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Friday, January 4, 2019

Geology (updated)

From Wikipedia, the free encyclopedia

Geology (from the Ancient Greek γῆ, ("earth") and -λoγία, -logia, ("study of", "discourse")) is an earth science concerned with the solid Earth, the rocks of which it is composed, and the processes by which they change over time. Geology can also refer to the study of the solid features of any terrestrial planet or natural satellite such as Mars or the Moon. Modern geology significantly overlaps all other earth sciences, including hydrology and the atmospheric sciences, and so is treated as one major aspect of integrated earth system science and planetary science
 
1875 geological map of Europe, compiled by the Belgian geologist André Dumont. Colors indicate the distribution of different rock types across the continent, as they were known then.

Geology describes the structure of the Earth beneath its surface, and the processes that have shaped that structure. It also provides tools to determine the relative and absolute ages of rocks found in a given location, and also to describe the histories of those rocks. By combining these tools, geologists are able to chronicle the geological history of the Earth as a whole, and also to demonstrate the age of the Earth. Geology provides the primary evidence for plate tectonics, the evolutionary history of life, and the Earth's past climates

Geologists use a wide variety of methods to understand the Earth's structure and evolution, including field work, rock description, geophysical techniques, chemical analysis, physical experiments, and numerical modelling. In practical terms, geology is important for mineral and hydrocarbon exploration and exploitation, evaluating water resources, understanding of natural hazards, the remediation of environmental problems, and providing insights into past climate change. Geology, a major academic discipline, also plays a role in geotechnical engineering.

Geologic materials

The majority of geological data comes from research on solid Earth materials. These typically fall into one of two categories: rock and unconsolidated material.

Rock

This schematic diagram of the rock cycle shows the relationship between magma and sedimentary, metamorphic, and igneous rock

The majority of research in geology is associated with the study of rock, as rock provides the primary record of the majority of the geologic history of the Earth. There are three major types of rock: igneous, sedimentary, and metamorphic. The rock cycle illustrates the relationships among them (see diagram). 

When a rock crystallizes from melt (magma or lava), it is an igneous rock. This rock can be weathered and eroded, then redeposited and lithified into a sedimentary rock. It can then be turned into a metamorphic rock by heat and pressure that change its mineral content, resulting in a characteristic fabric. All three types may melt again, and when this happens, new magma is formed, from which an igneous rock may once more crystallize. 

Minerals

Tests

To study all three types of rock, geologists evaluate the minerals of which they are composed. Each mineral has distinct physical properties, and there are many tests to determine each of them. The specimens can be tested for:
  • Luster: Measurement of the amount of light reflected from the surface. Luster is broken into metallic and nonmetallic.
  • Color: Minerals are grouped by their color. Mostly diagnostic but impurities can change a mineral’s color.
  • Streak: Performed by scratching the sample on a porcelain plate. The color of the streak can help name the mineral.
  • Hardness: The resistance of a mineral to scratch.
  • Breakage pattern: A mineral can either show fracture or cleavage, the former being breakage of uneven surfaces and the latter a breakage along closely spaced parallel planes.
  • Specific gravity: the weight of a specific volume of a mineral.
  • Effervescence: Involves dripping hydrochloric acid on the mineral to test for fizzing.
  • Magnetism: Involves using a magnet to test for magnetism.
  • Taste: Minerals can have a distinctive taste, like halite (which tastes like table salt).
  • Smell: Minerals can have a distinctive odor. For example, sulfur smells like rotten eggs.

Unconsolidated material

Geologists also study unlithified materials (referred to as drift), which typically come from more recent deposits. These materials are superficial deposits that lie above the bedrock. This study is often known as Quaternary geology, after the Quaternary period of geologic history.

Whole-Earth structure

Plate tectonics

Oceanic-continental convergence resulting in subduction and volcanic arcs illustrates one effect of plate tectonics.
 
In the 1960s, it was discovered that the Earth's lithosphere, which includes the crust and rigid uppermost portion of the upper mantle, is separated into tectonic plates that move across the plastically deforming, solid, upper mantle, which is called the asthenosphere. This theory is supported by several types of observations, including seafloor spreading and the global distribution of mountain terrain and seismicity. 

There is an intimate coupling between the movement of the plates on the surface and the convection of the mantle (that is, the heat transfer caused by bulk movement of molecules within fluids). Thus, oceanic plates and the adjoining mantle convection currents always move in the same direction – because the oceanic lithosphere is actually the rigid upper thermal boundary layer of the convecting mantle. This coupling between rigid plates moving on the surface of the Earth and the convecting mantle is called plate tectonics. 

In this diagram, subducting slabs are in blue and continental margins and a few plate boundaries are in red. The blue blob in the cutaway section is the seismically imaged Farallon Plate, which is subducting beneath North America. The remnants of this plate on the surface of the Earth are the Juan de Fuca Plate and Explorer Plate, both in the northwestern United States and southwestern Canada, and the Cocos Plate on the west coast of Mexico.
 
The development of plate tectonics has provided a physical basis for many observations of the solid Earth. Long linear regions of geologic features are explained as plate boundaries. For example:
Transform boundaries, such as the San Andreas Fault system, resulted in widespread powerful earthquakes. Plate tectonics also has provided a mechanism for Alfred Wegener's theory of continental drift, in which the continents move across the surface of the Earth over geologic time. They also provided a driving force for crustal deformation, and a new setting for the observations of structural geology. The power of the theory of plate tectonics lies in its ability to combine all of these observations into a single theory of how the lithosphere moves over the convecting mantle.

Earth structure

The Earth's layered structure. (1) inner core; (2) outer core; (3) lower mantle; (4) upper mantle; (5) lithosphere; (6) crust (part of the lithosphere)
 
Earth layered structure. Typical wave paths from earthquakes like these gave early seismologists insights into the layered structure of the Earth
 
Advances in seismology, computer modeling, and mineralogy and crystallography at high temperatures and pressures give insights into the internal composition and structure of the Earth. 

Seismologists can use the arrival times of seismic waves in reverse to image the interior of the Earth. Early advances in this field showed the existence of a liquid outer core (where shear waves were not able to propagate) and a dense solid inner core. These advances led to the development of a layered model of the Earth, with a crust and lithosphere on top, the mantle below (separated within itself by seismic discontinuities at 410 and 660 kilometers), and the outer core and inner core below that. More recently, seismologists have been able to create detailed images of wave speeds inside the earth in the same way a doctor images a body in a CT scan. These images have led to a much more detailed view of the interior of the Earth, and have replaced the simplified layered model with a much more dynamic model. 

Mineralogists have been able to use the pressure and temperature data from the seismic and modelling studies alongside knowledge of the elemental composition of the Earth to reproduce these conditions in experimental settings and measure changes in crystal structure. These studies explain the chemical changes associated with the major seismic discontinuities in the mantle and show the crystallographic structures expected in the inner core of the Earth.

Geologic time

The geologic time scale encompasses the history of the Earth. It is bracketed at the earliest by the dates of the first Solar System material at 4.567 Ga (or 4.567 billion years ago) and the formation of the Earth at 4.54 Ga (4.54 billion years), which is the beginning of the informally recognized Hadean eon – a division of geologic time. At the later end of the scale, it is marked by the present day (in the Holocene epoch).

Time scale

The following four timelines show the geologic time scale. The first shows the entire time from the formation of the Earth to the present, but this gives little space for the most recent eon. Therefore, the second timeline shows an expanded view of the most recent eon. In a similar way, the most recent era is expanded in the third timeline, and the most recent period is expanded in the fourth timeline. 

SiderianRhyacianOrosirianStatherianCalymmianEctasianStenianTonianCryogenianEdiacaranEoarcheanPaleoarcheanMesoarcheanNeoarcheanPaleoproterozoicMesoproterozoicNeoproterozoicPaleozoicMesozoicCenozoicHadeanArcheanProterozoicPhanerozoicPrecambrian
CambrianOrdovicianSilurianDevonianCarboniferousPermianTriassicJurassicCretaceousPaleogeneNeogeneQuaternaryPaleozoicMesozoicCenozoicPhanerozoic
PaleoceneEoceneOligoceneMiocenePliocenePleistoceneHolocenePaleogeneNeogeneQuaternaryCenozoic
GelasianCalabrian (stage)PleistocenePleistocenePleistoceneHoloceneQuaternary
Millions of Years

Important milestones

Geological time put in a diagram called a geological clock, showing the relative lengths of the eons of the Earth's history.

Dating methods

Relative dating

Cross-cutting relations can be used to determine the relative ages of rock strata and other geological structures. Explanations: A – folded rock strata cut by a thrust fault; B – large intrusion (cutting through A); C – erosional angular unconformity (cutting off A & B) on which rock strata were deposited; D – volcanic dyke (cutting through A, B & C); E – even younger rock strata (overlying C & D); F – normal fault (cutting through A, B, C & E).
 
Methods for relative dating were developed when geology first emerged as a natural science. Geologists still use the following principles today as a means to provide information about geologic history and the timing of geologic events. 

The principle of uniformitarianism states that the geologic processes observed in operation that modify the Earth's crust at present have worked in much the same way over geologic time. A fundamental principle of geology advanced by the 18th century Scottish physician and geologist James Hutton is that "the present is the key to the past." In Hutton's words: "the past history of our globe must be explained by what can be seen to be happening now."

The principle of intrusive relationships concerns crosscutting intrusions. In geology, when an igneous intrusion cuts across a formation of sedimentary rock, it can be determined that the igneous intrusion is younger than the sedimentary rock. Different types of intrusions include stocks, laccoliths, batholiths, sills and dikes

The principle of cross-cutting relationships pertains to the formation of faults and the age of the sequences through which they cut. Faults are younger than the rocks they cut; accordingly, if a fault is found that penetrates some formations but not those on top of it, then the formations that were cut are older than the fault, and the ones that are not cut must be younger than the fault. Finding the key bed in these situations may help determine whether the fault is a normal fault or a thrust fault.

The principle of inclusions and components states that, with sedimentary rocks, if inclusions (or clasts) are found in a formation, then the inclusions must be older than the formation that contains them. For example, in sedimentary rocks, it is common for gravel from an older formation to be ripped up and included in a newer layer. A similar situation with igneous rocks occurs when xenoliths are found. These foreign bodies are picked up as magma or lava flows, and are incorporated, later to cool in the matrix. As a result, xenoliths are older than the rock that contains them. 

The Permian through Jurassic stratigraphy of the Colorado Plateau area of southeastern Utah is an example of both original horizontality and the law of superposition. These strata make up much of the famous prominent rock formations in widely spaced protected areas such as Capitol Reef National Park and Canyonlands National Park. From top to bottom: Rounded tan domes of the Navajo Sandstone, layered red Kayenta Formation, cliff-forming, vertically jointed, red Wingate Sandstone, slope-forming, purplish Chinle Formation, layered, lighter-red Moenkopi Formation, and white, layered Cutler Formation sandstone. Picture from Glen Canyon National Recreation Area, Utah.
 
The principle of original horizontality states that the deposition of sediments occurs as essentially horizontal beds. Observation of modern marine and non-marine sediments in a wide variety of environments supports this generalization (although cross-bedding is inclined, the overall orientation of cross-bedded units is horizontal).

The principle of superposition states that a sedimentary rock layer in a tectonically undisturbed sequence is younger than the one beneath it and older than the one above it. Logically a younger layer cannot slip beneath a layer previously deposited. This principle allows sedimentary layers to be viewed as a form of vertical time line, a partial or complete record of the time elapsed from deposition of the lowest layer to deposition of the highest bed.

The principle of faunal succession is based on the appearance of fossils in sedimentary rocks. As organisms exist during the same period throughout the world, their presence or (sometimes) absence provides a relative age of the formations where they appear. Based on principles that William Smith laid out almost a hundred years before the publication of Charles Darwin's theory of evolution, the principles of succession developed independently of evolutionary thought. The principle becomes quite complex, however, given the uncertainties of fossilization, localization of fossil types due to lateral changes in habitat (facies change in sedimentary strata), and that not all fossils formed globally at the same time.

Absolute dating

Geologists also use methods to determine the absolute age of rock samples and geological events. These dates are useful on their own and may also be used in conjunction with relative dating methods or to calibrate relative methods.

At the beginning of the 20th century, advancement in geological science was facilitated by the ability to obtain accurate absolute dates to geologic events using radioactive isotopes and other methods. This changed the understanding of geologic time. Previously, geologists could only use fossils and stratigraphic correlation to date sections of rock relative to one another. With isotopic dates, it became possible to assign absolute ages to rock units, and these absolute dates could be applied to fossil sequences in which there was datable material, converting the old relative ages into new absolute ages.

For many geologic applications, isotope ratios of radioactive elements are measured in minerals that give the amount of time that has passed since a rock passed through its particular closure temperature, the point at which different radiometric isotopes stop diffusing into and out of the crystal lattice. These are used in geochronologic and thermochronologic studies. Common methods include uranium-lead dating, potassium-argon dating, argon-argon dating and uranium-thorium dating. These methods are used for a variety of applications. Dating of lava and volcanic ash layers found within a stratigraphic sequence can provide absolute age data for sedimentary rock units that do not contain radioactive isotopes and calibrate relative dating techniques. These methods can also be used to determine ages of pluton emplacement. Thermochemical techniques can be used to determine temperature profiles within the crust, the uplift of mountain ranges, and paleotopography. 

Fractionation of the lanthanide series elements is used to compute ages since rocks were removed from the mantle. 

Other methods are used for more recent events. Optically stimulated luminescence and cosmogenic radionuclide dating are used to date surfaces and/or erosion rates. Dendrochronology can also be used for the dating of landscapes. Radiocarbon dating is used for geologically young materials containing organic carbon.

Geological development of an area

An originally horizontal sequence of sedimentary rocks (in shades of tan) are affected by igneous activity. Deep below the surface are a magma chamber and large associated igneous bodies. The magma chamber feeds the volcano, and sends offshoots of magma that will later crystallize into dikes and sills. Magma also advances upwards to form intrusive igneous bodies. The diagram illustrates both a cinder cone volcano, which releases ash, and a composite volcano, which releases both lava and ash.
 
An illustration of the three types of faults.
A. Strike-slip faults occur when rock units slide past one another.
B. Normal faults occur when rocks are undergoing horizontal extension.
C. Reverse (or thrust) faults occur when rocks are undergoing horizontal shortening.
 
The geology of an area changes through time as rock units are deposited and inserted, and deformational processes change their shapes and locations. 

Rock units are first emplaced either by deposition onto the surface or intrusion into the overlying rock. Deposition can occur when sediments settle onto the surface of the Earth and later lithify into sedimentary rock, or when as volcanic material such as volcanic ash or lava flows blanket the surface. Igneous intrusions such as batholiths, laccoliths, dikes, and sills, push upwards into the overlying rock, and crystallize as they intrude. 

After the initial sequence of rocks has been deposited, the rock units can be deformed and/or metamorphosed. Deformation typically occurs as a result of horizontal shortening, horizontal extension, or side-to-side (strike-slip) motion. These structural regimes broadly relate to convergent boundaries, divergent boundaries, and transform boundaries, respectively, between tectonic plates. 

When rock units are placed under horizontal compression, they shorten and become thicker. Because rock units, other than muds, do not significantly change in volume, this is accomplished in two primary ways: through faulting and folding. In the shallow crust, where brittle deformation can occur, thrust faults form, which causes deeper rock to move on top of shallower rock. Because deeper rock is often older, as noted by the principle of superposition, this can result in older rocks moving on top of younger ones. Movement along faults can result in folding, either because the faults are not planar or because rock layers are dragged along, forming drag folds as slip occurs along the fault. Deeper in the Earth, rocks behave plastically and fold instead of faulting. These folds can either be those where the material in the center of the fold buckles upwards, creating "antiforms", or where it buckles downwards, creating "synforms". If the tops of the rock units within the folds remain pointing upwards, they are called anticlines and synclines, respectively. If some of the units in the fold are facing downward, the structure is called an overturned anticline or syncline, and if all of the rock units are overturned or the correct up-direction is unknown, they are simply called by the most general terms, antiforms and synforms. 

A diagram of folds, indicating an anticline and a syncline.
 
Even higher pressures and temperatures during horizontal shortening can cause both folding and metamorphism of the rocks. This metamorphism causes changes in the mineral composition of the rocks; creates a foliation, or planar surface, that is related to mineral growth under stress. This can remove signs of the original textures of the rocks, such as bedding in sedimentary rocks, flow features of lavas, and crystal patterns in crystalline rocks

Extension causes the rock units as a whole to become longer and thinner. This is primarily accomplished through normal faulting and through the ductile stretching and thinning. Normal faults drop rock units that are higher below those that are lower. This typically results in younger units ending up below older units. Stretching of units can result in their thinning. In fact, at one location within the Maria Fold and Thrust Belt, the entire sedimentary sequence of the Grand Canyon appears over a length of less than a meter. Rocks at the depth to be ductilely stretched are often also metamorphosed. These stretched rocks can also pinch into lenses, known as boudins, after the French word for "sausage" because of their visual similarity.

Where rock units slide past one another, strike-slip faults develop in shallow regions, and become shear zones at deeper depths where the rocks deform ductilely.

Geologic cross section of Kittatinny Mountain. This cross section shows metamorphic rocks, overlain by younger sediments deposited after the metamorphic event. These rock units were later folded and faulted during the uplift of the mountain.
 
The addition of new rock units, both depositionally and intrusively, often occurs during deformation. Faulting and other deformational processes result in the creation of topographic gradients, causing material on the rock unit that is increasing in elevation to be eroded by hillslopes and channels. These sediments are deposited on the rock unit that is going down. Continual motion along the fault maintains the topographic gradient in spite of the movement of sediment, and continues to create accommodation space for the material to deposit. Deformational events are often also associated with volcanism and igneous activity. Volcanic ashes and lavas accumulate on the surface, and igneous intrusions enter from below. Dikes, long, planar igneous intrusions, enter along cracks, and therefore often form in large numbers in areas that are being actively deformed. This can result in the emplacement of dike swarms, such as those that are observable across the Canadian shield, or rings of dikes around the lava tube of a volcano. 

All of these processes do not necessarily occur in a single environment, and do not necessarily occur in a single order. The Hawaiian Islands, for example, consist almost entirely of layered basaltic lava flows. The sedimentary sequences of the mid-continental United States and the Grand Canyon in the southwestern United States contain almost-undeformed stacks of sedimentary rocks that have remained in place since Cambrian time. Other areas are much more geologically complex. In the southwestern United States, sedimentary, volcanic, and intrusive rocks have been metamorphosed, faulted, foliated, and folded. Even older rocks, such as the Acasta gneiss of the Slave craton in northwestern Canada, the oldest known rock in the world have been metamorphosed to the point where their origin is undiscernable without laboratory analysis. In addition, these processes can occur in stages. In many places, the Grand Canyon in the southwestern United States being a very visible example, the lower rock units were metamorphosed and deformed, and then deformation ended and the upper, undeformed units were deposited. Although any amount of rock emplacement and rock deformation can occur, and they can occur any number of times, these concepts provide a guide to understanding the geological history of an area.

Methods of geology

Geologists use a number of field, laboratory, and numerical modeling methods to decipher Earth history and to understand the processes that occur on and inside the Earth. In typical geological investigations, geologists use primary information related to petrology (the study of rocks), stratigraphy (the study of sedimentary layers), and structural geology (the study of positions of rock units and their deformation). In many cases, geologists also study modern soils, rivers, landscapes, and glaciers; investigate past and current life and biogeochemical pathways, and use geophysical methods to investigate the subsurface. Sub-specialities of geology may distinguish endogenous and exogenous geology.

Field methods

A standard Brunton Pocket Transit, commonly used by geologists for mapping and surveying.
 
A typical USGS field mapping camp in the 1950s
 
Today, handheld computers with GPS and geographic information systems software are often used in geological field work (digital geologic mapping).
 
Geological field work varies depending on the task at hand. Typical fieldwork could consist of:

Petrology

A petrographic microscope – an optical microscope fitted with cross-polarizing lenses, a conoscopic lens, and compensators (plates of anisotropic materials; gypsum plates and quartz wedges are common), for crystallographic analysis.
 
In addition to identifying rocks in the field (lithology), petrologists identify rock samples in the laboratory. Two of the primary methods for identifying rocks in the laboratory are through optical microscopy and by using an electron microprobe. In an optical mineralogy analysis, petrologists analyze thin sections of rock samples using a petrographic microscope, where the minerals can be identified through their different properties in plane-polarized and cross-polarized light, including their birefringence, pleochroism, twinning, and interference properties with a conoscopic lens. In the electron microprobe, individual locations are analyzed for their exact chemical compositions and variation in composition within individual crystals. Stable and radioactive isotope studies provide insight into the geochemical evolution of rock units. 

Petrologists can also use fluid inclusion data and perform high temperature and pressure physical experiments to understand the temperatures and pressures at which different mineral phases appear, and how they change through igneous and metamorphic processes. This research can be extrapolated to the field to understand metamorphic processes and the conditions of crystallization of igneous rocks. This work can also help to explain processes that occur within the Earth, such as subduction and magma chamber evolution.

Structural geology

A diagram of an orogenic wedge. The wedge grows through faulting in the interior and along the main basal fault, called the décollement. It builds its shape into a critical taper, in which the angles within the wedge remain the same as failures inside the material balance failures along the décollement. It is analogous to a bulldozer pushing a pile of dirt, where the bulldozer is the overriding plate.
 
Structural geologists use microscopic analysis of oriented thin sections of geologic samples to observe the fabric within the rocks, which gives information about strain within the crystalline structure of the rocks. They also plot and combine measurements of geological structures to better understand the orientations of faults and folds to reconstruct the history of rock deformation in the area. In addition, they perform analog and numerical experiments of rock deformation in large and small settings. 

The analysis of structures is often accomplished by plotting the orientations of various features onto stereonets. A stereonet is a stereographic projection of a sphere onto a plane, in which planes are projected as lines and lines are projected as points. These can be used to find the locations of fold axes, relationships between faults, and relationships between other geologic structures. 

Among the most well-known experiments in structural geology are those involving orogenic wedges, which are zones in which mountains are built along convergent tectonic plate boundaries. In the analog versions of these experiments, horizontal layers of sand are pulled along a lower surface into a back stop, which results in realistic-looking patterns of faulting and the growth of a critically tapered (all angles remain the same) orogenic wedge. Numerical models work in the same way as these analog models, though they are often more sophisticated and can include patterns of erosion and uplift in the mountain belt. This helps to show the relationship between erosion and the shape of a mountain range. These studies can also give useful information about pathways for metamorphism through pressure, temperature, space, and time.

Stratigraphy

Different colours shows the different minerals composing the mount Ritagli di Lecca seen from Fondachelli-Fantina, Sicily

In the laboratory, stratigraphers analyze samples of stratigraphic sections that can be returned from the field, such as those from drill cores. Stratigraphers also analyze data from geophysical surveys that show the locations of stratigraphic units in the subsurface. Geophysical data and well logs can be combined to produce a better view of the subsurface, and stratigraphers often use computer programs to do this in three dimensions. Stratigraphers can then use these data to reconstruct ancient processes occurring on the surface of the Earth, interpret past environments, and locate areas for water, coal, and hydrocarbon extraction. 

In the laboratory, biostratigraphers analyze rock samples from outcrop and drill cores for the fossils found in them. These fossils help scientists to date the core and to understand the depositional environment in which the rock units formed. Geochronologists precisely date rocks within the stratigraphic section to provide better absolute bounds on the timing and rates of deposition. Magnetic stratigraphers look for signs of magnetic reversals in igneous rock units within the drill cores. Other scientists perform stable-isotope studies on the rocks to gain information about past climate.

Planetary geology

Surface of Mars as photographed by the Viking 2 lander December 9, 1977.

With the advent of space exploration in the twentieth century, geologists have begun to look at other planetary bodies in the same ways that have been developed to study the Earth. This new field of study is called planetary geology (sometimes known as astrogeology) and relies on known geologic principles to study other bodies of the solar system. 

Although the Greek-language-origin prefix geo refers to Earth, "geology" is often used in conjunction with the names of other planetary bodies when describing their composition and internal processes: examples are "the geology of Mars" and "Lunar geology". Specialised terms such as selenology (studies of the Moon), areology (of Mars), etc., are also in use. 

Although planetary geologists are interested in studying all aspects of other planets, a significant focus is to search for evidence of past or present life on other worlds. This has led to many missions whose primary or ancillary purpose is to examine planetary bodies for evidence of life. One of these is the Phoenix lander, which analyzed Martian polar soil for water, chemical, and mineralogical constituents related to biological processes.

Applied geology

Economic geology

Economic geology is a branch of geology that deals with aspects of economic minerals that humankind uses to fulfill various needs. Economic minerals are those extracted profitably for various practical uses. Economic geologists help locate and manage the Earth's natural resources, such as petroleum and coal, as well as mineral resources, which include metals such as iron, copper, and uranium.

Mining geology

Mining geology consists of the extractions of mineral resources from the Earth. Some resources of economic interests include gemstones, metals such as gold and copper, and many minerals such as asbestos, perlite, mica, phosphates, zeolites, clay, pumice, quartz, and silica, as well as elements such as sulfur, chlorine, and helium.

Petroleum geology

Mud log in process, a common way to study the lithology when drilling oil wells.

Petroleum geologists study the locations of the subsurface of the Earth that can contain extractable hydrocarbons, especially petroleum and natural gas. Because many of these reservoirs are found in sedimentary basins, they study the formation of these basins, as well as their sedimentary and tectonic evolution and the present-day positions of the rock units.

Engineering geology

Engineering geology is the application of the geologic principles to engineering practice for the purpose of assuring that the geologic factors affecting the location, design, construction, operation, and maintenance of engineering works are properly addressed. 

In the field of civil engineering, geological principles and analyses are used in order to ascertain the mechanical principles of the material on which structures are built. This allows tunnels to be built without collapsing, bridges and skyscrapers to be built with sturdy foundations, and buildings to be built that will not settle in clay and mud.

Hydrology and environmental issues

Geology and geologic principles can be applied to various environmental problems such as stream restoration, the restoration of brownfields, and the understanding of the interaction between natural habitat and the geologic environment. Groundwater hydrology, or hydrogeology, is used to locate groundwater, which can often provide a ready supply of uncontaminated water and is especially important in arid regions, and to monitor the spread of contaminants in groundwater wells.

Geologists also obtain data through stratigraphy, boreholes, core samples, and ice cores. Ice cores and sediment cores are used to for paleoclimate reconstructions, which tell geologists about past and present temperature, precipitation, and sea level across the globe. These datasets are our primary source of information on global climate change outside of instrumental data.

Natural hazards

Geologists and geophysicists study natural hazards in order to enact safe building codes and warning systems that are used to prevent loss of property and life. Examples of important natural hazards that are pertinent to geology (as opposed those that are mainly or only pertinent to meteorology) are:

Rockfall in the Grand Canyon

History of geology

William Smith's geologic map of England, Wales, and southern Scotland. Completed in 1815, it was the second national-scale geologic map, and by far the most accurate of its time.
 
The study of the physical material of the Earth dates back at least to ancient Greece when Theophrastus (372–287 BCE) wrote the work Peri Lithon (On Stones). During the Roman period, Pliny the Elder wrote in detail of the many minerals and metals then in practical use – even correctly noting the origin of amber

Some modern scholars, such as Fielding H. Garrison, are of the opinion that the origin of the science of geology can be traced to Persia after the Muslim conquests had come to an end. Abu al-Rayhan al-Biruni (973–1048 CE) was one of the earliest Persian geologists, whose works included the earliest writings on the geology of India, hypothesizing that the Indian subcontinent was once a sea. Drawing from Greek and Indian scientific literature that were not destroyed by the Muslim conquests, the Persian scholar Ibn Sina (Avicenna, 981–1037) proposed detailed explanations for the formation of mountains, the origin of earthquakes, and other topics central to modern geology, which provided an essential foundation for the later development of the science. In China, the polymath Shen Kuo (1031–1095) formulated a hypothesis for the process of land formation: based on his observation of fossil animal shells in a geological stratum in a mountain hundreds of miles from the ocean, he inferred that the land was formed by erosion of the mountains and by deposition of silt.

Nicolas Steno (1638–1686) is credited with the law of superposition, the principle of original horizontality, and the principle of lateral continuity: three defining principles of stratigraphy

The word geology was first used by Ulisse Aldrovandi in 1603, then by Jean-André Deluc in 1778 and introduced as a fixed term by Horace-Bénédict de Saussure in 1779. The word is derived from the Greek γῆ, , meaning "earth" and λόγος, logos, meaning "speech". But according to another source, the word "geology" comes from a Norwegian, Mikkel Pedersøn Escholt (1600–1699), who was a priest and scholar. Escholt first used the definition in his book titled, Geologia Norvegica (1657).

William Smith (1769–1839) drew some of the first geological maps and began the process of ordering rock strata (layers) by examining the fossils contained in them.

James Hutton is often viewed as the first modern geologist. In 1785 he presented a paper entitled Theory of the Earth to the Royal Society of Edinburgh. In his paper, he explained his theory that the Earth must be much older than had previously been supposed to allow enough time for mountains to be eroded and for sediments to form new rocks at the bottom of the sea, which in turn were raised up to become dry land. Hutton published a two-volume version of his ideas in 1795 (Vol. 1, Vol. 2). 

Scotsman James Hutton, father of modern geology
 
Followers of Hutton were known as Plutonists because they believed that some rocks were formed by vulcanism, which is the deposition of lava from volcanoes, as opposed to the Neptunists, led by Abraham Werner, who believed that all rocks had settled out of a large ocean whose level gradually dropped over time. 

The first geological map of the U.S. was produced in 1809 by William Maclure. In 1807, Maclure commenced the self-imposed task of making a geological survey of the United States. Almost every state in the Union was traversed and mapped by him, the Allegheny Mountains being crossed and recrossed some 50 times. The results of his unaided labours were submitted to the American Philosophical Society in a memoir entitled Observations on the Geology of the United States explanatory of a Geological Map, and published in the Society's Transactions, together with the nation's first geological map. This antedates William Smith's geological map of England by six years, although it was constructed using a different classification of rocks. 

Sir Charles Lyell first published his famous book, Principles of Geology, in 1830. This book, which influenced the thought of Charles Darwin, successfully promoted the doctrine of uniformitarianism. This theory states that slow geological processes have occurred throughout the Earth's history and are still occurring today. In contrast, catastrophism is the theory that Earth's features formed in single, catastrophic events and remained unchanged thereafter. Though Hutton believed in uniformitarianism, the idea was not widely accepted at the time. 

Much of 19th-century geology revolved around the question of the Earth's exact age. Estimates varied from a few hundred thousand to billions of years. By the early 20th century, radiometric dating allowed the Earth's age to be estimated at two billion years. The awareness of this vast amount of time opened the door to new theories about the processes that shaped the planet.

Some of the most significant advances in 20th-century geology have been the development of the theory of plate tectonics in the 1960s and the refinement of estimates of the planet's age. Plate tectonics theory arose from two separate geological observations: seafloor spreading and continental drift. The theory revolutionized the Earth sciences. Today the Earth is known to be approximately 4.5 billion years old.

Oil shale geology

From Wikipedia, the free encyclopedia

A pick axe sitting on a wider, protruding rock. Various sized rock prudences are in the photo; most are a little wider than the pick handle.
Outcrop of Ordovician kukersite oil shale, northern Estonia
 
Lower Jurassic oil shale near Holzmaden, Germany
 
Oil shale geology is a branch of geologic sciences which studies the formation and composition of oil shales–fine-grained sedimentary rocks containing significant amounts of kerogen, and belonging to the group of sapropel fuels. Oil shale formation takes place in a number of depositional settings and has considerable compositional variation. Oil shales can be classified by their composition (carbonate minerals such as calcite or detrital minerals such as quartz and clays) or by their depositional environment (large lakes, shallow marine, and lagoon/small lake settings). Much of the organic matter in oil shales is of algal origin, but may also include remains of vascular land plants. Three major type of organic matter (macerals) in oil shale are telalginite, lamalginite, and bituminite. Some oil shale deposits also contain metals which include vanadium, zinc, copper, and uranium.

Most oil shale deposits were formed during Middle Cambrian, Early and Middle Ordovician, Late Devonian, Late Jurassic, and Paleogene times through burial by sedimentary loading on top of the algal swamp deposits, resulting in conversion of the organic matter to kerogen by diagenetic processes. The largest deposits are found in the remains of large lakes such as the deposits of the Green River Formation of Wyoming and Utah, USA. Oil-shale deposits formed in the shallow seas of continental shelves generally are much thinner than large lake basin deposits.

Classification and varieties

A lump of cannel coal approximately 15 cm wide.
Cannel coal from the Pennsylvanian of northeastern Ohio
 
A lump of greenish-brown oil shale approximately 15 cm wide.
Marinite from Jordan
 
Two lumps of grey rock with some brownish stripes. Weathered surface on right; fresh surface on left.
Lamosite from the Mahogany Zone of the Green River Formation, Colorado
 
Oil shale belongs to the group of sapropel fuels. It does not have a definite geological definition nor a specific chemical formula, and its seams do not always have discrete boundaries. Oil shales vary considerably in their mineral content, chemical composition, age, type of kerogen, and depositional history and not all oil shales would necessarily be classified as shales in the strict sense. Their common feature is low solubility in low-boiling organic solvents and generation of liquid organic products on thermal decomposition.

There are varying classifications of oil shales depending on their mineral content, type of kerogen, age, depositional history, and organisms from which they are derived. The age of the known oil shale deposits ranges from Cambrian to Paleogene age. Lithologies comprise shales and marl and carbonate rocks, all of which form a mixture of tightly bound organic matter and inorganic components.

Oil shales have been divided into three categories based on mineral composition – carbonate-rich shale, siliceous shale and cannel shale. Carbonate-rich shales derive their name from the large amount of carbonate minerals such as calcite and dolomite. As many as twenty carbonate minerals have been found in oil shales, the majority of which are considered authigenic or diagenetic. Carbonate-rich oil shales, particularly that of lacustrine-sourced deposits, have usually the organic-rich layers sandwiched between carbonate-rich layers. These deposits are hard formations that are resistant to weathering and they are difficult to process using ex-situ methods. Siliceous oil shales are usually dark brown or black shales. They are not rich in carbonates but rather in siliceous minerals such as quartz, feldspar, clay, chert and opal. Siliceous shales are not as hard and weather-resistant as carbonate-rich shales, and may be better suited for extraction via ex-situ methods. Cannel shales are usually dark brown or black shales, which consist of organic matter that completely encloses other mineral grains. They are suitable for extraction via ex-situ methods.

Another classification according to the type of kerogen, is based on the hydrogen, carbon, and oxygen content of the original organic matter in the oil shale. This classification is using the Van Krevelen diagram. The most used classification of oil shales was developed between 1987 and 1991 by Adrian C. Hutton of the University of Wollongong, adapting petrographic terms from coal terminology. According to this classification, oil shales are designated as terrestrial, lacustrine (lake-bottom-deposited), or marine (ocean bottom-deposited), based on the environment where the initial biomass was deposited. Hutton's classification scheme has proven useful in estimating the yield and composition of the extracted oil.

Classification of oil shales by environment of deposition
Terrestrial Lacustrine Marine
cannel coal

lamosite;
torbanite

kukersite;
tasmanite;
marinite

Cannel coal (also called candle coal) is a type of terrestrial shale, which is hydrogen-rich brown to black coal, sometimes with shaly texture, composed of resins, spores, waxes, cutinaceous and corky materials derived from terrestrial vascular plants as well as varied amounts of vitrinite and inertinite. Lacustrine shales consist of lamosite and torbanite. Lamosite is a pale-brown and grayish-brown to dark-gray to black oil shale whose chief organic constituent is lamalginite derived from lacustrine planktonic algae. Torbanite, named after Torbane Hill in Scotland, is a black oil shale whose organic matter is telalginite derived from lipid-rich Botryococcus and related algal forms. Marine shales consist of three varieties, namely kukersite, tasmanite, and marinite. Kukersite, named after Kukruse in Estonia, is a light-brown marine oil shale whose principal organic component is telalginite derived from the green alga, Gloeocapsomorpha prisca. Tasmanite, named after Tasmania, is a brown to black oil shale whose organic matter consists of telalginite derived chiefly from unicellular tasmanitid algae of marine origin. Marinite is a gray to dark-gray to black oil shale of marine origin in which the chief organic components are lamalginite and bituminite derived from marine phytoplankton with varied admixtures of bitumen, telalginite, and vitrinite.

Composition

White, abstract branching figures in brown rock.
Fossils in Ordovician kukersite oil shale, northern Estonia
 
See caption.
Photomicrograph showing detail of the varves in a rich Colorado oil shale specimen. The organic laminae are themselves finely laminated. The mineral laminae contain considerable organic matter, but they are readily distinguished by their coarser grain and greater thickness. Note sand grains (white). Enlarged 320 diameters.
 
A rock with the fossilized skeleton of a primitive organism.
Fossil in oil shale from Messel pit, south of Frankfurt am Main, Germany
 
As a sapropel fuel, oil shale differs from humus fuels in its lower content of organic matter. The organic matter has an atomic ratio of hydrogen to carbon of about 1.5 – approximately the same as that of crude oil and four to five times higher than coals. The organic matter in oil shales forms a complex macromolecular structure which is insoluble in common organic solvents. It is mixed with varied amounts of mineral matter. For commercial grades of oil shale, the ratio of organic matter to mineral matter is about 0.75:5 to 1.5:5.

The organic portion of oil shale consists largely of a pre-bitumen bituminous groundmass, such as remains of algae, spores, pollen, plant cuticles and corky fragments of herbaceous and woody plants, and cellular debris from other lacustrine, marine, and land plants. While terrestrial oil shales contain resins, spores, waxy cuticles, and corky tissues of roots and stems of vascular terrestrial plants, lacustrine oil shales include lipid-rich organic matter derived from algae. Marine oil shales are composed of marine algae, acritarchs, and marine dinoflagellates. Organic matter in oil shale also contains organic sulfur (about 1.8% on average) and a lower proportion of nitrogen.

Three major types of organic matter (macerals) in oil shale are telalginite, lamalginite, and bituminite. Telalginite is defined as structured organic matter composed of large colonial or thick-walled unicellular algae such as Botryococcus and Tasmanites. Lamalginite includes thin-walled colonial or unicellular algae that occur as distinct laminae, but display few or no recognizable biologic structures. Under the microscope, telalginite and lamalginite are easily recognized by their bright shades of yellow under ultraviolet/blue fluorescent light. Bituminite is largely amorphous, lacks recognizable biologic structures, and displays relatively low fluorescence under the microscope. Other organic constituents include vitrinite and inertinite, which are macerals derived from the humic matter of land plants. These macerals are usually found in relatively small amounts in most oil shales.

Mineral matter in oil shale contains fine-grained silicate and carbonate minerals such as calcite, dolomite, siderite, quartz, rutile, orthoclase, albite, anorthite, muscovite, amphipole, marcasite, limonite, gypsum, nahcolite, dawsonite and alum. Some oil-shale deposits also contain metals such as vanadium, zinc, copper, and uranium among others.

General composition of oil shales
Inorganic matrix Bitumens Kerogens
quartz; feldspars; clays (mainly illite and chlorite; carbonates (calcite and dolomite); pyrite and others soluble in CS2 insoluble in CS2; containing uranium, iron, vanadium, nickel, molybdenum, etc.

Formation

Most oil shale deposits were formed during Middle Cambrian, Early and Middle Ordovician, Late Devonian, Late Jurassic and Paleogene times. These were formed by the deposition of organic matter in a variety of depositional environments including freshwater to highly saline lakes, epicontinental marine basins and subtidal shelves and were restricted to estuarine areas such as oxbow lakes, peat bogs, limnic and coastal swamps, and muskegs. When plants die in such an anaerobic aquatic environment, low oxygen levels prevent their complete bacterial decay.

For undecayed organic matter to be preserved and to form oil shale, the environment must remain uniform for prolonged periods of time in order to build up sufficiently thick sequences of algal matter. Eventually, the algal swamp or other restricted environment is disrupted and oil shale accumulation ceases. Burial by sedimentary loading on top of the algal swamp deposits converts the organic matter to kerogen by the following normal diagenetic processes:
  • Compaction due to sediment loading on the coal, leading to compression of the organic matter.
  • With ongoing heat and compaction, removal of moisture in the peat and from the intracellular structure of fossilized plants, and removal of molecular water.
  • Methanogenesis—similar to treating wood in a pressure cooker— results in methane being produced, removing hydrogen, some carbon, and some further oxygen.
  • Dehydration, which removes hydroxyl groups from the cellulose and other plant molecules, resulting in the production of hydrogen-reduced coals or oil shales.
Though similar in their formation process, oil shales differ from coals in several distinct ways. The precursors of the organic matter in oil shale and coal differ in a sense that oil shale is of algal origin, but may also include remains of vascular land plants that more commonly compose much of the organic matter in coal. The origin of some of the organic matter in oil shale is obscure because of the lack of recognizable biologic structures that would help identify the precursor organisms. Such materials may be of bacterial origin or the product of bacterial degradation of algae or other organic matter.

Lower temperature and pressure during the diagenesis process compared to other modes of hydrocarbon generation result in a lower maturation level of oil shale. Continuous burial and further heating and increased pressure over time could result in the conventional production of oil and gas from the oil shale source rock. The largest deposits are found in the remains of large lakes such as the deposits of the Green River Formation of Wyoming and Utah, USA. Large lake oil shale basins are typically found in areas of block faulting or crustal warping due to mountain building. Deposits such as the Green River may be as much as 2,000 feet (610 m) and yield up to 40 gallons of oil for each ton (166 l/t) of shale.

Oil shale deposits formed in the shallow seas of continental shelves generally are much thinner than large lake basin deposits. These are typically a few meters thick and are spread over very large areas, extending up to thousands of square kilometers. Of the three lithologic types of oil shales, siliceous oil shales are most commonly found in such environments. These oil shales are not as organically rich as lake-deposited oil shales, and generally do not contain more than 30 gallons of extractable oil per ton of oil shale. Oil shales deposited in lagoonal or small lake environments are rarely extensive and are often associated with coal-bearing rocks. These oil shales can have high yields– as much as 40 gallons per ton (166 l/t) of oil shale. However, due to their small areal extent, they are considered unlikely candidates for commercial exploitation.

Properties of some oil shales deposits
Country Location Type Age Organic carbon (%) Yield (%) Conversion ratio (%)
Australia Glen Davis,
New South Wales
torbanite Permian 40 31 66
Tasmania tasmanite Permian 81 75 78
Brazil Irati Formation,
Irati
marinite Permian
7.4
Paraíba Valley lacustrine
shales
Permian 13-16.5 6.8-11.5 45-59
Canada Nova Scotia torbanite,
lamosite
Permian 8-26 3.6-19 40-60
China Fushun cannel coal;
lacustrine shales
Eocene 7.9 3 33
Estonia Estonia
Deposit
kukersite Ordovician 77 22 66
France Autun,St. Hilarie torbanite Permian 8-22 5-10
Creveney,
Severac

Toarcian 5-10 4-5 60
South Africa Ermelo torbanite Permian 44-52 18-35 34-60
Spain Puertollano lacustrine shale Permian 26 18 57
Sweden Kvarntorp marinite Lower Paleozoic 19 6 26
United Kingdom Scotland torbanite Carboniferous 12 8 56
United States Alaska
Jurassic 25-55 0.4-0.5 28-57
Green River Formationin Colorado,
Wyoming and Utah
lamosite Early to
Mid Eocene
11-16 9-13 70
Mississippi marinite Devonian


Formations in the United States

The United States has two significant oil shale deposits which are suited for commercial development due to their size, grade and location. The Eocene Green River Formation covers parts of Colorado, Wyoming and Utah; the second significant deposit is Devonian oil shales in the eastern United States. In both places, there are sub-basins varying in volume and quality of the reserves. Oil shale in the Green River Formation is found in five sedimentary basins namely, Green River, Uinta, Piceance Creek, Sand Wash and Washakie. The first three have undergone some significant exploration and attempts to commercialize the oil shale reserves since the 1960s. The Green River Formation includes deposits from two large lakes which covered an estimated area of over 65,000 square kilometres (25,100 sq mi) during the Early to Middle Eocene. These lakes were separated by the Uinta uplift and the Axial Basin anticline. For significant periods during their 10 Ma life, the lakes became closed systems allowing many changes in size, salinity and sedimentation. The deposition of oil shales resulted from abundant blue-green algae that thrived in the lakes.

The oil shale that underlies almost 750,000 square kilometres (289,580 sq mi) in the eastern United States was formed in a marine depositional environment, very different from the Green River Basins. These deposits have also undergone commercialization attempts; they are also resources for natural gas and have been mined for low-grade oil shale. These oil shales were formed during the Late Devonian and Early Mississippian periods. During this time, much of the eastern United States was covered by a large shallow sea. The oil shale is thought to have been the result of slow deposition of planktonic algae. under anoxic conditions. In parts of the basin close to the shoreline, the organic mixture that helped form the oil shale contains organic-rich sediment from the rising Appalachian mountains.

Formations in Brazil

Brazil has nine significant locations of oil shale deposits. The size, location and quality of oil shale deposits in the Paraíba Valley and the Irati Formation have attracted the most attention. These two contain an estimated 1.4 billion barrels of in-situ shale oil with total resources as much as more than three billion barrels. While the "Irati formation" deposit is the smaller of the two, containing an estimated 600 million barrels in-situ compared to 840 million in the Paraíba Valley formation, the former is more economically viable.

The Irati Formation consists of two oil shale beds separated by 12 metres (40 ft) of limestone and shale. The upper layer is thicker (9 metres (30 ft)) but the thinner lower bed (4 metres (10 ft)) is of greater value; the weight percent of shale oil yield is around 12% for the lower layer as compared to 7% for the upper one. The oil shale yield varies laterally, and may be as little as 7% for the lower layer and 4% for the upper layer. The formation is a very fine grained and laminated deposit ranging in color from dark gray to brown to black. While 60-70% of the shale consists of clay minerals, the balance is made up of organic matter.

No consensus has been reached on the exact depositional nature of the Irati oil shale. One theory suggests that the organic material in the Irati oil shale originated from algae deposited in a lacustrine environment with salinity varying from that of freshwater to brackish water. Other theory suggests that the organic sediment may have been deposited in a shallow, partially restricted marine environment. Hutton's classification describes it as a marine source oil shale.

Formation in Estonia

The kukersite oil shale of Ordovician age in Estonia is part of the Baltic oil shale basin and was deposited in shallow marine environments. The deposit is one of the world’s highest-grade deposits with more than 40% organic content and 66% conversion ratio into shale oil and gas. The oil shale is located in a single calcareous layer 2.5 to 3 metres (8.2 to 9.8 ft) in thickness and is buried at depths from 7 to 100 metres (23 to 328 ft). The total area of the basin is about 3,000 square kilometres (1,200 sq mi). Oil yield from Kukersite is 30 to 47%. Most of the organic matter is derived from the fossil green alga, Gloeocapsomorpha prisca, which has affinities to the modern cyanobacterium, Entophysalis major, an extant species that forms algal mats in inter-tidal to very shallow subtidal waters. Matrix minerals include low-magnesium calcite, dolomite, and siliciclastic minerals. It is not enriched in heavy metals.

Reserves

As source rocks for most conventional oil reservoirs, oil shale deposits are found in all world oil provinces, although most of them are too deep to be exploited economically. As with all oil and gas resources, analysts distinguish between oil shale resources and oil shale reserves. "Resources" refers to all oil shale deposits, while "reserves", represents those deposits from which producers can extract oil shale economically using existing technology. Since extraction technologies develop continuously, planners can only estimate the amount of recoverable kerogen. Although resources of oil shale occur in many countries, only 33 countries possess known deposits of possible economic value. Well-explored deposits, potentially classifiable as reserves, include the Green River deposits in the western United States, the Tertiary deposits in Queensland, Australia, deposits in Sweden and Estonia, the El-Lajjun deposit in Jordan, and deposits in France, Germany, Brazil, China, southern Mongolia and Russia. These deposits have given rise to expectations of yielding at least 40 liters of shale oil per tonne of oil shale, using the Fischer Assay.

A 2008 estimate set the total world resources of oil shale at 689 gigatons — equivalent to yield of 4.8 trillion barrels (760 billion cubic metres) of shale oil, with the largest reserves in the United States, which is thought to have 3.7 trillion barrels (590 billion cubic metres), though only a part of it is recoverable. According to the 2010 World Energy Outlook by the International Energy Agency, the world oil shale resources may be equivalent of more than 5 trillion barrels (790 billion cubic metres) of oil in place of which more than 1 trillion barrels (160 billion cubic metres) may be technically recoverable. For comparison, the world's proven conventional oil reserves were estimated at 1.317 trillion barrels (209.4×109 m3), as of 1 January 2007. The largest known commercial deposits in the world occur in the United States in the Green River Formation, which covers portions of Colorado, Utah, and Wyoming; about 70% of this resource lies on land owned or managed by the United States federal government. Deposits in the United States constitute 62% of world resources; together, the United States, Russia and Brazil account for 86% of the world's resources in terms of shale-oil content. These figures remain tentative, with exploration or analysis of several deposits still outstanding. Professor Alan R. Carroll of University of Wisconsin–Madison regards the Upper Permian lacustrine oil-shale deposits of northwest China, absent from previous global oil shale assessments, as comparable in size to the Green River Formation.

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