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Wednesday, November 16, 2022

Optical amplifier

From Wikipedia, the free encyclopedia

Optical amplifiers are used to create laser guide stars which provide feedback to the adaptive optics control systems which dynamically adjust the shape of the mirrors in the largest astronomical telescopes.

An optical amplifier is a device that amplifies an optical signal directly, without the need to first convert it to an electrical signal. An optical amplifier may be thought of as a laser without an optical cavity, or one in which feedback from the cavity is suppressed. Optical amplifiers are important in optical communication and laser physics. They are used as optical repeaters in the long distance fiberoptic cables which carry much of the world's telecommunication links.

There are several different physical mechanisms that can be used to amplify a light signal, which correspond to the major types of optical amplifiers. In doped fiber amplifiers and bulk lasers, stimulated emission in the amplifier's gain medium causes amplification of incoming light. In semiconductor optical amplifiers (SOAs), electron-hole recombination occurs. In Raman amplifiers, Raman scattering of incoming light with phonons in the lattice of the gain medium produces photons coherent with the incoming photons. Parametric amplifiers use parametric amplification.

History

The principle of optical amplification was invented by Gordon Gould on November 13, 1957. He filed patent No. 804,539 on April 6, 1959 titled "Light Amplifiers Employing Collisions to Produce Population Inversions" (subsequently amended as a continuation in part and finally issued as No. 4,746,201A on May 4, 1988). The patent covered “the amplification of light by the stimulated emission of photons from ions, atoms or molecules in gaseous, liquid or solid state.” In total, Gould obtained 48 patents related to the optical amplifier that covered 80% of the lasers on the market at the time of issuance.

Gould co-founded an optical telecommunications equipment firm, Optelecom Inc., that helped start Ciena Corp with his former head of Light Optics Research, David Huber and Kevin Kimberlin. Huber and Steve Alexander of Ciena invented the dual-stage optical amplifier (US Patent 5,159,601) that was a key to the first dense wave division multiplexing (DWDM) system, that they released in June 1996. This marked the start of optical networking. Its significance was recognized at the time by optical authority, Shoichi Sudo and technology analyst, George Gilder in 1997, when Sudo wrote that optical amplifiers “will usher in a worldwide revolution called the Information Age” and Gilder compared the optical amplifier to the integrated circuit in importance, predicting that it would make possible the Age of Information. Today optical amplification WDM systems are the common basis of all local, metro, national, intercontinental and subsea telecommunications networks and the technology of choice for the fiber optic backbones of the Internet (e.g. fiber-optic cables form a basis of modern day computer networking).

Laser amplifiers

Almost any laser active gain medium can be pumped to produce gain for light at the wavelength of a laser made with the same material as its gain medium. Such amplifiers are commonly used to produce high power laser systems. Special types such as regenerative amplifiers and chirped-pulse amplifiers are used to amplify ultrashort pulses.

Solid-state amplifiers

Solid-state amplifiers are optical amplifiers that uses a wide range of doped solid-state materials (Nd: Yb:YAG, Ti:Sa) and different geometries (disk, slab, rod) to amplify optical signals. The variety of materials allows the amplification of different wavelength while the shape of the medium can distinguish between more suitable for energy of average power scaling. Beside their use in fundamental research from gravitational wave detection to high energy physics at the National Ignition Facility they can also be found in many of today’s ultra short pulsed lasers.

Doped fiber amplifiers

Schematic diagram of a simple Doped Fiber Amplifier

Doped fiber amplifiers (DFAs) are optical amplifiers that use a doped optical fiber as a gain medium to amplify an optical signal. They are related to fiber lasers. The signal to be amplified and a pump laser are multiplexed into the doped fiber, and the signal is amplified through interaction with the doping ions.

Amplification is achieved by stimulated emission of photons from dopant ions in the doped fiber. The pump laser excites ions into a higher energy from where they can decay via stimulated emission of a photon at the signal wavelength back to a lower energy level. The excited ions can also decay spontaneously (spontaneous emission) or even through nonradiative processes involving interactions with phonons of the glass matrix. These last two decay mechanisms compete with stimulated emission reducing the efficiency of light amplification.

The amplification window of an optical amplifier is the range of optical wavelengths for which the amplifier yields a usable gain. The amplification window is determined by the spectroscopic properties of the dopant ions, the glass structure of the optical fiber, and the wavelength and power of the pump laser.

Although the electronic transitions of an isolated ion are very well defined, broadening of the energy levels occurs when the ions are incorporated into the glass of the optical fiber and thus the amplification window is also broadened. This broadening is both homogeneous (all ions exhibit the same broadened spectrum) and inhomogeneous (different ions in different glass locations exhibit different spectra). Homogeneous broadening arises from the interactions with phonons of the glass, while inhomogeneous broadening is caused by differences in the glass sites where different ions are hosted. Different sites expose ions to different local electric fields, which shifts the energy levels via the Stark effect. In addition, the Stark effect also removes the degeneracy of energy states having the same total angular momentum (specified by the quantum number J). Thus, for example, the trivalent erbium ion (Er3+) has a ground state with J = 15/2, and in the presence of an electric field splits into J + 1/2 = 8 sublevels with slightly different energies. The first excited state has J = 13/2 and therefore a Stark manifold with 7 sublevels. Transitions from the J = 13/2 excited state to the J= 15/2 ground state are responsible for the gain at 1500 nm wavelength. The gain spectrum of the EDFA has several peaks that are smeared by the above broadening mechanisms. The net result is a very broad spectrum (30 nm in silica, typically). The broad gain-bandwidth of fiber amplifiers make them particularly useful in wavelength-division multiplexed communications systems as a single amplifier can be utilized to amplify all signals being carried on a fiber and whose wavelengths fall within the gain window.

An erbium-doped waveguide amplifier (EDWA) is an optical amplifier that uses a waveguide to boost an optical signal.

Basic principle of EDFA

A relatively high-powered beam of light is mixed with the input signal using a wavelength selective coupler (WSC). The input signal and the excitation light must be at significantly different wavelengths. The mixed light is guided into a section of fiber with erbium ions included in the core. This high-powered light beam excites the erbium ions to their higher-energy state. When the photons belonging to the signal at a different wavelength from the pump light meet the excited erbium ions, the erbium ions give up some of their energy to the signal and return to their lower-energy state.

A significant point is that the erbium gives up its energy in the form of additional photons which are exactly in the same phase and direction as the signal being amplified. So the signal is amplified along its direction of travel only. This is not unusual – when an atom "lases" it always gives up its energy in the same direction and phase as the incoming light. Thus all of the additional signal power is guided in the same fiber mode as the incoming signal. An optical isolator is usually placed at the output to prevent reflections returning from the attached fiber. Such reflections disrupt amplifier operation and in the extreme case can cause the amplifier to become a laser.

The erbium doped amplifier is a high gain amplifier.

Noise

The principal source of noise in DFAs is Amplified Spontaneous Emission (ASE), which has a spectrum approximately the same as the gain spectrum of the amplifier. Noise figure in an ideal DFA is 3 dB, while practical amplifiers can have noise figure as large as 6–8 dB.

As well as decaying via stimulated emission, electrons in the upper energy level can also decay by spontaneous emission, which occurs at random, depending upon the glass structure and inversion level. Photons are emitted spontaneously in all directions, but a proportion of those will be emitted in a direction that falls within the numerical aperture of the fiber and are thus captured and guided by the fiber. Those photons captured may then interact with other dopant ions, and are thus amplified by stimulated emission. The initial spontaneous emission is therefore amplified in the same manner as the signals, hence the term Amplified Spontaneous Emission. ASE is emitted by the amplifier in both the forward and reverse directions, but only the forward ASE is a direct concern to system performance since that noise will co-propagate with the signal to the receiver where it degrades system performance. Counter-propagating ASE can, however, lead to degradation of the amplifier's performance since the ASE can deplete the inversion level and thereby reduce the gain of the amplifier and increase the noise produced relative to the desired signal gain.

Noise figure can be analyzed in both the optical domain and in the electrical domain. In the optical domain, measurement of the ASE, the optical signal gain, and signal wavelength using an optical spectrum analyzer permits calculation of the noise figure. For the electrical measurement method, the detected photocurrent noise is evaluated with a low-noise electrical spectrum analyzer, which along with measurement of the amplifier gain permits a noise figure measurement. Generally, the optical technique provides a more simple method, though it is not inclusive of excess noise effects captured by the electrical method such multi-path interference (MPI) noise generation. In both methods, attention to effects such as the spontaneous emission accompanying the input signal are critical to accurate measurement of noise figure.

Gain saturation

Gain is achieved in a DFA due to population inversion of the dopant ions. The inversion level of a DFA is set, primarily, by the power of the pump wavelength and the power at the amplified wavelengths. As the signal power increases, or the pump power decreases, the inversion level will reduce and thereby the gain of the amplifier will be reduced. This effect is known as gain saturation – as the signal level increases, the amplifier saturates and cannot produce any more output power, and therefore the gain reduces. Saturation is also commonly known as gain compression.

To achieve optimum noise performance DFAs are operated under a significant amount of gain compression (10 dB typically), since that reduces the rate of spontaneous emission, thereby reducing ASE. Another advantage of operating the DFA in the gain saturation region is that small fluctuations in the input signal power are reduced in the output amplified signal: smaller input signal powers experience larger (less saturated) gain, while larger input powers see less gain.

The leading edge of the pulse is amplified, until the saturation energy of the gain medium is reached. In some condition, the width (FWHM) of the pulse is reduced.

Inhomogeneous broadening effects

Due to the inhomogeneous portion of the linewidth broadening of the dopant ions, the gain spectrum has an inhomogeneous component and gain saturation occurs, to a small extent, in an inhomogeneous manner. This effect is known as spectral hole burning because a high power signal at one wavelength can 'burn' a hole in the gain for wavelengths close to that signal by saturation of the inhomogeneously broadened ions. Spectral holes vary in width depending on the characteristics of the optical fiber in question and the power of the burning signal, but are typically less than 1 nm at the short wavelength end of the C-band, and a few nm at the long wavelength end of the C-band. The depth of the holes are very small, though, making it difficult to observe in practice.

Polarization effects

Although the DFA is essentially a polarization independent amplifier, a small proportion of the dopant ions interact preferentially with certain polarizations and a small dependence on the polarization of the input signal may occur (typically < 0.5 dB). This is called Polarization Dependent Gain (PDG). The absorption and emission cross sections of the ions can be modeled as ellipsoids with the major axes aligned at random in all directions in different glass sites. The random distribution of the orientation of the ellipsoids in a glass produces a macroscopically isotropic medium, but a strong pump laser induces an anisotropic distribution by selectively exciting those ions that are more aligned with the optical field vector of the pump. Also, those excited ions aligned with the signal field produce more stimulated emission. The change in gain is thus dependent on the alignment of the polarizations of the pump and signal lasers – i.e. whether the two lasers are interacting with the same sub-set of dopant ions or not. In an ideal doped fiber without birefringence, the PDG would be inconveniently large. Fortunately, in optical fibers small amounts of birefringence are always present and, furthermore, the fast and slow axes vary randomly along the fiber length. A typical DFA has several tens of meters, long enough to already show this randomness of the birefringence axes. These two combined effects (which in transmission fibers give rise to polarization mode dispersion) produce a misalignment of the relative polarizations of the signal and pump lasers along the fiber, thus tending to average out the PDG. The result is that PDG is very difficult to observe in a single amplifier (but is noticeable in links with several cascaded amplifiers).

Erbium-doped optical fiber amplifiers

The erbium-doped fiber amplifier (EDFA) is the most deployed fiber amplifier as its amplification window coincides with the third transmission window of silica-based optical fiber. The core of a silica fiber is doped with trivalent erbium ions (Er3+) and can be efficiently pumped with a laser at or near wavelengths of 980 nm and 1480 nm, and gain is exhibited in the 1550 nm region. The EDFA amplification region varies from application to application and can be anywhere from a few nm up to ~80nm. Typical use of EDFA in telecommunications calls for Conventional, or C-band amplifiers (from ~1525 nm to ~1565 nm) or Long, or L-band amplifiers (from ~1565 nm to ~1610 nm). Both of these bands can be amplified by EDFAs, but it is normal to use two different amplifiers, each optimized for one of the bands.

The principal difference between C- and L-band amplifiers is that a longer length of doped fiber is used in L-band amplifiers. The longer length of fiber allows a lower inversion level to be used, thereby giving emission at longer wavelengths (due to the band-structure of Erbium in silica) while still providing a useful amount of gain.

EDFAs have two commonly used pumping bands – 980 nm and 1480 nm. The 980 nm band has a higher absorption cross-section and is generally used where low-noise performance is required. The absorption band is relatively narrow and so wavelength stabilised laser sources are typically needed. The 1480 nm band has a lower, but broader, absorption cross-section and is generally used for higher power amplifiers. A combination of 980 nm and 1480 nm pumping is generally utilised in amplifiers.

Gain and lasing in Erbium-doped fibers were first demonstrated in 1986–87 by two groups; one including David N. Payne, R. Mears, I.M Jauncey and L. Reekie, from the University of Southampton and one from AT&T Bell Laboratories, consisting of E. Desurvire, P. Becker, and J. Simpson. The dual-stage optical amplifier which enabled Dense Wave Division Multiplexing (DWDM) was invented by Stephen B. Alexander at Ciena Corporation.

Doped fiber amplifiers for other wavelength ranges

Thulium doped fiber amplifiers have been used in the S-band (1450–1490 nm) and Praseodymium doped amplifiers in the 1300 nm region. However, those regions have not seen any significant commercial use so far and so those amplifiers have not been the subject of as much development as the EDFA. However, Ytterbium doped fiber lasers and amplifiers, operating near 1 micrometre wavelength, have many applications in industrial processing of materials, as these devices can be made with extremely high output power (tens of kilowatts).

Semiconductor optical amplifier

Semiconductor optical amplifiers (SOAs) are amplifiers which use a semiconductor to provide the gain medium. These amplifiers have a similar structure to Fabry–Pérot laser diodes but with anti-reflection design elements at the end faces. Recent designs include anti-reflective coatings and tilted wave guide and window regions which can reduce end face reflection to less than 0.001%. Since this creates a loss of power from the cavity which is greater than the gain, it prevents the amplifier from acting as a laser. Another type of SOA consists of two regions. One part has a structure of a Fabry-Pérot laser diode and the other has a tapered geometry in order to reduce the power density on the output facet.

Semiconductor optical amplifiers are typically made from group III-V compound semiconductors such as GaAs/AlGaAs, InP/InGaAs, InP/InGaAsP and InP/InAlGaAs, though any direct band gap semiconductors such as II-VI could conceivably be used. Such amplifiers are often used in telecommunication systems in the form of fiber-pigtailed components, operating at signal wavelengths between 850 nm and 1600 nm and generating gains of up to 30 dB.

The semiconductor optical amplifier is of small size and electrically pumped. It can be potentially less expensive than the EDFA and can be integrated with semiconductor lasers, modulators, etc. However, the performance is still not comparable with the EDFA. The SOA has higher noise, lower gain, moderate polarization dependence and high nonlinearity with fast transient time. The main advantage of SOA is that all four types of nonlinear operations (cross gain modulation, cross phase modulation, wavelength conversion and four wave mixing) can be conducted. Furthermore, SOA can be run with a low power laser. This originates from the short nanosecond or less upper state lifetime, so that the gain reacts rapidly to changes of pump or signal power and the changes of gain also cause phase changes which can distort the signals. This nonlinearity presents the most severe problem for optical communication applications. However it provides the possibility for gain in different wavelength regions from the EDFA. "Linear optical amplifiers" using gain-clamping techniques have been developed.

High optical nonlinearity makes semiconductor amplifiers attractive for all optical signal processing like all-optical switching and wavelength conversion. There has been much research on semiconductor optical amplifiers as elements for optical signal processing, wavelength conversion, clock recovery, signal demultiplexing, and pattern recognition.

Vertical-cavity SOA

A recent addition to the SOA family is the vertical-cavity SOA (VCSOA). These devices are similar in structure to, and share many features with, vertical-cavity surface-emitting lasers (VCSELs). The major difference when comparing VCSOAs and VCSELs is the reduced mirror reflectivity used in the amplifier cavity. With VCSOAs, reduced feedback is necessary to prevent the device from reaching lasing threshold. Due to the extremely short cavity length, and correspondingly thin gain medium, these devices exhibit very low single-pass gain (typically on the order of a few percent) and also a very large free spectral range (FSR). The small single-pass gain requires relatively high mirror reflectivity to boost the total signal gain. In addition to boosting the total signal gain, the use of the resonant cavity structure results in a very narrow gain bandwidth; coupled with the large FSR of the optical cavity, this effectively limits operation of the VCSOA to single-channel amplification. Thus, VCSOAs can be seen as amplifying filters.

Given their vertical-cavity geometry, VCSOAs are resonant cavity optical amplifiers that operate with the input/output signal entering/exiting normal to the wafer surface. In addition to their small size, the surface normal operation of VCSOAs leads to a number of advantages, including low power consumption, low noise figure, polarization insensitive gain, and the ability to fabricate high fill factor two-dimensional arrays on a single semiconductor chip. These devices are still in the early stages of research, though promising preamplifier results have been demonstrated. Further extensions to VCSOA technology are the demonstration of wavelength tunable devices. These MEMS-tunable vertical-cavity SOAs utilize a microelectromechanical systems (MEMS) based tuning mechanism for wide and continuous tuning of the peak gain wavelength of the amplifier. SOAs have a more rapid gain response, which is in the order of 1 to 100 ps.

Tapered amplifiers

For high output power and broader wavelength range, tapered amplifiers are used. These amplifiers consist of a lateral single-mode section and a section with a tapered structure, where the laser light is amplified. The tapered structure leads to a reduction of the power density at the output facet.

Typical parameters:

  • wavelength range: 633 to 1480 nm
  • input power: 10 to 50 mW
  • output power: up to 3 W

Raman amplifier

In a Raman amplifier, the signal is intensified by Raman amplification. Unlike the EDFA and SOA the amplification effect is achieved by a nonlinear interaction between the signal and a pump laser within an optical fiber. There are two types of Raman amplifier: distributed and lumped. A distributed Raman amplifier is one in which the transmission fiber is utilised as the gain medium by multiplexing a pump wavelength with signal wavelength, while a lumped Raman amplifier utilises a dedicated, shorter length of fiber to provide amplification. In the case of a lumped Raman amplifier, a highly nonlinear fiber with a small core is utilised to increase the interaction between signal and pump wavelengths, and thereby reduce the length of fiber required.

The pump light may be coupled into the transmission fiber in the same direction as the signal (co-directional pumping), in the opposite direction (contra-directional pumping) or both. Contra-directional pumping is more common as the transfer of noise from the pump to the signal is reduced.

The pump power required for Raman amplification is higher than that required by the EDFA, with in excess of 500 mW being required to achieve useful levels of gain in a distributed amplifier. Lumped amplifiers, where the pump light can be safely contained to avoid safety implications of high optical powers, may use over 1 W of optical power.

The principal advantage of Raman amplification is its ability to provide distributed amplification within the transmission fiber, thereby increasing the length of spans between amplifier and regeneration sites. The amplification bandwidth of Raman amplifiers is defined by the pump wavelengths utilised and so amplification can be provided over wider, and different, regions than may be possible with other amplifier types which rely on dopants and device design to define the amplification 'window'.

Raman amplifiers have some fundamental advantages. First, Raman gain exists in every fiber, which provides a cost-effective means of upgrading from the terminal ends. Second, the gain is nonresonant, which means that gain is available over the entire transparency region of the fiber ranging from approximately 0.3 to 2µm. A third advantage of Raman amplifiers is that the gain spectrum can be tailored by adjusting the pump wavelengths. For instance, multiple pump lines can be used to increase the optical bandwidth, and the pump distribution determines the gain flatness. Another advantage of Raman amplification is that it is a relatively broad-band amplifier with a bandwidth > 5 THz, and the gain is reasonably flat over a wide wavelength range.

However, a number of challenges for Raman amplifiers prevented their earlier adoption. First, compared to the EDFAs, Raman amplifiers have relatively poor pumping efficiency at lower signal powers. Although a disadvantage, this lack of pump efficiency also makes gain clamping easier in Raman amplifiers. Second, Raman amplifiers require a longer gain fiber. However, this disadvantage can be mitigated by combining gain and the dispersion compensation in a single fiber. A third disadvantage of Raman amplifiers is a fast response time, which gives rise to new sources of noise, as further discussed below. Finally, there are concerns of nonlinear penalty in the amplifier for the WDM signal channels.

Optical parametric amplifier

An optical parametric amplifier allows the amplification of a weak signal-impulse in a nonlinear medium such as a noncentrosymmetric nonlinear medium (e.g. Beta barium borate (BBO)) or even a standard fused silica optical fiber via the Kerr effect. In contrast to the previously mentioned amplifiers, which are mostly used in telecommunication environments, this type finds its main application in expanding the frequency tunability of ultrafast solid-state lasers (e.g. Ti:sapphire). By using a noncollinear interaction geometry optical parametric amplifiers are capable of extremely broad amplification bandwidths.

Recent achievements

The adoption of high power fiber lasers as an industrial material processing tool has been ongoing for several years and is now expanding into other markets including the medical and scientific markets. One key enhancement enabling penetration into the scientific market has been the improvements in high finesse fiber amplifiers, which are now capable of delivering single frequency linewidths (<5 kHz) together with excellent beam quality and stable linearly polarized output. Systems meeting these specifications have steadily progressed in the last few years from a few watts of output power, initially to the tens of watts and now into the hundreds of watts power level. This power scaling has been achieved with developments in the fiber technology, such as the adoption of stimulated brillouin scattering (SBS) suppression/mitigation techniques within the fiber, along with improvements in the overall amplifier design including large mode area (LMA) fibers with a low-aperture core, micro-structured rod-type fiber helical core, or chirally-coupled core fibers, and tapered double-clad fibers (T-DCF). The latest generation of high finesse, high power and pulsed fiber amplifiers now deliver power levels exceeding what is available from commercial solid-state single frequency sources and are opening up new scientific applications as a result of the higher power levels and stable optimized performance.

Implementations

There are several simulation tools that can be used to design optical amplifiers. Popular commercial tools have been developed by Optiwave Systems and VPI Systems.

C. V. Raman

From Wikipedia, the free encyclopedia
 

Chandrasekhara Venkata Raman

Sir CV Raman.JPG
Raman in 1930
 
Born
Chandrasekhara Venkata Raman

7 November 1888
Died21 November 1970 (aged 82)
NationalityIndian
Alma materUniversity of Madras (B.A., M.A.)
Known forRaman effect
SpouseLokasundari Ammal (1908–1970)
ChildrenChandrasekhar Raman and Venkatraman Radhakrishnan
AwardsFellow of the Royal Society (1924)
Matteucci Medal (1928)
Knight Bachelor (1930)
Hughes Medal (1930)
Nobel Prize in Physics (1930)
Bharat Ratna (1954)
Lenin Peace Prize (1957)
Scientific career
FieldsPhysics
Institutions
Doctoral studentsG. N. Ramachandran
Vikram Ambalal Sarabhai
Shivaramakrishnan Pancharatnam
Other notable studentsKariamanickam Srinivasa Krishnan
K. R. Ramanathan
Signature
Sir Chandrasekhara Venkata Raman

Sir Chandrasekhara Venkata Raman FRS (/ˈrɑːmən/; 7 November 1888 – 21 November 1970) was an Indian physicist known for his work in the field of light scattering. Using a spectrograph that he developed, he and his student K. S. Krishnan discovered that when light traverses a transparent material, the deflected light changes its wavelength and frequency. This phenomenon, a hitherto unknown type of scattering of light, which they called "modified scattering" was subsequently termed the Raman effect or Raman scattering. Raman received the 1930 Nobel Prize in Physics for the discovery and was the first Asian to receive a Nobel Prize in any branch of science.

Born to Tamil Brahmin parents, Raman was a precocious child, completing his secondary and higher secondary education from St Aloysius' Anglo-Indian High School at the ages of 11 and 13, respectively. He topped the bachelor's degree examination of the University of Madras with honours in physics from Presidency College at age 16. His first research paper, on diffraction of light, was published in 1906 while he was still a graduate student. The next year he obtained a master's degree. He joined the Indian Finance Service in Calcutta as Assistant Accountant General at age 19. There he became acquainted with the Indian Association for the Cultivation of Science (IACS), the first research institute in India, which allowed him to carry out independent research and where he made his major contributions in acoustics and optics.

In 1917, he was appointed the first Palit Professor of Physics by Ashutosh Mukherjee at the Rajabazar Science College under the University of Calcutta. On his first trip to Europe, seeing the Mediterranean Sea motivated him to identify the prevailing explanation for the blue colour of the sea at the time, namely the reflected Rayleigh-scattered light from the sky, as being incorrect. He founded the Indian Journal of Physics in 1926. He moved to Bangalore in 1933 to become the first Indian director of the Indian Institute of Science. He founded the Indian Academy of Sciences the same year. He established the Raman Research Institute in 1948 where he worked to his last days.

The Raman effect was discovered on 28 February 1928. The day is celebrated annually by the Government of India as the National Science Day. In 1954, the Government of India honoured him with the first Bharat Ratna, its highest civilian award. He later smashed the medallion in protest against Prime Minister Jawaharlal Nehru's policies on scientific research.

Early life and education

C. V. Raman was born in Tiruchirapalli, Madras Presidency, British Raj (now Tiruchirapalli, Tamil Nadu), to Tamil Brahmin parents, Chandrasekhara Ramanathan Iyer and Parvathi Ammal. He was the second of eight siblings. His father was a teacher at a local high school, and earned a modest income. He recalled: "I was born with a copper spoon in my mouth. At my birth my father was earning the magnificent salary of ten rupees per month!" In 1892, his family moved to Visakhapatnam (then Vishakapatnam, Vizagapatam or Vizag) in Andhra Pradesh as his father was appointed to the faculty of physics at Mrs A.V. Narasimha Rao College.

Raman was educated at the St Aloysius' Anglo-Indian High School, Visakhapatnam. He passed matriculation at age 11 and the First Examination in Arts examination (equivalent to today's intermediate examination, pre-university course) with a scholarship at age 13, securing first position in both under the Andhra Pradesh school board (now Andhra Pradesh Board of Secondary Education) examination.

In 1902, Raman joined Presidency College in Madras (now Chennai) where his father had been transferred to teach mathematics and physics. In 1904, he obtained a B.A. degree from the University of Madras, where he stood first and won the gold medals in physics and English. At age 18, while still a graduate student, he published his first scientific paper on "Unsymmetrical diffraction bands due to a rectangular aperture" in the British journal Philosophical Magazine in 1906. He earned an M.A. degree from the same university with highest distinction in 1907. His second paper published in the same journal that year was on surface tension of liquids. It was alongside Lord Rayleigh's paper on the sensitivity of ear to sound, and from which Lord Rayleigh started to communicate with Raman, courteously addressing him as "Professor."

Aware of Raman's capacity, his physics teacher Rhishard Llewellyn Jones insisted he continue research in England. Jones arranged for Raman's physical inspection with Colonel (Sir Gerald) Giffard. Raman often had poor health and was considered as a "weakling." The inspection revealed that he would not withstand the harsh weathers of England, the incident of which he later recalled, and said, "[Giffard] examined me and certified that I was going to die of tuberculosis… if I were to go to England."

Career

Raman's elder brother Chandrasekhara Subrahmanya Ayyar had joined the Indian Finance Service (now Indian Audit and Accounts Service), the most prestigious government service in India. In no condition to study abroad, Raman followed suit and qualified for the Indian Finance Service achieving first position in the entrance examination in February 1907. He was posted in Calcutta (now Kolkata) as Assistant Accountant General in June 1907. It was there that he became highly impressed with the Indian Association for the Cultivation of Science (IACS), the first research institute founded in India in 1876. He immediately befriended Asutosh Dey, who would eventually become his lifelong collaborator, Amrita Lal Sircar, founder and secretary of IACS, and Ashutosh Mukherjee, executive member of the institute and Vice-Chancellor of the University of Calcutta. With their support, he obtained permission to conduct research at IACS in his own time even "at very unusual hours," as Raman later reminisced. Up to that time the institute had not yet recruited regular researchers, or produced any research paper. Raman's article "Newton's rings in polarised light" published in Nature in 1907 became the first from the institute. The work inspired IACS to publish a journal, Bulletin of Indian Association for the Cultivation of Science, in 1909 in which Raman was the major contributor.

In 1909, Raman was transferred to Rangoon, British Burma (now Myanmar), to take up the position of currency officer. After only a few months, he had to return to Madras as his father died from an illness. The subsequent death of his father and funeral rituals compelled him to remain there for the rest of the year. Soon after he resumed office at Rangoon, he was transferred back to India at Nagpur, Maharashtra, in 1910. Even before he served a year in Nagpur, he was promoted to Accountant General in 1911 and again posted to Calcutta.

From 1915, the University of Calcutta started assigning research scholars under Raman at IACS. Sudhangsu Kumar Banerji (who later become Director General of Observatories of India Meteorological Department), a PhD scholar under Ganesh Prasad, was his first student. From the next year, other universities followed suit including University of Allahabad, Rangoon University, Queen's College Indore, Institute of Science, Nagpur, Krisnath College, and University of Madras. By 1919, Raman had guided more than a dozen students. Following Sircar's death in 1919, Raman received two honorary positions at IACS, Honorary Professor and Honorary Secretary. He referred to this period as the "golden era" of his life.

Raman was chosen by the University of Calcutta to become the Palit Professor of Physics, a position established after the benefactor Sir Taraknath Palit, in 1913. The university senate made the appointment on 30 January 1914, as recorded in the meeting minutes:

The following appointments to the Palit Professorships were made at the meeting of the Senate on 30 January 1914: Dr P C Ray and Mr C.V. Raman, MA... The appointment of each Professor shall be permanent. A Professor shall vacate his office upon completion of sixtieth year of his age.

Prior to 1914, Ashutosh Mukherjee had invited Jagadish Chandra Bose to take up the position, but Bose declined. As a second choice, Raman became the first Palit Professor of Physics but was delayed for taking up the position as World War I broke out. It was only in 1917 when he joined Rajabazar Science College, a campus created by the University of Calcutta in 1914, that he became a full-fledged professor. He reluctantly resigned as a civil servant after a decade of service, which was described as "supreme sacrifice" since his salary as a professor would be roughly half of his salary at the time. But to his advantage, the terms and conditions as a professor were explicitly indicated in the report of his joining the university, which stated:

Mr C.V. Raman's acceptance of the Sir T N Palit Professorship on condition that he will not be required to go out of India... Reported that Mr C. V. Raman joined his appointment as Palit Professor of Physics from 2.7.17... Mr Raman informed that he will not be required to take any teaching work in MA and MSc classes, to the detriment of his own research or assisting advanced students in their researches.

Raman's appointment as the Palit Professor was strongly objected to by some members of the Senate of the University of Calcutta, especially foreign members, as he had no PhD and had never studied abroad. As a kind of rebuttal, Mukherjee arranged for an honorary DSc which the University of Calcutta conferred Raman in 1921. The same year he visited Oxford to deliver a lecture at the Congress of Universities of the British Empire. He had earned quite a reputation by then, and his hosts were Nobel laureates J. J. Thomson and Lord Rutherford. Upon his election as Fellow of the Royal Society in 1924, Mukherjee asked him of his future plans, which he replied, saying, "The Nobel Prize of course." In 1926, he established the Indian Journal of Physics and acted as the first editor. The second volume of the journal published his famous article "A new radiation", reporting the discovery of the Raman effect.

Raman was succeeded by Debendra Mohan Bose as the Palit Professor in 1932. Following his appointment as Director of the Indian Institute of Science (IISc) in Bangalore, he left Calcutta in 1933. Maharaja Krishnaraja Wadiyar IV, the King of Mysore, Jamsetji Tata and Nawab Sir Mir Osman Ali Khan, the Nizam of Hyderabad, had contributed the lands and funds for the Indian Institute of Science in Bangalore. The Viceroy of India, Lord Minto approved the establishment in 1909, and the British government appointed its first director, Morris Travers. Raman became the fourth director and the first Indian director. During his tenure at IISc, he recruited G. N. Ramachandran, who later went on to become a distinguished X-ray crystallographer. He founded the Indian Academy of Sciences in 1934 and started publishing the academy's journal Proceedings of the Indian Academy of Sciences (later split up into Proceedings - Mathematical Sciences, Journal of Chemical Sciences, and Journal of Earth System Science). Around that time the Calcutta Physical Society was established, the concept of which he had initiated early in 1917.

With his former student Panchapakesa Krishnamurti, Raman started a company called Travancore Chemical and Manufacturing Co. Ltd. in 1943. The company, renamed as TCM Limited in 1996, was one of the first organic and inorganic chemical manufacturers in India. In 1947, Raman was appointed the first National Professor by the new government of independent India.

Raman retired from IISC in 1948 and established the Raman Research Institute in Bangalore a year later. He served as its director and remained active there until his death in 1970.

Scientific contributions

Energy level diagram showing the states involved in Raman signal
 
Raman at the 1930 Nobel Prize Award Ceremony with other winners, from left C. V. Raman (physics), Hans Fischer (chemistry), Karl Landsteiner (medicine) and Sinclair Lewis (literature)

Musical sound

One of Raman's interests was on the scientific basis of musical sounds. He was inspired by Hermann von Helmholtz's The Sensations of Tone, the book he came across when he joined IACS. He published his findings prolifically between 1916 and 1921. He worked out the theory of transverse vibration of bowed string instruments based on superposition of velocities. One of his earliest studies was on the wolf tone in violins and cellos. He studied the acoustics of various violin and related instruments, including Indian stringed instruments, and water splashes. He even performed what he called "Experiments with mechanically-played violins."

Raman also studied the uniqueness of Indian drums. His analyses of the harmonic nature of the sounds of tabla and mridangam were the first scientific studies on Indian percussions. He wrote a critical research on vibrations of the pianoforte string that was known as Kaufmann's theory. During his brief visit of England in 1921, he managed to study how sound travels in the Whispering Gallery of the dome of St Paul's Cathedral in London that produces unusual sound effects. His work on acoustics was an important prelude, both experimentally and conceptually, to his later works on optics and quantum mechanics.

Blue colour of the sea

Raman, in his broadening venture on optics, started to investigate scattering of light starting in 1919. His first phenomenal discovery of the physics of light was the blue colour of seawater. During a voyage home from England on board the S.S. Narkunda in September 1921, he contemplated the blue colour of the Mediterranean Sea. Using simple optical equipment, a pocket-sized spectroscope and a Nicol prism in hand, he studied the seawater. Of several hypotheses on the colour of the sea propounded at the time, the best explanation had been that of Lord Rayleigh's in 1910, according to which, "The much admired dark blue of the deep sea has nothing to do with the colour of water, but is simply the blue of the sky seen by reflection". Rayleigh had correctly described the nature of the blue sky by a phenomenon now known as Rayleigh scattering, the scattering of light and refraction by particles in the atmosphere. His explanation of the blue colour of water was instinctively accepted as correct. Raman could view the water using Nicol prism to avoid the influence of sunlight reflected by the surface. He described how the sea appears even more blue than usual, contradicting Rayleigh.

As soon as the S.S. Narkunda docked in Bombay Harbour (now Mumbai Harbour), Raman finished an article "The colour of the sea" that was published in the November 1921 issue of Nature. He noted that Rayleigh's explanation is "questionable by a simple mode of observation" (using Nicol prism). As he thought:

Looking down into the water with a Nicol in front of the eye to cut off surface reflections, the track of the sun's rays could be seen entering the water and appearing by virtue of perspective to converge to a point at a considerable depth inside it. The question is: What is it that diffracts the light and makes its passage visible? An interesting possibility that should be considered in this connection is that the diffracting particles may, at least in part, be the molecules of the water themselves.

When he reached Calcutta, he asked his student K. R. Ramanathan, who was from the University of Rangoon, to conduct further research at IACS. By early 1922, Raman came to a conclusion, as he reported in the Proceedings of the Royal Society of London:

It is proposed in this paper to urge an entirely different view, that in this phenomenon, as in the parallel case of the colour of the sky, molecular diffraction determines the observed luminosity and in great measure also its colour. As a necessary preliminary to the discussion, a theoretical calculation and experimental observations of the intensity of molecular scattering in water will be presented.

True to his words, Ramanathan published an elaborate experimental finding in 1923. His subsequent study of the Bay of Bengal in 1924 provided the full evidence. It is now known that the intrinsic colour of water is mainly attributed to the selective absorption of longer wavelengths of light in the red and orange regions of the spectrum, owing to overtones of the infrared absorbing O-H (oxygen and hydrogen combined) stretching modes of water molecules.

Raman effect

Background

Raman's second important discovery on the scattering of light was a new type of radiation, an eponymous phenomenon called the Raman effect. After discovering the nature of light scattering that caused blue colour of water, he focused on the principle behind the phenomenon. His experiments in 1923 showed the possibility of other light rays formed in addition to incident ray when sunlight was filtered through a violet glass in certain liquids and solids. Ramanathan believed that this was a case of a "trace of fluorescence." In 1925, K. S. Krishnan, a new Research Associate, noted the theoretical background for the existence of an additional scattering line beside the usual polarised elastic scattering when light scatters through liquid. He referred to the phenomenon as "feeble fluorescence." But the theoretical attempts to justify the phenomenon were quite futile for the next two years.

The major impetus was the discovery of Compton effect. Arthur Compton at Washington University in St. Louis had found evidence in 1923 that electromagnetic waves can also be described as particles. By 1927, the phenomenon was widely accepted by scientists, including Raman. As the news of Compton's Nobel Prize in Physics was announced in December 1927, Raman ecstatically told Krishnan, saying:

"Excellent news... very nice indeed. But look here Krishnan. If this is true of X-Rays, it must be true of Light too. I have always thought so. There must be an Optical analogue to Compton Effect. We must pursue it and we are on the right lines. It must and shall be found. The Nobel Prize must be won."

But the origin of the inspiration went further. As Compton later recollected "that it was probably the Toronto debate that led him to discover the Raman effect two years later." The Toronto debate was about the discussion on the existence of light quantum at the British Association for the Advancement of Science meeting held at Toronto in 1924. There Compton presented his experimental findings, which William Duane of Harvard University argued with his own with evidence that light was a wave. Raman took Duane's side and said, "Compton, you're a very good debater, but the truth isn't in you."

The scattering experiments

An early Raman spectrum of benzene published by Raman and Krishnan.

Krishnan started the experiment in the beginning of January 1928. On 7 January, he discovered that no matter what kind of pure liquid he used, it always produced polarised fluorescence within the visible spectrum of light. As Raman saw the result, he was astonished why he never observed such phenomenon all those years. That night he and Krishnan named the new phenomenon as "modified scattering" with reference to the Compton effect as an unmodified scattering. On 16 February, they sent a manuscript to Nature titled "A new type of secondary radiation", which was published on 31 March.

On 28 February 1928, they obtained spectra of the modified scattering separate from the incident light. Due to difficulty in measuring the wavelengths of light, they had been relying on visual observation of the colour produced from sunlight through prism. Raman had invented a type of spectrograph for detecting and measuring electromagnetic waves. Referring to the invention, Raman later remarked, "When I got my Nobel Prize, I had spent hardly 200 rupees on my equipment," although it was obvious that his total expenditure for the entire experiment was much more than that. From that moment they could employ the instrument using monochromatic light from a mercury arc lamp which penetrated transparent material and was allowed to fall on a spectrograph to record its spectrum. The lines of scattering could now be measured and photographed.

Announcement

The same day, Raman made the announcement before the press. The Associated Press of India reported it the next day, on 29 February, as "New theory of radiation: Prof. Raman's Discovery." It ran the story as:

Prof. C. V. Raman, F.R.S., of the Calcutta University, has made a discovery which promises to be of fundamental significance to physics... The new phenomenon exhibits features even more startling than those discovered by Prof. Compton with X-rays. The principal feature observed is that when matter is excited by light of one colour, the atoms contained in it emit light of two colours, one of which is different from the exciting colour and is lower down the spectrum. The astonishing thing is that the altered colour is quite independent of the nature of the substance used.

The news was reproduced by The Statesman on 1 March under the headline "Scattering of Light by Atoms – New Phenomenon – Calcutta Professor's Discovery." Raman submitted a three-paragraph report of the discovery on 8 March to Nature and was published on 21 April. The actual data was sent to the same journal on 22 March and was published on 5 May. Raman presented the formal and detail description as "A new radiation" at the meeting of South Indian Science Association in Bangalore on 16 March. His lecture was published in the Indian Journal of Physics on 31 March. 1,000 copies of the paper reprint were sent to scientists in different countries on that day.

Reception and outcome

Some physicists, particularly French and German physicists were initially sceptical of the authenticity of the discovery. Georg Joos at the Friedrich Schiller University of Jena asked Arnold Sommerfeld at the University of Munich, "Do you think that Raman's work on the optical Compton effect in liquids is reliable?... The sharpness of the scattered lines in liquids seems doubtful to me". Sommerfeld then tried to reproduce the experiment, but failed. On 20 June 1928, Peter Pringsheim at the University of Berlin was able to reproduce Raman's results successfully. He was the first to coin the terms Ramaneffekt and Linien des Ramaneffekts in his articles published the following months. Use of the English versions, "Raman effect" and "Raman lines" immediately followed.

In addition to being a new phenomenon itself, the Raman effect was one of the earliest proofs of the quantum nature of light. Robert W. Wood at the Johns Hopkins University was the first American to confirm the Raman effect in the early 1929. He made a series of experimental verification, after which he commented, saying, "It appears to me that this very beautiful discovery which resulted from Raman's long and patient study of the phenomenon of light scattering is one of the most convincing proofs of the quantum theory". The field of Raman spectroscopy came to be based on this phenomenon, and Ernest Rutherford, President of the Royal Society, referred to it in his presentation of the Hughes Medal to Raman in 1930 as "among the best three or four discoveries in experimental physics in the last decade".

Raman was confident that he would win the Nobel Prize in Physics as well but was disappointed when the Nobel Prize went to Owen Richardson in 1928 and to Louis de Broglie in 1929. He was so confident of winning the prize in 1930 that he booked tickets in July, even though the awards were to be announced in November. He would scan each day's newspaper for announcement of the prize, tossing it away if it did not carry the news. He did eventually win that year.

Later work

Raman had association with the Banaras Hindu University in Varanasi. He attended the foundation ceremony of BHU and delivered lectures on mathematics and "Some new paths in physics" during the lecture series organised at the university from 5 to 8 February 1916. He also held the position of permanent visiting professor.

With Suri Bhagavantam, he determined the spin of photons in 1932, which further confirmed the quantum nature of light. With another student, Nagendra Nath, he provided the correct theoretical explanation for the acousto-optic effect (light scattering by sound waves) in a series of articles resulting in the celebrated Raman–Nath theory. Modulators, and switching systems based on this effect have enabled optical communication components based on laser systems.

Other investigations he carried out included experimental and theoretical studies on the diffraction of light by acoustic waves of ultrasonic and hypersonic frequencies, and those on the effects produced by X-rays on infrared vibrations in crystals exposed to ordinary light which were published between 1935 and 1942.

In 1948, through studying the spectroscopic behaviour of crystals, he approached the fundamental problems of crystal dynamics in a new manner. He dealt with the structure and properties of diamond from 1944 to 1968, the structure and optical behaviour of numerous iridescent substances including labradorite, pearly feldspar, agate, quartz, opal, and pearl in the early 1950s. Among his other interests were the optics of colloids, and electrical and magnetic anisotropy. His last interests in the 1960s were on biological properties such as the colours of flowers and the physiology of human vision.

Personal life

Raman married Lokasundari Ammal (1892–1980) on 6 May 1907. It was a self-arranged marriage and his wife was 13 years old. His wife later jokingly recounted that their marriage was not so much about her musical prowess (she was playing veena when they first met) as "the extra allowance which the Finance Department gave to its married officers." The extra allowance refers to an additional INR 150 for married officers at the time. Soon after they moved to Calcutta in 1907, the couple were accused of converting to Christianity. It was because they frequently visited St. John's Church, Kolkata as Lokasundari was fascinated with the church music and Raman with the acoustics.

They had two sons, Chandrasekhar Raman and Venkatraman Radhakrishnan, a radio astronomer. Raman was the paternal uncle of Subrahmanyan Chandrasekhar, recipient of the 1983 Nobel Prize in Physics.

Throughout his life, Raman developed an extensive personal collection of stones, minerals, and materials with interesting light-scattering properties, which he obtained from his world travels and as gifts. He often carried a small, handheld spectroscope to study specimens. These, along with his spectrograph, are on display at IISc.

Lord Rutherford was instrumental in some of Raman's most pivotal moments in life. He nominated Raman for the Nobel Prize in Physics in 1930, presented him the Hughes Medal as President of the Royal Society in 1930, and recommended him for the position of Director at IISc in 1932.

Raman had a sense of obsession with the Nobel Prize. In a speech at the University of Calcutta, he said, "I'm not flattered by the honour [Fellowship to the Royal Society in 1924] done to me. This is a small achievement. If there is anything that I aspire for, it is the Nobel Prize. You will find that I get that in five years." He knew that if he were to receive the Nobel Prize, he could not wait for the announcement of the Nobel Committee normally made towards the end of the year considering the time required to reach Sweden by sea route. With confidence, he booked two tickets, one for his wife, for a steamship to Stockholm in July 1930. Soon after he received the Nobel Prize, he was asked in an interview the possible consequences if he had discovered the Raman effect earlier, which he replied, "Then I should have shared the Nobel Prize with Compton and I should not have liked that; I would rather receive the whole of it."

Religious views

Although Raman hardly talked about religion, he was openly an agnostic, but objected to being labelled atheist. His agnosticism was largely influenced by that of his father who adhered to the philosophies of Herbert Spencer, Charles Bradlaugh, and Robert G. Ingersoll. He resented Hindu traditional rituals but did not give them up in family circles. He was also influenced by the philosophy of Advaita Vedanta. Traditional pagri (Indian turban) with a tuft underneath and a upanayana (Hindu sacred thread) were his signature attire. Though it was not customary to wear turbans in South Indian culture, he explained his habit as, "Oh, if I did not wear one, my head will swell. You all praise me so much and I need a turban to contain my ego." He even attributed his turban for the recognition he received on his first visit to England, particular from J. J. Thomson and Lord Rutherford. In a public speech, he once said,

There is no Heaven, no Swarga, no Hell, no rebirth, no reincarnation and no immortality. The only thing that is true is that a man is born, he lives and he dies. Therefore, he should live his life properly.

In a friendly meeting with Mahatma Gandhi and Gilbert Rahm, a German zoologist, the conversation turned to religion. Raman spoke,

I shall answer your [Rahm's] question. If there is a God we must look for him in the Universe. If he is not there, he is not worth looking for... The growing discoveries in the science of astronomy and physics seem to be further and further revelations of God.

On his deathbed, he said to his wife, "I believe only in the Spirit of Man," and asked for his funeral, "Just a clean and simple cremation for me, no mumbo-jumbo please."

Death

At the end of October 1970, Raman had a cardiac arrest and collapsed in his laboratory. He was moved to the hospital where doctors diagnosed his condition and declared that he would not survive another four hours. He however survived a few days and requested to stay in the gardens of his institute surrounded by his followers.

Two days before Raman died, he told one of his former students, "Do not allow the journals of the Academy to die, for they are the sensitive indicators of the quality of science being done in the country and whether science is taking root in it or not." That evening, Raman met with the Board of Management of his institute in his bedroom and discussed with them the fate of the institute's management. He also willed his wife to perform a simple cremation without any rituals upon his death. He died from natural causes early the next morning on 21 November 1970 at the age of 82.

On the news of Raman's death, Prime Minister Indira Gandhi publicly announced, saying,

The country, the House [of Parliament], and everyone of us will mourn the death of Dr. C. V. Raman. He was the greatest scientist of modern India and one of the greatest intellects our country has produced in its long history. His mind was like the diamond, which he studied and explained. His life's work consisted in throwing light upon the nature of lights, and the world honoured him in many ways for the new knowledge which he won for science.

Controversies

The Nobel Prize

Independent discovery

In 1928, Grigory Landsberg and Leonid Mandelstam at the Moscow State University independently discovered the Raman effect. They published their findings in July issue of Naturwissenschaften, and presented their findings at the Sixth Congress of the Russian Association of Physicists held at Saratov between 5 and 16 August. In 1930, they were nominated for the Nobel Prize alongside Raman. According to the Nobel Committee, however: (1) the Russians did not come to an independent interpretation of their discovery as they cited Raman's article; (2) they observed the effect only in crystals, whereas Raman and Krishnan observed it in solids, liquids and gases, and therefore proved the universal nature of the effect; (3) the problems concerning the intensity of Raman and infrared lines in the spectra had been explained during the previous year; (4) the Raman method had been applied with great success in different fields of molecular physics; and (5) the Raman effect had effectively helped to check the symmetry properties of molecules, and thus the problems concerning nuclear spin in atomic physics.

The Nobel Committee proposed only Raman's name to the Royal Swedish Academy of Sciences for the Nobel Prize. Evidence later appeared that the Russians had discovered the phenomenon earlier, a week before Raman and Krishnan's discovery. According to Mandelstam's letter (to Orest Khvolson), the Russian had observed the spectral line on 21 February 1928.

Role of Krishnan

Krishnan was not nominated for the Nobel Prize even though he was the main researcher in the discovery of Raman effect. It was he alone who first noted the new scattering. Krishnan co-authored all the scientific papers on the discovery in 1928 except two. He alone wrote all the follow-up studies. Krishnan himself never claimed himself worthy of the prize. But Raman admitted later that Krishnan was the co-discoverer. He however remained openly antagonistic towards Krishnan, which the latter described as "the greatest tragedy of my life." After Krishnan's death, Raman said to a correspondent from The Times of India, "Krishnan was the greatest charlatan I have known, and all his life he masqueraded in the cloak of another man's discovery."

The Raman–Born controversy

During October 1933 to March 1934, Max Born was employed by IISc as Reader in Theoretical Physics following the invitation by Raman early in 1933. Born at the time was a refugee from Nazi Germany and temporarily employed at St John's College, Cambridge. Since the beginning of the 20th century Born had developed a theory on lattice dynamics based on thermal properties. He presented his theory in one of his lectures at IISc. By then Raman had developed a different theory and claimed that Born's theory contradicted the experimental data. Their debate lasted for decades.

In this dispute, Born received support from most physicists, as his view was proven to be a better explanation. Raman's theory was generally regarded as having a partial relevance. Beyond the intellectual debate, their rivalry extended to personal and social levels. Born later said that Raman probably thought of him as an "enemy." In spite of the mounting evidence for Born's theory, Raman refused to concede. As the editor of Current Science he rejected articles which supported Born's theory. Born was nominated several times for the Nobel Prize specifically for his contributions to lattice theory, and eventually won it for his statistical works on quantum mechanics in 1954. The account was written as a "belated Nobel Prize."

Indian authorities

Raman had an aversion to the then Prime Minister of India Jawaharlal Nehru and Nehru's policies on science. In one instance he smashed the bust of Nehru on the floor. In another he shattered his Bharat Ratna medallion to pieces with a hammer, as it was given to him by the Nehru government. He publicly ridiculed Nehru when the latter visited the Raman Research Institute in 1948. There they displayed a piece of gold and copper against an ultraviolet light. Nehru was tricked into believing that copper which glowed more brilliantly than any other metal was gold. Raman was quick to remark, "Mr Prime Minister, everything that glitters is not gold."

On the same occasion Nehru, offered Raman financial assistance to his institute which Raman flatly refused by replying, "I certainly don't want this to become another government laboratory." Raman was particularly against the control of research programmes by the government such as in the establishment of the Bhabha Atomic Research Centre (BARC), Defense Research and Development Organization (DRDO), and the Council of Scientific and Industrial Research (CSIR). He remained hostile to people associated with these establishments including Homi J. Bhabha, S.S. Bhatnagar, and his once favourite student, Krishnan. He even called such programmes as the "Nehru–Bhatnagar effect." In 1959, Raman proposed to establish another research institute in Madras. The Government of Madras advised him to apply for funds from the central government. But Raman clearly foresaw, as he replied to C. Subramaniam, then the Minister for Finance Education in Madras, that his proposal to Nehru's government "would be met with a refusal." So ended the plan.

Raman described AICC authorities as "a big tamasha" (drama or spectacle) that just kept on discussing issues without action. As to problems of food resources in India, his advice to the government was, "We must stop breeding like pigs and the matter will solve itself."

Indian Academy of Sciences

The Indian Academy of Sciences was born out of conflicts during the procedures of proposal for a national scientific organisation in line with the Royal Society. In 1933, the Indian Science Congress Association (ISCA), at the time the largest scientific organisation, planned to establish a national science body, which would be authorised to advise the government on scientific matters. Sir Richard Gregory, then editor of Nature, on his visit to India had suggested Raman, as editor of Current Science, to establish an Indian Academy of Sciences. Raman was of the opinion that it should be an exclusively Indian membership as opposed to the general consensus that British members should be included. He resolved that "How can India Science prosper under the tutelage of an academy which has its own council of 30, 15 of who are Britishers of whom only two or three are fit enough to be its Fellows." On 1 April 1933, he convened a separate meeting of the south Indian scientists. He and Subba Rao officially resigned from ISCA.

Raman registered the new organisation as Indian Academy of Sciences on 24 April to the Registrar of Societies. It was a provisional name to be changed to the Royal Society of India after approval from the Royal Charter. The Government of India did not recognise it as an official national scientific body, as such the ICSA created a separate organisation named the National Institute of Sciences of India on 7 January 1935 (but again changed to the Indian National Science Academy in 1970). INSA had been led by the foremost rivals of Raman including Meghnad Saha, Bhabha, Bhatnagar, and Krishnan.

Indian Institute of Science

Raman had a great fallout with the authorities at the Indian Institute of Science (IISc). He was accused of biased development in physics, while ignoring other fields. He lacked diplomatic personality on other colleagues, which S. Ramaseshan, his nephew and later Director of IISc, reminisced, saying, "Raman went in there like a bull in a china shop." He wanted research in physics at the level of those of western institutes, but at the expense of other fields of science. Max Born observed, "Raman found a sleepy place where very little work was being done by a number of extremely well paid people." At the Council meeting, Kenneth Aston, professor in the Electrical Technology Department, harshly criticised Raman and Raman's recruitment of Born. Raman had every intention of giving full position of professor to Born. Aston even made personal attack on Born by referring to him as someone "who was rejected by his own country, a renegade and therefore a second-rate scientist unfit to be part of the faculty, much less to be the head of the department of physics."

The Council of IISc constituted a review committee to oversee Raman's conduct in January 1936. The committee, chaired by James Irvine, Principal and Vice-Chancellor of the University of St Andrews, reported in March that Raman had misused the funds and entirely shifted the "centre of gravity" towards research in physics, and also that the proposal of Born as Professor of Mathematical Physics (which was already approved by the Council in November 1935) was not financially feasible. The Council offered Raman two choices, either to resign from the institute with effect from 1 April or resign as the Director and continue as Professor of physics; if he did not make the choice, he was to be fired. Raman was inclined to take up the second choice.

The Royal Society

Raman never seemed to have thought highly of the Fellowship of the Royal Society. He tendered his resignation as a Fellow on 9 March 1968, which the Council of the Royal Society accepted on 4 April. However, the exact reason was not documented. One reason could be Raman's objection to the designation "British subjects" as one of the categories of the Fellows. Particularly after the Independence of India, the Royal Society had its own disputes on this matter.

According to Subrahmanyan Chandrasekhar, The London Times had once made a list of the Fellows, in which Raman was omitted. Raman wrote to and demanded explanation from Patrick Blackett, the then President of the society. He was dejected by Blackett's response that the society had no role in the newspaper. According to Krishnan, another cause was a disapproving review Raman received on a manuscript he had submitted to the Proceedings of the Royal Society. It could have been these cumulative factors as Raman wrote in his resignation letter, and said, "I have taken this decision after careful consideration of all the circumstances of the case. I would request that my resignation be accepted and my name removed from the list of the Fellows of the Society."

Honours and awards

Bust of Chandrasekhara Venkata Raman in the garden of Birla Industrial & Technological Museum.

Raman was honoured with many honorary doctorates and memberships of scientific societies. Within India, apart from being the founder and President of the Indian Academy of Sciences (FASc), he was a Fellow of the Asiatic Society of Bengal (FASB), and from 1943, a Foundation Fellow of the Indian Association for the Cultivation of Science (FIAS). In 1935, he was appointed a Foundation Fellow of the National Institute of Sciences of India (FNI, now the Indian National Science Academy. He was a member of the Deutsche Akademie of Munich, the Swiss Physical Society of Zürich, the Royal Philosophical Society of Glasgow, the Royal Irish Academy, the Hungarian Academy of Sciences, the Academy of Sciences of the USSR, the Optical Society of America, the Mineralogical Society of America, the Romanian Academy of Sciences, the Catgut Acoustical Society of America and the Czechoslovak Academy of Sciences.

In 1924, he was elected a Fellow of the Royal Society. However, he resigned from the fellowship in 1968 for unrecorded reasons, the only Indian FRS ever to do so.

He was the President of the 16th session of the Indian Science Congress in 1929. He was the founder President of the Indian Academy of Sciences from 1933 until his death. He was member of the Pontifical Academy of Sciences in 1961.

Awards

Posthumous recognition and contemporary references

  • India celebrates National Science Day on 28 February of every year to commemorate the discovery of the Raman effect in 1928.
  • Postal stamps featuring Raman were issued in 1971 and 2009.
  • A road in India's capital, New Delhi, is named C. V. Raman Marg.
  • An area in eastern Bangalore is called CV Raman Nagar.
  • The road running north of the national seminar complex in Bangalore is named C. V. Raman Road.
  • A building at the Indian Institute of Science in Bangalore is named the Raman Building.
  • A hospital in eastern Bangalore on 80 Ft. Rd. is named the Sir C. V. Raman Hospital.
  • There is also CV Raman Nagar in Trichy, his birthplace.
  • Raman, a lunar crater is named after C. V. Raman.
  • C. V. Raman Global University was established in 1997.
  • In 1998, the American Chemical Society and Indian Association for the Cultivation of Science recognised Raman's discovery as an International Historic Chemical Landmark at the Indian Association for the Cultivation of Science in Jadavpur, Calcutta, India. The inscription on the commemoration plaque reads:

    At this institute, Sir C. V. Raman discovered in 1928 that when a beam of coloured light entered a liquid, a fraction of the light scattered by that liquid was of a different color. Raman showed that the nature of this scattered light was dependent on the type of sample present. Other scientists quickly understood the significance of this phenomenon as an analytical and research tool and called it the Raman Effect. This method became even more valuable with the advent of modern computers and lasers. Its current uses range from the non-destructive identification of minerals to the early detection of life-threatening diseases. For his discovery Raman was awarded the Nobel Prize in Physics in 1930.

  • Dr. C.V. Raman University was established in Chhattisgarh in 2006.
  • On 7 November 2013, a Google Doodle honoured Raman on the 125th anniversary of his birthday.
  • Raman Science Centre in Nagpur is named after Sir C. V. Raman.
  • Dr. C.V. Raman University, Bihar was established in 2018.
  • Dr. C.V. Raman University, Khandwa was established in 2018.

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