Amethyst

From Wikipedia, the free encyclopedia

https://en.wikipedia.org/wiki/Amethyst

 

Amethyst
Amethyst cluster from Artigas, Uruguay
General
Category	Silicate mineral
Formula (repeating unit)	Silica (silicon dioxide, SiO2)
Crystal system	Trigonal
Crystal class	Trapezohedral (32)
Space group	P3221 (no. 154)
Identification
Color	Purple, violet, dark purple
Crystal habit	6 sided prism ending in 6 sided pyramid (typical)
Twinning	Dauphine law, Brazil law, and Japan law
Cleavage	None
Fracture	Conchoidal
Mohs scale hardness	7 (lower in impure varieties)
Luster	Vitreous/glassy
Streak	White
Diaphaneity	Transparent to translucent
Specific gravity	2.65 constant; variable in impure varieties
Optical properties	Uniaxial (+)
Refractive index	nω = 1.543–1.553 nε = 1.552–1.554
Birefringence	+0.009 (B-G interval)
Pleochroism	Weak to moderate purple/reddish purple
Melting point	1650±75 °C
Solubility	Insoluble in common solvents
Other characteristics	Piezoelectric

Amethyst is a violet variety of quartz. The name comes from the Koine Greek αμέθυστος amethystos from α- a-, "not" and μεθύσκω (Ancient Greek) methysko / μεθώ metho (Modern Greek), "intoxicate", a reference to the belief that the stone protected its owner from drunkenness. Ancient Greeks wore amethyst and carved drinking vessels from it in the belief that it would prevent intoxification.

Amethyst, a semiprecious stone, is often used in jewelry.

Structure

Amethyst is a purple variety of quartz (SiO
₂) and owes its violet color to irradiation, impurities of iron (Fe³⁺
) and in some cases other transition metals, and the presence of other trace elements, which result in complex crystal lattice substitutions. The irradiation causes the iron Fe³⁺
ions that replace Si in the lattice to lose an electron and form a [FeO
₄]⁰ color center. Amethyst is a three-dimensional network of tetrahedra where the silicon atoms are in the center and are surrounded by four oxygen atoms located at the vertices of a tetrahedron. This structure is quite rigid and results in quartz's hardness and resistance to weathering. The hardness of the mineral is the same as quartz, thus making it suitable for use in jewelry.

Hue and tone

Amethyst occurs in primary hues from a light lavender or pale violet to a deep purple. Amethyst may exhibit one or both secondary hues, red and blue. High-quality amethyst can be found in Siberia, Sri Lanka, Brazil, Uruguay, and the Far East. The ideal grade, called "Deep Siberian", has a primary purple hue of around 75–80%, with 15–20% blue and (depending on the light source) red secondary hues. "Rose de France" is defined by its markedly light shade of the purple, reminiscent of a lavender / lilac shade. These pale colors were once considered undesirable, but have recently become popular due to intensive marketing.

Green quartz is sometimes called green amethyst; the scientific name is prasiolite. Other names for green quartz are vermarine and lime citrine.

Amethyst frequently shows color zoning, with the most intense color typically found at the crystal terminations. One of gem cutters' tasks is to make a finished product with even color. Sometimes, only a thin layer of a natural, uncut amethyst is violet colored, or the color is very uneven. The uncut gem may have only a small portion that is suitable for faceting.

Natural purple/violet amethyst

 

Heat-treated amethyst

The color of amethyst has been demonstrated to result from substitution by irradiation of trivalent iron (Fe³⁺) for silicon in the structure, in the presence of trace elements of large ionic radius, and to a certain extent, the amethyst color can naturally result from displacement of transition elements even if the iron concentration is low. Natural amethyst is dichroic in reddish violet and bluish violet, but when heated, turns yellow-orange, yellow-brown, or dark brownish and may resemble citrine, but loses its dichroism, unlike genuine citrine. When partially heated, amethyst can result in ametrine.

Amethyst can fade in tone if overexposed to light sources, and can be artificially darkened with adequate irradiation. It does not fluoresce under either short-wave or long-wave UV light.

Geographic distribution

Amethyst is found in many locations around the world. Between 2000 and 2010, the greatest production was from Marabá and Pau d'Arco, Pará, and the Paraná Basin, Rio Grande do Sul, Brazil; Sandoval, Santa Cruz, Bolivia; Artigas, Uruguay; Kalomo, Zambia; and Thunder Bay, Ontario. Lesser amounts are found in many other locations in Africa, Brazil, Spain, Argentina, Russia, Afghanistan, South Korea, Mexico, and the United States.

Main amethyst-producing countries

Amethyst is produced in abundance in the state of Rio Grande do Sul in Brazil where it occurs in large geodes within volcanic rocks.

Many of the hollow agates of southwestern Brazil and Uruguay contain a crop of amethyst crystals in the interior. Artigas, Uruguay and neighboring Brazilian state Rio Grande do Sul are large world producers, with lesser quantities mined in Minas Gerais and Bahia states.

An amethyst geode that formed when large crystals grew in open spaces inside the rock

The largest amethyst geode found as of 2007 was the Empress of Uruguay, found in Artigas, Uruguay in 2007. It stands at a height of 3.27 meters, lies open along its length, and weighs 2.5 tons.

Amethyst is also found and mined in South Korea. The large opencast amethyst vein at Maissau, Lower Austria, was historically important, but is no longer included among significant producers. Much fine amethyst comes from Russia, especially near Mursinka in the Ekaterinburg district, where it occurs in drusy cavities in granitic rocks. Amethyst was historically mined in many localities in south India, though these are no longer significant producers. One of the largest global amethyst producers is Zambia in southern Africa, with an annual production around 1000 tons.

Amethyst occurs at many localities in the United States. The most important production is at Four Peaks, Gila and Maricopa Counties, Arizona, and Jackson's Crossroads, Wilkes County, Georgia.

Smaller occurrences have been reported in the Red Feather Lakes, near Fort Collins, Colorado; Amethyst Mountain, Texas; Yellowstone National Park; Delaware County, Pennsylvania; Haywood County, North Carolina; Deer Hill and Stow, Maine, and in the Lake Superior region of Minnesota, Wisconsin, and Michigan.

Amethyst is relatively common in the Canadian provinces of Ontario and Nova Scotia. The largest amethyst mine in North America is located in Thunder Bay, Ontario.

Amethyst is the official state gemstone of South Carolina. Several South Carolina amethysts are on display at the Smithsonian Museum of Natural History.

History

Roman intaglio engraved gem of Caracalla in amethyst, once in the Treasury of Sainte-Chapelle

 

Uninscribed amethyst scarab at the center of a string of amethyst ball beads from Egypt

Amethyst was used as a gemstone by the ancient Egyptians and was largely employed in antiquity for intaglio engraved gems.

The ancient Greeks believed amethyst gems could prevent intoxication, while medieval European soldiers wore amethyst amulets as protection in battle in the belief that amethysts heal people and keep them cool-headed. Beads of amethyst were found in Anglo-Saxon graves in England. Anglican bishops wear an episcopal ring often set with an amethyst, an allusion to the description of the Apostles as "not drunk" at Pentecost in Acts 2:15.

A large geode, or "amethyst-grotto", from near Santa Cruz in southern Brazil was presented at a 1902 exhibition in Düsseldorf, Germany.

Synthetic amethyst

Synthetic (laboratory-grown) amethyst is produced by a synthesis method called hydrothermal growth, which grows the crystals inside a high-pressure autoclave.

Synthetic amethyst is made to imitate the best quality amethyst. Its chemical and physical properties are the same as those of natural amethyst, and it cannot be differentiated with absolute certainty without advanced gemmological testing (which is often cost-prohibitive). One test based on "Brazil law twinning" (a form of quartz twinning where right- and left-hand quartz structures are combined in a single crystal) can be used to identify most synthetic amethyst rather easily. Synthesizing twinned amethyst is possible, but this type is not available in large quantities in the market.

Treated amethyst is produced by gamma ray, X-ray, or electron-beam irradiation of clear quartz (rock crystal), which has been first doped with ferric impurities. Exposure to heat partially cancels the irradiation effects and amethyst generally becomes yellow or even green. Much of the citrine, cairngorm, or yellow quartz of jewelry is said to be merely "burnt amethyst".

Cultural history

Ancient Greece

Emerald cut amethyst

The Greek word amethystos may be translated as "not drunken", from Greek a-, "not" + methustos, "intoxicated". Amethyst was considered to be a strong antidote against drunkenness. In his poem "L'Amethyste, ou les Amours de Bacchus et d'Amethyste" (Amethyst or the loves of Bacchus and Amethyste), the French poet Rémy Belleau (1528–1577) invented a myth in which Bacchus, the god of intoxication, of wine, and grapes was pursuing a maiden named Amethyste, who refused his affections. Amethyste prayed to the gods to remain chaste, a prayer which the chaste goddess Diana answered, transforming her into a white stone. Humbled by Amethyste's desire to remain chaste, Bacchus poured wine over the stone as an offering, dyeing the crystals purple.

Variations of the story include that Dionysus had been insulted by a mortal and swore to slay the next mortal who crossed his path, creating fierce tigers to carry out his wrath. The mortal turned out to be a beautiful young woman, Amethystos, who was on her way to pay tribute to Artemis. Her life was spared by Artemis, who transformed the maiden into a statue of pure crystalline quartz to protect her from the brutal claws. Dionysus wept tears of wine in remorse for his action at the sight of the beautiful statue. The god's tears then stained the quartz purple.

This myth and its variations are not found in classical sources. However, the goddess Rhea does present Dionysus with an amethyst stone to preserve the wine-drinker's sanity in historical text.

Other cultural associations

Tibetans consider amethyst sacred to the Buddha and make prayer beads from it. Amethyst is considered the birthstone of February. In the Middle Ages, it was considered a symbol of royalty and used to decorate English regalia. In the Old World, amethyst was considered one of the cardinal gems, in that it was one of the five gemstones considered precious above all others, until large deposits were found in Brazil.

Value

Amethyst geodes displayed at the 2012 Tucson Gem & Mineral Show

Until the 18th century, amethyst was included in the cardinal, or most valuable, gemstones (along with diamond, sapphire, ruby, and emerald), but since the discovery of extensive deposits in locations such as Brazil, it has lost most of its value. It is now considered a semiprecious stone.

Collectors look for depth of color, possibly with red flashes if cut conventionally. As amethyst is readily available in large structures, the value of the gem is not primarily defined by carat weight. This is different from most gemstones, since the carat weight typically exponentially increases the value of the stone. The biggest factor in the value of amethyst is the color displayed.

The highest-grade amethyst (called deep Russian) is exceptionally rare. When one is found, its value is dependent on the demand of collectors; however, the highest-grade sapphires or rubies are still orders of magnitude more expensive than amethyst.

Handling and care

The most suitable setting for gem amethyst is a prong or a bezel setting. The channel method must be used with caution.

Amethyst has a good hardness, and handling it with proper care will prevent any damage to the stone. Amethyst is sensitive to strong heat and may lose or change its colour when exposed to prolonged heat or light. Polishing the stone or cleaning it by ultrasonic or steamer must be done with caution.

Footnotes

1. 
   

The earliest reference to amethyst as a symbol of sobriety is in a poem by Asclepiades of Samos (born c. 320 BCE).

An epigram by Plato the Younger also mentions amethyst in connection with drinking: "The stone is an amethyst; but I, the tipler Dionysus, say, "Let it either persuade me to be sober, or let it learn to get drunk."

Pliny says about amethysts: "The falsehoods of the magicians would persuade us that these stones are preventive of inebriety, and that it is from this that they have derived their name." which is why wine goblets were often carved from it.

The "myth" of Amethyste and Bacchus was invented by the French poet Remy Belleau (1528–1577).

Ruby

From Wikipedia, the free encyclopedia

https://en.wikipedia.org/wiki/Ruby

Ruby
A ruby crystal from Dodoma Region, Tanzania

Main ruby producing countries

Ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum (aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sapphires. Ruby is one of the traditional cardinal gems, alongside amethyst, sapphire, emerald, and diamond. The word ruby comes from ruber, Latin for red. The color of a ruby is due to the element chromium.

Some gemstones that are popularly or historically called rubies, such as the Black Prince's Ruby in the British Imperial State Crown, are actually spinels. These were once known as "Balas rubies".

The quality of a ruby is determined by its color, cut, and clarity, which, along with carat weight, affect its value. The brightest and most valuable shade of red, called blood-red or pigeon blood, commands a large premium over other rubies of similar quality. After color follows clarity: similar to diamonds, a clear stone will command a premium, but a ruby without any needle-like rutile inclusions may indicate that the stone has been treated. Ruby is the traditional birthstone for July and is usually pinker than garnet, although some rhodolite garnets have a similar pinkish hue to most rubies. The world's most valuable ruby to be sold at auction is the Sunrise Ruby, which sold for US$34.8 million.

Physical properties

Crystal structure of rubies

Rubies have a hardness of 9.0 on the Mohs scale of mineral hardness. Among the natural gems, only moissanite and diamond are harder, with diamond having a Mohs hardness of 10.0 and moissanite falling somewhere in between corundum (ruby) and diamond in hardness. Sapphire, ruby, and pure corundum are α-alumina, the most stable form of Al₂O₃, in which 3 electrons leave each aluminium ion to join the regular octahedral group of six nearby O²⁻ ions; in pure corundum this leaves all of the aluminium ions with a very stable configuration of no unpaired electrons or unfilled energy levels, and the crystal is perfectly colorless, and transparent except for flaws.

Crystal structure of ruby showing the substitution of Al³⁺ ions (blue) with Cr³⁺ (red). The substitution density of Cr³⁺ ions in this model is approximately 2%, approximating the maximum doping normally encountered.

When a chromium atom replaces an occasional aluminium atom, it too loses 3 electrons to become a chromium³⁺ ion to maintain the charge balance of the Al₂O₃ crystal. However, the Cr³⁺ ions are larger and have electron orbitals in different directions than aluminium. The octahedral arrangement of the O²⁻ ions is distorted, and the energy levels of the different orbitals of those Cr³⁺ ions are slightly altered because of the directions to the O²⁻ ions. Those energy differences correspond to absorption in the ultraviolet, violet, and yellow-green regions of the spectrum.

Transmittance of ruby in optical and near-IR spectra. Note the two broad violet and yellow-green absorption bands and one narrow absorption band at the wavelength of 694 nm, which is the wavelength of the ruby laser.

If one percent of the aluminium ions are replaced by chromium in ruby, the yellow-green absorption results in a red color for the gem. Additionally, absorption at any of the above wavelengths stimulates fluorescent emission of 694-nanometer-wavelength red light, which adds to its red color and perceived luster. The chromium concentration in artificial rubies can be adjusted (in the crystal growth process) to be ten to twenty times less than in the natural gemstones. Theodore Maiman says that "because of the low chromium level in these crystals they display a lighter red color than gemstone ruby and are referred to as pink ruby."

After absorbing short-wavelength light, there is a short interval of time when the crystal lattice of ruby is in an excited state before fluorescence occurs. If 694-nanometer photons pass through the crystal during that time, they can stimulate more fluorescent photons to be emitted in-phase with them, thus strengthening the intensity of that red light. By arranging mirrors or other means to pass emitted light repeatedly through the crystal, a ruby laser in this way produces a very high intensity of coherent red light.

All natural rubies have imperfections in them, including color impurities and inclusions of rutile needles known as "silk". Gemologists use these needle inclusions found in natural rubies to distinguish them from synthetics, simulants, or substitutes. Usually, the rough stone is heated before cutting. These days, almost all rubies are treated in some form, with heat treatment being the most common practice. Untreated rubies of high quality command a large premium.

Some rubies show a three-point or six-point asterism or "star". These rubies are cut into cabochons to display the effect properly. Asterisms are best visible with a single-light source and move across the stone as the light moves or the stone is rotated.

Maharlika Star Ruby 10,820 Carats. Largest Ruby with Star Asterism

Versus pink sapphire

Generally, gemstone-quality corundum in all shades of red, including pink, are called rubies. However, in the United States, a minimum color saturation must be met to be called a ruby; otherwise, the stone will be called a pink sapphire. Drawing a distinction between rubies and pink sapphires is relatively new, having arisen sometime in the 20th century. Often, the distinction between ruby and pink sapphire is not clear and can be debated. As a result of the difficulty and subjectiveness of such distinctions, trade organizations such as the International Colored Gemstone Association (ICGA) have adopted the broader definition for ruby which encompasses its lighter shades, including pink.

Occurrence and mining

Historically, rubies have been mined in Thailand, in the Pailin and Samlout District of Cambodia, as well as in Afghanistan, Australia, Brazil, Colombia, India, Namibia, Japan, and Scotland. After the Second World War, ruby deposits were found in Madagascar, Mozambique, Nepal, Pakistan, Tajikistan, Tanzania, and Vietnam.

The Republic of North Macedonia is the only country in mainland Europe to have naturally occurring rubies. They can mainly be found around the city of Prilep. Macedonian rubies have a unique raspberry color.

A few rubies have been found in the U.S. states of Montana, North Carolina, South Carolina and Wyoming.

Spinel, another red gemstone, is sometimes found along with rubies in the same gem gravel or marble. Red spinels may be mistaken for rubies by those lacking experience with gems. However, the finest red spinels, now heavily sought, can have values approaching all but the finest examples of ruby. The Mogok Valley in Upper Myanmar (Burma) was for centuries the world's main source for rubies. That region has produced some exceptional rubies; however, in recent years few good rubies have been found. In central Myanmar, the area of Mong Hsu began producing rubies during the 1990s and rapidly became the world's main ruby mining area. The most recently found ruby deposit in Myanmar is in Namya (Namyazeik) located in the northern state of Kachin.

In Pakistani Kashmir there are vast proven reserves of millions of rubies, worth up to half a billion dollars. However, as of 2017 there was only one mine (at Chitta Katha) due to lack of investment. In Afghanistan, rubies are mined at Jegdalek. In 2017 the Aappaluttoq mine in Greenland began running.

The rubies in Greenland are said to be among the oldest in the world at approximately 3 billion years old. The Aappaluttoq mine in Greenland is located 160 kilometers south of Nuuk, the capital of Greenland. The rubies are traceable from mine to market.

The Montepuez ruby mine in northeastern Mozambique is situated on one of the most significant ruby deposits in the world, although, rubies were only discovered here for the first time in 2009. In less than a decade, Mozambique has become the world's most productive source for gem-quality ruby.

Factors affecting value

Rubies, as with other gemstones, are graded using criteria known as the four Cs, namely color, cut, clarity and carat weight. Rubies are also evaluated on the basis of their geographic origin.

Color

In the evaluation of colored gemstones, color is the most important factor. Color divides into three components: hue, saturation and tone. Hue refers to color as we normally use the term. Transparent gemstones occur in the pure spectral hues of red, orange, yellow, green, blue, violet. In nature, there are rarely pure hues, so when speaking of the hue of a gemstone, we speak of primary and secondary and sometimes tertiary hues. Ruby is defined to be red. All other hues of the gem species corundum are called sapphire. Ruby may exhibit a range of secondary hues, including orange, purple, violet, and pink.

• 
  A naturally occurring ruby crystal
   
• 
  Natural ruby with inclusions
   
• 
  A cut pink ruby
   
• 
  Purple rubies

Clarity

Because rubies host many inclusions, their clarity is evaluated by the inclusions’ size, number, location, and visibility. Rubies with the highest clarity grades are known as “eye-clean,” because their inclusions are the least visible to the naked human eye. Rubies may also have thin, intersecting inclusions called silk. Silk can scatter light, brightening the gem's appearance, and the presence of silk can also show whether a ruby has been previously heat treated, since intense heat will degrade a ruby's silk.

Treatments and enhancements

Improving the quality of gemstones by treating them is common practice. Some treatments are used in almost all cases and are therefore considered acceptable. During the late 1990s, a large supply of low-cost materials caused a sudden surge in supply of heat-treated rubies, leading to a downward pressure on ruby prices.

Improvements used include color alteration, improving transparency by dissolving rutile inclusions, healing of fractures (cracks) or even completely filling them.

The most common treatment is the application of heat. Most rubies at the lower end of the market are heat treated to improve color, remove purple tinge, blue patches, and silk. These heat treatments typically occur around temperatures of 1800 °C (3300 °F). Some rubies undergo a process of low tube heat, when the stone is heated over charcoal of a temperature of about 1300 °C (2400 °F) for 20 to 30 minutes. The silk is partially broken, and the color is improved.

Another treatment, which has become more frequent in recent years, is lead glass filling. Filling the fractures inside the ruby with lead glass (or a similar material) dramatically improves the transparency of the stone, making previously unsuitable rubies fit for applications in jewelry. The process is done in four steps:

1. The rough stones are pre-polished to eradicate all surface impurities that may affect the process
2. The rough is cleaned with hydrogen fluoride
3. The first heating process during which no fillers are added. The heating process eradicates impurities inside the fractures. Although this can be done at temperatures up to 1400 °C (2500 °F) it most likely occurs at a temperature of around 900 °C (1600 °F) since the rutile silk is still intact.
4. The second heating process in an electrical oven with different chemical additives. Different solutions and mixes have shown to be successful; however, mostly lead-containing glass-powder is used at present. The ruby is dipped into oils, then covered with powder, embedded on a tile and placed in the oven where it is heated at around 900 °C (1600 °F) for one hour in an oxidizing atmosphere. The orange colored powder transforms upon heating into a transparent to yellow-colored paste, which fills all fractures. After cooling the color of the paste is fully transparent and dramatically improves the overall transparency of the ruby.

If a color needs to be added, the glass powder can be "enhanced" with copper or other metal oxides as well as elements such as sodium, calcium, potassium etc.

The second heating process can be repeated three to four times, even applying different mixtures. When jewelry containing rubies is heated (for repairs) it should not be coated with boracic acid or any other substance, as this can etch the surface; it does not have to be "protected" like a diamond.

The treatment can be identified by noting bubbles in cavities and fractures using a 10× loupe.

Synthesis and imitation

Artificial ruby under a normal light (top) and under a green laser light (bottom). Red light is emitted.

In 1837, Gaudin made the first synthetic rubies by fusing potash alum at a high temperature with a little chromium as a pigment. In 1847, Ebelmen made white sapphire by fusing alumina in boric acid. In 1877, Edmond Frémy and industrial glass-maker Charles Feil made crystal corundum from which small stones could be cut. In 1887, Fremy and Auguste Verneuil manufactured artificial ruby by fusing BaF₂ and Al₂O₃ with a little chromium at red heat.

In 1903, Verneuil announced he could produce synthetic rubies on a commercial scale using this flame fusion process, later also known as the Verneuil process. By 1910, Verneuil's laboratory had expanded into a 30 furnace production facility, with annual gemstone production having reached 1,000 kilograms (2,000 lb) in 1907.

Other processes in which synthetic rubies can be produced are through Czochralski's pulling process, flux process, and the hydrothermal process. Most synthetic rubies originate from flame fusion, due to the low costs involved. Synthetic rubies may have no imperfections visible to the naked eye but magnification may reveal curved striae and gas bubbles. The fewer the number and the less obvious the imperfections, the more valuable the ruby is; unless there are no imperfections (i.e., a perfect ruby), in which case it will be suspected of being artificial. Dopants are added to some manufactured rubies so they can be identified as synthetic, but most need gemological testing to determine their origin.

Synthetic rubies have technological uses as well as gemological ones. Rods of synthetic ruby are used to make ruby lasers and masers. The first working laser was made by Theodore H. Maiman in 1960. Maiman used a solid-state light-pumped synthetic ruby to produce red laser light at a wavelength of 694 nanometers (nm). Ruby lasers are still in use.

Rubies are also used in applications where high hardness is required such as at wear-exposed locations in mechanical clockworks, or as scanning probe tips in a coordinate measuring machine.

Imitation rubies are also marketed. Red spinels, red garnets, and colored glass have been falsely claimed to be rubies. Imitations go back to Roman times and already in the 17th century techniques were developed to color foil red—by burning scarlet wool in the bottom part of the furnace—which was then placed under the imitation stone. Trade terms such as balas ruby for red spinel and rubellite for red tourmaline can mislead unsuspecting buyers. Such terms are therefore discouraged from use by many gemological associations such as the Laboratory Manual Harmonisation Committee (LMHC).

Records and famous examples

Rubies at the National Museum of Natural History, Washington, D.C., USA

• The Smithsonian's National Museum of Natural History in Washington, D.C. has some of the world's largest and finest ruby gemstones. The 23.1-carat (4.62 g) Burmese ruby, set in a platinum ring with diamonds, was donated by businessman and philanthropist Peter Buck in memory of his late wife Carmen Lúcia. This gemstone displays a richly saturated red color combined with an exceptional transparency. The finely proportioned cut provides vivid red reflections. The stone was mined from the Mogok region of Burma (now Myanmar) in the 1930s.
• In 2007, the London jeweler Garrard & Co featured a heart-shaped 40.63-carat ruby on their website.
• On 13/14 December 2011, Elizabeth Taylor's complete jewelry collection was auctioned by Christie's. Several ruby-set pieces were included in the sale, notably a ring set with an 8.24 ct gem that broke the 'price-per-carat' record for rubies (US$512,925 per carat – i.e., over US$4.2 million in total), and a necklace that sold for over US$3.7 million.
• The Liberty Bell Ruby is the largest mined ruby in the world. It was stolen in a heist in 2011.
• The Sunrise Ruby is the world's most expensive ruby, most expensive colored gemstone, and most expensive gemstone other than a diamond. In May 2015, it sold at auction in Switzerland to an anonymous buyer for US$30 million.
• A synthetic ruby crystal became the gain medium in the world's first optical laser, conceived, designed and constructed by Theodore H. "Ted" Maiman, on 16 May 1961 at Hughes Research Laboratories

The concept of electromagnetic radiation amplification through the mechanism of stimulated emission had already been successfully demonstrated in the laboratory by way of the maser, using other materials such as ammonia and, later, ruby, but the ruby laser was the first device to work at optical (694.3 nm) wavelengths. Maiman's prototype laser is still in working order.

The Ruby Eye Amulet from Mesopotamia, Adilnor Collection, Sweden.

Historical and cultural references

• The Old Testament of the Bible mentions ruby many times in the Book of Exodus, and many times in the Book of Proverbs, as well as various other times. It is not certain that the Biblical words mean 'ruby' as distinct from other jewels.
• An early recorded transport and trading of rubies arises in the literature on the North Silk Road of China, wherein about 200 BC rubies were carried along this ancient trackway moving westward from China.
• Rubies have always been held in high esteem in Asian countries. They were used to ornament armor, scabbards, and harnesses of noblemen in India and China. Rubies were laid beneath the foundation of buildings to secure good fortune to the structure.
• A traditional Hindu astrological belief holds rubies as the "gemstone of the Sun and also the heavenly deity Surya, the leader of the nine heavenly bodies (Navagraha)." The belief is that worshiping and wearing rubies causes the Sun to be favorable to the wearer.
• In the Marvel comic books, the Godstone is a ruby that the son of J. Jonah Jameson, John Jameson found on the Moon that becomes activated by moonlight, grafts itself to his chest which turns him into the Man-Wolf.

Corundum

From Wikipedia, the free encyclopedia

https://en.wikipedia.org/wiki/Corundum

 

Corundum
General
Category	Oxide mineral – Hematite group
Formula (repeating unit)	Al2O3
IMA symbol	Crn
Strunz classification	4.CB.05
Dana classification	4.3.1.1
Crystal system	Trigonal
Crystal class	Hexagonal scalenohedral (3m) H-M symbol: (3 2/m)
Space group	R3c (No. 167)
Unit cell	a = 4.75 Å, c = 12.982 Å; Z = 6
Identification
Color	Colorless, gray, golden-brown, brown; purple, pink to red, orange, yellow, green, blue, violet; may be color zoned, asteriated mainly grey and brown
Crystal habit	Steep bipyramidal, tabular, prismatic, rhombohedral crystals, massive or granular
Twinning	Polysynthetic twinning common
Cleavage	None – parting in 3 directions
Fracture	Conchoidal to uneven
Tenacity	Brittle
Mohs scale hardness	9 (defining mineral)
Luster	Adamantine to vitreous
Streak	Colorless
Diaphaneity	Transparent, translucent to opaque
Specific gravity	3.95–4.10
Optical properties	Uniaxial (−)
Refractive index	nω = 1.767–1.772 nε = 1.759–1.763
Pleochroism	None
Melting point	2,044 °C (3,711 °F)
Fusibility	Infusible
Solubility	Insoluble
Alters to	May alter to mica on surfaces causing a decrease in hardness
Other characteristics	May fluoresce or phosphoresce under UV light
Major varieties
Sapphire	Any color except red
Ruby	Red
Emery	Black granular corundum intimately mixed with magnetite, hematite, or hercynite

Corundum is a crystalline form of aluminium oxide (Al₂O₃) typically containing traces of iron, titanium, vanadium, and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. Corundum has two primary gem varieties: ruby and sapphire. Rubies are red due to the presence of chromium, and sapphires exhibit a range of colors depending on what transition metal is present. A rare type of sapphire, padparadscha sapphire, is pink-orange.

The name "corundum" is derived from the Tamil-Dravidian word kurundam (ruby-sapphire) (appearing in Sanskrit as kuruvinda).

Because of corundum's hardness (pure corundum is defined to have 9.0 on the Mohs scale), it can scratch almost all other minerals. It is commonly used as an abrasive on sandpaper and on large tools used in machining metals, plastics, and wood. Emery, a variety of corundum with no value as a gemstone, is commonly used as an abrasive. It is a black granular form of corundum, in which the mineral is intimately mixed with magnetite, hematite, or hercynite.

In addition to its hardness, corundum has a density of 4.02 g/cm³ (251 lb/cu ft), which is unusually high for a transparent mineral composed of the low-atomic mass elements aluminium and oxygen.

Geology and occurrence

Corundum from Brazil, size about 2 cm × 3 cm (0.8 in × 1 in)

Corundum occurs as a mineral in mica schist, gneiss, and some marbles in metamorphic terranes. It also occurs in low-silica igneous syenite and nepheline syenite intrusives. Other occurrences are as masses adjacent to ultramafic intrusives, associated with lamprophyre dikes and as large crystals in pegmatites. It commonly occurs as a detrital mineral in stream and beach sands because of its hardness and resistance to weathering. The largest documented single crystal of corundum measured about 65 cm × 40 cm × 40 cm (26 in × 16 in × 16 in), and weighed 152 kg (335 lb). The record has since been surpassed by certain synthetic boules.

Corundum for abrasives is mined in Zimbabwe, Pakistan, Afghanistan, Russia, Sri Lanka, and India. Historically it was mined from deposits associated with dunites in North Carolina, US, and from a nepheline syenite in Craigmont, Ontario. Emery-grade corundum is found on the Greek island of Naxos and near Peekskill, New York, US. Abrasive corundum is synthetically manufactured from bauxite.

Four corundum axes dating to 2500 BC from the Liangzhu culture and Sanxingcun culture (the latter of which is located in Jintan District) have been discovered in China.

Synthetic corundum

• In 1837, Marc Antoine Gaudin made the first synthetic rubies by reacting alumina at a high temperature with a small amount of chromium as a colourant.
• In 1847, J. J. Ebelmen made white synthetic sapphires by reacting alumina in boric acid.
• In 1877, Frenic and Freil made crystal corundum from which small stones could be cut. Frimy and Auguste Verneuil manufactured artificial ruby by fusing BaF₂ and Al₂O₃ with a little chromium at temperatures above 2,000 °C (3,630 °F).
• In 1903, Verneuil announced that he could produce synthetic rubies on a commercial scale using this flame fusion process.

The Verneuil process allows the production of flawless single-crystal sapphire and ruby gems of much larger size than normally found in nature. It is also possible to grow gem-quality synthetic corundum by flux-growth and hydrothermal synthesis. Because of the simplicity of the methods involved in corundum synthesis, large quantities of these crystals have become available on the market at a fraction of the cost of natural stones.

Apart from ornamental uses, synthetic corundum is also used to produce mechanical parts (tubes, rods, bearings, and other machined parts), scratch-resistant optics, scratch-resistant watch crystals, instrument windows for satellites and spacecraft (because of its transparency in the ultraviolet to infrared range), and laser components. For example, the KAGRA gravitational wave detector's main mirrors are 23 kg (50 lb) sapphires, and Advanced LIGO considered 40 kg (88 lb) sapphire mirrors. Corundum has also found use in the development of ceramic armour thanks to its high hardiness.

Structure and physical properties

Crystal structure of corundum

Molar volume vs. pressure at room temperature

Corundum crystallizes with trigonal symmetry in the space group R3c and has the lattice parameters a = 4.75 Å and c = 12.982 Å at standard conditions. The unit cell contains six formula units.

The toughness of corundum is sensitive to surface roughness and crystallographic orientation. It may be 6–7 MPa·m^1/2 for synthetic crystals, and around 4 MPa·m^1/2 for natural.

In the lattice of corundum, the oxygen atoms form a slightly distorted hexagonal close packing, in which two-thirds of the octahedral sites between the oxygen ions are occupied by aluminium ions. The absence of aluminium ions from one of the three sites breaks the symmetry of the hexagonal close packing, reducing the space group symmetry to R3c and the crystal class to trigonal. The structure of corundum is sometimes described as a pseudohexagonal structure.

The Young’s modulus of corundum (sapphire) has been reported by many different sources with values varying between 300-500 GPa, but a commonly cited value used for calculations is 345 GPa. The Young’s modulus is temperature dependent, and has been reported in the [0001] direction as 435 GPa at 323 K and 386 GPa at 1,273 K. The shear modulus of corundum is 145 GPa, and the bulk modulus is 240 GPa.

Single crystal corundum fibers have potential applications in high temperature composites, and the Young’s modulus is highly dependent on the crystallographic orientation along the fiber axis. The fiber exhibits a max modulus of 461 GPa when the crystallographic c-axis [0001] is aligned with the fiber axis, and minimum moduli ~373 GPa when a direction 45° away from the c-axis is aligned with the fiber axis.

The hardness of corundum measured by indentation at low loads of 1-2 N has been reported as 22-23 GPa in major crystallographic planes: (0001) (basal plane), (1010) (rhombohedral plane), (1120) (prismatic plane), and (1012). The hardness can drop significantly under high indentation loads. The drop with respect to load varies with the crystallographic plane due to the difference in crack resistance and propagation between directions. One extreme case is seen in the (0001) plane, where the hardness under high load (~1kN) is nearly half the value under low load (1-2 N).

Polycrystalline corundum formed through sintering and treated with a hot isostatic press process can achieve grain sizes in the range of 0.55-0.7 μm, and has been measured to have four-point bending strength between 600-700 MPa and three-point bending strength between 750-900 Mpa.

Generalization

Main article: Corundum (structure)

 

Because of its prevalence, corundum has also become the name of a major structure type (corundum type) found in various binary and ternary compounds.