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Friday, May 17, 2019

Radiation protection

From Wikipedia, the free encyclopedia
 Radiation protection, also known as radiological protection, is defined by the International Atomic Energy Agency (IAEA) as "The protection of people from harmful effects of exposure to ionizing radiation, and the means for achieving this". The IAEA also states "The accepted understanding of the term radiation protection is restricted to protection of people. Suggestions to extend the definition to include the protection of non-human species or the protection of the environment are controversial". Exposure can be from a radiation source external to the human body or due to the bodily intake of a radioactive material.

Ionizing radiation is widely used in industry and medicine, and can present a significant health hazard by causing microscopic damage to living tissue. This can result in skin burns and radiation sickness at high exposures, known as "tissue" or "deterministic" effects (conventionally indicated by the gray), and statistically elevated risks of cancer at low exposures, known as "stochastic effects" (conventionally measured by the sievert).

Fundamental to radiation protection is the reduction of expected dose and the measurement of dose uptake. For radiation protection and dosimetry assessment the International Committee on Radiation Protection (ICRP) and International Commission on Radiation Units and Measurements (ICRU) publish recommendations and data which is used to calculate the biological effects on the human body of certain levels of radiation, and thereby advise acceptable dose uptake limits. Supporting these are preventive dose reduction techniques such as radiation shielding, exposure planning and avoidance of ingestion of radioactive substances. Radiation protection instruments are used to indicate radiation hazards, and personal dosimeters and bioassay techniques are used to measure personal dose uptake.

Principles

International policy relationships in radiological protection
 
External dose quantities used in radiation protection and dosimetry - based on ICRU report 57
 
Graphic showing relationships between radioactivity and detected ionizing radiation
 
The ICRP recommends, develops and maintains the International System of Radiological Protection, based on evaluation of the large body of scientific studies available to equate risk to received dose levels. The system's health objectives are "to manage and control exposures to ionising radiation so that deterministic effects are prevented, and the risks of stochastic effects are reduced to the extent reasonably achievable".

The ICRP's recommendations flow down to national and regional regulators, which have the opportunity to incorporate them into their own law; this process is shown in the accompanying block diagram. In most countries a national regulatory authority works towards ensuring a secure radiation environment in society by setting dose limitation requirements that are generally based on the recommendations of the ICRP.

Exposure situations

The ICRP recognises planned, emergency, and existing exposure situations, as described below:
  • Planned exposure – defined as "...where radiological protection can be planned in advance, before exposures occur, and where the magnitude and extent of the exposures can be reasonably predicted." These are such as in occupational exposure situations, where it is necessary for personnel to work in a known radiation environment.
  • Emergency exposure – defined as "...unexpected situations that may require urgent protective actions". This would be such as an emergency nuclear event.
  • Existing exposure – defined as "...being those that already exist when a decision on control has to be taken". These can be such as from naturally occurring radioactive materials which exist in the environment.

Regulation of dose uptake

The ICRP uses the following overall principles for all controllable exposure situations.
  • Justification: No unnecessary use of radiation is permitted, which means that the advantages must outweigh the disadvantages.
  • Limitation: Each individual must be protected against risks that are too great, through the application of individual radiation dose limits.
  • Optimization: This process is intended for application to those situations that have been deemed to be justified. It means "the likelihood of incurring exposures, the number of people exposed, and the magnitude of their individual doses" should all be kept as Low As Reasonably Achievable (known as ALARA or ALARP). It takes into account economic and societal factors.

Factors in external dose uptake

There are three factors that control the amount, or dose, of radiation received from a source. Radiation exposure can be managed by a combination of these factors:
  1. Time: Reducing the time of an exposure reduces the effective dose proportionally. An example of reducing radiation doses by reducing the time of exposures might be improving operator training to reduce the time they take to handle a radioactive source.
  2. Distance: Increasing distance reduces dose due to the inverse square law. Distance can be as simple as handling a source with forceps rather than fingers.
  3. Shielding: Sources of radiation can be shielded with solid or liquid material, which absorbs the energy of the radiation. The term 'biological shield' is used for absorbing material placed around a nuclear reactor, or other source of radiation, to reduce the radiation to a level safe for humans.

Internal dose uptake

Large scale glovebox in the nuclear industry used to contain airborne radioactive particles.
 
Internal dose, due to the inhalation or ingestion of radioactive substances, can result in stochastic or deterministic effects, depending on the amount of radioactive material ingested and other biokinetic factors.

The risk from a low level internal source is represented by the dose quantity committed dose, which has the same risk as the same amount of external effective dose.

The intake of radioactive material can occur through four pathways:
  • Inhalation of airborne contaminants such as radon gas and radioactive particles
  • Ingestion of radioactive contamination in food or liquids
  • Absorption of vapours such as tritium oxide through the skin
  • Injection of medical radioisotopes such as technetium-99m
The occupational hazards from airborne radioactive particles in nuclear and radio-chemical applications are greatly reduced by the extensive use of gloveboxes to contain such material. To protect against breathing in radioactive particles in ambient air, respirators with particulate filters are worn. 

To monitor the concentration of radioactive particles in ambient air, radioactive particulate monitoring instruments measure the concentration or presence of airborne materials.

For ingested radioactive materials in food and drink, specialist laboratory radiometric assay methods are used to measure the concentration of such materials.

Recommended limits on dose uptake

USA Dept of Energy 2010 dose chart in sieverts for a variety of situations and applications.
 
Various doses of radiation in sieverts, ranging from trivial to lethal.
 
The ICRP recommends a number of limits for dose uptake in table 8 of ICRP report 103. These limits are "situational", for planned, emergency and existing situations. Within these situations, limits are given for certain exposed groups:
  • Planned exposure – limits given for occupational, medical and public exposure. The occupational exposure limit of effective dose is 20 mSv per year, averaged over defined periods of 5 years, with no single year exceeding 50 mSv. The public exposure limit is 1 mSv in a year.
  • Emergency exposure – limits given for occupational and public exposure
  • Existing exposure – reference levels for all persons exposed
Further detail of some of the limits can be found on the ICRPedia page.

The public information dose chart of the USA Department of Energy, shown here on the right, applies to USA regulation, which is based on ICRP recommendations. Note that examples in lines 1 to 4 have a scale of dose rate (radiation per unit time), whilst 5 and 6 have a scale of total accumulated dose.

ALARP & ALARA

ALARP is an acronym for an important principle in exposure to radiation and other occupational health risks and in the UK stands for "As Low As Reasonably Practicable". The aim is to minimize the risk of radioactive exposure or other hazard while keeping in mind that some exposure may be acceptable in order to further the task at hand. The equivalent term ALARA, "As Low As Reasonably Achievable", is more commonly used outside the UK. 

This compromise is well illustrated in radiology. The application of radiation can aid the patient by providing doctors and other health care professionals with a medical diagnosis, but the exposure of the patient should be reasonably low enough to keep the statistical probability of cancers or sarcomas (stochastic effects) below an acceptable level, and to eliminate deterministic effects (e.g. skin reddening or cataracts). An acceptable level of incidence of stochastic effects is considered to be equal for a worker to the risk in other radiation work generally considered to be safe.

This policy is based on the principle that any amount of radiation exposure, no matter how small, can increase the chance of negative biological effects such as cancer. It is also based on the principle that the probability of the occurrence of negative effects of radiation exposure increases with cumulative lifetime dose. These ideas are combined to form the linear no-threshold model which says that there is not a threshold at which there is an increase in the rate of occurrence of stochastic effects with increasing dose. At the same time, radiology and other practices that involve use of ionizing radiation bring benefits, so reducing radiation exposure can reduce the efficacy of a medical practice. The economic cost, for example of adding a barrier against radiation, must also be considered when applying the ALARP principle. Computed Tomography, better known as C.T. Scans or CAT Scans have made an enormous contribution to medicine, however not without some risk. They use ionizing radiation which can cause cancer, especially in children. When caregivers follow proper indications for their use and child safe techniques rather than adult techniques, downstream cancer can be prevented.

Personal radiation dosimeters

The radiation dosimeter is an important personal dose measuring instrument. It is worn by the person being monitored and is used to estimate the external radiation dose deposited in the individual wearing the device. They are used for Gamma, X-ray, beta and other strongly penetrating radiation, but not for weakly penetrating radiation such as alpha particles. Traditionally film badges were used for long term monitoring, and quartz fibre dosimeters for short term monitoring. However, these are mostly superseded by such as thermoluminescent dosimetry (TLD) badges and electronic dosimeters. Electronic dosimeters can give an alarm warning if a preset dose threshold has been reached, enabling safer working in potentially higher radiation levels, where the received dose must be continually monitored. 

Workers exposed to radiation, such as radiographers, nuclear power plant workers, doctors using radiotherapy, those in laboratories using radionuclides, and HAZMAT teams are required to wear dosimeters so a record of occupational exposure can be made. Such devices are generally termed "legal dosimeters" if they have been approved for use in recording personnel dose for regulatory purposes. 

Dosimeters can be worn to obtain a whole body dose and there are also specialist types that can be worn on the fingers or clipped to headgear, to measure the localised body irradiation for specific activities. 

Common types of wearable dosimeters for ionizing radiation include:

Radiation shielding

Diagram showing various forms of ionizing radiation, and the sort of material that is used to stop or reduce that type.
 
The total absorption coefficient of lead (atomic number 82) for gamma rays, plotted versus gamma energy, and the contributions by the three effects. Here, the photoelectric effect dominates at low energy. Above 5 MeV, pair production starts to dominate.
 
A lead castle built to shield a radioactive sample in a lab
 
Almost any material can act as a shield from gamma or x-rays if used in sufficient amounts. Different types of ionizing radiation interact in different ways with shielding material. The effectiveness of shielding is dependent on the Stopping power of radiation particles, which varies with the type and energy of radiation and the shielding material used. Different shielding techniques are therefore used dependent on the application and the type and energy of the radiation. 

Shielding reduces the intensity of radiation depending on the thickness. This is an exponential relationship with gradually diminishing effect as equal slices of shielding material are added. A quantity known as the halving-thicknesses is used to calculate this. For example, a practical shield in a fallout shelter with ten halving-thicknesses of packed dirt, which is roughly 115 cm (3 ft 9 in) reduces gamma rays to 1/1024 of their original intensity (i.e. 1/210). 

The effectiveness of a shielding material in general increases with its atomic number, called Z, except for neutron shielding which is more readily shielded by the likes of neutron absorbers and moderators such as compounds of boron e.g. boric acid, cadmium, carbon and hydrogen respectively.

Graded-Z shielding is a laminate of several materials with different Z values (atomic numbers) designed to protect against ionizing radiation. Compared to single-material shielding, the same mass of graded-Z shielding has been shown to reduce electron penetration over 60%. It is commonly used in satellite-based particle detectors, offering several benefits:
  • Protection from radiation damage
  • Reduction of background noise for detectors
  • Lower mass compared to single-material shielding
Designs vary, but typically involve a gradient from high-Z (usually tantalum) through successively lower-Z elements such as tin, steel, and copper, usually ending with aluminium. Sometimes even lighter materials such as polypropylene or boron carbide are used. 

In a typical graded-Z shield, the high-Z layer effectively scatters protons and electrons. It also absorbs gamma rays, which produces X-ray fluorescence. Each subsequent layer absorbs the X-ray fluorescence of the previous material, eventually reducing the energy to a suitable level. Each decrease in energy produces bremsstrahlung and Auger electrons, which are below the detector's energy threshold. Some designs also include an outer layer of aluminium, which may simply be the skin of the satellite. The effectiveness of a material as a biological shield is related to its cross-section for scattering and absorption, and to a first approximation is proportional to the total mass of material per unit area interposed along the line of sight between the radiation source and the region to be protected. Hence, shielding strength or "thickness" is conventionally measured in units of g/cm2. The radiation that manages to get through falls exponentially with the thickness of the shield. In x-ray facilities, walls surrounding the room with the x-ray generator may contain lead sheets, or the plaster may contain barium sulfate. Operators view the target through a leaded glass screen, or if they must remain in the same room as the target, wear lead aprons.

Particle radiation

Particle radiation consists of a stream of charged or neutral particles, both charged ions and subatomic elementary particles. This includes solar wind, cosmic radiation, and neutron flux in nuclear reactors.

Electromagnetic radiation

Electromagnetic radiation consists of emissions of electromagnetic waves, the properties of which depend on the wavelength.
  • X-ray and gamma radiation are best absorbed by atoms with heavy nuclei; the heavier the nucleus, the better the absorption. In some special applications, depleted uranium or thorium are used, but lead is much more common; several centimeters are often required. Barium sulfate is used in some applications too. However, when cost is important, almost any material can be used, but it must be far thicker. Most nuclear reactors use thick concrete shields to create a bioshield with a thin water cooled layer of lead on the inside to protect the porous concrete from the coolant inside. The concrete is also made with heavy aggregates, such as Baryte or MagnaDense (Magnetite), to aid in the shielding properties of the concrete. Gamma rays are better absorbed by materials with high atomic numbers and high density, although neither effect is important compared to the total mass per area in the path of the gamma ray.
  • Ultraviolet (UV) radiation is ionizing in its shortest wavelengths but it is not penetrating, so it can be shielded by thin opaque layers such as sunscreen, clothing, and protective eyewear. Protection from UV is simpler than for the other forms of radiation above, so it is often considered separately.
In some cases, improper shielding can actually make the situation worse, when the radiation interacts with the shielding material and creates secondary radiation that absorbs in the organisms more readily. For example, although high atomic number materials are very effective in shielding photons, using them to shield beta particles may cause higher radiation exposure due to the production of bremsstrahlung x-rays, and hence low atomic number materials are recommended. Also, using material with a high neutron activation cross section to shield neutrons will result in the shielding material itself becoming radioactive and hence more dangerous than if it were not present.

Personal Protective Equipment (PPE) - Radiation

Personal Protection Equipment (PPE) includes all clothing and accessories which can be worn to prevent severe illness and injury as a result of exposure to radioactive material. Because radiation can affect humans through internal and external contamination, various protection strategies have been developed to protect humans from the harmful effects of radiation exposure from a spectrum of sources. A few of these strategies developed to shield from internal, external, and high energy radiation are outlined below.

Internal Contamination Protective Equipment

Internal contamination protection equipment protects against the inhalation and ingestion of radioactive material. Internal deposition of radioactive material result in direct exposure of radiation to organs and tissues inside the body. The respiratory protective equipment described below are designed to minimize the possibility of such material being inhaled or ingested as emergency workers are exposed to potentially radioactive environments.

Reusable Air Purifying Respirators (APR)
  • Elastic face piece worn over the mouth and nose
  • Contains filters, cartridges, and canisters to provide increased protection and better filtration
  • Battery powered blower forces contamination through air purifying filters
  • Purified air delivered under positive pressure to face piece
Supplied-Air Respirator (SAR)
  • Compressed air delivered from a stationary source to the face piece
Auxiliary Escape Respirator
  • Protects wearer from breathing harmful gases, vapors, fumes, and dust
  • Can be designed as an air-purifying escape respirator (APER) or a self-contained breathing apparatus (SCBA) type respirator
  • SCBA type escape respirators have an attached source of breathing air and a hood that provides a barrier against contaminated outside air
  • Provides very pure, dry compressed air to full facepiece mask via a hose
  • Air is exhaled to environment
  • By law, must be worn whenever entering environments immediately dangerous to life and health (IDLH) or when information is inadequate to rule out IDLH atmosphere

External Contamination Protective Equipment

External contamination protection equipment provides a barrier to shield radioactive material from being deposited externally on the body or clothes. The dermal protective equipment described below acts as a barrier to block radioactive material from physically touching the skin, but does not protect against externally penetrating high energy radiation. 

Chemical- Resistant Inner Suit
  • Porous overall suit - Dermal protection from aerosols, dry particles, and non hazardous liquids.
  • Non-porous overall suit to provide dermal protection from:
    • Dry powders and solids
    • Blood-borne pathogens and bio-hazards
    • Chemical splashes and inorganic acid/base aerosols
    • Mild Liquid Chemical Splashes from toxics and corrosices
    • Toxic industrial chemicals and materials
Level C Equivalent: Bunker Gear
  • Fire fighter protective clothing
  • Flame/water resistant
  • Helmet, gloves, foot gear, and hood
Level B Equivalent - Non-gas-tight Encapsulating Suit
  • Designed for environments which are immediately health risks but contain no substances which can be absorbed by skin
Level A Equivalent - Totally Encapsulating Chemical - and Vapor Protective Suit
  • Designed for environments which are immediate health risks and contain substances which can be absorbed by skin

External penetrating radiation

Many solutions to low energy radiation exposure like X-rays already exist. Lead aprons, for example, can protect patients and clinicians from the potentially harmful radiation effects of day to day medical examinations. It is quite feasible to protect large surface areas of the body from radiation in the lower energy spectrum because very little shielding material is required to provide the necessary protection.
Personal shielding against more energetic radiation such as gamma radiation is very difficult to achieve as the large mass of shielding material required to properly protect the entire body would make functional movement nearly impossible. For this, partial body shielding of radio-sensitive internal organs is the most viable protection strategy.

The immediate danger of intense exposure to high energy gamma radiation is Acute Radiation Syndrome (ARS), a result of irreversible bone marrow damage. The concept of selective shielding is based in the regenerative potential of the hematopoietic stem cells found in bone marrow. The regenerative quality of stem cells make it only necessary to protect enough bone marrow to repopulate the body with unaffected stem cells after the exposure: a similar concept which is applied in hematopoietic stem cell transplantation (HSCT) which is a common treatment for patients suffering from leukemia. This scientific advancement allows for the development of a new class of relatively light weight protective equipment which shields high concentrations of bone marrow to defer the hematopoietic sub-syndrome of Acute Radiation Syndrome to much higher dosages.

One technique is to apply selective shielding to protect the high concentration of bone marrow stored in the hips and other radio-sensitive organs in the abdominal area. This allows first responders a safe way to perform necessary missions in radioactive environments. The Organisation for Economic Co-operation and Development (OECD) and the Nuclear Energy Agency (NEA) have published a brief section outlining the benefits of partial body shielding in the 2015 report: Occupational Radiation Protection in Severe Accident Management.

Radiation protection instruments

Practical radiation measurement using calibrated radiation protection instruments is essential in evaluating the effectiveness of protection measures, and in assessing the radiation dose likely to be received by individuals. The measuring instruments for radiation protection are both "installed" (in a fixed position) and portable (hand-held or transportable).

Installed instruments

Installed instruments are fixed in positions which are known to be important in assessing the general radiation hazard in an area. Examples are installed "area" radiation monitors, Gamma interlock monitors, personnel exit monitors, and airborne particulate monitors.

The area radiation monitor will measure the ambient radiation, usually X-Ray, Gamma or neutrons; these are radiations which can have significant radiation levels over a range in excess of tens of metres from their source, and thereby cover a wide area.

Gamma radiation "interlock monitors" are used in applications to prevent inadvertent exposure of workers to an excess dose by preventing personnel access to an area when a high radiation level is present. These interlock the process access directly.

Airborne contamination monitors measure the concentration of radioactive particles in the ambient air to guard against radioactive particles being ingested, or deposited in the lungs of personnel. These instruments will normally give a local alarm, but are often connected to an integrated safety system so that areas of plant can be evacuated and personnel are prevented from entering an air of high airborne contamination.

Personnel exit monitors (PEM) are used to monitor workers who are exiting a "contamination controlled" or potentially contaminated area. These can be in the form of hand monitors, clothing frisk probes, or whole body monitors. These monitor the surface of the workers body and clothing to check if any radioactive contamination has been deposited. These generally measure alpha or beta or gamma, or combinations of these. 

The UK National Physical Laboratory publishes a good practice guide through its Ionising Radiation Metrology Forum concerning the provision of such equipment and the methodology of calculating the alarm levels to be used.

Portable instruments

Hand-held ion chamber survey meter in use for surface dose rate on one of three radioisotope thermoelectric generators (RTGs) for the Cassini spacecraft.

Portable instruments are hand-held or transportable. The hand-held instrument is generally used as a survey meter to check an object or person in detail, or assess an area where no installed instrumentation exists. They can also be used for personnel exit monitoring or personnel contamination checks in the field. These generally measure alpha, beta or gamma, or combinations of these.

Transportable instruments are generally instruments that would have been permanently installed, but are temporarily placed in an area to provide continuous monitoring where it is likely there will be a hazard. Such instruments are often installed on trolleys to allow easy deployment, and are associated with temporary operational situations.

In the United Kingdom the HSE has issued a user guidance note on selecting the correct radiation measurement instrument for the application concerned. This covers all radiation instrument technologies, and is a useful comparative guide.

Instrument types

A number of commonly used detection instrument types are listed below, and are used for both fixed and survey monitoring.
The links should be followed for a fuller description of each.

Radiation related quantities

The following table shows the main radiation related quantities and units. 

Ionising radiation related quantities
Quantity Unit Symbol Derivation Year SI equivalence
Activity (A) curie Ci 3.7 × 1010 s−1 1953 3.7×1010 Bq
becquerel Bq s−1 1974 SI unit
rutherford Rd 106 s−1 1946 1,000,000 Bq
Exposure (X) röntgen R esu / 0.001293 g of air 1928 2.58 × 10−4 C/kg
Absorbed dose (D) erg
erg⋅g−1 1950 1.0 × 10−4 Gy
rad rad 100 erg⋅g−1 1953 0.010 Gy
gray Gy J⋅kg−1 1974 SI unit
Dose equivalent (H) röntgen equivalent man rem 100 erg⋅g−1 1971 0.010 Sv
sievert Sv J⋅kg−1 × WR 1977 SI unit

Spacecraft radiation challenges

Spacecraft, both manned and unmanned, must cope with the high radiation environment of outerspace. Radiation emitted by the Sun and other galactic sources, and trapped in radiation "belts" is more dangerous and hundreds of times more intense than radiation sources such as medical X-rays or normal cosmic radiation usually experienced on Earth. When the intensely ionizing particles found in space strike human tissue, it can result in cell damage and may eventually lead to cancer.

The usual method for radiation protection is material shielding by spacecraft and equipment structures (usually aluminium), possibly augmented by polyethylene in human spaceflight where the main concern is high energy protons and cosmic ray ions. On unmanned spacecraft in high electron dose environments such as Jupiter missions, or medium Earth orbit (MEO), additional shielding with materials of a high atomic number can be effective. On long duration manned missions, advantage can be taken of the good shielding characteristics of liquid hydrogen fuel and water. 

The NASA Space Radiation Laboratory makes use of a particle accelerator that produces beams of protons or heavy ions. These ions are typical of those accelerated in cosmic sources and by the Sun. The beams of ions move through a 100-meter (328-foot) transport tunnel to the 37-square-meter (400-square-foot) shielded target hall. There, they hit the target, which may be a biological sample or shielding material. In a 2002 NASA study, it was determined that materials that have high hydrogen contents, such as polyethylene, can reduce primary and secondary radiation to a greater extent than metals, such as aluminum. The problem with this "passive shielding" method is that radiation interactions in the material generate secondary radiation.

Active Shielding, that is, using magnets, high voltages, or artificial magnetospheres to slow down or deflect radiation, has been considered to potentially combat radiation in a feasible way. So far, the cost of equipment, power and weight of active shielding equipment outweigh their benefits. For example, active radiation equipment would need a habitable volume size to house it, and magnetic and electrostatic configurations often are not homogenous in intensity, allowing high-energy particles to penetrate the magnetic and electric fields from low-intensity parts, like cusps in dipolar magnetic field of Earth. As of 2012, NASA is undergoing research in superconducting magnetic architecture for potential active shielding applications.

Early radiation dangers

Using early Crookes tube X-Ray apparatus in 1896. One man is viewing his hand with a fluoroscope to optimise tube emissions, the other has his head close to the tube. No precautions are being taken.
 
Monument to the X-ray and Radium Martyrs of All Nations erected 1936 at St. Georg hospital in Hamburg, commemorating 359 early radiology workers.
 
The dangers of radioactivity and radiation were not immediately recognized. The discovery of x‑rays in 1895 led to widespread experimentation by scientists, physicians, and inventors. Many people began recounting stories of burns, hair loss and worse in technical journals as early as 1896. In February of that year, Professor Daniel and Dr. Dudley of Vanderbilt University performed an experiment involving x-raying Dudley's head that resulted in his hair loss. A report by Dr. H.D. Hawks, a graduate of Columbia College, of his suffering severe hand and chest burns in an x-ray demonstration, was the first of many other reports in Electrical Review.

Many experimenters including Elihu Thomson at Thomas Edison's lab, William J. Morton, and Nikola Tesla also reported burns. Elihu Thomson deliberately exposed a finger to an x-ray tube over a period of time and suffered pain, swelling, and blistering. Other effects, including ultraviolet rays and ozone were sometimes blamed for the damage. Many physicists claimed that there were no effects from x-ray exposure at all.

As early as 1902 William Herbert Rollins wrote almost despairingly that his warnings about the dangers involved in careless use of x-rays was not being heeded, either by industry or by his colleagues. By this time Rollins had proved that x-rays could kill experimental animals, could cause a pregnant guinea pig to abort, and that they could kill a fetus. He also stressed that "animals vary in susceptibility to the external action of X-light" and warned that these differences be considered when patients were treated by means of x-rays.

Before the biological effects of radiation were known, many physicists and corporations began marketing radioactive substances as patent medicine in the form of glow-in-the-dark pigments. Examples were radium enema treatments, and radium-containing waters to be drunk as tonics. Marie Curie protested against this sort of treatment, warning that the effects of radiation on the human body were not well understood. Curie later died from aplastic anaemia, likely caused by exposure to ionizing radiation. By the 1930s, after a number of cases of bone necrosis and death of radium treatment enthusiasts, radium-containing medicinal products had been largely removed from the market (radioactive quackery).

Alpha particle

From Wikipedia, the free encyclopedia

Alpha particle
Alpha Decay.svg
Composition2 protons, 2 neutrons
StatisticsBosonic
Symbolα, α2+, He2+
Mass6.644657230(82)×10−27 kg 4.001506179127(63) u
3.727379378(23) GeV/c2
Electric charge+2 e
Spin0

Alpha particles, also called alpha ray or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be produced in other ways. Alpha particles are named after the first letter in the Greek alphabet, α. The symbol for the alpha particle is α or α2+. Because they are identical to helium nuclei, they are also sometimes written as He2+ or 4
2
He2+
indicating a helium ion with a +2 charge (missing its two electrons). If the ion gains electrons from its environment, the alpha particle becomes a normal (electrically neutral) helium atom 4
2
He
.

Alpha particles, like helium nuclei, have a net spin of zero. Due to the mechanism of their production in standard alpha radioactive decay, alpha particles generally have a kinetic energy of about 5 MeV, and a velocity in the vicinity of 5% the speed of light. (See discussion below for the limits of these figures in alpha decay.) They are a highly ionizing form of particle radiation, and (when resulting from radioactive alpha decay) have low penetration depth. They can be stopped by a few centimeters of air, or by the skin.

However, so-called long range alpha particles from ternary fission are three times as energetic, and penetrate three times as far. As noted, the helium nuclei that form 10–12% of cosmic rays are also usually of much higher energy than those produced by nuclear decay processes, and are thus capable of being highly penetrating and able to traverse the human body and also many meters of dense solid shielding, depending on their energy. To a lesser extent, this is also true of very high-energy helium nuclei produced by particle accelerators.

When alpha particle emitting isotopes are ingested, they are far more dangerous than their half-life or decay rate would suggest, due to the high relative biological effectiveness of alpha radiation to cause biological damage. Alpha radiation is an average of about 20 times more dangerous, and in experiments with inhaled alpha emitters, up to 1000 times more dangerous than an equivalent activity of beta emitting or gamma emitting radioisotopes.

Name

Some science authors use doubly ionized helium nuclei (He2+) and alpha particles as interchangeable terms. The nomenclature is not well defined, and thus not all high-velocity helium nuclei are considered by all authors to be alpha particles. As with beta and gamma particles/rays, the name used for the particle carries some mild connotations about its production process and energy, but these are not rigorously applied. Thus, alpha particles may be loosely used as a term when referring to stellar helium nuclei reactions (for example the alpha processes), and even when they occur as components of cosmic rays. A higher energy version of alphas than produced in alpha decay is a common product of an uncommon nuclear fission result called ternary fission. However, helium nuclei produced by particle accelerators (cyclotrons, synchrotrons, and the like) are less likely to be referred to as "alpha particles".

Sources of alpha particles

Alpha decay

A physicist observes alpha particles from the decay of a polonium source in a cloud chamber
 
Alpha radiation detected in an isopropanol cloud chamber (after injection of an artificial source radon-220).

The best-known source of alpha particles is alpha decay of heavier (more than 106 u atomic weight) atoms. When an atom emits an alpha particle in alpha decay, the atom's mass number decreases by four due to the loss of the four nucleons in the alpha particle. The atomic number of the atom goes down by exactly two, as a result of the loss of two protons – the atom becomes a new element. Examples of this sort of nuclear transmutation are when uranium becomes thorium, or radium becomes radon gas, due to alpha decay. 

Alpha particles are commonly emitted by all of the larger radioactive nuclei such as uranium, thorium, actinium, and radium, as well as the transuranic elements. Unlike other types of decay, alpha decay as a process must have a minimum-size atomic nucleus that can support it. The smallest nuclei that have to date been found to be capable of alpha emission are beryllium-8 and the lightest nuclides of tellurium (element 52), with mass numbers between 104 and 109. The process of alpha decay sometimes leaves the nucleus in an excited state, wherein the emission of a gamma ray then removes the excess energy.

Mechanism of production in alpha decay

In contrast to beta decay, the fundamental interactions responsible for alpha decay are a balance between the electromagnetic force and nuclear force. Alpha decay results from the Coulomb repulsion between the alpha particle and the rest of the nucleus, which both have a positive electric charge, but which is kept in check by the nuclear force. In classical physics, alpha particles do not have enough energy to escape the potential well from the strong force inside the nucleus (this well involves escaping the strong force to go up one side of the well, which is followed by the electromagnetic force causing a repulsive push-off down the other side). 

However, the quantum tunnelling effect allows alphas to escape even though they do not have enough energy to overcome the nuclear force. This is allowed by the wave nature of matter, which allows the alpha particle to spend some of its time in a region so far from the nucleus that the potential from the repulsive electromagnetic force has fully compensated for the attraction of the nuclear force. From this point, alpha particles can escape, and in quantum mechanics, after a certain time, they do so.

Ternary fission

Especially energetic alpha particles deriving from a nuclear process are produced in the relatively rare (one in a few hundred) nuclear fission process of ternary fission. In this process, three charged particles are produced from the event instead of the normal two, with the smallest of the charged particles most probably (90% probability) being an alpha particle. Such alpha particles are termed "long range alphas" since at their typical energy of 16 MeV, they are at far higher energy than is ever produced by alpha decay. Ternary fission happens in both neutron-induced fission (the nuclear reaction that happens in a nuclear reactor), and also when fissionable and fissile actinides nuclides (i.e., heavy atoms capable of fission) undergo spontaneous fission as a form of radioactive decay. In both induced and spontaneous fission, the higher energies available in heavy nuclei result in long range alphas of higher energy than those from alpha decay.

Accelerators

Energetic helium nuclei may be produced by cyclotrons, synchrotrons, and other particle accelerators, but they are not normally referred to as "alpha particles."

Solar core reactions

As noted, helium nuclei may participate in nuclear reactions in stars, and occasionally and historically these have been referred to as alpha reactions.

Cosmic rays

In addition, extremely high energy helium nuclei sometimes referred to as alpha particles make up about 10 to 12% of cosmic rays. The mechanisms of cosmic ray production continue to be debated.

Energy and absorption

The energy of the alpha emitted in alpha decay is mildly dependent on the half-life for the emission process, with many orders of magnitude differences in half-life being associated with energy changes of less than 50%.

The energy of alpha particles emitted varies, with higher energy alpha particles being emitted from larger nuclei, but most alpha particles have energies of between 3 and 7 MeV (mega-electron-volts), corresponding to extremely long and extremely short half-lives of alpha-emitting nuclides, respectively.

This energy is a substantial amount of energy for a single particle, but their high mass means alpha particles have a lower speed (with a typical kinetic energy of 5 MeV; the speed is 15,000 km/s, which is 5% of the speed of light) than any other common type of radiation (β particles, neutrons, etc.) Because of their charge and large mass, alpha particles are easily absorbed by materials, and they can travel only a few centimetres in air. They can be absorbed by tissue paper or the outer layers of human skin (about 40 micrometres, equivalent to a few cells deep).

Biological effects

Due to the short range of absorption and inability to penetrate the outer layers of skin, alpha particles are not, in general, dangerous to life unless the source is ingested or inhaled. Because of this high mass and strong absorption, if alpha-emitting radionuclides do enter the body (upon being inhaled, ingested, or injected, as with the use of Thorotrast for high-quality X-ray images prior to the 1950s), alpha radiation is the most destructive form of ionizing radiation. It is the most strongly ionizing, and with large enough doses can cause any or all of the symptoms of radiation poisoning. It is estimated that chromosome damage from alpha particles is anywhere from 10 to 1000 times greater than that caused by an equivalent amount of gamma or beta radiation, with the average being set at 20 times. A study of European nuclear workers exposed internally to alpha radiation from plutonium and uranium found that when relative biological effectiveness is considered to be 20, the carcinogenic potential (in terms of lung cancer) of alpha radiation appears to be consistent with that reported for doses of external gamma radiation i.e. a given dose of alpha-particles inhaled presents the same risk as a 20-times higher dose of gamma radiation. The powerful alpha emitter polonium-210 (a milligram of 210Po emits as many alpha particles per second as 4.215 grams of 226Ra) is suspected of playing a role in lung cancer and bladder cancer related to tobacco smoking. 210Po was used to kill Russian dissident and ex-FSB officer Alexander V. Litvinenko in 2006.

History of discovery and use

Alpha radiation consists of helium-4 nucleus and is readily stopped by a sheet of paper. Beta radiation, consisting of electrons, is halted by an aluminium plate. Gamma radiation is eventually absorbed as it penetrates a dense material. Lead is good at absorbing gamma radiation, due to its density.
 
An alpha particle is deflected by a magnetic field
 
Dispersing of alpha particles on a thin metal sheet
 
In the years 1899 and 1900, physicists Ernest Rutherford (working in McGill University in Montreal, Canada) and Paul Villard (working in Paris) separated radiation into three types: eventually named alpha, beta, and gamma by Rutherford, based on penetration of objects and deflection by a magnetic field. Alpha rays were defined by Rutherford as those having the lowest penetration of ordinary objects. 

Rutherford's work also included measurements of the ratio of an alpha particle's mass to its charge, which led him to the hypothesis that alpha particles were doubly charged helium ions (later shown to be bare helium nuclei). In 1907, Ernest Rutherford and Thomas Royds finally proved that alpha particles were indeed helium ions. To do this they allowed alpha particles to penetrate a very thin glass wall of an evacuated tube, thus capturing a large number of the hypothesized helium ions inside the tube. They then caused an electric spark inside the tube, which provided a shower of electrons that were taken up by the ions to form neutral atoms of a gas. Subsequent study of the spectra of the resulting gas showed that it was helium and that the alpha particles were indeed the hypothesized helium ions.

Because alpha particles occur naturally, but can have energy high enough to participate in a nuclear reaction, study of them led to much early knowledge of nuclear physics. Rutherford used alpha particles emitted by radium bromide to infer that J. J. Thomson's Plum pudding model of the atom was fundamentally flawed. In Rutherford's gold foil experiment conducted by his students Hans Geiger and Ernest Marsden, a narrow beam of alpha particles was established, passing through very thin (a few hundred atoms thick) gold foil. The alpha particles were detected by a zinc sulfide screen, which emits a flash of light upon an alpha particle collision. Rutherford hypothesized that, assuming the "plum pudding" model of the atom was correct, the positively charged alpha particles would be only slightly deflected, if at all, by the dispersed positive charge predicted.

It was found that some of the alpha particles were deflected at much larger angles than expected (at a suggestion by Rutherford to check it) and some even bounced almost directly back. Although most of the alpha particles went straight through as expected, Rutherford commented that the few particles that were deflected was akin to shooting a fifteen-inch shell at tissue paper only to have it bounce off, again assuming the "plum pudding" theory was correct. It was determined that the atom's positive charge was concentrated in a small area in its center, making the positive charge dense enough to deflect any positively charged alpha particles that came close to what was later termed the nucleus.
Prior to this discovery, it was not known that alpha particles were themselves atomic nuclei, nor was the existence of protons or neutrons known. After this discovery, J.J. Thomson's "plum pudding" model was abandoned, and Rutherford's experiment led to the Bohr model (named for Niels Bohr) and later the modern wave-mechanical model of the atom. 

Energy-loss (Bragg curve) in air for typical alpha particle emitted through radioactive decay.
 
The trace of a single alpha particle obtained by nuclear physicist Wolfhart Willimczik with his spark chamber specially made for alpha particles.
 
Rutherford went on to use alpha particles to accidentally produce what he later understood as a directed nuclear transmutation of one element to another, in 1917. Transmutation of elements from one to another had been understood since 1901 as a result of natural radioactive decay, but when Rutherford projected alpha particles from alpha decay into air, he discovered this produced a new type of radiation which proved to be hydrogen nuclei (Rutherford named these protons). Further experimentation showed the protons to be coming from the nitrogen component of air, and the reaction was deduced to be a transmutation of nitrogen into oxygen in the reaction
14N + α → 17O + p 
This was the first-discovered nuclear reaction

To the adjacent pictures: According to the energy-loss curve by Bragg it is recognizable that the alpha particle indeed loses more energy on the end of the trace.

Anti-alpha particle

In 2011, members of the international STAR collaboration using the Relativistic Heavy Ion Collider at the U.S. Department of Energy's Brookhaven National Laboratory detected the antimatter partner of the helium nucleus, also known as the anti-alpha. The experiment used gold ions moving at nearly the speed of light and colliding head on to produce the antiparticle.

Applications

  • Some smoke detectors contain a small amount of the alpha emitter americium-241. The alpha particles ionize air within a small gap. A small current is passed through that ionized air. Smoke particles from fire that enter the air gap reduce the current flow, sounding the alarm. The isotope is extremely dangerous if inhaled or ingested, but the danger is minimal if the source is kept sealed. Many municipalities have established programs to collect and dispose of old smoke detectors, to keep them out of the general waste stream.
  • Alpha decay can provide a safe power source for radioisotope thermoelectric generators used for space probes and artificial heart pacemakers. Alpha decay is much more easily shielded against than other forms of radioactive decay. Plutonium-238, a source of alpha particles, requires only 2.5 mm of lead shielding to protect against unwanted radiation.
  • Static eliminators typically use polonium-210, an alpha emitter, to ionize air, allowing the "static cling" to more rapidly dissipate.
  • Researchers are currently trying to use the damaging nature of alpha emitting radionuclides inside the body by directing small amounts towards a tumor. The alphas damage the tumor and stop its growth, while their small penetration depth prevents radiation damage of the surrounding healthy tissue. This type of cancer therapy is called unsealed source radiotherapy.

Alpha radiation and DRAM errors

In computer technology, dynamic random access memory (DRAM) "soft errors" were linked to alpha particles in 1978 in Intel's DRAM chips. The discovery led to strict control of radioactive elements in the packaging of semiconductor materials, and the problem is largely considered to be solved.

Operator (computer programming)

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