Fire

From Wikipedia, the free encyclopedia

An outdoor wood fire

 

Fire is the rapid oxidation of a material in the exothermic chemical process of combustion, releasing heat, light, and various reaction products. Slower oxidative processes like rusting or digestion are not included by this definition.

Fire is hot because the conversion of the weak double bond in molecular oxygen, O₂, to the stronger bonds in the combustion products carbon dioxide and water releases energy (418 kJ per 32 g of O₂); the bond energies of the fuel play only a minor role here. At a certain point in the combustion reaction, called the ignition point, flames are produced. The flame is the visible portion of the fire. Flames consist primarily of carbon dioxide, water vapor, oxygen and nitrogen. If hot enough, the gases may become ionized to produce plasma. Depending on the substances alight, and any impurities outside, the color of the flame and the fire's intensity will be different. 

Fire in its most common form can result in conflagration, which has the potential to cause physical damage through burning. Fire is an important process that affects ecological systems around the globe. The positive effects of fire include stimulating growth and maintaining various ecological systems. 

The negative effects of fire include hazard to life and property, atmospheric pollution, and water contamination. If fire removes protective vegetation, heavy rainfall may lead to an increase in soil erosion by water. Also, when vegetation is burned, the nitrogen it contains is released into the atmosphere, unlike elements such as potassium and phosphorus which remain in the ash and are quickly recycled into the soil. This loss of nitrogen caused by a fire produces a long-term reduction in the fertility of the soil, which only slowly recovers as nitrogen is "fixed" from the atmosphere by lightning and by leguminous plants such as clover.

Fire has been used by humans in rituals, in agriculture for clearing land, for cooking, generating heat and light, for signaling, propulsion purposes, smelting, forging, incineration of waste, cremation, and as a weapon or mode of destruction.

Physical properties

Chemistry

The fire tetrahedron

 

Fires start when a flammable or a combustible material, in combination with a sufficient quantity of an oxidizer such as oxygen gas or another oxygen-rich compound (though non-oxygen oxidizers exist), is exposed to a source of heat or ambient temperature above the flash point for the fuel/oxidizer mix, and is able to sustain a rate of rapid oxidation that produces a chain reaction. This is commonly called the fire tetrahedron. Fire cannot exist without all of these elements in place and in the right proportions. For example, a flammable liquid will start burning only if the fuel and oxygen are in the right proportions. Some fuel-oxygen mixes may require a catalyst, a substance that is not consumed, when added, in any chemical reaction during combustion, but which enables the reactants to combust more readily.

Once ignited, a chain reaction must take place whereby fires can sustain their own heat by the further release of heat energy in the process of combustion and may propagate, provided there is a continuous supply of an oxidizer and fuel.

If the oxidizer is oxygen from the surrounding air, the presence of a force of gravity, or of some similar force caused by acceleration, is necessary to produce convection, which removes combustion products and brings a supply of oxygen to the fire. Without gravity, a fire rapidly surrounds itself with its own combustion products and non-oxidizing gases from the air, which exclude oxygen and extinguish the fire. Because of this, the risk of fire in a spacecraft is small when it is coasting in inertial flight. This does not apply if oxygen is supplied to the fire by some process other than thermal convection.

Fire can be extinguished by removing any one of the elements of the fire tetrahedron. Consider a natural gas flame, such as from a stove-top burner. The fire can be extinguished by any of the following:

• turning off the gas supply, which removes the fuel source;
• covering the flame completely, which smothers the flame as the combustion both uses the available oxidizer (the oxygen in the air) and displaces it from the area around the flame with CO₂;
• application of water, which removes heat from the fire faster than the fire can produce it (similarly, blowing hard on a flame will displace the heat of the currently burning gas from its fuel source, to the same end), or
• application of a retardant chemical such as Halon to the flame, which retards the chemical reaction itself until the rate of combustion is too slow to maintain the chain reaction.

In contrast, fire is intensified by increasing the overall rate of combustion. Methods to do this include balancing the input of fuel and oxidizer to stoichiometric proportions, increasing fuel and oxidizer input in this balanced mix, increasing the ambient temperature so the fire's own heat is better able to sustain combustion, or providing a catalyst, a non-reactant medium in which the fuel and oxidizer can more readily react.

Flame

A candle's flame

 

Northwest Crown Fire Experiment, Canada

 

Photo of a fire taken with a 1/4000th of a second exposure

 

Fire is affected by gravity. Left: Flame on Earth; Right: Flame on the ISS

 

A flame is a mixture of reacting gases and solids emitting visible, infrared, and sometimes ultraviolet light, the frequency spectrum of which depends on the chemical composition of the burning material and intermediate reaction products. In many cases, such as the burning of organic matter, for example wood, or the incomplete combustion of gas, incandescent solid particles called soot produce the familiar red-orange glow of "fire". This light has a continuous spectrum. Complete combustion of gas has a dim blue color due to the emission of single-wavelength radiation from various electron transitions in the excited molecules formed in the flame. Usually oxygen is involved, but hydrogen burning in chlorine also produces a flame, producing hydrogen chloride (HCl). Other possible combinations producing flames, amongst many, are fluorine and hydrogen, and hydrazine and nitrogen tetroxide. Hydrogen and hydrazine/UDMH flames are similarly pale blue, while burning boron and its compounds, evaluated in mid-20th century as a high energy fuel for jet and rocket engines, emits intense green flame, leading to its informal nickname of "Green Dragon". 

The glow of a flame is complex. Black-body radiation is emitted from soot, gas, and fuel particles, though the soot particles are too small to behave like perfect blackbodies. There is also photon emission by de-excited atoms and molecules in the gases. Much of the radiation is emitted in the visible and infrared bands. The color depends on temperature for the black-body radiation, and on chemical makeup for the emission spectra. The dominant color in a flame changes with temperature. The photo of the forest fire in Canada is an excellent example of this variation. Near the ground, where most burning is occurring, the fire is white, the hottest color possible for organic material in general, or yellow. Above the yellow region, the color changes to orange, which is cooler, then red, which is cooler still. Above the red region, combustion no longer occurs, and the uncombusted carbon particles are visible as black smoke. 

The common distribution of a flame under normal gravity conditions depends on convection, as soot tends to rise to the top of a general flame, as in a candle in normal gravity conditions, making it yellow. In micro gravity or zero gravity, such as an environment in outer space, convection no longer occurs, and the flame becomes spherical, with a tendency to become more blue and more efficient (although it may go out if not moved steadily, as the CO₂ from combustion does not disperse as readily in micro gravity, and tends to smother the flame). There are several possible explanations for this difference, of which the most likely is that the temperature is sufficiently evenly distributed that soot is not formed and complete combustion occurs. Experiments by NASA reveal that diffusion flames in micro gravity allow more soot to be completely oxidized after they are produced than diffusion flames on Earth, because of a series of mechanisms that behave differently in micro gravity when compared to normal gravity conditions. These discoveries have potential applications in applied science and industry, especially concerning fuel efficiency.

In combustion engines, various steps are taken to eliminate a flame. The method depends mainly on whether the fuel is oil, wood, or a high-energy fuel such as jet fuel.

Flame temperatures

Temperatures of flames by appearance

It is true that objects at specific temperatures do radiate visible light. Objects whose surface is at a temperature above approximately 400 °C (752 °F) will glow, emitting light at a color that indicates the temperature of that surface. See the section on red heat for more about this effect. It is a misconception that one can judge the temperature of a fire by the color of its flames or the sparks in the flames. For many reasons, chemically and optically, these colors may not match the red/orange/yellow/white heat temperatures on the chart. Barium nitrate burns a bright green, for instance, and this is not present on the heat chart.

Typical temperatures of flames

The "adiabatic flame temperature" of a given fuel and oxidizer pair indicates the temperature at which the gases achieve stable combustion.

• Oxy–dicyanoacetylene 4,990 °C (9,000 °F)
• Oxy–acetylene 3,480 °C (6,300 °F)
• Oxyhydrogen 2,800 °C (5,100 °F)
• Air–acetylene 2,534 °C (4,600 °F)
• Blowtorch (air–MAPP gas) 2,200 °C (4,000 °F)
• Bunsen burner (air–natural gas) 1,300 to 1,600 °C (2,400 to 2,900 °F)
• Candle (air–paraffin) 1,000 °C (1,800 °F)
• Smoldering cigarette:
  • Temperature without drawing: side of the lit portion; 400 °C (750 °F); middle of the lit portion: 585 °C (1,100 °F)
  • Temperature during drawing: middle of the lit portion: 700 °C (1,300 °F)
  • Always hotter in the middle.

Fire ecology

Every natural ecosystem has its own fire regime, and the organisms in those ecosystems are adapted to or dependent upon that fire regime. Fire creates a mosaic of different habitat patches, each at a different stage of succession. Different species of plants, animals, and microbes specialize in exploiting a particular stage, and by creating these different types of patches, fire allows a greater number of species to exist within a landscape.

Fossil record

The fossil record of fire first appears with the establishment of a land-based flora in the Middle Ordovician period, 470 million years ago, permitting the accumulation of oxygen in the atmosphere as never before, as the new hordes of land plants pumped it out as a waste product. When this concentration rose above 13%, it permitted the possibility of wildfire. Wildfire is first recorded in the Late Silurian fossil record, 420 million years ago, by fossils of charcoalified plants. Apart from a controversial gap in the Late Devonian, charcoal is present ever since. The level of atmospheric oxygen is closely related to the prevalence of charcoal: clearly oxygen is the key factor in the abundance of wildfire. Fire also became more abundant when grasses radiated and became the dominant component of many ecosystems, around 6 to 7 million years ago; this kindling provided tinder which allowed for the more rapid spread of fire. These widespread fires may have initiated a positive feedback process, whereby they produced a warmer, drier climate more conducive to fire.

Human control

Bushman starting a fire in Namibia

 

Process of ignition of a match

 

The ability to control fire was a dramatic change in the habits of early humans. Making fire to generate heat and light made it possible for people to cook food, simultaneously increasing the variety and availability of nutrients and reducing disease by killing organisms in the food. The heat produced would also help people stay warm in cold weather, enabling them to live in cooler climates. Fire also kept nocturnal predators at bay. Evidence of cooked food is found from 1.9 million years ago, although there is a theory that fire could have been used in a controlled fashion about 1 million years ago. Evidence becomes widespread around 50 to 100 thousand years ago, suggesting regular use from this time; resistance to air pollution started to evolve in human populations at a similar point in time. The use of fire became progressively more sophisticated, with it being used to create charcoal and to control wildlife from tens of thousands of years ago.

Fire has also been used for centuries as a method of torture and execution, as evidenced by death by burning as well as torture devices such as the iron boot, which could be filled with water, oil, or even lead and then heated over an open fire to the agony of the wearer.

By the Neolithic Revolution, during the introduction of grain-based agriculture, people all over the world used fire as a tool in landscape management. These fires were typically controlled burns or "cool fires", as opposed to uncontrolled "hot fires", which damage the soil. Hot fires destroy plants and animals, and endanger communities. This is especially a problem in the forests of today where traditional burning is prevented in order to encourage the growth of timber crops. Cool fires are generally conducted in the spring and autumn. They clear undergrowth, burning up biomass that could trigger a hot fire should it get too dense. They provide a greater variety of environments, which encourages game and plant diversity. For humans, they make dense, impassable forests traversable. Another human use for fire in regards to landscape management is its use to clear land for agriculture. Slash-and-burn agriculture is still common across much of tropical Africa, Asia and South America. "For small farmers, it is a convenient way to clear overgrown areas and release nutrients from standing vegetation back into the soil", said Miguel Pinedo-Vasquez, an ecologist at the Earth Institute’s Center for Environmental Research and Conservation. However this useful strategy is also problematic. Growing population, fragmentation of forests and warming climate are making the earth's surface more prone to ever-larger escaped fires. These harm ecosystems and human infrastructure, cause health problems, and send up spirals of carbon and soot that may encourage even more warming of the atmosphere – and thus feed back into more fires. Globally today, as much as 5 million square kilometres – an area more than half the size of the United States – burns in a given year.

There are numerous modern applications of fire. In its broadest sense, fire is used by nearly every human being on earth in a controlled setting every day. Users of internal combustion vehicles employ fire every time they drive. Thermal power stations provide electricity for a large percentage of humanity. 

Hamburg after four fire-bombing raids in July 1943, which killed an estimated 50,000 people

 

The use of fire in warfare has a long history. Fire was the basis of all early thermal weapons. Homer detailed the use of fire by Greek soldiers who hid in a wooden horse to burn Troy during the Trojan war. Later the Byzantine fleet used Greek fire to attack ships and men. In the First World War, the first modern flamethrowers were used by infantry, and were successfully mounted on armoured vehicles in the Second World War. In the latter war, incendiary bombs were used by Axis and Allies alike, notably on Tokyo, Rotterdam, London, Hamburg and, notoriously, at Dresden; in the latter two cases firestorms were deliberately caused in which a ring of fire surrounding each city was drawn inward by an updraft caused by a central cluster of fires. The United States Army Air Force also extensively used incendiaries against Japanese targets in the latter months of the war, devastating entire cities constructed primarily of wood and paper houses. The use of napalm was employed in July 1944, towards the end of the Second World War; although its use did not gain public attention until the Vietnam War. Molotov cocktails were also used.

Use as fuel

A coal-fired power station in the People's Republic of China

 

Disability-adjusted life year for fires per 100,000 inhabitants in 2004

 

  no data

  less than 50

  50–100

  100–150

  150–200

  200–250

  250–300

  300–350

  350–400

  400–450

  450–500

  500–600

  more than 600

Setting fuel aflame releases usable energy. Wood was a prehistoric fuel, and is still viable today. The use of fossil fuels, such as petroleum, natural gas, and coal, in power plants supplies the vast majority of the world's electricity today; the International Energy Agency states that nearly 80% of the world's power came from these sources in 2002. The fire in a power station is used to heat water, creating steam that drives turbines. The turbines then spin an electric generator to produce electricity. Fire is also used to provide mechanical work directly, in both external and internal combustion engines.

The unburnable solid remains of a combustible material left after a fire is called clinker if its melting point is below the flame temperature, so that it fuses and then solidifies as it cools, and ash if its melting point is above the flame temperature.

Protection and prevention

Wildfire prevention programs around the world may employ techniques such as wildland fire use and prescribed or controlled burns. Wildland fire use refers to any fire of natural causes that is monitored but allowed to burn. Controlled burns are fires ignited by government agencies under less dangerous weather conditions.

Fire fighting services are provided in most developed areas to extinguish or contain uncontrolled fires. Trained firefighters use fire apparatus, water supply resources such as water mains and fire hydrants or they might use A and B class foam depending on what is feeding the fire. 

Fire prevention is intended to reduce sources of ignition. Fire prevention also includes education to teach people how to avoid causing fires. Buildings, especially schools and tall buildings, often conduct fire drills to inform and prepare citizens on how to react to a building fire. Purposely starting destructive fires constitutes arson and is a crime in most jurisdictions.

Model building codes require passive fire protection and active fire protection systems to minimize damage resulting from a fire. The most common form of active fire protection is fire sprinklers. To maximize passive fire protection of buildings, building materials and furnishings in most developed countries are tested for fire-resistance, combustibility and flammability. Upholstery, carpeting and plastics used in vehicles and vessels are also tested.

Where fire prevention and fire protection have failed to prevent damage, fire insurance can mitigate the financial impact.

Restoration

Different restoration methods and measures are used depending on the type of fire damage that occurred. Restoration after fire damage can be performed by property management teams, building maintenance personnel, or by the homeowners themselves; however, contacting a certified professional fire damage restoration specialist is often regarded as the safest way to restore fire damaged property due to their training and extensive experience. Most are usually listed under "Fire and Water Restoration" and they can help speed repairs, whether for individual homeowners or for the largest of institutions.

Fire and Water Restoration companies are regulated by the appropriate state's Department of Consumer Affairs – usually the state contractors license board. In California, all Fire and Water Restoration companies must register with the California Contractors State License Board. Presently, the California Contractors State License Board has no specific classification for "water and fire damage restoration." Hence, the Contractor's State License Board requires both an asbestos certification (ASB) as well as a demolition classification (C-21) in order to perform Fire and Water Restoration work.

Wood

From Wikipedia, the free encyclopedia

 

Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic material, a natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin that resists compression. Wood is sometimes defined as only the secondary xylem in the stems of trees, or it is defined more broadly to include the same type of tissue elsewhere such as in the roots of trees or shrubs. In a living tree it performs a support function, enabling woody plants to grow large or to stand up by themselves. It also conveys water and nutrients between the leaves, other growing tissues, and the roots. Wood may also refer to other plant materials with comparable properties, and to material engineered from wood, or wood chips or fiber.

 

Wood has been used for thousands of years for fuel, as a construction material, for making tools and weapons, furniture and paper. More recently it emerged as a feedstock for the production of purified cellulose and its derivatives, such as cellophane and cellulose acetate.

As of 2005, the growing stock of forests worldwide was about 434 billion cubic meters, 47% of which was commercial. As an abundant, carbon-neutral renewable resource, woody materials have been of intense interest as a source of renewable energy. In 1991 approximately 3.5 billion cubic meters of wood were harvested. Dominant uses were for furniture and building construction.

History

A 2011 discovery in the Canadian province of New Brunswick yielded the earliest known plants to have grown wood, approximately 395 to 400 million years ago.

Wood can be dated by carbon dating and in some species by dendrochronology to determine when a wooden object was created.

People have used wood for thousands of years for many purposes, including as a fuel or as a construction material for making houses, tools, weapons, furniture, packaging, artworks, and paper. Known constructions using wood date back ten thousand years. Buildings like the European Neolithic long house were made primarily of wood.

Recent use of wood has been enhanced by the addition of steel and bronze into construction.

The year-to-year variation in tree-ring widths and isotopic abundances gives clues to the prevailing climate at the time a tree was cut.

Physical properties

Diagram of secondary growth in a tree showing idealized vertical and horizontal sections. A new layer of wood is added in each growing season, thickening the stem, existing branches and roots, to form a growth ring.

Growth rings

Wood, in the strict sense, is yielded by trees, which increase in diameter by the formation, between the existing wood and the inner bark, of new woody layers which envelop the entire stem, living branches, and roots. This process is known as secondary growth; it is the result of cell division in the vascular cambium, a lateral meristem, and subsequent expansion of the new cells. These cells then go on to form thickened secondary cell walls, composed mainly of cellulose, hemicellulose and lignin.

Where the differences between the four seasons are distinct, e.g. New Zealand, growth can occur in a discrete annual or seasonal pattern, leading to growth rings; these can usually be most clearly seen on the end of a log, but are also visible on the other surfaces. If the distinctiveness between seasons is annual (as is the case in equatorial regions, e.g. Singapore), these growth rings are referred to as annual rings. Where there is little seasonal difference growth rings are likely to be indistinct or absent. If the bark of the tree has been removed in a particular area, the rings will likely be deformed as the plant overgrows the scar. 

If there are differences within a growth ring, then the part of a growth ring nearest the center of the tree, and formed early in the growing season when growth is rapid, is usually composed of wider elements. It is usually lighter in color than that near the outer portion of the ring, and is known as earlywood or springwood. The outer portion formed later in the season is then known as the latewood or summerwood. However, there are major differences, depending on the kind of wood (see below).

Knots

A knot on a tree trunk

 

As a tree grows, lower branches often die, and their bases may become overgrown and enclosed by subsequent layers of trunk wood, forming a type of imperfection known as a knot. The dead branch may not be attached to the trunk wood except at its base, and can drop out after the tree has been sawn into boards. Knots affect the technical properties of the wood, usually reducing the local strength and increasing the tendency for splitting along the wood grain, but may be exploited for visual effect. In a longitudinally sawn plank, a knot will appear as a roughly circular "solid" (usually darker) piece of wood around which the grain of the rest of the wood "flows" (parts and rejoins). Within a knot, the direction of the wood (grain direction) is up to 90 degrees different from the grain direction of the regular wood. 

In the tree a knot is either the base of a side branch or a dormant bud. A knot (when the base of a side branch) is conical in shape (hence the roughly circular cross-section) with the inner tip at the point in stem diameter at which the plant's vascular cambium was located when the branch formed as a bud.

In grading lumber and structural timber, knots are classified according to their form, size, soundness, and the firmness with which they are held in place. This firmness is affected by, among other factors, the length of time for which the branch was dead while the attaching stem continued to grow. 

Wood knot in vertical section

Knots materially affect cracking and warping, ease in working, and cleavability of timber. They are defects which weaken timber and lower its value for structural purposes where strength is an important consideration. The weakening effect is much more serious when timber is subjected to forces perpendicular to the grain and/or tension than when under load along the grain and/or compression. The extent to which knots affect the strength of a beam depends upon their position, size, number, and condition. A knot on the upper side is compressed, while one on the lower side is subjected to tension. If there is a season check in the knot, as is often the case, it will offer little resistance to this tensile stress. Small knots, however, may be located along the neutral plane of a beam and increase the strength by preventing longitudinal shearing. Knots in a board or plank are least injurious when they extend through it at right angles to its broadest surface. Knots which occur near the ends of a beam do not weaken it. Sound knots which occur in the central portion one-fourth the height of the beam from either edge are not serious defects.

— Samuel J. Record, The Mechanical Properties of Wood

Knots do not necessarily influence the stiffness of structural timber, this will depend on the size and location. Stiffness and elastic strength are more dependent upon the sound wood than upon localized defects. The breaking strength is very susceptible to defects. Sound knots do not weaken wood when subject to compression parallel to the grain. 

In some decorative applications, wood with knots may be desirable to add visual interest. In applications where wood is painted, such as skirting boards, fascia boards, door frames and furniture, resins present in the timber may continue to 'bleed' through to the surface of a knot for months or even years after manufacture and show as a yellow or brownish stain. A knot primer paint or solution (knotting), correctly applied during preparation, may do much to reduce this problem but it is difficult to control completely, especially when using mass-produced kiln-dried timber stocks.

Heartwood and sapwood

A section of a Yew branch showing 27 annual growth rings, pale sapwood, dark heartwood, and pith (center dark spot). The dark radial lines are small knots.

 

Heartwood (or duramen) is wood that as a result of a naturally occurring chemical transformation has become more resistant to decay. Heartwood formation is a genetically programmed process that occurs spontaneously. Some uncertainty exists as to whether the wood dies during heartwood formation, as it can still chemically react to decay organisms, but only once.

Heartwood is often visually distinct from the living sapwood, and can be distinguished in a cross-section where the boundary will tend to follow the growth rings. For example, it is sometimes much darker. However, other processes such as decay or insect invasion can also discolor wood, even in woody plants that do not form heartwood, which may lead to confusion.

Sapwood (or alburnum) is the younger, outermost wood; in the growing tree it is living wood, and its principal functions are to conduct water from the roots to the leaves and to store up and give back according to the season the reserves prepared in the leaves. However, by the time they become competent to conduct water, all xylem tracheids and vessels have lost their cytoplasm and the cells are therefore functionally dead. All wood in a tree is first formed as sapwood. The more leaves a tree bears and the more vigorous its growth, the larger the volume of sapwood required. Hence trees making rapid growth in the open have thicker sapwood for their size than trees of the same species growing in dense forests. Sometimes trees (of species that do form heartwood) grown in the open may become of considerable size, 30 cm (12 in) or more in diameter, before any heartwood begins to form, for example, in second-growth hickory, or open-grown pines. 

The term heartwood derives solely from its position and not from any vital importance to the tree. This is evidenced by the fact that a tree can thrive with its heart completely decayed. Some species begin to form heartwood very early in life, so having only a thin layer of live sapwood, while in others the change comes slowly. Thin sapwood is characteristic of such species as chestnut, black locust, mulberry, osage-orange, and sassafras, while in maple, ash, hickory, hackberry, beech, and pine, thick sapwood is the rule. Others never form heartwood.

No definite relation exists between the annual rings of growth and the amount of sapwood. Within the same species the cross-sectional area of the sapwood is very roughly proportional to the size of the crown of the tree. If the rings are narrow, more of them are required than where they are wide. As the tree gets larger, the sapwood must necessarily become thinner or increase materially in volume. Sapwood is relatively thicker in the upper portion of the trunk of a tree than near the base, because the age and the diameter of the upper sections are less. 

When a tree is very young it is covered with limbs almost, if not entirely, to the ground, but as it grows older some or all of them will eventually die and are either broken off or fall off. Subsequent growth of wood may completely conceal the stubs which will however remain as knots. No matter how smooth and clear a log is on the outside, it is more or less knotty near the middle. Consequently, the sapwood of an old tree, and particularly of a forest-grown tree, will be freer from knots than the inner heartwood. Since in most uses of wood, knots are defects that weaken the timber and interfere with its ease of working and other properties, it follows that a given piece of sapwood, because of its position in the tree, may well be stronger than a piece of heartwood from the same tree. 

It is remarkable that the inner heartwood of old trees remains as sound as it usually does, since in many cases it is hundreds, and in a few instances thousands, of years old. Every broken limb or root, or deep wound from fire, insects, or falling timber, may afford an entrance for decay, which, once started, may penetrate to all parts of the trunk. The larvae of many insects bore into the trees and their tunnels remain indefinitely as sources of weakness. Whatever advantages, however, that sapwood may have in this connection are due solely to its relative age and position. 

If a tree grows all its life in the open and the conditions of soil and site remain unchanged, it will make its most rapid growth in youth, and gradually decline. The annual rings of growth are for many years quite wide, but later they become narrower and narrower. Since each succeeding ring is laid down on the outside of the wood previously formed, it follows that unless a tree materially increases its production of wood from year to year, the rings must necessarily become thinner as the trunk gets wider. As a tree reaches maturity its crown becomes more open and the annual wood production is lessened, thereby reducing still more the width of the growth rings. In the case of forest-grown trees so much depends upon the competition of the trees in their struggle for light and nourishment that periods of rapid and slow growth may alternate. Some trees, such as southern oaks, maintain the same width of ring for hundreds of years. Upon the whole, however, as a tree gets larger in diameter the width of the growth rings decreases. 

Different pieces of wood cut from a large tree may differ decidedly, particularly if the tree is big and mature. In some trees, the wood laid on late in the life of a tree is softer, lighter, weaker, and more even-textured than that produced earlier, but in other trees, the reverse applies. This may or may not correspond to heartwood and sapwood. In a large log the sapwood, because of the time in the life of the tree when it was grown, may be inferior in hardness, strength, and toughness to equally sound heartwood from the same log. In a smaller tree, the reverse may be true.

Color

The wood of coast redwood is distinctively red.

 

In species which show a distinct difference between heartwood and sapwood the natural color of heartwood is usually darker than that of the sapwood, and very frequently the contrast is conspicuous (see section of yew log above). This is produced by deposits in the heartwood of chemical substances, so that a dramatic color variation does not imply a significant difference in the mechanical properties of heartwood and sapwood, although there may be a marked biochemical difference between the two. 

Some experiments on very resinous longleaf pine specimens indicate an increase in strength, due to the resin which increases the strength when dry. Such resin-saturated heartwood is called "fat lighter". Structures built of fat lighter are almost impervious to rot and termites; however they are very flammable. Stumps of old longleaf pines are often dug, split into small pieces and sold as kindling for fires. Stumps thus dug may actually remain a century or more since being cut. Spruce impregnated with crude resin and dried is also greatly increased in strength thereby. 

Since the latewood of a growth ring is usually darker in color than the earlywood, this fact may be used in visually judging the density, and therefore the hardness and strength of the material. This is particularly the case with coniferous woods. In ring-porous woods the vessels of the early wood often appear on a finished surface as darker than the denser latewood, though on cross sections of heartwood the reverse is commonly true. Otherwise the color of wood is no indication of strength. 

Abnormal discoloration of wood often denotes a diseased condition, indicating unsoundness. The black check in western hemlock is the result of insect attacks. The reddish-brown streaks so common in hickory and certain other woods are mostly the result of injury by birds. The discoloration is merely an indication of an injury, and in all probability does not of itself affect the properties of the wood. Certain rot-producing fungi impart to wood characteristic colors which thus become symptomatic of weakness; however an attractive effect known as spalting produced by this process is often considered a desirable characteristic. Ordinary sap-staining is due to fungal growth, but does not necessarily produce a weakening effect.

Water content

Water occurs in living wood in three locations, namely:

• in the cell walls,
• in the protoplasmic contents of the cells
• as free water in the cell cavities and spaces, especially of the xylem

In heartwood it occurs only in the first and last forms. Wood that is thoroughly air-dried retains 8–16% of the water in the cell walls, and none, or practically none, in the other forms. Even oven-dried wood retains a small percentage of moisture, but for all except chemical purposes, may be considered absolutely dry.

The general effect of the water content upon the wood substance is to render it softer and more pliable. A similar effect occurs in the softening action of water on rawhide, paper, or cloth. Within certain limits, the greater the water content, the greater its softening effect.

Drying produces a decided increase in the strength of wood, particularly in small specimens. An extreme example is the case of a completely dry spruce block 5 cm in section, which will sustain a permanent load four times as great as a green (undried) block of the same size will. 

The greatest strength increase due to drying is in the ultimate crushing strength, and strength at elastic limit in endwise compression; these are followed by the modulus of rupture, and stress at elastic limit in cross-bending, while the modulus of elasticity is least affected.

Structure

Magnified cross-section of black walnut, showing the vessels, rays (white lines) and annual rings: this is intermediate between diffuse-porous and ring-porous, with vessel size declining gradually

 

Wood is a heterogeneous, hygroscopic, cellular and anisotropic material. It consists of cells, and the cell walls are composed of micro-fibrils of cellulose (40–50%) and hemicellulose (15–25%) impregnated with lignin (15–30%).

In coniferous or softwood species the wood cells are mostly of one kind, tracheids, and as a result the material is much more uniform in structure than that of most hardwoods. There are no vessels ("pores") in coniferous wood such as one sees so prominently in oak and ash, for example.

The structure of hardwoods is more complex. The water conducting capability is mostly taken care of by vessels: in some cases (oak, chestnut, ash) these are quite large and distinct, in others (buckeye, poplar, willow) too small to be seen without a hand lens. In discussing such woods it is customary to divide them into two large classes, ring-porous and diffuse-porous.

In ring-porous species, such as ash, black locust, catalpa, chestnut, elm, hickory, mulberry, and oak, the larger vessels or pores (as cross sections of vessels are called) are localized in the part of the growth ring formed in spring, thus forming a region of more or less open and porous tissue. The rest of the ring, produced in summer, is made up of smaller vessels and a much greater proportion of wood fibers. These fibers are the elements which give strength and toughness to wood, while the vessels are a source of weakness.

In diffuse-porous woods the pores are evenly sized so that the water conducting capability is scattered throughout the growth ring instead of being collected in a band or row. Examples of this kind of wood are alder, basswood, birch, buckeye, maple, willow, and the Populus species such as aspen, cottonwood and poplar. Some species, such as walnut and cherry, are on the border between the two classes, forming an intermediate group.

Earlywood and latewood

In softwood

Earlywood and latewood in a softwood; radial view, growth rings closely spaced in Rocky Mountain Douglas-fir

 

In temperate softwoods, there often is a marked difference between latewood and earlywood. The latewood will be denser than that formed early in the season. When examined under a microscope, the cells of dense latewood are seen to be very thick-walled and with very small cell cavities, while those formed first in the season have thin walls and large cell cavities. The strength is in the walls, not the cavities. Hence the greater the proportion of latewood, the greater the density and strength. In choosing a piece of pine where strength or stiffness is the important consideration, the principal thing to observe is the comparative amounts of earlywood and latewood. The width of ring is not nearly so important as the proportion and nature of the latewood in the ring. 

If a heavy piece of pine is compared with a lightweight piece it will be seen at once that the heavier one contains a larger proportion of latewood than the other, and is therefore showing more clearly demarcated growth rings. In white pines there is not much contrast between the different parts of the ring, and as a result the wood is very uniform in texture and is easy to work. In hard pines, on the other hand, the latewood is very dense and is deep-colored, presenting a very decided contrast to the soft, straw-colored earlywood.

It is not only the proportion of latewood, but also its quality, that counts. In specimens that show a very large proportion of latewood it may be noticeably more porous and weigh considerably less than the latewood in pieces that contain less latewood. One can judge comparative density, and therefore to some extent strength, by visual inspection.

No satisfactory explanation can as yet be given for the exact mechanisms determining the formation of earlywood and latewood. Several factors may be involved. In conifers, at least, rate of growth alone does not determine the proportion of the two portions of the ring, for in some cases the wood of slow growth is very hard and heavy, while in others the opposite is true. The quality of the site where the tree grows undoubtedly affects the character of the wood formed, though it is not possible to formulate a rule governing it. In general, however, it may be said that where strength or ease of working is essential, woods of moderate to slow growth should be chosen.

In ring-porous woods

Earlywood and latewood in a ring-porous wood (ash) in a Fraxinus excelsior; tangential view, wide growth rings

 

In ring-porous woods, each season's growth is always well defined, because the large pores formed early in the season abut on the denser tissue of the year before. 

In the case of the ring-porous hardwoods, there seems to exist a pretty definite relation between the rate of growth of timber and its properties. This may be briefly summed up in the general statement that the more rapid the growth or the wider the rings of growth, the heavier, harder, stronger, and stiffer the wood. This, it must be remembered, applies only to ring-porous woods such as oak, ash, hickory, and others of the same group, and is, of course, subject to some exceptions and limitations. 

In ring-porous woods of good growth, it is usually the latewood in which the thick-walled, strength-giving fibers are most abundant. As the breadth of ring diminishes, this latewood is reduced so that very slow growth produces comparatively light, porous wood composed of thin-walled vessels and wood parenchyma. In good oak, these large vessels of the earlywood occupy from 6 to 10 percent of the volume of the log, while in inferior material they may make up 25% or more. The latewood of good oak is dark colored and firm, and consists mostly of thick-walled fibers which form one-half or more of the wood. In inferior oak, this latewood is much reduced both in quantity and quality. Such variation is very largely the result of rate of growth.

Wide-ringed wood is often called "second-growth", because the growth of the young timber in open stands after the old trees have been removed is more rapid than in trees in a closed forest, and in the manufacture of articles where strength is an important consideration such "second-growth" hardwood material is preferred. This is particularly the case in the choice of hickory for handles and spokes. Here not only strength, but toughness and resilience are important.

The results of a series of tests on hickory by the U.S. Forest Service show that:

"The work or shock-resisting ability is greatest in wide-ringed wood that has from 5 to 14 rings per inch (rings 1.8-5 mm thick), is fairly constant from 14 to 38 rings per inch (rings 0.7–1.8 mm thick), and decreases rapidly from 38 to 47 rings per inch (rings 0.5–0.7 mm thick). The strength at maximum load is not so great with the most rapid-growing wood; it is maximum with from 14 to 20 rings per inch (rings 1.3–1.8 mm thick), and again becomes less as the wood becomes more closely ringed. The natural deduction is that wood of first-class mechanical value shows from 5 to 20 rings per inch (rings 1.3–5 mm thick) and that slower growth yields poorer stock. Thus the inspector or buyer of hickory should discriminate against timber that has more than 20 rings per inch (rings less than 1.3 mm thick). Exceptions exist, however, in the case of normal growth upon dry situations, in which the slow-growing material may be strong and tough."

The effect of rate of growth on the qualities of chestnut wood is summarized by the same authority as follows:

"When the rings are wide, the transition from spring wood to summer wood is gradual, while in the narrow rings the spring wood passes into summer wood abruptly. The width of the spring wood changes but little with the width of the annual ring, so that the narrowing or broadening of the annual ring is always at the expense of the summer wood. The narrow vessels of the summer wood make it richer in wood substance than the spring wood composed of wide vessels. Therefore, rapid-growing specimens with wide rings have more wood substance than slow-growing trees with narrow rings. Since the more the wood substance the greater the weight, and the greater the weight the stronger the wood, chestnuts with wide rings must have stronger wood than chestnuts with narrow rings. This agrees with the accepted view that sprouts (which always have wide rings) yield better and stronger wood than seedling chestnuts, which grow more slowly in diameter."

In diffuse-porous woods

In the diffuse-porous woods, the demarcation between rings is not always so clear and in some cases is almost (if not entirely) invisible to the unaided eye. Conversely, when there is a clear demarcation there may not be a noticeable difference in structure within the growth ring. 

In diffuse-porous woods, as has been stated, the vessels or pores are even-sized, so that the water conducting capability is scattered throughout the ring instead of collected in the earlywood. The effect of rate of growth is, therefore, not the same as in the ring-porous woods, approaching more nearly the conditions in the conifers. In general it may be stated that such woods of medium growth afford stronger material than when very rapidly or very slowly grown. In many uses of wood, total strength is not the main consideration. If ease of working is prized, wood should be chosen with regard to its uniformity of texture and straightness of grain, which will in most cases occur when there is little contrast between the latewood of one season's growth and the earlywood of the next.

Monocot wood

Trunks of the coconut palm, a monocot, in Java. From this perspective these look not much different from trunks of a dicot or conifer

 

Structural material that resembles ordinary, "dicot" or conifer timber in its gross handling characteristics is produced by a number of monocot plants, and these also are colloquially called wood. Of these, bamboo, botanically a member of the grass family, has considerable economic importance, larger culms being widely used as a building and construction material and in the manufacture of engineered flooring, panels and veneer. Another major plant group that produces material that often is called wood are the palms. Of much less importance are plants such as Pandanus, Dracaena and Cordyline. With all this material, the structure and composition of the processed raw material is quite different from ordinary wood.

Specific gravity

The single most revealing property of wood as an indicator of wood quality is specific gravity (Timell 1986), as both pulp yield and lumber strength are determined by it. Specific gravity is the ratio of the mass of a substance to the mass of an equal volume of water; density is the ratio of a mass of a quantity of a substance to the volume of that quantity and is expressed in mass per unit substance, e.g., grams per milliliter (g/cm³ or g/ml). The terms are essentially equivalent as long as the metric system is used. Upon drying, wood shrinks and its density increases. Minimum values are associated with green (water-saturated) wood and are referred to as basic specific gravity (Timell 1986).

Wood density

Wood density is determined by multiple growth and physiological factors compounded into “one fairly easily measured wood characteristic” (Elliott 1970).

Age, diameter, height, radial (trunk) growth, geographical location, site and growing conditions, silvicultural treatment, and seed source all to some degree influence wood density. Variation is to be expected. Within an individual tree, the variation in wood density is often as great as or even greater than that between different trees (Timell 1986). Variation of specific gravity within the bole of a tree can occur in either the horizontal or vertical direction.

Hard and soft woods

It is common to classify wood as either softwood or hardwood. The wood from conifers (e.g. pine) is called softwood, and the wood from dicotyledons (usually broad-leaved trees, (e.g. oak) is called hardwood. These names are a bit misleading, as hardwoods are not necessarily hard, and softwoods are not necessarily soft. The well-known balsa (a hardwood) is actually softer than any commercial softwood. Conversely, some softwoods (e.g. yew) are harder than many hardwoods. 

There is a strong relationship between the properties of wood and the properties of the particular tree that yielded it. The density of wood varies with species. The density of a wood correlates with its strength (mechanical properties). For example, mahogany is a medium-dense hardwood that is excellent for fine furniture crafting, whereas balsa is light, making it useful for model building. One of the densest woods is black ironwood.

Chemistry of wood

Chemical structure of lignin, which comprises about 25% of wood dry matter and is responsible for many of its properties.

 

The chemical composition of wood varies from species to species, but is approximately 50% carbon, 42% oxygen, 6% hydrogen, 1% nitrogen, and 1% other elements (mainly calcium, potassium, sodium, magnesium, iron, and manganese) by weight. Wood also contains sulfur, chlorine, silicon, phosphorus, and other elements in small quantity.

Aside from water, wood has three main components. Cellulose, a crystalline polymer derived from glucose, constitutes about 41–43%. Next in abundance is hemicellulose, which is around 20% in deciduous trees but near 30% in conifers. It is mainly five-carbon sugars that are linked in an irregular manner, in contrast to the cellulose. Lignin is the third component at around 27% in coniferous wood vs. 23% in deciduous trees. Lignin confers the hydrophobic properties reflecting the fact that it is based on aromatic rings. These three components are interwoven, and direct covalent linkages exist between the lignin and the hemicellulose. A major focus of the paper industry is the separation of the lignin from the cellulose, from which paper is made.

In chemical terms, the difference between hardwood and softwood is reflected in the composition of the constituent lignin. Hardwood lignin is primarily derived from sinapyl alcohol and coniferyl alcohol. Softwood lignin is mainly derived from coniferyl alcohol.

Extractives

Aside from the lignocellulose, wood consists of a variety of low molecular weight organic compounds, called extractives. The wood extractives are fatty acids, resin acids, waxes and terpenes. For example, rosin is exuded by conifers as protection from insects. The extraction of these organic materials from wood provides tall oil, turpentine, and rosin.

Uses

Fuel

Wood has a long history of being used as fuel, which continues to this day, mostly in rural areas of the world. Hardwood is preferred over softwood because it creates less smoke and burns longer. Adding a woodstove or fireplace to a home is often felt to add ambiance and warmth.

Construction

The Saitta House, Dyker Heights, Brooklyn, New York built in 1899 is made of and decorated in wood.

 

Wood has been an important construction material since humans began building shelters, houses and boats. Nearly all boats were made out of wood until the late 19th century, and wood remains in common use today in boat construction. Elm in particular was used for this purpose as it resisted decay as long as it was kept wet (it also served for water pipe before the advent of more modern plumbing). 

Wood to be used for construction work is commonly known as lumber in North America. Elsewhere, lumber usually refers to felled trees, and the word for sawn planks ready for use is timber. In Medieval Europe oak was the wood of choice for all wood construction, including beams, walls, doors, and floors. Today a wider variety of woods is used: solid wood doors are often made from poplar, small-knotted pine, and Douglas fir. 

The churches of Kizhi, Russia are among a handful of World Heritage Sites built entirely of wood, without metal joints.

 

New domestic housing in many parts of the world today is commonly made from timber-framed construction. Engineered wood products are becoming a bigger part of the construction industry. They may be used in both residential and commercial buildings as structural and aesthetic materials.

In buildings made of other materials, wood will still be found as a supporting material, especially in roof construction, in interior doors and their frames, and as exterior cladding. 

Wood is also commonly used as shuttering material to form the mold into which concrete is poured during reinforced concrete construction.

Wood flooring

Wood can be cut into straight planks and made into a wood flooring.

A solid wood floor is a floor laid with planks or battens created from a single piece of timber, usually a hardwood. Since wood is hydroscopic (it acquires and loses moisture from the ambient conditions around it) this potential instability effectively limits the length and width of the boards. 

Solid hardwood flooring is usually cheaper than engineered timbers and damaged areas can be sanded down and refinished repeatedly, the number of times being limited only by the thickness of wood above the tongue. 

Solid hardwood floors were originally used for structural purposes, being installed perpendicular to the wooden support beams of a building (the joists or bearers) and solid construction timber is still often used for sports floors as well as most traditional wood blocks, mosaics and parquetry.

Engineered wood

Engineered wood products, glued building products "engineered" for application-specific performance requirements, are often used in construction and industrial applications. Glued engineered wood products are manufactured by bonding together wood strands, veneers, lumber or other forms of wood fiber with glue to form a larger, more efficient composite structural unit.

These products include glued laminated timber (glulam), wood structural panels (including plywood, oriented strand board and composite panels), laminated veneer lumber (LVL) and other structural composite lumber (SCL) products, parallel strand lumber, and I-joists. Approximately 100 million cubic meters of wood was consumed for this purpose in 1991. The trends suggest that particle board and fiber board will overtake plywood. 

Wood unsuitable for construction in its native form may be broken down mechanically (into fibers or chips) or chemically (into cellulose) and used as a raw material for other building materials, such as engineered wood, as well as chipboard, hardboard, and medium-density fiberboard (MDF). Such wood derivatives are widely used: wood fibers are an important component of most paper, and cellulose is used as a component of some synthetic materials. Wood derivatives can be used for kinds of flooring, for example laminate flooring.

Furniture and utensils

Wood has always been used extensively for furniture, such as chairs and beds. It is also used for tool handles and cutlery, such as chopsticks, toothpicks, and other utensils, like the wooden spoon and pencil.

Next generation wood products

Further developments include new lignin glue applications, recyclable food packaging, rubber tire replacement applications, anti-bacterial medical agents, and high strength fabrics or composites. As scientists and engineers further learn and develop new techniques to extract various components from wood, or alternatively to modify wood, for example by adding components to wood, new more advanced products will appear on the marketplace. Moisture content electronic monitoring can also enhance next generation wood protection.

In the arts

Prayer Bead with the Adoration of the Magi and the Crucifixion, Gothic boxwood miniature

 

Wood has long been used as an artistic medium. It has been used to make sculptures and carvings for millennia. Examples include the totem poles carved by North American indigenous people from conifer trunks, often Western Red Cedar (Thuja plicata). 

Other uses of wood in the arts include:

• Woodcut printmaking and engraving
• Wood can be a surface to paint on, such as in panel painting
• Many musical instruments are made mostly or entirely of wood

Sports and recreational equipment

Many types of sports equipment are made of wood, or were constructed of wood in the past. For example, cricket bats are typically made of white willow. The baseball bats which are legal for use in Major League Baseball are frequently made of ash wood or hickory, and in recent years have been constructed from maple even though that wood is somewhat more fragile. NBA courts have been traditionally made out of parquetry.

Many other types of sports and recreation equipment, such as skis, ice hockey sticks, lacrosse sticks and archery bows, were commonly made of wood in the past, but have since been replaced with more modern materials such as aluminium, titanium or composite materials such as fiberglass and carbon fiber. One noteworthy example of this trend is the family of golf clubs commonly known as the woods, the heads of which were traditionally made of persimmon wood in the early days of the game of golf, but are now generally made of metal or (especially in the case of drivers) carbon-fiber composites.

Bacterial degradation

Little is known about the bacteria that degrade cellulose. Symbiotic bacteria in Xylophaga may play a role in the degradation of sunken wood; while bacteria such as Alphaproteobacteria, Flavobacteria, Actinobacteria, Clostridia, and Bacteroidetes have been detected in wood submerged over a year.