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A mineral is a naturally occurring substance that is solid and inorganic representable by a chemical formula, usually abiogenic, and has an ordered atomic structure. It is different from a rock, which can be an aggregate of minerals or non-minerals and does not have a specific chemical composition. The exact definition of a mineral is under debate, especially with respect to the requirement a valid species be abiogenic, and to a lesser extent with regard to it having an ordered atomic structure. The study of minerals is called mineralogy.
There are over 4,900 known mineral species; over 4,660 of these have been approved by the International Mineralogical Association (IMA). The silicate minerals compose over 90% of the Earth's crust. The diversity and abundance of mineral species is controlled by the Earth's chemistry. Silicon and oxygen constitute approximately 75% of the Earth's crust, which translates directly into the predominance of silicate minerals. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish various species, and these properties in turn are influenced by the mineral's geological environment of formation. Changes in the temperature, pressure, and bulk composition of a rock mass cause changes in its mineralogy; however, a rock can maintain its bulk composition, but as long as temperature and pressure change, its mineralogy can change as well.
Minerals can be described by various physical properties which relate to their chemical structure and composition. Common distinguishing characteristics include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, tenacity, cleavage, fracture, parting, and specific gravity. More specific tests for minerals include reaction to acid, magnetism, taste or smell, and radioactivity.
Minerals are classified by key chemical constituents; the two dominant systems are the Dana classification and the Strunz classification. The silicate class of minerals is subdivided into six subclasses by the degree of polymerization in the chemical structure. All silicate minerals have a base unit of a [SiO4]4− silica tetrahedra—that is, a silicon cation coordinated by four oxygen anions, which gives the shape of a tetrahedron. These tetrahedra can be polymerized to give the subclasses: orthosilicates (no polymerization, thus single tetrahedra), disilicates (two tetrahedra bonded together), cyclosilicates (rings of tetrahedra), inosilicates (chains of tetrahedra), phyllosilicates (sheets of tetrahedra), and tectosilicates (three-dimensional network of tetrahedra). Other important mineral groups include the native elements, sulfides, oxides, halides, carbonates, sulfates, and phosphates.
Definition
Basic definition
The general definition of a mineral encompasses the following criteria:[1]- Naturally occurring
- Stable at room temperature
- Represented by a chemical formula
- Usually abiogenic (not resulting from the activity of living organisms)
- Ordered atomic arrangement
The requirement of a valid mineral species to be abiogenic has also been described as similar to have to be inorganic; however, this criterion is imprecise and organic compounds have been assigned a separate classification branch. Finally, the requirement of an ordered atomic arrangement is usually synonymous to being crystalline; however, crystals are periodic in addition to being ordered, so the broader criterion is used instead.[1] The presence of an ordered atomic arrangement translates to a variety of macroscopic physical properties, such as crystal form, hardness, and cleavage.[5] There have been several recent proposals to amend the definition to consider biogenic or amorphous substances as minerals. The formal definition of a mineral approved by the IMA in 1995:
"A mineral is an element or chemical compound that is normally crystalline and that has been formed as a result of geological processes."[6]In addition, biogenic substances were explicitly excluded:
"Biogenic substances are chemical compounds produced entirely by biological processes without a geological component (e.g., urinary calculi, oxalate crystals in plant tissues, shells of marine molluscs, etc.) and are not regarded as minerals. However, if geological processes were involved in the genesis of the compound, then the product can be accepted as a mineral."[6]
Recent advances
Mineral classification schemes and their definitions are evolving to match recent advances in mineral science. Recent changes have included the addition of an organic class, in both the new Dana and the Strunz classification schemes.[7][8] The organic class includes a very rare group of minerals with hydrocarbons. The IMA Commission on New Minerals and Mineral Names adopted in 2009 a hierarchical scheme for the naming and classification of mineral groups and group names[9] and established seven commissions and four working groups to review and classify minerals into an official listing of their published names.[10] According to these new rules, "mineral species can be grouped in a number of different ways, on the basis of chemistry, crystal structure, occurrence, association, genetic history, or resource, for example, depending on the purpose to be served by the classification."[9]The Nickel (1995) exclusion of biogenic substances was not universally adhered to. For example, Lowenstam (1981) stated that "organisms are capable of forming a diverse array of minerals, some of which cannot be formed inorganically in the biosphere."[11] The distinction is a matter of classification and less to do with the constituents of the minerals themselves. Skinner (2005) views all solids as potential minerals and includes biominerals in the mineral kingdom, which are those that are created by the metabolic activities of organisms. Skinner expanded the previous definition of a mineral to classify "element or compound, amorphous or crystalline, formed through biogeochemical processes," as a mineral.[12]
Recent advances in high-resolution genetic and x-ray absorption spectroscopy is opening new revelations on the biogeochemical relations between microorganisms and minerals that may make Nickel's (1995)[6] biogenic mineral exclusion obsolete and Skinner's (2005) biogenic mineral inclusion a necessity.[12] For example, the IMA commissioned 'Environmental Mineralogy and Geochemistry Working Group'[13] deals with minerals in the hydrosphere, atmosphere, and biosphere. Mineral forming microorganisms inhabit the areas that this working group deals with. These organisms exist on nearly every rock, soil, and particle surface spanning the globe reaching depths at 1600 metres below the sea floor (possibly further) and 70 kilometres into the stratosphere (possibly entering the mesosphere).[14][15][16] Biologists and geologists have started to research and appreciate the magnitude of mineral geoengineering that these creatures are capable of. Bacteria have contributed to the formation of minerals for billions of years and critically define the biogeochemical cycles on this planet. Microorganisms can precipitate metals from solution contributing to the formation of ore deposits in addition to their ability to catalyze mineral dissolution, to respire, precipitate, and form minerals.[17][18][19]
Prior to the International Mineralogical Association's listing, over 60 biominerals had been discovered, named, and published.[20] These minerals (a sub-set tabulated in Lowenstam (1981)[11]) are considered minerals proper according to the Skinner (2005) definition.[12] These biominerals are not listed in the International Mineral Association official list of mineral names,[21] however, many of these biomineral representatives are distributed amongst the 78 mineral classes listed in the Dana classification scheme.[12] Another rare class of minerals (primarily biological in origin) include the mineral liquid crystals that are crystalline and liquid at the same time. To date over 80,000 liquid crystalline compounds have been identified.[22][23]
Concerning the use of the term “mineral” to name this family of liquid crystals, one can argue that the term inorganic would be more appropriate. However, inorganic liquid crystals have long been used for organometallic liquid crystals. Therefore, in order to avoid any confusion between these fairly chemically different families, and taking into account that a large number of these liquid crystals occur naturally in nature, we think that the use of the old fashioned but adequate “mineral” adjective taken sensus largo is more specific that an alternative such as “purely inorganic”, to name this subclass of the inorganic liquid crystals family.[23]The Skinner (2005) definition[12] of a mineral takes this matter into account by stating that a mineral can be crystalline or amorphous. Liquid mineral crystals are amorphous. Biominerals and liquid mineral crystals, however, are not the primary form of minerals, most are geological in origin,[24] but these groups do help to identify at the margins of what constitutes a mineral proper. The formal Nickel (1995) definition explicitly mentioned crystalline nature as a key to defining a substance as a mineral. A 2011 article defined icosahedrite, an aluminium-iron-copper alloy as mineral; named for its unique natural icosahedral symmetry, it is also a quasicrystal. Unlike a true crystal, quasicrystals are ordered but not periodic.[25][26]
Rocks, ores, and gems
Schist is a metamorphic rock characterized by an abundance of platy minerals. In this example, the rock has prominent sillimanite porphyroblasts as large as 3 cm (1.2 in).
Minerals are not equivalent to rocks. Whereas a mineral is a naturally occurring usually solid substance, stable at room temperature, representable by a chemical formula, usually abiogenic, and has an ordered atomic structure, a rock is either an aggregate of one or more minerals, or not composed of minerals at all.[27] Rocks like limestone or quartzite are composed primarily of one mineral—calcite or aragonite in the case of limestone, and quartz in the latter case.[28][29] Other rocks can be defined by relative abundances of key (essential) minerals; a granite is defined by proportions of quartz, alkali feldspar, and plagioclase feldspar.[30] The other minerals in the rock are termed accessory, and do not greatly affect the bulk composition of the rock. Rocks can also be composed entirely of non-mineral material; coal is a sedimentary rock composed primarily of organically derived carbon.[27][31]
In rocks, some mineral species and groups are much more abundant than others; these are termed the rock-forming minerals. The major examples of these are quartz, the feldspars, the micas, the amphiboles, the pyroxenes, the olivines, and calcite; except the last one, all of the minerals are silicates.[32] Overall, around 150 minerals are considered particularly important, whether in terms of their abundance or aesthetic value in terms of collecting.[33]
Commercially valuable minerals and rocks are referred to as industrial minerals. For example, muscovite, a white mica, can be used for windows (sometimes referred to as isinglass), as a filler, or as an insulator.[34] Ores are minerals that have a high concentration of a certain element, typically a metal. Examples are cinnabar (HgS), an ore of mercury, sphalerite (ZnS), an ore of zinc, or cassiterite (SnO2), an ore of tin. Gems are minerals with an ornamental value, and are distinguished from non-gems by their beauty, durability, and usually, rarity. There are about 20 mineral species that qualify as gem minerals, which constitute about 35 of the most common gemstones. Gem minerals are often present in several varieties, and so one mineral can account for several different gemstones; for example, ruby and sapphire are both corundum, Al2O3.[35]
Nomenclature and classification
In general, a mineral is defined as naturally occurring solid, that is stable at room temperature, representable by a chemical formula, usually abiogenic, and has an ordered atomic structure. However, a mineral can be also narrowed down in terms of a mineral group, series, species, or variety, in order from most broad to least broad. The basic level of definition is that of mineral species, which is distinguished from other species by specific and unique chemical and physical properties. For example, quartz is defined by its formula, SiO2, and a specific crystalline structure that distinguishes it from other minerals with the same chemical formula (termed polymorphs). When there exists a range of composition between two minerals species, a mineral series is defined. For example, the biotite series is represented by variable amounts of the endmembers phlogopite, siderophyllite, annite, and eastonite. In contrast, a mineral group is a grouping of mineral species with some common chemical properties that share a crystal structure. The pyroxene group has a common formula of XY(Si,Al)2O6, where X and Y are both cations, with X typically bigger than Y; the pyroxenes are single-chain silicates that crystallize in either the orthorhombic or monoclinic crystal systems. Finally, a mineral variety is a specific type of mineral species that differs by some physical characteristic, such as colour or crystal habit. An example is amethyst, which is a purple variety of quartz.[36]Two common classifications are used for minerals; both the Dana and Strunz classifications rely on the composition of the mineral, specifically with regards to important chemical groups, and its structure. The Dana System of Mineralogy was first published in 1837 by James Dwight Dana, a leading geologist of his time; it is in its eighth edition (1997 ed.). The Dana classification, assigns a four-part number to a mineral species. First is its class, based on important compositional groups; next, the type gives the ratio of cations to anions in the mineral; finally, the last two numbers group minerals by structural similarity with a given type or class. The less commonly used Strunz classification, named for German mineralogist Karl Hugo Strunz, is based on the Dana system, but combines both chemical and structural criteria, the latter with regards to distribution of chemical bonds.[37]
There are over 4,660 approved mineral species.[38] They are most commonly named after a person (45%), followed by discovery location (23%); names based on chemical composition (14%) and physical properties (8%) are the two other major groups of mineral name etymologies.[36][39] The common suffix -ite of mineral names descends from the ancient Greek suffix - ί τ η ς (-ites), meaning "connected with or belonging to".[40]
Mineral chemistry
Hübnerite, the manganese-rich end-member of the wolframite series, with minor quartz in the background
The abundance and diversity of minerals is controlled directly by their chemistry, in turn dependent on elemental abundances in the Earth. The majority of minerals observed are derived from the Earth's crust. Eight elements account for most of the key components of minerals, due to their abundance in the crust. These eight elements, summing to over 98% of the crust by weight, are, in order of decreasing abundance: oxygen, silicon, aluminium, iron, magnesium, calcium, sodium and potassium. Oxygen and silicon are by far the two most important — oxygen composes 46.6% of the crust by weight, and silicon accounts for 27.7%.[41]
The minerals that form are directly controlled by the bulk chemistry of the parent body. For example, a magma rich in iron and magnesium will form mafic minerals, such as olivine and the pyroxenes; in contrast, a more silica-rich magma will crystallize to form minerals than incorporate more SiO2, such as the feldspars and quartz. In a limestone, calcite or aragonite (both CaCO3) form because the rock is rich in calcium and carbonate. A corollary is that a mineral will not be found in a rock whose bulk chemistry does not resemble the bulk chemistry of a given mineral with the exception of trace minerals. For example, kyanite, Al2SiO5 forms from the metamorphism of aluminium-rich shales; it would not likely occur in aluminium-poor rock, such quartzite.
The chemical composition may vary between end member species of a mineral series. For example, the plagioclase feldspars comprise a continuous series from sodium-rich end member albite (NaAlSi3O8) to calcium-rich anorthite (CaAl2Si2O8) with four recognized intermediate varieties between them (given in order from sodium- to calcium-rich): oligoclase, andesine, labradorite, and bytownite.[42] Other examples of series include the olivine series of magnesium-rich forsterite and iron-rich fayalite, and the wolframite series of manganese-rich hübnerite and iron-rich ferberite.
Chemical substitution and coordination polyhedra explain this common feature of minerals. In nature, minerals are not pure substances, and are contaminated by whatever other elements are present in the given chemical system. As a result, it is possible for one element to be substituted for another.[43] Chemical substitution will occur between ions of a similar size and charge; for example, K+ will not substitute for Si4+ because of chemical and structural incompatibilities caused by a big difference in size and charge. A common example of chemical substitution is that of Si4+ by Al3+, which are close in charge, size, and abundance in the crust. In the example of plagioclase, there are three cases of substitution. Feldspars are all framework silicates, which have a silicon-oxygen ratio of 2:1, and the space for other elements is given by the substitution of Si4+ by Al3+ to give a base unit of [AlSi3O8]−; without the substitution, the formula would be charge-balanced as SiO2, giving quartz.[44] The significance of this structural property will be explained further by coordination polyhedra. The second substitution occurs between Na+ and Ca2+; however, the difference in charge has to accounted for by making a second substitution of Si4+ by Al3+.[45]
Coordination polyhedra are geometric representation of how a cation is surrounded by an anion. In mineralogy, due its abundance in the crust, coordination polyhedra are usually considered in terms of oxygen. The base unit of silicate minerals is the silica tetrahedron — one Si4+ surrounded by four O2−. An alternate way of describing the coordination of the silicate is by a number: in the case of the silica tetrahedron, the silicon is said to have a coordination number of 4. Various cations have a specific range of possible coordination numbers; for silicon, it is almost always 4, except for very high-pressure minerals where compound is compressed such that silicon is in six-fold (octahedral) coordination by oxygen. Bigger cations have a bigger coordination number because of the increase in relative size as compared to oxygen (the last orbital subshell of heavier atoms is different too). Changes in coordination numbers between leads to physical and mineralogical differences; for example, at high pressure such as in the mantle, many minerals, especially silicates such as olivine and garnet will change to a perovskite structure, where silicon is in octahedral coordination. Another example are the aluminosilicates kyanite, andalusite, and sillimanite (polymorphs, as they share the formula Al2SiO5), which differ by the coordination number of the Al3+; these minerals transition from one another as a response to changes in pressure and temperature.[41] In the case of silicate materials, the substitution of Si4+ by Al3+ allows for a variety of minerals because of the need to balance charges.[46]
When minerals react, the products will sometimes assume the shape of the reagent; the product mineral is termed to be a pseudomorph of (or after) the reagent. Illustrated here is a pseudomorph of kaolinite after orthoclase. Here, the pseudomorph preserved the Carlsbad twinning common in orthoclase.
Changes in temperature and pressure, and composition alter the mineralogy of a rock sample. Changes in composition can be caused by processes such as weathering or metasomatism (hydrothermal alteration). Changes in temperature and pressure occur when the host rock undergoes tectonic or magmatic movement into differing physical regimes. Changes in thermodynamic conditions make it favourable for mineral assemblages to react with each other to produce new minerals; as such, it is possible for two rocks to have an identical or a very similar bulk rock chemistry without having a similar mineralogy. This process of mineralogical alteration is related to the rock cycle. An example of a series of mineral reactions is illustrated as follows.[47]
Orthoclase feldspar (KAlSi3O8) is a mineral commonly found in granite, a plutonic igneous rock. When exposed to weathering, it reacts to form kaolinite (Al2Si2O5(OH)4, a sedimentary mineral, and silicic acid):
- 2 KAlSi3O8 + 5 H2O + 2 H+ → Al2Si2O5(OH)4 + 4 H2SiO3 + 2 K+
- Al2Si2O5(OH)4 + SiO2 → Al2Si4O10(OH)2 + H2O
- Al2Si4O10(OH)2 → Al2SiO5 + 3 SiO2 + H2O
Physical properties of minerals
Classifying minerals ranges from simple to difficult. A mineral can be identified by several physical properties, some of them being sufficient for full identification without equivocation. In other cases, minerals can only be classified by more complex optical, chemical or X-ray diffraction analysis; these methods, however, can be costly and time-consuming. Physical properties applied for classification include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, cleavage and fracture, and specific gravity. Other less general tests include fluorescence, phosphorescence, magnetism, radioactivity, tenacity (response to mechanical induced changes of shape or form), piezoelectricity and reactivity to dilute acids.[49]Crystal structure and habit
Topaz has a characteristic orthorhombic elongated crystal shape.
Crystal structure results from the orderly geometric spatial arrangement of atoms in the internal structure of a mineral. This crystal structure is based on regular internal atomic or ionic arrangement that is often expressed in the geometric form that the crystal takes. Even when the mineral grains are too small to see or are irregularly shaped, the underlying crystal structure is always periodic and can be determined by X-ray diffraction.[1] Minerals are typically described by their symmetry content. Crystals are restricted to 32 point groups, which differ by their symmetry. These groups are classified in turn into more broad categories, the most encompassing of these being the six crystal families.[50]
These families can be described by the relative lengths of the three crystallographic axes, and the angles between them; these relationships correspond to the symmetry operations that define the narrower point groups. They are summarized below; a, b, and c represent the axes, and α, β, γ represent the angle opposite the respective crystallographic axis (e.g. α is the angle opposite the a-axis, viz. the angle between the b and c axes):[50]
| Crystal family | Lengths | Angles | Common examples |
|---|---|---|---|
| Isometric | a=b=c | α=β=γ=90° | Garnet, halite, pyrite |
| Tetragonal | a=b≠c | α=β=γ=90° | Rutile, zircon, andalusite |
| Orthorhombic | a≠b≠c | α=β=γ=90° | Olivine, aragonite, orthopyroxenes |
| Hexagonal | a=b≠c | α=β=90°, γ=120° | Quartz, calcite, tourmaline |
| Monoclinic | a≠b≠c | α=γ=90°, β≠90° | Clinopyroxenes, orthoclase, gypsum |
| Triclinic | a≠b≠c | α≠β≠γ≠90° | Anorthite, albite, kyanite |
The hexagonal crystal family is also split into two crystal systems — the trigonal, which has a three-fold axis of symmetry, and the hexagonal, which has a six-fold axis of symmetry.
Chemistry and crystal structure together define a mineral. With a restriction to 32 point groups, minerals of different chemistry may have identical crystal structure. For example, halite (NaCl), galena (PbS), and periclase (MgO) all belong to the hexaoctahedral point group (isometric family), as they have a similar stoichiometry between their different constituent elements. In contrast, polymorphs are groupings of minerals that share a chemical formula but have a different structure. For example, pyrite and marcasite, both iron sulfides, have the formula FeS2; however, the former is isometric while the latter is orthorhombic. This polymorphism extends to other sulfides with the generic AX2 formula; these two groups are collectively known as the pyrite and marcasite groups.[51]
Polymorphism can extend beyond pure symmetry content. The aluminosilicates are a group of three minerals — kyanite, andalusite, and sillimanite — which share the chemical formula Al2SiO5. Kyanite is triclinic, while andalusite and sillimanite are both orthorhombic and belong to the dipyramidal point group. These difference arise correspond to how aluminium is coordinated within the crystal structure. In all minerals, one aluminium ion is always in six-fold coordination by oxygen; the silicon, as a general rule is in four-fold coordination in all minerals; an exception is a case like stishovite (SiO2, an ultra-high pressure quartz polymorph with rutile structure).[52] In kyanite, the second aluminium is in six-fold coordination; its chemical formula can be expressed as Al[6]Al[6]SiO5, to reflect its crystal structure. Andalusite has the second aluminium in five-fold coordination (Al[6]Al[5]SiO5) and sillimanite has it in four-fold coordination (Al[6]Al[4]SiO5).[53]
Differences in crystal structure and chemistry greatly influence other physical properties of the mineral. The carbon allotropes diamond and graphite have vastly different properties; diamond is the hardest natural substance, has an adamantine lustre, and belongs to the isometric crystal family, whereas as graphite is very soft, has a greasy lustre, and crystallises in the hexagonal family. This difference is accounted by differences in bonding. In diamond, the carbons are in sp3 hybrid orbitals, which means they form a framework where each carbon is covalently bonded to three neighbours in a tetrahedral fashion; on the other hand, graphite is composed of sheets of carbons in sp2 hybrid orbitals, where each carbon is bonded covalently to only two others. These sheets are held together by much weaker van der Waals forces, and this discrepancy translates to big macroscopic differences.[54]
Twinning is the intergrowth of two or more crystal of a single mineral species. The geometry of the twinning is controlled by the mineral's symmetry. As a result, there are several types of twins, including contact twins, reticulated twins, geniculated twins, penetration twins, cyclic twins, and polysynthetic twins. Contact, or simple twins, consist of two crystals joined at a plane; this type of twinning is common in spinel. Reticulated twins, common in rutile, are interlocking crystals resembling netting. Geniculated twins have a bend in the middle that is caused by start of the twin. Penetration twins consist of two single crystals that have grown into each other; examples of this twinning include cross-shaped staurolite twins and Carlsbad twinning in orthoclase. Cyclic twins are caused by repeated twinning around a rotation axis. It occurs around three, four, five, six, or eight-fold axes, and the corresponding patterns are called threelings, fourlings, fivelings, sixlings, and eightlings. Sixlings are common in aragonite. Polysynthetic twins are similar to cyclic twinning by the presence of repetitive twinning; however, instead of occurring around a rotational axis, it occurs along parallel planes, usually on a microscopic scale.[55][56]
Crystal habit refers to the overall shape of crystal. Several terms are used to describe this property. Common habits include acicular, which described needlelike crystals like in natrolite, bladed, dendritic (tree-pattern, common in native copper), equant, which is typical of garnet, prismatic (elongated in one direction), and tabular, which differs from bladed habit in that the former is platy whereas the latter has a defined elongation. Related to crystal form, the quality of crystal faces is diagnostic of some minerals, especially with a petrographic microscope. Euhedral crystals have a defined external shape, while anhedral crystals do not; those intermediate forms are termed subhedral.[57][58]
Hardness
Main article: Mohs scale of mineral hardness
The hardness of a mineral defines how much it can resist scratching. This physical property is controlled by the chemical composition and crystalline structure of a mineral. A mineral's hardness is not necessarily constant for all sides, which is a function of its structure; crystallographic weakness renders some directions softer than others.[59] An example of this property exists in kyanite, which has a Mohs hardness of 5½ parallel to [001] but 7 parallel to [100].[60]
The most common scale of measurement is the ordinal Mohs hardness scale. Defined by ten indicators, a mineral with a higher index scratches those below it. The scale ranges from talc, a phyllosilicate, to diamond, a carbon polymorph that is the hardest natural material. The scale is provided below:[59]
| Mohs hardness | Mineral | Chemical formula |
|---|---|---|
| 1 | Talc | Mg3Si4O10(OH)2 |
| 2 | Gypsum | CaSO4·2H2O |
| 3 | Calcite | CaCO3 |
| 4 | Fluorite | CaF2 |
| 5 | Apatite | Ca5(PO4)3(OH,Cl,F) |
| 6 | Orthoclase | KAlSi3O8 |
| 7 | Quartz | SiO2 |
| 8 | Topaz | Al2SiO4(OH,F)2 |
| 9 | Corundum | Al2O3 |
| 10 | Diamond | C |
Lustre and diaphaneity
Pyrite has a metallic lustre.
Lustre indicates how light reflects from the mineral's surface, with regards to its quality and intensity. There are numerous qualitative terms used to describe this property, which are split into metallic and non-metallic categories. Metallic and sub-metallic minerals have high reflectivity like metal; examples of minerals with this lustre are galena and pyrite. Non-metallic lustres include: adamantine, such as in diamond; vitreous, which is a glassy lustre very common in silicate minerals; pearly, such as in talc and apophyllite, resinous, such as members of the garnet group, silky which common in fibrous minerals such as asbestiform chrysotile.[61]
The diaphaneity of a mineral describes the ability of light to pass through it. Transparent minerals do not diminish the intensity of light passing through it. An example of such a mineral is muscovite (potassium mica); some varieties are sufficiently clear to have been used for windows. Translucent minerals allow some light to pass, but less than those that are transparent. Jadeite and nephrite (mineral forms of jade are examples of minerals with this property). Minerals that do not allow light to pass are called opaque.[62][63]
The diaphaneity of a mineral depends on thickness of the sample. When a mineral is sufficiently thin (e.g., in a thin section for petrography), it may become transparent even if that property is not seen in hand sample. In contrast, some minerals, such as hematite or pyrite are opaque even in thin-section.[63]
Colour and streak
Main article: Streak (mineralogy)
Colour is the most obvious property of a mineral, but it is often non-diagnostic.[64] It is caused by electromagnetic radiation interacting with electrons (except in the case of incandescence, which does not apply to minerals).[65] Two broad classes of elements are defined with regards to their contribution to a mineral's colour. Idiochromatic elements are essential to a mineral's composition; their contribution to a mineral's colour is diagnostic.[62][66] Examples of such minerals are malachite (green) and azurite (blue). In contrast, allochromatic elements in minerals are present in trace amounts as impurities. An example of such a mineral would be the ruby and sapphire varieties of the mineral corundum.[66] The colours of pseudochromatic minerals are the result of interference of light waves. Examples include opal, labradorite, ammolite and bornite.
In addition to simple body colour, minerals can have various other distinctive optical properties, such as play of colours, asterism, chatoyancy, iridescence, tarnish, and pleochroism. Several of these properties involve variability
in colour. Play of colour, such as in opal, results in the sample reflecting different colours as it is turned, while pleochroism describes the change in colour as light passes through a mineral in a different orientation. Iridescence is a variety of the play of colours where light scatters off a coating on the surface of crystal, cleavage planes, or off layers having minor gradations in chemistry.[67] In contrast, the play of colours in opal is caused by light refracting from ordered microscopic silica spheres within its physical structure.[68] Chatoyancy ("cat's eye") is the wavy banding of colour that is observed as the sample is rotated; asterism, a variety of chatoyancy, gives the appearance of a star on the mineral grain. The latter property is particularly common in gem-quality corundum.[67][68]
The streak of a mineral refers to the colour of a mineral in powdered form, which may or may not be identical to its body colour.[66] The most common way of testing this property is done with a streak plate, which is made out of porcelain and coloured either white or black. The streak of a mineral is independent of trace elements[62] or any weathering surface.[66] A common example of this property is illustrated with hematite, which is coloured black, silver, or red in hand sample, but has a cherry-red[62] to reddish-brown streak.[66] Streak is more often distinctive for metallic minerals, in contrast to non-metallic minerals whose body colour is created by allochromatic elements.[62]
Streak testing is constrained by the hardness of the mineral, as those harder than 7 powder the streak plate instead.[66]
Cleavage, parting, fracture, and tenacity
Perfect basal cleavage as seen in biotite (black), and good cleavage seen in the matrix (pink orthoclase).
By definition, minerals have a characteristic atomic arrangement. Weakness in this crystalline structure causes planes of weakness, and the breakage of a mineral along such planes is termed cleavage. The quality of cleavage can be described based on how cleanly and easily the mineral breaks; common descriptors, in order of decreasing quality, are "perfect", "good", "distinct", and "poor". In particularly transparent mineral, or in thin-section, cleavage can be seen a series of parallel lines marking the planar surfaces when viewed at a side. Cleavage is not a universal property among minerals; for example, quartz, consisting of extensively interconnected silica tetrahedra, does not have a crystallographic weakness which would allow it to cleave. In contrast, micas, which have perfect basal cleavage, consist of sheets of silica tetrahedra which are very weakly held together.[69][70]
As cleavage is a function of crystallography, there are a variety of cleavage types. Cleavage occurs typically in either one, two, three, four, or six directions. Basal cleavage in one direction is a distinctive property of the micas. Two-directional cleavage is described as prismatic, and occurs in minerals such as the amphiboles and pyroxenes. Minerals such as galena or halite have cubic (or isometric) cleavage in three directions, at 90°; when three directions of cleavage are present, but not at 90°, such as in calcite or rhodochrosite, it is termed rhombohedral cleavage. Octahedral cleavage (four directions) is present in fluorite and diamond, and sphalerite has six-directional dodecahedral cleavage.[69][70]
Minerals with many cleavages might not break equally well in all of the directions; for example, calcite has good cleavage in three direction, but gypsum has perfect cleavage in one direction, and poor cleavage in two other directions. Angles between cleavage planes vary between minerals. For example, as the amphiboles are double-chain silicates and the pyroxenes are single-chain silicates, the angle between their cleavage planes is different. The pyroxenes cleave in two directions at approximately 90°, whereas the amphiboles distinctively cleave in two directions separated by approximately 120° and 60°. The cleavage angles can be measured with a contact goniometer, which is similar to a protractor.[69][70]
Parting, sometimes called "false cleavage", is similar in appearance to cleavage but is instead produced by structural defects in the mineral as opposed to systematic weakness. Parting varies from crystal to crystal of a mineral, whereas all crystals of a given mineral will cleave if the atomic structure allows for that property. In general, parting is caused by some stress applied to a crystal. The sources of the stresses include deformation (e.g. an increase in pressure), exsolution, or twinning. Minerals that often display parting include the pyroxenes, hematite, magnetite, and corundum.[69][71]
When a mineral is broken in a direction that does not correspond to a plane of cleavage, it is termed to have been fractured. There are several types of uneven fracture. The classic example is conchoidal fracture, like that of quartz; rounded surfaces are created, which are marked by smooth curved lines. This type of fracture occurs only in very homogeneous minerals. Other types of fracture are fibrous, splintery, and hackly. The latter describes a break along a rough, jagged surface; an example of this property is found in native copper.[72]
Tenacity is related to both cleavage and fracture. Whereas fracture and cleavage describes the surfaces that are created when a mineral is broken, tenacity describes how resistant a mineral is to such breaking. Minerals can be described as brittle, ductile, malleable, sectile, flexible, or elastic.[73]
Specific gravity
Specific gravity numerically describes the density of a mineral. The dimensions of density are mass divided by volume with units: kg/m3 or g/cm3. Specific gravity measures how much water a mineral sample displaces. Defined as the quotient of the mass of the sample and difference between the weight of the sample in air and its corresponding weight in water, specific gravity is a unitless ratio. Among most minerals, this property is not diagnostic. Rock forming minerals — typically silicates or occasionally carbonates — have a specific gravity of 2.5–3.5.[74]
High specific gravity is a diagnostic property of a mineral. A variation in chemistry (and consequently, mineral class) correlates to a change in specific gravity. Among more common minerals, oxides and sulfides tend to have a higher specific gravity as they include elements with higher atomic mass. A generalization is that minerals with metallic or adamantine lustre tend to have higher specific gravities than those having a non-metallic to dull lustre. For example, hematite, Fe2O3, has a specific gravity of 5.26[75] while galena, PbS, has a specific gravity of 7.2–7.6,[76] which is a result of their high iron and lead content, respectively. A very high specific gravity becomes very pronounced in native metals; kamacite, an iron-nickel alloy common in iron meteorites has a specific gravity of 7.9,[77] and gold has an observed specific gravity between 15 and 19.3.[74][78]
Other properties
Other properties can be used to diagnose minerals. These are less general, and apply to specific minerals.
Dropping dilute acid (often 10% HCl) aids in distinguishing carbonates from other mineral classes. The acid reacts with the carbonate ([CO3]2−) group, which causes the affected area to effervesce, giving off carbon dioxide gas. This test can be further expanded to test the mineral in its original crystal form or powdered. An example of this test is done when distinguish calcite from dolomite, especially within rocks (limestone and dolostone respectively). Calcite immediately effervesces in acid, whereas acid must be applied to powdered dolomite (often to a scratched surface in a rock), for it to effervesce.[79] Zeolite minerals will not effervesce in acid; instead, they become frosted after 5–10 minutes, and if left in acid for a day, they dissolve or become a silica gel.[80]
When tested, magnetism is a very conspicuous property of minerals. Among common minerals, magnetite exhibits this property strongly, and it is also present, albeit not as strongly, in pyrrhotite and ilmenite.[79]
Minerals can also be tested for taste or smell. Halite, NaCl, is table salt; its potassium-bearing counterpart, sylvite, has a pronounced bitter taste. Sulfides have a characteristic smell, especially as samples are fractured, reacting, or powdered.[79]
Radioactivity is a rare property; minerals may be composed of radioactive elements. They could be a defining constituent, such as uranium in uraninite, autunite, and carnotite, or as trace impurities. In the latter case, the decay of a radioactive element damages the mineral crystal; the result, termed a radioactive halo or pleochroic halo, is observable by various techniques, such as thin-section petrography.[79]
Mineral classes
As the composition of the Earth's crust is dominated by silicon and oxygen, silicate elements are by far the most important class of minerals in terms of rock formation and diversity. However, non-silicate minerals are of great economic importance, especially as ores.[81][82]Non-silicate minerals are subdivided into several other classes by their dominant chemistry, which included native elements, sulfides, halides, oxides and hydroxides, carbonates and nitrates, borates, sulfates, phosphates, and organic compounds. The majority of non-silicate mineral species are extremely rare (constituting in total 8% of the Earth's crust), although some are relative common, such as calcite, pyrite, magnetite, and hematite. There are two major structural styles observed in non-silicates: close-packing and silicate-like linked tetrahedra. The close-packed structures, which is a way to densely pack atoms while minimizing interstitial space. Hexagonal close-packing involves stacking layers where every other layer is the same ("ababab"), whereas cubic close-packing involves stacking groups of three layers ("abcabcabc"). Analogues to linked silica tetrahedra include SO4 (sulfate), PO4 (phosphate), AsO4 (arsenate), and VO4 (vanadate). The non-silicates have great economic importance, as they concentrate elements more than the silicate minerals do.[83]
The largest grouping of minerals by far are the silicates; most rocks are composed of greater than 95% silicate minerals, and over 90% of the Earth's crust is composed of these minerals.[84] The two main constituents of silicates are silicon and oxygen, which are the two most abundant elements in the Earth's crust. Other common elements in silicate minerals correspond to other common elements in the Earth's crust, such aluminium, magnesium, iron, calcium, sodium, and potassium.[85] Some important rock-forming silicates include the feldspars, quartz, olivines, pyroxenes, amphiboles, garnets, and micas.
Silicates
Main article: Silicate minerals
The base of unit of a silicate mineral is the [SiO4]4− tetrahedron. In the vast majority of cases, silicon is in four-fold or tetrahedral coordination with oxygen. In very high-pressure situations, silicon will be six-fold or octahedral coordination, such as in the perovskite structure or the quartz polymorph stishovite (SiO2). In the latter case, the mineral no longer has a silicate structure, but that of rutile (TiO2), and its associated group, which are simple oxides.
These silica tetrahedra are then polymerized to some degree to create various structures, such as one-dimensional chains, two-dimensional sheets, and three-dimensional frameworks. The basic silicate mineral where no polymerization of the tetrahedra has occurred requires other elements to balance out the base 4- charge. In other silicate structures, different combinations of elements are required to balance out the resultant negative charge. It is common for the Si4+ to be substituted by Al3+ because of similarity in ionic radius and charge; in those case, the [AlO4]5− tetrahedra form the same structures as do the unsubstituted tetrahedra, but their charge-balancing requirements are different.[86]
The degree of polymerization can be described by both the structure formed and how many tetrahedral corners (or coordinating oxygens) are shared (for aluminium and silicon in tetrahedral sites).[87] Orthosilicates (or nesosilicates) have no linking of polyhedra, thus tetrahedra share no corners. Disilicates (or sorosilicates) have two tetrahedra sharing one oxygen atom. Inosilicates are chain silicates; single-chain silicates have two shared corners, whereas double-chain silicates have two or three shared corners. In phyllosilicates, a sheet structure is formed which requires three shared oxygens; in the case of double-chain silicates, some tetrahedra must share two corners instead of three as otherwise a sheet structure would result. Framework silicates, or tectosilicates, have tetrahedra that share all four corners. The ring silicates, or cyclosilicates, only need tetrahedra to share two corners to form the cyclical structure.[88]
The silicate subclasses are described below in order of decreasing polymerization.
Tectosilicates
Main category: Tectosilicates
Natrolite is a mineral series in the zeolite group; this sample has a very prominent acicular crystal habit.
Tectosilicates, also known as framework silicates, have the highest degree of polymerization. With all corners of a tetrahedra shared, the silicon:oxygen ratio becomes 1:2. Examples are quartz, the feldspars, feldspathoids, and the zeolites. Framework silicates tend to be particularly chemically stable as a result of strong covalent bonds.[89]
Forming 12% of the Earth's crust, quartz (SiO2) is the most abundant mineral species. It is characterized by its high chemical and physical resistivity. Quartz has several polymorphs, including tridymite and cristobalite at high temperatures, high-pressure coesite, and ultra-high pressure stishovite. The latter mineral can only be formed on Earth by meteorite impacts, and its structure has been composed so much that it had changed from a silicate structure to that of rutile (TiO2). The silica polymorph that is most stable at the Earth's surface is α-quartz. Its counterpart, β-quartz, is present only at high temperatures and pressures (changes to α-quartz below 573 °C at 1 bar). These two polymorphs differ by a "kinking" of bonds; this change in structure gives β-quartz greater symmetry than α-quartz, and they are thus also called high quartz (β) and low quartz (α).[84][90]
Feldspars are the most abundant group in the Earth's crust, at about 50%. In the feldspars, Al3+ substitutes for Si4+, which creates a charge imbalance that must be accounted for by the addition of cations. The base structure becomes either [AlSi3O8]− or [Al2Si2O8]2− There are 22 mineral species of feldspars, subdivided into two major subgroups—alkali and plagioclase—and two less common groups—celsian and banalsite. The alkali feldspars are most commonly in a series between potassium-rich orthoclase and sodium-rich albite; in the case of plagioclase, the most common series ranges from albite to calcium-rich anorthite. Crystal twinning is common in feldspars, especially polysynthetic twins in plagioclase and Carlsbad twins in alkali feldspars. If the latter subgroup cools slowly from a melt, it forms exsolution lamellae because the two components—orthoclase and albite—are unstable in solid solution. Exsolution can be on a scale from microscopic to readily observable in hand-sample; perthitic texture forms when Na-rich feldspar exsolve in a K-rich host. The opposite texture (antiperthitic), where K-rich feldspar exsolves in a Na-rich host, is very rare.[91]
Feldsapthoids are structurally similar to feldspar, but differ in that they form in Si-deficient conditions which allows for further substitution by Al3+. As a result, feldsapthoids cannot be associated with quartz. A common example of a feldsapthoid is nepheline ((Na, K)AlSiO4); compared to alkali feldspar, nepheline has an Al2O3:SiO2 ratio of 1:2, as opposed to 1:6 in the feldspar.[92] Zeolites often have distinctive crystal habits, occurring in needles, plates, or blocky masses. They form in the presence of water at low temperatures and pressures, and have channels and voids in their structure. Zeolites have several industrial applications, especially in waste water treatment.[93]
Phyllosilicates
Phyllosilicates consist of sheets of polymerized tetrahedra. They are bound at three oxygen sites, which gives a characteristic silicon:oxygen ratio of 2:5. Important examples include the mica, chlorite, and the kaolinite-serpentine groups. The sheets are weakly bound by van der Waals forces or hydrogen bonds, which causes a crystallographic weakness, in turn leading to a prominent basal cleavage among the phyllosilicates.[94] In addition to the tetrahedra, phyllosilicates have a sheet of octahedra (elements in six-fold coordination by oxygen) that balanced out the basic tetrahedra, which have a negative charge (e.g. [Si4O10]4−) These tetrahedra (T) and octahedra (O) sheets are stacked in a variety of combinations to create phyllosilicate groups. Within an octahedral sheet, there are three octahedral sites in a unit structure; however, not all of the sites may be occupied. In that case, the mineral is termed dioctahedral, whereas in other case it is termed trioctahedral.[95]
The kaolinite-serpentine group consists of T-O stacks (the 1:1 clay minerals); their hardness ranges from 2 to 4, as the sheets are held by hydrogen bonds. The 2:1 clay minerals (pyrophyllite-talc) consist of T-O-T stacks, but they are softer (hardness from 1 to 2), as they are instead held together by van der Waals forces. These two groups of minerals are subgrouped by octahedral occupation; specifically, kaolinite and pyrophyllite are dioctahedral whereas serpentine and talc trioctahedral.[96]
Micas are also T-O-T-stacked phyllosilicates, but differ from the other T-O-T and T-O-stacked subclass members in that they incorporate aluminium into the tetrahedral sheets (clay minerals have Al3+ in octahedral sites). Common examples of micas are muscovite, and the biotite series. The chlorite group is related to mica group, but a brucite-like (Mg(OH)2) layer between the T-O-T stacks.[97]
Because of their chemical structure, phyllosilicates typically have flexible, elastic, transparent layers that are electrical insulators and can be split into very thin flakes. Micas can be used in electronics as insulators, in construction, as optical filler, or even cosmetics. Chrysotile, a species of serpentine, is the most common mineral species in industrial asbestos, as it is less dangerous in terms of health than the amphibole asbestos.[98]
Inosilicates
Inosilicates consist of tetrahedra repeatedly bonded in chains. These chains can be single, where a tetrahedron is bound to two others to form a continuous chain; alternatively, two chains can be merged to create double-chain silicates. Single-chain silicates have a silicon:oxygen ratio of 1:3 (e.g. [Si2O6]4−), whereas the double-chain variety has a ratio of 4:11, e.g. [Si8O22]12−. Inosilicates contain two important rock-forming mineral groups; single-chain silicates are most commonly pyroxenes, while double-chain silicates are often amphiboles.[99] Higher-order chains exist (e.g. three-member, four-member, five-member chains, etc.) but they are rare.[100]
The pyroxene group consists of 21 mineral species.[101] Pyroxenes have a general structure formula of XY(Si2O6), where X is an octahedral site, while Y can vary in coordination number from six to eight. Most varieties of pyroxene consist of permutations of Ca2+, Fe2+ and Mg2+ to balance the negative charge on the backbone. Pyroxenes are common in the Earth's crust (about 10%) and are a key constituent of mafic igneous rocks.[102]
Amphiboles have great variability in chemistry, described variously as a "mineralogical garbage can" or a "mineralogical shark swimming a sea of elements". The backbone of the amphiboles is the [Si8O22]12−; it is balanced by cations in three possible positions, although the third position is not always used, and one element can occupy both remaining ones. Finally, the amphiboles are usually hydrated, that is, they have a hydroxyl group ([OH]−), although it can be replaced by a fluoride, a chloride, or an oxide ion.[103] Because of the variable chemistry, there are over 80 species of amphibole, although variations, as in the pyroxenes, most commonly involve mixtures of Ca2+, Fe2+ and Mg2+.[101] Several amphibole mineral species can have an asbestiform crystal habit.
These asbestos minerals form long, thin, flexible, and strong fibres, which are electrical insulators, chemically inert and heat-resistant; as such, they have several applications, especially in construction materials. However, asbestos are known carcinogens, and cause various other illnesses, such as asbestosis; amphibole asbestos (anthophyllite, tremolite, actinolite, grunerite, and riebeckite) are considered more dangerous than chrysotile serpentine asbestos.[104]
Cyclosilicates
Cyclosilicates, or ring silicates, have a ratio of silicon to oxygen of 1:3. Six-member rings are most common, with a base structure of [Si6O18]12−; examples include the tourmaline group and beryl. Other ring structures exist, with 3, 4, 8, 9, 12 having been described.[105] Cyclosilicates tend to be strong, with elongated, striated crystals.[106]
Tourmalines have a very complex chemistry that can be described by a general formula XY3Z6(BO3)3T6O18V3W. The T6O18 is the basic ring structure, where T is usually Si4+, but substitutable by Al3+ or B3+. Tourmalines can be subgrouped by the occupancy of the X site, and from there further subdivided by the chemistry of the W site. The Y and Z sites can accommodate a variety of cations, especially various transition metals; this variability in structural transition metal content gives the tourmaline group greater variability in colour. Other cyclosilicates include beryl, Al2Be3Si6O18, whose varieties include the gemstones emerald (green) and aquamarine (bluish). Cordierite is structurally similar to beryl, and is a common metamorphic mineral.[107]
Sorosilicates
Sorosilicates, also termed disilicates, have tetrahedron-tetrahedron bonding at one oxygen, which results in a 2:7 ratio of silicon to oxygen. The resultant common structural element is the [Si2O7]6− group. The most common disilicates by far are members of the epidote group. Epidotes are found in variety of geologic settings, ranging from mid-ocean ridge to granites to metapelites. Epidotes are built around the structure [(SiO4)(Si2O7)]10− structure; for example, the mineral species epidote has calcium, aluminium, and ferric iron to charge balance: Ca2Al2(Fe3+, Al)(SiO4)(Si2O7)O(OH). The presence of iron as Fe3+ and Fe2+ helps understand oxygen fugacity, which in turn is a significant factor in petrogenesis.[108]
Other examples of sorosilicates include lawsonite, a metamorphic mineral forming in the blueschist facies (subduction zone setting with low temperature and high pressure), vesuvianite, which takes up a significant amount of calcium in its chemical structure.[108][109]
Orthosilicates
Orthosilicates consist of isolated tetrahedra that are charge-balanced by other cations.[110] Also termed nesosilicates, this type of silicate has a silicon:oxygen ratio of 1:4 (e.g. SiO4). Typical orthosilicates tend to form blocky equant crystals, and are fairly hard.[111] Several rock-forming minerals are part of this subclass, such as the aluminosilicates, the olivine group, and the garnet group.
The aluminosilicates—kyanite, andalusite, and sillimanite, all Al2SiO5—are structurally composed of one [SiO4]4− tetrahedron, and one Al3+ in octahedral coordination. The remaining Al3+ can be in six-fold coordination (kyanite), five-fold (andalusite) or four-fold (sillimanite); which mineral forms in a given environment is depend on pressure and temperature conditions. In the olivine structure, the main olivine series of (Mg, Fe)2SiO4 consist of magnesium-rich forsterite and iron-rich fayalite. Both iron and magnesium are in octahedral by oxygen. Other mineral species having this structure exist, such as tephroite, Mn2SiO4.[112] The garnet group has a general formula of X3Y2(SiO4)3, where X is a large eight-fold coordinated cation, and Y is a smaller six-fold coordinated cation.
There are six ideal endmembers of garnet, split into two group. The pyralspite garnets have Al3+ in the Y position: pyrope (Mg3Al2(SiO4)3), almandine (Fe3Al2(SiO4)3), and spessartine (Mn3Al2(SiO4)3). The ugrandite garnets have Ca2+ in the X position: uvarovite (Ca3Cr2(SiO4)3), grossular (Ca3Al2(SiO4)3) and andradite (Ca3Fe2(SiO4)3). While there are two subgroups of garnet, solid solutions exist between all six end-members.[110]
Other orthosilicates include zircon, staurolite, and topaz. Zircon (ZrSiO4) is useful in geochronology as the Zr4+ can be substituted by U6+; furthermore, because of its very resistant structure, it is difficult to reset it as a chronometer. Staurolite is a common metamorphic intermediate-grade index mineral. It has a particularly complicated crystal structure that was only fully described in 1986. Topaz (Al2SiO4(F, OH)2, often found in granitic pegmatites associated with tourmaline, is a common gemstone mineral.[113]
Non-silicates
Native elements
Native elements are those that are not chemically bonded to other elements. This mineral group includes native metals, semi-metals, and non-metals, and various alloys and solid solutions. The metals are held together by metallic bonding, which confers distinctive physical properties such as their shiny metallic lustre, ductility and malleability, and electrical conductivity. Native elements are subdivided into groups by their structure or chemical attributes.
The gold group, with a cubic close-packed structure, includes metals such as gold, silver, and copper. The platinum group is similar in structure to the gold group. The iron-nickel group is characterized by several iron-nickel alloy species. Two examples are kamacite and taenite, which are found in iron meteorites; these species differ by the amount of Ni in the alloy; kamacite has less than 5–7% nickel and is a variety of native iron, whereas the nickel content of taenite ranges from 7–37%. Arsenic group minerals consist of semi-metals, which have only some metallic; for example, they lack the malleability of metals. Native carbon occurs in two allotropes, graphite and diamond; the latter forms at very high pressure in the mantle, which gives it a much stronger structure than graphite.[114]
Sulfides
The sulfide minerals are chemical compounds of one or more metals or semimetals with a sulfur; tellurium, arsenic, or selenium can substitute for the sulfur. Sulfides tend to be soft, brittle minerals with a high specific gravity. Many powdered sulfides, such as pyrite, have a sulfurous smell when powdered. Sulfides are susceptible to weathering, and many readily dissolve in water; these dissolved minerals can be later redeposited, which creates enriched secondary ore deposits.[115] Sulfides are classified by the ratio of the metal or semimetal to the sulfur, such as M:S equal to 2:1, or 1:1.[116] Many sulfide minerals are economically important as metal ores; examples include sphalerite (ZnS), an ore of zinc, galena (PbS), an ore of lead, cinnabar (HgS), an ore of mercury, and molybdenite (MoS2, an ore of molybdenum.[117] Pyrite (FeS2), is the most commonly occurring sulfide, and can be found in most geological environments. It is not, however, an ore of iron, but can be instead oxidized to produce sulfuric acid.[118] Related to the sulfides are the rare sulfosalts, in which a metallic element is bonded to sulfur and a semimetal such as antimony, arsenic, or bismuth. Like the sulfides, sulfosalts are typically soft, heavy, and brittle minerals.[119]
Oxides
Oxide minerals are divided into three categories: simple oxides, hydroxides, and multiple oxides. Simple oxides are characterized by O2− as the main anion and primarily ionic bonding. They can be further subdivided by the ratio of oxygen to the cations. The periclase group consists of minerals with a 1:1 ratio. Oxides with a 2:1 ratio include cuprite (Cu2O) and water ice. Corundum group minerals have a 2:3 ratio, and includes minerals such as corundum (Al2O3), and hematite (Fe2O3). Rutile group minerals have a ratio of 1:2; the eponymous species, rutile (TiO2) is the chief ore of titanium; other examples include cassiterite (SnO2; ore of tin), and pyrolusite (MnO2; ore of manganese).[120][121] In hydroxides, the dominant anion is the hydroxyl ion, OH−. Bauxites are the chief aluminium ore, and are a heterogeneous mixture of the hydroxide minerals diaspore, gibbsite, and bohmite; they form in areas with a very high rate of chemical weathering (mainly tropical conditions).[122] Finally, multiple oxides are compounds of two metals with oxygen. A major group within this class are the spinels, with a general formula of X2+Y3+2O4. Examples of species include spinel (MgAl2O4), chromite (FeCr2O4), and magnetite (Fe3O4). The latter is readily distinguishable by its strong magnetism, which occurs as it has iron in two oxidation states (Fe2+Fe3+2O4), which makes it a multiple oxide instead of a single oxide.[123]Halides
Pink cubic halite (NaCl; halide class) crystals on a nahcolite matrix (NaHCO3; a carbonate, and mineral form of sodium bicarbonate, used as baking soda).
The halide minerals are compounds where a halogen (fluorine, chlorine, iodine, and bromine) is the main anion. These minerals tend to be soft, weak, brittle, and water-soluble. Common examples of halides include halite (NaCl, table salt), sylvite (KCl), fluorite (CaF2). Halite and sylvite commonly form as evaporites, and can be dominant minerals in chemical sedimentary rocks. Cryolite, Na3AlF6, is a key mineral in the extraction of aluminium from bauxites; however, as the only significant occurrence at Ivittuut, Greenland, in a granitic pegmatite, was depleted, synthetic cryolite can be made from fluorite.[124]
Carbonates
The carbonate minerals are those were the main anionic group is carbonate, [CO3]2−. Carbonates tend to be brittle, many have rhombohedral cleavage, and all react with acid.[125] Due to the last characteristic, field geologists often carry dilute hydrochloric acid to distinguish carbonates from non-carbonates. The reaction of acid with carbonates, most commonly found as the polymorph calcite and aragonite (CaCO3), relates to the dissolution and precipitation of the mineral, which is a key in the formation of limestone caves, features within them such as stalactite and stalagmites, and karst landforms. Carbonates are most often formed as biogenic or chemical sediments in marine environments. The carbonate group is structurally a triangle, where a central C4+ cation is surrounded by three O2− anions; different groups of minerals form from different arrangements of these triangles.[126] The most common carbonate mineral is calcite, and is the primary constituent of sedimentary limestone and metamorphic marble. Calcite, CaCO3, can have a high magnesium impurity; under high-Mg conditions, its polymorph aragonite will form instead; the marine geochemistry in this regard can be described as an aragonite or calcite sea, depending on which mineral preferentially forms. Dolomite is a double carbonate, with the formula CaMg(CO3)2. Secondary dolomitization of limestone is common, where calcite or aragonite are converted to dolomite; this reaction increases pore space (the unit cell volume of dolomite is 88% that of calcite), which can create a reservoir for oil and gas. These two minerals species are members of eponymous mineral groups: the calcite group includes carbonates with the general formula XCO3, and the dolomite group constitutes minerals with general formula XY(CO3)2.[127]Sulfates
The sulfate minerals all contain the sulfate anion, [SO4]2−. They tend to be transparent to translucent, soft, and many are fragile.[128] Sulfate minerals commonly form as evaporites, where they precipitate out of evaporating saline waters; alternative, sulfates can also be found in hydrothermal vein systems associated with sulfides,[129] or as oxidation products of sulfides.[130] Sulfates can be subdivded into anhydrous and hydrous minerals. The most common hydrous sulfate by far is gypsum, CaSO4⋅2H2O. It forms as an evaporite, and is associated with other evaporites such as calcite and halite; if it incorporates sand grains as it crystallizes, gypsum can form desert roses. Gypsum has very low thermal conductivity and maintains a low temperature when heated as it loses that heat by dehydrating; as such, gypsum is used as an insulator in materials such as plaster and drywall. The anhydrous equivalent of gypsum is anhydrite; it can form directly from seawater in highly arid conditions. The barite group has the general formula XSO4, where the X is a large 12-coordinated cation. Examples include barite (BaSO4), celestine (SrSO4), and anglesite (PbSO4); anhydrite is not part of the barite group, as the smaller Ca2+ is only in eight-fold coordination.[131]
Phosphates
The phosphate minerals are characterized by the tetrahedral [PO4]3− unit, although the structure can be generalized, and phosphorus is replaced by antimony, arsenic, or vanadium. The most common phosphate is the apatite group; common species within this group are fluorapatite (Ca5(PO4)3F), chlorapatite (Ca5(PO4)3Cl) and hydroxylapatite (Ca5(PO4)3(OH)). Minerals in this group are the main crystalline constituents of teeth and bones in vertebrates. The relatively abundant monazite group has a general structure of ATO4, where T is phosphorus or arsenic, and A is often a rare-earth element (REE). Monazite is important in two ways: first, as a REE "sink", it can sufficiently concentrate these elements to become an ore; secondly, monazite group elements can incorporate relatively large amounts of uranium and thorium, which can be used to date the rock based on the decay of the U and Th to lead.[132]Organic minerals
The Strunz classification includes a class for organic minerals. These rare compounds contain organic carbon, but can be formed by a geologic process. For example, whewellite, CaC2O4⋅H2O is an oxalate that can be deposited in hydrothermal ore veins. While hydrated calcium oxalate can be found in coal seams and other sedimentary deposits involving organic matter, the hydrothermal occurrence is not considered to be related to biological activity.[82]Astrobiology
It has been suggested that biominerals could be important indicators of extraterrestrial life and thus could play an important role in the search for past or present life on the planet Mars. Furthermore, organic components (biosignatures) that are often associated with biominerals are believed to play crucial roles in both pre-biotic and biotic reactions.[133]On January 24, 2014, NASA reported that current studies by the Curiosity and Opportunity rovers on Mars will now be searching for evidence of ancient life, including a biosphere based on autotrophic, chemotrophic and/or chemolithoautotrophic microorganisms, as well as ancient water, including fluvio-lacustrine environments (plains related to ancient rivers or lakes) that may have been habitable.[134][135][136][137] The search for evidence of habitability, taphonomy (related to fossils), and organic carbon on the planet Mars is now a primary NASA objective.[134][135]
