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Monday, August 14, 2023

Magma

From Wikipedia, the free encyclopedia
Lava flow on Hawaii. Lava is the extrusive equivalent of magma.

Magma (from Ancient Greek μάγμα (mágma) 'thick unguent') is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as lava by laypeople) is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and gas bubbles.

Magma is produced by melting of the mantle or the crust in various tectonic settings, which on Earth include subduction zones, continental rift zones, mid-ocean ridges and hotspots. Mantle and crustal melts migrate upwards through the crust where they are thought to be stored in magma chambers or trans-crustal crystal-rich mush zones. During magma's storage in the crust, its composition may be modified by fractional crystallization, contamination with crustal melts, magma mixing, and degassing. Following its ascent through the crust, magma may feed a volcano and be extruded as lava, or it may solidify underground to form an intrusion, such as a dike, a sill, a laccolith, a pluton, or a batholith.

While the study of magma has relied on observing magma after its transition into a lava flow, magma has been encountered in situ three times during geothermal drilling projects, twice in Iceland (see Use in energy production) and once in Hawaii.

Physical and chemical properties

Magma consists of liquid rock that usually contains suspended solid crystals. As magma approaches the surface and the overburden pressure drops, dissolved gases bubble out of the liquid, so that magma near the surface consists of materials in solid, liquid, and gas phases.

Composition

Most magma is rich in silica. Rare nonsilicate magma can form by local melting of nonsilicate mineral deposits or by separation of a magma into separate immiscible silicate and nonsilicate liquid phases.

Silicate magmas are molten mixtures dominated by oxygen and silicon, the most abundant chemical elements in the Earth's crust, with smaller quantities of aluminium, calcium, magnesium, iron, sodium, and potassium, and minor amounts of many other elements. Petrologists routinely express the composition of a silicate magma in terms of the weight or molar mass fraction of the oxides of the major elements (other than oxygen) present in the magma.

Because many of the properties of a magma (such as its viscosity and temperature) are observed to correlate with silica content, silicate magmas are divided into four chemical types based on silica content: felsic, intermediate, mafic, and ultramafic.

Felsic magma

Felsic or silicic magmas have a silica content greater than 63%. They include rhyolite and dacite magmas. With such a high silica content, these magmas are extremely viscous, ranging from 108 cP (105 Pa⋅s) for hot rhyolite magma at 1,200 °C (2,190 °F) to 1011 cP (108 Pa⋅s) for cool rhyolite magma at 800 °C (1,470 °F). For comparison, water has a viscosity of about 1 cP (0.001 Pa⋅s). Because of this very high viscosity, felsic lavas usually erupt explosively to produce pyroclastic (fragmental) deposits. However, rhyolite lavas occasionally erupt effusively to form lava spines, lava domes or "coulees" (which are thick, short lava flows). The lavas typically fragment as they extrude, producing block lava flows. These often contain obsidian.

Felsic lavas can erupt at temperatures as low as 800 °C (1,470 °F). Unusually hot (>950 °C; >1,740 °F) rhyolite lavas, however, may flow for distances of many tens of kilometres, such as in the Snake River Plain of the northwestern United States.

Intermediate magma

Intermediate or andesitic magmas contain 52% to 63% silica, and are lower in aluminium and usually somewhat richer in magnesium and iron than felsic magmas. Intermediate lavas form andesite domes and block lavas, and may occur on steep composite volcanoes, such as in the Andes. They are also commonly hotter, in the range of 850 to 1,100 °C (1,560 to 2,010 °F)). Because of their lower silica content and higher eruptive temperatures, they tend to be much less viscous, with a typical viscosity of 3.5 × 106 cP (3,500 Pa⋅s) at 1,200 °C (2,190 °F). This is slightly greater than the viscosity of smooth peanut butter. Intermediate magmas show a greater tendency to form phenocrysts, Higher iron and magnesium tends to manifest as a darker groundmass, including amphibole or pyroxene phenocrysts.

Mafic magmas

Mafic or basaltic magmas have a silica content of 52% to 45%. They are typified by their high ferromagnesian content, and generally erupt at temperatures of 1,100 to 1,200 °C (2,010 to 2,190 °F). Viscosities can be relatively low, around 104 to 105 cP (10 to 100 Pa⋅s), although this is still many orders of magnitude higher than water. This viscosity is similar to that of ketchup. Basalt lavas tend to produce low-profile shield volcanoes or flood basalts, because the fluidal lava flows for long distances from the vent. The thickness of a basalt lava, particularly on a low slope, may be much greater than the thickness of the moving lava flow at any one time, because basalt lavas may "inflate" by supply of lava beneath a solidified crust. Most basalt lavas are of ʻAʻā or pāhoehoe types, rather than block lavas. Underwater, they can form pillow lavas, which are rather similar to entrail-type pahoehoe lavas on land.

Ultramafic magmas

Ultramafic magmas, such as picritic basalt, komatiite, and highly magnesian magmas that form boninite, take the composition and temperatures to the extreme. All have a silica content under 45%. Komatiites contain over 18% magnesium oxide, and are thought to have erupted at temperatures of 1,600 °C (2,910 °F). At this temperature there is practically no polymerization of the mineral compounds, creating a highly mobile liquid. Viscosities of komatiite magmas are thought to have been as low as 100 to 1000 cP (0.1 to 1 Pa⋅s), similar to that of light motor oil. Most ultramafic lavas are no younger than the Proterozoic, with a few ultramafic magmas known from the Phanerozoic in Central America that are attributed to a hot mantle plume. No modern komatiite lavas are known, as the Earth's mantle has cooled too much to produce highly magnesian magmas.

Alkaline magmas

Some silicic magmas have an elevated content of alkali metal oxides (sodium and potassium), particularly in regions of continental rifting, areas overlying deeply subducted plates, or at intraplate hotspots. Their silica content can range from ultramafic (nephelinites, basanites and tephrites) to felsic (trachytes). They are more likely to be generated at greater depths in the mantle than subalkaline magmas. Olivine nephelinite magmas are both ultramafic and highly alkaline, and are thought to have come from much deeper in the mantle of the Earth than other magmas.


Examples of magma compositions (wt%)
Component Nephelinite Tholeiitic picrite Tholeiitic basalt Andesite Rhyolite
SiO2 39.7 46.4 53.8 60.0 73.2
TiO2 2.8 2.0 2.0 1.0 0.2
Al2O3 11.4 8.5 13.9 16.0 14.0
Fe2O3 5.3 2.5 2.6 1.9 0.6
FeO 8.2 9.8 9.3 6.2 1.7
MnO 0.2 0.2 0.2 0.2 0.0
MgO 12.1 20.8 4.1 3.9 0.4
CaO 12.8 7.4 7.9 5.9 1.3
Na2O 3.8 1.6 3.0 3.9 3.9
K2O 1.2 0.3 1.5 0.9 4.1
P2O5 0.9 0.2 0.4 0.2 0.0

Tholeiitic basalt magma

  SiO2 (53.8%)
  Al2O3 (13.9%)
  FeO (9.3%)
  CaO (7.9%)
  MgO (4.1%)
  Na2O (3.0%)
  Fe2O3 (2.6%)
  TiO2 (2.0%)
  K2O (1.5%)
  P2O5 (0.4%)
  MnO (0.2%)

Rhyolite magma

  SiO2 (73.2%)
  Al2O3 (14%)
  FeO (1.7%)
  CaO (1.3%)
  MgO (0.4%)
  Na2O (3.9%)
  Fe2O3 (0.6%)
  TiO2 (0.2%)
  K2O (4.1%)
  P2O5 (0.%)
  MnO (0.%)

Non-silicate magmas

Some lavas of unusual composition have erupted onto the surface of the Earth. These include:

  • Carbonatite and natrocarbonatite lavas are known from Ol Doinyo Lengai volcano in Tanzania, which is the sole example of an active carbonatite volcano. Carbonatites in the geologic record are typically 75% carbonate minerals, with lesser amounts of silica-undersaturated silicate minerals (such as micas and olivine), apatite, magnetite, and pyrochlore. This may not reflect the original composition of the lava, which may have included sodium carbonate that was subsequently removed by hydrothermal activity, though laboratory experiments show that a calcite-rich magma is possible. Carbonatite lavas show stable isotope ratios indicating they are derived from the highly alkaline silicic lavas with which they are always associated, probably by separation of an immiscible phase. Natrocarbonatite lavas of Ol Doinyo Lengai are composed mostly of sodium carbonate, with about half as much calcium carbonate and half again as much potassium carbonate, and minor amounts of halides, fluorides, and sulphates. The lavas are extremely fluid, with viscosities only slightly greater than water, and are very cool, with measured temperatures of 491 to 544 °C (916 to 1,011 °F).
  • Iron oxide magmas are thought to be the source of the iron ore at Kiruna, Sweden which formed during the Proterozoic. Iron oxide lavas of Pliocene age occur at the El Laco volcanic complex on the Chile-Argentina border. Iron oxide lavas are thought to be the result of immiscible separation of iron oxide magma from a parental magma of calc-alkaline or alkaline composition. When erupted, the temperature of the molten iron oxide magma is about 700 to 800 °C (1,292 to 1,472 °F).
  • Sulfur lava flows up to 250 metres (820 feet) long and 10 metres (33 feet) wide occur at Lastarria volcano, Chile. They were formed by the melting of sulfur deposits at temperatures as low as 113 °C (235 °F).

Magmatic gases

The concentrations of different gases can vary considerably. Water vapor is typically the most abundant magmatic gas, followed by carbon dioxide and sulfur dioxide. Other principal magmatic gases include hydrogen sulfide, hydrogen chloride, and hydrogen fluoride.

The solubility of magmatic gases in magma depends on pressure, magma composition, and temperature. Magma that is extruded as lava is extremely dry, but magma at depth and under great pressure can contain a dissolved water content in excess of 10%. Water is somewhat less soluble in low-silica magma than high-silica magma, so that at 1,100 °C and 0.5 GPa, a basaltic magma can dissolve 8% H2O while a granite pegmatite magma can dissolve 11% H2O. However, magmas are not necessarily saturated under typical conditions.


Water concentrations in magmas (wt%)
Magma composition H2O concentration
wt %
MORB (tholeiites) 0.1 – 0.2
Island tholeiite 0.3 – 0.6
Alkali basalts 0.8 – 1.5
Volcanic arc basalts 2–4
Basanites and nephelinites 1.5–2
Island arc andesites and dacites 1–3
Continental margin andesites and dacites 2–5
Rhyolites up to 7

Carbon dioxide is much less soluble in magmas than water, and frequently separates into a distinct fluid phase even at great depth. This explains the presence of carbon dioxide fluid inclusions in crystals formed in magmas at great depth.

Rheology

Viscosity is a key melt property in understanding the behaviour of magmas. Whereas temperatures in common silicate lavas range from about 800 °C (1,470 °F) for felsic lavas to 1,200 °C (2,190 °F) for mafic lavas, the viscosity of the same lavas ranges over seven orders of magnitude, from 104 cP (10 Pa⋅s) for mafic lava to 1011 cP (108 Pa⋅s) for felsic magmas. The viscosity is mostly determined by composition but is also dependent on temperature. The tendency of felsic lava to be cooler than mafic lava increases the viscosity difference.

The silicon ion is small and highly charged, and so it has a strong tendency to coordinate with four oxygen ions, which form a tetrahedral arrangement around the much smaller silicon ion. This is called a silica tetrahedron. In a magma that is low in silicon, these silica tetrahedra are isolated, but as the silicon content increases, silica tetrahedra begin to partially polymerize, forming chains, sheets, and clumps of silica tetrahedra linked by bridging oxygen ions. These greatly increase the viscosity of the magma.

The tendency towards polymerization is expressed as NBO/T, where NBO is the number of non-bridging oxygen ions and T is the number of network-forming ions. Silicon is the main network-forming ion, but in magmas high in sodium, aluminium also acts as a network former, and ferric iron can act as a network former when other network formers are lacking. Most other metallic ions reduce the tendency to polymerize and are described as network modifiers. In a hypothetical magma formed entirely from melted silica, NBO/T would be 0, while in a hypothetical magma so low in network formers that no polymerization takes place, NBO/T would be 4. Neither extreme is common in nature, but basalt magmas typically have NBO/T between 0.6 and 0.9, andesitic magmas have NBO/T of 0.3 to 0.5, and rhyolitic magmas have NBO/T of 0.02 to 0.2. Water acts as a network modifier, and dissolved water drastically reduces melt viscosity. Carbon dioxide neutralizes network modifiers, so dissolved carbon dioxide increases the viscosity. Higher-temperature melts are less viscous, since more thermal energy is available to break bonds between oxygen and network formers.

Most magmas contain solid crystals of various minerals, fragments of exotic rocks known as xenoliths and fragments of previously solidified magma. The crystal content of most magmas gives them thixotropic and shear thinning properties. In other words, most magmas do not behave like Newtonian fluids, in which the rate of flow is proportional to the shear stress. Instead, a typical magma is a Bingham fluid, which shows considerable resistance to flow until a stress threshold, called the yield stress, is crossed. This results in plug flow of partially crystalline magma. A familiar example of plug flow is toothpaste squeezed out of a toothpaste tube. The toothpaste comes out as a semisolid plug, because shear is concentrated in a thin layer in the toothpaste next to the tube, and only here does the toothpaste behave as a fluid. Thixotropic behavior also hinders crystals from settling out of the magma. Once the crystal content reaches about 60%, the magma ceases to behave like a fluid and begins to behave like a solid. Such a mixture of crystals with melted rock is sometimes described as crystal mush.

Magma is typically also viscoelastic, meaning it flows like a liquid under low stresses, but once the applied stress exceeds a critical value, the melt cannot dissipate the stress fast enough through relaxation alone, resulting in transient fracture propagation. Once stresses are reduced below the critical threshold, the melt viscously relaxes once more and heals the fracture.

Temperature

Temperatures of molten lava, which is magma extruded onto the surface, are almost all in the range 700 to 1,400 °C (1,300 to 2,600 °F), but very rare carbonatite magmas may be as cool as 490 °C (910 °F), and komatiite magmas may have been as hot as 1,600 °C (2,900 °F). Magma has occasionally been encountered during drilling in geothermal fields, including drilling in Hawaii that penetrated a dacitic magma body at a depth of 2,488 m (8,163 ft). The temperature of this magma was estimated at 1,050 °C (1,920 °F). Temperatures of deeper magmas must be inferred from theoretical computations and the geothermal gradient.

Most magmas contain some solid crystals suspended in the liquid phase. This indicates that the temperature of the magma lies between the solidus, which is defined as the temperature at which the magma completely solidifies, and the liquidus, defined as the temperature at which the magma is completely liquid. Calculations of solidus temperatures at likely depths suggests that magma generated beneath areas of rifting starts at a temperature of about 1,300 to 1,500 °C (2,400 to 2,700 °F). Magma generated from mantle plumes may be as hot as 1,600 °C (2,900 °F). The temperature of magma generated in subduction zones, where water vapor lowers the melting temperature, may be as low as 1,060 °C (1,940 °F).

Density

Magma densities depend mostly on composition, iron content being the most important parameter.

Type Density (kg/m3)
Basaltic magma 2650–2800
Andesitic magma 2450–2500
Rhyolitic magma 2180–2250

Magma expands slightly at lower pressure or higher temperature. When magma approaches the surface, its dissolved gases begin to bubble out of the liquid. These bubbles had significantly reduced the density of the magma at depth and helped drive it toward the surface in the first place.

Origins

The temperature within the interior of the earth is described by the geothermal gradient, which is the rate of temperature change with depth. The geothermal gradient is established by the balance between heating through radioactive decay in the Earth's interior and heat loss from the surface of the earth. The geothermal gradient averages about 25 °C/km in the Earth's upper crust, but this varies widely by region, from a low of 5–10 °C/km within oceanic trenches and subduction zones to 30–80 °C/km along mid-ocean ridges or near mantle plumes. The gradient becomes less steep with depth, dropping to just 0.25 to 0.3  °C/km in the mantle, where slow convection efficiently transports heat. The average geothermal gradient is not normally steep enough to bring rocks to their melting point anywhere in the crust or upper mantle, so magma is produced only where the geothermal gradient is unusually steep or the melting point of the rock is unusually low. However, the ascent of magma towards the surface in such settings is the most important process for transporting heat through the crust of the Earth.

Rocks may melt in response to a decrease in pressure, to a change in composition (such as an addition of water), to an increase in temperature, or to a combination of these processes. Other mechanisms, such as melting from a meteorite impact, are less important today, but impacts during the accretion of the Earth led to extensive melting, and the outer several hundred kilometers of our early Earth was probably an ocean of magma. Impacts of large meteorites in the last few hundred million years have been proposed as one mechanism responsible for the extensive basalt magmatism of several large igneous provinces.

Decompression

Decompression melting occurs because of a decrease in pressure. It is the most important mechanism for producing magma from the upper mantle.

The solidus temperatures of most rocks (the temperatures below which they are completely solid) increase with increasing pressure in the absence of water. Peridotite at depth in the Earth's mantle may be hotter than its solidus temperature at some shallower level. If such rock rises during the convection of solid mantle, it will cool slightly as it expands in an adiabatic process, but the cooling is only about 0.3 °C per kilometer. Experimental studies of appropriate peridotite samples document that the solidus temperatures increase by 3 °C to 4 °C per kilometer. If the rock rises far enough, it will begin to melt. Melt droplets can coalesce into larger volumes and be intruded upwards. This process of melting from the upward movement of solid mantle is critical in the evolution of the Earth.

Decompression melting creates the ocean crust at mid-ocean ridges, making it by far the most important source of magma on Earth. It also causes volcanism in intraplate regions, such as Europe, Africa and the Pacific sea floor. Intraplate volcanism is attributed to the rise of mantle plumes or to intraplate extension, with the importance of each mechanism being a topic of continuing research.

Effects of water and carbon dioxide

The change of rock composition most responsible for the creation of magma is the addition of water. Water lowers the solidus temperature of rocks at a given pressure. For example, at a depth of about 100 kilometers, peridotite begins to melt near 800 °C in the presence of excess water, but near 1,500 °C in the absence of water. Water is driven out of the oceanic lithosphere in subduction zones, and it causes melting in the overlying mantle. Hydrous magmas with the composition of basalt or andesite are produced directly and indirectly as results of dehydration during the subduction process. Such magmas, and those derived from them, build up island arcs such as those in the Pacific Ring of Fire. These magmas form rocks of the calc-alkaline series, an important part of the continental crust. With low density and viscosity, hydrous magmas are highly buoyant and will move upwards in Earth's mantle.

The addition of carbon dioxide is relatively a much less important cause of magma formation than the addition of water, but genesis of some silica-undersaturated magmas has been attributed to the dominance of carbon dioxide over water in their mantle source regions. In the presence of carbon dioxide, experiments document that the peridotite solidus temperature decreases by about 200 °C in a narrow pressure interval at pressures corresponding to a depth of about 70 km. At greater depths, carbon dioxide can have more effect: at depths to about 200 km, the temperatures of initial melting of a carbonated peridotite composition were determined to be 450 °C to 600 °C lower than for the same composition with no carbon dioxide. Magmas of rock types such as nephelinite, carbonatite, and kimberlite are among those that may be generated following an influx of carbon dioxide into mantle at depths greater than about 70 km.

Temperature increase

Increase in temperature is the most typical mechanism for formation of magma within continental crust. Such temperature increases can occur because of the upward intrusion of magma from the mantle. Temperatures can also exceed the solidus of a crustal rock in continental crust thickened by compression at a plate boundary. The plate boundary between the Indian and Asian continental masses provides a well-studied example, as the Tibetan Plateau just north of the boundary has crust about 80 kilometers thick, roughly twice the thickness of normal continental crust. Studies of electrical resistivity deduced from magnetotelluric data have detected a layer that appears to contain silicate melt and that stretches for at least 1,000 kilometers within the middle crust along the southern margin of the Tibetan Plateau. Granite and rhyolite are types of igneous rock commonly interpreted as products of the melting of continental crust because of increases in temperature. Temperature increases also may contribute to the melting of lithosphere dragged down in a subduction zone.

The melting process

Phase diagram for the diopside-anorthite system

When rocks melt, they do so over a range of temperature, because most rocks are made of several minerals, which all have different melting points. The temperature at which the first melt appears (the solidus) is lower than the melting temperature of any one of the pure minerals. This is similar to the lowering of the melting point of ice when it is mixed with salt. The first melt is called the eutectic and has a composition that depends on the combination of minerals present.

For example, a mixture of anorthite and diopside, which are two of the predominant minerals in basalt, begins to melt at about 1274 °C. This is well below the melting temperatures of 1392 °C for pure diopside and 1553 °C for pure anorthite. The resulting melt is composed of about 43 wt% anorthite. As additional heat is added to the rock, the temperature remains at 1274 °C until either the anorthite or diopside is fully melted. The temperature then rises as the remaining mineral continues to melt, which shifts the melt composition away from the eutectic. For example, if the content of anorthite is greater than 43%, the entire supply of diopside will melt at 1274 °C., along with enough of the anorthite to keep the melt at the eutectic composition. Further heating causes the temperature to slowly rise as the remaining anorthite gradually melts and the melt becomes increasingly rich in anorthite liquid. If the mixture has only a slight excess of anorthite, this will melt before the temperature rises much above 1274 °C. If the mixture is almost all anorthite, the temperature will reach nearly the melting point of pure anorthite before all the anorthite is melted. If the anorthite content of the mixture is less than 43%, then all the anorthite will melt at the eutectic temperature, along with part of the diopside, and the remaining diopside will then gradually melt as the temperature continues to rise.

Because of eutectic melting, the composition of the melt can be quite different from the source rock. For example, a mixture of 10% anorthite with diopside could experience about 23% partial melting before the melt deviated from the eutectic, which has the composition of about 43% anorthite. This effect of partial melting is reflected in the compositions of different magmas. A low degree of partial melting of the upper mantle (2% to 4%) can produce highly alkaline magmas such as melilitites, while a greater degree of partial melting (8% to 11%) can produce alkali olivine basalt. Oceanic magmas likely result from partial melting of 3% to 15% of the source rock. Some calk-alkaline granitoids may be produced by a high degree of partial melting, as much as 15% to 30%. High-magnesium magmas, such as komatiite and picrite, may also be the products of a high degree of partial melting of mantle rock.

Certain chemical elements, called incompatible elements, have a combination of ionic radius and ionic charge that is unlike that of the more abundant elements in the source rock. The ions of these elements fit rather poorly in the structure of the minerals making up the source rock, and readily leave the solid minerals to become highly concentrated in melts produced by a low degree of partial melting. Incompatible elements commonly include potassium, barium, caesium, and rubidium, which are large and weakly charged (the large-ion lithophile elements, or LILEs), as well as elements whose ions carry a high charge (the high-field-strength elements, or HSFEs), which include such elements as zirconium, niobium, hafnium, tantalum, the rare-earth elements, and the actinides. Potassium can become so enriched in melt produced by a very low degree of partial melting that, when the magma subsequently cools and solidifies, it forms unusual potassic rock such as lamprophyre, lamproite, or kimberlite.

When enough rock is melted, the small globules of melt (generally occurring between mineral grains) link up and soften the rock. Under pressure within the earth, as little as a fraction of a percent of partial melting may be sufficient to cause melt to be squeezed from its source. Melt rapidly separates from its source rock once the degree of partial melting exceeds 30%. However, usually much less than 30% of a magma source rock is melted before the heat supply is exhausted.

Pegmatite may be produced by low degrees of partial melting of the crust. Some granite-composition magmas are eutectic (or cotectic) melts, and they may be produced by low to high degrees of partial melting of the crust, as well as by fractional crystallization.

Evolution of magmas

Schematic diagrams showing the principles behind fractional crystallisation in a magma. While cooling, the magma evolves in composition because different minerals crystallize from the melt. 1: olivine crystallizes; 2: olivine and pyroxene crystallize; 3: pyroxene and plagioclase crystallize; 4: plagioclase crystallizes. At the bottom of the magma reservoir, a cumulate rock forms.

Most magmas are fully melted only for small parts of their histories. More typically, they are mixes of melt and crystals, and sometimes also of gas bubbles. Melt, crystals, and bubbles usually have different densities, and so they can separate as magmas evolve.

As magma cools, minerals typically crystallize from the melt at different temperatures. This resembles the original melting process in reverse. However, because the melt has usually separated from its original source rock and moved to a shallower depth, the reverse process of crystallization is not precisely identical. For example, if a melt was 50% each of diopside and anorthite, then anorthite would begin crystallizing from the melt at a temperature somewhat higher than the eutectic temperature of 1274 °C. This shifts the remaining melt towards its eutectic composition of 43% diopside. The eutectic is reached at 1274 °C, the temperature at which diopside and anorthite begin crystallizing together. If the melt was 90% diopside, the diopside would begin crystallizing first until the eutectic was reached.

If the crystals remained suspended in the melt, the crystallization process would not change the overall composition of the melt plus solid minerals. This situation is described as equillibrium crystallization. However, in a series of experiments culminating in his 1915 paper, Crystallization-differentiation in silicate liquids, Norman L. Bowen demonstrated that crystals of olivine and diopside that crystallized out of a cooling melt of forsterite, diopside, and silica would sink through the melt on geologically relevant time scales. Geologists subsequently found considerable field evidence of such fractional crystallization.

When crystals separate from a magma, then the residual magma will differ in composition from the parent magma. For instance, a magma of gabbroic composition can produce a residual melt of granitic composition if early formed crystals are separated from the magma. Gabbro may have a liquidus temperature near 1,200 °C, and the derivative granite-composition melt may have a liquidus temperature as low as about 700 °C. Incompatible elements are concentrated in the last residues of magma during fractional crystallization and in the first melts produced during partial melting: either process can form the magma that crystallizes to pegmatite, a rock type commonly enriched in incompatible elements. Bowen's reaction series is important for understanding the idealised sequence of fractional crystallisation of a magma.

Magma composition can be determined by processes other than partial melting and fractional crystallization. For instance, magmas commonly interact with rocks they intrude, both by melting those rocks and by reacting with them. Assimilation near the roof of a magma chamber and fractional crystallization near its base can even take place simultaneously. Magmas of different compositions can mix with one another. In rare cases, melts can separate into two immiscible melts of contrasting compositions.

Primary magmas

When rock melts, the liquid is a primary magma. Primary magmas have not undergone any differentiation and represent the starting composition of a magma. In practice, it is difficult to unambiguously identify primary magmas, though it has been suggested that boninite is a variety of andesite crystallized from a primary magma. The Great Dyke of Zimbabwe has also been interpreted as rock crystallized from a primary magma. The interpretation of leucosomes of migmatites as primary magmas is contradicted by zircon data, which suggests leucosomes are a residue (a cumulate rock) left by extraction of a primary magma.

Parental magma

When it is impossible to find the primitive or primary magma composition, it is often useful to attempt to identify a parental magma. A parental magma is a magma composition from which the observed range of magma chemistries has been derived by the processes of igneous differentiation. It need not be a primitive melt.

For instance, a series of basalt flows are assumed to be related to one another. A composition from which they could reasonably be produced by fractional crystallization is termed a parental magma. Fractional crystallization models would be produced to test the hypothesis that they share a common parental magma.

Migration and solidification

Magma develops within the mantle or crust where the temperature and pressure conditions favor the molten state. After its formation, magma buoyantly rises toward the Earth's surface, due to its lower density than the source rock. As it migrates through the crust, magma may collect and reside in magma chambers (though recent work suggests that magma may be stored in trans-crustal crystal-rich mush zones rather than dominantly liquid magma chambers). Magma can remain in a chamber until it either cools and crystallizes to form intrusive rock, it erupts as a volcano, or it moves into another magma chamber.

Plutonism

When magma cools it begins to form solid mineral phases. Some of these settle at the bottom of the magma chamber forming cumulates that might form mafic layered intrusions. Magma that cools slowly within a magma chamber usually ends up forming bodies of plutonic rocks such as gabbro, diorite and granite, depending upon the composition of the magma. Alternatively, if the magma is erupted it forms volcanic rocks such as basalt, andesite and rhyolite (the extrusive equivalents of gabbro, diorite and granite, respectively).

Volcanism

Magma that is extruded onto the surface during a volcanic eruption is called lava. Lava cools and solidifies relatively quickly compared to underground bodies of magma. This fast cooling does not allow crystals to grow large, and a part of the melt does not crystallize at all, becoming glass. Rocks largely composed of volcanic glass include obsidian, scoria and pumice.

Before and during volcanic eruptions, volatiles such as CO2 and H2O partially leave the melt through a process known as exsolution. Magma with low water content becomes increasingly viscous. If massive exsolution occurs when magma heads upwards during a volcanic eruption, the resulting eruption is usually explosive.

Use in energy production

The Iceland Deep Drilling Project, while drilling several 5,000 m holes in an attempt to harness the heat in the volcanic bedrock below the surface of Iceland, struck a pocket of magma at 2,100 m in 2009. Because this was only the third time in recorded history that magma had been reached, IDDP decided to invest in the hole, naming it IDDP-1.

A cemented steel case was constructed in the hole with a perforation at the bottom close to the magma. The high temperatures and pressure of the magma steam were used to generate 36 MW of power, making IDDP-1 the world's first magma-enhanced geothermal system.

Metamorphism

From Wikipedia, the free encyclopedia
Schematic representation of a metamorphic reaction. Abbreviations of minerals: act = actinolite; chl = chlorite; ep = epidote; gt = garnet; hbl = hornblende; plag = plagioclase. Two minerals represented in the figure do not participate in the reaction, they can be quartz and K-feldspar. This reaction takes place in nature when a mafic rock goes from amphibolite facies to greenschist facies.
A cross-polarized thin section image of a garnet-mica-schist from Salangen, Norway showing the strong strain fabric of schists. The black crystal is garnet, the pink-orange-yellow colored strands are muscovite mica, and the brown crystals are biotite mica. The grey and white crystals are quartz and (limited) feldspar.

Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of 150 °C (300 °F), and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface.

Various forms of metamorphism exist, including regional, contact, hydrothermal, shock, and dynamic metamorphism. These differ in the characteristic temperatures, pressures, and rate at which they take place and in the extent to which reactive fluids are involved. Metamorphism occurring at increasing pressure and temperature conditions is known as prograde metamorphism, while decreasing temperature and pressure characterize retrograde metamorphism.

Metamorphic petrology is the study of metamorphism. Metamorphic petrologists rely heavily on statistical mechanics and experimental petrology to understand metamorphic processes.

Metamorphic processes

(Left) Randomly-orientated grains in a rock before metamorphism. (Right) Grains align orthogonal to the applied stress if a rock is subjected to stress during metamorphism

Metamorphism is the set of processes by which existing rock is transformed physically or chemically at elevated temperature, without actually melting to any great degree. The importance of heating in the formation of metamorphic rock was first recognized by the pioneering Scottish naturalist, James Hutton, who is often described as the father of modern geology. Hutton wrote in 1795 that some rock beds of the Scottish Highlands had originally been sedimentary rock, but had been transformed by great heat.

Hutton also speculated that pressure was important in metamorphism. This hypothesis was tested by his friend, James Hall, who sealed chalk into a makeshift pressure vessel constructed from a cannon barrel and heated it in an iron foundry furnace. Hall found that this produced a material strongly resembling marble, rather than the usual quicklime produced by heating of chalk in the open air. French geologists subsequently added metasomatism, the circulation of fluids through buried rock, to the list of processes that help bring about metamorphism. However, metamorphism can take place without metasomatism (isochemical metamorphism) or at depths of just a few hundred meters where pressures are relatively low (for example, in contact metamorphism).

Rock can be transformed without melting because heat causes atomic bonds to break, freeing the atoms to move and form new bonds with other atoms. Pore fluid present between mineral grains is an important medium through which atoms are exchanged. This permits recrystallization of existing minerals or crystallization of new minerals with different crystalline structures or chemical compositions (neocrystallization). The transformation converts the minerals in the protolith into forms that are more stable (closer to chemical equilibrium) under the conditions of pressure and temperature at which metamorphism takes place.

Metamorphism is generally regarded to begin at temperatures of 100 to 200 °C (212 to 392 °F). This excludes diagenetic changes due to compaction and lithification, which result in the formation of sedimentary rocks. The upper boundary of metamorphic conditions lies at the solidus of the rock, which is the temperature at which the rock begins to melt. At this point, the process becomes an igneous process. The solidus temperature depends on the composition of the rock, the pressure, and whether the rock is saturated with water. Typical solidus temperatures range from 650 °C (1,202 °F) for wet granite at a few hundred megapascals (Mpa) of pressure to about 1,080 °C (1,980 °F) for wet basalt at atmospheric pressure. Migmatites are rocks formed at this upper limit, which contains pods and veins of material that has started to melt but has not fully segregated from the refractory residue.

The metamorphic process can occur at almost any pressure, from near surface pressure (for contact metamorphism) to pressures in excess of 16 kbar (1500 Mpa).

Recrystallization

Basalt hand sample showing fine texture
Amphibolite formed by metamorphism of basalt showing coarse texture

The change in the grain size and orientation in the rock during the process of metamorphism is called recrystallization. For instance, the small calcite crystals in the sedimentary rocks limestone and chalk change into larger crystals in the metamorphic rock marble. In metamorphosed sandstone, recrystallization of the original quartz sand grains results in very compact quartzite, also known as metaquartzite, in which the often larger quartz crystals are interlocked. Both high temperatures and pressures contribute to recrystallization. High temperatures allow the atoms and ions in solid crystals to migrate, thus reorganizing the crystals, while high pressures cause solution of the crystals within the rock at their points of contact (pressure solution) and redeposition in pore space.

During recrystallization, the identity of the mineral does not change, only its texture. Recrystallization generally begins when temperatures reach above half the melting point of the mineral on the Kelvin scale.

Pressure solution begins during diagenesis (the process of lithification of sediments into sedimentary rock) but is completed during early stages of metamorphism. For a sandstone protolith, the dividing line between diagenesis and metamorphism can be placed at the point where strained quartz grains begin to be replaced by new, unstrained, small quartz grains, producing a mortar texture that can be identified in thin sections under a polarizing microscope. With increasing grade of metamorphism, further recrystallization produces foam texture, characterized by polygonal grains meeting at triple junctions, and then porphyroblastic texture, characterized by coarse, irregular grains, including some larger grains (porphyroblasts.)

A mylonite (through a petrographic microscope)

Metamorphic rocks are typically more coarsely crystalline than the protolith from which they formed. Atoms in the interior of a crystal are surrounded by a stable arrangement of neighboring atoms. This is partially missing at the surface of the crystal, producing a surface energy that makes the surface thermodynamically unstable. Recrystallization to coarser crystals reduces the surface area and so minimizes the surface energy.

Although grain coarsening is a common result of metamorphism, rock that is intensely deformed may eliminate strain energy by recrystallizing as a fine-grained rock called mylonite. Certain kinds of rock, such as those rich in quartz, carbonate minerals, or olivine, are particularly prone to form mylonites, while feldspar and garnet are resistant to mylonitization.

Phase change

Phase diagram of Al2SiO5 (nesosilicates)

Phase change metamorphism is the creating of a new mineral with the same chemical formula as a mineral of the protolith. This involves a rearrangement of the atoms in the crystals. An example is provided by the aluminium silicate minerals, kyanite, andalusite, and sillimanite. All three have the identical composition, Al2SiO5. Kyanite is stable at surface conditions. However, at atmospheric pressure, kyanite transforms to andalusite at a temperature of about 190 °C (374 °F). Andalusite, in turn, transforms to sillimanite when the temperature reaches about 800 °C (1,470 °F). At pressures above about 4 kbar (400 Mpa), kyanite transforms directly to sillimanite as the temperature increases. A similar phase change is sometimes seen between calcite and aragonite, with calcite transforming to aragonite at elevated pressure and relatively low temperature.

Neocrystallization

Neocrystallization involves the creation of new mineral crystals different from the protolith. Chemical reactions digest the minerals of the protolith which yields new minerals. This is a very slow process as it can also involve the diffusion of atoms through solid crystals.

An example of a neocrystallization reaction is the reaction of fayalite with plagioclase at elevated pressure and temperature to form garnet. The reaction is:

fayalite3 Fe
2
SiO
4
+ plagioclaseCaAl
2
Si
2
O
8
garnet2 CaFe
2
Al
2
Si
3
O
12

 

 

 

 

(Reaction 1)

Many complex high-temperature reactions may take place between minerals without them melting, and each mineral assemblage produced provides us with a clue as to the temperatures and pressures at the time of metamorphism. These reactions are possible because of rapid diffusion of atoms at elevated temperature. Pore fluid between mineral grains can be an important medium through which atoms are exchanged.

A particularly important group of neocrystallization reactions are those that release volatiles such as water and carbon dioxide. During metamorphism of basalt to eclogite in subduction zones, hydrous minerals break down, producing copious quantities of water. The water rises into the overlying mantle, where it lowers the melting temperature of the mantle rock, generating magma via flux melting. The mantle-derived magmas can ultimately reach the Earth's surface, resulting in volcanic eruptions. The resulting arc volcanoes tend to produce dangerous eruptions, because their high water content makes them extremely explosive.

Examples of dehydration reactions that release water include:

hornblende7Ca2Mg3Al4Si6O22(OH)2 + quartz10SiO2cummingtonite3Mg7Si8O22(OH)2 + anorthite14CaAl2Si2O8 + water4H2O

 

 

 

 

(Reaction 2)

muscovite2KAl2(AlSi3O10)(OH)2 + quartz2SiO2sillimanite2Al2SiO5 + potassium feldspar2KAlSi3O8 + water2H2O

 

 

 

 

(Reaction 3)

An example of a decarbonation reaction is:

calciteCaCO3 + quartzSiO2wollastoniteCaSiO3 + carbon dioxideCO2

 

 

 

 

(Reaction 4)

Plastic deformation

In plastic deformation pressure is applied to the protolith, which causes it to shear or bend, but not break. In order for this to happen temperatures must be high enough that brittle fractures do not occur, but not so high that diffusion of crystals takes place. As with pressure solution, the early stages of plastic deformation begin during diagenesis.

Types

Regional

Regional metamorphism is a general term for metamorphism that affects entire regions of the Earth's crust. It most often refers to dynamothermal metamorphism, which takes place in orogenic belts (regions where mountain building is taking place), but also includes burial metamorphism, which results simply from rock being buried to great depths below the Earth's surface in a subsiding basin.

Dynamothermal

A metamorphic rock, deformed during the Variscan orogeny, at Vall de Cardós, Lérida, Spain

To many geologists, regional metamorphism is practically synonymous with dynamothermal metamorphism. This form of metamorphism takes place at convergent plate boundaries, where two continental plates or a continental plate and an island arc collide. The collision zone becomes a belt of mountain formation called an orogeny. The orogenic belt is characterized by thickening of the Earth's crust, during which the deeply buried crustal rock is subjected to high temperatures and pressures and is intensely deformed. Subsequent erosion of the mountains exposes the roots of the orogenic belt as extensive outcrops of metamorphic rock, characteristic of mountain chains.

Metamorphic rock formed in these settings tends to shown well-developed foliation. Foliation develops when a rock is being shortened along one axis during metamorphism. This causes crystals of platy minerals, such as mica and chlorite, to become rotated such that their short axes are parallel to the direction of shortening. This results in a banded, or foliated, rock, with the bands showing the colors of the minerals that formed them. Foliated rock often develops planes of cleavage. Slate is an example of a foliated metamorphic rock, originating from shale, and it typically shows well-developed cleavage that allows slate to be split into thin plates.

The type of foliation that develops depends on the metamorphic grade. For instance, starting with a mudstone, the following sequence develops with increasing temperature: The mudstone is first converted to slate, which is a very fine-grained, foliated metamorphic rock, characteristic of very low grade metamorphism. Slate in turn is converted to phyllite, which is fine-grained and found in areas of low grade metamorphism. Schist is medium to coarse-grained and found in areas of medium grade metamorphism. High-grade metamorphism transforms the rock to gneiss, which is coarse to very coarse-grained.

Rocks that were subjected to uniform pressure from all sides, or those that lack minerals with distinctive growth habits, will not be foliated. Marble lacks platy minerals and is generally not foliated, which allows its use as a material for sculpture and architecture.

Collisional orogenies are preceded by subduction of oceanic crust. The conditions within the subducting slab as it plunges toward the mantle in a subduction zone produce their own distinctive regional metamorphic effects, characterized by paired metamorphic belts.

The pioneering work of George Barrow on regional metamorphism in the Scottish Highlands showed that some regional metamorphism produces well-defined, mappable zones of increasing metamorphic grade. This Barrovian metamorphism is the most recognized metamorphic series in the world. However, Barrovian metamorphism is specific to pelitic rock, formed from mudstone or siltstone, and it is not unique even in pelitic rock. A different sequence in the northeast of Scotland defines Buchan metamorphism, which took place at lower pressure than the Barrovian.

Burial

Sioux Quartzite, a product of burial metamorphism

Burial metamorphism takes place simply through rock being buried to great depths below the Earth's surface in a subsiding basin. Here the rock subjected to high temperatures and the great pressure caused by the immense weight of the rock layers above. Burial metamorphism tends to produced low-grade metamorphic rock. This shows none of the effects of deformation and folding so characteristic of dynamothermal metamorphism.

Examples of metamorphic rocks formed by burial metamorphism include some of the rocks of the Midcontinent Rift System of North America, such as the Sioux Quartzite, and in the Hamersley Basin of Australia.

Contact

A metamorphic aureole in the Henry Mountains, Utah. The greyish rock on top is the igneous intrusion, consisting of porphyritic granodiorite from the Henry Mountains laccolith, and the pinkish rock on the bottom is the sedimentary country rock, a siltstone. In between, the metamorphosed siltstone is visible as both the dark layer (~5  cm thick) and the pale layer below it.

Contact metamorphism occurs typically around intrusive igneous rocks as a result of the temperature increase caused by the intrusion of magma into cooler country rock. The area surrounding the intrusion where the contact metamorphism effects are present is called the metamorphic aureole, the contact aureole, or simply the aureole. Contact metamorphic rocks are usually known as hornfels. Rocks formed by contact metamorphism may not present signs of strong deformation and are often fine-grained and extremely tough.

Contact metamorphism is greater adjacent to the intrusion and dissipates with distance from the contact. The size of the aureole depends on the heat of the intrusion, its size, and the temperature difference with the wall rocks. Dikes generally have small aureoles with minimal metamorphism, extending not more than one or two dike thicknesses into the surrounding rock, whereas the aureoles around batholiths can be up to several kilometers wide.

The metamorphic grade of an aureole is measured by the peak metamorphic mineral which forms in the aureole. This is usually related to the metamorphic temperatures of pelitic or aluminosilicate rocks and the minerals they form. The metamorphic grades of aureoles at shallow depth are albite-epidote hornfels, hornblende hornfels, pyroxene hornfels, and sillimanite hornfels, in increasing order of temperature of formation. However, the albite-epidote hornfels is often not formed, even though it is the lowest temperature grade.

Magmatic fluids coming from the intrusive rock may also take part in the metamorphic reactions. An extensive addition of magmatic fluids can significantly modify the chemistry of the affected rocks. In this case the metamorphism grades into metasomatism. If the intruded rock is rich in carbonate the result is a skarn. Fluorine-rich magmatic waters which leave a cooling granite may often form greisens within and adjacent to the contact of the granite. Metasomatic altered aureoles can localize the deposition of metallic ore minerals and thus are of economic interest.

Fenitization, or Na-metasomatism, is a distinctive form of contact metamorphism accompanied by metasomatism. It takes place around intrusions of a rare type of magma called a carbonatite that is highly enriched in carbonates and low in silica. Cooling bodies of carbonatite magma give off highly alkaline fluids rich in sodium as they solidify, and the hot, reactive fluid replaces much of the mineral content in the aureole with sodium-rich minerals.

A special type of contact metamorphism, associated with fossil fuel fires, is known as pyrometamorphism.

Hydrothermal

Hydrothermal metamorphism is the result of the interaction of a rock with a high-temperature fluid of variable composition. The difference in composition between an existing rock and the invading fluid triggers a set of metamorphic and metasomatic reactions. The hydrothermal fluid may be magmatic (originate in an intruding magma), circulating groundwater, or ocean water. Convective circulation of hydrothermal fluids in the ocean floor basalts produces extensive hydrothermal metamorphism adjacent to spreading centers and other submarine volcanic areas. The fluids eventually escape through vents on the ocean floor known as black smokers. The patterns of this hydrothermal alteration are used as a guide in the search for deposits of valuable metal ores.

Shock

Shock metamorphism occurs when an extraterrestrial object (a meteorite for instance) collides with the Earth's surface. Impact metamorphism is, therefore, characterized by ultrahigh pressure conditions and low temperature. The resulting minerals (such as SiO2 polymorphs coesite and stishovite) and textures are characteristic of these conditions.

Dynamic

Dynamic metamorphism is associated with zones of high strain such as fault zones. In these environments, mechanical deformation is more important than chemical reactions in transforming the rock. The minerals present in the rock often do not reflect conditions of chemical equilibrium, and the textures produced by dynamic metamorphism are more significant than the mineral makeup.

There are three deformation mechanisms by which rock is mechanically deformed. These are cataclasis, the deformation of rock via the fracture and rotation of mineral grains; plastic deformation of individual mineral crystals; and movement of individual atoms by diffusive processes. The textures of dynamic metamorphic zones are dependent on the depth at which they were formed, as the temperature and confining pressure determine the deformation mechanisms which predominate.

At the shallowest depths, a fault zone will be filled with various kinds of unconsolidated cataclastic rock, such as fault gouge or fault breccia. At greater depths, these are replaced by consolidated cataclastic rock, such as crush breccia, in which the larger rock fragments are cemented together by calcite or quartz. At depths greater than about 5 kilometers (3.1 mi), cataclasites appear; these are quite hard rocks consist of crushed rock fragments in a flinty matrix, which forms only at elevated temperature. At still greater depths, where temperatures exceed 300 °C (572 °F), plastic deformation takes over, and the fault zone is composed of mylonite. Mylonite is distinguished by its strong foliation, which is absent in most cataclastic rock. It is distinguished from the surrounding rock by its finer grain size.

There is considerable evidence that cataclasites form as much through plastic deformation and recrystallization as brittle fracture of grains, and that the rock may never fully lose cohesion during the process. Different minerals become ductile at different temperatures, with quartz being among the first to become ductile, and sheared rock composed of different minerals may simultaneously show both plastic deformation and brittle fracture.

The strain rate also affects the way in which rocks deform. Ductile deformation is more likely at low strain rates (less than 10−14 sec−1) in the middle and lower crust, but high strain rates can cause brittle deformation. At the highest strain rates, the rock may be so strongly heated that it briefly melts, forming a glassy rock called pseudotachylite. Pseudotachylites seem to be restricted to dry rock, such as granulite.

Classification of metamorphic rocks

Metamorphic rocks are classified by their protolith, if this can be determined from the properties of the rock itself. For example, if examination of a metamorphic rock shows that its protolith was basalt, it will be described as a metabasalt. When the protolith cannot be determined, the rock is classified by its mineral composition or its degree of foliation.

Metamorphic grades

Metamorphic grade is an informal indication of the amount or degree of metamorphism.

In the Barrovian sequence (described by George Barrow in zones of progressive metamorphism in Scotland), metamorphic grades are also classified by mineral assemblage based on the appearance of key minerals in rocks of pelitic (shaly, aluminous) origin:

Low grade ------------------- Intermediate --------------------- High grade

Greenschist ------------- Amphibolite ----------------------- Granulite
Slate --- Phyllite ---------- Schist ---------------------- Gneiss --- Migmatite
Chlorite zone
Biotite zone
Garnet zone
Staurolite zone
Kyanite zone
Sillimanite zone

A more complete indication of this intensity or degree is provided by the concept of metamorphic facies.

Metamorphic facies

Metamorphic facies are recognizable terranes or zones with an assemblage of key minerals that were in equilibrium under specific range of temperature and pressure during a metamorphic event. The facies are named after the metamorphic rock formed under those facies conditions from basalt.

The particular mineral assemblage is somewhat dependent on the composition of that protolith, so that (for example) the amphibolite facies of a marble will not be identical with the amphibolite facies of a pellite. However, the facies are defined such that metamorphic rock with as broad a range of compositions as is practical can be assigned to a particular facies. The present definition of metamorphic facies is largely based on the work of the Finnish geologist, Pentti Eskola in 1921, with refinements based on subsequent experimental work. Eskola drew upon the zonal schemes, based on index minerals, that were pioneered by the British geologist, George Barrow.

The metamorphic facies is not usually considered when classifying metamorphic rock based on protolith, mineral mode, or texture. However, a few metamorphic facies produce rock of such distinctive character that the facies name is used for the rock when more precise classification is not possible. The chief examples are amphibolite and eclogite. The British Geological Survey strongly discourages use of granulite as a classification for rock metamorphosed to the granulite facies. Instead, such rock will often be classified as a granofels. However, this is not universally accepted.

Temperatures and pressures of metamorphic facies
Temperature Pressure Facies
Low Low Zeolite
Lower Moderate Lower Moderate Prehnite-Pumpellyite
Moderate to High Low Hornfels
Low to Moderate Moderate to High Blueschist
Moderate → High Moderate GreenschistAmphiboliteGranulite
Moderate to High High Eclogite

See diagram for more detail.

Prograde and retrograde

Metamorphism is further divided into prograde and retrograde metamorphism. Prograde metamorphism involves the change of mineral assemblages (paragenesis) with increasing temperature and (usually) pressure conditions. These are solid state dehydration reactions, and involve the loss of volatiles such as water or carbon dioxide. Prograde metamorphism results in rock characteristic of the maximum pressure and temperature experienced. Metamorphic rocks usually do not undergo further change when they are brought back to the surface.

Retrograde metamorphism involves the reconstitution of a rock via revolatisation under decreasing temperatures (and usually pressures), allowing the mineral assemblages formed in prograde metamorphism to revert to those more stable at less extreme conditions. This is a relatively uncommon process, because volatiles produced during prograde metamorphism usually migrate out of the rock and are not available to recombine with the rock during cooling. Localized retrograde metamorphism can take place when fractures in the rock provide a pathway for groundwater to enter the cooling rock.

Equilibrium mineral assemblages

Petrogenetic grid showing aluminium silicate-muscovite-quartz-K feldspar phase boundaries
ACF compatibility diagrams (aluminium-calcium-iron) showing phase equilibria in metamorphic mafic rocks at different P-T circumstances (metamorphic facies). Dots represent mineral phases, thin grey lines are equilibria between two phases. Mineral abbreviations: act = actinolite; cc = calcite; chl = chlorite; di = diopside; ep = epidote; glau = glaucophane; gt = garnet; hbl = hornblende; ky = kyanite; law = lawsonite; plag = plagioclase; om = omphacite; opx = orthopyroxene; zo = zoisite

Metamorphic processes act to bring the protolith closer to thermodynamic equilibrium, which is its state of maximum stability. For example, shear stress (nonhydrodynamic stress) is incompatible with thermodynamic equilibrium, so sheared rock will tend to deform in ways that relieve the shear stress. The most stable assemblage of minerals for a rock of a given composition is that which minimizes the Gibbs free energy

where:

In other words, a metamorphic reaction will take place only if it lowers the total Gibbs free energy of the protolith. Recrystallization to coarser crystals lowers the Gibbs free energy by reducing surface energy, while phase changes and neocrystallization reduce the bulk Gibbs free energy. A reaction will begin at the temperature and pressure where the Gibbs free energy of the reagents becomes greater than that of the products.

A mineral phase will generally be more stable if it has a lower internal energy, reflecting tighter binding between its atoms. Phases with a higher density (expressed as a lower molar volume V) are more stable at higher pressure, while minerals with a less ordered structure (expressed as a higher entropy S) are favored at high temperature. Thus andalusite is stable only at low pressure, since it has the lowest density of any aluminium silicate polymorph, while sillimanite is the stable form at higher temperatures, since it has the least ordered structure.

The Gibbs free energy of a particular mineral at a specified temperature and pressure can be expressed by various analytic formulas. These are calibrated against experimentally measured properties and phase boundaries of mineral assemblages. The equilibrium mineral assemblage for a given bulk composition of rock at a specified temperature and pressure can then be calculated on a computer.

However, it is often very useful to represent equilibrium mineral assemblages using various kinds of diagrams. These include petrogenetic grids and compatibility diagrams (compositional phase diagrams.)

Petrogenetic grids

A petrogenetic grid is a geologic phase diagram that plots experimentally derived metamorphic reactions at their pressure and temperature conditions for a given rock composition. This allows metamorphic petrologists to determine the pressure and temperature conditions under which rocks metamorphose. The Al2SiO5 nesosilicate phase diagram shown is a very simple petrogenetic grid for rocks that only have a composition consisting of aluminum (Al), silicon (Si), and oxygen (O). As the rock undergoes different temperatures and pressure, it could be any of the three given polymorphic minerals. For a rock that contains multiple phases, the boundaries between many phase transformations may be plotted, though the petrogenetic grid quickly becomes complicated. For example, a petrogenetic grid might show both the aluminium silicate phase transitions and the transition from aluminum silicate plus potassium feldspar to muscovite plus quartz.

Compatibility diagrams

Whereas a petrogenetic grid shows phases for a single composition over a range of temperature and pressure, a compatibility diagram shows how the mineral assemblage varies with composition at a fixed temperature and pressure. Compatibility diagrams provide an excellent way to analyze how variations in the rock's composition affect the mineral paragenesis that develops in a rock at particular pressure and temperature conditions. Because of the difficulty of depicting more than three components (as a ternary diagram), usually only the three most important components are plotted, though occasionally a compatibility diagram for four components is plotted as a projected tetrahedron.

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