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Thursday, December 20, 2018

Hybrid vehicle

From Wikipedia, the free encyclopedia
 
A hybrid vehicle uses two or more distinct types of power, such as internal combustion engine to drive an electric generator that powers an electric motor, e.g. in diesel-electric trains using diesel engines to drive an electric generator that powers an electric motor, and submarines that use diesels when surfaced and batteries when submerged. Other means to store energy include pressurized fluid in hydraulic hybrids
 
The basic principle with hybrid vehicles is that the different motors work better at different speeds; the electric motor is more efficient at producing torque, or turning power, and the combustion engine is better for maintaining high speed (better than typical electric motor). Switching from one to the other at the proper time while speeding up yields a win-win in terms of energy efficiency, as such that translates into greater fuel efficiency, for example.

Vehicle type

A biodiesel hybrid bus in Montreal, Canada

Two-wheeled and cycle-type vehicles

Mopeds, electric bicycles, and even electric kick scooters are a simple form of a hybrid, powered by an internal combustion engine or electric motor and the rider's muscles. Early prototype motorcycles in the late 19th century used the same principle.
  • In a parallel hybrid bicycle human and motor torques are mechanically coupled at the pedal or one of the wheels, e.g. using a hub motor, a roller pressing onto a tire, or a connection to a wheel using a transmission element. Most motorized bicycles, mopeds are of this type.
  • In a series hybrid bicycle (SHB) (a kind of chainless bicycle) the user pedals a generator, charging a battery or feeding the motor, which delivers all of the torque required. They are commercially available, being simple in theory and manufacturing.
The first published prototype of an SHB is by Augustus Kinzel (US Patent 3'884'317) in 1975. In 1994 Bernie Macdonalds conceived the Electrilite SHB with power electronics allowing regenerative braking and pedaling while stationary. In 1995 Thomas Muller designed and built a "Fahrrad mit elektromagnetischem Antrieb" for his 1995 diploma thesis. In 1996 Jürg Blatter and Andreas Fuchs of Berne University of Applied Sciences built an SHB and in 1998 modified a Leitra tricycle (European patent EP 1165188). Until 2005 they built several prototype SH tricycles and quadricycles. In 1999 Harald Kutzke described an "active bicycle": the aim is to approach the ideal bicycle weighing nothing and having no drag by electronic compensation.
  • A series hybrid electric-petroleum bicycle (SHEPB) is powered by pedals, batteries, a petrol generator, or plug-in charger - providing flexibility and range enhancements over electric-only bicycles.
A SHEPB prototype made by David Kitson in Australia in 2014 used a lightweight brushless DC electric motor from an aerial drone and small hand-tool sized internal combustion engine, and a 3D printed drive system and lightweight housing, altogether weighing less than 4.5 kg. Active cooling keeps plastic parts from softening. The prototype uses a regular electric bicycle charge port.

Heavy vehicle

Bus Rapid Transit of Metz, a diesel-electric hybrid driving system by Van Hool
 
Hybrid power trains use diesel-electric or turbo-electric to power railway locomotives, buses, heavy goods vehicles, mobile hydraulic machinery, and ships. A diesel/turbine engine drives an electric generator or hydraulic pump, which powers electric/hydraulic motor(s) - strictly an electric/hydraulic transmission (not a hybrid), unless it can accept power from outside. With large vehicles conversion losses decrease, and the advantages in distributing power through wires or pipes rather than mechanical elements become more prominent, especially when powering multiple drives — e.g. driven wheels or propellers. Until recently most heavy vehicles had little secondary energy storage, e.g. batteries/hydraulic accumulators — excepting non-nuclear submarines, one of the oldest production hybrids, running on diesels while surfaced and batteries when submerged. Both series and parallel setups were used in WW2 submarines.

Rail transport


Europe
 
The new Autorail à grande capacité (AGC or high-capacity railcar) built by the Canadian company Bombardier for service in France is diesel/electric motors, using 1500 or 25000 V on different rail systems. It was tested in Rotterdam, the Netherlands with Railfeeding, a Genesse and Wyoming company.

China
 
The First Hybrid Evaluating locomotive was designed by rail research center MATRAI in 1999 and built in 2000. It was a G12 locomotive upgraded with batteries, a 200 kW diesel generator and 4 AC motors. 

Japan
 
Japan's first hybrid train with significant energy storage is the KiHa E200, with roof-mounted lithium ion batteries.

India
 
Indian railway launched one of its kind CNG-Diesel hybrid trains in January 2015. The train has a 1400 hp engine which uses fumigation technology.The first of these train is set to run on the 81 km long Rewari-Rohtak route. CNG is less-polluting alternative for diesel and petrol and is popular as an alternative fuel in India. Already many transport vehicles such as auto-rickshaws and buses run on CNG fuel. 

North America
 
In the US, General Electric made a locomotive with sodium - nickel chloride (Na-NiCl2) battery storage. They expect ≥10% fuel economy.

Variant diesel electric locomotive include the Green Goat (GG) and Green Kid (GK) switching/yard engines built by Canada's Railpower Technologies, with lead acid (Pba) batteries and 1000 to 2000 hp electric motors, and a new clean burning ~160 hp diesel generator. No fuel is wasted for idling — ~60–85% of the time for these type locomotives. It is unclear if regenerative braking is used; but in principle it is easily utilized. 

Since these engines typically need extra weight for traction purposes anyway the battery pack's weight is a negligible penalty. The diesel generator and batteries are normally built on an existing "retired" "yard" locomotive's frame. The existing motors and running gear are all rebuilt and reused. Fuel savings of 40–60% and up to 80% pollution reductions are claimed over a "typical" older switching/yard engine. The advantages hybrid cars have for frequent starts and stops and idle periods apply to typical switching yard use. "Green Goat" locomotives have been purchased by Canadian Pacific Railway, BNSF Railway, Kansas City Southern Railway, and Union Pacific Railroad among others.

Cranes

Railpower Technologies engineers working with TSI Terminal Systems are testing a hybrid diesel electric power unit with battery storage for use in Rubber Tyred Gantry (RTG) cranes. RTG cranes are typically used for loading and unloading shipping containers onto trains or trucks in ports and container storage yards. The energy used to lift the containers can be partially regained when they are lowered. Diesel fuel and emission reductions of 50–70% are predicted by Railpower engineers. First systems are expected to be operational in 2007.

Road transport, commercial vehicles

GMC Yukon hybrid version

Hybrid systems are coming into use for trucks, buses and other heavy highway vehicles. Small fleet sizes and installation costs are compensated by fuel savings. With advances such as higher capacity, lowered battery cost etc. Toyota, Ford, GM and others are introducing hybrid pickups and SUVs. Kenworth Truck Company recently introduced the Kenworth T270 Class 6 that for city usage seems to be competitive. FedEx and others are investing in hybrid delivery vehicles — particularly for city use where hybrid technology may pay off first. As of December 2013 FedEx is trialling two delivery trucks with Wrightspeed electric motors and diesel generators; the retrofit kits are claimed to pay for themselves in a few years. The diesel engines run at a constant RPM for peak efficiency.

In 1978 students at Minneapolis, Minnesota's Hennepin Vocational Technical Center, converted a Volkswagen Beetle to a petro-hydraulic hybrid with off-the shelf components. A car rated at 32 mpg was returning 75 mpg with the 60 hp engine replaced by a 16 hp engine, and reached 70 mph. In the 1990s, engineers at EPA’s National Vehicle and Fuel Emissions Laboratory developed a petro-hydraulic powertrain for a typical American sedan car. The test car achieved over 80 mpg on combined EPA city/highway driving cycles. Acceleration was 0-60 mph in 8 seconds, using a 1.9 liter diesel engine. No lightweight materials were used. The EPA estimated that produced in high volumes the hydraulic components would add only $700 to the cost. Under EPA testing, a hydraulic hybrid Ford Expedition returned 32 mpg (7.4 L/100 km) City, and 22 mpg (11 L/100 km) highway. UPS currently has two trucks in service using this technology.

Military off-road vehicles

Since 1985, the US military has been testing serial hybrid Humvees and have found them to deliver faster acceleration, a stealth mode with low thermal signature/ near silent operation, and greater fuel economy.

Ships

Ships with both mast-mounted sails and steam engines were an early form of hybrid vehicle. Another example is the diesel-electric submarine. This runs on batteries when submerged and the batteries can be re-charged by the diesel engine when the craft is on the surface. 

Newer hybrid ship-propulsion schemes include large towing kites manufactured by companies such as SkySails. Towing kites can fly at heights several times higher than the tallest ship masts, capturing stronger and steadier winds.

Aircraft

The Boeing Fuel Cell Demonstrator Airplane has a Proton Exchange Membrane (PEM) fuel cell/lithium-ion battery hybrid system to power an electric motor, which is coupled to a conventional propeller. The fuel cell provides all power for the cruise phase of flight. During takeoff and climb, the flight segment that requires the most power, the system draws on lightweight lithium-ion batteries. 

The demonstrator aircraft is a Dimona motor glider, built by Diamond Aircraft Industries of Austria, which also carried out structural modifications to the aircraft. With a wing span of 16.3 meters (53 feet), the airplane will be able to cruise at about 100 km/h (62 mph) on power from the fuel cell.

Hybrid FanWings have been designed. A FanWing is created by two engines with the capability to autorotate and landing like a helicopter.

Engine type

Hybrid electric-petroleum vehicles

 
Hybrid Optare Solo

When the term hybrid vehicle is used, it most often refers to a Hybrid electric vehicle. These encompass such vehicles as the Saturn Vue, Toyota Prius, Toyota Yaris, Toyota Camry Hybrid, Ford Escape Hybrid, Toyota Highlander Hybrid, Honda Insight, Honda Civic Hybrid, Lexus RX 400h and 450h, Hyundai Ioniq and others. A petroleum-electric hybrid most commonly uses internal combustion engines (using a variety of fuels, generally gasoline or Diesel engines) and electric motors to power the vehicle. The energy is stored in the fuel of the internal combustion engine and an electric battery set. There are many types of petroleum-electric hybrid drivetrains, from Full hybrid to Mild hybrid, which offer varying advantages and disadvantages.

William H. Patton filed a patent application for a gasoline-electric hybrid rail-car propulsion system in early 1889, and for a similar hybrid boat propulsion system in mid 1889. There is no evidence that his hybrid boat met with any success, but he built a prototype hybrid tram and sold a small hybrid locomotive.

In 1899, Henri Pieper developed the world's first petro-electric hybrid automobile. In 1900, Ferdinand Porsche developed a series-hybrid using two motor-in-wheel-hub arrangements with an internal combustion generator set providing the electric power; Porsche's hybrid set two speed records.[citation needed] While liquid fuel/electric hybrids date back to the late 19th century, the braking regenerative hybrid was invented by David Arthurs, an electrical engineer from Springdale, Arkansas in 1978–79. His home-converted Opel GT was reported to return as much as 75 mpg with plans still sold to this original design, and the "Mother Earth News" modified version on their website.

The plug-in-electric-vehicle (PEV) is becoming more and more common. It has the range needed in locations where there are wide gaps with no services. The batteries can be plugged into house (mains) electricity for charging, as well being charged while the engine is running.

Continuously outboard recharged electric vehicle (COREV)

Some battery electric vehicles (BEVs) can be recharged while the user drives. Such a vehicle establishes contact with an electrified rail, plate or overhead wires on the highway via an attached conducting wheel or other similar mechanism. The BEV's batteries are recharged by this process—on the highway—and can then be used normally on other roads until the battery is discharged. For example, some of the battery-electric locomotives used for maintenance trains on the London Underground are capable of this mode of operation.

Developing a BEV infrastructure would provide the advantage of virtually unrestricted highway range. Since many destinations are within 100 km of a major highway, BEV technology could reduce the need for expensive battery systems. Unfortunately, private use of the existing electrical system is almost universally prohibited. Besides, the technology for such electrical infrastructure is largely outdated and, outside some cities, not widely distributed (see Conduit current collection, trams, electric rail, trolleys, third rail). Updating the required electrical and infrastructure costs could perhaps be funded by toll revenue or by dedicated transportation taxes.

Hybrid fuel (dual mode)

Ford Escape Plug-in Hybrid with a flexible fuel capability to run on E85 (ethanol)

In addition to vehicles that use two or more different devices for propulsion, some also consider vehicles that use distinct energy sources or input types ("fuels") using the same engine to be hybrids, although to avoid confusion with hybrids as described above and to use correctly the terms, these are perhaps more correctly described as dual mode vehicles:
  • Some electric trolleybuses can switch between an on-board diesel engine and overhead electrical power depending on conditions (see dual mode bus). In principle, this could be combined with a battery subsystem to create a true plug-in hybrid trolleybus, although as of 2006, no such design seems to have been announced.
  • Flexible-fuel vehicles can use a mixture of input fuels mixed in one tank — typically gasoline and ethanol, methanol, or biobutanol.
  • Bi-fuel vehicle: Liquified petroleum gas and natural gas are very different from petroleum or diesel and cannot be used in the same tanks, so it would be impossible to build an (LPG or NG) flexible fuel system. Instead vehicles are built with two, parallel, fuel systems feeding one engine. For example, some Chevrolet Silverado 2500 HDs can effortlessly switch between petroleum and natural gas, offering a range of over 1000 km (650 miles). While the duplicated tanks cost space in some applications, the increased range, decreased cost of fuel, and flexibility where LPG or CNG infrastructure is incomplete may be a significant incentive to purchase. While the US Natural gas infrastructure is partially incomplete, it is increasing at a fast pace, and already has 2600 CNG stations in place. With a growing fueling station infrastructure, a large scale adoption of these bi-fuel vehicles could be seen in the near future. Rising gas prices may also push consumers to purchase these vehicles. When gas prices trade around $4.00, the price per MMBTU of gasoline is $28.00, compared to natural gas's $4.00 per MMBTU. On a per unit of energy comparative basis, this makes natural gas much cheaper than gasoline. All of these factors are making CNG-Gasoline bi-fuel vehicles very attractive.
  • Some vehicles have been modified to use another fuel source if it is available, such as cars modified to run on autogas (LPG) and diesels modified to run on waste vegetable oil that has not been processed into biodiesel.
  • Power-assist mechanisms for bicycles and other human-powered vehicles are also included (see Motorized bicycle).

Fluid power hybrid

Chrysler minivan, petro-hydraulic hybrid
 
French MDI petro-air hybrid car developed with Tata

Hydraulic hybrid and pneumatic hybrid vehicles use an engine to charge a pressure accumulator to drive the wheels via hydraulic (liquid) or pneumatic (compressed air) drive units. In most cases the engine is detached from the drivetrain, serving solely to charge the energy accumulator. The transmission is seamless. Regenerative braking can be used to recover some of the supplied drive energy back into the accumulator.

Petro-air hybrid

A French company, MDI, has designed and has running models of a petro-air hybrid engine car. The system does not use air motors to drive the vehicle, being directly driven by a hybrid engine. The engine uses a mixture of compressed air and gasoline injected into the cylinders. A key aspect of the hybrid engine is the "active chamber", which is a compartment heating air via fuel doubling the energy output. Tata Motors of India assessed the design phase towards full production for the Indian market and moved into "completing detailed development of the compressed air engine into specific vehicle and stationary applications".

Petro-hydraulic hybrid

Peugeot 2008 HYbrid air/hydraulic concept car
 
Peugeot 2008 HYbrid air/hydraulic cutaway

Petro-hydraulic configurations have been common in trains and heavy vehicles for decades. The auto industry recently focused on this hybrid configuration as it now shows promise for introduction into smaller vehicles.

In petro-hydraulic hybrids, the energy recovery rate is high and therefore the system is more efficient than electric battery charged hybrids using the current electric battery technology, demonstrating a 60% to 70% increase in energy economy in US Environmental Protection Agency (EPA) testing. The charging engine needs only to be sized for average usage with acceleration bursts using the stored energy in the hydraulic accumulator, which is charged when in low energy demanding vehicle operation. The charging engine runs at optimum speed and load for efficiency and longevity. Under tests undertaken by the US Environmental Protection Agency (EPA), a hydraulic hybrid Ford Expedition returned 32 miles per US gallon (7.4 L/100 km; 38 mpg‑imp) City, and 22 miles per US gallon (11 L/100 km; 26 mpg‑imp) highway. UPS currently has two trucks in service using this technology.

Although petro-hydraulic hybrid technology has been known for decades, and used in trains and very large construction vehicles, high costs of the equipment precluded the systems from lighter trucks and cars. In the modern sense an experiment proved the viability of small petro-hydraulic hybrid road vehicles in 1978. A group of students at Minneapolis, Minnesota's Hennepin Vocational Technical Center, converted a Volkswagen Beetle car to run as a petro-hydraulic hybrid using off-the shelf components. A car rated at 32 mpg‑US (7.4 L/100 km; 38 mpg‑imp) was returning 75 mpg‑US (3.1 L/100 km; 90 mpg‑imp) with the 60 hp engine replaced by a 16 hp engine. The experimental car reached 70 mph (110 km/h).

In the 1990s, a team of engineers working at EPA’s National Vehicle and Fuel Emissions Laboratory succeeded in developing a revolutionary type of petro-hydraulic hybrid powertrain that would propel a typical American sedan car. The test car achieved over 80 mpg on combined EPA city/highway driving cycles. Acceleration was 0-60 mph in 8 seconds, using a 1.9 liter diesel engine. No lightweight materials were used. The EPA estimated that produced in high volumes the hydraulic components would add only $700 to the base cost of the vehicle.

The petro-hydraulic hybrid system has faster and more efficient charge/discharge cycling than petro-electric hybrids and is also cheaper to build. The accumulator vessel size dictates total energy storage capacity and may require more space than an electric battery set. Any vehicle space consumed by a larger size of accumulator vessel may be offset by the need for a smaller sized charging engine, in HP and physical size. 

Research is underway in large corporations and small companies. Focus has now switched to smaller vehicles. The system components were expensive which precluded installation in smaller trucks and cars. A drawback was that the power driving motors were not efficient enough at part load. A British company (Artemis Intelligent Power) made a breakthrough introducing an electronically controlled hydraulic motor/pump, the Digital Displacement® motor/pump. The pump is highly efficient at all speed ranges and loads, giving feasibility to small applications of petro-hydraulic hybrids. The company converted a BMW car as a test bed to prove viability. The BMW 530i, gave double the mpg in city driving compared to the standard car. This test was using the standard 3,000 cc engine, with a smaller engine the figures would have been more impressive. The design of petro-hydraulic hybrids using well sized accumulators allows downsizing an engine to average power usage, not peak power usage. Peak power is provided by the energy stored in the accumulator. A smaller more efficient constant speed engine reduces weight and liberates space for a larger accumulator.

Current vehicle bodies are designed around the mechanicals of existing engine/transmission setups. It is restrictive and far from ideal to install petro-hydraulic mechanicals into existing bodies not designed for hydraulic setups. One research project's goal is to create a blank paper design new car, to maximize the packaging of petro-hydraulic hybrid components in the vehicle. All bulky hydraulic components are integrated into the chassis of the car. One design has claimed to return 130 mpg in tests by using a large hydraulic accumulator which is also the structural chassis of the car. The small hydraulic driving motors are incorporated within the wheel hubs driving the wheels and reversing to claw-back kinetic braking energy. The hub motors eliminates the need for friction brakes, mechanical transmissions, drive shafts and U joints, reducing costs and weight. Hydrostatic drive with no friction brakes are used in industrial vehicles. The aim is 170 mpg in average driving conditions. Energy created by shock absorbers and kinetic braking energy that normally would be wasted assists in charging the accumulator. A small fossil fuelled piston engine sized for average power use charges the accumulator. The accumulator is sized at running the car for 15 minutes when fully charged. The aim is a fully charged accumulator which will produce a 0-60 mph acceleration speed of under 5 seconds using four wheel drive.

In January 2011 industry giant Chrysler announced a partnership with the US Environmental Protection Agency (EPA) to design and develop an experimental petro-hydraulic hybrid powertrain suitable for use in large passenger cars. In 2012 an existing production minvan was adapted to the new hydraulic powertrain for assessment.

PSA Peugeot Citroën exhibited an experimental "Hybrid Air" engine at the 2013 Geneva Motor Show. The vehicle uses nitrogen gas compressed by energy harvested from braking or deceleration to power a hydraulic drive which supplements power from its conventional gasoline engine. The hydraulic and electronic components were supplied by Robert Bosch GmbH. Mileage was estimated to be about 118 mpg‑US (2 L/100 km; 142 mpg‑imp) on the Euro test cycle if installed in a Citroën C3 type of body. PSA Although the car was ready for production and was proven and feasible delivering the claimed results, Peugeot Citroën were unable to attract a major manufacturer to share the high development costs and are shelving the project until a partnership can be arranged.

Electric-human power hybrid vehicle

Another form of hybrid vehicle are human power-electric vehicles. These include such vehicles as the Sinclair C5, Twike, electric bicycles, and electric skateboards.

Hybrid vehicle power train configurations

Parallel hybrid

Ford Escape Hybrid, a series-parallel drivetrain
 
In a parallel hybrid vehicle an electric motor and an internal combustion engine are coupled such that they can power the vehicle either individually or together. Most commonly the internal combustion engine, the electric motor and gear box are coupled by automatically controlled clutches. For electric driving the clutch between the internal combustion engine is open while the clutch to the gear box is engaged. While in combustion mode the engine and motor run at the same speed. 

The first mass production parallel hybrid sold outside Japan was the 1st generation Honda Insight.

Mild parallel hybrid

These types use a generally compact electric motor (usually <20 a="" acceleration="" aka="" and="" assist="" auto-stop="" class="mw-redirect" deceleration="" during="" extra="" features="" generate="" href="https://en.wikipedia.org/wiki/Regenerative_braking" kw="" nbsp="" on="" phase="" power="" provide="" start="" the="" title="Regenerative braking" to="">regenerative braking
). 

On-road examples include Honda Civic Hybrid, Honda Insight 2nd generation, Honda CR-Z, Honda Accord Hybrid, Mercedes Benz S400 BlueHYBRID, BMW 7 Series hybrids, General Motors BAS Hybrids, Suzuki S-Cross, Suzuki Wagon R and Smart fortwo with micro hybrid drive.

Power-split or series-parallel hybrid

In a power-split hybrid electric drive train there are two motors: a traction electric motor and an internal combustion engine. The power from these two motors can be shared to drive the wheels via a power split device, which is a simple planetary gear set. The ratio can be from 100% for the combustion engine to 100% for the traction electric motor, or anything in between, such as 40% for the electric motor and 60% for the combustion engine. The combustion engine can act as a generator charging the batteries. 

Modern versions such as the Toyota Hybrid Synergy Drive have a second electric motor/generator connected to the planetary gear. In cooperation with the traction motor/generator and the power-split device this provides a continuously variable transmission. 

On the open road, the primary power source is the internal combustion engine. When maximum power is required, for example to overtake, the traction electric motor is used to assist. This increases the available power for a short period, giving the effect of having a larger engine than actually installed. In most applications, the combustion engine is switched off when the car is slow or stationary thereby reducing curbside emissions. 

Passenger car installations include Toyota Prius, Ford Escape and Fusion, as well as Lexus RX400h, RX450h, GS450h, LS600h, and CT200h.

Series hybrid

Chevrolet Volt, a series hybrid plug-in hybrid, also called extended range electric vehicle (EREV).

A series- or serial-hybrid vehicle is driven by an electric motor, functioning as an electric vehicle while the battery pack energy supply is sufficient, with an engine tuned for running as a generator when the battery pack is insufficient. There is typically no mechanical connection between the engine and the wheels, and the primary purpose of the range extender is to charge the battery. Series-hybrids have also been referred to as extended range electric vehicle, range-extended electric vehicle, or electric vehicle-extended range (EREV/REEV/EVER).

The BMW i3 with Range Extender is a production series-hybrid. It operates as an electric vehicle until the battery charge is low, and then activates an engine-powered generator to maintain power, and is also available without the range extender. The Fisker Karma was the first series-hybrid production vehicle. 

When describing cars, the battery of a series-hybrid is usually charged by being plugged in - but a series-hybrid may also allow for a battery to only act as a buffer (and for regeneration purposes), and for the electric motor's power to be supplied constantly by a supporting engine. Series arrangements have been common in diesel-electric locomotives and ships. Ferdinand Porsche effectively invented this arrangement in speed-record-setting racing cars in the early 20th century, such as the Lohner-Porsche Mixte Hybrid. Porsche named his arrangement "System Mixt" and it was a wheel hub motor design, where each of the two front wheels was powered by a separate motor. This arrangement was sometimes referred to as an electric transmission, as the electric generator and driving motor replaced a mechanical transmission. The vehicle could not move unless the internal combustion engine was running. 

In 1997 Toyota released the first series-hybrid bus sold in Japan. GM introduced the Chevy Volt series plug-in hybrid in 2010, aiming for an all-electric range of 40 mi (64 km), though this car also has a mechanical connection between the engine and drivetrain. Supercapacitors combined with a lithium ion battery bank have been used by AFS Trinity in a converted Saturn Vue SUV vehicle. Using supercapacitors they claim up to 150 mpg in a series-hybrid arrangement.

Plug-in hybrid electric vehicle (PHEV)

The Toyota Prius Prime has an all-electric range of 25 mi (40 km).
 
The Ford Fusion Energi is a plug-in hybrid with an all-electric range of 21 mi (34 km).

Another subtype of hybrid vehicles is the plug-in hybrid electric vehicle (PHEV). The plug-in hybrid is usually a general fuel-electric (parallel or serial) hybrid with increased energy storage capacity, usually through a lithium-ion battery, which allows the vehicle to drive on all-electric mode a distance that depends on the battery size and its mechanical layout (series or parallel). It may be connected to mains electricity supply at the end of the journey to avoid charging using the on-board internal combustion engine.

This concept is attractive to those seeking to minimize on-road emissions by avoiding – or at least minimizing – the use of ICE during daily driving. As with pure electric vehicles, the total emissions saving, for example in CO2 terms, is dependent upon the energy source of the electricity generating company. 

For some users, this type of vehicle may also be financially attractive so long as the electrical energy being used is cheaper than the petrol/diesel that they would have otherwise used. Current tax systems in many European countries use mineral oil taxation as a major income source. This is generally not the case for electricity, which is taxed uniformly for the domestic customer, however that person uses it. Some electricity suppliers also offer price benefits for off-peak night users, which may further increase the attractiveness of the plug-in option for commuters and urban motorists.

Road safety for cyclists, pedestrians

The Nissan Leaf was the first plug-in electric car equipped with Nissan's Vehicle Sound for Pedestrians.

A 2009 National Highway Traffic Safety Administration report examined hybrid electric vehicle accidents that involved pedestrians and cyclists and compared them to accidents involving internal combustion engine vehicles (ICEV). The findings showed that, in certain road situations, HEVs are more dangerous for those on foot or bicycle. For accidents where a vehicle was slowing or stopping, backing up, entering or leaving a parking space (when the sound difference between HEVs and ICEVs is most pronounced), HEVs were twice as likely to be involved in a pedestrian crash than ICEVs. For crashes involving cyclists or pedestrians, there was a higher incident rate for HEVs than ICEVs when a vehicle was turning a corner. But there was no statistically significant difference between the types of vehicles when they were driving straight.

Several automakers developed electric vehicle warning sounds designed to alert pedestrians to the presence of electric drive vehicles such as hybrid electric vehicle, plug-in hybrid electric vehicles and all-electric vehicles (EVs) travelling at low speeds. Their purpose is to make pedestrians, cyclists, the blind, and others aware of the vehicle's presence while operating in all-electric mode.

Vehicles in the market with such safety devices include the Nissan Leaf, Chevrolet Volt, Fisker Karma, Honda FCX Clarity, Nissan Fuga Hybrid/Infiniti M35, Hyundai ix35 FCEV, Hyundai Sonata Hybrid, 2012 Honda Fit EV, the 2012 Toyota Camry Hybrid, 2012 Lexus CT200h, and all Prius family cars recently introduced, including the standard 2012 model year Prius, the Toyota Prius v, and the Toyota Prius Plug-in Hybrid.

Environmental issues

Fuel consumption and emissions reductions

The hybrid vehicle typically achieves greater fuel economy and lower emissions than conventional internal combustion engine vehicles (ICEVs), resulting in fewer emissions being generated. These savings are primarily achieved by three elements of a typical hybrid design:
  • Relying on both the engine and the electric motors for peak power needs, resulting in a smaller engine size more for average usage rather than peak power usage. A smaller engine can have less internal losses and lower weight.
  • Having significant battery storage capacity to store and reuse recaptured energy, especially in stop-and-go traffic typical of the city driving cycle.
  • Recapturing significant amounts of energy during braking that are normally wasted as heat. This regenerative braking reduces vehicle speed by converting some of its kinetic energy into electricity, depending upon the power rating of the motor/generator.
Other techniques that are not necessarily 'hybrid' features, but that are frequently found on hybrid vehicles include:
  • Using Atkinson cycle engines instead of Otto cycle engines for improved fuel economy.
  • Shutting down the engine during traffic stops or while coasting or during other idle periods.
  • Improving aerodynamics; (part of the reason that SUVs get such bad fuel economy is the drag on the car. A box shaped car or truck has to exert more force to move through the air causing more stress on the engine making it work harder). Improving the shape and aerodynamics of a car is a good way to help better the fuel economy and also improve vehicle handling at the same time.
  • Using low rolling resistance tires (tires were often made to give a quiet, smooth ride, high grip, etc., but efficiency was a lower priority). Tires cause mechanical drag, once again making the engine work harder, consuming more fuel. Hybrid cars may use special tires that are more inflated than regular tires and stiffer or by choice of carcass structure and rubber compound have lower rolling resistance while retaining acceptable grip, and so improving fuel economy whatever the power source.
  • Powering the a/c, power steering, and other auxiliary pumps electrically as and when needed; this reduces mechanical losses when compared with driving them continuously with traditional engine belts.
These features make a hybrid vehicle particularly efficient for city traffic where there are frequent stops, coasting and idling periods. In addition noise emissions are reduced, particularly at idling and low operating speeds, in comparison to conventional engine vehicles. For continuous high speed highway use these features are much less useful in reducing emissions.

Hybrid vehicle emissions

Hybrid vehicle emissions today are getting close to or even lower than the recommended level set by the EPA (Environmental Protection Agency). The recommended levels they suggest for a typical passenger vehicle should be equated to 5.5 metric tons of CO2. The three most popular hybrid vehicles, Honda Civic, Honda Insight and Toyota Prius, set the standards even higher by producing 4.1, 3.5, and 3.5 tons showing a major improvement in carbon dioxide emissions. Hybrid vehicles can reduce air emissions of smog-forming pollutants by up to 90% and cut carbon dioxide emissions in half.

More fossil fuel is needed to build hybrid vehicles than conventional cars but reduced emissions when running the vehicle more than outweigh this.

Environmental impact of hybrid car battery

Though hybrid cars consume less fuel than conventional cars, there is still an issue regarding the environmental damage of the hybrid car battery. Today most hybrid car batteries are one of two types: 1) nickel metal hydride, or 2) lithium ion; both are regarded as more environmentally friendly than lead-based batteries which constitute the bulk of petrol car starter batteries today. There are many types of batteries. Some are far more toxic than others. Lithium ion is the least toxic of the two mentioned above.

The toxicity levels and environmental impact of nickel metal hydride batteries—the type currently used in hybrids—are much lower than batteries like lead acid or nickel cadmium according to one source. Another source claims nickel metal hydride batteries are much more toxic than lead batteries, also that recycling them and disposing of them safely is difficult. In general various soluble and insoluble nickel compounds, such as nickel chloride and nickel oxide, have known carcinogenic effects in chick embryos and rats. The main nickel compound in NiMH batteries is nickel oxyhydroxide (NiOOH), which is used as the positive electrode.

The lithium-ion battery has attracted attention due to its potential for use in hybrid electric vehicles. Hitachi is a leader in its development. In addition to its smaller size and lighter weight, lithium-ion batteries deliver performance that helps to protect the environment with features such as improved charge efficiency without memory effect. The lithium-ion batteries are appealing because they have the highest energy density of any rechargeable batteries and can produce a voltage more than three times that of nickel–metal hydride battery cell while simultaneously storing large quantities of electricity as well. The batteries also produce higher output (boosting vehicle power), higher efficiency (avoiding wasteful use of electricity), and provides excellent durability, compared with the life of the battery being roughly equivalent to the life of the vehicle. Additionally, use of lithium-ion batteries reduces the overall weight of the vehicle and also achieves improved fuel economy of 30% better than petro-powered vehicles with a consequent reduction in CO2 emissions helping to prevent global warming. 

Charging

There is two different levels of charging. Level one charging is the slower method as it uses a 120 V/15 A single-phase grounded outlet. Level two is a faster method; existing Level 2 equipment offers charging from 208 V or 240 V (at up to 80 A, 19.2 kW). It may require dedicated equipment and a connection installation for home or public units, although vehicles such as the Tesla have the power electronics on board and need only the outlet. The optimum charging window for Lithium ion batteries is 3-4.2 V. Recharging with a 120 volt household outlet takes several hours, a 240 volt charger takes 1–4 hours, and a quick charge takes approximately 30 minutes to achieve 80% charge. Three important factors—distance on charge, cost of charging, and time to charge In order for the hybrid to run on electrical power, the car must perform the action of braking in order to generate some electricity. The electricity then gets discharged most effectively when the car accelerates or climbs up an incline. In 2014, hybrid electric car batteries can run on solely electricity for 70–130 miles (110–210 km) on a single charge. Hybrid battery capacity currently ranges from 4.4 kWh to 85 kWh on a fully electric car. On a hybrid car, the battery packs currently range from 0.6 kWh to 2.4 kWh representing a large difference in use of electricity in hybrid cars.

Raw materials increasing costs

There is an impending increase in the costs of many rare materials used in the manufacture of hybrid cars. For example, the rare earth element dysprosium is required to fabricate many of the advanced electric motors and battery systems in hybrid propulsion systems. Neodymium is another rare earth metal which is a crucial ingredient in high-strength magnets that are found in permanent magnet electric motors.

Nearly all the rare earth elements in the world come from China, and many analysts believe that an overall increase in Chinese electronics manufacturing will consume this entire supply by 2012. In addition, export quotas on Chinese rare earth elements have resulted in an unknown amount of supply.

A few non-Chinese sources such as the advanced Hoidas Lake project in northern Canada as well as Mount Weld in Australia are currently under development; however, the barriers to entry are high and require years to go online.

How hybrid-electric vehicles work

Hybrids-Electric vehicles (HEVs) combine the advantage of gasoline engines and electric motors. The key areas for efficiency or performance gains are regenerative braking, dual power sources, and less idling.
  • Regenerate Braking. The drivetrain can be used to convert kinetic energy (from the moving car) into stored electrical energy (batteries). The same electric motor that powers the drivetrain is used to resist the motion of the drivetrain. This applied resistance from the electric motor causes the wheel to slow down and simultaneously recharge the batteries.
  • Dual Power. Power can come from either the engine, motor or both depending on driving circumstances. Additional power to assist the engine in accelerating or climbing might be provided by the electric motor. Or more commonly, a smaller electric motor provides all of the power for low-speed driving conditions and is augmented by the engine at higher speeds.
  • Automatic Start/Shutoff. It automatically shuts off the engine when the vehicle comes to a stop and restarts it when the accelerator is pressed down. This automation is much simpler with an electric motor. Also see dual power above.

Alternative green vehicles

Other types of green vehicles include other vehicles that go fully or partly on alternative energy sources than fossil fuel. Another option is to use alternative fuel composition (i.e. biofuels) in conventional fossil fuel-based vehicles, making them go partly on renewable energy sources. 

Other approaches include personal rapid transit, a public transportation concept that offers automated on-demand non-stop transportation, on a network of specially built guideways.

Peugeot/Citroën Hybrid Vehicle

Peugeot and Citroën have announced that they too are building a car that uses compressed air as an energy source. However, the car they are designing uses a hybrid system which also uses a gasoline engine (which is used for propelling the car over 70 km/h, or when the compressed air tank has been depleted.

Marketing

Automakers spend around $US8 million in marketing Hybrid vehicles each year. With combined effort from many car companies, the Hybrid industry has sold millions of Hybrids. Hybrid car companies like Toyota, Honda, Ford and BMW have pulled together to create a movement of Hybrid vehicle sales pushed by Washington lobbyist to lower the worlds emissions and become less reliant on our petroleum consumption. In 2005, sales went beyond 200,000 Hybrids, but in retrospect that only reduced the global use for gasoline consumption by 200,000 gallons per day — a tiny fraction of the 360 million gallons used per day. According to Bradley Berman author of Driving Change—One Hybrid at a time, "Cold economics shows that in real dollars, except for a brief spike in the 1970s, gas prices have remained remarkably steady and cheap. Fuel continues to represent a small part of the overall cost of owning and operating a personal vehicle". Other marketing tactics include greenwashing which is the "unjustified appropriation of environmental virtue." Temma Ehrenfeld explained in an article by Newsweek. Hybrids may be more efficient than many other gasoline motors as far as gasoline consumption is concerned but as far as being green and good for the environment is completely inaccurate. Hybrid car companies have a long time to go if they expect to really go green. According to Harvard business professor Theodore Levitt states "managing products" and "meeting customers' needs", "you must adapt to consumer expectations and anticipation of future desires." This means people buy what they want, if they want a fuel efficient car they buy a Hybrid without thinking about the actual efficiency of the product. This "Green Myopia" as Ottman calls it, fails because marketers focus on the greenness of the product and not on the actual effectiveness. Researchers and analysts say people are drawn to the new technology, as well as the convenience of fewer fill ups. Secondly, people find it rewarding to own the better, newer, flashier, and so called greener car. In the beginning of the Hybrid movement car companies reached out to the young people, by using top celebrities, astronauts, and popular TV shows to market Hybrids. This made the new technology of Hybrids a status to obtain for many people and a must to be cool or even the practical choice for the time. With the many benefits and status of owning a Hybrid it is easy to think it's the right thing to do, but in fact may not be as green as it appears.

Adoption rate

While the adoption rate for hybrids in the US is small today (2.2% of new car sales in 2011), this compares with a 17.1% share of new car sales in Japan in 2011, and it has the potential to be very large over time as more models are offered and incremental costs decline due to learning and scale benefits. However, forecasts vary widely. For instance, Bob Lutz, a long-time skeptic of hybrids, indicated he expects hybrids "will never comprise more than 10% of the US auto market." Other sources also expect hybrid penetration rates in the US will remain under 10% for many years.

More optimistic views as of 2006 include predictions that hybrids would dominate new car sales in the US and elsewhere over the next 10 to 20 years. Another approach, taken by Saurin Shah, examines the penetration rates (or S-curves) of four analogs (historical and current) to hybrid and electrical vehicles in an attempt to gauge how quickly the vehicle stock could be hybridized and/or electrified in the United States. The analogs are (1) the electric motors in US factories in the early 20th century, (2) diesel electric locomotives on US railways in the 1920–1945 period, (3) a range of new automotive features/technologies introduced in the US over the past fifty years, and 4) e-bike purchases in China over the past few years. These analogs collectively suggest it would take at least 30 years for hybrid and electric vehicles to capture 80% of the US passenger vehicle stock. 

European Union 2020 Regulation Standards

The European Parliament, Council and European Commission has reached an agreement which is aimed at reducing the average CO2 passenger car emissions to 95 g/km by 2020, according to a European Commission press release. 

According to the release, the key details of the agreement are as follows: 

Emissions target: The agreement will reduce average CO2 emissions from new cars to 95 g/km from 2020, as proposed by the Commission. This is a 40% reduction from the mandatory 2015 target of 130 g/km. The target is an average for each manufacturer's new car fleet; it allows OEMs to build some vehicles that emit less than the average and some that emit more. 2025 target: The Commission is required to propose a further emissions reduction target by end-2015 to take effect in 2025. This target will be in line with the EU's long-term climate goals. Supercredits for low-emission vehicles: The Regulation will give manufacturers additional incentives to produce cars with CO2 emissions of 50 g/km or less (which will be electric or plug-in hybrid cars). Each of these vehicles will be counted as two vehicles in 2020, 1.67 in 2021, 1.33 in 2022 and then as one vehicle from 2023 onwards. These supercredits will help manufacturers further reduce the average emissions of their new car fleet. However, to prevent the scheme from undermining the environmental integrity of the legislation, there will be a 2.5 g/km cap per manufacturer on the contribution that supercredits can make to their target in any year.

Emulsion

From Wikipedia, the free encyclopedia

  1. Two immiscible liquids, not yet emulsified
  2. An emulsion of Phase II dispersed in Phase I
  3. The unstable emulsion progressively separates
  4. The surfactant (outline around particles) positions itself on the interfaces between Phase II and Phase I, stabilizing the emulsion
An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable). Emulsions are part of a more general class of two-phase systems of matter called colloids. Although the terms colloid and emulsion are sometimes used interchangeably, emulsion should be used when both phases, dispersed and continuous, are liquids. In an emulsion, one liquid (the dispersed phase) is dispersed in the other (the continuous phase). Examples of emulsions include vinaigrettes, homogenized milk, and some cutting fluids for metal working. Graphene and its modified forms are also a good example of recent unconventional surfactants helping in stabilizing emulsion systems.

The word "emulsion" comes from the Latin mulgeo, mulgere "to milk", as milk is an emulsion of fat and water, along with other components.

Two liquids can form different types of emulsions. As an example, oil and water can form, first, an oil-in-water emulsion, wherein the oil is the dispersed phase, and water is the dispersion medium. (Lipoproteins, used by all complex living organisms, are one example of this.) Second, they can form a water-in-oil emulsion, wherein water is the dispersed phase and oil is the external phase. Multiple emulsions are also possible, including a "water-in-oil-in-water" emulsion and an "oil-in-water-in-oil" emulsion.

Emulsions, being liquids, do not exhibit a static internal structure. The droplets dispersed in the liquid matrix (called the “dispersion medium”) are usually assumed to be statistically distributed.

The term "emulsion" is also used to refer to the photo-sensitive side of photographic film. Such a photographic emulsion consists of silver halide colloidal particles dispersed in a gelatin matrix. Nuclear emulsions are similar to photographic emulsions, except that they are used in particle physics to detect high-energy elementary particles.

Appearance and properties

IUPAC definition: fluid system in which liquid droplets are dispersed in a liquid. The droplets may be amorphous, liquid-crystalline, or any mixture thereof.
The diameters of the droplets constituting the dispersed phase usually range from approximately 10 nm to 100 μm; i.e., the droplets may exceed the usual size limits for colloidal particles.

An emulsion is termed an oil/water (o/w) emulsion if the dispersed phase is an organic material and the continuous phase is water or an aqueous solution and is termed water/oil (w/o) if the dispersed phase is water or an aqueous solution and the continuous phase is an organic liquid (an "oil").
 
A w/o emulsion is sometimes called an inverse emulsion. The term "inverse emulsion" is misleading, suggesting incorrectly that the emulsion has properties that are the opposite of those of an emulsion. Its use is, therefore, not recommended.

Emulsions contain both a dispersed and a continuous phase, with the boundary between the phases called the "interface". Emulsions tend to have a cloudy appearance because the many phase interfaces scatter light as it passes through the emulsion. Emulsions appear white when all light is scattered equally. If the emulsion is dilute enough, higher-frequency (low-wavelength) light will be scattered more, and the emulsion will appear bluer – this is called the "Tyndall effect". If the emulsion is concentrated enough, the color will be distorted toward comparatively longer wavelengths, and will appear more yellow. This phenomenon is easily observable when comparing skimmed milk, which contains little fat, to cream, which contains a much higher concentration of milk fat. One example would be a mixture of water and oil.

Two special classes of emulsions – microemulsions and nanoemulsions, with droplet sizes below 100 nm – appear translucent. This property is due to the fact that light waves are scattered by the droplets only if their sizes exceed about one-quarter of the wavelength of the incident light. Since the visible spectrum of light is composed of wavelengths between 390 and 750 nanometers (nm), if the droplet sizes in the emulsion are below about 100 nm, the light can penetrate through the emulsion without being scattered. Due to their similarity in appearance, translucent nanoemulsions and microemulsions are frequently confused. Unlike translucent nanoemulsions, which require specialized equipment to be produced, microemulsions are spontaneously formed by “solubilizing” oil molecules with a mixture of surfactants, co-surfactants, and co-solvents. The required surfactant concentration in a microemulsion is, however, several times higher than that in a translucent nanoemulsion, and significantly exceeds the concentration of the dispersed phase. Because of many undesirable side-effects caused by surfactants, their presence is disadvantageous or prohibitive in many applications. In addition, the stability of a microemulsion is often easily compromised by dilution, by heating, or by changing pH levels.

Common emulsions are inherently unstable and, thus, do not tend to form spontaneously. Energy input – through shaking, stirring, homogenizing, or exposure to power ultrasound – is needed to form an emulsion. Over time, emulsions tend to revert to the stable state of the phases comprising the emulsion. An example of this is seen in the separation of the oil and vinegar components of vinaigrette, an unstable emulsion that will quickly separate unless shaken almost continuously. There are important exceptions to this rule – microemulsions are thermodynamically stable, while translucent nanoemulsions are kinetically stable.

Whether an emulsion of oil and water turns into a "water-in-oil" emulsion or an "oil-in-water" emulsion depends on the volume fraction of both phases and the type of emulsifier (surfactant) (see Emulsifier, below) present. In general, the Bancroft rule applies. Emulsifiers and emulsifying particles tend to promote dispersion of the phase in which they do not dissolve very well. For example, proteins dissolve better in water than in oil, and so tend to form oil-in-water emulsions (that is, they promote the dispersion of oil droplets throughout a continuous phase of water).

The geometric structure of an emulsion mixture of two lyophobic liquids with a large concentration of the secondary component is fractal: Emulsion particles unavoidably form dynamic inhomogeneous structures on small length scale. The geometry of these structures is fractal. The size of elementary irregularities is governed by a universal function which depends on the volume content of the components. The fractal dimension of these irregularities is 2.5.

Instability

Emulsion stability refers to the ability of an emulsion to resist change in its properties over time. There are four types of instability in emulsions: flocculation, creaming/sedimentation, coalescence, and Ostwald ripening. Flocculation occurs when there is an attractive force between the droplets, so they form flocs, like bunches of grapes. Coalescence occurs when droplets bump into each other and combine to form a larger droplet, so the average droplet size increases over time. Emulsions can also undergo creaming, where the droplets rise to the top of the emulsion under the influence of buoyancy, or under the influence of the centripetal force induced when a centrifuge is used. Creaming is a common phenomenon in dairy and non-dairy beverages (i.e. milk, coffee milk, almond milk, soy milk) and usually does not change the droplet size. Sedimentation is the opposite phenomenon of creaming and normally observed in water-in-oil emulsions. Sedimentation happens when the dispersed phase is denser than the continuous phase and the gravitational forces pull the denser globules towards the bottom of the emulsion. Similar to creaming, sedimentation follows Stoke’s law.
An appropriate "surface active agent" (or "surfactant") can increase the kinetic stability of an emulsion so that the size of the droplets does not change significantly with time. It is then said to be stable. For example, oil-in-water emulsions containing mono- and diglycerides and milk protein as surfactant showed that stable oil droplet size over 28 days storage at 25°C.

Monitoring physical stability

The stability of emulsions can be characterized using techniques such as light scattering, focused beam reflectance measurement, centrifugation, and rheology. Each method has advantages and disadvantages.

Accelerating methods for shelf life prediction

The kinetic process of destabilization can be rather long – up to several months, or even years for some products. Often the formulator must accelerate this process in order to test products in a reasonable time during product design. Thermal methods are the most commonly used – these consist of increasing the emulsion temperature to accelerate destabilization (if below critical temperatures for phase inversion or chemical degradation). Temperature affects not only the viscosity but also the inter-facial tension in the case of non-ionic surfactants or, on a broader scope, interactions of forces inside the system. Storing an emulsion at high temperatures enables the simulation of realistic conditions for a product (e.g., a tube of sunscreen emulsion in a car in the summer heat), but also to accelerate destabilization processes up to 200 times.

Mechanical methods of acceleration, including vibration, centrifugation, and agitation, can also be used.

These methods are almost always empirical, without a sound scientific basis.

Emulsifiers

An emulsifier (also known as an "emulgent") is a substance that stabilizes an emulsion by increasing its kinetic stability. One class of emulsifiers is known as "surface active agents", or surfactants. Emulsifiers are compounds that typically have a polar or hydrophilic (i.e. water-soluble) part and a non-polar (i.e. hydrophobic or lipophilic) part. Because of this, emulsifiers tend to have more or less solubility either in water or in oil. Emulsifiers that are more soluble in water (and conversely, less soluble in oil) will generally form oil-in-water emulsions, while emulsifiers that are more soluble in oil will form water-in-oil emulsions.

Examples of food emulsifiers are:
Detergents are another class of surfactant, and will interact physically with both oil and water, thus stabilizing the interface between the oil and water droplets in suspension. This principle is exploited in soap, to remove grease for the purpose of cleaning. Many different emulsifiers are used in pharmacy to prepare emulsions such as creams and lotions. Common examples include emulsifying wax, polysorbate 20, and ceteareth 20.

Sometimes the inner phase itself can act as an emulsifier, and the result is a nanoemulsion, where the inner state disperses into "nano-size" droplets within the outer phase. A well-known example of this phenomenon, the "Ouzo effect", happens when water is poured into a strong alcoholic anise-based beverage, such as ouzo, pastis, absinthe, arak, or raki. The anisolic compounds, which are soluble in ethanol, then form nano-size droplets and emulsify within the water. The resulting color of the drink is opaque and milky white.

Mechanisms of emulsification

A number of different chemical and physical processes and mechanisms can be involved in the process of emulsification:
  • Surface tension theory – according to this theory, emulsification takes place by reduction of interfacial tension between two phases
  • Repulsion theory – the emulsifying agent creates a film over one phase that forms globules, which repel each other. This repulsive force causes them to remain suspended in the dispersion medium
  • Viscosity modification – emulgents like acacia and tragacanth, which are hydrocolloids, as well as PEG (or polyethylene glycol), glycerine, and other polymers like CMC (carboxymethyl cellulose), all increase the viscosity of the medium, which helps create and maintain the suspension of globules of dispersed phase

Uses

In food

Oil-in-water emulsions are common in food products:
  • Crema (foam) in espresso – coffee oil in water (brewed coffee), unstable emulsion
  • Mayonnaise and Hollandaise sauces – these are oil-in-water emulsions stabilized with egg yolk lecithin, or with other types of food additives, such as sodium stearoyl lactylate
  • Homogenized milk – an emulsion of milk fat in water, with milk proteins as the emulsifier
  • Vinaigrette – an emulsion of vegetable oil in vinegar, if this is prepared using only oil and vinegar (i.e., without an emulsifier), an unstable emulsion results
Water-in-oil emulsions are less common in food, but still exist:
Other foods can be turned into products similar to emulsions, for example meat emulsion is a suspension of meat in liquid that is similar to true emulsions.

Health care

In pharmaceutics, hairstyling, personal hygiene, and cosmetics, emulsions are frequently used. These are usually oil and water emulsions but dispersed, and which is continuous depends in many cases on the pharmaceutical formulation. These emulsions may be called creams, ointments, liniments (balms), pastes, films, or liquids, depending mostly on their oil-to-water ratios, other additives, and their intended route of administration. The first 5 are topical dosage forms, and may be used on the surface of the skin, transdermally, ophthalmically, rectally, or vaginally. A highly liquid emulsion may also be used orally, or may be injected in some cases.

Microemulsions are used to deliver vaccines and kill microbes. Typical emulsions used in these techniques are nanoemulsions of soybean oil, with particles that are 400–600 nm in diameter. The process is not chemical, as with other types of antimicrobial treatments, but mechanical. The smaller the droplet the greater the surface tension and thus the greater the force required to merge with other lipids. The oil is emulsified with detergents using a high-shear mixer to stabilize the emulsion so, when they encounter the lipids in the cell membrane or envelope of bacteria or viruses, they force the lipids to merge with themselves. On a mass scale, in effect this disintegrates the membrane and kills the pathogen. The soybean oil emulsion does not harm normal human cells, or the cells of most other higher organisms, with the exceptions of sperm cells and blood cells, which are vulnerable to nanoemulsions due to the peculiarities of their membrane structures. For this reason, these nanoemulsions are not currently used intravenously (IV). The most effective application of this type of nanoemulsion is for the disinfection of surfaces. Some types of nanoemulsions have been shown to effectively destroy HIV-1 and tuberculosis pathogens on non-porous surfaces.

In firefighting

Emulsifying agents are effective at extinguishing fires on small, thin-layer spills of flammable liquids (class B fires). Such agents encapsulate the fuel in a fuel-water emulsion, thereby trapping the flammable vapors in the water phase. This emulsion is achieved by applying an aqueous surfactant solution to the fuel through a high-pressure nozzle. Emulsifiers are not effective at extinguishing large fires involving bulk/deep liquid fuels, because the amount of emulsifier agent needed for extinguishment is a function of the volume of the fuel, whereas other agents such as aqueous film-forming foam need cover only the surface of the fuel to achieve vapor mitigation.

Chemical synthesis

Emulsions are used to manufacture polymer dispersions – polymer production in an emulsion 'phase' has a number of process advantages, including prevention of coagulation of product. Products produced by such polymerisations may be used as the emulsions – products including primary components for glues and paints. Synthetic latexes (rubbers) are also produced by this process.

Surfactant

From Wikipedia, the free encyclopedia

Schematic diagram of a micelle of oil in aqueous suspension, such as might occur in an emulsion of oil in water. In this example, the surfactant molecules' oil-soluble tails project into the oil (blue), while the water-soluble ends remain in contact with the water phase (red).

Surfactants are compounds that lower the surface tension (or interfacial tension) between two liquids, between a gas and a liquid, or between a liquid and a solid. Surfactants may act as detergents, wetting agents, emulsifiers, foaming agents, and dispersants.

Etymology and definition

The term surfactant is a blend of surface active agent.

In the United States National Library of Medicine's Medical Subject Headings (MeSH) vocabulary, surfactant is reserved for the meaning pulmonary surfactant. For the more general meaning, surface active agent/s is the heading. 

Schematic diagram of a micelle – the lipophilic tails of the surfactant ions remain inside the oil because they interact more strongly with oil than with water. The polar "heads" of the surfactant molecules coating the micelle interact more strongly with water, so they form a hydrophilic outer layer that forms a barrier between micelles. This inhibits the oil droplets, the hydrophobic cores of micelles, from merging into fewer, larger droplets ("emulsion breaking") of the micelle. The compounds that coat a micelle are typically amphiphilic in nature, meaning that micelles may be stable either as droplets of aprotic solvents such as oil in water, or as protic solvents such as water in oil. When the droplet is aprotic it sometimes is known as a reverse micelle.

Composition and structure

Surfactants are usually organic compounds that are amphiphilic, meaning they contain both hydrophobic groups (their tails) and hydrophilic groups (their heads). Therefore, a surfactant contains both a water-insoluble (or oil-soluble) component and a water-soluble component. Surfactants will diffuse in water and adsorb at interfaces between air and water or at the interface between oil and water, in the case where water is mixed with oil. The water-insoluble hydrophobic group may extend out of the bulk water phase, into the air or into the oil phase, while the water-soluble head group remains in the water phase.

World production of surfactants is estimated at 15 Mton/y, of which about half are soaps. Other surfactants produced on a particularly large scale are linear alkylbenzene sulfonates (1700 kton/y), lignin sulfonates (600 kton/y), fatty alcohol ethoxylates (700 ktons/y), and alkylphenol ethoxylates (500 kton/y).

Sodium stearate, the most common component of most soap, which comprises about 50% of commercial surfactants
 
4-(5-Dodecyl) benzenesulfonate, a linear dodecylbenzenesulfonate, one of the most common surfactants

Structure of surfactant phases in water

In the bulk aqueous phase, surfactants form aggregates, such as micelles, where the hydrophobic tails form the core of the aggregate and the hydrophilic heads are in contact with the surrounding liquid. Other types of aggregates can also be formed, such as spherical or cylindrical micelles or lipid bilayers. The shape of the aggregates depends on the chemical structure of the surfactants, namely the balance in size between the hydrophilic head and hydrophobic tail. A measure of this is the HLB, Hydrophilic-lipophilic balance. Surfactants reduce the surface tension of water by adsorbing at the liquid-air interface. The relation that links the surface tension and the surface excess is known as the Gibbs isotherm.

Dynamics of surfactants at interfaces

The dynamics of surfactant adsorption is of great importance for practical applications such as in foaming, emulsifying or coating processes, where bubbles or drops are rapidly generated and need to be stabilized. The dynamics of adsorption depend on the diffusion coefficient of the surfactant. As the interface is created, the adsorption is limited by the diffusion of the surfactant to the interface. In some cases, there can exist an energetic barrier to adsorption or desorption of the surfactant. If such a barrier limits the adsorption rate, the dynamics are said to be ‘kinetically limited'. Such energy barriers can be due to steric or electrostatic repulsions. The surface rheology of surfactant layers, including the elasticity and viscosity of the layer, play an important role in the stability of foams and emulsions.

Characterization of interfaces and surfactant layers

Interfacial and surface tension can be characterized by classical methods such as the -pendant or spinning drop method. Dynamic surface tensions, i.e. surface tension as a function of time, can be obtained by the maximum bubble pressure apparatus.
 
The structure of surfactant layers can be studied by ellipsometry or X-Ray reflectivity. 

Surface rheology can be characterized by the oscillating drop method or shear surface rheometers such as double-cone, double-ring or magnetic rod shear surface rheometer.

Detergents in biochemistry and biotechnology

In solution, detergents help solubilize a variety of chemical species by dissociating aggregates and unfolding proteins. Popular surfactants in the biochemistry laboratory are SDS and CTAB. Detergents are key reagents to extract protein by lysis of the cells and tissues: They disorganize the membrane's lipidic bilayer (SDS, Triton X-100, X-114, CHAPS, DOC, and NP-40), and solubilize proteins. Milder detergents such as octyl thioglucoside, octyl glucoside or dodecyl maltoside are used to solubilize membrane proteins such as enzymes and receptors without denaturing them. Non-solubilized material is harvested by centrifugation or other means. For electrophoresis, for example, proteins are classically treated with SDS to denature the native tertiary and quaternary structures, allowing the separation of proteins according to their molecular weight

Detergents have also been used to decellularise organs. This process maintains a matrix of proteins that preserves the structure of the organ and often the microvascular network. The process has been successfully used to prepare organs such as the liver and heart for transplant in rats. Pulmonary surfactants are also naturally secreted by type II cells of the lung alveoli in mammals.

Classification

The "tails" of most surfactants are fairly similar, consisting of a hydrocarbon chain, which can be branched, linear, or aromatic. Fluorosurfactants have fluorocarbon chains. Siloxane surfactants have siloxane chains. 

Many important surfactants include a polyether chain terminating in a highly polar anionic group. The polyether groups often comprise ethoxylated (polyethylene oxide-like) sequences inserted to increase the hydrophilic character of a surfactant. Polypropylene oxides conversely, may be inserted to increase the lipophilic character of a surfactant. 

Surfactant molecules have either one tail or two; those with two tails are said to be double-chained

Surfactant classification according to the composition of their head: nonionic, anionic, cationic, amphoteric.

Most commonly, surfactants are classified according to polar head group. A non-ionic surfactant has no charged groups in its head. The head of an ionic surfactant carries a net positive, or negative charge. If the charge is negative, the surfactant is more specifically called anionic; if the charge is positive, it is called cationic. If a surfactant contains a head with two oppositely charged groups, it is termed zwitterionic. Commonly encountered surfactants of each type include: 

Anionic:

Sulfate, sulfonate, and phosphate esters:

Anionic surfactants contain anionic functional groups at their head, such as sulfate, sulfonate, phosphate, and carboxylates. Prominent alkyl sulfates include ammonium lauryl sulfate, sodium lauryl sulfate (sodium dodecyl sulfate, SLS, or SDS), and the related alkyl-ether sulfates sodium laureth sulfate (sodium lauryl ether sulfate or SLES), and sodium myreth sulfate

Carboxylates:

These are the most common surfactants and comprise the carboxylate salts (soaps), such as sodium stearate. More specialized species include sodium lauroyl sarcosinate and carboxylate-based fluorosurfactants such as perfluorononanoate, perfluorooctanoate (PFOA or PFO). 

Others include:
Cationic head groups:

pH-dependent primary, secondary, or tertiary amines; primary and secondary amines become positively charged at pH less than 10: octenidine dihydrochloride


Zwitterionic surfactants:

Zwitterionic (amphoteric) surfactants have both cationic and anionic centers attached to the same molecule. The cationic part is based on primary, secondary, or tertiary amines or quaternary ammonium cations. The anionic part can be more variable and include sulfonates, as in the sultaines CHAPS (3-[(3-Cholamidopropyl)dimethylammonio]-1-propanesulfonate) and cocamidopropyl hydroxysultaine. Betaines such as cocamidopropyl betaine have a carboxylate with the ammonium. The most common biological zwitterionic surfactants have a phosphate anion with an amine or ammonium, such as the phospholipids phosphatidylserine, phosphatidylethanolamine, phosphatidylcholine, and sphingomyelins

Nonionic:

Nonionic surfactants have covalently bonded oxygen-containing hydrophilic groups, which are bonded to hydrophobic parent structures. The water-solubility of the oxygen groups is the result of hydrogen bonding. Hydrogen bonding decreases with increasing temperature, and the water solubility of nonionic surfactants therefore decreases with increasing temperature. 

Nonionic surfactants are less sensitive to water hardness than anionic surfactants, and they foam less strongly. The differences between the individual types of nonionic surfactants are slight, and the choice is primarily governed having regard to the costs of special properties (e.g., effectiveness and efficiency, toxicity, dermatological compatibility, biodegradability) or permission for use in food.

Ethoxylates:
Fatty alcohol ethoxylates:
Alkylphenol ethoxylates:
Fatty acid ethoxylates
Ethoxylated amines and/or fatty acid amides:
Terminally blocked ethoxylates:
Fatty acid esters of polyhydroxy compounds:
Fatty acid esters of glycerol:
Fatty acid esters of sorbitol:
Alkyl polyglucosides:

Amine oxides:

Sulfoxides:

Phosphine oxides

According to the composition of their counter-ion

In the case of ionic surfactants, the counter-ion can be:

In pharmacy

A wetting agent is a surfactant that, when dissolved in water, lowers the advancing contact angle, aids in displacing an air phase at the surface, and replaces it with a liquid phase. Examples of application of wetting to pharmacy and medicine include the displacement of air from the surface of sulfur, charcoal, and other powders for the purpose of dispersing these drugs in liquid vehicles; the displacement of air from the matrix of cotton pads and bandages so that medicinal solutions can be absorbed for application to various body areas; the displacement of dirt and debris by the use of detergents in the washing of wounds; and the application of medicinal lotions and sprays to surface of skin and mucous membranes.

Pharmaceutical forms

The human body produces different types of surfactant in different parts or organs for different purposes. Pulmonary surfactant is produced in lungs in order to facilitate breathing by increasing total lung capacity, TLC, and lung compliance. In respiratory distress syndrome or RDS surfactant replacement therapy helps patients have normal respiration by using pharmaceutical forms of the surfactants. One of the most important pharmaceutical pulmonary surfactants is Survanta (beractant) or its generic form Beraksurf produced by Abbvie and Tekzima respectively.

Current market and forecast

The annual global production of surfactants was 13 million tonnes in 2008. In 2014, the world market for surfactants reached a volume of more than 33 billion US-dollars. Market researchers expect annual revenues to increase by 2.5% per year to around 40.4 billion US-dollars until 2022. The commercially most significant type of surfactants is currently the anionic surfactant alkyl benzene sulfonate (LAS), which is widely used in cleaners and detergents.

Health and environmental controversy

Surfactants are routinely deposited in numerous ways on land and into water systems, whether as part of an intended process or as industrial and household waste. Some of them are known to be toxic to animals, ecosystems, and humans, and can increase the diffusion of other environmental contaminants. As a result, there are proposed or voluntary restrictions on the use of some surfactants. For example, PFOS is a persistent organic pollutant as judged by the Stockholm Convention. Additionally, PFOA has been subject to a voluntary agreement by the U.S. Environmental Protection Agency and eight chemical companies to reduce and eliminate emissions of the chemical and its precursors.

The two major surfactants used in the year 2000 were linear alkylbenzene sulfonates (LAS) and the alkyl phenol ethoxylates (APE). They break down in the aerobic conditions found in sewage treatment plants and in soil to the metabolite nonylphenol, which is thought to be an endocrine disruptor.

Ordinary dishwashing detergent, for example, will promote water penetration in soil, but the effect would last only a few days (many standard laundry detergent powders contain levels of chemicals such as alkali and chelating agents that can be damaging to plants and should not be applied to soils). Commercial soil wetting agents will continue to work for a considerable period, but they will eventually be degraded by soil micro-organisms. Some can, however, interfere with the life-cycles of some aquatic organisms, so care should be taken to prevent run-off of these products into streams, and excess product should not be washed down.

Anionic surfactants can be found in soils as the result of sludge application, wastewater irrigation, and remediation processes. Relatively high concentrations of surfactants together with multimetals can represent an environmental risk. At low concentrations, surfactant application is unlikely to have a significant effect on trace metal mobility.

Biosurfactants

Biosurfactants are surface-active substances synthesised by living cells. Interest in microbial surfactants is due to their diversity, environmentally friendly nature, possibility of large-scale production, selectivity, performance under extreme conditions, and potential applications in environmental protection. A few of the popular examples of microbial biosurfactants includes Emulsan produced by Acinetobacter calcoaceticus, Sophorolipids produced by several yeasts belonging to candida and the starmerella clade, and Rhamnolipid produced by Pseudomonas aeruginosa etc. 

Biosurfactants enhance the emulsification of hydrocarbons, have the potential to solubilise hydrocarbon contaminants and increase their availability for microbial degradation. The use of chemicals for the treatment of a hydrocarbon polluted site may contaminate the environment with their by-products, whereas biological treatment may efficiently destroy pollutants, while being biodegradable themselves. Hence, biosurfactant-producing microorganisms may play an important role in the accelerated bioremediation of hydrocarbon-contaminated sites. These compounds can also be used in enhanced oil recovery and may be considered for other potential applications in environmental protection. Other applications include herbicides and pesticides formulations, detergents, healthcare and cosmetics, pulp and paper, coal, textiles, ceramic processing and food industries, uranium ore-processing, and mechanical dewatering of peat.

Several microorganisms are known to synthesise surface-active agents; most of them are bacteria and yeasts. When grown on hydrocarbon substrate as the carbon source, these microorganisms synthesise a wide range of chemicals with surface activity, such as glycolipid, phospholipid, and others. These chemicals are synthesised to emulsify the hydrocarbon substrate and facilitate its transport into the cells. In some bacterial species such as Pseudomonas aeruginosa, biosurfactants are also involved in a group motility behavior called swarming motility.

Safety and environmental risks

Most anionic and nonionic surfactants are nontoxic, having LD50 comparable to sodium chloride. The toxicity of quaternary ammonium compounds, which are antibacterial and antifungal, varies. Dialkyldimethylammonium chlorides (DDAC, DSDMAC) used as fabric softeners have low LD50 (5 g/kg) and are essentially non-toxic, while the disinfectant alkylbenzyldimethylammonium chloride has an LD50 of 0.35 g/kg. 

Prolonged exposure to surfactants can irritate and damage the skin because surfactants disrupt the lipid membrane that protects skin and other cells. Skin irritancy generally increases in the series nonionic, amphoteric, anionic, cationic surfactants.

The biodegradability of a surfactant is determined by its hydrophobic hydrocarbon group.

Biosurfactants and Deepwater Horizon

The use of biosurfactants as a way to remove petroleum from contaminated sites has been studied and found to be safe and effective in the removal of petroleum products from soil. Other studies found that surfactants are often more toxic than the oil that is being dispersed, and the combination of the oil and the surfactant can be more toxic than either alone. Biosurfactants were not used by BP after the Deepwater Horizon oil spill. However, unprecedented amounts of Corexit (active ingredient: dioctyl sodium sulfosuccinate (DOSS), sorbitan monooleate (Span 80), and polyoxyethylenated sorbitan monooleate (Tween-80)), were sprayed directly into the ocean at the leak and on the sea-water's surface, the theory being that the surfactants isolate droplets of oil, making it easier for petroleum-consuming microbes to digest the oil.

Biosurfactants produced by microbe or bacteria can be used to enhance oil production by microbial enhanced oil recovery method (MEOR).

Applications

Surfactants play an important role as cleaning, wetting, dispersing, emulsifying, foaming and anti-foaming agents in many practical applications and products, including detergents, fabric softeners, emulsions, soaps, paints, adhesives, inks, anti-fogs, ski waxes, snowboard wax, deinking of recycled papers, in flotation, washing and enzymatic processes, laxatives. Also agrochemical formulations such as Herbicides (some), insecticides, biocides (sanitizers), and spermicides (nonoxynol-9). Personal care products such as cosmetics, shampoos,shower gel, hair conditioners (after shampoo), toothpastes. Surfactants are used in firefighting and pipelines (liquid drag reducing agents). Alkali surfactant polymers are used to mobilize oil in oil wells). Surfactants are used as plasticizer in nanocellulose, Ferrofluids, and leak detectors. Surfactants are used with quantum dots in order to manipulate growth. and assembly of the dots, reactions on their surface, electrical properties, etc., it is important to understand how surfactants arrange on the surface of the quantum dots.

Operator (computer programming)

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