Water resources

From Wikipedia, the free encyclopedia

This article is about all types of waters that are of potential use to humans. For a naturally occurring type of water resource that humans use a lot, see fresh water.

Water resources are natural resources of water that are potentially useful for humans, for example as a source of drinking water supply or irrigation water. 97% of the water on Earth is salt water and only three percent is fresh water; slightly over two-thirds of this is frozen in glaciers and polar ice caps. The remaining unfrozen freshwater is found mainly as groundwater, with only a small fraction present above ground or in the air. Natural sources of fresh water include surface water, under river flow, groundwater and frozen water. Non-natural or human-made sources of fresh water can include wastewater that has been treated for reuse options, and desalinated seawater. People use water resources for agricultural, industrial and household activities.

Water resources are under threat from multiple issues. There is water scarcity, water pollution, water conflict and climate change. Fresh water is in principle a renewable resource. However, the world's supply of groundwater is steadily decreasing. Groundwater depletion (or overdrafting) is occurring for example in Asia, South America and North America.

Natural sources of fresh water

Further information: Water distribution on Earth

Distribution of Freshwater Resources by Type

  Glaciers (69%)

  Groundwater (30%)

  Other Freshwater (e.g., Soil Moisture) (0.7%)

  Directly Accessible Water (0.3%)

Natural sources of fresh water include surface water, under river flow, groundwater and frozen water.

Surface water

Main article: Surface water

Lake Chungará and Parinacota volcano in northern Chile

Surface water is water in a river, lake or fresh water wetland. Surface water is naturally replenished by precipitation and naturally lost through discharge to the oceans, evaporation, evapotranspiration and groundwater recharge. The only natural input to any surface water system is precipitation within its watershed. The total quantity of water in that system at any given time is also dependent on many other factors. These factors include storage capacity in lakes, wetlands and artificial reservoirs, the permeability of the soil beneath these storage bodies, the runoff characteristics of the land in the watershed, the timing of the precipitation and local evaporation rates. All of these factors also affect the proportions of water loss.

Humans often increase storage capacity by constructing reservoirs and decrease it by draining wetlands. Humans often increase runoff quantities and velocities by paving areas and channelizing the stream flow.

Natural surface water can be augmented by importing surface water from another watershed through a canal or pipeline.

Brazil is estimated to have the largest supply of fresh water in the world, followed by Russia and Canada.

• 
  Panorama of a natural wetland (Sinclair Wetlands, New Zealand)

Water from glaciers

Glacier runoff is considered to be surface water. The Himalayas, which are often called "The Roof of the World", contain some of the most extensive and rough high altitude areas on Earth as well as the greatest area of glaciers and permafrost outside of the poles. Ten of Asia's largest rivers flow from there, and more than a billion people's livelihoods depend on them. To complicate matters, temperatures there are rising more rapidly than the global average. In Nepal, the temperature has risen by 0.6 degrees Celsius over the last decade, whereas globally, the Earth has warmed approximately 0.7 degrees Celsius over the last hundred years.

Groundwater

Relative groundwater travel times in the subsurface

Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidated deposit is called an aquifer when it can yield a usable quantity of water. The depth at which soil pore spaces or fractures and voids in rock become completely saturated with water is called the water table. Groundwater is recharged from the surface; it may discharge from the surface naturally at springs and seeps, and can form oases or wetlands. Groundwater is also often withdrawn for agricultural, municipal, and industrial use by constructing and operating extraction wells. The study of the distribution and movement of groundwater is hydrogeology, also called groundwater hydrology.

Typically, groundwater is thought of as water flowing through shallow aquifers, but, in the technical sense, it can also contain soil moisture, permafrost (frozen soil), immobile water in very low permeability bedrock, and deep geothermal or oil formation water. Groundwater is hypothesized to provide lubrication that can possibly influence the movement of faults. It is likely that much of Earth's subsurface contains some water, which may be mixed with other fluids in some instances.

Under river flow

Throughout the course of a river, the total volume of water transported downstream will often be a combination of the visible free water flow together with a substantial contribution flowing through rocks and sediments that underlie the river and its floodplain called the hyporheic zone. For many rivers in large valleys, this unseen component of flow may greatly exceed the visible flow. The hyporheic zone often forms a dynamic interface between surface water and groundwater from aquifers, exchanging flow between rivers and aquifers that may be fully charged or depleted. This is especially significant in karst areas where pot-holes and underground rivers are common.

Artificial sources of usable water

There are several artificial sources of fresh water. One is treated wastewater (reclaimed water). Another is atmospheric water generators.^[8][9][10] Desalinated seawater is another important source. It is important to consider the economic and environmental side effects of these technologies.

Wastewater reuse

Water reclamation is the process of converting municipal wastewater or sewage and industrial wastewater into water that can be reused for a variety of purposes . It is also called wastewater reuse, water reuse or water recycling. There are many types of reuse. It is possible to reuse water in this way in cities or for irrigation in agriculture. Other types of reuse are environmental reuse, industrial reuse, and reuse for drinking water, whether planned or not. Reuse may include irrigation of gardens and agricultural fields or replenishing surface water and groundwater. This latter is also known as groundwater recharge. Reused water also serve various needs in residences such as toilet flushing, businesses, and industry. It is possible to treat wastewater to reach drinking water standards. Injecting reclaimed water into the water supply distribution system is known as direct potable reuse. Drinking reclaimed water is not typical. Reusing treated municipal wastewater for irrigation is a long-established practice. This is especially so in arid countries. Reusing wastewater as part of sustainable water management allows water to remain an alternative water source for human activities. This can reduce scarcity. It also eases pressures on groundwater and other natural water bodies.

There are several technologies used to treat wastewater for reuse. A combination of these technologies can meet strict treatment standards and make sure that the processed water is hygienically safe, meaning free from pathogens. The following are some of the typical technologies: Ozonation, ultrafiltration, aerobic treatment (membrane bioreactor), forward osmosis, reverse osmosis, and advanced oxidation, or activated carbon. Some water-demanding activities do not require high grade water. In this case, wastewater can be reused with little or no treatment.

Desalinated water

Desalination is a process that removes mineral components from saline water. More generally, desalination is the removal of salts and minerals from a substance. One example is soil desalination. This is important for agriculture. It is possible to desalinate saltwater, especially sea water, to produce water for human consumption or irrigation. The by-product of the desalination process is brine. Many seagoing ships and submarines use desalination. Modern interest in desalination mostly focuses on cost-effective provision of fresh water for human use. Along with recycled wastewater, it is one of the few water resources independent of rainfall.

Due to its energy consumption, desalinating sea water is generally more costly than fresh water from surface water or groundwater, water recycling and water conservation; however, these alternatives are not always available and depletion of reserves is a critical problem worldwide. Desalination processes are using either thermal methods (in the case of distillation) or membrane-based methods (e.g. in the case of reverse osmosis) energy types.

Research into other options

Air-capture over oceans

Schematic illustration of a proposed approach for capturing moisture above the ocean surface and transporting it to proximal land for improving water security

Map of water stress and spatial variability of water yield along the delineated near-offshore region of 200 km across the world

Researchers proposed "significantly increasing freshwater through the capture of humid air over oceans" to address present and, especially, future water scarcity/insecurity.

Atmospheric water generators on land

Further information: Atmospheric water generator

A potentials-assessment study proposed hypothetical portable solar-powered atmospheric water harvesting devices which are under development, along with design criteria, finding they could help a billion people to access safe drinking water, albeit such off-the-grid generation may sometimes "undermine efforts to develop permanent piped infrastructure" among other problems.

Water uses

Total renewable freshwater resources of the world, in mm/year (1 mm is equivalent to 1 L of water per m²) (long-term average for the years 1961–1990). Resolution is 0.5° longitude x 0.5° latitude (equivalent to 55 km x 55 km at the equator). Computed by the global freshwater model WaterGAP.

The total quantity of water available at any given time is an important consideration. Some human water users have an intermittent need for water. For example, many farms require large quantities of water in the spring, and no water at all in the winter. Other users have a continuous need for water, such as a power plant that requires water for cooling. Over the long term the average rate of precipitation within a watershed is the upper bound for average consumption of natural surface water from that watershed.

Agriculture and other irrigation

Further information: Sustainable Water and Innovative Irrigation Management

Irrigation of agricultural fields in Andalusia, Spain. Irrigation canal on the left.

Irrigation (also referred to as watering of plants) is the practice of applying controlled amounts of water to land to help grow crops, landscape plants, and lawns. Irrigation has been a key aspect of agriculture for over 5,000 years and has been developed by many cultures around the world. Irrigation helps to grow crops, maintain landscapes, and revegetate disturbed soils in dry areas and during times of below-average rainfall. In addition to these uses, irrigation is also employed to protect crops from frost, suppress weed growth in grain fields, and prevent soil consolidation. It is also used to cool livestock, reduce dust, dispose of sewage, and support mining operations. Drainage, which involves the removal of surface and sub-surface water from a given location, is often studied in conjunction with irrigation.

There are several methods of irrigation that differ in how water is supplied to plants. Surface irrigation, also known as gravity irrigation, is the oldest form of irrigation and has been in use for thousands of years. In sprinkler irrigation, water is piped to one or more central locations within the field and distributed by overhead high-pressure water devices. Micro-irrigation is a system that distributes water under low pressure through a piped network and applies it as a small discharge to each plant. Micro-irrigation uses less pressure and water flow than sprinkler irrigation. Drip irrigation delivers water directly to the root zone of plants. Subirrigation has been used in field crops in areas with high water tables for many years. It involves artificially raising the water table to moisten the soil below the root zone of plants.

Irrigation water can come from groundwater (extracted from springs or by using wells), from surface water (withdrawn from rivers, lakes or reservoirs) or from non-conventional sources like treated wastewater, desalinated water, drainage water, or fog collection. Irrigation can be supplementary to rainfall, which is common in many parts of the world as rainfed agriculture, or it can be full irrigation, where crops rarely rely on any contribution from rainfall. Full irrigation is less common and only occurs in arid landscapes with very low rainfall or when crops are grown in semi-arid areas outside of rainy seasons.

Industries

See also: Industrial water treatment and Industrial wastewater treatment

It is estimated that 22% of worldwide water is used in industry. Major industrial users include hydroelectric dams, thermoelectric power plants, which use water for cooling, ore and oil refineries, which use water in chemical processes, and manufacturing plants, which use water as a solvent. Water withdrawal can be very high for certain industries, but consumption is generally much lower than that of agriculture.

Water is used in renewable power generation. Hydroelectric power derives energy from the force of water flowing downhill, driving a turbine connected to a generator. This hydroelectricity is a low-cost, non-polluting, renewable energy source. Significantly, hydroelectric power can also be used for load following unlike most renewable energy sources which are intermittent. Ultimately, the energy in a hydroelectric power plant is supplied by the sun. Heat from the sun evaporates water, which condenses as rain in higher altitudes and flows downhill. Pumped-storage hydroelectric plants also exist, which use grid electricity to pump water uphill when demand is low, and use the stored water to produce electricity when demand is high.

Thermoelectric power plants using cooling towers have high consumption, nearly equal to their withdrawal, as most of the withdrawn water is evaporated as part of the cooling process. The withdrawal, however, is lower than in once-through cooling systems.

Water is also used in many large scale industrial processes, such as thermoelectric power production, oil refining, fertilizer production and other chemical plant use, and natural gas extraction from shale rock. Discharge of untreated water from industrial uses is pollution. Pollution includes discharged solutes and increased water temperature (thermal pollution).

Drinking water and domestic use (households)

Main articles: Water supply, Drinking water, and Water footprint

Drinking water

It is estimated that 8% of worldwide water use is for domestic purposes. These include drinking water, bathing, cooking, toilet flushing, cleaning, laundry and gardening. Basic domestic water requirements have been estimated by Peter Gleick at around 50 liters per person per day, excluding water for gardens.

Drinking water is water that is of sufficiently high quality so that it can be consumed or used without risk of immediate or long term harm. Such water is commonly called potable water. In most developed countries, the water supplied to domestic, commerce and industry is all of drinking water standard even though only a very small proportion is actually consumed or used in food preparation.

844 million people still lacked even a basic drinking water service in 2017. Of those, 159 million people worldwide drink water directly from surface water sources, such as lakes and streams. One in eight people in the world do not have access to safe water.

Challenges and threats

Water scarcity

Water scarcity (closely related to water stress or water crisis) is the lack of fresh water resources to meet the standard water demand. There are two type of water scarcity. One is physical. The other is economic water scarcity. Physical water scarcity is where there is not enough water to meet all demands. This includes water needed for ecosystems to function. Regions with a desert climate often face physical water scarcity. Central Asia, West Asia, and North Africa are examples of arid areas. Economic water scarcity results from a lack of investment in infrastructure or technology to draw water from rivers, aquifers, or other water sources. It also results from weak human capacity to meet water demand. Many people in Sub-Saharan Africa are living with economic water scarcity.

Water pollution

Polluted water

Water pollution (or aquatic pollution) is the contamination of water bodies, with a negative impact on their uses. It is usually a result of human activities. Water bodies include lakes, rivers, oceans, aquifers, reservoirs and groundwater. Water pollution results when contaminants mix with these water bodies. Contaminants can come from one of four main sources. These are sewage discharges, industrial activities, agricultural activities, and urban runoff including stormwater. Water pollution may affect either surface water or groundwater. This form of pollution can lead to many problems. One is the degradation of aquatic ecosystems. Another is spreading water-borne diseases when people use polluted water for drinking or irrigation. Water pollution also reduces the ecosystem services such as drinking water provided by the water resource.

Water conflict

Water conflict typically refers to violence or disputes associated with access to, or control of, water resources, or the use of water or water systems as weapons or casualties of conflicts. The term water war is colloquially used in media for some disputes over water, and often is more limited to describing a conflict between countries, states, or groups over the rights to access water resources. The United Nations recognizes that water disputes result from opposing interests of water users, public or private. A wide range of water conflicts appear throughout history, though they are rarely traditional wars waged over water alone. Instead, water has long been a source of tension and one of the causes for conflicts. Water conflicts arise for several reasons, including territorial disputes, a fight for resources, and strategic advantage.

Climate change

Impacts of climate change that are tied to water, affect people's water security on a daily basis. They include more frequent and intense heavy precipitation which affects the frequency, size and timing of floods. Also droughts can alter the total amount of freshwater and cause a decline in groundwater storage, and reduction in groundwater recharge. Reduction in water quality due to extreme events can also occur. Faster melting of glaciers can also occur.

Groundwater overdrafting

The world's supply of groundwater is steadily decreasing. Groundwater depletion (or overdrafting) is occurring for example in Asia, South America and North America. It is still unclear how much natural renewal balances this usage, and whether ecosystems are threatened.

Within a long period of groundwater depletion in California's Central Valley, short periods of recovery were mostly driven by extreme weather events that typically caused flooding and had negative social, environmental and economic consequences.

Overdrafting is the process of extracting groundwater beyond the equilibrium yield of an aquifer. Groundwater is one of the largest sources of fresh water and is found underground. The primary cause of groundwater depletion is the excessive pumping of groundwater up from underground aquifers. Insufficient recharge can lead to depletion, reducing the usefulness of the aquifer for humans. Depletion can also have impacts on the environment around the aquifer, such as soil compression and land subsidence, local climatic change, soil chemistry changes, and other deterioration of the local environment.

Water resource management

Further information: Water resources law

Global values of water resources and human water use (excluding Antarctica). Water resources 1961-90, water use around 2000. Computed by the global freshwater model WaterGAP.

Water resource management is the activity of planning, developing, distributing and managing the optimum use of water resources. It is an aspect of water cycle management. The field of water resources management will have to continue to adapt to the current and future issues facing the allocation of water. With the growing uncertainties of global climate change and the long-term impacts of past management actions, this decision-making will be even more difficult. It is likely that ongoing climate change will lead to situations that have not been encountered. As a result, alternative management strategies, including participatory approaches and adaptive capacity are increasingly being used to strengthen water decision-making.

Ideally, water resource management planning has regard to all the competing demands for water and seeks to allocate water on an equitable basis to satisfy all uses and demands. As with other resource management, this is rarely possible in practice so decision-makers must prioritise issues of sustainability, equity and factor optimisation (in that order!) to achieve acceptable outcomes. One of the biggest concerns for water-based resources in the future is the sustainability of the current and future water resource allocation.

Sustainable Development Goal 6 has a target related to water resources management: "Target 6.5: By 2030, implement integrated water resources management at all levels, including through transboundary cooperation as appropriate."

Sustainable water management

At present, only about 0.08 percent of all the world's fresh water is accessible. And there is ever-increasing demand for drinking, manufacturing, leisure and agriculture. Due to the small percentage of water available, optimizing the fresh water we have left from natural resources has been a growing challenge around the world.

Much effort in water resource management is directed at optimizing the use of water and in minimizing the environmental impact of water use on the natural environment. The observation of water as an integral part of the ecosystem is based on integrated water resources management, based on the 1992 Dublin Principles (see below).

Sustainable water management requires a holistic approach based on the principles of Integrated Water Resource Management, originally articulated in 1992 at the Dublin (January) and Rio (July) conferences. The four Dublin Principles, promulgated in the Dublin Statement are:

1. Fresh water is a finite and vulnerable resource, essential to sustain life, development and the environment;
2. Water development and management should be based on a participatory approach, involving users, planners and policy-makers at all levels;
3. Women play a central part in the provision, management and safeguarding of water;
4. Water has an economic value in all its competing uses and should be recognized as an economic good.

Implementation of these principles has guided reform of national water management law around the world since 1992.

Further challenges to sustainable and equitable water resources management include the fact that many water bodies are shared across boundaries which may be international (see water conflict) or intra-national (see Murray-Darling basin).

Integrated water resources management

Integrated water resources management (IWRM) has been defined by the Global Water Partnership (GWP) as "a process which promotes the coordinated development and management of water, land and related resources, in order to maximize the resultant economic and social welfare in an equitable manner without compromising the sustainability of vital ecosystems".

Some scholars say that IWRM is complementary to water security because water security is a goal or destination, whilst IWRM is the process necessary to achieve that goal.

IWRM is a paradigm that emerged at international conferences in the late 1900s and early 2000s, although participatory water management institutions have existed for centuries. Discussions on a holistic way of managing water resources began already in the 1950s leading up to the 1977 United Nations Water Conference. The development of IWRM was particularly recommended in the final statement of the ministers at the International Conference on Water and the Environment in 1992, known as the Dublin Statement. This concept aims to promote changes in practices which are considered fundamental to improved water resource management. IWRM was a topic of the second World Water Forum, which was attended by a more varied group of stakeholders than the preceding conferences and contributed to the creation of the GWP.

In the International Water Association definition, IWRM rests upon three principles that together act as the overall framework:

1. Social equity: ensuring equal access for all users (particularly marginalized and poorer user groups) to an adequate quantity and quality of water necessary to sustain human well-being.
2. Economic efficiency: bringing the greatest benefit to the greatest number of users possible with the available financial and water resources.
3. Ecological sustainability: requiring that aquatic ecosystems are acknowledged as users and that adequate allocation is made to sustain their natural functioning.

In 2002, the development of IWRM was discussed at the World Summit on Sustainable Development held in Johannesburg, which aimed to encourage the implementation of IWRM at a global level.^[58] The third World Water Forum recommended IWRM and discussed information sharing, stakeholder participation, and gender and class dynamics.

Operationally, IWRM approaches involve applying knowledge from various disciplines as well as the insights from diverse stakeholders to devise and implement efficient, equitable and sustainable solutions to water and development problems. As such, IWRM is a comprehensive, participatory planning and implementation tool for managing and developing water resources in a way that balances social and economic needs, and that ensures the protection of ecosystems for future generations. In addition, in light of contributing the achievement of Sustainable Development goals (SDGs),  IWRM has been evolving into more sustainable approach as it considers the Nexus approach, which is a cross-sectoral water resource management. The Nexus approach is based on the recognition that "water, energy and food are closely linked through global and local water, carbon and energy cycles or chains."

An IWRM approach aims at avoiding a fragmented approach of water resources management by considering the following aspects: Enabling environment, roles of Institutions, management Instruments. Some of the cross-cutting conditions that are also important to consider when implementing IWRM are: Political will and commitment, capacity development, adequate investment, financial stability and sustainable cost recovery, monitoring and evaluation. There is not one correct administrative model. The art of IWRM lies in selecting, adjusting and applying the right mix of these tools for a given situation. IWRM practices depend on context; at the operational level, the challenge is to translate the agreed principles into concrete action.

Managing water in urban settings

Typical urban water cycle depicting drinking water purification and municipal sewage treatment systems

Integrated urban water management (IUWM) is the practice of managing freshwater, wastewater, and storm water as components of a basin-wide management plan. It builds on existing water supply and sanitation considerations within an urban settlement by incorporating urban water management within the scope of the entire river basin. IUWM is commonly seen as a strategy for achieving the goals of Water Sensitive Urban Design. IUWM seeks to change the impact of urban development on the natural water cycle, based on the premise that by managing the urban water cycle as a whole; a more efficient use of resources can be achieved providing not only economic benefits but also improved social and environmental outcomes. One approach is to establish an inner, urban, water cycle loop through the implementation of reuse strategies. Developing this urban water cycle loop requires an understanding both of the natural, pre-development, water balance and the post-development water balance. Accounting for flows in the pre- and post-development systems is an important step toward limiting urban impacts on the natural water cycle.

IUWM within an urban water system can also be conducted by performance assessment of any new intervention strategies by developing a holistic approach which encompasses various system elements and criteria including sustainability type ones in which integration of water system components including water supply, waste water and storm water subsystems would be advantageous. Simulation of metabolism type flows in urban water system can also be useful for analysing processes in urban water cycle of IUWM.

Chemical waste

From Wikipedia, the free encyclopedia
https://en.wikipedia.org/wiki/Chemical_waste

Chemical waste is any excess, unused, or unwanted chemical. Chemical waste may be classified as hazardous waste, non-hazardous waste, universal waste, or household hazardous waste, each of which is regulated separately by national governments and the United Nations. Hazardous waste is material that displays one or more of the following four characteristics: ignitability, corrosivity, reactivity, and toxicity. This information, along with chemical disposal requirements, is typically available on a chemical's Safety Data Sheet (SDS). Radioactive and biohazardous wastes require additional or different methods of handling and disposal, and are often regulated differently than standard hazardous wastes.

Laboratory chemical waste in the US

The U.S. Environmental Protection Agency (EPA) prohibits disposing of certain materials down drains. Therefore, when hazardous chemical waste is generated in a laboratory setting, it is usually stored on-site in appropriate waste containers, such as triple-rinsed chemical storage containers or carboys, where it is later collected and disposed of in order to meet safety, health, and legislative requirements. Many universities' Environment, Health, and Safety (EHS) divisions/departments serve this collection and oversight role.

Organic solvents and other organic waste is typically incinerated. Some chemical wastes are recycled, such as waste elemental mercury.

Laboratory waste containment

Laboratory waste containers

Packaging

During packaging, chemical liquid waste containers are filled to no greater than 75% capacity to allow for vapor expansion and to reduce potential spills that can occur from transporting or moving overfilled containers. Containers for chemical liquid waste are typically constructed from materials compatible with the hazardous waste being stored, such as inert materials like polypropylene (PP) or polytetrafluoroethylene (PTFE). These containers are also constructed of mechanically robust materials in order to minimize leakage during storage or transit.

In addition to the general packaging requirements mentioned above, precipitates, solids, and other non-fluid wastes are typically stored separately from liquid waste. Chemically contaminated glassware is disposed of separately from other chemical waste in containers that cannot be punctured by broken glass.

Labelling

Containers may be labelled with the group name from a list of chemical waste categories, along with an itemized list of the contents. All chemicals or materials contaminated by chemicals pose a significant hazard, and as such regulations require that the identity of the chemicals in a waste container is obvious.

Storage

Chemical waste containers are kept closed to prevent spillage, except when waste is being added. Suitable containers are labeled in order to inform disposal specialists of the contents as well as to prevent the addition of incompatible chemicals. Liquid waste is stored in containers with secure screw-top or similar lids that cannot be easily dislodged in transit. Solid waste is stored in various sturdy, chemically inert containers, such as large, sealed buckets or thick plastic bags. Secondary containment, such as trays or safety cabinets, are used to capture spills and leaks from the primary container and to segregate incompatible hazardous wastes, such as acids and bases.

Chemical compatibility guidelines

Main article: Compatibility (chemical)

Many chemicals react adversely when combined. Incompatible chemicals are therefore stored in separate areas of laboratories.

Acids are separated from alkalis, metals, cyanides, sulfides, azides, phosphides, and oxidizers, as when acids combine with these types of compounds, violent exothermic reactions can occur. In addition, some of these reactions produce flammable gases, which, combined with the heat produced, may cause explosions. In the case of cyanides, sulfides, azides, phosphides, etc. Toxic gases are also produced.

Oxidizers are separated from acids, organic materials, metals, reducing agents, and ammonia, as when oxidizers combine with these types of compounds, flammable and sometimes toxic compounds can be created. Oxidizers also increase the likelihood that any flammable material present will ignite, seen most readily in research laboratories with improper storage of organic solvents.

Environmental pollution

Pharmaceuticals

Pharmaceuticals comprise one of the few groups of chemicals that are specifically designed to act on living cells. They present a special risk when they persist in the environment.

With the exception of watercourses downstream of sewage treatment plants, the concentration of pharmaceuticals in surface and ground water is generally low. Concentrations in sewage sludge and in landfill leachate may be substantially higher^[21] and provide alternative routes for EPPPs to enter the human and animal food-chain.

However, even at very low environmental concentrations (often ug/L or ng/L), the chronic exposure to environmental pharmaceuticals chemicals can add to the effects of other chemicals in the cocktail is still not studied. The different chemicals might be potentiating synergistic effects (higher than additive effects). An extremely sensitive group in this respect are foetuses.

EPPPs are already found in water all over the world. The diffuse exposure might contribute to

• extinction of species and imbalance of sensible ecosystems, as many EPPPs affect the reproductive systems of for example frogs, mussels, and fish;
• genetic, developmental, immune and hormonal health effects to humans and other species, in the same way as e.g. oestrogen-like chemicals;
• development of microbes resistant to antibiotics, as is found in India.

PPCPs

Further information on how pollutants enter the environment through the manufacturing of PPCPs: Industrial ecology

The use of pharmaceuticals and personal care products (PPCPs) is on the rise with an estimated increase from 2 billion to 3.9 billion annual prescriptions between 1999 and 2009 in the United States alone. PPCPs enter into the environment through individual human activity and as residues from manufacturing, agribusiness, veterinary use, and hospital and community use. In Europe, the input of pharmaceutical residues via domestic waste water is estimated to be around 80% whereas 20% is coming from hospitals. Individuals may add PPCPs to the environment through waste excretion and bathing as well as by directly disposing of unused medications to septic tanks, sewers, or trash. Because PPCPs tend to dissolve relatively easily and do not evaporate at normal temperatures, they often end up in soil and water bodies.

Some PPCPs are broken down or processed easily by a human or animal body and/or degrade quickly in the environment. However, others do not break down or degrade easily. The likelihood or ease with which an individual substance will break down depends on its chemical makeup and the metabolic pathway of the compound.

River pollution

In 2022, the most comprehensive study of pharmaceutical pollution of the world's rivers finds that it threatens "environmental and/or human health in more than a quarter of the studied locations". It investigated 1,052 sampling sites along 258 rivers in 104 countries, representing the river pollution of 470 million people. It found that "the most contaminated sites were in low- to middle-income countries and were associated with areas with poor wastewater and waste management infrastructure and pharmaceutical manufacturing" and lists the most frequently detected and concentrated pharmaceuticals.

Pharmaceutical pollution of the world's rivers by chemical and region

Textile industry

See also: Sustainable fashion, Supply Chain Act, Eco-tariff, and Environmental impact of fashion

Indigo color water pollution in Phnom Penh, Cambodia, 2005

The textile industry is one of the largest polluters in the globalized world of mostly free market dominated socioeconomic systems. Chemically polluted textile wastewater degrades the quality of the soil and water. The pollution comes from the type of conduct of chemical treatments used e.g., that many or most market-driven companies use despite "eco-friendly alternatives". Textile industry wastewater is considered to be one the largest polluters of water and soil ecosystems, causing "carcinogenic, mutagenic, genotoxic, cytotoxic and allergenic threats to living organisms". The textile industry uses over 8000 chemicals in its supply chain, also polluting the environment with large amounts of microplastics and has been identified in one review as the industry sector producing the largest amount of pollution.

A campaign of big clothing brands like Nike, Adidas and Puma to voluntarily reform their manufacturing supply chains to commit to achieving zero discharges of hazardous chemicals by 2020 (global goal) appears to have failed.

The textile industry also creates a lot of pollution that leads to externalities which can cause large economic problems. The problem usually occurs when there is no division of ownership rights. This means that the problem of pollution is largely caused because of incomplete information about which company pollutes and at what scale the damage was caused by the pollution.

Planetary boundary

A study by "Scienmag" defines a 'planetary boundary' for novel entities such as plastic and chemical pollution. The study reported that the boundary has been crossed.

Regulation of chemical waste

Chemicals waste may fall under regulations such as COSHH in the United Kingdom or the Clean Water Act and Resource Conservation and Recovery Act in the United States. In the U.S., the Environmental Protection Agency (EPA) and the Occupational Safety and Health Administration (OSHA), as well as state and local regulations, also regulate chemical use and disposal.

Chemical waste in Canadian aquaculture

Chemical waste in oceans is becoming a major issue for marine life. There have been many studies conducted to try and prove the effects of chemicals in oceans. In Canada, many of the studies concentrated on the Atlantic provinces, where fishing and aquaculture are an important part of the economy. In New Brunswick, a study was done on sea urchins in an attempt to identify the effects of toxic and chemical waste on life beneath the ocean, specifically the waste from salmon farms. Sea urchins were used to check the levels of metals in the environment. Green sea urchins have been used as they are widely distributed, abundant in many locations, and easily accessible. By investigating the concentrations of metals in the green sea urchins, the impacts of chemicals from salmon aquaculture activity could be assessed and detected. Samples were taken at 25-meter intervals along a transect in the direction of the main tidal flow. The study found that there were impacts to at least 75 meters based on the intestine metal concentrations.

Red mud

From Wikipedia, the free encyclopedia

https://en.wikipedia.org/wiki/Red_mud

Red mud near Stade (Germany)

Bauxite, an aluminium ore (Hérault department, France). The reddish colour is due to iron oxides that make up the main part of the red mud.

Red mud, now more frequently termed bauxite residue, is an industrial waste generated during the processing of bauxite into alumina using the Bayer process. It is composed of various oxide compounds, including the iron oxides which give its red colour. Over 97% of the alumina produced globally is through the Bayer process; for every tonne (2,200 lb) of alumina produced, approximately 1 to 1.5 tonnes (2,200 to 3,300 lb) of red mud are also produced; the global average is 1.23. Annual production of alumina in 2023 was over 142 million tonnes (310 billion pounds) resulting in the generation of approximately 170 million tonnes (370 billion pounds) of red mud.

Due to this high level of production and the material's high alkalinity, if not stored properly, it can pose a significant environmental hazard. As a result, significant effort is being invested in finding better methods for safe storage and dealing with it such as waste valorization in order to create useful materials for cement and concrete.

Less commonly, this material is also known as bauxite tailings, red sludge, or alumina refinery residues. Increasingly, the name processed bauxite is being adopted, especially when used in cement applications.

Production

Red mud is a side-product of the Bayer process, the principal means of refining bauxite en route to alumina. The resulting alumina is the raw material for producing aluminium by the Hall–Héroult process. A typical bauxite plant produces one to two times as much red mud as alumina. This ratio is dependent on the type of bauxite used in the refining process and the extraction conditions.

More than 60 manufacturing operations across the world use the Bayer process to make alumina from bauxite ore. Bauxite ore is mined, normally in open cast mines, and transferred to an alumina refinery for processing. The alumina is extracted using sodium hydroxide under conditions of high temperature and pressure. The insoluble part of the bauxite (the residue) is removed, giving rise to a solution of sodium aluminate, which is then seeded with an aluminium hydroxide crystal and allowed to cool which causes the remaining aluminium hydroxide to precipitate from the solution. Some of the aluminium hydroxide is used to seed the next batch, while the remainder is calcined (heated) at over 1,000 °C (1,830 °F) in rotary kilns or fluid flash calciners to produce aluminium oxide (alumina).

The alumina content of the bauxite used is normally between 42 and 50%, but ores with a wide range of alumina contents can be used. The aluminium compound may be present as gibbsite (Al(OH)₃), boehmite (γ-AlO(OH)) or diaspore (α-AlO(OH)). The residue invariably has a high concentration of iron oxide which gives the product a characteristic red colour. A small residual amount of the sodium hydroxide used in the process remains with the residue, causing the material to have a high pH/alkalinity, normally above 12. Various stages of solid/liquid separation processes recycle as much sodium hydroxide as possible from the residue back into the Bayer Process, in order to reduce production costs and make the process as efficient as possible. This also lowers the final alkalinity of the residue, making it easier and safer to handle and store.

Composition

Red mud is composed of a mixture of solid and metallic oxides. The red colour arises from iron oxides, which can comprise up to 60% of the mass. The mud is highly basic with a pH ranging from 10 to 13. In addition to iron, the other dominant components include silica, unleached residual aluminium compounds, and titanium oxide.

The main constituents of the residue after the extraction of the aluminium component are insoluble metallic oxides. The percentage of these oxides produced by a particular alumina refinery will depend on the quality and nature of the bauxite ore and the extraction conditions. The table below shows the composition ranges for common chemical constituents, but the values vary widely:

Chemical	Percentage composition
Fe2O3	5–60%
Al2O3	5–30%
TiO2	0–15%
CaO	2–14%
SiO2	3–50%
Na2O	1–10%

Mineralogically expressed the components present are:

Chemical name	Chemical formula	Percentage composition
Sodalite	3Na2O⋅3Al2O3⋅6SiO2⋅Na2SO4	4–40%
Cancrinite	Na3⋅CaAl3⋅Si3⋅O12CO3	0–20%
Aluminous-goethite (aluminous iron oxide)	α-(Fe,Al)OOH	10–30%
Hematite (iron oxide)	Fe2O3	10–30%
Silica (crystalline & amorphous)	SiO2	5–20%
Tricalcium aluminate	3CaO⋅Al2O3⋅6H2O	2–20%
Boehmite	AlO(OH)	0–20%
Titanium dioxide	TiO2	0–10%
Perovskite	CaTiO3	0–15%
Muscovite	K2O⋅3Al2O3⋅6SiO2⋅2H2O	0–15%
Calcium carbonate	CaCO3	2–10%
Gibbsite	Al(OH)3	0–5%
Kaolinite	Al2O3⋅2SiO2⋅2H2O	0–5%

In general, the composition of the residue reflects that of the non-aluminium components, with the exception of part of the silicon component: crystalline silica (quartz) will not react but some of the silica present, often termed, reactive silica, will react under the extraction conditions and form sodium aluminium silicate as well as other related compounds.

Environmental hazards

Discharge of red mud can be hazardous environmentally because of its alkalinity and species components.

Until 1972, Italian company Montedison was discharging red mud off the coast of Corsica. The case is important in international law governing the Mediterranean sea.

In October 2010, approximately one million cubic metres (35 million cubic feet) of red mud slurry from an alumina plant near Kolontár in Hungary was accidentally released into the surrounding countryside in the Ajka alumina plant accident, killing ten people and contaminating a large area. All life in the Marcal river was said to have been "extinguished" by the red mud, and within days the mud had reached the Danube. The long-term environmental effects of the spill have been minor after a €127 million remediation effort by the Hungarian government.

Residue storage areas

Residue storage methods have changed substantially since the original plants were built. The practice in early years was to pump the slurry, at a concentration of about 20% solids, into lagoons or ponds sometimes created in former bauxite mines or depleted quarries. In other cases, impoundments were constructed with dams or levees, while for some operations valleys were dammed and the residue deposited in these holding areas.

It was once common practice for the red mud to be discharged into rivers, estuaries, or the sea via pipelines or barges; in other instances the residue was shipped out to sea and disposed of in deep ocean trenches many kilometres offshore. From 2016, all disposal into the sea, estuaries and rivers was stopped.

As residue storage space ran out and concern increased over wet storage, since the mid-1980s dry stacking has been increasingly adopted. In this method, residues are thickened to a high density slurry (48–55% solids or higher), and then deposited in a way that it consolidates and dries.

An increasingly popular treatment process is filtration whereby a filter cake (typically resulting in 23–27% moisture) is produced. This cake can be washed with either water or steam to reduce alkalinity before being transported and stored as a semi-dried material. Residue produced in this form is ideal for reuse as it has lower alkalinity, is cheaper to transport, and is easier to handle and process. Another option for ensuring safe storage is to use amphirols to dewater the material once deposited and then 'conditioned' using farming equipment such as harrows to accelerate carbonation and thereby reduce the alkalinity. Bauxite residue produced after press filtration and 'conditioning as described above are classified as non-hazardous under the EU Waste Framework Directive.

In 2013 Vedanta Aluminium, Ltd. commissioned a red mud powder-producing unit at its Lanjigarh refinery in Odisha, India, describing it as the first of its kind in the alumina industry, tackling major environmental hazards.

Use

Since the Bayer process was first adopted industrially in 1894, the value of the remaining oxides has been recognized. Attempts have been made to recover the principal components – especially the iron oxides. Since bauxite mining began, a large amount of research effort has been devoted to seeking uses for the residue. Many studies are now being financed by the European Union under the Horizon Europe programme. Several studies have been conducted to develop uses of red mud. An estimated 3 to 4 million tonnes (6.6 to 8.8 billion pounds) are used annually in the production of cement, road construction and as a source for iron. Potential applications include the production of low cost concrete, application to sandy soils to improve phosphorus cycling, amelioration of soil acidity, landfill capping and carbon sequestration.

Reviews describing the current use of bauxite residue in Portland cement clinker, supplementary cementious materials/blended cements and special calcium aluminate cements (CAC) and calcium sulfo-aluminate (CSA) cements have been extensively researched and documented.^[27]

• Cement manufacture, use in concrete as a supplementary cementitious material. From 500,000 to 1,500,000 tonnes (1.1 to 3.3 billion pounds).^[28][29]
• Raw material recovery of specific components present in the residue: iron, titanium, steel and REE (rare-earth elements) production. From 400,000 to 1,500,000 tonnes;
• Landfill capping/roads/soil amelioration – 200,000 to 500,000 tonnes;
• Use as a component in building or construction materials (bricks, tiles, ceramics etc.) – 100,000 to 300,000 tonnes;
• Other (refractory, adsorbent, acid mine drainage (Virotec), catalyst etc.) – 100,000 tonnes.
• Use in building panels, bricks, foamed insulating bricks, tiles, gravel/railway ballast, calcium and silicon fertilizer, refuse tip capping/site restoration, lanthanides (rare earths) recovery, scandium recovery, gallium recovery, yttrium recovery, treatment of acid mine drainage, adsorbent of heavy metals, dyes, phosphates, fluoride, water treatment chemical, glass ceramics, ceramics, foamed glass, pigments, oil drilling or gas extraction, filler for PVC, wood substitute, geopolymers, catalysts, plasma spray coating of aluminium and copper, manufacture of aluminium titanate-mullite composites for high temperature resistant coatings, desulfurisation of flue gas, arsenic removal, chromium removal.

In 2015, a major initiative was launched in Europe with funds from the European Union to address the valorization of red mud. Some 15 PhD students were recruited as part the European Training Network (ETN) for Zero-Waste Valorisation of Bauxite Residue. The key focus will be the recovery of iron, aluminium, titanium and rare-earth elements (including scandium) while valorising the residue into building materials. A European Innovation Partnership has been formed to explore options for using by-products from the aluminium industry, BRAVO (Bauxite Residue and Aluminium Valorisation Operations). This sought to bring together industry with researchers and stakeholders to explore the best available technologies to recover critical raw materials but has not proceeded. Additionally, EU funding of approximately €11.5 million has been allocated to a four-year programme starting in May 2018 looking at uses of bauxite residue with other wastes, RemovAL. A particular focus of this project is the installation of pilot plants to evaluate some of the interesting technologies from previous laboratory studies. As part of the H2020 project RemovAl, it is planned to erect a house in the Aspra Spitia area of Greece that will be made entirely out of materials from bauxite residue.

Other EU funded projects that have involved bauxite residue and waste recovery have been ENEXAL (ENergy-EXergy of ALuminium industry) [2010–2014], EURARE (European Rare earth resources) [2013–2017] and three more recent projects are ENSUREAL (ENsuring SUstainable ALumina production) [2017–2021], SIDEREWIN (Sustainable Electro-winning of Iron) [2017–2022] and SCALE (SCandium – ALuminium in Europe) [2016–2020] a €7 million project to look at the recovery of scandium from bauxite residue.

In 2020, the International Aluminium Institute, launched a roadmap for maximising the use of bauxite residue in cement and concrete.

In November 2020, The ReActiv: Industrial Residue Activation for Sustainable Cement Production research project was launched, this is being funded by the EU. One of the world's largest cement companies, Holcim, in cooperation with 20 partners across 12 European countries, launched the ambitious 4-year ReActiv project (reactivproject.eu). The ReActiv project will create a novel sustainable symbiotic value chain, linking the by-product of the alumina production industry and the cement production industry. In ReActiv modification will be made to both the alumina production and the cement production side of the chain, in order to link them through the new ReActiv technologies. The latter will modify the properties of the industrial residue, transforming it into a reactive material (with pozzolanic or hydraulic activity) suitable for new, low CO₂ footprint, cement products. In this manner ReActiv proposes a win-win scenario for both industrial sectors (reducing wastes and CO₂ emissions respectively).

Fluorchemie GmbH have developed a new flame-retardant additive from bauxite residue, the product is termed MKRS (modified re-carbonised red mud) with the trademark ALFERROCK(R) and has potential applicability in a wide range of polymers (PCT WO2014/000014). One of its particular benefits is the ability to operate over a much broader temperature range, 220–350 °C (428–662 °F), that alternative zero halogen inorganic flame retardants such as aluminium hydroxide, boehmite or magnesium hydroxide. In addition to polymer systems where aluminium hydroxide or magnesium hydroxide can be used, it has also found to be effective in foamed polymers such as EPS and PUR foams at loadings up to 60%.

In a suitable compact solid form, with a density of approximately 3.93 grams per cubic centimetre (0.142 lb/cu in), ALFERROCK produced by the calcination of bauxite residues, has been found to be very effective as a thermal energy storage medium (WO2017/157664). The material can repeatedly be heated and cooled without deterioration and has a specific thermal capacity in the range of 0.6 – 0.8 kJ/(kg·K) at 20 °C (68 °F) and 0.9 – 1.3 kJ/(kg·K) at 726 °C (1,339 °F); this enables the material to work effectively in energy storage device to maximise the benefits of solar power, wind turbines and hydro-electric systems. High strength geopolymers have been developed from red mud.

Sustainable Approach to Low-Grade Bauxite Processing

The IB2 process is a French technology developed to enhance the extraction of alumina from bauxite, especially low-grade bauxite. This method aims to boost alumina production efficiency while decreasing the environmental impacts typically linked with this process, notably the generation of red mud and carbon dioxide emissions.

The IB2 technology, patented in 2019, is the outcome of a decade of research and development efforts by Yves Occello, a former Pechiney chemist. This process improves the traditional Bayer process, which has been utilized for more than a century to extract alumina from bauxite. It presents a significant decrease in caustic soda consumption and a notable reduction in red mud output, thereby minimizing hazardous waste and environmental risks.

In addition to reducing red mud production, the IB2 process aids in lowering CO₂ emissions, primarily through the optimized treatment of low-grade bauxite. By limiting the necessity to import high-grade bauxite, this process reduces the carbon footprint associated with ore transportation. Furthermore, the process yields a byproduct that can be utilized in the production of eco-friendly cements, promoting the concept of a circular economy.

The inventor of the technology is chemist Yves Occello, who founded the company IB2 with Romain Girbal in 2017.

Bauxite

From Wikipedia, the free encyclopedia

https://en.wikipedia.org/wiki/Bauxite 

Reddish-brown bauxite

Bauxite with US penny for comparison

QEMSCAN mineral maps of bauxite ore-forming pisoliths

Bauxite (/ˈbɔːksaɪt/) is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite (Al(OH)₃), boehmite (γ-AlO(OH)) and diaspore (α-AlO(OH)), mixed with the two iron oxides goethite (FeO(OH)) and haematite (Fe₂O₃), the aluminium clay mineral kaolinite (Al₂Si₂O₅(OH)₄) and small amounts of anatase (TiO₂) and ilmenite (FeTiO₃ or FeO·TiO₂). Bauxite appears dull in luster and is reddish-brown, white, or tan.

In 1821, the French geologist Pierre Berthier discovered bauxite near the village of Les Baux in Provence, southern France.

Bauxite extraction and refining has numerous negative consequences to the environment and to people. The negative impacts are well documented and there are many examples from all over the world. These impacts include the destruction of the environment, water, and air soil pollution and soil degradation.

Formation

Bauxite with core of unweathered rock

Numerous classification schemes have been proposed for bauxite but, as of 1982, there was no consensus.

Vadász (1951) distinguished lateritic bauxites (silicate bauxites) from karst bauxite ores (carbonate bauxites):

• The carbonate bauxites occur predominantly in Europe, Guyana, Suriname, and Jamaica above carbonate rocks (limestone and dolomite), where they were formed by lateritic weathering and residual accumulation of intercalated clay layers – dispersed clays which were concentrated as the enclosing limestones gradually dissolved during chemical weathering.
• The lateritic bauxites are found mostly in the countries of the tropics. They were formed by lateritization of various silicate rocks such as granite, gneiss, basalt, syenite, and shale. In comparison with the iron-rich laterites, the formation of bauxites depends even more on intense weathering conditions in a location with very good drainage. This enables the dissolution of the kaolinite and the precipitation of the gibbsite. Zones with highest aluminium content are frequently located below a ferruginous surface layer. The aluminium hydroxide in the lateritic bauxite deposits is almost exclusively gibbsite.

In the case of Jamaica, recent analysis of the soils showed elevated levels of cadmium, suggesting that the bauxite originates from Miocene volcanic ash deposits from episodes of significant volcanism in Central America.

Production and reserves

Main article: List of countries by bauxite production

World bauxite production in 2005

One of the world's largest bauxite mines in Weipa, in northern Queensland, Australia

Australia is the largest producer of bauxite, followed by Guinea and China. Bauxite is usually strip mined because it is almost always found near the surface of the terrain, with little or no overburden. Increased aluminium recycling, which requires less electric power than producing aluminium from ores, may considerably extend the world's bauxite reserves.

2023 Bauxite production and reserves (thousand tons)

Country	Production	Reserves
World	327,000	30,000,000
Australia	110,000	3,500,000
Guinea	82,000	7,400,000
China	60,000	710,000
Brazil	35,000	2,700,000
Indonesia	23,000	1,000,000
India	22,000	650,000
Jamaica	7,700	2,000,000
Russia	6,100	480,000
Kazakhstan	5,800	160,000
Vietnam	4,000	5,800,000
Saudi Arabia	4,000	180,000
Greece	1,800	Undisclosed
Guyana	1,700	850,000
Other countries	9,000	4,570,000

Aluminium production

See also: Aluminium § Production and refinement

Bauxite being loaded at Cabo Rojo, Dominican Republic, to be shipped elsewhere for processing; 2007

As of 2010, approximately 70% to 80% of the world's dry bauxite production is processed first into alumina and then into aluminium by electrolysis. Bauxite rocks are typically classified according to their intended commercial application: metallurgical, abrasive, cement, chemical, and refractory.

Bauxite ore is usually heated in a pressure vessel along with a sodium hydroxide solution at a temperature of 150 to 200 °C (300 to 390 °F). At these temperatures, the aluminium is dissolved as sodium aluminate (the Bayer process). The aluminium compounds in the bauxite may be present as gibbsite(Al(OH)₃), boehmite(AlOOH) or diaspore(AlOOH); the different forms of the aluminium component will dictate the extraction conditions. The undissolved waste, bauxite tailings, after the aluminium compounds are extracted contains iron oxides, silica, calcia, titania and some un-reacted alumina. After separation of the residue by filtering, pure gibbsite is precipitated when the liquid is cooled, and then seeded with fine-grained aluminium hydroxide. The gibbsite is usually converted into aluminium oxide, Al₂O₃, by heating in rotary kilns or fluid flash calciners to a temperature in excess of 1,000 °C (1,830 °F). This aluminium oxide is dissolved at a temperature of about 960 °C (1,760 °F) in molten cryolite. Next, this molten substance can yield metallic aluminium by passing an electric current through it in the process of electrolysis, which is called the Hall–Héroult process, named after its American and French discoverers.

Prior to the invention of this process, and prior to the Deville process, aluminium ore was refined by heating ore along with elemental sodium or potassium in a vacuum. The method was complicated and consumed materials that were themselves expensive at that time. This made early elemental aluminium more expensive than gold.

Maritime safety

As a bulk cargo, bauxite is a Group A cargo that may liquefy if excessively moist. Liquefaction and the free surface effect can cause the cargo to shift rapidly inside the hold and make the ship unstable, potentially sinking the ship. One vessel suspected to have been sunk in this way was the MS Bulk Jupiter in 2015. One method which can demonstrate this effect is the "can test", in which a sample of the material is placed in a cylindrical can and struck against a surface many times. If a moist slurry forms in the can, then there is a likelihood for the cargo to liquefy; although conversely, even if the sample remains dry it does not conclusively prove that it will remain that way, or that it is safe for loading.

Source of gallium

Bauxite is the main source of the rare metal gallium.

During the processing of bauxite to alumina in the Bayer process, gallium accumulates in the sodium hydroxide liquor. From this it can be extracted by a variety of methods. The most recent is the use of ion-exchange resin. Achievable extraction efficiencies critically depend on the original concentration in the feed bauxite. At a typical feed concentration of 50 ppm, about 15 percent of the contained gallium is extractable. The remainder reports to the red mud and aluminium hydroxide streams.

Bauxite is also a potential source for vanadium.

Socio-ecological impacts

Mineração Rio do Norte (MRN) Bauxite Mine

The social and environmental impacts of bauxite extraction are well documented. Most of the world's bauxite deposits can be found within 1 to 20 metres (3 ft 3 in to 65 ft 7 in) of the earths surface. Strip mining is the most common technique used for extracting shallow bauxite. This process involves removing the vegetation, top soil, and overburden to expose the bauxite ore. The overlying soil is typically stockpiled in order to rehabilitate the mine once operations have finished. During the strip mining process, the biodiversity and habitat once present in the area is completely lost and the hydrological and soil characteristics in the region are permanently altered. Other environmental impacts of bauxite mining include soil degradation, air pollution, and water pollution.

Red mud

Main article: Red mud

Red mud is a highly alkaline sludge, with a high pH around 13, that is a byproduct of the Bayer process. It contains several elements such as sodium aluminoscilicate, calcium titanate, monohydrate aluminium, and trihydrate aluminium that do not break down in nature. When improperly stored, red mud can contaminate soil and water, which can result in local extinction of all life. Red mud was responsible for killing all life in the Marcal River in Hungary after a spill occurred in 2010. When red mud dries, it turns into dust that can cause lung disease, cancer and birth defects.

Conflicts

In the tropical regions of Asia, central Africa, South America and northern Australia, there has been an increase of bauxite mines on traditional and indigenous lands. This has resulted in a number of negative social impacts on local and indigenous peoples. In the Boké Region of Guinea, there has been a significant increase in bauxite mining pressure on the local population. This has resulted in potable water issues, air pollution, food contamination, and land expropriation disputes due to improper compensation.

Bauxite mining has led to protests, civil unrest, and violent conflicts in Guinea, Ghana, Vietnam, and India.

Guinea

Guinea has a long history of mining related conflicts between communities and mining companies. Between 2015 and 2018, new bauxite mining operations in the Boké Region of Guinea have caused in 35 conflicts which include movements of revolts and road blockades. These conflicts have resulted in the loss of human life, the destruction of heavy machinery, and damage to government buildings.

Ghana

The Atewa range in Ghana, classified as an ecologically important forest reserve with an area of 17,400 hectares (43,000 acres), has been is a recent site of conflict and controversy surrounding baxuite mining. The forest reserve is one of the only two upland evergreen forests in Ghana, and makes up a significant portion of the remaining 20% of forested habitat left in Ghana. The Atewa range falls under the jurisdiction of Akyem Abuakwa Traditional Area and is overseen by the king known as Okyenhene. In 2013, an NGO called A Rocha Ghana held a summit with the forestry and water resource commission, the minister of lands, the minister of the environment, and other important stakeholders. They came to the conclusion that no future government should mine bauxite in the region because the reserve is environmentally and culturally significant. In 2016, the government along with NGO's began the process of upgrading the reserved to a national park. However, that year an election took place, and before it became official, the newly elected National Patriotic Party (NPP) rejected the plan. In 2017, the government of Ghana signed a Memorandum of Understanding with China to develop new bauxite mining infrastructure in Ghana. Although there was no official plan to mine the Atewa Forest Reserve, tensions between local communities, NGO and the government began to rise. In 2019, tensions began to reach a peak when the government presented the Ghana Integrated Bauxite and Aluminium Development Authority Act that would create the legal framework required to develop and establish an integrated bauxite industry. In may of that year, the government began drilling deep holes in the reserve. These actions sparked several protests, including a 95-kilometre (59 mi) march from the reserve to the presidential palace, an informational billboard campaign led by A Rocha Ghana, and a youth march. In 2020, A Rocha Ghana also sued the government over the drilling in the reserve after they failed to provide a statement explaining their actions.

Vietnam

In early 2009, the Vietnamese Government proposed a plan to mine remote regions of the central highlands. This proposal was highly controversial and sparked a nationwide debate and the most significant domestic conflict since the Vietnam War. Government scientists, journalists, religious leaders, retired high level state officials, and General Võ Nguyên Giáp, the military leader of anti-colonial revolution, were among the many people across Vietnamese society who opposed the governments plans. In an attempt to stop the spread of information across the globe, the government banned domestic reporters from reporting on bauxite mining. However, reporters turned to Vietnamese language websites and blogs where the reporting and discussion continued. On April 12, 2009, several well-respected Vietnamese scholars started a petition against the mining of bauxite that was signed by 135 accomplished and well known "Intellectuals". This petition helped unite the scattered anti-bauxite movement into a unified opposition against the state. These acts of governmental defiance were met with repressive state actions. Many domestic online reporters were arrested, and legislative action was taken to repress scientific research.

India

Most of India's bauxite ore reserves, which are among the top ten largest in the world, are located on tribal land. These tribal lands are densely populated and home to over 100 million Indigenous Indian peoples.  The mountain summits located on these lands act as a source of water and greatly contribute to the regions fertility. The Indian bauxite industry is interested in developing this land for aluminum production, which poses great risk to the terrestrial and aquatic ecosystems. Historically, the Indigenous peoples living on these lands have shown resistance to development, and oppose any new bauxite mining projects in the area. This has led to violent conflicts between Indigenous communities and police. On December 16, 2000, police killed three Indigenous protestors and wounded over a dozen more during a protest over a bauxite project in the Kashipur region.