NaOCl (H2O) ® Na+
+ OCl-
OCl- + H2O ↔ HOCl + OH-
H+ + Cl- + OCl-
®
OH- + Cl2
H+
+ Cl- + HOCl ® H2O + Cl2
In both of the
bottom reactions gaseous chlorine is generated in serious quantities. This is because often, not always but in this
case, which I would have known had I bothered to read the labels instead of
just assuming, toilet bleach is fairly concentrated hydrochloric acid. Needless to say it starting foaming at once,
and when I came had just enough to flush before being driven out, coughing and
tearing.
Lesson: read labels
on chemicals before using!