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Saturday, August 30, 2014
Superabsorption of light via quantum engineering
Superabsorption of light via quantum engineering
Original link: http://www.nature.com/ncomms/2014/140822/ncomms5705/full/ncomms5705.html
Almost 60 years ago Dicke introduced the term superradiance to describe a signature quantum effect: N atoms can collectively emit light at a rate proportional to N2.
Structures that superradiate must also have enhanced absorption, but
the former always dominates in natural systems. Here we show that this
restriction can be overcome by combining several well-established
quantum control techniques. Our analytical and numerical calculations
show that superabsorption can then be achieved and sustained in certain
simple nanostructures, by trapping the system in a highly excited state
through transition rate engineering. This opens the prospect of a new
class of quantum nanotechnology with potential applications including
photon detection and light-based power transmission. An array of quantum
dots or a molecular ring structure could provide a suitable platform
for an experimental demonstration.
Superradiance can occur when N individual atoms interact with the surrounding electromagnetic field1.
Here we use the term ‘atom’ broadly to refer to entities with a
discrete dipole-allowed transition, including semiconductor quantum dots2, crystal defects and molecules3.
Following an initial excitation of all atoms, dipole-allowed decay down
a series of symmetrical ‘Dicke ladder’ states leads to an enhanced
light–matter coupling that, when the system reaches the state half way
down the ladder, depends on the square of the atomic transition dipole1, 4, 5. Thus when N dipoles add coherently, light can be emitted at an enhanced rate proportional to N2. Even for moderate N
this represents a significant increase over the prediction of classical
physics, and the effect has found applications ranging from probing
exciton delocalization in biological systems6, to developing a new class of laser7 and may even lead to observable effects in astrophysics8.
Time-reversal
symmetry of quantum mechanics implies that systems with enhanced
emission rates will also have enhanced absorption rates. Naturally
emission dominates if an excited state of the collective emits into a
vacuum, since there are no photons to absorb. Even in an intense light
field where absorption and emission are closely balanced, a given
transition remains more likely to emit than to absorb. Thus it might
seem that the inverse of superradiance is intrinsically ephemeral.
However,
here we show that certain interactions between the atoms allow us to
control a quantum system such that a sustained superabsorbing state can
exist. For atoms in close proximity and with a suitable geometrical
arrangement, ever present atomic dipolar interactions are sufficient for
our purposes. An appropriate realization involves a ring structure that
is strikingly reminiscent of the photosynthetic light harvesting
complex LH1 (refs 9, 10; see Fig. 1).
Although the potential for enhanced absorption inherently exists in all
superradiating systems, natural systems are not designed to ulitize it.
Rather, these will always perform an (often strongly) biased random
walk down the ladder of accessible states, being attracted by the bottom
most rung. Strongly enhanced absorption near the middle of the Dicke
ladder is thus an improbable process and can only last for a vanishingly
short time.
Figure 1: One potential realization of superabsorption.
Photons absorbed by the ring give rise
to delocalized excitons; ideally the ring maintains a specific exciton
population to achieve enhanced absorption. Combined with a suitable
charge sensor (for example, a quantum point contact) this enables photon
sensing. We also model an application for photon harvesting, where
newly created excitons are transferred from the ring to a central core
absorber, followed by an irreversible process (for example, one-way
transfer down a strongly coupled chain) to a centre converting the
exciton into stored energy.
By contrast, in this Communication, we will show how to harness
environmental quantum control techniques to break the dominance of
emission over absorption and extend the time during which a collective
system maintains the capability for quantum-enhanced absorption. By
interfacing the well-established physical phenomena of superradiance,
light filtering, photonic band gaps and quantum feedback control, we
show that sustained superlinear scaling of the light absorption rate
with the number of atoms is possible. Since this represents the
reciprocal process to superradiance, we shall refer to it as
‘superabsorption’. Note that this effect is quite distinct from other
recent studies investigating collective light–matter interactions in the
context of ‘cloaking’11 and time-reversed lasing12.
In the following we present the Dicke model of superradiance before
describing the requirements for unlocking engineered superabsorption.
Our discussion explores its potential for practical technologies through
the examples of photon sensing and light-based energy transmission.
The Hamiltonian of an ensemble of N identical atoms is (ħ=1):
where ωA is the bare atomic transition frequency;
,
, and
are the usual Pauli operators defined with respect to the ith atom’s ground, |g›i, and optically excited state, |e›i. When the wavelength λ of light is much larger than all interatomic distances rij, (λ>>rij),
the atoms become indistinguishable and light interacts with the system
collectively. The dynamics are then best described by collective
operators:
which generate transitions between the eigenstates of the
Hamiltonian (1) and obey SU(2) commutation relations. We can succinctly
express the light–matter interaction Hamiltonian as
where Ê is the light field operator and d is the
atomic dipole matrix element. The Hamiltonian (3) causes the system to
move along a ladder of states called the ‘Dicke’ or ‘bright’ states
which are characterized by the eigenvalues J and M of Ĵ2 and Ĵz, respectively. In the absence of interactions between the atoms, Ĵ2 commutes with ĤS+ĤL and thus its eigenvalue
is a conserved quantity. The Dicke states form a ladder from
to
shown in Fig. 2a; the N+1 rungs correspond to the fully symmetric superpositions of N/2+M excited atoms for each value of M. The collective excitation operators
Figure 2: Engineering the Dicke ladder.
(a) The ladder of Dicke states of an N atom system, with emission (red) and absorption (blue) processes. In the presence of interactions Ω≠0, the frequency shift of each transition is given by ωA+δM. (b) The effective two-level system (E2LS) picture with the optional trapping process for energy extraction in the dashed box. (c)
A scheme for using the environment to confine the ladder of states into
an effective two-level system either by tailoring the spectral density κ(ω) or the mode occupation n(ω).
explore this ladder of states, and the transition rates between adjacent Dicke ladder states are then readily calculated:
where γ=8π2d2/(3ε0ħλ3) is the free atom decay rate.
If the system is initialized in the fully excited state
with no environmental photons, then the system cascades down the ladder, as shown by the red arrows in Fig. 2a. Upon reaching the midway point (M=0) its emission rate exceeds the rate γN expected of N uncorrelated atoms for N>2. For a larger number of atoms the peak transition rate of equation (5) follows a quadratic dependence on N and is well-approximated by
This is the essence of superradiance: constructive interference
between the different possible decay paths greatly enhances the emission
rate, producing a high intensity pulse. The enhancement is the result
of simple combinatorics: near the middle of the ladder, |J, 0›, there are a large number of possible configurations of excited atoms that contribute to each respective Dicke state.
Superradiance is not an intrinsically transient effect: steady-state operation can occur through repumping13, or in cavities14, 15, and recently a superradiant laser with potential for extraordinary stability and narrow linewidth has been demonstrated7.
Superabsorption
The
crucial ingredient for achieving superabsorption is to engineer the
transition rates in a way that primarily confines the dynamics to an
effective two-level system (E2LS) around the M=0 transition (see Fig. 2b), which exhibits the required quadratic absorption rate as depicted in Fig. 3c.
Figure 3: Enhanced absorption probability.
(a) the probability of absorbing a photon within the lifetime
(N) of the superabsorbing E2LS comprising N atoms, compared with that of N individual atoms over the same duration. The relative advantage is linear in N as expected, and the coloured shading indicates the quantum advantage. (b) lifetime of the E2LS for growing N relative to the four atoms case
. Note that the decrease in lifetime corresponds to an increasing time
resolution of a superabsorbing photon detector: after initialization the
system is receptive to a photon of the requisite frequency only during
this time window. (c) absorption rate at the midpoint of the Dicke ladder (blue) and for N individual absorbers (red). The clearly visible N2 scaling that is typical of superradiant pulses also applies to the absorption rate.
To ensure that most transitions take place within the E2LS we must
either suppress the total loss rate from the E2LS or enhance the
probability of transitions within it. This becomes possible if the
frequency of the E2LS transition is distinct from that of other
transitions, and in particular the one immediately below the targeted
transition within the E2LS. This will never be the case for a
non-interacting set of atoms, which must have a degenerate set of ladder
transition energies, but it can occur once suitable interactions are
included. Dicke physics requires that the atoms remain identical, but
interactions are still permissible in certain symmetric geometries such
as rings4, 16, and these structures will continue to exhibit superradiance, and are therefore also capable of superabsorption.
To show this, we consider the candidate superabsorber depicted in Fig. 1.
We assume that the interactions act between adjacent atoms only and are
due to Förster-type coupling. This leads to a Dicke ladder of
non-degenerate transitions whose dynamics are found from a collective
quantum optical master equation:
κ(ω)=∑k|gk|2δ(ω−ωk)≡χ(ω)|g(ω)|2 is the spectral density at frequency ω; n(ωβ) is the occupation number of the ωβ mode, and
is the Lindbladian dissipator
.
moves the system up a Dicke ladder transition with frequency ωβ.
Equation
(7) also features unitary dynamics due to the field interaction that
comprises two components: the Lamb shift, accounted for by renormalising
ωA in the system Hamiltonian ĤS, and the field induced dipole–dipole interaction
which describes energy conserving ‘hopping’ of excitons between
sites mediated by virtual photon exchange. Such interactions can also be
added to the system implicitly, yielding analogous results (see Supplementary Method 4). The hopping interaction strength Ωi,j is given by ref. 4
with
being a unit vector parallel to the direction of the dipoles. For a circular geometry with dipoles perpendicular to rij and retaining only nearest neighbour interactions (a good approximation for larger rings since
), Ω:=Ω(i, i+1) is a constant. However, note that the restriction to εnearest neighbour coupling is not a requirement; please see the Supplementary Method 3 for a full discussion. Owing to the high degree of symmetry of the ring geometry, to first order ĤI does not mix the |J,M› eigenstates, only shifting their energies4 according to
The shift of the transition frequencies is given by the difference of two adjacent levels EM−EM−1:
These altered frequencies break the degeneracy in the Dicke
ladder where each transition now has a unique frequency. For example the
transition frequency from the ground state to the first Dicke state is ω−N/2+1→−N/2=ωA−2Ω.
Crucially, the Dicke states still represent a very good approximation
of the eigenbasis of the system, yet each transition in the ladder now
samples both κ(ω) and n(ω) at its own unique
frequency. One might expect that the speed of the collective
transitions could cause sufficient lifetime broadening to mask the
shifts. However in Supplementary Method 2, we show that this is not the case.
Transition rate engineering
Our aim is to enhance transition rates at the frequency of the E2LS, which we shall call the ‘good' frequency (ω0→−1=ωgood) and suppress those for transitions directly out of the E2LS at the ‘bad’ frequency (ω−1→−2=ωbad). The required type of control of the environment is known as reservoir engineering17; in principle we have a choice between tailoring κ(ω), n(ω)
or both. Tailoring the spectral density has the advantage that it can,
in theory, completely eliminate the rate of loss from our E2LS when
there is no mode of the right frequency present to allow decay. This
requires placing the device inside a suitably designed cavity or a
photonic bandgap (PBG) crystal with a stop band at ωbad (see Fig. 2c),
where the required dimensionality of the PBG depends on the orientation
of the optical dipoles. Suppression of emission rates by several orders
of magnitude is then achievable with state-of-the-art systems18, 19, 20, 21. Photonic crystal cavities can offer both enhancement of a resonant transition (ωgood) and suppression of an off-resonant one (ωbad; ref. 22), making them ideal for the type of control required.
Control of n(ω) is technically easier to achieve, for example, by using filtered thermal or pseudothermal23, 24 light. However, this approach has the limitation that even in the optimal control regime, where n(ω)=0 everywhere except in a narrow region around ωgood, spontaneous emission will still cause loss from the E2LS.
Since
both environmental control approaches rely on frequency selectivity, a
sufficiently large detuning between adjacent Dicke transitions will be
critical for achieving effective containment within the E2LS.
Fortunately, this detuning is already within the frequency selectivity
of current experimental controls for moderately sized rings, of say N~10: see the Supplementary Tables 1 and 2.
In
practice the environmental control will never be quite perfect and our
system will, over long times, inevitably evolve away from the E2LS. For
example, one may only have control over n(ω) but not κ(ω), or an imperfect PBG with κ(ωbad)>0, and both cases lead to an exponential decay of E2LS population with the lifetime
. Dephasing processes will also lead to leakage out of the fully
symmetric subspace and thus shorten the effective lifetime of the E2LS.
However, these imperfections need not dominate the behaviour and destroy
the effect. We shall discuss the issue of sustained operation in the
reinitialization section.
Let us now consider the properties of the system immediately following initialization: Figure 3 shows the increased photon absorption rate of the superabsorbing E2LS compared with N uncorrelated atoms, Γ−1→0/N.
Clearly, the probability of absorbing a photon within a given time
window (up to the E2LS lifetime) is much higher in the superabsorbing
configuration, providing an opportunity for photon dectection with
improved sensitivity. The inset of Fig. 3 shows the lifetime of the E2LS,
, as a function of N, here assumed to be limited by an imperfect PBG with κ(ωbad)/κ(ωgood)=1/100. For photon sensing, the reduction of the operational window with increasing N
may even be a desirable attribute (offering time resolved detection).
Generally, the system we have so far described can function as sensor as
long as the temporary presence of an additional exciton can be
registered, for example, through continuously monitoring the system’s
charge state with a quantum point contact25, 26, 27, 28.
Trapping
We
have detailed how to create a photon sensor using superabsorption. We
can also employ the superabsorption phenomenon in the context of energy
harvesting if we can meet a further requirement: a non-radiative channel
to extract excitons from the upper of these two levels, turning them
into useful work as depicted in the dashed box of Fig. 2b.
Specifically, we require an irreversible trapping process that extracts
only the excitons that are absorbed by the E2LS, and does not extract
excitons from levels below the E2LS. Moreover, the trapping process
competes with the re-emission of the photons at a rate proportional to n(ωgood)+1,
so that ideally it is much faster than that. Note that in this limit
saturation is not an issue since absorbed photons are quickly
transferred and converted, leaving the system free to absorb the next
photon.
The excitons are delocalized across the ring and need to
be extracted collectively to preserve the symmetry of the Dicke states.
In designing this process we take inspiration from natural light
harvesting systems: a ‘trap’ atom is located at the centre of the ring
and symmetrically coupled via a resonant hopping interaction to all the
other atoms (see Fig. 1). The corresponding trapping Hamiltonian is
where the superscript T denotes the trap site, g is the strength of the coupling between the ring and the trap, and the trap’s transition frequency ωtrap ideally matches ωgood.
In this case the interaction is mediated by the electromagnetic field
as described in the previous section, but it could have other physical
origins depending on the system of interest. Once an exciton has moved
to the trap site we assume that it is then removed into the wider
environment by a process which irreversibly absorbs its energy. We note
that more exotic and potentially far more efficient trapping
implementations can be envisioned, such as, for example, a reservoir of
excitons with an effective ‘Fermi level’ capable of accepting excitons
only above the energy level E−1. However, at present
our aim is to focus on the simplest system capable of exhibiting
enhanced photon energy harvesting by superabsorption.
The above trapping process is adequately described phenomenologically (see Supplementary Method 6, Supplementary Figs 1 & 2) as collective exciton extraction from the midpoint (M=0) by adding the dissipator
to the righthand side of equation (7) with
, and where Γtrap is the rate of the trapping process. The rate of exciton extraction Itrap is then simply given by the population of the trapping level multiplied by the trapping rate:
Consider an ideal E2LS realized by a PBG completely blocking ωbad, that is, a vanishing Γloss:=κ(ωbad)(n(ωbad)+1)Γ−1→−2. Assuming a faster trapping than emission rate, Γtrap>>Γemit:=κ(ωgood)(n(ωgood)+1)Γ0→−1, our figure of merit Itrap matches the absorption rate Γabsorb:=κ(ωgood)n(ωgood)Γ−1→0 for all t:
where μ=γκ(ωgood)n(ωgood).
It is clear from this equation that under these conditions we achieve a
superlinear scaling of the exciton current flowing out of the
superabsorber. Trapping processes like the one described here have been
demonstrated experimentally and meet the requirement Γtrap>>Γemit, see Supplementary Method 6.
The inevitable loss out of the E2LS entails an exponential decay of Itrap(t) with the lifetime
, as shown in Fig. 4.
The initial net superabsorption rate far exceeds that possible from
uncorrelated atoms, however it is only a transient effect and the system
needs to be reinitialized periodically to maintain its advantage. This
aspect will be discussed in the next section.
Figure 4: A superabsorption cycle.
Superabsorption of the effective two-level system indicated in Fig. 2.
The green shading indicates the superabsorption region, the red when
the extraction rate is below what could be extracted from uncorrelated
atoms; both are for a system of 20 atoms and mode occupancy n(ωgood)=10. The maximum extraction possible from independent atoms (Γind=n(ωgood)Nγ) is used for comparison.
We have detailed the case where a PBG is used to increase the
lifetime of the E2LS. If instead intense filtered thermal light is used
to ensure n(ωgood)>>1, then many
absorption-trapping cycles can take place before a spontaneous emission
event happens. This set-up would enable quantum-enhanced light-based
power transmission, where a large number of photons need to be harvested
quickly in a confined area.
Reinitialization
Reinitialization
could be achieved by exploiting a chirped pulse of laser light to
re-excite the system, or through a temporary reversal of the trapping
process. In practice there will be an energy cost associated with
reinitialization but, as we show below, in all but the most severe cases
this cost is more than offset by the faster photon to exciton
conversion rate during the transient superabsorption period.
Furthermore, the frequency with which one has to reinitialize does not
have a fundamental lower bound, it is limited only by the quality of the
control one can apply.
Perhaps the most elegant way of
implementing the reinitialization step (short of self-initialization,
see below) would make use of quantum feedback control29:
The superabsorption enhancement is derived from coherence between
states that all possess the same number of excitons. Therefore, the
number of excitons could be continually monitored (for example, by a
quantum point contact or by monitoring fluorescence of a probe field
tuned to a level or two below the desired manifold) without destroying
the desired effect. A suitably designed feedback system could then feed
in an excitation only when a loss event occurs, providing optimal
efficiency
where σ=γκ(ωbad)(1+n(ωbad)). Provided μ>σ superabsorption will occur, and for σ=0, we recover the theoretical maximum of the idealized case in equation (14).
A
far simpler reinitialization scheme would only require periodic
reinitialization following a fixed time interval, and does away with the
need for feedback control. To account for the relative cost of such
reinitialization, we need to quantify the total number of excitons
absorbed in a given time. Let us fix the time at which reinitialization
is performed to the natural lifetime of the E2LS,
. Integrating the trapping rate Itrap(t) over
one lifetime and subtracting the reinitialization cost gives a fair
measure of the number of excitons the system has absorbed within the
given time. We can then consider the extreme limits of the
reinitialization cost, from simply replacing a single lost exciton, to
having to replace all of the N/2 excitons that make up the
superabsorbing state. A larger system requires more frequent
reinitializations, since its loss rate is also enhanced by the system
size. However, the bias in favour of absorption created by the
environmental control is sufficient to ensure this does not negate the
superabsorption process. Figure 5
shows how the number of excitons absorbed in a given time scales with
the number of atoms, and for all cost models we find a superlinear
scaling.
Figure 5: Superlinear exciton absorption.
The total number of excitons absorbed within the common reference time
as a function of the number of atoms N. The coloured curves
represent the reinitialization cost models described in the main text,
and the red line shows the maximum extracted from independent atoms for
comparison. The scaling is superlinear in all coupled atom cases,
approximately following the ideal N2 law (green), except for large N
in the pessimistic cost model of full reinitialization (blue). If
quantum feedback control enables the replacement of a single exciton as
soon as a loss event has happened, then the nearly quadratic scaling
persists up to an arbitrary number of atoms (olive).
We have shown that the absorptive analogue of quantum
superradiance can be engineered in structures with suitably symmetric
interactions. We have provided an intuitive explanation of this
many-body light–matter effect by introducing an E2LS. Despite its
simplicity this analytic model can provide highly accurate predictions,
as we have validated through the extensive exact numerical calculations
that are summarized in the Methods section, see Supplementary Method 5 and Supplementary Fig. 3.
As we have already discussed, absorbing light beyond the limits of
classical physics raises prospects for at least two new types of
technology, and superabsorption could be realized in a broad range of
candidate systems.
The foremost application of the phenomenon may
be in the context of optical or microwave sensors, either in future
cameras or for scientific instruments. In addition to the obvious merits
of being sensitive to low light levels, the frequency specificity of
the superabsorber may be a desirable attribute. The small size of the
ring structure and collective ‘antenna array’ could lead to high spatial
and angular resolution, and the fact that the superabsorber is
(re)initialized into its fully receptive state by an excitation pulse
allows detection events to be confined into a narrowly defined time
window. Note that for sensing applications the cost of
(re)initialization is likely unimportant, and a trapping mechanism is
not required if the number of excitons in the system can be monitored
differently, for example, with a quantum point contact.
Light harvesting technologies represent another potential application, and indeed our Fig. 5
indicates that one can obtain a net increase in the number of exctions
absorbed compared with conventional systems even allowing for the energy
cost of sustaining the superabsorbing state. The technique would be
particularly suited to wireless power transfer using narrowband light,
for example, for remote sensors or biologically implanted devices, where
wired electrical power is impractical. For solar light harvesting a
given superabsorber can only achieve optimal performance for a specific
frequency range; however, one could engineer a range of different
systems to jointly cover the solar spectrum.
There are multiple
candidate systems for engineering the above applications. Molecular
rings have the advantage of featuring a natural symmetry and
intrinsically low levels of disorder. Taking Ω=350 cm−1 as appropriate for a B850 ring (ref. 30)
with eight atoms produces transition wavelength shifts exceeding 6 nm,
and a wavelength selectivity on the scale of nanometres is readily
available with current laser and cavity linewidths. Of course, the
dipole alignment of the B850 ring is not optimized for this purpose.
However, complex ring structures can be designed and synthesized
artificially (for example, porphyrin rings31) and this route should enable far superior properties. Self-assembly into much larger molecular J or H aggregates with established superradiant properties32, 33
may provide further opportunities. Alternatively, superradiance,
long-range interactions and optical control have been demonstrated in
quantum dots2, 34, and there has been recent progress in synthesizing ring-like clusters with high spectral and spatial order35.
Further, suppression of the local density of optical states by two
orders of magnitude at specific frequencies has been demonstrated in an
appropriate semiconductor photonic crystal environment18. For typical parameters of those systems that would be consistent with the requirements for superabsorption see the Supplementary Discussion 1.
To
demonstrate the effect of superabsorption (that is, sustained
confinement into an E2LS with enhanced absorption and emission rates) as
an instance of an engineered physical phenomenon, several additional
possibilities present themselves. For example, circuit QED experiments
possess long coherence times and have already demonstrated sub and
superradiant effects36, 37, as well as tuneable cross Lamb shifts38 and recent three-dimensional structures39 provide further flexibility. Bose–Einstein Condensates offer similar properties but with much larger numbers of atoms40, 41.
Dissipative Dicke model studies with nonlinear atom-photon interaction
can enable a steady-state at the midpoint of the Dicke ladder (M=0; refs 42, 43), which may provide a route to self-initialising superabsorbing systems.
The master equation (7) is an N atom generalization of the standard quantum optical master equation; we give the full derivation in the Supplementary Method 1. In particular, it assumes that all N
atoms are spatially indistinguishable due to occupying a volume with
linear dimensions much smaller than the relevant wavelength of light. In
addition, interactions between atoms must respect certain symmetry
requirements to only shift the Dicke states to first order (for example,
as is exemplified by equation (10)). However, as we also discuss in Supplementary Method 5—and
verify with numerical calculations—superlinear scaling of the
absorption rate with the number of atoms remains possible beyond a first
order perturbative treatment of suitably symmetrical interactions.
Numerical calculations
The
E2LS model reduces the complexity of the problem and makes it
analytically tractable. To verify this approach we have compared it with
two different independent numerical models. Supplementary Fig. 3 shows excellent agreement between the E2LS model and the Monte Carlo simulations of the master equation (7). In Supplementary Figs 1 and 2,
we extend the model further by incorporating an explicit trap site and
allow coherent transfer from the ring to the trap, as described in the
Trapping Section, showing that superabsorption is still realized in that
case and that the E2LS model still provides a good description of the
behaviour. This model uses a generalized master equation solved
numerically.
Imperfections
Any real physical system used
to demonstrate superabsorption or indeed superradiance, will have
imperfections such as slightly varying frequencies for each atom, or a
deviation away from perfect ring symmetry. In essence all such
imperfections in superradiance are alike; they diminish the collective
effect because they lead to the emission of distinguishable photons. It
might therefore be a concern that these collective effects could only be
realized in the ideal case. However, superradiant effects of molecular
aggregates with a spatial extent smaller than the wavelength of light
are known to possess a certain degree of robustness against inhomogenous
broadening44, dephasing processes45 and exciton phonon coupling46.
This is because the increased transition rates produced by
superradiance serve to counterbalance the effect of disorder: the faster
rate broadens the natural linewidth of the transitions, effectively
preventing the introduction of distinguishability from the disorder.
Intuitively, we expect a superabsorption advantage to be achievable
whenever an imperfect system is still capable of displaying superradiant
behaviour (of course with the additional requirement that the energy
shifts of adjacent decay process are resolvable). In Supplementary Method 5 and Supplementary Figs 4 and 5,
we model realistic imperfections by considering static energy disorder
and show that superabsorption can still be realized in the presence of
disorder.