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Saturday, April 13, 2019

Why religion is not going away and science will not destroy it

Secularism has failed to continue its steady global march
Peter Harrison | Apr 12 2019

In 1966, just over 50 years ago, the distinguished Canadian-born anthropologist Anthony Wallace confidently predicted the global demise of religion at the hands of an advancing science: ‘belief in supernatural powers is doomed to die out, all over the world, as a result of the increasing adequacy and diffusion of scientific knowledge’. Wallace’s vision was not exceptional. On the contrary, the modern social sciences, which took shape in 19th-century western Europe, took their own recent historical experience of secularisation as a universal model. An assumption lay at the core of the social sciences, either presuming or sometimes predicting that all cultures would eventually converge on something roughly approximating secular, Western, liberal democracy. Then something closer to the opposite happened.

Not only has secularism failed to continue its steady global march but countries as varied as Iran, India, Israel, Algeria and Turkey have either had their secular governments replaced by religious ones, or have seen the rise of influential religious nationalist movements. Secularisation, as predicted by the social sciences, has failed.

To be sure, this failure is not unqualified. Many Western countries continue to witness decline in religious belief and practice. The most recent census data released in Australia, for example, shows that 30 per cent of the population identify as having ‘no religion’, and that this percentage is increasing. International surveys confirm comparatively low levels of religious commitment in western Europe and Australasia. Even the United States, a long-time source of embarrassment for the secularisation thesis, has seen a rise in unbelief. The percentage of atheists in the US now sits at an all-time high (if ‘high’ is the right word) of around 3 per cent. Yet, for all that, globally, the total number of people who consider themselves to be religious remains high, and demographic trends suggest that the overall pattern for the immediate future will be one of religious growth. But this isn’t the only failure of the secularisation thesis.

Scientists, intellectuals and social scientists expected that the spread of modern science would drive secularisation – that science would be a secularising force. But that simply hasn’t been the case. If we look at those societies where religion remains vibrant, their key common features are less to do with science, and more to do with feelings of existential security and protection from some of the basic uncertainties of life in the form of public goods. A social safety net might be correlated with scientific advances but only loosely, and again the case of the US is instructive. The US is arguably the most scientifically and technologically advanced society in the world, and yet at the same time the most religious of Western societies. As the British sociologist David Martin concluded in The Future of Christianity (2011): ‘There is no consistent relation between the degree of scientific advance and a reduced profile of religious influence, belief and practice.’

The story of science and secularisation becomes even more intriguing when we consider those societies that have witnessed significant reactions against secularist agendas. India’s first prime minister Jawaharlal Nehru championed secular and scientific ideals, and enlisted scientific education in the project of modernisation. Nehru was confident that Hindu visions of a Vedic past and Muslim dreams of an Islamic theocracy would both succumb to the inexorable historical march of secularisation. ‘There is only one-way traffic in Time,’ he declared. But as the subsequent rise of Hindu and Islamic fundamentalism adequately attests, Nehru was wrong. Moreover, the association of science with a secularising agenda has backfired, with science becoming a collateral casualty of resistance to secularism.

Turkey provides an even more revealing case. Like most pioneering nationalists, Mustafa Kemal Atatürk, the founder of the Turkish republic, was a committed secularist. Atatürk believed that science was destined to displace religion. In order to make sure that Turkey was on the right side of history, he gave science, in particular evolutionary biology, a central place in the state education system of the fledgling Turkish republic. As a result, evolution came to be associated with Atatürk’s entire political programme, including secularism. Islamist parties in Turkey, seeking to counter the secularist ideals of the nation’s founders, have also attacked the teaching of evolution. For them, evolution is associated with secular materialism. This sentiment culminated in the decision this June to remove the teaching of evolution from the high-school classroom. Again, science has become a victim of guilt by association.

The US represents a different cultural context, where it might seem that the key issue is a conflict between literal readings of Genesis and key features of evolutionary history. But in fact, much of the creationist discourse centres on moral values. In the US case too, we see anti-evolutionism motivated at least in part by the assumption that evolutionary theory is a stalking horse for secular materialism and its attendant moral commitments. As in India and Turkey, secularism is actually hurting science.

In brief, global secularisation is not inevitable and, when it does happen, it is not caused by science. Further, when the attempt is made to use science to advance secularism, the results can damage science. The thesis that ‘science causes secularisation’ simply fails the empirical test, and enlisting science as an instrument of secularisation turns out to be poor strategy. The science and secularism pairing is so awkward that it raises the question: why did anyone think otherwise?

Historically, two related sources advanced the idea that science would displace religion. First, 19th-century progressivist conceptions of history, particularly associated with the French philosopher Auguste Comte, held to a theory of history in which societies pass through three stages – religious, metaphysical and scientific (or ‘positive’). Comte coined the term ‘sociology’ and he wanted to diminish the social influence of religion and replace it with a new science of society. Comte’s influence extended to the ‘young Turks’ and Atatürk.

The 19th century also witnessed the inception of the ‘conflict model’ of science and religion. This was the view that history can be understood in terms of a ‘conflict between two epochs in the evolution of human thought – the theological and the scientific’. This description comes from Andrew Dickson White’s influential A History of the Warfare of Science with Theology in Christendom (1896), the title of which nicely encapsulates its author’s general theory. White’s work, as well as John William Draper’s earlier History of the Conflict Between Religion and Science (1874), firmly established the conflict thesis as the default way of thinking about the historical relations between science and religion. Both works were translated into multiple languages. Draper’s History went through more than 50 printings in the US alone, was translated into 20 languages and, notably, became a bestseller in the late Ottoman empire, where it informed Atatürk’s understanding that progress meant science superseding religion.

Today, people are less confident that history moves through a series of set stages toward a single destination. Nor, despite its popular persistence, do most historians of science support the idea of an enduring conflict between science and religion. Renowned collisions, such as the Galileo affair, turned on politics and personalities, not just science and religion. Darwin had significant religious supporters and scientific detractors, as well as vice versa. Many other alleged instances of science-religion conflict have now been exposed as pure inventions. In fact, contrary to conflict, the historical norm has more often been one of mutual support between science and religion. In its formative years in the 17th century, modern science relied on religious legitimation. During the 18th and 19th centuries, natural theology helped to popularise science.

The conflict model of science and religion offered a mistaken view of the past and, when combined with expectations of secularisation, led to a flawed vision of the future. Secularisation theory failed at both description and prediction. The real question is why we continue to encounter proponents of science-religion conflict. Many are prominent scientists. It would be superfluous to rehearse Richard Dawkins’s musings on this topic, but he is by no means a solitary voice. Stephen Hawking thought that ‘science will win because it works’; Sam Harris has declared that ‘science must destroy religion’; Stephen Weinberg thinks that science has weakened religious certitude; Colin Blakemore predicts that science will eventually make religion unnecessary. Historical evidence simply does not support such contentions. Indeed, it suggests that they are misguided.

So why do they persist? The answers are political. Leaving aside any lingering fondness for quaint 19th-century understandings of history, we must look to the fear of Islamic fundamentalism, exasperation with creationism, an aversion to alliances between the religious Right and climate-change denial, and worries about the erosion of scientific authority. While we might be sympathetic to these concerns, there is no disguising the fact that they arise out of an unhelpful intrusion of normative commitments into the discussion. Wishful thinking – hoping that science will vanquish religion – is no substitute for a sober assessment of present realities. Continuing with this advocacy is likely to have an effect opposite to that intended.

Religion is not going away any time soon, and science will not destroy it. If anything, it is science that is subject to increasing threats to its authority and social legitimacy. Given this, science needs all the friends it can get. Its advocates would be well advised to stop fabricating an enemy out of religion, or insisting that the only path to a secure future lies in a marriage of science and secularism.
Aeon counter – do not remove

Peter Harrison is an Australian Laureate Fellow and director of the Institute for Advanced Studies in the Humanities at the University of Queensland. He is the author of The Territories of Science and Religion (2015), and the editor of Narratives of Secularization (2017). This article was originally published at Aeon and has been republished under Creative Commons.

Modern Monetary Theory

From Wikipedia, the free encyclopedia

Modern Monetary Theory or Modern Money Theory (MMT) is a heterodox macroeconomic theory that describes currency as a public monopoly for a government and unemployment as the evidence that a currency monopolist is restricting the supply of the financial assets needed to pay taxes and satisfy savings desires. MMT is seen as an evolution of chartalism and is sometimes referred to as neo-chartalism.

MMT advocates argue that the government should use fiscal policy to achieve full employment, creating new money to fund government purchases. The primary risk once the economy reaches full employment is inflation, which can be addressed by raising taxes and issuing bonds, to remove excess money from the system. MMT is controversial, with active debate about its policy effectiveness and risks.

Overview

U.S. money supply change from a year ago ($ Billions).
 
Percent change in U.S. money supply vs. year ago. Money supply increases about 6% per year.
 
MMT states that a government that can create its own money, such as the United States:
  1. Cannot default on debt denominated in its own currency;
  2. Can pay for goods, services, and financial assets without a need to collect money in the form of taxes or debt issuance in advance of such purchases;
  3. Is limited in its money creation and purchases by inflation, which accelerates once the economic resources (i.e., labor and capital) of the economy are utilized at full employment;
  4. Can control inflation by taxation and bond issuance, which remove excess money from circulation, although the political will to do so may not always exist;
  5. Does not need to compete with the private sector for scarce savings by issuing bonds.
These tenets challenge the mainstream economics view that government spending should be funded a priori by taxes and debt issuance. MMT asks in effect: "Why not create the money to buy what we think is important, and then raise taxes or issue bonds when we get inflation?"

The first four MMT tenets are not in conflict with mainstream economics in terms of how money creation is executed and inflation works. For example, as former Fed Chair Alan Greenspan said, "The United States can pay any debt it has because we can always print money to do that. So there is zero probability of default." However, MMT disagrees with mainstream economics about the fifth tenet in terms of impact on interest rates.

History

MMT synthesises ideas from the State Theory of Money of Georg Friedrich Knapp (also known as Chartalism) and Credit Theory of Money of Alfred Mitchell-Innes, the functional finance proposals of Abba Lerner, Hyman Minsky's views on the banking system and Wynne Godley's Sectoral balances approach.

Knapp, writing in 1905, argued that "money is a creature of law" rather than a commodity. Knapp contrasted his state theory of money with the Gold Standard view of "metallism", where the value of a unit of currency depends on the quantity of precious metal it contains or for which it may be exchanged. He argued that the state can create pure paper money and make it exchangeable by recognizing it as legal tender, with the criterion for the money of a state being "that which is accepted at the public pay offices."

The prevailing view of money was that it had evolved from systems of barter to become a medium of exchange because it represented a durable commodity which had some use value, but proponents of MMT such as Randall Wray and Mathew Forstater argue that more general statements appearing to support a chartalist view of tax-driven paper money appear in the earlier writings of many classical economists, including Adam Smith, Jean-Baptiste Say, J.S. Mill, Karl Marx, and William Stanley Jevons.

Alfred Mitchell-Innes, writing in 1914, argued that money exists not as a medium of exchange but as a standard of deferred payment, with government money being debt the government may reclaim through taxation. Innes argued:
Whenever a tax is imposed, each taxpayer becomes responsible for the redemption of a small part of the debt which the government has contracted by its issues of money, whether coins, certificates, notes, drafts on the treasury, or by whatever name this money is called. He has to acquire his portion of the debt from some holder of a coin or certificate or other form of government money, and present it to the Treasury in liquidation of his legal debt. He has to redeem or cancel that portion of the debt...The redemption of government debt by taxation is the basic law of coinage and of any issue of government ‘money’ in whatever form.
— Alfred Mitchell-Innes, The Credit Theory of Money, The Banking Law Journal
Knapp and "chartalism" are referenced by John Maynard Keynes in the opening pages of his 1930 Treatise on Money and appear to have influenced Keynesian ideas on the role of the state in the economy.

By 1947, when Abba Lerner wrote his article Money as a Creature of the State, economists had largely abandoned the idea that the value of money was closely linked to gold. Lerner argued that responsibility for avoiding inflation and depressions lay with the state because of its ability to create or tax away money.

Economists Warren Mosler, L. Randall Wray, Stephanie Kelton, Bill Mitchell and Pavlina R. Tcherneva are largely responsible for reviving the idea of chartalism as an explanation of money creation; Wray refers to this revived formulation as Neo-Chartalism.

Bill Mitchell, Professor of Economics and Director of the Centre of Full Employment and Equity or CofFEE, at the University of Newcastle, New South Wales, refers to an increasing related theoretical work as Modern Monetary Theory

Pavlina R. Tcherneva has developed the first mathematical framework for MMT and has largely focused on developing the idea of the Job Guarantee

Scott Fullwiler has added detailed technical analysis of the banking and monetary systems.

Rodger Malcolm Mitchell's book Free Money (1996) describes in layman's terms the essence of chartalism. 

Some contemporary proponents, such as Wray, label chartalism within post-Keynesian economics, while chartalism has been proposed as an alternative or complementary theory to monetary circuit theory, both being forms of endogenous money, i.e., money created within the economy, as by government deficit spending or bank lending, rather than from outside, as by gold. In the complementary view, chartalism explains the "vertical" (government-to-private and vice versa) interactions, while circuit theory is a model of the "horizontal" (private-to-private) interactions.

Hyman Minsky seemed to favor a chartalist approach to understanding money creation in his Stabilizing an Unstable Economy, while Basil Moore, in his book Horizontalists and Verticalists, lists the differences between bank money and state money. 

James K. Galbraith supports chartalism and wrote the foreword for Mosler's book Seven Deadly Innocent Frauds of Economic Policy in 2010.

Steven Hail of the University of Adelaide is another well known MMT economist.

In February 2019, the first academic textbook based on the theory was published.

Theoretical approach

In sovereign financial systems, banks can create money but these "horizontal" transactions do not increase net financial assets as assets are offset by liabilities. According to MMT adherents, "The balance sheet of the government does not include any domestic monetary instrument on its asset side; it owns no money. All monetary instruments issued by the government are on its liability side and are created and destroyed with spending and taxing/bond offerings, respectively." In MMT, "vertical money" enters circulation through government spending. Taxation and its legal tender enable power to discharge debt and establish the fiat money as currency, giving it value by creating demand for it in the form of a private tax obligation that must be met. In addition, fines, fees and licenses create demand for the currency. This can be a currency issued by the domestic government, or a foreign currency. An ongoing tax obligation, in concert with private confidence and acceptance of the currency, maintains its value. Because the government can issue its own currency at will, MMT maintains that the level of taxation relative to government spending (the government's deficit spending or budget surplus) is in reality a policy tool that regulates inflation and unemployment, and not a means of funding the government's activities by itself. The approach of MMT typically reverses theories of governmental austerity. The policy implications of the two are likewise typically opposed.

Vertical transactions

Illustration of the saving identity with the three sectors, the computation of the surplus or deficit balances for each and the flows between them

MMT labels any transactions between the government, or public sector, and the non-government, or private sector, as a "vertical transaction". The government sector is considered to include the treasury and the central bank. The non-government sector includes domestic and foreign private individuals and firms (including the private banking system) and foreign buyers and sellers of the currency.

Interaction between government and the banking sector

MMT is based on an account of the "operational realities" of interactions between the government and its central bank, and the commercial banking sector, with proponents like Scott Fullwiler arguing that understanding reserve accounting is critical to understanding monetary policy options.

A sovereign government typically has an operating account with the country's central bank. From this account, the government can spend and also receive taxes and other inflows. Each commercial bank also has an account with the central bank, by means of which it manages its reserves (that is, the amount of available short-term money that it holds).

When the government spends money, the treasury debits its operating account at the central bank, and deposits this money into private bank accounts (and hence into the commercial banking system). This money adds to the total deposits in the commercial bank sector. Taxation works exactly in reverse; private bank accounts are debited, and hence deposits in the commercial banking sector fall.

Government bonds and interest rate maintenance

The Federal Reserve raising the Federal Funds Rate above U.S. Treasury interest rates creates an inverted yield curve, which is a predictor of recessions.
 
Virtually all central banks set an interest rate target, and conduct open market operations to ensure base interest rates remain at that target level. According to MMT, the issuing of government bonds is best understood as an operation to offset government spending rather than a requirement to finance it.

In most countries, commercial banks’ reserve accounts with the central bank must have a positive balance at the end of every day; in some countries, the amount is specifically set as a proportion of the liabilities a bank has (i.e. its customer deposits). This is known as a reserve requirement. At the end of every day, a commercial bank will have to examine the status of their reserve accounts. Those that are in deficit have the option of borrowing the required funds from the central bank, where they may be charged a lending rate (sometimes known as a discount rate) on the amount they borrow. On the other hand, the banks that have excess reserves can simply leave them with the central bank and earn a support rate from the central bank. Some countries, such as Japan, have a support rate of zero.

Banks with more reserves than they need will be willing to lend to banks with a reserve shortage on the interbank lending market. The surplus banks will want to earn a higher rate than the support rate that the central bank pays on reserves; whereas the deficit banks will want to pay a lower interest rate than the discount rate the central bank charges for borrowing. Thus they will lend to each other until each bank has reached their reserve requirement. In a balanced system, where there are just enough total reserves for all the banks to meet requirements, the short-term interbank lending rate will be in between the support rate and the discount rate.

Under an MMT framework where government spending injects new reserves into the commercial banking system, and taxes withdraw it from the banking system, government activity would have an instant effect on interbank lending. If on a particular day, the government spends more than it taxes, reserves have been added to the banking system. This will typically lead to a system-wide surplus of reserves, with competition between banks seeking to lend their excess reserves forcing the short-term interest rate down to the support rate (or alternately, to zero if a support rate is not in place). At this point banks will simply keep their reserve surplus with their central bank and earn the support rate.

The alternate case is where the government receives more taxes on a particular day than it spends. In this case, there may be a system-wide deficit of reserves. As a result, surplus funds will be in demand on the interbank market, and thus the short-term interest rate will rise towards the discount rate. Thus, if the central bank wants to maintain a target interest rate somewhere between the support rate and the discount rate, it must manage the liquidity in the system to ensure that there is the correct amount of reserves in the banking system.

Central banks manage this by buying and selling government bonds on the open market. On a day where there are excess reserves in the banking system, the central bank sells bonds and therefore removes reserves from the banking system, as private individuals pay for the bonds. On a day where there are not enough reserves in the system, the central bank buys government bonds from the private sector, and therefore adds reserves to the banking system. 

It is important to note that the central bank buys bonds by simply creating money—it is not financed in any way.[citation needed] It is a net injection of reserves into the banking system. If a central bank is to maintain a target interest rate, then it must necessarily buy and sell government bonds on the open market in order to maintain the correct amount of reserves in the system.

MMT and quantitative easing

Federal Reserve pays remittance payments to the treasury on all the interest it makes on its assets.
 
Federal Reserve total assets, treasuries, and mortages
 
Proponents of MMT claim that it provides a better framework for understanding quantitative easing (QE) than the traditional textbook money multiplier model. Paul Sheard argues that, when the central bank purchases government debt securities as opposed to private sector risk assets, QE is best viewed as a debt refinancing operation of the consolidated government. MMT emphasizes that governments create central bank reserves when they run budget deficits and expunge those reserves when they issue debt securities. Sheard argues that QE can be seen as the third stage in this process, turning the government debt securities back into reserves. The unwinding of QE just reverses this yet again.

Horizontal transactions

MMT economists describe any transactions within the private sector as "horizontal" transactions, including the expansion of the broad money supply through the extension of credit by banks.

MMT economists regard the concept of the money multiplier, where a bank is completely constrained in lending through the deposits it holds and its capital requirement, as misleading. Rather than being a practical limitation on lending, the cost of borrowing funds from the interbank market (or the central bank) represents a profitability consideration when the private bank lends in excess of its reserve and/or capital requirements.

According to MMT, bank credit should be regarded as a "leverage" of the monetary base and should not be regarded as increasing the net financial assets held by an economy: only the government or central bank is able to issue high-powered money with no corresponding liability. Stephanie Kelton argues that bank money is generally accepted in settlement of debt and taxes because of state guarantees, but that state-issued high-powered money sits atop a "hierarchy of money".

Foreign sector

Imports and exports

MMT proponents such as Warren Mosler argue that trade deficits need not be unsustainable and are beneficial to the standard of living in the short run. Imports are an economic benefit to the importing nation because they provide the nation with real goods it can consume, that it otherwise would not have had. Exports, on the other hand, are an economic cost to the exporting nation because it is losing real goods that it could have consumed. Currency transferred to foreign ownership, however, represents a future claim over goods of that nation.

Cheap imports may also cause the failure of local firms providing similar goods at higher prices, and hence unemployment but MMT commentators label that consideration as a subjective value-based one, rather than an economic-based one: it is up to a nation to decide whether it values the benefit of cheaper imports more than it values employment in a particular industry. Similarly a nation overly dependent on imports may face a supply shock if the exchange rate drops significantly, though central banks can and do trade on the FX markets to avoid sharp shocks to the exchange rate.

Foreign sector and government

MMT argues that as long as there is a demand for the issuer's currency, whether the bond holder is foreign or not, governments can never be insolvent when the debt obligations are in their own currency; this is because the government is not constrained in creating its own currency (although the bond holder may affect the exchange rate by converting to local currency).

MMT does agree with mainstream economics, that debt denominated in a foreign currency certainly is a fiscal risk to governments, since the indebted government cannot create foreign currency. In this case the only way the government can sustainably repay its foreign debt is to ensure that its currency is continually and highly demanded by foreigners over the period that it wishes to repay the debt – an exchange rate collapse would potentially multiply the debt many times over asymptotically, making it impossible to repay. In that case, the government can default, or attempt to shift to an export-led strategy or raise interest rates to attract foreign investment in the currency. Either one has a negative effect on the economy.

Policy implications

Economist Stephanie Kelton explained several policy claims made by MMT in March 2019:
  • Under MMT, fiscal policy (i.e., government taxing and spending decisions) is the primary means of achieving full employment, establishing the budget deficit at the level necessary to reach that goal. In mainstream economics, monetary policy (i.e., central bank adjustment of interest rates and its balance sheet) is the primary mechanism, assuming there is some interest rate low enough to achieve full employment. Kelton claims that cutting interest rates is ineffective in a slump, because businesses expecting weak profits and few customers will not invest at even very low interest rates.
  • Government interest expenses are proportional to interest rates, so raising rates is a form of stimulus (it increases the budget deficit and injects money into the private sector, other things equal), while cutting rates is a form of austerity.
  • Achieving full employment can be administered via a federally funded job guarantee, which acts as an automatic stabilizer. When private sector jobs are plentiful, the government spending on guaranteed jobs is lower, and vice versa.
  • Under MMT, expansionary fiscal policy (i.e., money creation to fund purchases) can increase bank reserves, which can lower interest rates. In mainstream economics, expansionary fiscal policy (i.e., debt issuance and spending) can result in higher interest rates, crowding out economic activity.
Economist John T. Harvey explained several of the premises of MMT and their policy implications in March 2019:
  • The private sector treats labor as a cost to be minimized, so it cannot be expected to achieve full employment without government creating jobs as well, such as through a job guarantee.
  • The public sector's deficit is the private sector's surplus and vice-versa, by accounting identity, a reason why private sector debt increased during the Clinton-era budget surpluses.
  • Idle resources (mainly labor) can be activated by money creation. Not acting to do so is immoral.
  • Demand can be insensitive to interest rate changes, so a key mainstream assumption, that lower interest rates lead to higher demand, is questionable.
  • When the economy is below full employment, there is a "free lunch" in creating money to fund government expenditure to achieve full employment. Unemployment is a burden; full employment is not.
  • Creating money alone does not cause inflation; spending it when the economy is at or above full employment can.
MMT claims that the word "borrowing" is a misnomer when it comes to a sovereign government's fiscal operations, because what the government is doing is accepting back its own IOUs, and nobody can borrow back their own debt instruments. Sovereign government goes into debt by issuing its own liabilities that are financial wealth to the private sector. "Private debt is debt, but government debt is financial wealth to the private sector."

In this theory, sovereign government is not financially constrained in its ability to spend; it is argued that the government can afford to buy anything that is for sale in currency that it issues (there may be political constraints, like a debt ceiling law). The only constraint is that excessive spending by any sector of the economy (whether households, firms, or public) has the potential to cause inflationary pressures. 

MMT economists advocate a government-funded job guarantee scheme to eliminate involuntary unemployment. Proponents argue that this can be consistent with price stability as it targets unemployment directly rather than attempting to increase private sector job creation indirectly through a much larger economic stimulus, and maintains a "buffer stock" of labor that can readily switch to the private sector when jobs become available. A job guarantee program could also be considered a powerful automatic stabilizer to the economy, expanding when private sector activity cools down and shrinking in size when private sector activity heats up.

Comparison of MMT with mainstream Keynesian economics

MMT can be compared and contrasted with mainstream Keynesian economics in a variety of ways:

Topic Mainstream MMT
Funding government spending Advocates taxation and issuing bonds (debt) as preferred methods for funding government spending Advocates creating new money; emphasizes that taxation and debt issuance are not required to fund spending
Purpose of taxation Fund government spending and address inequality Prevent inflation, by taking money away from private sector, a form of austerity; and address inequality
Achieving full employment Main strategy uses monetary policy; Fed has "dual mandate" of maximum employment and stable prices, but these goals are not always compatible. For example, much higher interest rates used to reduce inflation also caused high unemployment in the early 1980's. Main strategy uses fiscal policy; running a budget deficit large enough to achieve the goal. Economist Paul Krugman explained that expansionary fiscal policy may be required to achieve full employment when monetary policy is constrained by the zero lower bound on interest rates, but isn't required while the Fed has room to lower interest rates.
Inflation control Driven by monetary policy; Fed sets interest rates consistent with a stable price level, sometimes setting a target inflation rate. Driven by fiscal policy; government increases taxes or issues bonds to remove money from private sector
Setting interest rates Managed by Fed to achieve "dual mandate" of maximum employment and stable prices. Creating money increases supply of bank reserves, which drives down interest rates to near-zero, as explained by economist Stephanie Kelton.[4] Economist Paul Krugman claimed MMT does not have a compelling argument for this mechanism.
Budget deficit impact on interest rates At full employment, higher budget deficit can crowd-out investment Creating new money can drive down interest rates, encouraging investment and thus "crowding-in" economic activity, as explained by economist Stephanie Kelton. Economist Paul Krugman claimed MMT does not have a compelling argument for this mechanism.
Automatic stabilizers Primary stabilizers are unemployment insurance and food stamps, which increase budget deficits in a downturn In addition to the other stabilizers, advocates a job guarantee, which would increase deficits in a downturn

Criticisms

A 2019 survey of leading economists showed a unanimous rejection of assertions attributed to modern monetary theory in the survey: "Countries that borrow in their own currency should not worry about government deficits because they can always create money to finance their debt. [...] Countries that borrow in their own currency can finance as much real government spending as they want by creating money". Directly responding to the survey, MMT economist William K. Black said "MMT scholars do not make or support either claim". Multiple MMT academics regard the attribution of these claims as a smear.

The post-Keynesian economist Thomas Palley argues that MMT is largely a restatement of elementary Keynesian economics, but prone to "over-simplistic analysis" and understating the risks of its policy implications. Palley denies the MMT claim that standard Keynesian analysis does not fully capture the accounting identities and financial restraints on a government that can issue its own money. He argues that these insights are well captured by standard Keynesian stock-flow consistent IS-LM models, and have been well understood by Keynesian economists for decades. He also criticizes MMT for essentially assuming away the problem of fiscal - monetary conflict. In Palley's view the policies proposed by MMT proponents would cause serious financial instability in an open economy with flexible exchange rates, while using fixed exchange rates would restore hard financial constraints on the government and "undermines MMT’s main claim about sovereign money freeing governments from standard market disciplines and financial constraints". He also argues that MMT lacks a plausible theory of inflation, particularly in the context of full employment in the employer of last resort policy first proposed by Hyman Minsky and advocated by Bill Mitchell and other MMT theorists; of a lack of appreciation of the financial instability that could be caused by permanently zero interest rates; and of overstating the importance of government created money. Palley concludes that MMT provides no new insights about monetary theory, while making unsubstantiated claims about macroeconomic policy, and that MMT has only received attention recently due to it being a "policy polemic for depressed times".

Marc Lavoie argues that whilst the neochartalist argument is "essentially correct", many of its counter-intuitive claims depend on a "confusing" and "fictitious" consolidation of government and central banking operations.

New Keynesian economist and Nobel laureate Paul Krugman argues that MMT goes too far in its support for government budget deficits and ignores the inflationary implications of maintaining budget deficits when the economy is growing. Krugman described MMT devotees engage in calvinball, which is a game in the comic strip “Calvin and Hobbes” where the players may change the rules on whim. Austrian School economist Robert P. Murphy states that MMT is "dead wrong" and that "the MMT worldview doesn't live up to its promises". He observes that the MMT claim that cutting government deficits erodes private saving is true "only for the portion of private saving that is not invested" and argues that the national accounting identities used to explain this aspect of MMT could equally be used to support arguments that government deficits "crowd out" private sector investment.

The chartalist view of money itself, and the MMT emphasis on the importance of taxes in driving money is also a source of criticism. Economist Eladio Febrero argues that modern money draws its value from its ability to cancel (private) bank debt, particularly as legal tender, rather than to pay government taxes.

Tantalum

From Wikipedia, the free encyclopedia

Tantalum,  73Ta
Tantalum single crystal and 1cm3 cube.jpg
Tantalum
Pronunciation/ˈtæntələm/ (TAN-təl-əm)
Appearancegray blue
Standard atomic weight Ar, std(Ta)180.94788(2)
Tantalum in the periodic table
Hydrogen
Helium
Lithium Beryllium
Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium
Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium
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Nb

Ta

Db
hafniumtantalumtungsten
Atomic number (Z)73
Groupgroup 5
Periodperiod 6
Blockd-block
Element category  transition metal
Electron configuration[Xe] 4f14 5d3 6s2
Electrons per shell
2, 8, 18, 32, 11, 2
Physical properties
Phase at STPsolid
Melting point3290 K ​(3017 °C, ​5463 °F)
Boiling point5731 K ​(5458 °C, ​9856 °F)
Density (near r.t.)16.69 g/cm3
when liquid (at m.p.)15 g/cm3
Heat of fusion36.57 kJ/mol
Heat of vaporization753 kJ/mol
Molar heat capacity25.36 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 3297 3597 3957 4395 4939 5634
Atomic properties
Oxidation states−3, −1, +1, +2, +3, +4, +5 (a mildly acidic oxide)
ElectronegativityPauling scale: 1.5
Ionization energies
  • 1st: 761 kJ/mol
  • 2nd: 1500 kJ/mol

Atomic radiusempirical: 146 pm
Covalent radius170±8 pm
Color lines in a spectral range
Spectral lines of tantalum
Other properties
Natural occurrenceprimordial
Crystal structurebody-centered cubic (bcc)
Body-centered cubic crystal structure for tantalum

α-Ta
Crystal structuretetragonal
Tetragonal crystal structure for tantalum

β-Ta
Speed of sound thin rod3400 m/s (at 20 °C)
Thermal expansion6.3 µm/(m·K) (at 25 °C)
Thermal conductivity57.5 W/(m·K)
Electrical resistivity131 nΩ·m (at 20 °C)
Magnetic orderingparamagnetic
Magnetic susceptibility+154.0·10−6 cm3/mol (293 K)[4]
Young's modulus186 GPa
Shear modulus69 GPa
Bulk modulus200 GPa
Poisson ratio0.34
Mohs hardness6.5
Vickers hardness870–1200 MPa
Brinell hardness440–3430 MPa
CAS Number7440-25-7
History
DiscoveryAnders Gustaf Ekeberg (1802)
Recognized as a distinct element byHeinrich Rose (1844)
Main isotopes of tantalum
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
177Ta syn 56.56 h ε 177Hf
178Ta syn 2.36 h ε 178Hf
179Ta syn 1.82 y ε 179Hf
180Ta syn 8.125 h ε 180Hf
β 180W
180mTa 0.012% stable
181Ta 99.988% stable
182Ta syn 114.43 d β 182W
183Ta syn 5.1 d β 183W

Tantalum is a chemical element with symbol Ta and atomic number 73. Previously known as tantalium, its name comes from Tantalus, a villain from Greek mythology. Tantalum is a rare, hard, blue-gray, lustrous transition metal that is highly corrosion-resistant. It is part of the refractory metals group, which are widely used as minor components in alloys. The chemical inertness of tantalum makes it a valuable substance for laboratory equipment and a substitute for platinum. Its main use today is in tantalum capacitors in electronic equipment such as mobile phones, DVD players, video game systems and computers. Tantalum, always together with the chemically similar niobium, occurs in the mineral groups tantalite, columbite and coltan (a mix of columbite and tantalite, though not recognised as a separate mineral species). Tantalum is considered a technology-critical element.

History

Tantalum was discovered in Sweden in 1802 by Anders Ekeberg, in two mineral samples – one from Sweden and the other from Finland. One year earlier, Charles Hatchett had discovered columbium (now niobium), and in 1809 the English chemist William Hyde Wollaston compared its oxide, columbite with a density of 5.918 g/cm3, to that of tantalum, tantalite with a density of 7.935 g/cm3. He concluded that the two oxides, despite their difference in measured density, were identical and kept the name tantalum. After Friedrich Wöhler confirmed these results, it was thought that columbium and tantalum were the same element. This conclusion was disputed in 1846 by the German chemist Heinrich Rose, who argued that there were two additional elements in the tantalite sample, and he named them after the children of Tantalus: niobium (from Niobe, the goddess of tears), and pelopium (from Pelops). The supposed element "pelopium" was later identified as a mixture of tantalum and niobium, and it was found that the niobium was identical to the columbium already discovered in 1801 by Hatchett.

The differences between tantalum and niobium were demonstrated unequivocally in 1864 by Christian Wilhelm Blomstrand, and Henri Etienne Sainte-Claire Deville, as well as by Louis J. Troost, who determined the empirical formulas of some of their compounds in 1865. Further confirmation came from the Swiss chemist Jean Charles Galissard de Marignac, in 1866, who proved that there were only two elements. These discoveries did not stop scientists from publishing articles about the so-called ilmenium until 1871. De Marignac was the first to produce the metallic form of tantalum in 1864, when he reduced tantalum chloride by heating it in an atmosphere of hydrogen. Early investigators had only been able to produce impure tantalum, and the first relatively pure ductile metal was produced by Werner von Bolton in Charlottenburg in 1903. Wires made with metallic tantalum were used for light bulb filaments until tungsten replaced it in widespread use.

The name tantalum was derived from the name of the mythological Tantalus, the father of Niobe in Greek mythology. In the story, he had been punished after death by being condemned to stand knee-deep in water with perfect fruit growing above his head, both of which eternally tantalized him. (If he bent to drink the water, it drained below the level he could reach, and if he reached for the fruit, the branches moved out of his grasp.) Anders Ekeberg wrote "This metal I call tantalum ... partly in allusion to its incapacity, when immersed in acid, to absorb any and be saturated."

For decades, the commercial technology for separating tantalum from niobium involved the fractional crystallization of potassium heptafluorotantalate away from potassium oxypentafluoroniobate monohydrate, a process that was discovered by Jean Charles Galissard de Marignac in 1866. This method has been supplanted by solvent extraction from fluoride-containing solutions of tantalum.

Characteristics

Physical properties

Tantalum is dark (blue-gray), dense, ductile, very hard, easily fabricated, and highly conductive of heat and electricity. The metal is renowned for its resistance to corrosion by acids; in fact, at temperatures below 150 °C tantalum is almost completely immune to attack by the normally aggressive aqua regia. It can be dissolved with hydrofluoric acid or acidic solutions containing the fluoride ion and sulfur trioxide, as well as with a solution of potassium hydroxide. Tantalum's high melting point of 3017 °C (boiling point 5458 °C) is exceeded among the elements only by tungsten, rhenium and osmium for metals, and carbon.

Tantalum exists in two crystalline phases, alpha and beta. The alpha phase is relatively ductile and soft; it has body-centered cubic structure (space group Im3m, lattice constant a = 0.33058 nm), Knoop hardness 200–400 HN and electrical resistivity 15–60 µΩ⋅cm. The beta phase is hard and brittle; its crystal symmetry is tetragonal (space group P42/mnm, a = 1.0194 nm, c = 0.5313 nm), Knoop hardness is 1000–1300 HN and electrical resistivity is relatively high at 170–210 µΩ⋅cm. The beta phase is metastable and converts to the alpha phase upon heating to 750–775 °C. Bulk tantalum is almost entirely alpha phase, and the beta phase usually exists as thin films obtained by magnetron sputtering, chemical vapor deposition or electrochemical deposition from an eutectic molten salt solution.

Isotopes

Natural tantalum consists of two isotopes: 180mTa (0.012%) and 181Ta (99.988%). 181Ta is a stable isotope. 180mTa (m denotes a metastable state) is predicted to decay in three ways: isomeric transition to the ground state of 180Ta, beta decay to 180W, or electron capture to 180Hf. However, radioactivity of this nuclear isomer has never been observed, and only a lower limit on its half-life of 2.0 × 1016 years has been set. The ground state of 180Ta has a half-life of only 8 hours. 180mTa is the only naturally occurring nuclear isomer (excluding radiogenic and cosmogenic short-lived nuclides). It is also the rarest isotope in the Universe, taking into account the elemental abundance of tantalum and isotopic abundance of 180mTa in the natural mixture of isotopes (and again excluding radiogenic and cosmogenic short-lived nuclides).

Tantalum has been examined theoretically as a "salting" material for nuclear weapons (cobalt is the better-known hypothetical salting material). An external shell of 181Ta would be irradiated by the intensive high-energy neutron flux from a hypothetical exploding nuclear weapon. This would transmute the tantalum into the radioactive isotope 182Ta, which has a half-life of 114.4 days and produces gamma rays with approximately 1.12 million electron-volts (MeV) of energy apiece, which would significantly increase the radioactivity of the nuclear fallout from the explosion for several months. Such "salted" weapons have never been built or tested, as far as is publicly known, and certainly never used as weapons.

Tantalum can be used as a target material for accelerated proton beams for the production of various short-lived isotopes including 8Li, 80Rb, and 160Yb.

Chemical compounds

Tantalum forms compounds in oxidation states -III to +V. Most commonly encountered are oxides of Ta(V), which includes all minerals. The chemical properties of Ta and Nb are very similar. In aqueous media, Ta only exhibit the +V oxidation state. Like niobium, tantalum is barely soluble in dilute solutions of hydrochloric, sulfuric, nitric and phosphoric acids due to the precipitation of hydrous Ta(V) oxide. In basic media, Ta can be solubilized due to the formation of polyoxotantalate species.

Oxides, nitrides, carbides, sulfides

Tantalum pentoxide (Ta2O5) is the most important compound from the perspective of applications. Oxides of tantalum in lower oxidation states are numerous, including many defect structures, are lightly studied or poorly characterized.

Tantalates, compounds containing [TaO4]3− or [TaO3] are numerous. Lithium tantalate (LiTaO3) adopts a perovskite structure. Lanthanum tantalate (LaTaO4) contains isolated TaO3−
4
tetrahedra.

As in the cases of other refractory metals, the hardest known compounds of tantalum are nitrides and carbides. Tantalum carbide, TaC, like the more commonly used tungsten carbide, is a hard ceramic that is used in cutting tools. Tantalum(III) nitride is used as a thin film insulator in some microelectronic fabrication processes.

The best studied chalcogenide is TaS2, a layered semiconductor, as seen for other transition metal dichalcogenides. A tantalum-tellurium alloy forms quasicrystals.

Halides

Tantalum halides span the oxidation states of +5, +4, and +3. Tantalum pentafluoride (TaF5) is a white solid with a melting point of 97.0 °C. The anion [TaF7]2- is used for its separation from niobium. The chloride TaCl
5
, which exists as a dimer, is the main reagent in synthesis of new Ta compounds. It hydrolyzes readily to an oxychloride. The lower halides TaX
4
and TaX
3
, feature Ta-Ta bonds.

Organotantalum compounds

Organotantalum compounds include pentamethyltantalum, mixed alkyltantalum chlorides, alkyltantalum hydrides, alkylidene complexes as well as cyclopentadienyl derivatives of the same. Diverse salts and substituted derivatives are known for the hexacarbonyl [Ta(CO)6] and related isocyanides

Ta(CH3)5.

Occurrence

Tantalite, Pilbara district, Australia
 
Tantalum is estimated to make up about 1 ppm or 2 ppm of the Earth's crust by weight. There are many species of tantalum minerals, only some of which are so far being used by industry as raw materials: tantalite (a series consisting of tantalite-(Fe), tantalite-(Mn) and tantalite-(Mg)) microlite (now a group name), wodginite, euxenite (actually euxenite-(Y)), and polycrase (actually polycrase-(Y)). Tantalite (Fe, Mn)Ta2O6 is the most important mineral for tantalum extraction. Tantalite has the same mineral structure as columbite (Fe, Mn) (Ta, Nb)2O6; when there is more tantalum than niobium it is called tantalite and when there is more niobium than tantalum is it called columbite (or niobite). The high density of tantalite and other tantalum containing minerals makes the use of gravitational separation the best method. Other minerals include samarskite and fergusonite

Grey and white world map with China, Australia, Brazil and Kongo colored blue representing less than 10% of the tantalum world production each and Rwanda colored in green representing 60% of tantalum world production
Tantalum producers in 2015 with Rwanda being the main producer
 
The primary mining of tantalum is in Australia, where the largest producer, Global Advanced Metals, formerly known as Talison Minerals, operates two mines in Western Australia, Greenbushes in the Southwest and Wodgina in the Pilbara region. The Wodgina mine was reopened in January 2011 after mining at the site was suspended in late-2008 due to the global financial crisis. Less than a year after it reopened, Global Advanced Metals announced that due to again "... softening tantalum demand ...", and other factors, tantalum mining operations were to cease at the end of February 2012. Wodgina produces a primary tantalum concentrate which is further upgraded at the Greenbushes operation before being sold to customers. Whereas the large-scale producers of niobium are in Brazil and Canada, the ore there also yields a small percentage of tantalum. Some other countries such as China, Ethiopia, and Mozambique mine ores with a higher percentage of tantalum, and they produce a significant percentage of the world's output of it. Tantalum is also produced in Thailand and Malaysia as a by-product of the tin mining there. During gravitational separation of the ores from placer deposits, not only is cassiterite (SnO2) found, but a small percentage of tantalite also included. The slag from the tin smelters then contains economically useful amounts of tantalum, which is leached from the slag.

Grey and white world map with Canada, Brazil and Mozambique colored blue representing less than 20% of the tantalum world production each and Australia colored in green representing 60% of tantalum world production
Tantalum producers in 2006 with Australia being the main producer
 
World tantalum mine production has undergone an important geographic shift since the start of the 21st century when production was predominantly from Australia and Brazil. Beginning in 2007 and through 2014, the major sources of tantalum production from mines dramatically shifted to the DRC, Rwanda, and some other African countries. Future sources of supply of tantalum, in order of estimated size, are being explored in Saudi Arabia, Egypt, Greenland, China, Mozambique, Canada, Australia, the United States, Finland, and Brazil.

It is estimated that there are less than 50 years left of tantalum resources, based on extraction at current rates, demonstrating the need for increased recycling.

Status as a conflict resource

Tantalum is considered a conflict resource. Coltan, the industrial name for a columbitetantalite mineral from which niobium and tantalum are extracted, can also be found in Central Africa, which is why tantalum is being linked to warfare in the Democratic Republic of the Congo (formerly Zaire). According to an October 23, 2003 United Nations report, the smuggling and exportation of coltan has helped fuel the war in the Congo, a crisis that has resulted in approximately 5.4 million deaths since 1998 – making it the world’s deadliest documented conflict since World War II. Ethical questions have been raised about responsible corporate behavior, human rights, and endangering wildlife, due to the exploitation of resources such as coltan in the armed conflict regions of the Congo Basin. However, although important for the local economy in Congo, the contribution of coltan mining in Congo to the world supply of tantalum is usually small. The United States Geological Survey reports in its yearbook that this region produced a little less than 1% of the world's tantalum output in 2002–2006, peaking at 10% in 2000 and 2008.

The stated aim of the Solutions for Hope Tantalum Project is to "source conflict-free tantalum from the Democratic Republic of Congo"

Production and fabrication

Time trend of tantalum production until 2012
 
Several steps are involved in the extraction of tantalum from tantalite. First, the mineral is crushed and concentrated by gravity separation. This is generally carried out near the mine site.

Refining

The refining of tantalum from its ores is one of the more demanding separation processes in industrial metallurgy. The chief problem is that tantalum ores contain significant amounts of niobium, which has chemical properties almost identical to those of Ta. A large number of procedures have been developed to address this challenge. 

In modern times, the separation is achieved by hydrometallurgy. Extraction begins with leaching the ore with hydrofluoric acid together with sulfuric acid or hydrochloric acid. This step allows the tantalum and niobium to be separated from the various non-metallic impurities in the rock. Although Ta occurs as various minerals, it is conveniently represented as the pentoxide, since most oxides of tantalum(V) behave similarly under these conditions. A simplified equation for its extraction is thus:
Ta2O5 + 14 HF → 2 H2[TaF7] + 5 H2O
Completely analogous reactions occur for the niobium component, but the hexafluoride is typically predominant under the conditions of the extraction.
Nb2O5 + 12 HF → 2 H[NbF6] + 5 H2O
These equations are simplified: it is suspected that bisulfate (HSO4) and chloride compete as ligands for the Nb(V) and Ta(V) ions, when sulfuric and hydrochloric acids are used, respectively. The tantalum and niobium fluoride complexes are then removed from the aqueous solution by liquid-liquid extraction into organic solvents, such as cyclohexanone, octanol, and methyl isobutyl ketone. This simple procedure allows the removal of most metal-containing impurities (e.g. iron, manganese, titanium, zirconium), which remain in the aqueous phase in the form of their fluorides and other complexes. 

Separation of the tantalum from niobium is then achieved by lowering the ionic strength of the acid mixture, which causes the niobium to dissolve in the aqueous phase. It is proposed that oxyfluoride H2[NbOF5] is formed under these conditions. Subsequent to removal of the niobium, the solution of purified H2[TaF7] is neutralised with aqueous ammonia to precipitate hydrated tantalum oxide as a solid, which can be calcined to tantalum pentoxide (Ta2O5).

Instead of hydrolysis, the H2[TaF7] can be treated with potassium fluoride to produce potassium heptafluorotantalate:
H2[TaF7] + 2 KF → K2[TaF7] + 2 HF
Unlike H2[TaF7], the potassium salt is readily crystallized and handled as a solid. 

K2[TaF7] can be converted to metallic tantalum by reduction with sodium, at approximately 800 °C in molten salt.
K2[TaF7] + 5 Na → Ta + 5 NaF + 2 KF
In an older method, called the Marignac process, the mixture of H2[TaF7] and H2[NbOF5] was converted to a mixture of K2[TaF7] and K2[NbOF5], which was then be separated by fractional crystallization, exploiting their different water solubilities.

Electrolysis

Tantalum can also be refined by electrolysis, using a modified version of the Hall–Héroult process. Instead of requiring the input oxide and output metal to be in liquid form, tantalum electrolysis operates on non-liquid powdered oxides. The initial discovery came in 1997 when Cambridge University researchers immersed small samples of certain oxides in baths of molten salt and reduced the oxide with electric current. The cathode uses powdered metal oxide. The anode is made of carbon. The molten salt at 1,000 °C (1,830 °F) is the electrolyte. The first refinery has enough capacity to supply 3–4% of annual global demand.

Fabrication and metalworking

All welding of tantalum must be done in an inert atmosphere of argon or helium in order to shield it from contamination with atmospheric gases. Tantalum is not solderable. Grinding tantalum is difficult, especially so for annealed tantalum. In the annealed condition, tantalum is extremely ductile and can be readily formed as metal sheets.

Applications

Electronics

Tantalum electrolytic capacitor
 
The major use for tantalum, as the metal powder, is in the production of electronic components, mainly capacitors and some high-power resistors. Tantalum electrolytic capacitors exploit the tendency of tantalum to form a protective oxide surface layer, using tantalum powder, pressed into a pellet shape, as one "plate" of the capacitor, the oxide as the dielectric, and an electrolytic solution or conductive solid as the other "plate". Because the dielectric layer can be very thin (thinner than the similar layer in, for instance, an aluminium electrolytic capacitor), a high capacitance can be achieved in a small volume. Because of the size and weight advantages, tantalum capacitors are attractive for portable telephones, personal computers, automotive electronics and cameras.

Alloys

Tantalum is also used to produce a variety of alloys that have high melting points, strength, and ductility. Alloyed with other metals, it is also used in making carbide tools for metalworking equipment and in the production of superalloys for jet engine components, chemical process equipment, nuclear reactors, missile parts, heat exchangers, tanks, and vessels. Because of its ductility, tantalum can be drawn into fine wires or filaments, which are used for evaporating metals such as aluminium. Since it resists attack by body fluids and is nonirritating, tantalum is widely used in making surgical instruments and implants. For example, porous tantalum coatings are used in the construction of orthopedic implants due to tantalum's ability to form a direct bond to hard tissue.

Tantalum is inert against most acids except hydrofluoric acid and hot sulfuric acid, and hot alkaline solutions also cause tantalum to corrode. This property makes it a useful metal for chemical reaction vessels and pipes for corrosive liquids. Heat exchanging coils for the steam heating of hydrochloric acid are made from tantalum. Tantalum was extensively used in the production of ultra high frequency electron tubes for radio transmitters. Tantalum is capable of capturing oxygen and nitrogen by forming nitrides and oxides and therefore helped to sustain the high vacuum needed for the tubes when used for internal parts such as grids and plates.

Other uses

Bimetallic coins minted by the Bank of Kazakhstan with silver ring and tantalum center.
 
The high melting point and oxidation resistance lead to the use of the metal in the production of vacuum furnace parts. Tantalum is extremely inert and is therefore formed into a variety of corrosion resistant parts, such as thermowells, valve bodies, and tantalum fasteners. Due to its high density, shaped charge and explosively formed penetrator liners have been constructed from tantalum. Tantalum greatly increases the armor penetration capabilities of a shaped charge due to its high density and high melting point. It is also occasionally used in precious watches e.g. from Audemars Piguet, F.P. Journe, Hublot, Montblanc, Omega, and Panerai. Tantalum is also highly bioinert and is used as an orthopedic implant material. The high stiffness of tantalum makes it necessary to use it as highly porous foam or scaffold with lower stiffness for hip replacement implants to avoid stress shielding. Because tantalum is a non-ferrous, non-magnetic metal, these implants are considered to be acceptable for patients undergoing MRI procedures. The oxide is used to make special high refractive index glass for camera lenses.

Environmental issues

Tantalum receives far less attention in the environmental field than it does in other geosciences. Upper Crust Concentrations (UCC) and the Nb/Ta ratio in the upper crust and in minerals are available because these measurements are useful as a geochemical tool. The latest values for UCC and the Nb/Ta(w/w) ratio in the upper crust stand at 0.92 ppm and 12.7 respectively.

Little data is available on tantalum concentrations in the different environmental compartments, especially in natural waters where reliable estimates of ‘dissolved’ tantalum concentrations in seawater and freshwaters have not even been produced. Some values on dissolved concentrations in oceans have been published, but they are contradictory. Values in freshwaters fare little better, but, in all cases, they are probably below 1 ng L−1,since ‘dissolved’ concentrations in natural waters are well below most current analytical capabilities. Analysis requires pre-concentration procedures that, for the moment, do not give consistent results. And in any case, tantalum appears to be present in natural waters mostly as particulate matter rather than dissolved.

Values for concentrations in soils, bed sediments and atmospheric aerosols are easier to come by. Values in soils are close to 1 ppm and thus to UCC values. This indicates detrital origin. For atmospheric aerosols the values available are scattered and limited. When tantalum enrichment is observed, it is probably due to loss of more water-soluble elements in aerosols in the clouds.

Pollution linked to human use of the element has not been detected. Tantalum appears to be a very conservative element in biogeochemical terms, but its cycling and reactivity are still not fully understood.

Precautions

Compounds containing tantalum are rarely encountered in the laboratory. The metal is highly biocompatible and is used for body implants and coatings, therefore attention may be focused on other elements or the physical nature of the chemical compound.

People can be exposed to tantalum in the workplace by breathing it in, skin contact, or eye contact. The Occupational Safety and Health Administration (OSHA) has set the legal limit (permissible exposure limit) for tantalum exposure in the workplace as 5 mg/m3 over an 8-hour workday. The National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit (REL) of 5 mg/m3 over an 8-hour workday and a short-term limit of 10 mg/m3. At levels of 2500 mg/m3, tantalum is immediately dangerous to life and health.

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