains absorb the thermal energy to perform their reorientation. The randomization of the domains occurs in a similar fashion to the randomization at the curie temperature of a ferromagnetic material, except that magnetic dipoles overcome a decreasing external magnetic field while energy remains constant, instead of magnetic domains being disrupted from internal ferromagnetism as energy is added.

One of the most notable examples of the magnetocaloric effect is in the chemical element gadolinium and some of its alloys. Gadolinium's temperature increases when it enters certain magnetic fields. When it leaves the magnetic field, the temperature drops. The effect is considerably stronger for the gadolinium alloy Gd
₅(Si
₂Ge
₂). Praseodymium alloyed with nickel (PrNi
₅) has such a strong magnetocaloric effect that it has allowed scientists to approach to within one millikelvin, one thousandth of a degree of absolute zero.

Equation

The magnetocaloric effect can be quantified with the following equation:

$${\displaystyle \mathrm{\Delta }{T}_{ad}=-{\int }_{H_0}^{H_1}{\left(\frac{T}{C(T,H)}\right)}_H{\left(\frac{\mathrm{\partial }M(T,H)}{\mathrm{\partial }T}\right)}_{H}dH}$$

where ${\displaystyle \mathrm{\Delta }{T}_{ad}}$ is the adiabatic change in temperature of the magnetic system around temperature T, H is the applied external magnetic field, C is the heat capacity of the working magnet (refrigerant) and M is the magnetization of the refrigerant.

From the equation we can see that the magnetocaloric effect can be enhanced by:

• a large field variation
• a magnet material with a small heat capacity
• a magnet with large changes in net magnetization vs. temperature, at constant magnetic field

The adiabatic change in temperature, ${\displaystyle \mathrm{\Delta }{T}_{ad}}$, can be seen to be related to the magnet's change in magnetic entropy (${\displaystyle \mathrm{\Delta }S}$) since

$${\displaystyle \mathrm{\Delta }S(T)={\int }_{H_0}^{H_1}\left(\frac{\mathrm{\partial }M(T,H^{\prime })}{\mathrm{\partial }T}\right)d{H}^{\prime }}$$

This implies that the absolute change in the magnet's entropy determines the possible magnitude of the adiabatic temperature change under a thermodynamic cycle of magnetic field variation. T

Thermodynamic cycle

Analogy between magnetic refrigeration and vapor cycle or conventional refrigeration. H = externally applied magnetic field; Q = heat quantity; P = pressure; ΔT_ad = adiabatic temperature variation

The cycle is performed as a refrigeration cycle that is analogous to the Carnot refrigeration cycle, but with increases and decreases in magnetic field strength instead of increases and decreases in pressure. It can be described at a starting point whereby the chosen working substance is introduced into a magnetic field, i.e., the magnetic flux density is increased. The working material is the refrigerant, and starts in thermal equilibrium with the refrigerated environment.

• Adiabatic magnetization: A magnetocaloric substance is placed in an insulated environment. The increasing external magnetic field (+H) causes the magnetic dipoles of the atoms to align, thereby decreasing the material's magnetic entropy and heat capacity. Since overall energy is not lost (yet) and therefore total entropy is not reduced (according to thermodynamic laws), the net result is that the substance is heated (T + ΔT_ad).
• Isomagnetic enthalpic transfer: This added heat can then be removed (-Q) by a fluid or gas — gaseous or liquid helium, for example. The magnetic field is held constant to prevent the dipoles from reabsorbing the heat. Once sufficiently cooled, the magnetocaloric substance and the coolant are separated (H=0).
• Adiabatic demagnetization: The substance is returned to another adiabatic (insulated) condition so the total entropy remains constant. However, this time the magnetic field is decreased, the thermal energy causes the magnetic moments to overcome the field, and thus the sample cools, i.e., an adiabatic temperature change. Energy (and entropy) transfers from thermal entropy to magnetic entropy, measuring the disorder of the magnetic dipoles.
• Isomagnetic entropic transfer: The magnetic field is held constant to prevent the material from reheating. The material is placed in thermal contact with the environment to be refrigerated. Because the working material is cooler than the refrigerated environment (by design), heat energy migrates into the working material (+Q).

Once the refrigerant and refrigerated environment are in thermal equilibrium, the cycle can restart.

Applied technique

The basic operating principle of an adiabatic demagnetization refrigerator (ADR) is the use of a strong magnetic field to control the entropy of a sample of material, often called the "refrigerant". Magnetic field constrains the orientation of magnetic dipoles in the refrigerant. The stronger the magnetic field, the more aligned the dipoles are, corresponding to lower entropy and heat capacity because the material has (effectively) lost some of its internal degrees of freedom. If the refrigerant is kept at a constant temperature through thermal contact with a heat sink (usually liquid helium) while the magnetic field is switched on, the refrigerant must lose some energy because it is equilibrated with the heat sink. When the magnetic field is subsequently switched off, the heat capacity of the refrigerant rises again because the degrees of freedom associated with orientation of the dipoles are once again liberated, pulling their share of equipartitioned energy from the motion of the molecules, thereby lowering the overall temperature of a system with decreased energy. Since the system is now insulated when the magnetic field is switched off, the process is adiabatic, i.e., the system can no longer exchange energy with its surroundings (the heat sink), and its temperature decreases below its initial value, that of the heat sink.

The operation of a standard ADR proceeds roughly as follows. First, a strong magnetic field is applied to the refrigerant, forcing its various magnetic dipoles to align and putting these degrees of freedom of the refrigerant into a state of lowered entropy. The heat sink then absorbs the heat released by the refrigerant due to its loss of entropy. Thermal contact with the heat sink is then broken so that the system is insulated, and the magnetic field is switched off, increasing the heat capacity of the refrigerant, thus decreasing its temperature below the temperature of the heat sink. In practice, the magnetic field is decreased slowly in order to provide continuous cooling and keep the sample at an approximately constant low temperature. Once the field falls to zero or to some low limiting value determined by the properties of the refrigerant, the cooling power of the ADR vanishes, and heat leaks will cause the refrigerant to warm up.

Working materials

The magnetocaloric effect (MCE) is an intrinsic property of a magnetic solid. This thermal response of a solid to the application or removal of magnetic fields is maximized when the solid is near its magnetic ordering temperature. Thus, the materials considered for magnetic refrigeration devices should be magnetic materials with a magnetic phase transition temperature near the temperature region of interest. For refrigerators that could be used in the home, this temperature is room temperature. The temperature change can be further increased when the order-parameter of the phase transition changes strongly within the temperature range of interest.

The magnitudes of the magnetic entropy and the adiabatic temperature changes are strongly dependent upon the magnetic ordering process. The magnitude is generally small in antiferromagnets, ferrimagnets and spin glass systems but can be much larger for ferromagnets that undergo a magnetic phase transition. First order phase transitions are characterized by a discontinuity in the magnetization changes with temperature, resulting in a latent heat. Second order phase transitions do not have this latent heat associated with the phase transition.

In the late 1990s Pecharksy and Gschneidner reported a magnetic entropy change in Gd
₅(Si
₂Ge
₂) that was about 50% larger than that reported for Gd metal, which had the largest known magnetic entropy change at the time. This giant magnetocaloric effect (GMCE) occurred at 270 K, which is lower than that of Gd (294 K). Since the MCE occurs below room temperature these materials would not be suitable for refrigerators operating at room temperature. Since then other alloys have also demonstrated the giant magnetocaloric effect. These include Gd
₅(Si
_xGe
_1−x)
₄, La(Fe
_xSi
_1−x)
₁₃H
_x and MnFeP
_1−xAs
_x alloys. Gadolinium and its alloys undergo second-order phase transitions that have no magnetic or thermal hysteresis. However, the use of rare earth elements makes these materials very expensive.

Current research has been used to describe alloys with a significant magnetocaloric effect in terms of a thermodynamic system. Literature says that Gd₅(Si₂Ge₂) for example may be described as a thermodynamic system provided it satisfies the condition of being “a quantity of matter or region in space chosen for study”. Such systems have become relevant to modern research in thermodynamics because they serve as plausible materials for the creation of high performance thermoelectric materials.

Ni
₂Mn-X (X = Ga, Co, In, Al, Sb) Heusler alloys are also promising candidates for magnetic cooling applications because they have Curie temperatures near room temperature and, depending on composition, can have martensitic phase transformations near room temperature. These materials exhibit the magnetic shape memory effect and can also be used as actuators, energy harvesting devices, and sensors. When the martensitic transformation temperature and the Curie temperature are the same (based on composition) the magnitude of the magnetic entropy change is the largest. In February 2014, GE announced the development of a functional Ni-Mn-based magnetic refrigerator.

The development of this technology is very material-dependent and will likely not replace vapor-compression refrigeration without significantly improved materials that are cheap, abundant, and exhibit much larger magnetocaloric effects over a larger range of temperatures. Such materials need to show significant temperature changes under a field of two tesla or less, so that permanent magnets can be used for the production of the magnetic field.

Paramagnetic salts

The original proposed refrigerant was a paramagnetic salt, such as cerium magnesium nitrate. The active magnetic dipoles in this case are those of the electron shells of the paramagnetic atoms.

In a paramagnetic salt ADR, the heat sink is usually provided by a pumped ⁴
He (about 1.2 K) or ³
He (about 0.3 K) cryostat. An easily attainable 1 T magnetic field is generally required for initial magnetization. The minimum temperature attainable is determined by the self-magnetization tendencies of the refrigerant salt, but temperatures from 1 to 100 mK are accessible. Dilution refrigerators had for many years supplanted paramagnetic salt ADRs, but interest in space-based and simple to use lab-ADRs has remained, due to the complexity and unreliability of the dilution refrigerator.

At a low enough temperature, paramagnetic salts become either diamagnetic or ferromagnetic, limiting the lowest temperature that can be reached using this method.

Nuclear demagnetization

One variant of adiabatic demagnetization that continues to find substantial research application is nuclear demagnetization refrigeration (NDR). NDR follows the same principles, but in this case the cooling power arises from the magnetic dipoles of the nuclei of the refrigerant atoms, rather than their electron configurations. Since these dipoles are of much smaller magnitude, they are less prone to self-alignment and have lower intrinsic minimum fields. This allows NDR to cool the nuclear spin system to very low temperatures, often 1 µK or below. Unfortunately, the small magnitudes of nuclear magnetic dipoles also makes them less inclined to align to external fields. Magnetic fields of 3 teslas or greater are often needed for the initial magnetization step of NDR.

In NDR systems, the initial heat sink must sit at very low temperatures (10–100 mK). This precooling is often provided by the mixing chamber of a dilution refrigerator or a paramagnetic salt.

Commercial development

Research and a demonstration proof of concept device in 2001 succeeded in applying commercial-grade materials and permanent magnets at room temperatures to construct a magnetocaloric refrigerator.

On August 20, 2007, the Risø National Laboratory (Denmark) at the Technical University of Denmark, claimed to have reached a milestone in their magnetic cooling research when they reported a temperature span of 8.7 K. They hoped to introduce the first commercial applications of the technology by 2010.

As of 2013 this technology had proven commercially viable only for ultra-low temperature cryogenic applications available for decades. Magnetocaloric refrigeration systems are composed of pumps, motors, secondary fluids, heat exchangers of different types, magnets and magnetic materials. These processes are greatly affected by irreversibilities and should be adequately considered. At year-end, Cooltech Applications announced that its first commercial refrigeration equipment would enter the market in 2014. Cooltech Applications launched their first commercially available magnetic refrigeration system on 20 June 2016. At the 2015 Consumer Electronics Show in Las Vegas, a consortium of Haier, Astronautics Corporation of America and BASF presented the first cooling appliance. BASF claim of their technology a 35% improvement over using compressors.

In November 2015, at the Medica 2015 fair, Cooltech Applications presented, in collaboration with Kirsch medical GmbH, the world's first magnetocaloric medical cabinet. One year later, in September 2016, at the 7th International Conference on Magnetic Refrigeration at Room Temperature (Thermag VII)] held in Torino, Italy, Cooltech Applications presented the world's first magnetocaloric frozen heat exchanger.

In 2017, Cooltech Applications presented a fully functional 500 liters' magnetocaloric cooled cabinet with a 30 kg (66 lb) load and an air temperature inside the cabinet of +2 °C. That proved that magnetic refrigeration is a mature technology, capable of replacing the classic refrigeration solutions.

One year later, in September 2018, at the 8th International Conference on Magnetic Refrigeration at Room Temperature (Thermag VIII]), Cooltech Applications presented a paper on a magnetocaloric prototype designed as a 15 kW proof-of-concept unit. This has been considered by the community as the largest magnetocaloric prototype ever created.

At the same conference, Dr. Sergiu Lionte announced that, due to financial issues, Cooltech Applications declared bankruptcy. Later on, in 2019 Ubiblue company, today named Magnoric, is formed by some of the old Cooltech Application's team members. The entire patent portfolio form Cooltech Applications was taken over by Magnoric since then, while publishing additional patents at the same time.

In 2019, at the 5th Delft Days Conference on Magnetocalorics, Dr. Sergiu Lionte presented Ubiblue's (former Cooltech Application) last prototype. Later, the magnetocaloric community acknowledged that Ubiblue had the most developed magnetocalorics prototypes.

Thermal and magnetic hysteresis problems remain to be solved for first-order phase transition materials that exhibit the GMCE.

One potential application is in spacecraft.

Vapor-compression refrigeration units typically achieve performance coefficients of 60% of that of a theoretical ideal Carnot cycle, much higher than current MR technology. Small domestic refrigerators are however much less efficient.

In 2014 giant anisotropic behaviour of the magnetocaloric effect was found in HoMn
₂O
₅ at 10 K. The anisotropy of the magnetic entropy change gives rise to a large rotating MCE offering the possibility to build simplified, compact, and efficient magnetic cooling systems by rotating it in a constant magnetic field.

In 2015 Aprea et al. presented a new refrigeration concept, GeoThermag, which is a combination of magnetic refrigeration technology with that of low-temperature geothermal energy. To demonstrate the applicability of the GeoThermag technology, they developed a pilot system that consists of a 100-m deep geothermal probe; inside the probe, water flows and is used directly as a regenerating fluid for a magnetic refrigerator operating with gadolinium. The GeoThermag system showed the ability to produce cold water even at 281.8 K in the presence of a heat load of 60 W. In addition, the system has shown the existence of an optimal frequency f AMR, 0.26 Hz, for which it was possible to produce cold water at 287.9 K with a thermal load equal to 190 W with a COP of 2.20. Observing the temperature of the cold water that was obtained in the tests, the GeoThermag system showed a good ability to feed the cooling radiant floors and a reduced capacity for feeding the fan coil systems.

History

The effect was discovered first observed by German physicist Emil Warburg in 1881, subsequently by French physicist Pierre Weiss and Swiss physicist Auguste Piccard in 1917.

Major advances first appeared in the late 1920s when cooling via adiabatic demagnetization was independently proposed by chemistry Nobel Laureates Peter Debye in 1926 and William F. Giauque in 1927.

It was first demonstrated experimentally by Giauque and his colleague D. P. MacDougall in 1933 for cryogenic purposes when they reached 0.25 K. Between 1933 and 1997, advances in MCE cooling occurred.

In 1997, the first near room-temperature proof of concept magnetic refrigerator was demonstrated by Karl A. Gschneidner, Jr. by the Iowa State University at Ames Laboratory. This event attracted interest from scientists and companies worldwide who started developing new kinds of room temperature materials and magnetic refrigerator designs.

A major breakthrough came 2002 when a group at the University of Amsterdam demonstrated the giant magnetocaloric effect in MnFe(P,As) alloys that are based on abundant materials.

Refrigerators based on the magnetocaloric effect have been demonstrated in laboratories, using magnetic fields starting at 0.6 T up to 10 T. Magnetic fields above 2 T are difficult to produce with permanent magnets and are produced by a superconducting magnet (1 T is about 20.000 times the Earth's magnetic field).

Electronic skin

From Wikipedia, the free encyclopedia

https://en.wikipedia.org/wiki/Electronic_skin 

Electronic skin refers to flexible, stretc hable and self-healing electronics that are able to mimic functionalities of human or animal skin. The broad class of materials often contain sensing abilities that are intended to reproduce the capabilities of human skin to respond to environmental factors such as changes in heat and pressure.

Advances in electronic skin research focuses on designing materials that are stretchy, robust, and flexible. Research in the individual fields of flexible electronics and tactile sensing has progressed greatly; however, electronic skin design attempts to bring together advances in many areas of materials research without sacrificing individual benefits from each field. The successful combination of flexible and stretchable mechanical properties with sensors and the ability to self-heal would open the door to many possible applications including soft robotics, prosthetics, artificial intelligence and health monitoring.

Recent advances in the field of electronic skin have focused on incorporating green materials ideals and environmental awareness into the design process. As one of the main challenges facing electronic skin development is the ability of the material to withstand mechanical strain and maintain sensing ability or electronic properties, recyclability and self-healing properties are especially critical in the future design of new electronic skins.

Rehealable electronic skin

Self-healing abilities of electronic skin are critical to potential applications of electronic skin in fields such as soft robotics. Proper design of self-healing electronic skin requires not only healing of the base substrate but also the reestablishment of any sensing functions such as tactile sensing or electrical conductivity. Ideally, the self-healing process of electronic skin does not rely upon outside stimulation such as increased temperature, pressure, or solvation. Self-healing, or rehealable, electronic skin is often achieved through a polymer-based material or a hybrid material.

Polymer-based materials

In 2018, Zou et al. published work on electronic skin that is able to reform covalent bonds when damaged. The group looked at a polyimine-based crosslinked network, synthesized as seen in Figure 1. The e-skin is considered rehealable because of "reversible bond exchange," meaning that the bonds holding the network together are able to break and reform under certain conditions such as solvation and heating. The rehealable and reusable aspect of such a thermoset material is unique because many thermoset materials irreversibly form crosslinked networks through covalent bonds. In the polymer network the bonds formed during the healing process are indistinguishable from the original polymer network.

Figure 1. Polymerization scheme for formation of polyimine-based self-healing electronic skin.

Dynamic non-covalent crosslinking has also been shown to form a polymer network that is rehealable. In 2016, Oh et al. looked specifically at semiconducting polymers for organic transistors. They found that incorporating 2,6-pyridine dicarboxamide (PDCA) into the polymer backbone could impart self-healing abilities based on the network of hydrogen bonds formed between groups. With incorporation of PDCA in the polymer backbone, the materials was able to withstand up to 100% strain without showing signs of microscale cracking. In this example, the hydrogen bonds are available for energy dissipation as the strain increases.

Hybrid materials

Polymer networks are able to facilitate dynamic healing processes through hydrogen bonds or dynamic covalent chemistry. However, the incorporation of inorganic particles can greatly expand the functionality of polymer-based materials for electronic skin applications. The incorporation of micro-structured nickel particles into a polymer network (Figure 2) has been shown to maintain self-healing properties based on the reformation of hydrogen bonding networks around the inorganic particles. The material is able to regain its conductivity within 15 seconds of breakage, and the mechanical properties are regained after 10 minutes at room temperature without added stimulus. This material relies on hydrogen bonds formed between urea groups when they align. The hydrogen atoms of urea functional groups are ideally situated to form a hydrogen-bonding network because they are near an electron-withdrawing carbonyl group. This polymer network with embedded nickel particles demonstrates the possibility of using polymers as supramolecular hosts to develop self-healing conductive composites.

Figure 2. Self-healing material based on hydrogen bonding and interactions with micro-structured nickel particles.

Flexible and porous graphene foams that are interconnected in a 3D manner have also been shown to have self-healing properties. Thin film with poly(N,N-dimethylacrylamide)-poly(vinyl alcohol) (PDMAA) and reduced graphene oxide have shown high electrical conductivity and self-healing properties. The healing abilities of the hybrid composite are suspected to be due to the hydrogen bonds between the PDMAA chains, and the healing process is able to restore initial length and recover conductive properties.

Recyclable electronic skin

Zou et al. presents an interesting advance in the field of electronic skin that can be used in robotics, prosthetics, and many other applications in the form of a fully recyclable electronic skin material. The e-skin developed by the group consists of a network of covalently bound polymers that are thermoset, meaning cured at a specific temperature. However, the material is also recyclable and reusable. Because the polymer network is thermoset, it is chemically and thermally stable. However, at room temperature, the polyimine material, with or without silver nanoparticles, can be dissolved on the timescale of a few hours. The recycling process allows devices, which are damaged beyond self-healing capabilities, to be dissolved and formed into new devices (Figure 3). This advance opens the door for lower cost production and greener approaches to e-skin development.

Figure 3. Recycling process for conductive polyimine-based e-skin.

Flexible and stretchy electronic skin

The ability of electronic skin to withstand mechanical deformation including stretching and flexing without losing functionality is crucial for its applications as prosthetics, artificial intelligence, soft robotics, health monitoring, biocompatibility, and communication devices. Flexible electronics are often designed by depositing electronic materials on flexible polymer substrates, thereby relying on an organic substrate to impart favorable mechanical properties. Stretchable e-skin materials have been approached from two directions. Hybrid materials can rely on an organic network for stretchiness while embedding inorganic particles or sensors, which are not inherently stretchable. Other research has focused on developing stretchable materials that also have favorable electronic or sensing capabilities.

Zou et al. studied the inclusion of linkers that are described as "serpentine" in their polyimine matrix. These linkers make the e-skin sensors able to flex with movement and distortion. The incorporation of alkyl spacers in polymer-based materials has also been shown to increase flexibility without decreasing charge transfer mobility. Oh et al. developed a stretchable and flexible material based on 3,6-di(thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione (DPP) and non-conjugated 2,6-pyridine dicarboxamide (PDCA) as a source of hydrogen bonds (Figure 4).

Figure 4. A stretchable and self-healing semiconducting polymer-based material.

Graphene has also been shown to be a suitable material for electronic skin applications as well due to its stiffness and tensile strength. Graphene is an appealing material because its synthesis to flexible substrates is scalable and cost-efficient.

Mechanical Properties of Skin

Skin is composed of collagen, keratin, and elastin fibers, which provide robust mechanical strength, low modulus, tear resistance, and softness. The skin can be considered as a bilayer of epidermis and dermis. The epidermal layer has a modulus of about 140-600 kPa and a thickness of 0.05-1.5 mm. Dermis has a modulus of 2-80 kPa and a thickness of 0.3-3 mm. This bilayer skin exhibits an elastic linear response for strains less than 15% and a non linear response at larger strains. To achieve conformability, it is preferable for devices to match the mechanical properties of the epidermis layer when designing skin-based stretchy electronics.

Tuning Mechanical Properties

Conventional high performance electronic devices are made of inorganic materials such as silicon, which is rigid and brittle in nature and exhibits poor biocompatibility due to mechanical mismatch between the skin and the device, making skin integrated electronics applications difficult. To solve this challenge, researchers employed the method of constructing flexible electronics in the form of ultrathin layers. The resistance to bending of a material object (Flexural rigidity) is related to the third power of the thickness, according to the Euler-Bernoulli equation for a beam. It implies that objects with less thickness can bend and stretch more easily. As a result, even though the material has a relatively high Young's modulus, devices manufactured on ultrathin substrates exhibit a decrease in bending stiffness and allow bending to a small radius of curvature without fracturing. Thin devices have been developed as a result of significant advancements in the field of nanotechnology, fabrication, and manufacturing. The aforementioned approach was used to create devices composed of 100-200 nm thick Si nano membranes deposited on thin flexible polymeric substrates.

Furthermore, structural design considerations can be used to tune the mechanical stability of the devices. Engineering the original surface structure allows us to soften the stiff electronics. Buckling, island connection, and the Kirigami concept have all been employed successfully to make the entire system stretchy.

Mechanical buckling can be used to create wavy structures on elastomeric thin substrates. This feature improves the device's stretchability. The buckling approach was used to create Si nanoribbons from single crystal Si on an elastomeric substrate. The study demonstrated the device could bear a maximum strain of 10% when compressed and stretched.

In the case of island interconnect, the rigid material connects with flexible bridges made from different geometries, such as zig-zag, serpentine-shaped structures, etc., to reduce the effective stiffness, tune the stretchability of the system, and elastically deform under applied strains in specific directions. It has been demonstrated that serpentine-shaped structures have no significant effect on the electrical characteristics of epidermal electronics. It has also been shown that the entanglement of the interconnects, which oppose the movement of the device above the substrate, causes the spiral interconnects to stretch and deform significantly more than the serpentine structures. CMOS inverters constructed on a PDMS substrate employing 3D island interconnect technologies demonstrated 140% strain at stretching.

Kirigami is built around the concept of folding and cutting in 2D membranes. This contributes to an increase in the tensile strength of the substrate, as well as its out-of-plane deformation and stretchability. These 2D structures can subsequently be turned to 3D structures with varied topography, shape, and size controllability via the Buckling process, resulting in interesting properties and applications.

Conductive electronic skin

The development of conductive electronic skin is of interest for many electrical applications. Research into conductive electronic skin has taken two routes: conductive self-healing polymers or embedding conductive inorganic materials in non-conductive polymer networks.

The self-healing conductive composite synthesized by Tee et al. (Figure 2) investigated the incorporation of micro-structured nickel particles into a polymer host. The nickel particles adhere to the network though favorable interactions between the native oxide layer on the surface of the particles and the hydrogen-bonding polymer.

Nanoparticles have also been studied for their ability to impart conductivity on electronic skin materials. Zou et al. embedded silver nanoparticles (AgNPs) into a polymer matrix, making the e-skin conductive. The healing process for this material is noteworthy because it not only restores the mechanical properties of the polymer network, but also restores the conductive properties when silver nanoparticles have been embedded in the polymer network.

Sensing ability of electronic skin

Some of the challenges that face electronic skin sensing abilities include the fragility of sensors, the recovery time of sensors, repeatability, overcoming mechanical strain, and long-term stability.

Tactile sensors

Applied pressure can be measured by monitoring changes in resistance or capacitance. Coplanar interdigitated electrodes embedded on single-layer graphene have been shown to provide pressure sensitivity for applied pressure as low as 0.11 kPa through measuring changes in capacitance. Piezoresistive sensors have also shown high levels of sensitivity.

Ultrathin molybdenum disulfide sensing arrays integrated with graphene have demonstrated promising mechanical properties capable of pressure sensing. Modifications of organic field effect transistors (OFETs) have shown promise in electronic skin applications. Microstructured polydimethylsiloxane thin films can elastically deform when pressure is applied. The deformation of the thin film allows for storage and release of energy.

Visual representation of applied pressure has been one area of interest in development of tactile sensors. The Bao Group at Stanford University have designed an electrochromically active electronic skin that changes color with different amounts of applied pressure. Applied pressure can also be visualized by incorporation of active-matrix organic light-emitting diode displays which emit light when pressure is applied.

Prototype e-skins include a printed synaptic transistor–based electronic skin giving skin-like haptic sensations and touch/pain-sensitivity to a robotic hand, and a multilayer tactile sensor repairable hydrogel-based robot skin.

Other sensing applications

Humidity sensors have been incorporated in electronic skin design with sulfurized tungsten films. The conductivity of the film changes with different levels of humidity. Silicon nanoribbons have also been studied for their application as temperature, pressure, and humidity sensors. Scientists at the University of Glasgow have made inroads in developing an e-skin that feels pain real-time, with applications in prosthetics and more life-like humanoids.

A system of an electronic skin and a human-machine interface that can enable remote sensed tactile perception, and wearable or robotic sensing of many hazardous substances and pathogens.