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Thursday, September 4, 2014

Schrödinger equation

Schrödinger equation

From Wikipedia, the free encyclopedia

Erwin Schrödinger

In quantum mechanics, the Schrödinger equation is a partial differential equation that describes how the quantum state of a physical system changes with time. It was formulated in late 1925, and published in 1926, by the Austrian physicist Erwin Schrödinger.[1]

In classical mechanics, the equation of motion is Newton's second law, (F = ma), and equivalent formulations are the Euler–Lagrange equations and Hamilton's equations. All of these formulations are used to solve for the motion of a mechanical system and mathematically predict what the system will do at any time beyond the initial settings and configuration of the system.

In quantum mechanics, the analogue of Newton's law is Schrödinger's equation for a quantum system (usually atoms, molecules, and subatomic particles whether free, bound, or localized). It is not a simple algebraic equation, but (in general) a linear partial differential equation. The differential equation describes the wave function of the system, also called the quantum state or state vector.

The concept of a state vector is a fundamental postulate of quantum mechanics. But Schrödinger's equation, although often presented as a postulate, can in fact be derived from symmetry principles.

In the standard interpretation of quantum mechanics, the wave function is the most complete description that can be given to a physical system. Solutions to Schrödinger's equation describe not only molecular, atomic, and subatomic systems, but also macroscopic systems, possibly even the whole universe.[4]:292ff

Like Newton's second law, the Schrödinger equation can be mathematically transformed into other formulations such as Werner Heisenberg's matrix mechanics, and Richard Feynman's path integral formulation. Also like Newton's second law, the Schrödinger equation describes time in a way that is inconvenient for relativistic theories, a problem that is not as severe in matrix mechanics and completely absent in the path integral formulation.[citation needed]

Equation

Time-dependent equation

The form of the Schrödinger equation depends on the physical situation (see below for special cases). The most general form is the time-dependent Schrödinger equation, which gives a description of a system evolving with time:[5]:143
Time-dependent Schrödinger equation (general) i \hbar \frac{\partial}{\partial t}\Psi = \hat H \Psi
where i is the imaginary unit, ħ is the Planck constant divided by 2π (which is known as the reduced Planck constant), the symbol ∂/∂t indicates a partial derivative with respect to time t, Ψ (the Greek letter Psi) is the wave function of the quantum system, and Ĥ is the Hamiltonian operator (which characterizes the total energy of any given wave function and takes different forms depending on the situation).
A wave function that satisfies the non-relativistic Schrödinger equation with V = 0. In other words, this corresponds to a particle traveling freely through empty space. The real part of the wave function is plotted here.

The most famous example is the non-relativistic Schrödinger equation for a single particle moving in an electric field (but not a magnetic field; see the Pauli equation):
Time-dependent Schrödinger equation (single non-relativistic particle) i\hbar\frac{\partial}{\partial t} \Psi(\mathbf{r},t) = \left [ \frac{-\hbar^2}{2\mu}\nabla^2 + V(\mathbf{r},t)\right ] \Psi(\mathbf{r},t)
where μ is the particle's "reduced mass", V is its potential energy, ∇2 is the Laplacian, and Ψ is the wave function (more precisely, in this context, it is called the "position-space wave function"). In plain language, it means "total energy equals kinetic energy plus potential energy", but the terms take unfamiliar forms for reasons explained below.

Given the particular differential operators involved, this is a linear partial differential equation. It is also a diffusion equation, but unlike the heat equation, this one is also a wave equation given the imaginary unit present in the transient term.

The term "Schrödinger equation" can refer to both the general equation (first box above), or the specific nonrelativistic version (second box above and variations thereof). The general equation is indeed quite general, used throughout quantum mechanics, for everything from the Dirac equation to quantum field theory, by plugging in various complicated expressions for the Hamiltonian. The specific nonrelativistic version is a simplified approximation to reality, which is quite accurate in many situations, but very inaccurate in others (see relativistic quantum mechanics and relativistic quantum field theory).

To apply the Schrödinger equation, the Hamiltonian operator is set up for the system, accounting for the kinetic and potential energy of the particles constituting the system, then inserted into the Schrödinger equation. The resulting partial differential equation is solved for the wave function, which contains information about the system.

Time-independent equation

Each of these three rows is a wave function which satisfies the time-dependent Schrödinger equation for a harmonic oscillator. Left: The real part (blue) and imaginary part (red) of the wave function. Right: The probability distribution of finding the particle with this wave function at a given position. The top two rows are examples of stationary states, which correspond to standing waves. The bottom row is an example of a state which is not a stationary state. The right column illustrates why stationary states are called "stationary".

The time-independent Schrödinger equation predicts that wave functions can form standing waves, called stationary states (also called "orbitals", as in atomic orbitals or molecular orbitals). These states are important in their own right, and moreover if the stationary states are classified and understood, then it becomes easier to solve the time-dependent Schrödinger equation for any state. The time-independent Schrödinger equation is the equation describing stationary states. (It is only used when the Hamiltonian itself is not dependent on time. In general, the wave function still has a time dependency.)
Time-independent Schrödinger equation (general) E\Psi=\hat H \Psi
In words, the equation states:
When the Hamiltonian operator acts on a certain wave function Ψ, and the result is proportional to the same wave function Ψ, then Ψ is a stationary state, and the proportionality constant, E, is the energy of the state Ψ.
The time-independent Schrödinger equation is discussed further below. In linear algebra terminology, this equation is an eigenvalue equation.

As before, the most famous manifestation is the non-relativistic Schrödinger equation for a single particle moving in an electric field (but not a magnetic field):
Time-independent Schrödinger equation (single non-relativistic particle) E \Psi(\mathbf{r}) = \left[ \frac{-\hbar^2}{2m}\nabla^2 + V(\mathbf{r}) \right] \Psi(\mathbf{r})
with definitions as above.

Implications

The Schrödinger equation, and its solutions, introduced a breakthrough in thinking about physics. Schrödinger's equation was the first of its type, and solutions led to consequences that were very unusual and unexpected for the time.

Total, kinetic, and potential energy

The overall form of the equation is not unusual or unexpected as it uses the principle of the conservation of energy. The terms of the nonrelativistic Schrödinger equation can be interpreted as total energy of the system, equal to the system kinetic energy plus the system potential energy. In this respect, it is just the same as in classical physics.

Quantization

The Schrödinger equation predicts that if certain properties of a system are measured, the result may be quantized, meaning that only specific discrete values can occur. One example is energy quantization: the energy of an electron in an atom is always one of the quantized energy levels, a fact discovered via atomic spectroscopy. (Energy quantization is discussed below.) Another example is quantization of angular momentum. This was an assumption in the earlier Bohr model of the atom, but it is a prediction of the Schrödinger equation.

Another result of the Schrödinger equation is that not every measurement gives a quantized result in quantum mechanics. For example, position, momentum, time, and (in some situations) energy can have any value across a continuous range.[6]:165–167

Measurement and uncertainty

In classical mechanics, a particle has, at every moment, an exact position and an exact momentum.
These values change deterministically as the particle moves according to Newton's laws. In quantum mechanics, particles do not have exactly determined properties, and when they are measured, the result is randomly drawn from a probability distribution. The Schrödinger equation predicts what the probability distributions are, but fundamentally cannot predict the exact result of each measurement.

The Heisenberg uncertainty principle is the statement of the inherent measurement uncertainty in quantum mechanics. It states that the more precisely a particle's position is known, the less precisely its momentum is known, and vice versa.

The Schrödinger equation describes the (deterministic) evolution of the wave function of a particle. However, even if the wave function is known exactly, the result of a specific measurement on the wave function is uncertain.

Quantum tunneling

Quantum tunneling through a barrier. A particle coming from the left does not have enough energy to climb the barrier. However, it can sometimes "tunnel" to the other side.

In classical physics, when a ball is rolled slowly up a large hill, it will come to a stop and roll back, because it doesn't have enough energy to get over the top of the hill to the other side. However, the Schrödinger equation predicts that there is a small probability that the ball will get to the other side of the hill, even if it has too little energy to reach the top. This is called quantum tunneling. It is related to the uncertainty principle: Although the ball seems to be on one side of the hill, its position is uncertain so there is a chance of finding it on the other side.

Particles as waves

A double slit experiment showing the accumulation of electrons on a screen as time passes.

The nonrelativistic Schrödinger equation is a type of partial differential equation called a wave equation. Therefore it is often said particles can exhibit behavior usually attributed to waves. In most modern interpretations this description is reversed – the quantum state, i.e. wave, is the only genuine physical reality, and under the appropriate conditions it can show features of particle-like behavior.
Two-slit diffraction is a famous example of the strange behaviors that waves regularly display, that are not intuitively associated with particles. The overlapping waves from the two slits cancel each other out in some locations, and reinforce each other in other locations, causing a complex pattern to emerge. Intuitively, one would not expect this pattern from firing a single particle at the slits, because the particle should pass through one slit or the other, not a complex overlap of both.

However, since the Schrödinger equation is a wave equation, a single particle fired through a double-slit does show this same pattern (figure on right). Note: The experiment must be repeated many times for the complex pattern to emerge. The appearance of the pattern proves that each electron passes through both slits simultaneously.[7][8][9] Although this is counterintuitive, the prediction is correct; in particular, electron diffraction and neutron diffraction are well understood and widely used in science and engineering.

Related to diffraction, particles also display superposition and interference.

The superposition property allows the particle to be in a quantum superposition of two or more states with different classical properties at the same time. For example, a particle can have several different energies at the same time, and can be in several different locations at the same time. In the above example, a particle can pass through two slits at the same time. This superposition is still a single quantum state, as shown by the interference effects, even though that conflicts with classical intuition.

Interpretation of the wave function

The Schrödinger equation provides a way to calculate the possible wave functions of a system and how they dynamically change in time. However, the Schrödinger equation does not directly say what, exactly, the wave function is. Interpretations of quantum mechanics address questions such as what the relation is between the wave function, the underlying reality, and the results of experimental measurements.
An important aspect is the relationship between the Schrödinger equation and wavefunction collapse. In the oldest Copenhagen interpretation, particles follow the Schrödinger equation except during wavefunction collapse, during which they behave entirely differently. The advent of quantum decoherence theory allowed alternative approaches (such as the Everett many-worlds interpretation and consistent histories), wherein the Schrödinger equation is always satisfied, and wavefunction collapse should be explained as a consequence of the Schrödinger equation.

Historical background and development

Following Max Planck's quantization of light (see black body radiation), Albert Einstein interpreted Planck's quanta to be photons, particles of light, and proposed that the energy of a photon is proportional to its frequency, one of the first signs of wave–particle duality. Since energy and momentum are related in the same way as frequency and wavenumber in special relativity, it followed that the momentum p of a photon is inversely proportional to its wavelength λ, or proportional to its wavenumber k.
p = \frac{h}{\lambda} = \hbar k
where h is Planck's constant. Louis de Broglie hypothesized that this is true for all particles, even particles which have mass such as electrons. He showed that, assuming that the matter waves propagate along with their particle counterparts, electrons form standing waves, meaning that only certain discrete rotational frequencies about the nucleus of an atom are allowed.[10] These quantized orbits correspond to discrete energy levels, and de Broglie reproduced the Bohr model formula for the energy levels. The Bohr model was based on the assumed quantization of angular momentum L according to:
L = n{h \over 2\pi} = n\hbar.
According to de Broglie the electron is described by a wave and a whole number of wavelengths must fit along the circumference of the electron's orbit:
n \lambda = 2 \pi r.\,
This approach essentially confined the electron wave in one dimension, along a circular orbit of radius r.

In 1921, prior to de Broglie, Arthur C. Lunn at the University of Chicago had used the same argument based on the completion of the relativistic energy–momentum 4-vector to derive what we now call the de Broglie relation[11] Unlike de Broglie, Lunn went on to formulate the differential equation now known as the Schrödinger equation, and solve for its energy eigenvalues for the hydrogen atom. Unfortunately the paper was rejected by the Physical Review, as recounted by Kamen.[12]

Following up on de Broglie's ideas, physicist Peter Debye made an offhand comment that if particles behaved as waves, they should satisfy some sort of wave equation. Inspired by Debye's remark, Schrödinger decided to find a proper 3-dimensional wave equation for the electron. He was guided by William R. Hamilton's analogy between mechanics and optics, encoded in the observation that the zero-wavelength limit of optics resembles a mechanical system — the trajectories of light rays become sharp tracks that obey Fermat's principle, an analog of the principle of least action.[13] A modern version of his reasoning is reproduced below. The equation he found is:[14]
i\hbar \frac{\partial}{\partial t}\Psi(\mathbf{r},\,t)=-\frac{\hbar^2}{2m}\nabla^2\Psi(\mathbf{r},\,t) + V(\mathbf{r})\Psi(\mathbf{r},\,t).
However, by that time, Arnold Sommerfeld had refined the Bohr model with relativistic corrections.[15][16] Schrödinger used the relativistic energy momentum relation to find what is now known as the Klein–Gordon equation in a Coulomb potential (in natural units):
\left(E + {e^2\over r} \right)^2 \psi(x) = - \nabla^2\psi(x) + m^2 \psi(x).
He found the standing waves of this relativistic equation, but the relativistic corrections disagreed with Sommerfeld's formula. Discouraged, he put away his calculations and secluded himself in an isolated mountain cabin in December 1925.[17]

While at the cabin, Schrödinger decided that his earlier non-relativistic calculations were novel enough to publish, and decided to leave off the problem of relativistic corrections for the future.
Despite difficulties solving the differential equation for hydrogen (he had later help from his friend the mathematician Hermann Weyl[18]:3) Schrödinger showed that his non-relativistic version of the wave equation produced the correct spectral energies of hydrogen in a paper published in 1926.[18]:1[19] In the equation, Schrödinger computed the hydrogen spectral series by treating a hydrogen atom's electron as a wave Ψ(x, t), moving in a potential well V, created by the proton. This computation accurately reproduced the energy levels of the Bohr model. In a paper, Schrödinger himself explained this equation as follows:


This 1926 paper was enthusiastically endorsed by Einstein, who saw the matter-waves as an intuitive depiction of nature, as opposed to Heisenberg's matrix mechanics, which he considered overly formal.[21]

The Schrödinger equation details the behavior of Ψ but says nothing of its nature. Schrödinger tried to interpret it as a charge density in his fourth paper, but he was unsuccessful.[22]:219 In 1926, just a few days after Schrödinger's fourth and final paper was published, Max Born successfully interpreted Ψ as the probability amplitude, whose absolute square is equal to probability density.[22]:220 Schrödinger, though, always opposed a statistical or probabilistic approach, with its associated discontinuities—much like Einstein, who believed that quantum mechanics was a statistical approximation to an underlying deterministic theory— and never reconciled with the Copenhagen interpretation.[23]

Louis de Broglie in his later years proposed a real valued wave function connected to the complex wave function by a proportionality constant and developed the De Broglie–Bohm theory.

The wave equation for particles

The Schrödinger equation is mathematically a wave equation, since the solutions are functions which describe wave-like motions. Wave equations in physics can normally be derived from other physical laws – the wave equation for mechanical vibrations on strings and in matter can be derived from Newton's laws – where the wave function represents the displacement of matter, and electromagnetic waves from Maxwell's equations, where the wave functions are electric and magnetic fields. The basis for Schrödinger's equation, on the other hand, is the energy of the system and a separate postulate of quantum mechanics: the wave function is a description of the system.[24] The Schrödinger equation is therefore a new concept in itself; as Feynman put it:


The equation is structured to be a linear differential equation based on classical energy conservation, and consistent with the De Broglie relations. The solution is the wave function ψ, which contains all the information that can be known about the system. In the Copenhagen interpretation, the modulus of ψ is related to the probability the particles are in some spatial configuration at some instant of time. Solving the equation for ψ can be used to predict how the particles will behave under the influence of the specified potential and with each other.

The Schrödinger equation was developed principally from the De Broglie hypothesis, a wave equation that would describe particles,[26] and can be constructed as shown informally in the following sections.[27] For a more rigorous description of Schrödinger's equation, see also.[28]

Consistency with energy conservation

The total energy E of a particle is the sum of kinetic energy T and potential energy V, this sum is also the frequent expression for the Hamiltonian H in classical mechanics:
E = T + V =H \,\!
Explicitly, for a particle in one dimension with position x, mass m and momentum p, and potential energy V which generally varies with position and time t:
E = \frac{p^2}{2m}+V(x,t)=H.
For three dimensions, the position vector r and momentum vector p must be used:
E = \frac{\mathbf{p}\cdot\mathbf{p}}{2m}+V(\mathbf{r},t)=H
This formalism can be extended to any fixed number of particles: the total energy of the system is then the total kinetic energies of the particles, plus the total potential energy, again the Hamiltonian.
However, there can be interactions between the particles (an N-body problem), so the potential energy V can change as the spatial configuration of particles changes, and possibly with time. The potential energy, in general, is not the sum of the separate potential energies for each particle, it is a function of all the spatial positions of the particles. Explicitly:
E=\sum_{n=1}^N \frac{\mathbf{p}_n\cdot\mathbf{p}_n}{2m_n} + V(\mathbf{r}_1,\mathbf{r}_2\cdots\mathbf{r}_N,t) = H \,\!

Linearity

The simplest wavefunction is a plane wave of the form:
\Psi(\mathbf{r},t) = A e^{i(\mathbf{k}\cdot\mathbf{r}-\omega t)} \,\!
where the A is the amplitude, k the wavevector, and ω the angular frequency, of the plane wave. In general, physical situations are not purely described by plane waves, so for generality the superposition principle is required; any wave can be made by superposition of sinusoidal plane waves. So if the equation is linear, a linear combination of plane waves is also an allowed solution.
Hence a necessary and separate requirement is that the Schrödinger equation is a linear differential equation.

For discrete k the sum is a superposition of plane waves:
\Psi(\mathbf{r},t) = \sum_{n=1}^\infty A_n e^{i(\mathbf{k}_n\cdot\mathbf{r}-\omega_n t)} \,\!
for some real amplitude coefficients An, and for continuous k the sum becomes an integral, the Fourier transform of a momentum space wavefunction:[29]
\Psi(\mathbf{r},t) = \frac{1}{(\sqrt{2\pi})^3}\int\Phi(\mathbf{k})e^{i(\mathbf{k}\cdot\mathbf{r}-\omega t)}d^3\mathbf{k} \,\!
where d3k = dkxdkydkz is the differential volume element in k-space, and the integrals are taken over all k-space. The momentum wavefunction Φ(k) arises in the integrand since the position and momentum space wavefunctions are Fourier transforms of each other.

Consistency with the De Broglie relations

Diagrammatic summary of the quantities related to the wavefunction, as used in De broglie's hypothesis and development of the Schrödinger equation.[26]

Einstein's light quanta hypothesis (1905) states that the energy E of a photon is proportional to the frequency ν (or angular frequency, ω = 2πν) of the corresponding quantum wavepacket of light:
E = h\nu = \hbar \omega \,\!
Likewise De Broglie's hypothesis (1924) states that any particle can be associated with a wave, and that the momentum p of the particle is inversely proportional to the wavelength λ of such a wave (or proportional to the wavenumber, k = 2π/λ), in one dimension, by:
p = \frac{h}{\lambda} = \hbar k\;,
while in three dimensions, wavelength λ is related to the magnitude of the wavevector k:
\mathbf{p} = \hbar \mathbf{k}\,,\quad |\mathbf{k}| = \frac{2\pi}{\lambda} \,.
The Planck–Einstein and de Broglie relations illuminate the deep connections between energy with time, and space with momentum, and express wave–particle duality. In practice, natural units comprising ħ = 1 are used, as the De Broglie equations reduce to identities: allowing momentum, wavenumber, energy and frequency to be used interchangeably, to prevent duplication of quantities, and reduce the number of dimensions of related quantities. For familiarity SI units are still used in this article.

Schrödinger's insight,[citation needed] late in 1925, was to express the phase of a plane wave as a complex phase factor using these relations:
\Psi = Ae^{i(\mathbf{k}\cdot\mathbf{r}-\omega t)} = Ae^{i(\mathbf{p}\cdot\mathbf{r}-Et)/\hbar}
and to realize that the first order partial derivatives with respect to space
\nabla\Psi = \dfrac{i}{\hbar}\mathbf{p}Ae^{i(\mathbf{p}\cdot\mathbf{r}-Et)/\hbar} = \dfrac{i}{\hbar}\mathbf{p}\Psi
and time
\dfrac{\partial \Psi}{\partial t} = -\dfrac{i E}{\hbar} Ae^{i(\mathbf{p}\cdot\mathbf{r}-Et)/\hbar} = -\dfrac{i E}{\hbar} \Psi
Another postulate of quantum mechanics is that all observables are represented by linear Hermitian operators which act on the wavefunction, and the eigenvalues of the operator are the values the observable takes. The previous derivatives are consistent with the energy operator, corresponding to the time derivative,
\hat{E} \Psi = i\hbar\dfrac{\partial}{\partial t}\Psi = E\Psi
where E are the energy eigenvalues, and the momentum operator, corresponding to the spatial derivatives (the gradient ∇),
\hat{\mathbf{p}} \Psi = -i\hbar\nabla \Psi = \mathbf{p} \Psi
where p is a vector of the momentum eigenvalues. In the above, the "hats" ( ^ ) indicate these observables are operators, not simply ordinary numbers or vectors. The energy and momentum operators are differential operators, while the potential energy function V is just a multiplicative factor.

Substituting the energy and momentum operators into the classical energy conservation equation obtains the operator:
E= \dfrac{\mathbf{p}\cdot\mathbf{p}}{2m}+V \quad \rightarrow \quad \hat{E} = \dfrac{\hat{\mathbf{p}}\cdot\hat{\mathbf{p}}}{2m} + V
so in terms of derivatives with respect to time and space, acting this operator on the wavefunction Ψ immediately led Schrödinger to his equation:[citation needed]
i\hbar\dfrac{\partial \Psi}{\partial t}= -\dfrac{\hbar^2}{2m}\nabla^2\Psi +V\Psi
Wave–particle duality can be assessed from these equations as follows. The kinetic energy T is related to the square of momentum p. As the particle's momentum increases, the kinetic energy increases more rapidly, but since the wavenumber |k| increases the wavelength λ decreases. In terms of ordinary scalar and vector quantities (not operators):
\mathbf{p}\cdot\mathbf{p} \propto \mathbf{k}\cdot\mathbf{k} \propto T \propto \dfrac{1}{\lambda^2}
The kinetic energy is also proportional to the second spatial derivatives, so it is also proportional to the magnitude of the curvature of the wave, in terms of operators:
\hat{T} \Psi = \frac{-\hbar^2}{2m}\nabla\cdot\nabla \Psi \, \propto \, \nabla^2 \Psi \,.
As the curvature increases, the amplitude of the wave alternates between positive and negative more rapidly, and also shortens the wavelength. So the inverse relation between momentum and wavelength is consistent with the energy the particle has, and so the energy of the particle has a connection to a wave, all in the same mathematical formulation.[26]

Wave and particle motion

Increasing levels of wavepacket localization, meaning the particle has a more localized position.
In the limit ħ → 0, the particle's position and momentum become known exactly. This is equivalent to the classical particle.


















Schrödinger required that a wave packet solution near position r with wavevector near k will move along the trajectory determined by classical mechanics for times short enough for the spread in k (and hence in velocity) not to substantially increase the spread in r. Since, for a given spread in k, the spread in velocity is proportional to Planck's constant ħ, it is sometimes said that in the limit as ħ approaches zero, the equations of classical mechanics are restored from quantum mechanics.[30] Great care is required in how that limit is taken, and in what cases.

The limiting short-wavelength is equivalent to ħ tending to zero because this is limiting case of increasing the wave packet localization to the definite position of the particle (see images right). Using the Heisenberg uncertainty principle for position and momentum, the products of uncertainty in position and momentum become zero as ħ → 0:
\sigma(x) \sigma(p_x) \geqslant \frac{\hbar}{2} \quad \rightarrow \quad \sigma(x) \sigma(p_x) \geqslant 0 \,\!
where σ denotes the (root mean square) measurement uncertainty in x and px (and similarly for the y and z directions) which implies the position and momentum can only be known to arbitrary precision in this limit.

The Schrödinger equation in its general form
i\hbar \frac{\partial}{\partial t} \Psi\left(\mathbf{r},t\right) = \hat{H} \Psi\left(\mathbf{r},t\right) \,\!
is closely related to the Hamilton–Jacobi equation (HJE)
\frac{\partial}{\partial t} S(q_i,t) = H\left(q_i,\frac{\partial S}{\partial q_i},t \right) \,\!
where S is action and H is the Hamiltonian function (not operator). Here the generalized coordinates qi for i = 1, 2, 3 (used in the context of the HJE) can be set to the position in Cartesian coordinates as r = (q1, q2, q3) = (x, y, z).[30]
Substituting
\Psi = \sqrt{\rho(\mathbf{r},t)} e^{iS(\mathbf{r},t)/\hbar}\,\!
where ρ is the probability density, into the Schrödinger equation and then taking the limit ħ → 0 in the resulting equation, yields the Hamilton–Jacobi equation.

The implications are:
  • The motion of a particle, described by a (short-wavelength) wave packet solution to the Schrödinger equation, is also described by the Hamilton–Jacobi equation of motion.
  • The Schrödinger equation includes the wavefunction, so its wave packet solution implies the position of a (quantum) particle is fuzzily spread out in wave fronts. On the contrary, the Hamilton–Jacobi equation applies to a (classical) particle of definite position and momentum, instead the position and momentum at all times (the trajectory) are deterministic and can be simultaneously known.

Non-relativistic quantum mechanics

The quantum mechanics of particles without accounting for the effects of special relativity, for example particles propagating at speeds much less than light, is known as non-relativistic quantum mechanics. Following are several forms of Schrödinger's equation in this context for different situations: time independence and dependence, one and three spatial dimensions, and one and N particles.

In actuality, the particles constituting the system do not have the numerical labels used in theory. The language of mathematics forces us to label the positions of particles one way or another, otherwise there would be confusion between symbols representing which variables are for which particle.[28]

Time independent

If the Hamiltonian is not an explicit function of time, the equation is separable into a product of spatial and temporal parts. In general, the wavefunction takes the form:
\Psi(\text{space coords},t)=\psi(\text{space coords})\tau(t)\,.
where ψ(space coords) is a function of all the spatial coordinate(s) of the particle(s) constituting the system only, and τ(t) is a function of time only.

Substituting for ψ into the Schrödinger equation for the relevant number of particles in the relevant number of dimensions, solving by separation of variables implies the general solution of the time-dependent equation has the form:[14]
\Psi(\text{space coords},t) = \psi(\text{space coords}) e^{-i{E t/\hbar}} \,.
Since the time dependent phase factor is always the same, only the spatial part needs to be solved for in time independent problems. Additionally, the energy operator Ê = iħ∂/∂t can always be replaced by the energy eigenvalue E, thus the time independent Schrödinger equation is an eigenvalue equation for the Hamiltonian operator:[5]:143ff
\hat{H} \psi = E \psi
This is true for any number of particles in any number of dimensions (in a time independent potential). This case describes the standing wave solutions of the time-dependent equation, which are the states with definite energy (instead of a probability distribution of different energies). In physics, these standing waves are called "stationary states" or "energy eigenstates"; in chemistry they are called "atomic orbitals" or "molecular orbitals". Superpositions of energy eigenstates change their properties according to the relative phases between the energy levels.

The energy eigenvalues from this equation form a discrete spectrum of values, so mathematically energy must be quantized. More specifically, the energy eigenstates form a basis – any wavefunction may be written as a sum over the discrete energy states or an integral over continuous energy states, or more generally as an integral over a measure. This is the spectral theorem in mathematics, and in a finite state space it is just a statement of the completeness of the eigenvectors of a Hermitian matrix.

One-dimensional examples

For a particle in one dimension, the Hamiltonian is:
\hat{H} = \frac{\hat{p}^2}{2m} + V(x) \,, \quad \hat{p} = -i\hbar \frac{d}{d x}
and substituting this into the general Schrödinger equation gives:
-\frac{\hbar^2}{2m}\frac{d^2}{d x^2}\psi(x) + V(x)\psi(x) = E\psi(x)
This is the only case the Schrödinger equation is an ordinary differential equation, rather than a partial differential equation. The general solutions are always of the form:
\Psi(x,t)=\psi(x) e^{-iEt/\hbar} \, .
For N particles in one dimension, the Hamiltonian is:
\hat{H} = \sum_{n=1}^{N}\frac{\hat{p}_n^2}{2m_n} + V(x_1,x_2,\cdots x_N) \,,\quad \hat{p}_n = -i\hbar \frac{\partial}{\partial x_n}
where the position of particle n is xn. The corresponding Schrödinger equation is:
-\frac{\hbar^2}{2}\sum_{n=1}^{N}\frac{1}{m_n}\frac{\partial^2}{\partial x_n^2}\psi(x_1,x_2,\cdots x_N) + V(x_1,x_2,\cdots x_N)\psi(x_1,x_2,\cdots x_N) = E\psi(x_1,x_2,\cdots x_N) \, .
so the general solutions have the form:
\Psi(x_1,x_2,\cdots x_N,t) = e^{-iEt/\hbar}\psi(x_1,x_2\cdots x_N)
For non-interacting distinguishable particles,[6](refactored from 458) the potential of the system only influences each particle separately, so the total potential energy is the sum of potential energies for each particle:
V(x_1,x_2,\cdots x_N) = \sum_{n=1}^N V(x_n) \, .
and the wavefunction can be written as a product of the wavefunctions for each particle:
\Psi(x_1,x_2,\cdots x_N,t) = e^{-i{E t/\hbar}}\prod_{n=1}^N\psi(x_n) \, ,
For non-interacting identical particles, the potential is still a sum, but wavefunction is a bit more complicated - it is a sum over the permutations of products of the separate wavefunctions to account for particle exchange. In general for interacting particles, the above decompositions are not possible.

Free particle

For no potential, V = 0, so the particle is free and the equation reads:[5]:151ff
- E \psi = \frac{\hbar^2}{2m}{d^2 \psi \over d x^2}\,
which has oscillatory solutions for E > 0 (the Cn are arbitrary constants):
\psi_E(x) = C_1 e^{i\sqrt{2mE/\hbar^2}\,x} + C_2 e^{-i\sqrt{2mE/\hbar^2}\,x}\,
and exponential solutions for E < 0
\psi_{-|E|}(x) = C_1 e^{\sqrt{2m|E|/\hbar^2}\,x} + C_2 e^{-\sqrt{2m|E|/\hbar^2}\,x}.\,
The exponentially growing solutions have an infinite norm, and are not physical. They are not allowed in a finite volume with periodic or fixed boundary conditions.

Constant potential

Animation of a de Broglie wave incident on a barrier.

For a constant potential, V = V0, the solution is oscillatory for E > V0 and exponential for E < V0, corresponding to energies that are allowed or disallowed in classical mechanics. Oscillatory solutions have a classically allowed energy and correspond to actual classical motions, while the exponential solutions have a disallowed energy and describe a small amount of quantum bleeding into the classically disallowed region, due to quantum tunneling. If the potential V0 grows to infinity, the motion is classically confined to a finite region. Viewed far enough away, every solution is reduced an exponential; the condition that the exponential is decreasing restricts the energy levels to a discrete set, called the allowed energies.[29]

Harmonic oscillator

A harmonic oscillator in classical mechanics (A–B) and quantum mechanics (C–H). In (A–B), a ball, attached to a spring, oscillates back and forth. (C–H) are six solutions to the Schrödinger Equation for this situation. The horizontal axis is position, the vertical axis is the real part (blue) or imaginary part (red) of the wavefunction. Stationary states, or energy eigenstates, which are solutions to the time-independent Schrödinger Equation, are shown in C,D,E,F, but not G or H.

The Schrödinger equation for this situation is
E\psi = -\frac{\hbar^2}{2m}\frac{d^2}{d x^2}\psi + \frac{1}{2}m\omega^2x^2\psi
It is a notable quantum system to solve for; since the solutions are exact (but complicated – in terms of Hermite polynomials), and it can describe or at least approximate a wide variety of other systems, including vibrating atoms, molecules,[31] and atoms or ions in lattices,[32] and approximating other potentials near equilibrium points. It is also the basis of perturbation methods in quantum mechanics.
There is a family of solutions – in the position basis they are
\psi_n(x) = \sqrt{\frac{1}{2^n\,n!}} \cdot \left(\frac{m\omega}{\pi \hbar}\right)^{1/4} \cdot e^{ - \frac{m\omega x^2}{2 \hbar}} \cdot H_n\left(\sqrt{\frac{m\omega}{\hbar}} x \right)
where n = 0,1,2,..., and the functions Hn are the Hermite polynomials.

Three-dimensional examples

The extension from one dimension to three dimensions is straightforward, all position and momentum operators are replaced by their three-dimensional expressions and the partial derivative with respect to space is replaced by the gradient operator.

The Hamiltonian for one particle in three dimensions is:
\hat{H} = \frac{\hat{\mathbf{p}}\cdot\hat{\mathbf{p}}}{2m} + V(\mathbf{r}) \,, \quad \hat{\mathbf{p}} = -i\hbar \nabla
generating the equation:
-\frac{\hbar^2}{2m}\nabla^2\psi(\mathbf{r}) + V(\mathbf{r})\psi(\mathbf{r}) = E\psi(\mathbf{r})
with stationary state solutions of the form:
\Psi(\mathbf{r},t) = \psi(\mathbf{r}) e^{-iEt/\hbar}
where the position of the particle is r. Two useful coordinate systems for solving the Schrödinger equation are Cartesian coordinates so that r = (x, y, z) and spherical polar coordinates so that r = (r, θ, φ), although other orthogonal coordinates are useful for solving the equation for systems with certain geometric symmetries.

For N particles in three dimensions, the Hamiltonian is:
\hat{H} = \sum_{n=1}^{N}\frac{\hat{\mathbf{p}}_n\cdot\hat{\mathbf{p}}_n}{2m_n} + V(\mathbf{r}_1,\mathbf{r}_2,\cdots\mathbf{r}_N) \,,\quad \hat{\mathbf{p}}_n = -i\hbar \nabla_n
where the position of particle n is rn and the gradient operators are partial derivatives with respect to the particle's position coordinates. In Cartesian coordinates, for particle n, the position vector is rn = (xn, yn, zn) while the gradient and Laplacian operator are respectively:
\nabla_n = \mathbf{e}_x \frac{\partial}{\partial x_n} + \mathbf{e}_y\frac{\partial}{\partial y_n} + \mathbf{e}_z\frac{\partial}{\partial z_n}\,,\quad \nabla_n^2 = \nabla_n\cdot\nabla_n = \frac{\partial^2}{{\partial x_n}^2} + \frac{\partial^2}{{\partial y_n}^2} + \frac{\partial^2}{{\partial z_n}^2}
The Schrödinger equation is:
-\frac{\hbar^2}{2}\sum_{n=1}^{N}\frac{1}{m_n}\nabla_n^2\Psi(\mathbf{r}_1,\mathbf{r}_2,\cdots\mathbf{r}_N) + V(\mathbf{r}_1,\mathbf{r}_2,\cdots\mathbf{r}_N)\Psi(\mathbf{r}_1,\mathbf{r}_2,\cdots\mathbf{r}_N) = E\Psi(\mathbf{r}_1,\mathbf{r}_2,\cdots\mathbf{r}_N)
with stationary state solutions:
\Psi(\mathbf{r}_1,\mathbf{r}_2\cdots \mathbf{r}_N,t) = e^{-iEt/\hbar}\psi(\mathbf{r}_1,\mathbf{r}_2\cdots \mathbf{r}_N)
Again, for non-interacting distinguishable particles the potential is the sum of particle potentials
V(\mathbf{r}_1,\mathbf{r}_2,\cdots \mathbf{r}_N) = \sum_{n=1}^N V(\mathbf{r}_n)
and the wavefunction is a product of the particle wavefuntions
\Psi(\mathbf{r}_1,\mathbf{r}_2\cdots \mathbf{r}_N,t) = e^{-i{E t/\hbar}}\prod_{n=1}^N\psi(\mathbf{r}_n) \, .
For non-interacting identical particles, the potential is a sum but the wavefunction is a sum over permutations of products. The previous two equations do not apply to interacting particles.

Following are examples where exact solutions are known. See the main articles for further details.

Hydrogen atom

This form of the Schrödinger equation can be applied to the hydrogen atom:[24][26]
E \psi = -\frac{\hbar^2}{2\mu}\nabla^2\psi - \frac{e^2}{4\pi\epsilon_0 r}\psi
where e is the electron charge, r is the position of the electron (r = |r| is the magnitude of the position), the potential term is due to the Coulomb interaction, wherein ε0 is the electric constant (permittivity of free space) and
\mu = \frac{m_em_p}{m_e+m_p}
is the 2-body reduced mass of the hydrogen nucleus (just a proton) of mass mp and the electron of mass me. The negative sign arises in the potential term since the proton and electron are oppositely charged. The reduced mass in place of the electron mass is used since the electron and proton together orbit each other about a common centre of mass, and constitute a two-body problem to solve. The motion of the electron is of principle interest here, so the equivalent one-body problem is the motion of the electron using the reduced mass.

The wavefunction for hydrogen is a function of the electron's coordinates, and in fact can be separated into functions of each coordinate.[33] Usually this is done in spherical polar coordinates:
\psi(r,\theta,\phi) = R(r)Y_\ell^m(\theta, \phi) = R(r)\Theta(\theta)\Phi(\phi)
where R are radial functions and \scriptstyle Y_{\ell}^{m}(\theta, \phi ) \, are spherical harmonics of degree ℓ and order m. This is the only atom for which the Schrödinger equation has been solved for exactly. Multi-electron atoms require approximative methods. The family of solutions are:[34]
\psi_{n\ell m}(r,\theta,\phi) = \sqrt {{\left ( \frac{2}{n a_0} \right )}^3\frac{(n-\ell-1)!}{2n[(n+\ell)!]} } e^{- r/na_0} \left(\frac{2r}{na_0}\right)^{\ell} L_{n-\ell-1}^{2\ell+1}\left(\frac{2r}{na_0}\right) \cdot Y_{\ell}^{m}(\theta, \phi )
where:
\begin{align} n & = 1,2,3, \dots \\ \ell & = 0,1,2, \dots, n-1 \\ m & = -\ell,\dots,\ell \\ \end{align}
NB: generalized Laguerre polynomials are defined differently by different authors—see main article on them and the hydrogen atom.

Two-electron atoms or ions

The equation for any two-electron system, such as the neutral helium atom (He, Z = 2), the negative hydrogen ion (H–, Z = 1), or the positive lithium ion (Li+, Z = 3) is:[27]
E\psi = -\hbar^2\left[\frac{1}{2\mu}\left(\nabla_1^2 +\nabla_2^2 \right) + \frac{1}{M}\nabla_1\cdot\nabla_2\right] \psi + \frac{e^2}{4\pi\epsilon_0}\left[ \frac{1}{r_{12}} -Z\left( \frac{1}{r_1}+\frac{1}{r_2} \right) \right] \psi
where r1 is the position of one electron (r1 = |r1| is its magnitude), r2 is the position of the other electron (r2 = |r2| is the magnitude), r12 = |r12| is the magnitude of the separation between them given by
|\mathbf{r}_{12}| = |\mathbf{r}_2 - \mathbf{r}_1 | \,\!
μ is again the two-body reduced mass of an electron with respect to the nucleus of mass M, so this time
\mu = \frac{m_e M}{m_e+M} \,\!
and Z is the atomic number for the element (not a quantum number).

The cross-term of two laplacians
\frac{1}{M}\nabla_1\cdot\nabla_2\,\!
is known as the mass polarization term, which arises due to the motion of atomic nuclei. The wavefunction is a function of the two electron's positions:
\psi = \psi(\mathbf{r}_1,\mathbf{r}_2).
There is no closed form solution for this equation.

Time dependent

This is the equation of motion for the quantum state. In the most general form, it is written:[5]:143ff
i \hbar \frac{\partial}{\partial t}\Psi = \hat H \Psi.
and the solution, the wavefunction, is a function of all the particle coordinates of the system and time. Following are specific cases.

For one particle in one dimension, the Hamiltonian
\hat{H} = \frac{\hat{p}^2}{2m} + V(x,t) \,,\quad \hat{p} = -i\hbar \frac{\partial}{\partial x}
generates the equation:
i\hbar\frac{\partial}{\partial t}\Psi(x,t) = -\frac{\hbar^2}{2m}\frac{\partial^2}{\partial x^2}\Psi(x,t) + V(x,t)\Psi(x,t)
For N particles in one dimension, the Hamiltonian is:
\hat{H} = \sum_{n=1}^{N}\frac{\hat{p}_n^2}{2m_n} + V(x_1,x_2,\cdots x_N,t) \,,\quad \hat{p}_n = -i\hbar \frac{\partial}{\partial x_n}
where the position of particle n is xn, generating the equation:
i\hbar\frac{\partial}{\partial t}\Psi(x_1,x_2\cdots x_N,t) = -\frac{\hbar^2}{2}\sum_{n=1}^{N}\frac{1}{m_n}\frac{\partial^2}{\partial x_n^2}\Psi(x_1,x_2\cdots x_N,t) + V(x_1,x_2\cdots x_N,t)\Psi(x_1,x_2\cdots x_N,t) \, .
For one particle in three dimensions, the Hamiltonian is:
\hat{H} = \frac{\hat{\mathbf{p}}\cdot\hat{\mathbf{p}}}{2m} + V(\mathbf{r},t) \,,\quad \hat{\mathbf{p}} = -i\hbar \nabla
generating the equation:
i\hbar\frac{\partial}{\partial t}\Psi(\mathbf{r},t) = -\frac{\hbar^2}{2m}\nabla^2\Psi(\mathbf{r},t) + V(\mathbf{r},t)\Psi(\mathbf{r},t)
For N particles in three dimensions, the Hamiltonian is:
\hat{H} = \sum_{n=1}^{N}\frac{\hat{\mathbf{p}}_n\cdot\hat{\mathbf{p}}_n}{2m_n} + V(\mathbf{r}_1,\mathbf{r}_2,\cdots\mathbf{r}_N,t)\,,\quad \hat{\mathbf{p}}_n = -i\hbar \nabla_n
where the position of particle n is rn, generating the equation:[5]:141
i\hbar\frac{\partial}{\partial t}\Psi(\mathbf{r}_1,\mathbf{r}_2,\cdots\mathbf{r}_N,t) = -\frac{\hbar^2}{2}\sum_{n=1}^{N}\frac{1}{m_n}\nabla_n^2\Psi(\mathbf{r}_1,\mathbf{r}_2,\cdots\mathbf{r}_N,t) + V(\mathbf{r}_1,\mathbf{r}_2,\cdots\mathbf{r}_N,t)\Psi(\mathbf{r}_1,\mathbf{r}_2,\cdots\mathbf{r}_N,t)
This last equation is in a very high dimension, so the solutions are not easy to visualize.

Solution methods

Properties

The Schrödinger equation has the following properties: some are useful, but there are shortcomings. Ultimately, these properties arise from the Hamiltonian used, and solutions to the equation.

Linearity

In the development above, the Schrödinger equation was made to be linear for generality, though this has other implications. If two wave functions ψ1 and ψ2 are solutions, then so is any linear combination of the two:
\displaystyle \psi = a\psi_1 + b \psi_2
where a and b are any complex numbers (the sum can be extended for any number of wavefunctions). This property allows superpositions of quantum states to be solutions of the Schrödinger equation.
Even more generally, it holds that a general solution to the Schrödinger equation can be found by taking a weighted sum over all single state solutions achievable. For example, consider a wave function Ψ(x, t) such that the wave function is a product of two functions: one time independent, and one time dependent. If states of definite energy found using the time independent Shrödinger equation are given by ψE(x) with amplitude An and time dependent phase factor is given by
e^{{-iE_n t}/\hbar},
then a valid general solution is
\displaystyle \Psi(x,t) = \sum\limits_{n} A_n \psi_{E_n}(x) e^{{-iE_n t}/\hbar}.
Additionally, the ability to scale solutions allows one to solve for a wave function without normalizing it first. If one has a set of normalized solutions ψn, then
\displaystyle \Psi = \sum\limits_{n} A_n \psi_n
can be normalized by ensuring that
\displaystyle \sum\limits_{n}|A_n|^2 = 1.
This is much more convenient than having to verify that
\displaystyle \int\limits_{-\infty}^{\infty}|\Psi(x)|^2\,dx = \int\limits_{-\infty}^{\infty}\Psi(x)\Psi^{*}(x)\,dx = 1.

Real energy eigenstates

For the time-independent equation, an additional feature of linearity follows: if two wave functions ψ1 and ψ2 are solutions to the time-independent equation with the same energy E, then so is any linear combination:
\hat H (a\psi_1 + b \psi_2 ) = a \hat H \psi_1 + b \hat H \psi_2 = E (a \psi_1 + b\psi_2).
Two different solutions with the same energy are called degenerate.[29]

In an arbitrary potential, if a wave function ψ solves the time-independent equation, so does its complex conjugate, denoted ψ*. By taking linear combinations, the real and imaginary parts of ψ are each solutions. If there is no degeneracy they can only differ by a factor.

In the time-dependent equation, complex conjugate waves move in opposite directions. If Ψ(x, t) is one solution, then so is Ψ(x, –t). The symmetry of complex conjugation is called time-reversal symmetry.

Space and time derivatives

Continuity of the wavefunction and its first spatial derivative (in the x direction, y and z coordinates not shown), at some time t.

The Schrödinger equation is first order in time and second in space, which describes the time evolution of a quantum state (meaning it determines the future amplitude from the present).

Explicitly for one particle in 3-dimensional Cartesian coordinates – the equation is
i\hbar{\partial \Psi \over \partial t} = - {\hbar^2\over 2m} \left ( {\partial^2 \Psi \over \partial x^2} + {\partial^2 \Psi \over \partial y^2} + {\partial^2 \Psi \over \partial z^2} \right ) + V(x,y,z,t)\Psi.\,\!
The first time partial derivative implies the initial value (at t = 0) of the wavefunction
\Psi(x,y,z,0) \,\!
is an arbitrary constant. Likewise – the second order derivatives with respect to space implies the wavefunction and its first order spatial derivatives
\begin{align} & \Psi(x_b,y_b,z_b,t) \\ & \frac{\partial}{\partial x}\Psi(x_b,y_b,z_b,t) \quad \frac{\partial}{\partial y}\Psi(x_b,y_b,z_b,t) \quad \frac{\partial}{\partial z}\Psi(x_b,y_b,z_b,t) \end{align} \,\!
are all arbitrary constants at a given set of points, where xb, yb, zb are a set of points describing boundary b (derivatives are evaluated at the boundaries). Typically there are one or two boundaries, such as the step potential and particle in a box respectively.

As the first order derivatives are arbitrary, the wavefunction can be a continuously differentiable function of space, since at any boundary the gradient of the wavefunction can be matched.

On the contrary, wave equations in physics are usually second order in time, notable are the family of classical wave equations and the quantum Klein–Gordon equation.

Local conservation of probability

The Schrödinger equation is consistent with probability conservation. Multiplying the Schrödinger equation on the right by the complex conjugate wavefunction, and multiplying the wavefunction to the left of the complex conjugate of the Schrödinger equation, and subtracting, gives the continuity equation for probability:[35]
{ \partial \over \partial t} \rho\left(\mathbf{r},t\right) + \nabla \cdot \mathbf{j} = 0,
where
\rho=|\Psi|^2=\Psi^*(\mathbf{r},t)\Psi(\mathbf{r},t)\,\!
is the probability density (probability per unit volume, * denotes complex conjugate), and
\mathbf{j} = {1 \over 2m} \left( \Psi^*\hat{\mathbf{p}}\Psi - \Psi\hat{\mathbf{p}}\Psi^* \right)\,\!
is the probability current (flow per unit area).

Hence predictions from the Schrödinger equation do not violate probability conservation.

Positive energy

If the potential is bounded from below, meaning there is a minimum value of potential energy, the eigenfunctions of the Schrödinger equation have energy which is also bounded from below. This can be seen most easily by using the variational principle, as follows. (See also below).

For any linear operator  bounded from below, the eigenvector with the smallest eigenvalue is the vector ψ that minimizes the quantity
\langle \psi |\hat{A}|\psi \rangle
over all ψ which are normalized.[35] In this way, the smallest eigenvalue is expressed through the variational principle. For the Schrödinger Hamiltonian Ĥ bounded from below, the smallest eigenvalue is called the ground state energy. That energy is the minimum value of
\langle \psi|\hat{H}|\psi\rangle = \int \psi^*(\mathbf{r}) \left[ - \frac{\hbar^2}{2m} \nabla^2\psi(\mathbf{r}) + V(\mathbf{r})\psi(\mathbf{r})\right] d^3\mathbf{r} = \int \left[ \frac{\hbar^2}{2m}|\nabla\psi|^2 + V(\mathbf{r}) |\psi|^2 \right] d^3\mathbf{r} = \langle \hat{H}\rangle
(using integration by parts). Due to the complex modulus of ψ squared (which is positive definite), the right hand side always greater than the lowest value of V(x). In particular, the ground state energy is positive when V(x) is everywhere positive.

For potentials which are bounded below and are not infinite over a region, there is a ground state which minimizes the integral above. This lowest energy wavefunction is real and positive definite – meaning the wavefunction can increase and decrease, but is positive for all positions. It physically cannot be negative: if it were, smoothing out the bends at the sign change (to minimize the wavefunction) rapidly reduces the gradient contribution to the integral and hence the kinetic energy, while the potential energy changes linearly and less quickly. The kinetic and potential energy are both changing at different rates, so the total energy is not constant, which can't happen (conservation). The solutions are consistent with Schrödinger equation if this wavefunction is positive definite.

The lack of sign changes also shows that the ground state is nondegenerate, since if there were two ground states with common energy E, not proportional to each other, there would be a linear combination of the two that would also be a ground state resulting in a zero solution.

Analytic continuation to diffusion

The above properties (positive definiteness of energy) allow the analytic continuation of the Schrödinger equation to be identified as a stochastic process. This can be interpreted as the Huygens–Fresnel principle applied to De Broglie waves; the spreading wavefronts are diffusive probability amplitudes.[35]
For a particle in a random walk (again for which V = 0), the continuation is to let:[36]
\tau = it \,, \!
substituting into the time-dependent Schrödinger equation gives:
{\partial \over \partial \tau} \Psi(\mathbf{r},\tau) = \frac{\hbar}{2m} \nabla ^2 \Psi(\mathbf{r},\tau),
which has the same form as the diffusion equation, with diffusion coefficient ħ/2m.

Relativistic quantum mechanics

Relativistic quantum mechanics is obtained where quantum mechanics and special relativity simultaneously apply. The general form of the Schrödinger equation is still applicable, but the Hamiltonian operators are much less obvious, and more complicated.

One wishes to build relativistic wave equations from the relativistic energy–momentum relation
E^2 = (pc)^2 + (m_0c^2)^2 \, ,
instead of classical energy equations. The Klein–Gordon equation and the Dirac equation are two such equations. The Klein–Gordon equation was the first such equation to be obtained, even before the non-relativistic one, and applies to massive spinless particles. The Dirac equation arose from taking the "square root" of the Klein–Gordon equation by factorizing the entire relativistic wave operator into a product of two operators – one of these is the operator for the entire Dirac equation.
The Dirac equation introduces spin matrices, in the particular case of the Dirac equation they are the gamma matrices for spin-1/2 particles, and the solutions are 4-component spinor fields with two components corresponding to the particle and the other two for the antiparticle. In general, the Hamiltonian to be substituted in the general Schrödinger equation is not just a function of position and momentum operators, but also of spin matrices. Also, the solutions to a relativistic wave equation, for a massive particle of spin s, are complex-valued 2(2s + 1)-component spinor fields.

Quantum field theory

The general equation is also valid and used in quantum field theory, both in relativistic and non-relativistic situations. However, the solution ψ is no longer interpreted as a "wave", but more like a "field".
at

Matter wave

Matter wave

From Wikipedia, the free encyclopedia

This article is about the quantum mechanical concept wave-particle duality. For the ordinary type of wave propagating through material media, see Mechanical wave.

In quantum mechanics, the concept of matter waves or de Broglie waves /dəˈbrɔɪ/ reflects the wave–particle duality of matter. The theory was proposed by Louis de Broglie in 1924 in his PhD thesis.[1] The de Broglie relations show that the wavelength is inversely proportional to the momentum of a particle and is also called de Broglie wavelength. Also the frequency of matter waves, as deduced by de Broglie, is directly proportional to the total energy E (sum of its rest energy and the kinetic energy) of a particle.[2]

Historical context

Propagation of de Broglie waves in 1d – real part of the complex amplitude is blue, imaginary part is green. The probability (shown as the colour opacity) of finding the particle at a given point x is spread out like a waveform, there is no definite position of the particle. As the amplitude increases above zero the curvature decreases, so the amplitude decreases again, and vice versa – the result is an alternating amplitude: a wave. Top: plane wave. Bottom: wave packet.

At the end of the 19th century, light was thought to consist of waves of electromagnetic fields which propagated according to Maxwell’s equations, while matter was thought to consist of localized particles (See history of wave and particle viewpoints). This division was challenged when, in his 1905 paper on the photoelectric effect, Albert Einstein postulated that light was emitted and absorbed as localized packets, or "quanta" (light quanta are now called photons). These quanta would have an energy
E=h\nu
where \scriptstyle \nu is the frequency of the light and h is Planck’s constant. In the modern convention, frequency is symbolized by f as is done in the rest of this article. Einstein’s postulate was confirmed experimentally by Robert Millikan and Arthur Compton over the next two decades. Thus it became apparent that light has both wave-like and particle-like properties. De Broglie, in his 1924 PhD thesis, sought to expand this wave-particle duality to all particles:


In 1926, Erwin Schrödinger published an equation describing how a matter wave should evolve—the matter wave analogue of Maxwell’s equations—and used it to derive the energy spectrum of hydrogen. Schrödinger's equation describes a wave that moves with respect to an abstract mathematical "space", called phase space, or, more precisely the configuration space, not the same thing as ordinary physical space.[4] That same year Max Born published his now-standard interpretation that the square of the amplitude of the matter wave gives the probability of finding the particle at a given place in ordinary physical space. This interpretation was in contrast to De Broglie’s own interpretation, in which the wave corresponds to the physical motion of a localized particle.

Experimental confirmation

Matter waves were first experimentally confirmed to occur in the Davisson-Germer experiment for electrons, and the de Broglie hypothesis has been confirmed for other elementary particles.
Furthermore, neutral atoms and even molecules have been shown to be wave-like.

Electrons

In 1927 at Bell Labs, Clinton Davisson and Lester Germer fired slow-moving electrons at a crystalline nickel target. The angular dependence of the reflected electron intensity was measured, and was determined to have the same diffraction pattern as those predicted by Bragg for x-rays.
Before the acceptance of the de Broglie hypothesis, diffraction was a property that was thought to be only exhibited by waves. Therefore, the presence of any diffraction effects by matter demonstrated the wave-like nature of matter. When the de Broglie wavelength was inserted into the Bragg condition, the observed diffraction pattern was predicted, thereby experimentally confirming the de Broglie hypothesis for electrons.[5]

This was a pivotal result in the development of quantum mechanics. Just as the photoelectric effect demonstrated the particle nature of light, the Davisson–Germer experiment showed the wave-nature of matter, and completed the theory of wave-particle duality. For physicists this idea was important because it means that not only can any particle exhibit wave characteristics, but that one can use wave equations to describe phenomena in matter if one uses the de Broglie wavelength.

Neutral atoms

Experiments with Fresnel diffraction[6] and an atomic mirror for specular reflection[7][8] of neutral atoms confirm the application of the de Broglie hypothesis to atoms, i.e. the existence of atomic waves which undergo diffraction, interference and allow quantum reflection by the tails of the attractive potential.[9] Advances in laser cooling have allowed cooling of neutral atoms down to nanokelvin temperatures. At these temperatures, the thermal de Broglie wavelengths come into the micrometre range. Using Bragg diffraction of atoms and a Ramsey interferometry technique, the de Broglie wavelength of cold sodium atoms was explicitly measured and found to be consistent with the temperature measured by a different method.[10]
This effect has been used to demonstrate atomic holography, and it may allow the construction of an atom probe imaging system with nanometer resolution.[11][12] The description of these phenomena is based on the wave properties of neutral atoms, confirming the de Broglie hypothesis.

The effect has also been used to explain the spatial version of the quantum Zeno effect, in which an otherwise unstable object may be stabilised by rapidly-repeated observations.[8]

Molecules

Recent experiments even confirm the relations for molecules and even macromolecules, which are normally considered too large to undergo quantum mechanical effects. In 1999, a research team in Vienna demonstrated diffraction for molecules as large as fullerenes.[13] The researchers calculated a De Broglie wavelength of the most probable C60 velocity as 2.5 pm. More recent experiments prove the quantum nature of molecules with a mass up to 6910 amu.[14]

de Broglie relations

The de Broglie equations relate the wavelength λ to the momentum p, and frequency f to the total energy E of a particle:[2]
\begin{align} & \lambda = h/p\\ & f = E/h \end{align}
where h is Planck's constant. The equation can also be written as
\begin{align} & \mathbf p = \hbar \mathbf k\\ & E = \hbar \omega\\ \end{align}
where \hbar is the reduced Planck's constant, \mathbf k is the wave vector, and \omega is the angular frequency.
In each pair, the second is also referred to as the Planck-Einstein relation, since it was also proposed by Planck and Einstein.

Special relativity

Using two formulas from special relativity, one for the relativistic momentum and one for the energy
p = \gamma m_0v
E = m c^2 = \gamma m_0 c^2
allows the equations to be written as[1][15][16][17]
\begin{align}&\lambda =\,\, \frac {h}{\gamma m_0v}\, =\, \frac {h}{m_0v}\,\,\,\, \sqrt{1 - \frac{v^2}{c^2}}\\ & f = \frac{\gamma\,m_0c^2}{h} = \frac {m_0c^2}{h} \bigg/ \sqrt{1 - \frac{v^2}{c^2}} \end{align}
where m_0 denotes the particle's rest mass, v its velocity, \gamma the Lorentz factor, and c the speed of light in a vacuum. See below for details of the derivation of the de Broglie relations. Group velocity (equal to the particle's speed) should not be confused with phase velocity (equal to the product of the particle's frequency and its wavelength). In the case of a non-dispersive medium, they happen to be equal, but otherwise they are not.

Group velocity

Albert Einstein first explained the wave–particle duality of light in 1905. Louis de Broglie hypothesized that any particle should also exhibit such a duality. The velocity of a particle, he concluded then (but may be questioned today, see above), should always equal the group velocity of the corresponding wave. De Broglie deduced that if the duality equations already known for light were the same for any particle, then his hypothesis would hold. This means that
v_g = \frac{\partial \omega}{\partial k} = \frac{\partial (E/\hbar)}{\partial (p/\hbar)} = \frac{\partial E}{\partial p}
where E is the total energy of the particle, p is its momentum, ħ is the reduced Planck constant. For a free non-relativistic particle it follows that
\begin{align} v_g &= \frac{\partial E}{\partial p} = \frac{\partial}{\partial p} \left( \frac{1}{2}\frac{p^2}{m} \right)\\ &= \frac{p}{m}\\ &= v \end{align}
where m is the mass of the particle and v its velocity.

Also in special relativity we find that
\begin{align} v_g &= \frac{\partial E}{\partial p} = \frac{\partial}{\partial p} \left( \sqrt{p^2c^2+m_0^2c^4} \right)\\ &= \frac{pc^2}{\sqrt{p^2c^2 + m_0^2c^4}}\\ &= \frac{pc^2}{E} \end{align}
where m_0 is the rest mass of the particle and c is the speed of light in a vacuum. But (see below), using that the phase velocity is v_p=E/p=c^2/v, therefore
\begin{align} v_g &= \frac{pc^2}{E}\\ &= \frac{c^2}{v_p}\\ &= v \end{align}
where v is the velocity of the particle regardless of wave behavior.

Group velocity (equal to an electron's speed) should not be confused with phase velocity (equal to the product of the electron's frequency multiplied by its wavelength).

Both in relativistic and non-relativistic quantum physics, we can identify the group velocity of a particle's wave function with the particle velocity. Quantum mechanics has very accurately demonstrated this hypothesis, and the relation has been shown explicitly for particles as large as molecules.[citation needed]

Phase velocity

In quantum mechanics, particles also behave as waves with complex phases. By the de Broglie hypothesis, we see that
v_\mathrm{p} = \frac{\omega}{k} = \frac{E/\hbar}{p/\hbar} = \frac{E}{p}.
Using relativistic relations for energy and momentum, we have
v_\mathrm{p} = \frac{E}{p} = \frac{\gamma m_0 c^2}{\gamma m_0 v} = \frac{c^2}{v} = \frac{c}{\beta}
where E is the total energy of the particle (i.e. rest energy plus kinetic energy in kinematic sense), p the momentum, \gamma the Lorentz factor, c the speed of light, and β the speed as a fraction of c. The variable v can either be taken to be the speed of the particle or the group velocity of the corresponding matter wave. Since the particle speed v < c for any particle that has mass (according to special relativity), the phase velocity of matter waves always exceeds c, i.e.
v_\mathrm{p} > c, \,
and as we can see, it approaches c when the particle speed is in the relativistic range. The superluminal phase velocity does not violate special relativity, because phase propagation carries no energy. See the article on Dispersion (optics) for details.

Four-vectors

Using the four-momentum P = (E/c, p) and the four-wavevector K = (ω/c, k), the De Broglie relations form a single equation:
\mathbf{P}= \hbar\mathbf{K}
which is frame-independent.
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