Search This Blog

Sunday, October 1, 2023

Landlocked developing countries

The landlocked developing countries (LLDC) are developing countries that are landlocked. The economic and other disadvantages experienced by such countries makes the majority of landlocked countries the least developed countries (LDCs), with inhabitants of these countries occupying the bottom billion tier of the world's population in terms of poverty. Outside of Europe, there is not a single highly developed landlocked country as measured by the Human Development Index (HDI), and nine of the twelve countries with the lowest HDI scores are landlocked. Landlocked European countries are exceptions in terms of development outcomes due to their close integration with the regional European market. Landlocked countries that rely on transoceanic trade usually suffer a cost of trade that is double that of their maritime neighbours. Landlocked countries experience economic growth 6% less than non-landlocked countries, holding other variables constant.

32 out of the world's 44 landlocked countries, including all the landlocked countries in Africa, Asia, and South America, have been classified as the Landlocked Developing Countries (LLDCs) by the United Nations. As of 2012, about 442.8 million people lived in these LLDCs.

UN-OHRLLS

The United Nations has an Office of the High Representative for the Least Developed Countries, Landlocked Developing Countries and Small Island Developing States (UN-OHRLLS). It mainly holds the view that high transport costs due to distance and terrain result in the erosion of competitive edge for exports from landlocked countries. In addition, it recognizes the constraints on landlocked countries to be mainly physical, including lack of direct access to the sea, isolation from world markets and high transit costs due to physical distance. It also attributes geographic remoteness as one of the most significant reasons why developing landlocked nations cannot alleviate themselves, while European landlocked cases are mostly developed because of short distances to the sea through well-developed countries. One other commonly cited factor is the administrative burdens associated with border crossings as there is a heavy load of bureaucratic procedures, paperwork, custom charges, and most importantly, traffic delay due to border wait times, which affect delivery contracts. Delays and inefficiency compound geographically, where a 2 to 3 week wait due to border customs between Uganda and Kenya makes it impossible to book ships ahead of time in Mombasa, furthering delivery contract delays. Despite these explanations, it is also important to consider the transit countries that neighbour LLDCs, from whose ports the goods of LLDCs are exported.

Dependency problems

Although Adam Smith and traditional thought hold that geography and transportation are the culprits for keeping LLDCs from realizing development gains, Faye, Sachs and Snow hold the argument that no matter the advancement of infrastructure or lack of geographic distance to a port, landlocked nations are still dependent on their neighbouring transit nations. Outlying this specific relationship of dependency, Faye et al. insist that though LLDCs vary across the board in terms of HDI index scores, LLDCs almost uniformly straddle at the bottom of HDI rankings in terms of region, suggesting a correlated dependency relationship of development for landlocked countries with their respective regions. In fact, HDI levels decrease as one moves inland along the major transit route that runs from the coast of Kenya, across the country before going through Uganda, Rwanda and then finally Burundi. Just recently, it has been economically modeled that if the economic size of a transit country is increased by just 1%, a subsequent increase of at least 2% is experienced by the landlocked country, which shows that there is hope for LLDCs if the conditions of their transit neighbours are addressed. In fact, some LLDCs are seeing the brighter side of such a relationship, with the Central Asian nations geographic location between three BRIC nations (China, Russia and India) hungry for the region's oil and mineral wealth serving to boost economic development. The three major factors that LLDCs are dependent on their transit neighbours are dependence on transit infrastructure, dependence on political relations with neighbours, and dependence on internal peace and stability within transit neighbours.

Burundi

Burundi is shown in blue. Its possible export routes were: *dependent on infrastructure of transit neighbour Tanzania (yellow), or *dependent on political relations with transit neighbour Kenya (orange), or *dependent on internal stability of transit neighbour Mozambique (red). When all three routes were unavailable, Burundi had to rely on the port of Durban in South Africa (brown).

Burundi has relatively good internal road networks, but it cannot export its goods using the most direct route to the sea since the inland infrastructure of Tanzania is poorly connected to the port of Dar es Salaam. Thus Burundi relies on Kenya's port of Mombasa for export; but this route was severed briefly in the 1990s when political relations with Kenya deteriorated. Further, Burundi's exports could not pass through Mozambique around the same time due to the Mozambican civil war (1977-1992). Thus, Burundi had to export its goods using a 4500 km route, crossing several borders and changing transport modes, to reach the port of Durban in South Africa.

Other African countries

Central Asia

The mineral resource-rich countries of Central Asia and Mongolia offer a unique set of landlocked cases to explore in more depth, as these are nations where economic growth has grown exceptionally in recent years. In Central Asia, oil and coal deposits have influenced development: Kazakhstan’s GDI per capita in purchasing power parity was five times greater than Kyrgyzstan's in 2009. Despite substantial development growth, these nations are not on a stable and destined path to being well developed, as the exploitation of their natural resources translates into an overall low average income and disparity of income, and because their limited deposits of resources allow growth only in the short term, and most importantly because dependence on unprocessed materials increases the risk of shocks due to variations in market prices. And though it is widely conceived that free trade can permit faster economic growth, Mongolia is now subjected to a new geopolitical game about the traffic on its railway lines between China and Russia. Russian Railways now effectively owns 50% of Mongolia's rail infrastructure, which could mean more efficient modernization and the laying of new rail lines, but in reality also translates into powerful leverage to pressure the government of Mongolia to concede unfair terms for license grants of coal, copper, and gold mines. Thus, it can be argued that these nations with extraordinary mineral wealth should pursue economic diversification. All of these nations possess education qualifications, as they are inheritors of the Soviet Union's social education system. This implies that it is due to poor economic policies that more than 40% of the labour force is bogged down in the agricultural sector instead of being diverted into secondary or tertiary economic activity. Yet, it cannot be ignored that Mongolia benefits exceptionally from its proximity to two giant BRIC nations, resulting in a rapid development of railway ports along its borders, especially along the Chinese border, as the Chinese seek to direct coking coal from Mongolia to China's northwestern industrial core, and, as well as for transportation southeast towards Japan and South Korea, resulting in revenue generation through the seaport of Tianjin.

Armenia

The Republic of Armenia is a landlocked country having geographic disadvantages and faces limitations on foreign policy options. It needs to transport its goods via coastal neighbors to access ports to participate in international trade, to which Azerbaijan and Turkey are hostile and deny its access. Therefore, Armenia mainly depends on the Georgian ports of Batumi and Poti and the Georgian train system to participate in international trade. Armenia also shares a small border with neighboring Iran, through which it trades despite American sanctions. Armenia remains heavily dependent on imports from and export of moderately unsophisticated goods to Russia. While Russia stayed Armenia's dominant trade partner, in 2020, trade with the EU accounted for around 18% of Armenia's total trade. As of 2020, European Union is Armenia's third biggest export market, with a 17% share in total Armenian exports, and the second largest source of Armenian imports, with an 18.6% share in total Armenian imports. 

Nepal

Nepal is another landlocked country with extreme dependency on its transit neighbour India. India does not have poor relations with Nepal, nor does it lack relevant transport infrastructure or internal stability. However, there have been two cases of economic blockades imposed by the government of India on Nepal – the official 1989 blockade and the unofficial 2015 blockade – both of which left the nation in severe economic crisis. In the 1970s, Nepal suffered from large commodity concentration and a high geographic centralization in its export trade: over 98% of its exports were to India, and 90% of its imports came from India. As a result of all this, Nepal had a poor trade bargaining position. In the 1950s, Nepal was forced to comply with India's external tariffs as well as the prices of India's exports. This was problematic since the two countries have different levels of development, resulting in greater gains for India which was larger, more advanced and with more resources. It was feared that a parasitic relationship might emerge, since India had a head start in industrialization, and dominated Nepal in manufacturing, which could reduce Nepal to being just a supplier of raw materials. Because of these problems, and Nepal's inability to develop its own infant industries (as it could not compete with Indian manufactures) treaties were drafted in 1960 and 1971, with amendments to the equal tariffs conditions, and terms of trade have since progressed.

Almaty Ministerial Conference

In August, 2003, the International Ministerial Conference of Landlocked and Transit Developing Countries and Donor Countries on Transit Transport Cooperation (Almaty Ministerial Conference) was held in Almaty, Kazakhstan, setting the necessities of LLDCs in a universal document whereas there were no coordinated efforts on the global scale to serve the unique needs of LLDCs in the past. Other than acknowledging the main forms of dependency that must be addressed, it also acknowledged the additional dependency issue where neighbouring transit countries are often observed to export the same products as their landlocked neighbours. One result of the conference was a direct call for donor countries to step in to direct aid into setting up suitable infrastructure of transit countries to alleviate the burden of supporting LLDCs in regions of poor development in general. The general objectives of the Almaty Program of Action is as follows:

  • Reduce customs processes and fees to minimize costs and transport delays
  • Improve infrastructure with respect to existing preferences of local transport modes, where road should be focused in Africa and rail in South Asia
  • Implement preferences for landlocked countries’ commodities to boost their competitiveness in the international market
  • To establish relationships between donor countries with landlocked and transit countries for technical, financial and policy improvements

Current LLDCs

Map of current landlocked developing countries
Africa (16 countries)
Asia (12 countries)
Europe (2 countries)
South America (2 countries)

Cumulonimbus and aviation

From Wikipedia, the free encyclopedia
https://en.wikipedia.org/wiki/Cumulonimbus_and_aviation

Numerous accidents have occurred in the vicinity of thunderstorms due to the density of clouds. It is often said that the turbulence can be extreme enough inside a cumulonimbus to tear an aircraft into pieces, and even strong enough to hold a skydiver. However, this kind of accident is relatively rare. Moreover, the turbulence under a thunderstorm can be non-existent and is usually no more than moderate. Most thunderstorm-related crashes occur due to a stall close to the ground when the pilot gets caught by surprise by a thunderstorm-induced wind shift. Moreover, aircraft damage caused by thunderstorms is rarely in the form of structural failure due to turbulence but is typically less severe and the consequence of secondary effects of thunderstorms (e.g., denting by hail or paint removal by high-speed flight in torrential rain).

Thus, cumulonimbus are known to be extremely dangerous to air traffic, and it is recommended to avoid them as much as possible. Cumulonimbus can be extremely insidious, and an inattentive pilot can end up in a very dangerous situation while flying in apparently very calm air.

While there is a gradation with respect to thunderstorm severity, there is little quantitative difference between a significant shower generated by a cumulus congestus and a small thunderstorm with a few thunderclaps associated with a small cumulonimbus. For this reason, a glider pilot could exploit the rising air under a thunderstorm without recognising the situation – thinking instead that the rising air was due to a more benign variety of cumulus. However, forecasting thunderstorm severity is an inexact science; in numerous occasions, pilots got trapped by underestimating the severity of a thunderstorm that suddenly strengthened.

General hazards to aircraft

Even large airliners avoid crossing the path of a cumulonimbus. Two dangerous effects of cumulonimbus have been put forward to explain the crash of flight AF447 that sank into the sea on 31 May 2009 about 600 kilometres (370 mi) northeast of Brazil. It encountered a mesoscale convective system in the Intertropical Convergence Zone (known by sailors as the "doldrums"), where cumulonimbus rise to more than 15 kilometres (49,000 ft) in altitude. However, the aircraft did not disintegrate in flight. A different hypothesis was put forward and later confirmed: accumulation of ice on the aircraft's pitot tubes.

The inconsistency between the airspeeds measured by the different sensors is one of the causes of the accident according to the final report.

The US FAA recommends that aircraft (including gliders) stay at least 20 nautical miles away from a severe thunderstorm, while a glider pilot could be tempted to use the updraughts below and inside the cloud. There are two sorts of danger for this type of aircraft. One is related to the shear effects between updraughts and downdraughts inside the cloud – effects that can smash the glider. This shear creates a Kelvin-Helmholtz instability that can generate extremely violent sub-vortices. The second danger is more insidious: the strong updraughts below a supercell cumulonimbus can cover a large area and contain little or no turbulence as explained below. In this case, the glider can be sucked into the cloud, where the pilot can quickly lose visual reference to the ground, causing conditions to quickly become Instrument meteorological conditions (IMC), meaning that pilots are forced to fly by instruments alone, without visual reference of the ground or sky. In these conditions, the aircraft (if not equipped for IMC flight and flown by a pilot experienced in IMC flight) is likely to enter a graveyard spiral and eventually break up by exceeding the wing load limit. In this situation, the cause of the disintegration of the aircraft is not atmospheric turbulence but is the inability of the pilot to control the aircraft following the loss of visual reference to the ground. In the case of an instrument flight, cumulonimbus can catch a pilot by surprise when embedded in a more benign cloud mass. For example, nimbostratus can originate from the spreading of a cumulonimbus (nimbostratus cumulonimbogenitus), making the presence of active convective cells likely. Small private airplanes are generally not equipped with on-board weather radars; and during an IFR approach, they can be sent accidentally by air traffic control to non-obvious active cells.

Updraft characteristics

Figure 1 : Forward area of a severe cumulonimbus moving to the west. This area is precipitation-free and the site of widespread updrafts.

The updrafts under a cumulonimbus can be extremely laminar, extensive, and uniform, this is particularly true during the buildup of the thunderstorm. They can last more than one hour and correspond to a steady state of the cumulonimbus.

The updraft under the cloud is mostly due to buoyancy, but there is also a large pressure difference between the base and the top of the cumulonimbus (larger than would be found in this height range outside the cloud) and local low-level mechanical lifting such as the lifting generated by a downburst. The two last phenomena can overcome a stable air zone close to the surface by lifting cooler air parcels to a level where they are eventually warmer than the surrounding air. This can happen if these mechanical phenomena lift the parcel above the lifted condensation level (LCL), above which height the parcel's temperature Tp(z) decreases less with height (due to the release of latent heat and at approximately 6.5 K/km) than the surrounding air temperature Ts(z) decreases with height in the case of a conditionally unstable lapse rate aloft. In other words, the parcel can be lifted to a height where , where the former is the cooling rate of the parcel and the latter is the ambient lapse rate. In these conditions, the rising parcel may eventually become warmer than the surrounding air; in other words, there may exist a level above which . This scenario's conditionally unstable lapse rate aloft is relatively common when thunderstorms exist. In effect, at low level, such air parcels are sucked into the cloud as if by a vacuum cleaner. Soaring pilots refer to this near-base sucking as "cloud suck", a phenomenon known to generally be more intense the taller the cumulus cloud – and to thus be at maximum intensity with a cumulonimbus. Since the dynamic updraft is wide, the updraft velocity varies little laterally and thus the turbulence is minimised. So, it is said:

The observations reported by Marwitz (1973), Grandia and Marwitz (1975), and Ellrod and Marwitz (1976) indicate that the updraft air entering the base of cumulonimbi is smooth and relatively free of turbulence and remains so through a significant depth of the WER.

In fact, Ellrod and Marwitz's paper is more general. These authors state that in general, the buoyancy beneath the cumulonimbus cloud base is often negative. This explains why updrafts underneath the base of a cumulonimbus are often laminar. This phenomenon is well known by glider pilots. (see below). The phenomenon is enhanced under the weak echo region of a supercell thunderstorm that is extremely dangerous. At approximately 4 kilometres (13,000 ft) these smooth updrafts become suddenly very turbulent.

In general, updrafts reach their maximum intensity at 6 kilometres (20,000 ft) above the ground. At this altitude, a phase change occurs where water droplets become ice crystals and therefore release energy in the form of latent heat and thus the updraft strength increases. Supercell thunderstorms or derechos can have gigantic updrafts at this altitude, updrafts with speeds that can exceed 40 metres per second (78 kn). Such an updraft speed corresponds to the wind speed of a small hurricane. The speed can even exceed 50 metres per second (97 kn). The maximum number in the Beaufort scale is 12 ("hurricane force" wind) and is assigned to wind speeds of 64 knots or greater. If the Beaufort scale were extended, these updrafts would have a Beaufort number of 14 in the vertical direction. The turbulence is then extreme at this altitude.

Moreover, the diameters of the updraft columns vary between 2 km (air mass thunderstorm) and 10 km (supercell thunderstorm). The height of the cumulonimbus base is extremely variable. It varies from a few tens of meters above the ground to 4000 m above the ground. In the latter case, the updrafts can originate either from the ground (if the air is very dry – typical of deserts) or from aloft (when altocumulus castellanus degenerates into cumulonimbus). When the updraft originates from aloft, this is considered elevated convection.

Dangers pertaining to downbursts

Figure 2: Spreading of a downburst close to the ground.

Downbursts are dangerous for many reasons. First, downdraughts under cumulonimbus can be severe and extensive. A sailplane flying at 50 knots in a downdraught of 15 knots has an approximate glide ratio of 3, meaning that it covers only about three metres of ground for every metre it descends. Assuming that the glider is at cloud base height at 2,000 metres (6,600 ft), if it remains in the downdraught the entire time, it will only be able to glide 6 kilometres (3.7 mi) before being forced to land – likely under difficult and dangerous conditions. Even if the glider lands safely, it could be destroyed later by a wind gust. So when a rain curtain shows a downburst, it is of paramount importance to not land in this area.

Downdraughts of 50 knots are possible and can generate wind gusts of 60 knots or more. Safely landing a light aircraft in these conditions can be virtually impossible. Moreover, close to the ground, a glider or airplane pilot can be caught by surprise by a sudden reversal of the wind direction and transition from an upwind to a downwind situation. If the airspeed becomes too low, the aircraft will stall and may crash into the ground due to the altitude lost recovering from the stall. As a consequence of famous instances of crashes of this nature in the United States, a network of wind profilers and Terminal Doppler Weather Radars was developed in the vicinity of airports to monitor this wind shear. Based on FAA rules, every pilot must inquire about the wind speed and direction before landing.

Compared to airliners, sailplanes fly at low airspeeds. The usual approach speed of a sailplane is around 50 knots, but let's assume that the pilot is extra "careful" and flies his approach at 65 knots. William Cotton claims that the wind shear can be as high as 50 knots. In such a case, if the shear direction is such that the airspeed is reduced by the shear amount, this pilot's airspeed will drop to 15 knots, which is well below his glider's stall speed (typically 35–40 knots). If this airspeed drop occurs during the transition from the base leg to the final approach, the aircraft may enter into a spin from which there isn't enough altitude to recover. The exact quotation is the following:

Upon encountering a downburst with say a 50 kt tailwind component, airspeed can drop from say 65 kts to more like 15 kts. If the sailplane is making a turn from baseleg to final, the pilot finds himself (herself) in one of the deadliest situations a pilot can encounter, a "stall-spin" situation with no chance to recover since the aircraft is close to the ground on final approach.

So when the pilot encounters benign cumulonimbus, it may be a better choice to stay aloft and use the updraughts under the cumulus in front of the thunderstorm along the flanking line (or even under the cumulonimbus itself in its laminar region) and wait for the thunderstorm to dissipate instead of attempting a landing in the presence of possible downbursts.

Flight inside cumulonimbus

Soaring

In some countries, sailplanes are permitted to fly inside clouds. For example, during the 1972 World Soaring Championship at Vršac, Yugoslavia, Helmut Reichmann attempted to use the violent updraughts associated with cumulonimbus. Initially, he found an updraught of +8 m/s. After half a circle, he was in a downdraught of −15 m/s. He had to land very shortly afterward. The thunderstorm was in its mature stage. In another example, Terry Delore got trapped in a severe thunderstorm. He entered a seemingly innocuous cumulus at 2,000 feet (610 m). This cumulus evolved into a large cumulonimbus. At first, the flight inside the cloud was turbulence-free. Then his glider suddenly became uncontrollable. He was either inverted, in a nosedive, or in a chandelle. The airbrakes became stuck open due to hailstones blocking the orifices. When he landed, the airfield was still covered by hailstones. The wind gusts were between 30 and 40 knots. Everyone on the ground feared for the pilot's life. In the same book, the author narrates that an Italian instructor at Rieti had his students climb 10,000 metres (33,000 ft) inside cumulonimbus so that they get accustomed to them.

As mentioned above, a climb inside a cumulonimbus can be initially very smooth (due to the negative buoyancy of the air parcel) and suddenly become horribly turbulent. As an example, a glider pilot found initially very laminar updraughts and got sucked into the cloud where he encountered accelerations of 18 g and became unconscious.

Due to the phase change of water droplets (to ice), the cumulonimbus top is almost always turbulent. The glider can become covered with ice, and the controls can freeze and remain stuck. Many accidents of this kind have occurred. If the pilot bails out and opens their parachute, they may be sucked upward (or at least held aloft) as happened to William Rankin after ejecting from an F-8 fighter jet and falling into a cumulonimbus (within which his parachute opened).

A skydiver or paraglider pilot under a cumulonimbus is exposed to a potentially deadly risk of being rapidly sucked up to the top the cloud and being suffocated, struck by lightning, or frozen. If they survive, they may suffer irreversible brain damage due to lack of oxygen or require amputation as a consequence of frostbite. German paraglider pilot Ewa Wiśnierska barely survived a climb of more than 9,000 metres (30,000 ft) inside a cumulonimbus.

Commercial aviation

Heavy transportation airplanes may occasionally have to cross a thunderstorm line associated with a cold front or a squall. They may not be able to overfly the cumulonimbus, because at 36,000 feet, the aircraft may be in or near what is known as the coffin corner (stall speed is close to speed of sound), thus making it structurally dangerous to climb higher. However, some cells can rise to 70,000 feet. Another option would be to navigate around the cells. This is strongly discouraged, however, because in the opening, new cells can grow very rapidly and engulf the aircraft. Whenever an aircraft moves to the west and crosses a thunderstorm line, the pilot will first encounter a line of powerful and laminar updraughts (that are not thermal but dynamic). The pilot should refrain from pushing the stick to try to maintain a constant altitude (similar to mountain waves), because pushing the stick can cause the airspeed to increase to the point of hitting the yellow arc (on the airspeed indicator). An airspeed this high is not permissible in turbulent conditions and may lead to break-up of the aircraft. When the pilot exits the updraught zone, he will encounter very strong turbulence due to the shear between rising and sinking air. If the airspeed is too high at this point, the airplane will break apart. The crash of Flight AF 447 is indirectly related to this situation: the pilot opted for the shortest path while crossing the thunderstorm line associated with the Intertropical Convergence Zone, and the pitot tubes iced over. What followed is known.

On-board radars can be deceiving. Hail shafts generate weak radar echoes, which means radar would guide the pilot there—but, they're significantly more dangerous than cloudbursts. Close to the ground, heavy rain (or snow at altitude) tends to dampen turbulence (it is said that when rain comes, most of the danger is gone). So another counter-intuitive recommendation is to fly toward the zone of heavy precipitation or toward the darkest area of the thunderstorm line. This recommendation contradicts the usual use of on-board radars to avoid areas of strong precipitation, which is usually the best course of action. There is no "miracle" solution, and the best option is to avoid these thunderstorm systems by having enough fuel on board, thus reducing the temptation to take a more dangerous route in the interest of fuel savings.

Also, St. Elmo's fires while flying inside cumulonimbus can burn out the on-board electronic equipment and even pierce a wing by melting the metal skin.

Dangers pertaining to supercell thunderstorms

Figure 3 : Picture of a supercell with its characteristics
Figure 4 : Picture of the forward area of a supercell that seems usable by a glider. It is made of small cumulonimbus and an arcus. This area is treacherous because the updraughts will be laminar.

The updraughts inside a cumulonimbus associated with a supercell thunderstorm can reach 45 metres per second (87 kn). This corresponds to the wind speed of a weak hurricane. Moreover, the turbulence inside a cloud can become extreme and break apart an aircraft. Thus, it is extremely dangerous to fly inside such a system.

The thunderstorm system can be divided into two zones in the figure to the left: the precipitation-free zone, located on the left where the airmass has a widespread up motion, and the precipitation zone, on the right where the airmass is sinking. At the point where the two zones meet, there is a wall cloud that could initiate tornadoes. Moreover, even the cumulus congestus associated with a supercell thunderstorm can be very dangerous. Tornadoes can be produced up to 36 kilometres (22 mi) from the main cell.

In the updraught area, the air has a negative buoyancy and is sucked up by a low pressure zone at altitude. Turbulence is annihilated. In particular, in the forward area of the supercell, one can find a flanking line made of cumulus congestus or small cumulonimbus. The cloud base of the flanking line is higher than the base of the main cumulonimbus.

Since the updraught under these clouds (in the flanking line) is mainly dynamic, the airmass being smooth and the cloud base higher, a glider pilot could be tempted to fly in this zone. However, conditions can rapidly become dangerous, since the wall cloud can generate a tornado that will pulverise any aircraft. Moreover, since the rising air is widespread, the glider pilot (especially if flying a low-speed, low-performance glider like a paraglider) may be unable to escape and may be sucked into the cloud up to its top. Thus, the FAA recommends that aircraft should never be closer than 20 miles from severe thunderstorms.

Other dangers pertaining to cumulonimbus

Lightning

Although it rarely happens, a glider can be struck by lightning. Metal sailplanes are Faraday cages and thus should not be destroyed by a lightning strike. However, gliders made of wood or fibreglass can be destroyed. Moreover, modern sailplanes are filled with electronic devices that can be damaged by lightning. Also, any winch launch is discouraged when a thunderstorm is less than 20 kilometres (12 mi) away, because the air is electrified, and the cable will act as a lightning rod.

Hail

Hail can shred a sailplane canopy and seriously damage the wings and fuselage. Hail is barely visible and can be encountered in the updraught zone under the cloud. On 5 August 1977, an airplane pilot was taken by surprise in the vicinity of Colorado Springs by a supercell thunderstorm that produced 20 tornadoes. The pilot was flying in eerily calm air (the updraught zone can be laminar) when he saw the sky transitioning from pale grey to inky black. The pilot heard a loud sound that reoccurred more and more frequently. Then a hailstone pierced the windshield, rendering the pilot semi-unconscious. Eventually, the pilot landed his shredded airplane in a field.

Tornadoes

An EF5 tornado can generate ground winds of unbelievable speed; common sense dictates that an aircraft should never be close to such a meteorological phenomenon. Indeed the wind speed can reach 130 metres per second (250 kn), and one can easily guess that the aircraft can be torn into pieces in such conditions. However, airline transportation aircraft have overflown tornadoes by more than 8,000 feet (2,400 m) without damage. The fact that an airliner does not get destroyed can be explained as follows: tornadoes are violent phenomena only close to the ground and become weaker at height. A glider dared to cross a weak tornado during a soaring contest in Texas in 1967. The cumulonimbus base was at 12,000 feet (3,700 m). The glider crossed an extremely turbulent zone and ended up in a turbulence-free zone inverted. The controls were not responding, and the pilot contemplated abandoning the aircraft. After some time and a big fright, the controls started to respond again, and the pilot was able to continue his flight. Pilots in the vicinity did not notice anything.

On 6 October 1981 a Fokker aircraft hit a tornado which occurred in a supercell near the town of Moerdijk in the Netherlands, all 17 occupants of the aircraft were killed.

An empirical criterion for tornado formation has been developed by Dan Sowa from Northwest Orient Airlines as follows: the cumulonimbus overshooting top must enter into the stratosphere by at least 10000 feet. This criterion is, however, incorrect and the Sonnac tornado is a counter-example. It reached level EF2 while being generated by a small cumulonimbus that did not attain 9,000 metres (30,000 ft).

Myths and truth about cumulonimbus

Figure 5 : Picture of a tornado in South Oklahoma City, Oklahoma shortly before it entered Moore shot from a precipitation-free sunlit area. An absent-minded glider pilot would probably have found smooth and moderate updraughts in this sunlit zone.

Conventional wisdom

As a result of a faulty generalisation, it is very often incorrectly said that cumulonimbus and the updraughts under them are always turbulent. This fallacy originates from the fact that cumulonimbus are actually extremely turbulent at high altitude, and therefore, one might falsely deduce that cumulonimbus are turbulent at all altitudes. Reliable studies and glider pilots' experience have demonstrated that updraughts under cumulonimbus were generally smooth. As seen above, updraughts under a cumulonimbus are often dynamic and thus will be very smooth. The phenomenon is enhanced under the weak echo region of a supercell thunderstorm that is extremely dangerous. However, this phenomenon is little known in the aviation world. Thus, a widespread view in the aeronautical community is that cumulonimbus are always associated with very strong turbulence (at all altitudes) and severe thunderstorms. For example, Gil Roy, in a book endorsed by the fr:Fédération française de vol à voile, claims that:

Les cumulo-nimbus [sic] sont le siège de très violents orages. La partie avant, baptisée " front d'orage " est le théâtre de très fortes turbulences mais aussi de puissantes ascendances. (Translation: The cumulo-nimbus [sic] are always the seat of very violent thunderstorms. The forward area called thunderstorm front is the site of very strong turbulence but also of powerful updraughts.)

Also, the author talks about cumulo-nimbus [sic] of gigantic size that can reach a height of several thousand metres. While the word "several" isn't very precise, a thickness of 8000 metres is fairly typical for a cumulonimbus, with some as thick as 20000 metres or more. Moreover, the majority of cumulonimbus are associated with weak pulse thunderstorms or even simple showers without electric phenomena.

The reference to the thunderstorm front corresponds to the outflow boundary associated with downbursts that are indeed very dangerous and are the site of vortices associated with the Kelvin-Helmholtz instability at the junction between updraughts and downdraughts. However, in front of the thunderstorm, updraughts are generally laminar due to the negative buoyancy of air parcels (see above).

Also, the LUXORION web site states:

Les cumulonimbus provoquent toujours une turbulence sévère [...] Elle peut être rencontrée dans les basses couches et devancer le cumulonimbus de 10 à 25 km. (Translation: The cumulonimbus always generate a severe turbulence [...]. It can be encountered in the lower layers and get ahead of the cumulonimbus by 10 to 25 km.)

Such a claim is too broad and again contradicts the fact that updraughts in front of a thunderstorm are often laminar. However, it is true that the upper layers are almost always turbulent. However, in most cases, the aforesaid turbulence is not extreme. Along the same lines, Didier Morieux states:

Le cumulonimbus [...] est aussi le siège d'ascendances et de descendances pouvant atteindre des vitesses de 15 à 20 m/s donnant lieu à une turbulence considérable, susceptible de mettre en péril la structure des avions les plus solides.(Translation: The cumulonimbus is also the site of updraughts and downdraughts of speeds of 15 to 20 m/s generating considerable turbulence, likely to imperil the structure of most robust airplanes.)

Dennis Pagen is even more explicit. He states:

All the updrafts and downdrafts in a thunderstorm create considerable turbulence due to shear. All we have to do is think of the velocities involved and you can imagine the severity of the turbulence. Thunderstorm turbulence can (and has) tear apart airplanes.

The International cloud atlas soothes these claims: it simply states that "la turbulence is often very strong " below the cloud.

Serious hazard to glider pilots

A glider pilot convinced that cumulonimbus are always violent risks getting a nasty surprise. If he flies under the flanking line of a supercell thunderstorm and finds that the air is very smooth and updraughts are moderate, he may falsely infer that he is safe and not under a cumulonimbus; since he believes cumulonimbus are always turbulent. He may thus not realise when he is under a secondary cumulonimbus that can suck him inside the cloud, and he may encounter a wall cloud that could generate a tornado that could disintegrate his fragile skiff as shown in Figure 5. Dominique Musto cautions paraglider pilots (that might otherwise be swayed by the above myth) against the false sensation of safety in a region of extended updraughts that are rather weak as follows:

Pourtant malgré un ciel sombre et l'absence de soleil, les ascendances sont douces et généralisées dans tout le secteur. Quelque chose cloche ! Si nous ne réagissons pas très vite pour descendre, une main invisible risque de nous happer et de nous jeter en enfer! (Translation: However, notwithstanding a dark sky and lack of sunlight, the updraughts are smooth and extended in the entire area. Something is wrong. If we do not react quickly and descend, an invisible hand is likely to grab us and throw us into hell!)

This quotation summarises in three sentences the often-insidious dangers associated with cumulonimbus, dangers that are exacerbated for paraglider pilots, as German paraglider pilot Ewa Wiśnierska experienced. She survived climbing above 9,000 metres (30,000 ft) inside a cumulonimbus. A nearby fellow pilot caught in the same weather event wasn't so fortunate.

As well, in 2014, the 66 years old general Paolo Antoniazzi died after its paraglider got sucked into a cumulonimbus up to the altitude of 9,300 metres (30,500 ft).

Forerunners of a thunderstorm

The above quotation puts informally the harbingers of a thunderstorm. So a cumulonimbus acts as an enormous thermal machine that sucks up the air in the front (left side of Figure 3) and violently throws it out in the back through downbursts (right side of Figure 3). Consequently, a broad area of updraughts will be located in front of the thunderstorm. Typically, in a humid airmass, the updraughts will be on the order of 1 m/s; and in a dry air mass, they will be on the order of 2 to 3 m/s. Therefore, when a glider pilot is in an area where "updraughts are everywhere" and he is close to large clouds (that can be cumulus congestus), he is likely in the vicinity of a building thunderstorm.

Associated gravity waves

The downbursts associated with cumulonimbus can generate gravity waves far way from thunderstorms. These gravity waves can be felt up to 50 kilometres (31 mi) away and in some conditions several hundreds of kilometres away. A severe thunderstorm generating these gravity waves located at more than 40 kilometres (25 mi) away (according to Federal Aviation Administration recommendations) should not affect the safety of aircraft this far from the thunderstorm. These gravity waves can be modelled in the same manner as mountain waves and can be usable by a glider pilot.

Utilising cumulonimbus in cross-country flight or other

Exploitation of "small" cumulonimbus

Small cumulonimbus can relatively safely be exploited by experienced glider pilots. They generate moderate updraughts that are generally laminar. Thus, pulse-like summer thunderstorms can be used during cross-country flights, since the glider will move away from the cumulonimbus after having (in theory) climbed up to 500 feet below the cloud base (the maximum permissible height in the United States) and the passage of the glider in the proximity of the thunderstorm will be short. For example, during an official contest of the Soaring Society of America, pilots openly played with the cumulonimbus (and even with the updraughts contiguous to downbursts) and boasted about it. However, a rule of thumb says that the distance between two thermals is equal to three times the height of the cloud. Consequently, a cumulonimbus that is 13 km thick will eliminate any convective activity over a radius of approximately 40 km. Most gliders cannot perform such long glides, and therefore, an encounter with a pulse-like thunderstorm in a glider will often be followed soon by the end of the flight.

Shear exploitation in the vicinity of a downburst

Figure 3.22 from this reference shows the presence of a rotor outside a downburst. A more-than-foolhardy pilot could easily locate this updraught and exploit it. However, this photograph will dissuade any sensible pilot from using such monstrosities. Downbursts are the most significant hazard pertaining to thunderstorms. Moreover, if for any reason the pilot must land (hail storm or other), he will have to cross the downburst immediately above him and there will be a greatly increased chance of crashing – due to the unpredictable decrease of the airspeed. Moreover, if the glider transitions from the updraught to the downdraught, severe turbulence will occur due to the Kelvin-Helmholtz instability in the shear area. However, pilots have nonetheless exploited such updraughts.

Exploitation of flanking lines

Reckless pilots have exploited squalls by flying in front of thunderstorm systems as if flying along a ridge. The pilot really must land at an airport and put the glider in a hangar; the squall line will catch him again soon and imperil the glider if it is not protected. Dennis Pagen performed a similar flight in front of a supercell cumulonimbus during the Preliminaries of the hang glider 1990 World championship in Brazil where he was able to fly 35 km at high speed without a turn. Pagen acknowledges that his achievement was very risky, since hang gliders (and even more so paragliders) are significantly slower than sailplanes and can much more easily be sucked inside the cloud.

Conclusion

The only cumulonimbus clouds that could be usable by a glider pilot, subject to all necessary reservations, might be isolated small cumulonimbus or at a pinch the flanking lines associated with strong thunderstorms. However, examples above show that a seemingly innocuous cloud can rapidly become very dangerous. Squalls and supercell thunderstorms are definitely deadly hazards to uninformed pilots. Based on visual flight rules, flights in pre-storm areas must be visual; the pilots must be able to watch the evolution of a thundercloud and take the necessary actions of avoidance or to quickly land when appropriate.

The above examples demonstrate that the different phenomena associated with cumulonimbus can jeopardise any type of aircraft and its occupants when the pilot flies in the vicinity and especially inside a thundercloud. An airplane pilot should never come near a cumulonimbus.

Oxide

From Wikipedia, the free encyclopedia
The unit cell of rutile, an important oxide of titanium. Ti(IV) centers are grey; oxygen centers are red. Notice that oxygen forms three bonds to titanium and titanium forms six bonds to oxygen.

An oxide (/ˈɒksd/) is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of –2) of oxygen, an O2– ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of Al2O3 (called a passivation layer) that protects the foil from further oxidation.

Stoichiometry

Oxides are extraordinarily diverse in terms of stoichiometries (the measurable relationship between reactants and chemical equations of an equation or reaction) and in terms of the structures of each stoichiometry. Most elements form oxides of more than one stoichiometry. A well known example is carbon monoxide and carbon dioxide. This applies to binary oxides, that is, compounds containing only oxide and another element. Far more common than binary oxides are oxides of more complex stoichiometries. Such complexity can arise by the introduction of other cations (a positively charged ion, i.e. one that would be attracted to the cathode in electrolysis) or other anions (a negatively charged ion). Iron silicate, Fe2SiO4, the mineral fayalite, is one of many examples of a ternary oxide. For many metal oxides, the possibilities of polymorphism and nonstoichiometry exist as well. The commercially important dioxides of titanium exists in three distinct structures, for example. Many metal oxides exist in various nonstoichiometric states. Many molecular oxides exist with diverse ligands as well.

For simplicity sake, most of this article focuses on binary oxides.

Formation

Oxides are associated with all elements except a few noble gases. The pathways for the formation of this diverse family of compounds are correspondingly numerous.

Metal oxides

Many metal oxides arise by decomposition of other metal compounds, e.g. carbonates, hydroxides, and nitrates. In the making of calcium oxide, calcium carbonate (limestone) breaks down upon heating, releasing carbon dioxide:

The reaction of elements with oxygen in air is a key step in corrosion relevant to the commercial use of iron especially. Almost all elements form oxides upon heating with oxygen atmosphere. For example, zinc powder will burn in air to give zinc oxide:

The production of metals from ores often involves the production of oxides by roasting (heating) metal sulfide minerals in air. In this way, MoS2 (molybdenite) is converted to molybdenum trioxide, the precursor to virtually all molybdenum compounds:

Noble metals (such as gold and platinum) are prized because they resist direct chemical combination with oxygen.

Non-metal oxides

Important and prevalent nonmetal oxides are carbon dioxide and carbon monoxide. These species form upon full or partial oxidation of carbon or hydrocarbons. With a deficiency of oxygen, the monoxide is produced:

With excess oxygen, the dioxide is the product, the pathway proceeds by the intermediacy of carbon monoxide:

Elemental nitrogen (N2) is difficult to convert to oxides, but the combustion of ammonia gives nitric oxide, which further reacts with oxygen:

These reactions are practiced in the production of nitric acid, a commodity chemical.

The chemical produced on the largest scale industrially is sulfuric acid. It is produced by the oxidation of sulfur to sulfur dioxide, which is separately oxidized to sulfur trioxide:

Finally the trioxide is converted to sulfuric acid by a hydration reaction:

Structure

Oxides have a range of structures, from individual molecules to polymeric and crystalline structures. At standard conditions, oxides may range from solids to gases. Solid oxides of metals usually have polymeric structures at ambient conditions.

Molecular oxides

Although most metal oxides are crystalline solids, some oxides are molecules. Examples of molecular oxides are carbon dioxide and carbon monoxide. All simple oxides of nitrogen are molecular, e.g., NO, N2O, NO2 and N2O4. Phosphorus pentoxide is a more complex molecular oxide with a deceptive name, the real formula being P4O10. Tetroxides are rare, with a few more common examples being iridium tetroxide, ruthenium tetroxide, osmium tetroxide, and xenon tetroxide.

Reactions

Reduction

Reduction of metal oxide to the metal is practiced on a large scale in the production of some metals. Many metal oxides convert to metals simply by heating, (see Thermal decomposition). For example, silver oxide decomposes at 200 °C:

Most often, however, metals oxides are reduced by a chemical reagent. A common and cheap reducing agent is carbon in the form of coke. The most prominent example is that of iron ore smelting. Many reactions are involved, but the simplified equation is usually shown as:

Some metal oxides dissolve in the presence of reducing agents, which can include organic compounds. Reductive dissolution of ferric oxides is integral to geochemical phenomena such as the iron cycle.

Hydrolysis and dissolution

Because the M-O bonds are typically strong, metal oxides tend to be insoluble in solvents, though they may be attacked by aqueous acids and bases.

Dissolution of oxides often gives oxyanions. Adding aqueous base to P4O10 gives various phosphates. Adding aqueous base to MoO3 gives polyoxometalates. Oxycations are rarer, some examples being nitrosonium (NO+), vanadyl (VO2+), and uranyl (UO2+2). Of course many compounds are known with both oxides and other groups. In organic chemistry, these include ketones and many related carbonyl compounds. For the transition metals, many oxo complexes are known as well as oxyhalides.

Nomenclature and formulas

The chemical formulas of the oxides of the chemical elements in their highest oxidation state are predictable and are derived from the number of valence electrons for that element. Even the chemical formula of O4, tetraoxygen, is predictable as a group 16 element. One exception is copper, for which the highest oxidation state oxide is copper(II) oxide and not copper(I) oxide. Another exception is fluoride, which does not exist as one might expect—as F2O7—but as OF2.

Thermodynamic diagrams

From Wikipedia, the free encyclopedia https://en.wikipedia.org/wiki/Thermodynamic_diagrams Thermodynamic diagrams are diagrams used to repr...