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Wednesday, May 14, 2025

Sun in fiction

From Wikipedia, the free encyclopedia
https://en.wikipedia.org/wiki/Sun_in_fiction
Refer to caption
"Surveying a Dying Sun", cover of If, November 1953

The Sun has appeared as a setting in fiction at least since classical antiquity, but for a long time it received relatively sporadic attention. Many of the early depictions viewed it as an essentially Earth-like and thus potentially habitable body—a once-common belief about celestial objects in general known as the plurality of worlds—and depicted various kinds of solar inhabitants. As more became known about the Sun through advances in astronomy, in particular its temperature, solar inhabitants fell out of favour save for the occasional more exotic alien lifeforms. Instead, many stories focused on the eventual death of the Sun and the havoc it would wreak upon life on Earth. Before it was understood that the Sun is powered by nuclear fusion, the prevailing assumption among writers was that combustion was the source of its heat and light, and it was expected to run out of fuel relatively soon. Even after the true source of the Sun's energy was determined in the 1920s, the dimming or extinction of the Sun remained a recurring theme in disaster stories, with occasional attempts at averting disaster by reigniting the Sun. Another common way for the Sun to cause destruction is by exploding ("going nova"), and other mechanisms such as solar flares also appear on occasion.

Besides being a source of destruction, the Sun has been used in fiction as a source of power—both in the form of solar power and superpowers. The solar wind is also used for propulsion by spacecraft equipped with solar sails. Solar eclipses have appeared in a large number of stories, in the earliest ones often used as a ruse by characters who know that they can be predicted mathematically against those who do not by pretending to cause them, perhaps inspired by the story of Christopher Columbus doing the same with a lunar eclipse in 1504. When audiences grew weary of this trope by the 1930s or 1940s, eclipses became much more rare in fiction writing, though they saw a comeback towards the end of the century as harbingers of social upheaval. Sunspots, and their 11-year cycle of frequency in occurrence, appear in a small number of works. The Sun poses a danger to spacecraft that approach it closely, a situation that occurs by necessity or design in several stories. It is sometimes depicted as being sentient, though this is rare compared to other stars getting the same treatment. Overall, the Sun remains relatively uncommon as a point of focus in science fiction, particularly in comparison to depictions of Mars and Venus; says science fiction bibliographer Richard Bleiler, "Perhaps because it is generally taken for granted, the fictive potential of the Sun has barely been tapped".

Early depictions: inhabited

Although the Moon was visited early and often in science fiction, the fictive potential of the Sun was not explored until relatively late.

The Sun received comparatively little specific attention in early science fiction; prior to the late 1800s, when Mars became the most popular celestial object in fiction, the Sun was a distant second to the Moon. A large proportion of the works that nevertheless did focus on the Sun portrayed it as having inhabitants. In Lucian of Samosata's work A True Story from the second century CE, described by science fiction scholar Gary Westfahl as the first depiction of space travel in fiction, the inhabitants of the Sun are at war with those of the Moon. Later stories with an inhabited Sun include Athanasius Kircher's 1656 work Itinerarium exstaticum and Cyrano de Bergerac's posthumously published 1662 novel Comical History of the States and Empires of the Sun [fr]. In the 1700s, solar inhabitants were depicted by French authors Chevalier de Béthune [Wikidata], whose 1750 novel Relation du Monde de Mercure describes them ruling over the inhabitants of Mercury, and Marie-Anne de Roumier-Robert, whose 1765 novel Voyage de Milord Céton dans les sept planètes portrays a society on the Sun characterized by equality of the sexes.

The concept of the plurality of worlds—the notion that other heavenly bodies should be essentially Earth-like and therefore habitable—endured in fiction with regard to the Sun well into the 1800s. These works include George Fowler's 1813 novel A Flight to the Moon; or, The Vision of Randalthus, the anonymously published 1837 novel Journeys into the Moon, Several Planets and the Sun, and Joel R. Peabody's 1838 novel A World of Wonders. Even in the early 1900s, when the temperature of the surface of the Sun had been determined by spectroscopic measurement, the portrayal of the Sun as inhabited persisted in some works of juvenile fiction such as John Mastin [Wikidata]'s 1909 novel Through the Sun in an Airship and Donald Horner [Wikidata]'s 1910 novel By Aeroplane to the Sun.

In the 1900s, as it became evident that no conventional organisms could possibly survive the conditions on the Sun, more exotic solar lifeforms started appearing in fiction. Some of these live inside the Sun itself rather than on its surface, as in short stories like Jack Williamson's 1935 "Islands of the Sun", Raymond Z. Gallun's 1935 "Nova Solis", and Henry J. Kostkos's 1936 "We of the Sun". Others take up residence elsewhere in the Solar System: in Leigh Brackett's 1942 short story "Child of the Sun", an intelligent alien from the Sun lives on the fictional planet Vulcan inside the orbit of Mercury, and the titular creatures of Olaf Stapledon's 1947 novel The Flames are lizard-like solar beings residing inside igneous rocks on Earth. Arthur C. Clarke's 1958 short story "Out of the Sun" features life "formed of tangles of magnetic flux on the surface of our Sun", and Edmond Hamilton's 1962 short story "Sunfire!" depicts an energy-based lifeform living in the Sun's corona.

Disaster

The Sun has been a source of destruction or the threat thereof in many stories, most commonly either by fading or exploding. In the rare science fiction films where the Sun is a central point of focus, it seldom plays any other role.

Dimming and extinction

A photograph of fire
When the Sun was assumed to be powered by combustion, it was expected to burn out in the relatively near future.

The dimming or extinction of the Sun has been a recurring theme. The earliest such stories were inspired by the assumption that the heat and light of the Sun were products of combustion, and that the fuel sustaining it would eventually run out. Physicist Lord Kelvin estimated in 1862 that the Sun would fade within a few million years, a timeframe that was later incorporated in stories by Camille Flammarion and H. G. Wells, among others. In Flammarion's 1894 novel Omega: The Last Days of the World, humanity survives an encounter with a comet but succumbs to the dimming of the Sun thousands of years later, while the time traveller in Wells's 1895 novel The Time Machine discovers a cooled and reddened Sun over a barren Earth in the far future. Similarly, stories about the end of the world involving the death of the Sun were written in the early 1900s by among others George C. Wallis, whose 1901 short story "The Last Days of Earth" depicts the last survivors leaving a frozen Earth for a potentially habitable planet in another planetary system, and William Hope Hodgson, whose 1908 novel The House on the Borderland describes one character's vision of the destruction of both the Earth and Sun.

By the 1920s, the combustion hypothesis had fallen out of favour. The new explanation was that the Sun was fuelled by nuclear fusion, an understanding that was pioneered by the work of astrophysicist Arthur Eddington. As a result, science fiction authors started incorporating much longer solar lifespans in their stories, with J. B. S. Haldane's 1927 work "The Last Judgment" and Olaf Stapledon's 1930 novel Last and First Men both outlining the future evolution of humanity throughout millions of years of variation in solar luminosity. Stories depicting the Sun waning nevertheless kept appearing, such as Clark Ashton Smith's stories about the fictional future continent Zothique starting with the 1932 short story "The Empire of the Necromancers", and Jack Vance's Dying Earth series starting with the 1950 anthology The Dying Earth which also gave its name to the dying Earth subgenre of science fiction. Nat Schachner's 1934 short story "When the Sun Dies" describes the entire Earth freezing over in the 1980s as a result of a reduction in solar activity, and in Arthur C. Clarke's 1949 short story "History Lesson", future Venusians find humanity extinct due to the environmental changes brought about by the Sun fading. Clarke also touched upon the subject in the 1938 poem "The Twilight of the Sun" and the 1979 novel The Fountains of Paradise. In a variation on the theme, Fritz Leiber's 1951 short story "A Pail of Air" depicts Earth having been pulled away from the gravitational influence of the Sun and thus turned into a rogue planet, with a climate so cold that air has frozen and needs to be collected and thawed to turn it gaseous and breathable. Edmond Hamilton's 1934 short story "Thundering Worlds" sees all the planets leaving the Solar System to find a new star as the Sun dies, while his 1963 comic book story "Superman Under the Red Sun" depicts Superman travelling into the far future and losing his superpowers as a result of the aging red Sun. Eric C. Williams's 1965 short story "Sunout" depicts scientists reacting to the realization that the Sun is about to go out and they are powerless to do anything about it. In the 2019 film The Wandering Earth, the death of the Sun prompts humanity to relocate the entire Earth to a new planetary system.

A handful of stories describe efforts to reignite the fading Sun. In Clark Ashton Smith's 1954 short story "Phoenix" (written c. 1935), this is accomplished by detonating several nuclear weapons on the Sun's surface. In Gene Wolfe's 1980–1983 four-volume novel The Book of the New Sun and its sequels, a white hole is used to reinvigorate the dying Sun. The concept of using an explosive device for this purpose is also explored in the 2007 film Sunshine.

Exploding

Artist's impression of a supernova
Artist's impression of an exploding star. Several stories depict the Sun undergoing such an event.

Several stories depict the Sun exploding, or "going nova". It was recognized early on that the immense destructive power of such an event would leave little to no hope of survival for humanity, and so while Simon Newcomb's 1903 short story "The End of the World" depicts a few survivors in the immediate aftermath, Hugh Kingsmill's 1924 short story also entitled "The End of the World" instead focuses on the anticipation of the destruction of the Earth. According to science fiction scholar Brian Stableford, writing in the 2006 work Science Fact and Science Fiction: An Encyclopedia, it was thus not until the concept of space travel became widespread in science fiction—hence making evacuation of the Earth a conceivable prospect—that such stories became popular. In John W. Campbell's 1930 short story "The Voice of the Void" humanity leaves Earth ahead of this disaster, while in Joseph W. Skidmore]'s 1931 short story "Dramatis Personae" the Sun explodes without warning, leaving a few people already in spaceships as the only survivors. In Arthur C. Clarke's 1946 short story "Rescue Party", aliens come to Earth to save humanity from the violent demise of the Sun only to find that evacuation has already been undertaken, whereas in his 1954 short story "No Morning After", the aliens' warning goes unheeded. J. T. McIntosh's 1954 novel One in Three Hundred deals with the allocation of the limited capacity aboard the evacuating spaceships. The Sun exploding occasionally appears as a background event to explain why humanity has abandoned Earth in favour of colonizing the cosmos, one example being Theodore Sturgeon's 1956 short story "The Skills of Xanadu". In Norman Spinrad's 1966 novel The Solarians, the Sun is intentionally made to explode in an act of interstellar warfare, while in Larry Niven's 1971 short story "The Fourth Profession" aliens plan to induce such an event to use as a power source for space travel. In Edward Wellen's 1971 novel Hijack, the Mafia is duped into abandoning Earth by being misled that the Sun will turn into a nova. Connie Willis's 1979 short story "Daisy, in the Sun" is a coming-of-age parable that relates a young girl getting her first period to the imminent end of the world. It is now recognized that the Sun cannot explode in this manner as the necessary stellar conditions are not met.

Other

The heat of the Sun dooms life on Earth when the Earth's orbit is disrupted in John Hawkins's 1938 short story "Ark of Fire", the 1961 film The Day the Earth Caught Fire, and the 1961 episode "The Midnight Sun" of the television show The Twilight Zone. More fancifully, Clare Winger Harris's 1928 short story "The Menace of Mars" depicts an increase in heat from the Sun threatening the Earth as a result of a general cosmological change in the properties of the universe, which leads Mars to adjust Earth's orbit to serve as a shield against the Sun's radiation.

Refer to caption
A filament eruption, a type of solar storm

Solar storms such as solar flares appear in some stories. In Larry Niven's 1971 short story "Inconstant Moon", the sudden brightening of the Moon in the night sky leads the characters to conclude that the Sun has undergone a nova event that will destroy all life on Earth, though they later realize that a large solar flare would also produce that effect and that all hope might not be lost. The 1990 film Solar Crisis depicts a mission to bomb the Sun to avert the destruction that could be caused by an immense predicted solar flare, while the 2005 novel Sunstorm by Arthur C. Clarke and Stephen Baxter portrays mankind constructing a large shielding object at the Sun–Earth L1 Lagrange point as protection against the threat posed by a similar event. In David Koepp's 2022 novel Aurora, a coronal mass ejection threatens to end human civilization; the book appears alongside Niven's "Inconstant Moon" on a list of science fiction works with relatively scientifically plausible depictions of the Sun compiled by astronomer Andrew Fraknoi.

More long-lasting changes in solar output appear in Arthur G. Stangland [Wikidata]'s 1932 short story "50th Century Revolt", where an increase in solar activity forces humanity to slow the rotation of the Earth to a synchronous rotation—where the same side of the Earth faces the Sun at all times, thus protecting the other half of the planet from the scorching heat—for two millennia until the Sun dims again, and George O. Smith's 1953 novel Troubled Star, where aliens seek to turn the Sun into a variable star.

Properties and phenomena

Orbital mechanics

Refer to caption
Schematic diagram of the shared orbit of Earth and the fictional Counter-Earth (Gor). The two planets are always hidden from each other's view by the Sun. In reality, this orbital arrangement would not be stable.

The Sun hides Counter-Earth—a planet diametrically opposite Earth in its orbit—in some stories including Edgar Wallace's 1929 novel Planetoid 127 and John Norman's Gor series starting with the 1966 novel Tarnsman of Gor. This Counter-Earth is inhabited by counterparts of the people of Earth in the 1969 film Doppelgänger (a.k.a. Journey to the Far Side of the Sun) and by a society of women in the 1950s comic strip Twin Earths. The 1972 anthology The Day the Sun Stood Still contains three different short stories (by Poul Anderson, Robert Silverberg, and Gordon R. Dickson) where the Sun stops in the sky as in the biblical Book of Joshua.

Power source

The energy output of the Sun was harnessed for power production in fiction as early as Hugo Gernsback's 1911 novel Ralph 124C 41+ and in several stories since, with Robert A. Heinlein's 1940 short story "Let There Be Light" describing economically viable solar panels and Isaac Asimov's 1941 short story "Reason" (later included in the 1950 fix-up novel I, Robot) depicting solar power produced in space but consumed on Earth. Other works have depicted solar arrays in close orbits around the Sun itself; Murray Leinster's 1931 short story "The Power Planet" features a variant that uses thermoelectric rather than photovoltaic principles. The Sun is also the source of comic book superhero Superman's superpowers, as well as those of supervillains Sun Girl from DC Comics and Solarr from Marvel Comics.

Solar wind

Following German astronomer Ludwig Biermann's 1951 discovery of the solar wind—a stream of charged particles from the Sun—stories emerged about spacecraft with solar sails. These devices capture the small amount of pressure pointing away from the Sun exerted by the solar wind, as well as the radiation pressure from the sunlight itself, and use it for propulsion. The idea was popular in 1960s science fiction, appearing among others in Jack Vance's 1962 short story "Gateway to Strangeness" and Cordwainer Smith's 1963 short story "Think Blue, Count Two". Arthur C. Clarke's 1964 short story "Sunjammer" (a.k.a. "The Wind from the Sun") depicts a race to the Moon between solar sail-propelled spacecraft. Robert A. Heinlein had earlier written about a proto-variation on the concept using an inertialess drive. The 1990 anthology Project Solar Sail edited by Clarke and David Brin collects various stories and essays about solar sails.

Eclipses

Scene from the 1961 film Barabbas
The 1961 film Barabbas portrayed the crucifixion darkness by filming during the totality of the solar eclipse of February 15, 1961.

Solar eclipses are plot points in many stories. The earliest work of fiction in which an eclipse appears is the ancient Sumerian c. 2100 BCE Epic of Gilgamesh. Using knowledge of the underlying astronomy to be able to predict eclipses mathematically is a common trope—according to Stableford, it "became a key method by which European explorers could impress superstitious native populations in adventure stories". Several sources attribute the popularity of this trope to the possibly-apocryphal story of Christopher Columbus using foreknowledge of the March 1504 lunar eclipse to defuse a situation of increasingly strained relations with the Arawak people on Jamaica by pretending to cause the eclipse. H. Rider Haggard's 1885 novel King Solomon's Mines originally featured a solar eclipse in this manner, though later editions substituted a lunar eclipse to address the issue of the event having a several-hour duration, whereas solar eclipses last for a maximum of a few minutes. In a variation on the theme, Mark Twain's 1889 novel A Connecticut Yankee in King Arthur's Court depicts a time traveller using an almanac in this way to impress the people in Medieval Britain and become a person of influence.[5][64] The eclipse prediction motif recurred in fiction until the 1930s or 1940s, by which time it fell out of favour. Eclipses continued to appear, but much more rarely. In William Lemkin's 1930 short story "The Eclipse Special", scientists construct an aircraft that will allow them to move with the eclipse's path of totality and remain in the Sun's umbra for longer in order to extend the amount of time available to study the eclipse. The 1961 film Barabbas portrays the crucifixion darkness during the biblical crucifixion of Jesus as a solar eclipse, and the scene was filmed during the solar eclipse of February 15, 1961. According to science fiction scholar Lisa Yaszek, the decades around the turn of the millennium saw the emergence of a trend wherein marginalized groups "experience a reversal of fortunes when the Moon takes center stage and blots out the Sun".

Sunspots

The 11-year solar cycle of sunspot activity appears in a small number of works such as Clifford D. Simak's 1940 short story "Sunspot Purge" and Philip Latham's 1959 short story "Disturbing Sun".In Robert A. Heinlein's 1952 short story "The Year of the Jackpot", this cycle is one of many that herald the end of the world when they align. Hyman Kaner [Wikidata]'s 1946 novel The Sun Queen is set on a sunspot, where two humans from Earth encounter two factions at war. In science fiction horror films, sunspots are occasionally invoked as the cause of various types of abnormal phenomena such as zombies and mass delusions.

Close encounters

The Sun appears as a hazard to spaceships that approach it too closely in some stories. In John W. Campbell's 1935 short story "Blindness", a scientist studies the Sun at close range in order to solve the mysteries of nuclear energy at great personal cost, only to find that the method for getting there was worth more than the discoveries made. Willy Ley's 1937 short story "At the Perihelion" involves a close approach to the Sun as part of an escape from Mars,[4][5][74] and Charles L. Harness's 1949 novel The Paradox Men (a.k.a. Flight into Yesterday) is a space opera that climaxes with a swordfight atop a space station on the surface of the Sun. In Ray Bradbury's 1953 short story "The Golden Apples of the Sun", a crewed solar sample-return mission requires a spaceship to be cooled to near-absolute zero to endure the extreme heat during the critical phase. A fleet of near-Sun spacecraft that modulate the solar output for weather control purposes appears in Theodore L. Thomas's 1962 short story "The Weather Man". David Brin's 1980 novel Sundiver revolves around a hard science fiction journey into the Sun.

Sentient

A still frame from The Impossible Voyage (1904)
The Sun in the 1904 short film The Impossible Voyage, an early science fiction film by Georges Méliès

Some works depict the Sun as being sentient. According to The Encyclopedia of Science Fiction, this is more commonly applied to other stars; in Olaf Stapledon's 1937 novel Star Maker, all stars are sentient, and in Diana Wynne Jones's 1975 novel Dogsbody, both the Sun and Sirius are sentient. In Gregory Benford and Gordon Eklund's 1977 novel If the Stars are Gods, aliens come to the Solar System to communicate with the Sun. According to The Encyclopedia of Fantasy, the Sun is usually male in fictional mythologies where it is personified, though some exceptions exist such as the legendarium of J. R. R. Tolkien, in whose cosmology it is female. The Sun is likewise female in Alasdair Gray's 1983 short story "The Problem", and concerned with her spots.

Tuesday, May 13, 2025

Environmental remediation

From Wikipedia, the free encyclopedia
https://en.wikipedia.org/wiki/Environmental_remediation
Dredging contaminated sediment in New Bedford Harbor, Massachusetts. The harbor is contaminated with polychlorinated biphenyls (PCBs).

Environmental remediation is the cleanup of hazardous substances dealing with the removal, treatment and containment of pollution or contaminants from environmental media such as soil, groundwater, sediment. Remediation may be required by regulations before development of land revitalization projects. Developers who agree to voluntary cleanup may be offered incentives under state or municipal programs like New York State's Brownfield Cleanup Program. If remediation is done by removal the waste materials are simply transported off-site for disposal at another location. The waste material can also be contained by physical barriers like slurry walls. The use of slurry walls is well-established in the construction industry. The application of (low) pressure grouting, used to mitigate soil liquefaction risks in San Francisco and other earthquake zones, has achieved mixed results in field tests to create barriers, and site-specific results depend upon many variable conditions that can greatly impact outcomes.

Remedial action is generally subject to an array of regulatory requirements, and may also be based on assessments of human health and ecological risks where no legislative standards exist, or where standards are advisory.

Remediation standards

In the United States, the most comprehensive set of Preliminary Remediation Goals (PRGs) is from the Environmental Protection Agency (EPA) Regional Screening Levels (RSLs). A set of standards used in Europe exists and is often called the Dutch standards. The European Union (EU) is rapidly moving towards Europe-wide standards, although most of the industrialised nations in Europe have their own standards at present. In Canada, most standards for remediation are set by the provinces individually, but the Canadian Council of Ministers of the Environment provides guidance at a federal level in the form of the Canadian Environmental Quality Guidelines and the Canada-Wide Standards|Canada-Wide Standard for Petroleum Hydrocarbons in Soil.

Site assessment

Once a site is suspected of being contaminated there is a need to assess the contamination. Often the assessment begins with preparation of a Phase I Environmental Site Assessment. The historical use of the site and the materials used and produced on site will guide the assessment strategy and type of sampling and chemical analysis to be done. Often nearby sites owned by the same company or which are nearby and have been reclaimed, levelled or filled are also contaminated even where the current land use seems innocuous. For example, a car park may have been levelled by using contaminated waste in the fill. Also important is to consider off site contamination of nearby sites often through decades of emissions to soil, groundwater, and air. Ceiling dust, topsoil, surface and groundwater of nearby properties should also be tested, both before and after any remediation. This is a controversial step as:

  1. No one wants to have to pay for the cleanup of the site;
  2. If nearby properties are found to be contaminated it may have to be noted on their property title, potentially affecting the value;
  3. No one wants to pay for the cost of assessment.

Often corporations which do voluntary testing of their sites are protected from the reports to environmental agencies becoming public under Freedom of Information Acts, however a "Freedom of Information" inquiry will often produce other documents that are not protected or will produce references to the reports.

Funding remediation

In the US there has been a mechanism for taxing polluting industries to form a Superfund to remediate abandoned sites, or to litigate to force corporations to remediate their contaminated sites. Other countries have other mechanisms and commonly sites are rezoned to "higher" uses such as high density housing, to give the land a higher value so that after deducting cleanup costs there is still an incentive for a developer to purchase the land, clean it up, redevelop it and sell it on, often as apartments (home units).

Mapping remediation

There are several tools for mapping these sites and which allow the user to view additional information. One such tool is TOXMAP, a Geographic Information System (GIS) from the Division of Specialized Information Services of the United States National Library of Medicine (NLM) that uses maps of the United States to help users visually explore data from the United States Environmental Protection Agency's (EPA) Superfund and Toxics Release Inventory programs.

Technologies

Remediation technologies are many and varied but can generally be categorized into ex-situ and in-situ methods. Ex-situ methods involve excavation of affected soils and subsequent treatment at the surface as well as extraction of contaminated groundwater and treatment at the surface. In-situ methods seek to treat the contamination without removing the soils or groundwater. Various technologies have been developed for remediation of oil-contaminated soil/sediments.

Traditional remediation approaches consist of soil excavation and disposal to landfill and groundwater "pump and treat". In-situ technologies include but are not limited to: solidification and stabilization, soil vapor extraction, permeable reactive barriers, monitored natural attenuation, bioremediation-phytoremediation, chemical oxidation, steam-enhanced extraction and in situ thermal desorption and have been used extensively in the USA.

Barriers

Contaminants can be removed from a site or controlled. One option for control are barrier walls, which can be temporary to prevent contamination during treatment and removal, or more permanent. Techniques to construct barrier walls are deep soil mixing, jet grouting, low pressure grouting with cement and chemicals, freezing and slurry walls. Barrier walls must be constructed of impermeable materials and resistant to deterioration from contact with waste, for the lifespan of the barrier wall. It wasn't until the use of newer polymer and chemical grouts in the 1950s and 1960s that Federal agencies of the US government recognized the need to establish a minimum project life of 50 years in real world applications.

The Department of Energy is one US government agency that sponsors research to formulate, test and determine use applications for innovative polymer grouts used in waste containment barriers. Portland cement was used in the past, however cracking and poor performance under wet-dry conditions at arid sites need improved materials to remedy. Sites that need remediation have variable humidity, moisture and soil conditions. Field implementation remains challenging: different environmental and site conditions require different materials and the placement technologies are specific to the characteristics of the compounds used which vary in viscosity, gel time and density:

"The selection of subsurface barriers for any given site which needs remediation, and the selection of a particular barrier technology must be done, however, by means of the Superfund Process, with special emphasis on the remedial investigation and feasibility study portions. The chemical compatibility of the material with the wastes, leachates and geology with which it is likely to come in contact is of particular importance for barriers constructed from fluids which are supposed to set in-situ. EPA emphasizes this compatibility in its guidance documents, noting that thorough characterization of the waste, leachate, barrier material chemistry, site geochemistry, and compatibility testing of the barrier material with the likely disposal site chemical environment are all required."

These guidelines are for all materials - experimental and traditional.

Thermal desorption

Thermal desorption is a technology for soil remediation. During the process a desorber volatilizes the contaminants (e.g. oil, mercury or hydrocarbon) to separate them from especially soil or sludge. After that the contaminants can either be collected or destroyed in an offgas treatment system.

Excavation or dredging

Excavation of soil contaminated with dioxins at Da Nang International Airport in Vietnam

Excavation processes can be as simple as hauling the contaminated soil to a regulated landfill, but can also involve aerating the excavated material in the case of volatile organic compounds (VOCs). Recent advancements in bioaugmentation and biostimulation of the excavated material have also proven to be able to remediate semi-volatile organic compounds (SVOCs) onsite. If the contamination affects a river or bay bottom, then dredging of bay mud or other silty clays containing contaminants (including sewage sludge with harmful microorganisms) may be conducted. Recently, ExSitu Chemical oxidation has also been utilized in the remediation of contaminated soil. This process involves the excavation of the contaminated area into large bermed areas where they are treated using chemical oxidation methods.

Surfactant enhanced aquifer remediation (SEAR)

This is used in removing non-aqueous phase liquids (NAPLs) from aquifer. This is done by pumping surfactant solution into contaminated aquifer using injection wells which are passed through contaminated zones to the extraction wells. The Surfactant solution containing contaminants is then captured and pumped out by extraction wells for further treatment at the surface. Then the water after treatment is discharged into surface water or re-injected into groundwater.

In geologic formations that allow delivery of hydrocarbon mitigation agents or specialty surfactants, this approach provides a cost-effective and permanent solution to sites that have been previously unsuccessful utilizing other remedial approaches. This technology is also successful when utilized as the initial step in a multi-faceted remedial approach utilizing SEAR then In situ Oxidation, bioremediation enhancement or soil vapor extraction (SVE).

Pump and treat

Pump and treat involves pumping out contaminated groundwater with the use of a submersible or vacuum pump, and allowing the extracted groundwater to be purified by slowly proceeding through a series of vessels that contain materials designed to adsorb the contaminants from the groundwater. For petroleum-contaminated sites this material is usually activated carbon in granular form. Chemical reagents such as flocculants followed by sand filters may also be used to decrease the contamination of groundwater. Air stripping is a method that can be effective for volatile pollutants such as BTEX compounds found in gasoline.

For most biodegradable materials like BTEX, MTBE and most hydrocarbons, bioreactors can be used to clean the contaminated water to non-detectable levels. With fluidized bed bioreactors it is possible to achieve very low discharge concentrations which will meet or exceed discharge requirements for most pollutants.

Depending on geology and soil type, pump and treat may be a good method to quickly reduce high concentrations of pollutants. It is more difficult to reach sufficiently low concentrations to satisfy remediation standards, due to the equilibrium of absorption/desorption processes in the soil. However, pump and treat is typically not the best form of remediation. It is expensive to treat the groundwater, and typically is a very slow process to clean up a release with pump and treat. It is best suited to control the hydraulic gradient and keep a release from spreading further. Better options of in-situ treatment often include air sparge/soil vapor extraction (AS/SVE) or dual phase extraction/multiphase extraction (DPE/MPE). Other methods include trying to increase the dissolved oxygen content of the groundwater to support microbial degradation of the compound (especially petroleum) by direct injection of oxygen into the subsurface, or the direct injection of a slurry that slowly releases oxygen over time (typically magnesium peroxide or calcium oxy-hydroxide).

Solidification and stabilization

Solidification and stabilization work has a reasonably good track record but also a set of serious deficiencies related to durability of solutions and potential long-term effects. In addition CO2 emissions due to the use of cement are also becoming a major obstacle to its widespread use in solidification/stabilization projects.

Stabilization/solidification (S/S) is a remediation and treatment technology that relies on the reaction between a binder and soil to stop/prevent or reduce the mobility of contaminants.

  • Stabilization involves the addition of reagents to a contaminated material (e.g. soil or sludge) to produce more chemically stable constituents; and
  • Solidification involves the addition of reagents to a contaminated material to impart physical/dimensional stability to contain contaminants in a solid product and reduce access by external agents (e.g. air, rainfall).

Conventional S/S is an established remediation technology for contaminated soils and treatment technology for hazardous wastes in many countries in the world. However, the uptake of S/S technologies has been relatively modest, and a number of barriers have been identified including:

  • the relatively low cost and widespread use of disposal to landfill;
  • the lack of authoritative technical guidance on S/S;
  • uncertainty over the durability and rate of contaminant release from S/S-treated material;
  • experiences of past poor practice in the application of cement stabilization processes used in waste disposal in the 1980s and 1990s (ENDS, 1992); and
  • residual liability associated with immobilized contaminants remaining on-site, rather than their removal or destruction.

In situ oxidation

New in situ oxidation technologies have become popular for remediation of a wide range of soil and groundwater contaminants. Remediation by chemical oxidation involves the injection of strong oxidants such as hydrogen peroxide, ozone gas, potassium permanganate or persulfates.

Oxygen gas or ambient air can also be injected to promote growth of aerobic bacteria which accelerate natural attenuation of organic contaminants. One disadvantage of this approach is the possibility of decreasing anaerobic contaminant destruction natural attenuation where existing conditions enhance anaerobic bacteria which normally live in the soil prefer a reducing environment. In general, aerobic activity is much faster than anaerobic and overall destruction rates are typically greater when aerobic activity can be successfully promoted.

The injection of gases into the groundwater may also cause contamination to spread faster than normal depending on the hydrogeology of the site. In these cases, injections downgradient of groundwater flow may provide adequate microbial destruction of contaminants prior to exposure to surface waters or drinking water supply wells.

Migration of metal contaminants must also be considered whenever modifying subsurface oxidation-reduction potential. Certain metals are more soluble in oxidizing environments while others are more mobile in reducing environments.

Soil vapor extraction

Soil vapor extraction (SVE) is an effective remediation technology for soil. "Multi Phase Extraction" (MPE) is also an effective remediation technology when soil and groundwater are to be remediated coincidentally. SVE and MPE utilize different technologies to treat the off-gas volatile organic compounds (VOCs) generated after vacuum removal of air and vapors (and VOCs) from the subsurface and include granular activated carbon (most commonly used historically), thermal and/or catalytic oxidation and vapor condensation. Generally, carbon is used for low (below 500 ppmV) VOC concentration vapor streams, oxidation is used for moderate (up to 4,000 ppmV) VOC concentration streams, and vapor condensation is used for high (over 4,000 ppmV) VOC concentration vapor streams. Below is a brief summary of each technology.

  1. Granular activated carbon (GAC) is used as a filter for air or water. Commonly used to filter tap water in household sinks. GAC is a highly porous adsorbent material, produced by heating organic matter, such as coal, wood and coconut shell, in the absence of air, which is then crushed into granules. Activated carbon is positively charged and therefore able to remove negative ions from the water such as organic ions, ozone, chlorine, fluorides and dissolved organic solutes by adsorption onto the activated carbon. The activated carbon must be replaced periodically as it may become saturated and unable to adsorb (i.e. reduced absorption efficiency with loading). Activated carbon is not effective in removing heavy metals.
  2. Thermal oxidation (or incineration) can also be an effective remediation technology. This approach is somewhat controversial because of the risks of dioxins released in the atmosphere through the exhaust gases or effluent off-gas. Controlled, high temperature incineration with filtering of exhaust gases however should not pose any risks. Two different technologies can be employed to oxidize the contaminants of an extracted vapor stream. The selection of either thermal or catalytic depends on the type and concentration in parts per million by volume of constituent in the vapor stream. Thermal oxidation is more useful for higher concentration (~4,000 ppmV) influent vapor streams (which require less natural gas usage) than catalytic oxidation at ~2,000 ppmV.
  • Thermal oxidation which uses a system that acts as a furnace and maintains temperatures ranging from 1,350 to 1,500 °F (730 to 820 °C).
  • Catalytic oxidation which uses a catalyst on a support to facilitate a lower temperature oxidation. This system usually maintains temperatures ranging from 600 to 800 °F (316 to 427 °C).
  1. Vapor condensation is the most effective off-gas treatment technology for high (over 4,000 ppmV) VOC concentration vapor streams. The process involves cryogenically cooling the vapor stream to below 40 degrees C such that the VOCs condensate out of the vapor stream and into liquid form where it is collected in steel containers. The liquid form of the VOCs is referred to as dense non-aqueous phase liquids (DNAPL) when the source of the liquid consists predominantly of solvents or light non-aqueous phase liquids (LNAPL) when the source of the liquid consists predominantly of petroleum or fuel products. This recovered chemical can then be reused or recycled in a more environmentally sustainable or green manner than the alternatives described above. This technology is also known as cryogenic cooling and compression (C3-Technology).

Nanoremediation

Using nano-sized reactive agents to degrade or immobilize contaminants is termed nanoremediation. In soil or groundwater nanoremediation, nanoparticles are brought into contact with the contaminant through either in situ injection or a pump-and-treat process. The nanomaterials then degrade organic contaminants through redox reactions or adsorb to and immobilize metals such as lead or arsenic. In commercial settings, this technology has been dominantly applied to groundwater remediation, with research into wastewater treatment. Research is also investigating how nanoparticles may be applied to cleanup of soil and gases.

Nanomaterials are highly reactive because of their high surface area per unit mass, and due to this reactivity nanomaterials may react with target contaminants at a faster rate than would larger particles. Most field applications of nanoremediation have used nano zero-valent iron (nZVI), which may be emulsified or mixed with another metal to enhance dispersion.

That nanoparticles are highly reactive can mean that they rapidly clump together or react with soil particles or other material in the environment, limiting their dispersal to target contaminants. Some of the important challenges currently limiting nanoremediation technologies include identifying coatings or other formulations that increase dispersal of the nanoparticle agents to better reach target contaminants while limiting any potential toxicity to bioremediation agents, wildlife, or people.

Bioremediation

Bioremediation is a process that treats a polluted area either by altering environmental conditions to stimulate growth of microorganisms or through natural microorganism activity, resulting in the degradation of the target pollutants. Broad categories of bioremediation include biostimulation, bioaugmentation, and natural recovery (natural attenuation). Bioremediation is either done on the contaminated site (in situ) or after the removal of contaminated soils at another more controlled site (ex situ).

In the past, it has been difficult to turn to bioremediation as an implemented policy solution, as lack of adequate production of remediating microbes led to little options for implementation. Those that manufacture microbes for bioremediation must be approved by the EPA; however, the EPA traditionally has been more cautious about negative externalities that may or may not arise from the introduction of these species. One of their concerns is that the toxic chemicals would lead to the microbe's gene degradation, which would then be passed on to other harmful bacteria, creating more issues, if the pathogens evolve the ability to feed off of pollutants.

Entomoremediation

Entomoremediation is a variant of bioremediation in which insects decontaminate soils. Entomoremediation techniques engage microorganisms, collembolans, ants, flies, beetles, and termites. It is dependent on saprophytic insect larvae, resistant to adverse environmental conditions and able to bioaccumulate toxic heavy metal contaminants.

Hermetia illucens (black soldier fly - BSF) is an important entomoremediation participant. H. illucens has been observed to reduce polluted substrate dry weight by 49%. H. illucens larvae have been observed to accumulate cadmium at a concentration of 93% and bioaccumulation factor of 5.6, lead, mercury, zinc with a bioaccumulation factor of 3.6, and arsenic at a concentration of 22%. Black soldier fly larvae (BSFL) have also been used to monitor the degradation and reduction of anthropogenic oil contamination in the environment.

Entomoremediation is considered viable as an accessible low-energy, low-carbon, and highly renewable method for environmental decontamination.

Collapsing air microbubbles

Cleaning of oil contaminated sediments with self collapsing air microbubbles have been recently explored as a chemical free technology. Air microbubbles generated in water without adding any surfactant could be used to clean oil contaminated sediments. This technology holds promise over the use of chemicals (mainly surfactant) for traditional washing of oil contaminated sediments.

Community consultation and information

In preparation for any significant remediation there should be extensive community consultation. The proponent should both present information to and seek information from the community. The proponent needs to learn about "sensitive" (future) uses like childcare, schools, hospitals, and playgrounds as well as community concerns and interests information. Consultation should be open, on a group basis so that each member of the community is informed about issues they may not have individually thought about. An independent chairperson acceptable to both the proponent and the community should be engaged (at proponent expense if a fee is required). Minutes of meetings including questions asked and the answers to them and copies of presentations by the proponent should be available both on the internet and at a local library (even a school library) or community centre.

Incremental health risk

Incremental health risk is the increased risk that a receptor (normally a human being living nearby) will face from (the lack of) a remediation project. The use of incremental health risk is based on carcinogenic and other (e.g., mutagenic, teratogenic) effects and often involves value judgements about the acceptable projected rate of increase in cancer. In some jurisdictions this is 1 in 1,000,000 but in other jurisdictions the acceptable projected rate of increase is 1 in 100,000. A relatively small incremental health risk from a single project is not of much comfort if the area already has a relatively high health risk from other operations like incinerators or other emissions, or if other projects exist at the same time causing a greater cumulative risk or an unacceptably high total risk. An analogy often used by remediators is to compare the risk of the remediation on nearby residents to the risks of death through car accidents or tobacco smoking.

Emissions standards

Standards are set for the levels of dust, noise, odour, emissions to air and groundwater, and discharge to sewers or waterways of all chemicals of concern or chemicals likely to be produced during the remediation by processing of the contaminants. These are compared against both natural background levels in the area and standards for areas zoned as nearby areas are zoned and against standards used in other recent remediations. Just because the emission is emanating from an area zoned industrial does not mean that in a nearby residential area there should be permitted any exceedances of the appropriate residential standards.

Monitoring for compliance against each standards is critical to ensure that exceedances are detected and reported both to authorities and the local community.

Enforcement is necessary to ensure that continued or significant breaches result in fines or even a jail sentence for the polluter.

Penalties must be significant as otherwise fines are treated as a normal expense of doing business. Compliance must be cheaper than to have continuous breaches.

Transport and emergency safety assessment

Assessment should be made of the risks of operations, transporting contaminated material, disposal of waste which may be contaminated including workers' clothes, and a formal emergency response plan should be developed. Every worker and visitor entering the site should have a safety induction personalised to their involvement with the site.

Impacts of funding remediation

Local communities and government often resist the rezoning because of the adverse effects of the remediation and new development on the local amenities. The main impacts during remediation are noise, dust, odour, and incremental health risk. Then there is the noise, dust, and traffic of developments. Then, there is the impact on local traffic, schools, playing fields, and other public facilities due to the increased population.

Examples of major remediation projects

Homebush Bay, New South Wales, Australia

Remediation of pesticide plant on Homebush Bay

Dioxins from Union Carbide used in the production of now-banned pesticide 2,4,5-Trichlorophenoxyacetic acid and defoliant Agent Orange polluted Homebush Bay. Remediation was completed in 2010, but fishing will continue to be banned for decades.

Bakar, Croatia

An EU contract for immobilization of a polluted area of 20,000 m3 in Bakar, Croatia based on solidification/stabilization with ImmoCem is currently in progress. After three years of intensive research by the Croatian government, the EU funded the immobilization project in Bakar. The area is contaminated with large amounts of TPH, PAH, and metals. For the immobilization, the contractor chose to use the mix-in-plant procedure.

Pain and pleasure

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