Plant nutrition

From Wikipedia, the free encyclopedia

Farmer spreading decomposing manure to improve soil fertility and plant nutrition

Plant nutrition is the study of the chemical elements and compounds necessary for plant growth, plant metabolism and their external supply. In 1972, Emanuel Epstein defined two criteria for an element to be essential for plant growth:

1. in its absence the plant is unable to complete a normal life cycle.
2. or that the element is part of some essential plant constituent or metabolite.

This is in accordance with Justus von Liebig's law of the minimum. The essential plant nutrients include carbon, oxygen and hydrogen which are absorbed from the air, whereas other nutrients including nitrogen are typically obtained from the soil (exceptions include some parasitic or carnivorous plants).

There are seventeen most important nutrients for plants. Plants must obtain the following mineral nutrients from their growing medium:

• the macronutrients: nitrogen (N), phosphorus (P), potassium (K), calcium (Ca), sulfur (S), magnesium (Mg), carbon (C), oxygen(O), hydrogen (H)
• the micronutrients (or trace minerals): iron (Fe), boron (B), chlorine (Cl), manganese (Mn), zinc (Zn), copper (Cu), molybdenum (Mo), nickel (Ni)

These elements stay beneath soil as salts, so plants consume these elements as ions. The macronutrients are consumed in larger quantities; hydrogen, oxygen, nitrogen and carbon contribute to over 95% of a plants' entire biomass on a dry matter weight basis. Micronutrients are present in plant tissue in quantities measured in parts per million, ranging from 0.1 to 200 ppm, or less than 0.02% dry weight.

Most soil conditions across the world can provide plants adapted to that climate and soil with sufficient nutrition for a complete life cycle, without the addition of nutrients as fertilizer. However, if the soil is cropped it is necessary to artificially modify soil fertility through the addition of fertilizer to promote vigorous growth and increase or sustain yield. This is done because, even with adequate water and light, nutrient deficiency can limit growth and crop yield.

Processes

Plants take up essential elements from the soil through their roots and from the air (mainly consisting of nitrogen and oxygen) through their leaves. Nutrient uptake in the soil is achieved by cation exchange, wherein root hairs pump hydrogen ions (H⁺) into the soil through proton pumps. These hydrogen ions displace cations attached to negatively charged soil particles so that the cations are available for uptake by the root. In the leaves, stomata open to take in carbon dioxide and expel oxygen. The carbon dioxide molecules are used as the carbon source in photosynthesis. 

The root, especially the root hair, is the essential organ for the uptake of nutrients. The structure and architecture of the root can alter the rate of nutrient uptake. Nutrient ions are transported to the center of the root, the stele, in order for the nutrients to reach the conducting tissues, xylem and phloem. The Casparian strip, a cell wall outside the stele but within the root, prevents passive flow of water and nutrients, helping to regulate the uptake of nutrients and water. Xylem moves water and mineral ions within the plant and phloem accounts for organic molecule transportation. Water potential plays a key role in a plant's nutrient uptake. If the water potential is more negative within the plant than the surrounding soils, the nutrients will move from the region of higher solute concentration—in the soil—to the area of lower solute concentration - in the plant. 

There are three fundamental ways plants uptake nutrients through the root:

1. Simple diffusion occurs when a nonpolar molecule, such as O₂, CO₂, and NH₃ follows a concentration gradient, moving passively through the cell lipid bilayer membrane without the use of transport proteins.
2. Facilitated diffusion is the rapid movement of solutes or ions following a concentration gradient, facilitated by transport proteins.
3. Active transport is the uptake by cells of ions or molecules against a concentration gradient; this requires an energy source, usually ATP, to power molecular pumps that move the ions or molecules through the membrane.

Nutrients can be moved within plants to where they are most needed. For example, a plant will try to supply more nutrients to its younger leaves than to its older ones. When nutrients are mobile within the plant, symptoms of any deficiency become apparent first on the older leaves. However, not all nutrients are equally mobile. Nitrogen, phosphorus, and potassium are mobile nutrients while the others have varying degrees of mobility. When a less-mobile nutrient is deficient, the younger leaves suffer because the nutrient does not move up to them but stays in the older leaves. This phenomenon is helpful in determining which nutrients a plant may be lacking. 

Many plants engage in symbiosis with microorganisms. Two important types of these relationship are

1. with bacteria such as rhizobia, that carry out biological nitrogen fixation, in which atmospheric nitrogen (N₂) is converted into ammonium (NH⁺
   ₄); and
2. with mycorrhizal fungi, which through their association with the plant roots help to create a larger effective root surface area. Both of these mutualistic relationships enhance nutrient uptake.

Though nitrogen is plentiful in the Earth's atmosphere, relatively few plants harbour nitrogen-fixing bacteria, so most plants rely on nitrogen compounds present in the soil to support their growth. These can be supplied by mineralization of soil organic matter or added plant residues, nitrogen fixing bacteria, animal waste, through the breaking of triple bonded N₂ molecules by lightning strikes or through the application of fertilizers.

Functions of nutrients

At least 17 elements are known to be essential nutrients for plants. In relatively large amounts, the soil supplies nitrogen, phosphorus, potassium, calcium, magnesium, and sulfur; these are often called the macronutrients. In relatively small amounts, the soil supplies iron, manganese, boron, molybdenum, copper, zinc, chlorine, and cobalt, the so-called micronutrients. Nutrients must be available not only in sufficient amounts but also in appropriate ratios. 

Plant nutrition is a difficult subject to understand completely, partially because of the variation between different plants and even between different species or individuals of a given clone. Elements present at low levels may cause deficiency symptoms, and toxicity is possible at levels that are too high. Furthermore, deficiency of one element may present as symptoms of toxicity from another element, and vice versa. An abundance of one nutrient may cause a deficiency of another nutrient. For example, K⁺ uptake can be influenced by the amount of NH⁺
₄ available.

Although nitrogen is plentiful in the Earth's atmosphere, relatively few plants engage in nitrogen fixation (conversion of atmospheric nitrogen to a biologically useful form). Most plants, therefore, require nitrogen compounds to be present in the soil in which they grow. 

Carbon and oxygen are absorbed from the air while other nutrients are absorbed from the soil. Green plants obtain their carbohydrate supply from the carbon dioxide in the air by the process of photosynthesis. Each of these nutrients is used in a different place for a different essential function.

Macronutrients (derived from air and water)

Carbon

Carbon forms the backbone of most plant biomolecules, including proteins, starches and cellulose. Carbon is fixed through photosynthesis; this converts carbon dioxide from the air into carbohydrates which are used to store and transport energy within the plant.

Hydrogen

Hydrogen also is necessary for building sugars and building the plant. It is obtained almost entirely from water. Hydrogen ions are imperative for a proton gradient to help drive the electron transport chain in photosynthesis and for respiration.

Oxygen

Oxygen is a component of many organic and inorganic molecules within the plant, and is acquired in many forms. These include: O₂ and CO₂ (mainly from the air via leaves) and H₂O, NO⁻
₃, H₂PO⁻
₄ and SO²⁻
₄ (mainly from the soil water via roots). Plants produce oxygen gas (O₂) along with glucose during photosynthesis but then require O₂ to undergo aerobic cellular respiration and break down this glucose to produce ATP.

Macronutrients (primary)

Nitrogen

Nitrogen is a major constituent of several of the most important plant substances. For example, nitrogen compounds comprise 40% to 50% of the dry matter of protoplasm, and it is a constituent of amino acids, the building blocks of proteins. It is also an essential constituent of chlorophyll. Nitrogen deficiency most often results in stunted growth, slow growth, and chlorosis. Nitrogen deficient plants will also exhibit a purple appearance on the stems, petioles and underside of leaves from an accumulation of anthocyanin pigments. Most of the nitrogen taken up by plants is from the soil in the forms of NO⁻
₃, although in acid environments such as boreal forests where nitrification is less likely to occur, ammonium NH⁺
₄ is more likely to be the dominating source of nitrogen. Amino acids and proteins can only be built from NH⁺
₄, so NO⁻
₃ must be reduced. In many agricultural settings, nitrogen is the limiting nutrient for rapid growth. Nitrogen is transported via the xylem from the roots to the leaf canopy as nitrate ions, or in an organic form, such as amino acids or amides. Nitrogen can also be transported in the phloem sap as amides, amino acids and ureides; it is therefore mobile within the plant, and the older leaves exhibit chlorosis and necrosis earlier than the younger leaves.

There is an abundant supply of nitrogen in the earth’s atmosphere — N₂ gas comprises nearly 79% of air. However, N₂ is unavailable for use by most organisms because there is a triple bond between the two nitrogen atoms in the molecule, making it almost inert. In order for nitrogen to be used for growth it must be “fixed” (combined) in the form of ammonium (NH⁺
₄) or nitrate (NO⁻
₃) ions. The weathering of rocks releases these ions so slowly that it has a negligible effect on the availability of fixed nitrogen. Therefore, nitrogen is often the limiting factor for growth and biomass production in all environments where there is a suitable climate and availability of water to support life. 

Nitrogen enters the plant largely through the roots. A “pool” of soluble nitrogen accumulates. Its composition within a species varies widely depending on several factors, including day length, time of day, night temperatures, nutrient deficiencies, and nutrient imbalance. Short day length promotes asparagine formation, whereas glutamine is produced under long day regimes. Darkness favors protein breakdown accompanied by high asparagine accumulation. Night temperature modifies the effects due to night length, and soluble nitrogen tends to accumulate owing to retarded synthesis and breakdown of proteins. Low night temperature conserves glutamine; high night temperature increases accumulation of asparagine because of breakdown. Deficiency of K accentuates differences between long- and short-day plants. The pool of soluble nitrogen is much smaller than in well-nourished plants when N and P are deficient since uptake of nitrate and further reduction and conversion of N to organic forms is restricted more than is protein synthesis. Deficiencies of Ca, K, and S affect the conversion of organic N to protein more than uptake and reduction. The size of the pool of soluble N is no guide per se to growth rate, but the size of the pool in relation to total N might be a useful ratio in this regard. Nitrogen availability in the rooting medium also affects the size and structure of tracheids formed in the long lateral roots of white spruce (Krasowski and Owens 1999).

Microorganisms have a central role in almost all aspects of nitrogen availability, and therefore for life support on earth. Some bacteria can convert N₂ into ammonia by the process termed nitrogen fixation; these bacteria are either free-living or form symbiotic associations with plants or other organisms (e.g., termites, protozoa), while other bacteria bring about transformations of ammonia to nitrate, and of nitrate to N₂ or other nitrogen gases. Many bacteria and fungi degrade organic matter, releasing fixed nitrogen for reuse by other organisms. All these processes contribute to the nitrogen cycle.

Phosphorus

Like nitrogen, phosphorus is involved with many vital plant processes. Within a plant, it is present mainly as a structural component of the nucleic acids: deoxyribonucleic acid (DNA) and ribonucleic acid (RNA), as well as a constituent of fatty phospholipids, that are important in membrane development and function. It is present in both organic and inorganic forms, both of which are readily translocated within the plant. All energy transfers in the cell are critically dependent on phosphorus. As with all living things, phosphorus is part of the Adenosine triphosphate (ATP), which is of immediate use in all processes that require energy with the cells. Phosphorus can also be used to modify the activity of various enzymes by phosphorylation, and is used for cell signaling. Phosphorus is concentrated at the most actively growing points of a plant and stored within seeds in anticipation of their germination. Phosphorus is most commonly found in the soil in the form of polyprotic phosphoric acid (H₃PO₄), but is taken up most readily in the form of H₂PO⁻
₄. Phosphorus is available to plants in limited quantities in most soils because it is released very slowly from insoluble phosphates and is rapidly fixed once again. Under most environmental conditions it is the element that limits growth because of this constriction and due to its high demand by plants and microorganisms. Plants can increase phosphorus uptake by a mutualism with mycorrhiza. A Phosphorus deficiency in plants is characterized by an intense green coloration or reddening in leaves due to lack of chlorophyll. If the plant is experiencing high phosphorus deficiencies the leaves may become denatured and show signs of death. Occasionally the leaves may appear purple from an accumulation of anthocyanin. Because phosphorus is a mobile nutrient, older leaves will show the first signs of deficiency. 

On some soils, the phosphorus nutrition of some conifers, including the spruces, depends on the ability of mycorrhizae to take up, and make soil phosphorus available to the tree, hitherto unobtainable to the non-mycorrhizal root. Seedling white spruce, greenhouse-grown in sand testing negative for phosphorus, were very small and purple for many months until spontaneous mycorrhizal inoculation, the effect of which was manifested by a greening of foliage and the development of vigorous shoot growth. 

Phosphorus deficiency can produce symptoms similar to those of nitrogen deficiency, but as noted by Russel: “Phosphate deficiency differs from nitrogen deficiency in being extremely difficult to diagnose, and crops can be suffering from extreme starvation without there being any obvious signs that lack of phosphate is the cause”. Russell’s observation applies to at least some coniferous seedlings, but Benzian found that although response to phosphorus in very acid forest tree nurseries in England was consistently high, no species (including Sitka spruce) showed any visible symptom of deficiency other than a slight lack of lustre. Phosphorus levels have to be exceedingly low before visible symptoms appear in such seedlings. In sand culture at 0 ppm phosphorus, white spruce seedlings were very small and tinted deep purple; at 0.62 ppm, only the smallest seedlings were deep purple; at 6.2 ppm, the seedlings were of good size and color.

It is useful to apply a high phosphorus content fertilizer, such as bone meal, to perennials to help with successful root formation.

Potassium

Unlike other major elements, potassium does not enter into the composition of any of the important plant constituents involved in metabolism, but it does occur in all parts of plants in substantial amounts. It seems to be of particular importance in leaves and at growing points. Potassium is outstanding among the nutrient elements for its mobility and solubility within plant tissues. Processes involving potassium include the formation of carbohydrates and proteins, the regulation of internal plant moisture, as a catalyst and condensing agent of complex substances, as an accelerator of enzyme action, and as contributor to photosynthesis, especially under low light intensity. 

Potassium regulates the opening and closing of the stomata by a potassium ion pump. Since stomata are important in water regulation, potassium regulates water loss from the leaves and increases drought tolerance. Potassium deficiency may cause necrosis or interveinal chlorosis. The potassium ion (K⁺) is highly mobile and can aid in balancing the anion (negative) charges within the plant. Potassium helps in fruit coloration, shape and also increases its brix. Hence, quality fruits are produced in potassium-rich soils. Potassium serves as an activator of enzymes used in photosynthesis and respiration. Potassium is used to build cellulose and aids in photosynthesis by the formation of a chlorophyll precursor. Potassium deficiency may result in higher risk of pathogens, wilting, chlorosis, brown spotting, and higher chances of damage from frost and heat. 

When soil-potassium levels are high, plants take up more potassium than needed for healthy growth. The term luxury consumption has been applied to this. When potassium is moderately deficient, the effects first appear in the older tissues, and from there progress towards the growing points. Acute deficiency severely affects growing points, and die-back commonly occurs. Symptoms of potassium deficiency in white spruce include: browning and death of needles (chlorosis); reduced growth in height and diameter; impaired retention of needles; and reduced needle length. A relationship between potassium nutrition and cold resistance has been found in several tree species, including two species of spruce.

Macronutrients (secondary and tertiary)

Sulfur

Sulfur is a structural component of some amino acids (including cystein and methionine) and vitamins, and is essential for chloroplast growth and function; it is found in the iron-sulfur complexes of the electron transport chains in photosynthesis. It is needed for N₂ fixation by legumes, and the conversion of nitrate into amino acids and then into protein.

In plants, sulfur cannot be mobilized from older leaves for new growth, so deficiency symptoms are seen in the youngest tissues first. Symptoms of deficiency include yellowing of leaves and stunted growth.

Calcium

Calcium regulates transport of other nutrients into the plant and is also involved in the activation of certain plant enzymes. Calcium deficiency results in stunting. This nutrient is involved in photosynthesis and plant structure. Blossom end rot is also a result of inadequate calcium.

Another common symptom of calcium deficiency in leaves is the curling of the leaf towards the veins or center of the leaf. Many times this can also have a blackened appearance Calcium has been found to have a positive effect in combating salinity in soils. It has been shown to ameliorate the negative effects that salinity has such as reduced water usage of plants. Calcium in plants occurs chiefly in the leaves, with lower concentrations in seeds, fruits, and roots. A major function is as a constituent of cell walls. When coupled with certain acidic compounds of the jelly-like pectins of the middle lamella, calcium forms an insoluble salt. It is also intimately involved in meristems, and is particularly important in root development, with roles in cell division, cell elongation, and the detoxification of hydrogen ions. Other functions attributed to calcium are; the neutralization of organic acids; inhibition of some potassium-activated ions; and a role in nitrogen absorption. A notable feature of calcium-deficient plants is a defective root system. Roots are usually affected before above-ground parts.

Magnesium

The outstanding role of magnesium in plant nutrition is as a constituent of the chlorophyll molecule. As a carrier, it is also involved in numerous enzyme reactions as an effective activator, in which it is closely associated with energy-supplying phosphorus compounds. Magnesium is very mobile in plants, and, like potassium, when deficient is translocated from older to younger tissues, so that signs of deficiency appear first on the oldest tissues and then spread progressively to younger tissues.

Micro-nutrients

Plants are able sufficiently to accumulate most trace elements. Some plants are sensitive indicators of the chemical environment in which they grow (Dunn 1991), and some plants have barrier mechanisms that exclude or limit the uptake of a particular element or ion species, e.g., alder twigs commonly accumulate molybdenum but not arsenic, whereas the reverse is true of spruce bark (Dunn 1991). Otherwise, a plant can integrate the geochemical signature of the soil mass permeated by its root system together with the contained groundwaters. Sampling is facilitated by the tendency of many elements to accumulate in tissues at the plant’s extremities.

Iron

Iron is necessary for photosynthesis and is present as an enzyme cofactor in plants. Iron deficiency can result in interveinal chlorosis and necrosis. Iron is not a structural part of chlorophyll but very much essential for its synthesis. Copper deficiency can be responsible for promoting an iron deficiency. It helps in the electron transport of plant.

Molybdenum

Molybdenum is a cofactor to enzymes important in building amino acids and is involved in nitrogen metabolism. Molybdenum is part of the nitrate reductase enzyme (needed for the reduction of nitrate) and the nitrogenase enzyme (required for biological nitrogen fixation). Reduced productivity as a result of molybdenum deficiency is usually associated with the reduced activity of one or more of these enzymes.

Boron

Boron is absorbed by plants in the form of the anion BO³⁻
₃. It is available to plants in moderately soluble mineral forms of Ca, Mg and Na borates and the highly soluble form of organic compounds. It is available to plants over a range of pH, from 5.0 to 7.5. It is mobile in the soil, hence, it is prone to leaching. Leaching removes substantial amounts of boron in sandy soil, but little in fine silt or clay soil. Boron's fixation to those minerals at high pH can render boron unavailable, while low pH frees the fixed boron, leaving it prone to leaching in wet climates. It precipitates with other minerals in the form of borax in which form it was first used over 400 years ago as a soil supplement. Decomposition of organic material causes boron to be deposited in the topmost soil layer. When soil dries it can cause a precipitous drop in the availability of boron to plants as the plants cannot draw nutrients from that desiccated layer. Hence, boron deficiency diseases appear in dry weather. 

Boron has many functions within a plant: it affects flowering and fruiting, pollen germination, cell division, and active salt absorption. The metabolism of amino acids and proteins, carbohydrates, calcium, and water are strongly affected by boron. Many of those listed functions may be embodied by its function in moving the highly polar sugars through cell membranes by reducing their polarity and hence the energy needed to pass the sugar. If sugar cannot pass to the fastest growing parts rapidly enough, those parts die. 

Boron is not relocatable in the plant via the phloem. It must be supplied to the growing parts via the xylem. Foliar sprays affect only those parts sprayed, which may be insufficient for the fastest growing parts, and is very temporary. 

Boron is essential for the proper forming and strengthening of cell walls. Lack of boron results in short thick cells producing stunted fruiting bodies and roots. Calcium to boron ratio must be maintained in a narrow range for normal plant growth. For alfalfa, that calcium to boron ratio must be from 80:1 to 600:1. Boron deficiency appears at 800:1 and higher. Boron levels within plants differ with plant species and range from 2.3 mg/kg for barley to 94.7 mg/kg for poppy. Lack of boron causes failure of calcium metabolism which produces hollow heart in beets and peanuts. 

Inadequate amounts of boron affect many agricultural crops, legume forage crops most strongly. Of the micronutrients, boron deficiencies are second most common after zinc. Deficiency results in the death of the terminal growing points and stunted growth. 

Boron supplements derive from dry lake bed deposits such as those in Death Valley, USA, in the form of sodium tetraborate (borax), from which less soluble calcium borate is made. Foliar sprays are used on fruit crop trees in soils of high alkalinity. Boron is often applied to fields as a contaminant in other soil amendments but is not generally adequate to make up the rate of loss by cropping. The rates of application of borate to produce an adequate alfalfa crop range from 15 pounds per acre for a sandy-silt, acidic soil of low organic matter, to 60 pounds per acre for a soil with high organic matter, high cation exchange capacity and high pH.

Boron concentration in soil water solution higher than one ppm is toxic to most plants. Toxic concentrations within plants are 10 to 50 ppm for small grains and 200 ppm in boron-tolerant crops such as sugar beets, rutabaga, cucumbers, and conifers. Toxic soil conditions are generally limited to arid regions or can be caused by underground borax deposits in contact with water or volcanic gases dissolved in percolating water. Application rates should be limited to a few pounds per acre in a test plot to determine if boron is needed generally. Otherwise, testing for boron levels in plant material is required to determine remedies. Excess boron can be removed by irrigation and assisted by application of elemental sulfur to lower the pH and increase boron solubility. 

Boron deficiencies can be detected by analysis of plant material to apply a correction before the obvious symptoms appear, after which it is too late to prevent crop loss. Strawberries deficient in boron will produce lumpy fruit; apricots will not blossom or, if they do, will not fruit or will drop their fruit depending on the level of boron deficit. Broadcast of boron supplements is effective and long term; a foliar spray is immediate but must be repeated.

Copper

Copper is important for photosynthesis. Symptoms for copper deficiency include chlorosis.It is involved in many enzyme processes; necessary for proper photosynthesis; involved in the manufacture of lignin (cell walls) and involved in grain production. It is also hard to find in some soil conditions.

Manganese

Manganese is necessary for photosynthesis, including the building of chloroplasts. Manganese deficiency may result in coloration abnormalities, such as discolored spots on the foliage.

Sodium

Sodium is involved in the regeneration of phosphoenolpyruvate in CAM and C4 plants. Sodium can potentially replace potassium's regulation of stomatal opening and closing.

Essentiality of sodium:

• Essential for C4 plants rather C3
• Substitution of K by Na: Plants can be classified into four groups:

1. Group A—a high proportion of K can be replaced by Na and stimulate the growth, which cannot be achieved by the application of K
2. Group B—specific growth responses to Na are observed but they are much less distinct
3. Group C—Only minor substitution is possible and Na has no effect
4. Group D—No substitution occurs

• Stimulate the growth—increase leaf area and stomata. Improves the water balance
• Na functions in metabolism

1. C4 metabolism
2. Impair the conversion of pyruvate to phosphoenol-pyruvate
3. Reduce the photosystem II activity and ultrastructural changes in mesophyll chloroplast

• Replacing K functions

1. Internal osmoticum
2. Stomatal function
3. Photosynthesis
4. Counteraction in long distance transport
5. Enzyme activation

• Improves the crop quality e.g. improves the taste of carrots by increasing sucrose

Zinc

Zinc is required in a large number of enzymes and plays an essential role in DNA transcription. A typical symptom of zinc deficiency is the stunted growth of leaves, commonly known as "little leaf" and is caused by the oxidative degradation of the growth hormone auxin.

Nickel

In higher plants, nickel is absorbed by plants in the form of Ni²⁺ ion. Nickel is essential for activation of urease, an enzyme involved with nitrogen metabolism that is required to process urea. Without nickel, toxic levels of urea accumulate, leading to the formation of necrotic lesions. In lower plants, nickel activates several enzymes involved in a variety of processes, and can substitute for zinc and iron as a cofactor in some enzymes.

Chlorine

Chlorine, as compounded chloride, is necessary for osmosis and ionic balance; it also plays a role in photosynthesis.

Cobalt

Cobalt has proven to be beneficial to at least some plants although it does not appear to be essential for most species. It has, however, been shown to be essential for nitrogen fixation by the nitrogen-fixing bacteria associated with legumes and other plants.

Aluminium

Aluminum is one of the few elements capable of making soil more acidic. This is achieved by aluminum taking hydroxide ions out of water, leaving hydrogen ions behind. As a result, the soil is more acidic, which makes it unlivable for many plants. Another consequence of aluminum in soils is aluminum toxicity, which inhibits root growth.

• Tea has a high tolerance for aluminum (Al) toxicity and the growth is stimulated by Al application. The possible reason is the prevention of Cu, Mn or P toxicity effects.
• There have been reports that Al may serve as a fungicide against certain types of root rot.

Silicon

Silicon is not considered an essential element for plant growth and development. It is always found in abundance in the environment and hence if needed it is available. It is found in the structures of plants and improves the health of plants.

In plants, silicon has been shown in experiments to strengthen cell walls, improve plant strength, health, and productivity. There have been studies showing evidence of silicon improving drought and frost resistance, decreasing lodging potential and boosting the plant's natural pest and disease fighting systems. Silicon has also been shown to improve plant vigor and physiology by improving root mass and density, and increasing above ground plant biomass and crop yields. Silicon is currently under consideration by the Association of American Plant Food Control Officials (AAPFCO) for elevation to the status of a "plant beneficial substance".

Vanadium

Vanadium may be required by some plants, but at very low concentrations. It may also be substituting for molybdenum.

Selenium

Selenium is probably not essential for flowering plants, but it can be beneficial; it can stimulate plant growth, improve tolerance of oxidative stress, and increase resistance to pathogens and herbivory.

Selenium is, however, an essential mineral element for animal (including human) nutrition and selenium deficiencies are known to occur when food or animal feed is grown on selenium-deficient soils. The use of inorganic selenium fertilizers can increase selenium concentrations in edible crops and animal diets thereby improving animal health.

Nutrient deficiency

The effect of a nutrient deficiency can vary from a subtle depression of growth rate to obvious stunting, deformity, discoloration, distress, and even death. Visual symptoms distinctive enough to be useful in identifying a deficiency are rare. Most deficiencies are multiple and moderate. However, while a deficiency is seldom that of a single nutrient, nitrogen is commonly the nutrient in shortest supply.

Chlorosis of foliage is not always due to mineral nutrient deficiency. Solarization can produce superficially similar effects, though mineral deficiency tends to cause premature defoliation, whereas solarization does not, nor does solarization depress nitrogen concentration.

Nutrient status of plants

Nutrient status (mineral nutrient and trace element composition, also called ionome and nutrient profile) of plants are commonly portrayed by tissue elementary analysis. Interpretation of the results of such studies, however, has been controversial. During the last decades the nearly two-century-old “law of minimum” or “Liebig's law” (that states that plant growth is controlled not by the total amount of resources available, but by the scarcest resource) has been replaced by several mathematical approaches that use different models in order to take the interactions between the individual nutrients into account. The latest developments in this field are based on the fact that the nutrient elements (and compounds) do not act independently from each other; Baxter, 2015, because there may be direct chemical interactions between them or they may influence each other’s uptake, translocation, and biological action via a number of mechanisms as exemplified for the case of ammonia.

Plant nutrition in agricultural systems

Hydroponics

Hydroponics is a method for growing plants in a water-nutrient solution without the use of nutrient-rich soil. It allows researchers and home gardeners to grow their plants in a controlled environment. The most common solution is the Hoagland solution, developed by D. R. Hoagland in 1933. The solution consists of all the essential nutrients in the correct proportions necessary for most plant growth. An aerator is used to prevent an anoxic event or hypoxia. Hypoxia can affect nutrient uptake of a plant because, without oxygen present, respiration becomes inhibited within the root cells. The nutrient film technique is a hydroponic technique in which the roots are not fully submerged. This allows for adequate aeration of the roots, while a "film" thin layer of nutrient-rich water is pumped through the system to provide nutrients and water to the plant.

Soil science

From Wikipedia, the free encyclopedia

A soil scientist examines horizons within the soil profile

 

Soil science is the study of soil as a natural resource on the surface of the Earth including soil formation, classification and mapping; physical, chemical, biological, and fertility properties of soils; and these properties in relation to the use and management of soils.

Sometimes terms which refer to branches of soil science, such as pedology (formation, chemistry, morphology, and classification of soil) and edaphology (how soils interact with living things, especially plants), are used as if synonymous with soil science. The diversity of names associated with this discipline is related to the various associations concerned. Indeed, engineers, agronomists, chemists, geologists, physical geographers, ecologists, biologists, microbiologists, silviculturists, sanitarians, archaeologists, and specialists in regional planning, all contribute to further knowledge of soils and the advancement of the soil sciences. 

Soil scientists have raised concerns about how to preserve soil and arable land in a world with a growing population, possible future water crisis, increasing per capita food consumption, and land degradation.

Fields of study

Soil occupies the pedosphere, one of Earth's spheres that the geosciences use to organize the Earth conceptually. This is the conceptual perspective of pedology and edaphology, the two main branches of soil science. Pedology is the study of soil in its natural setting. Edaphology is the study of soil in relation to soil-dependent uses. Both branches apply a combination of soil physics, soil chemistry, and soil biology. Due to the numerous interactions between the biosphere, atmosphere and hydrosphere that are hosted within the pedosphere, more integrated, less soil-centric concepts are also valuable. Many concepts essential to understanding soil come from individuals not identifiable strictly as soil scientists. This highlights the interdisciplinary nature of soil concepts.

Research

Dependence on and curiosity about soil, exploring the diversity and dynamics of this resource continues to yield fresh discoveries and insights. New avenues of soil research are compelled by a need to understand soil in the context of climate change, greenhouse gases, and carbon sequestration. Interest in maintaining the planet's biodiversity and in exploring past cultures has also stimulated renewed interest in achieving a more refined understanding of soil.

Mapping

Most empirical knowledge of soil in nature comes from soil survey efforts. Soil survey, or soil mapping, is the process of determining the soil types or other properties of the soil cover over a landscape, and mapping them for others to understand and use. It relies heavily on distinguishing the individual influences of the five classic soil forming factors. This effort draws upon geomorphology, physical geography, and analysis of vegetation and land-use patterns. Primary data for the soil survey are acquired by field sampling and supported by remote sensing.

Classification

Map of global soil regions from the USDA

As of 2006, the World Reference Base for Soil Resources, via its Land & Water Development division, is the pre-eminent soil classification system. It replaces the previous FAO soil classification.

The WRB borrows from modern soil classification concepts, including USDA soil taxonomy. The classification is based mainly on soil morphology as an expression pedogenesis. A major difference with USDA soil taxonomy is that soil climate is not part of the system, except insofar as climate influences soil profile characteristics. 

Many other classification schemes exist, including vernacular systems. The structure in vernacular systems are either nominal, giving unique names to soils or landscapes, or descriptive, naming soils by their characteristics such as red, hot, fat, or sandy. Soils are distinguished by obvious characteristics, such as physical appearance (e.g., color, texture, landscape position), performance (e.g., production capability, flooding), and accompanying vegetation. A vernacular distinction familiar to many is classifying texture as heavy or light. Light soil content and better structure, take less effort to turn and cultivate. Contrary to popular belief, light soils do not weigh less than heavy soils on an air dry basis nor do they have more porosity.

History

Contemporaries Friedrich Albert Fallou, the German founder of soil science, and Vasily Dokuchaev, the Russian founder of soil science, are both credited with being among the first to identify soil as a resource whose distinctness and complexity deserved to be separated conceptually from geology and crop production and treated as a whole. As a founding father of soil science Fallou has primacy in time. Fallou was working on the origins of soil before Dokuchaev was born, however Dokuchaev's work was more extensive and is considered to be the more significant to modern soil theory than Fallou's, such that Fallou is treated as not notable by Dokuchaev's promoters.

Previously, soil had been considered a product of chemical transformations of rocks, a dead substrate from which plants derive nutritious elements. Soil and bedrock were in fact equated. Dokuchaev considers the soil as a natural body having its own genesis and its own history of development, a body with complex and multiform processes taking place within it. The soil is considered as different from bedrock. The latter becomes soil under the influence of a series of soil-formation factors (climate, vegetation, country, relief and age). According to him, soil should be called the "daily" or outward horizons of rocks regardless of the type; they are changed naturally by the common effect of water, air and various kinds of living and dead organisms.

A 1914 encyclopedic definition: "the different forms of earth on the surface of the rocks, formed by the breaking down or weathering of rocks". serves to illustrate the historic view of soil which persisted from the 19th century. Dokuchaev's late 19th century soil concept developed in the 20th century to one of soil as earthy material that has been altered by living processes. A corollary concept is that soil without a living component is simply a part of earth's outer layer. 

Further refinement of the soil concept is occurring in view of an appreciation of energy transport and transformation within soil. The term is popularly applied to the material on the surface of the Earth's moon and Mars, a usage acceptable within a portion of the scientific community. Accurate to this modern understanding of soil is Nikiforoff's 1959 definition of soil as the "excited skin of the sub aerial part of the earth's crust".

Areas of practice

Academically, soil scientists tend to be drawn to one of five areas of specialization: microbiology, pedology, edaphology, physics, or chemistry. Yet the work specifics are very much dictated by the challenges facing our civilization's desire to sustain the land that supports it, and the distinctions between the sub-disciplines of soil science often blur in the process. Soil science professionals commonly stay current in soil chemistry, soil physics, soil microbiology, pedology, and applied soil science in related disciplines.

One interesting effort drawing in soil scientists in the USA as of 2004 is the Soil Quality Initiative. Central to the Soil Quality Initiative is developing indices of soil health and then monitoring them in a way that gives us long term (decade-to-decade) feedback on our performance as stewards of the planet. The effort includes understanding the functions of soil microbiotic crusts and exploring the potential to sequester atmospheric carbon in soil organic matter. The concept of soil quality, however, has not been without its share of controversy and criticism, including critiques by Nobel Laureate Norman Borlaug and World Food Prize Winner Pedro Sanchez. 

A more traditional role for soil scientists has been to map soils. Most every area in the United States now has a published soil survey, which includes interpretive tables as to how soil properties support or limit activities and uses. An internationally accepted soil taxonomy allows uniform communication of soil characteristics and functions. National and international soil survey efforts have given the profession unique insights into landscape scale functions. The landscape functions that soil scientists are called upon to address in the field seem to fall roughly into six areas:

• Land-based treatment of wastes
  • Septic system
  • Manure
  • Municipal biosolids
  • Food and fiber processing waste
• Identification and protection of environmentally critical areas
  • Sensitive and unstable soils
  • Wetlands
  • Unique soil situations that support valuable habitat, and ecosystem diversity
• Management for optimum land productivity
  • Silviculture
  • Agronomy
    • Nutrient management
    • Water management
  • Native vegetation
  • Grazing
• Management for optimum water quality
  • Stormwater management
  • Sediment and erosion control
• Remediation and restoration of damaged lands
  • Mine reclamation
  • Flood and storm damage
  • Contamination
• Sustainability of desired uses
  • Soil conservation

There are also practical applications of soil science that might not be apparent from looking at a published soil survey.

• Radiometric dating: specifically a knowledge of local pedology is used to date prior activity at the site
  • Stratification (archeology) where soil formation processes and preservative qualities can inform the study of archaeological sites
  • Geological phenomena
    • Landslides
    • Active faults
• Altering soils to achieve new uses
  • Vitrification to contain radioactive wastes
  • Enhancing soil microbial capabilities in degrading contaminants (bioremediation).
  • Carbon sequestration
  • Environmental soil science
• Pedology
  • Soil genesis
  • Pedometrics
  • Soil morphology
    • Soil micromorphology
  • Soil classification
    • USDA soil taxonomy
• Soil biology
  • Soil microbiology
• Soil chemistry
  • Soil biochemistry
  • Soil mineralogy
• Soil physics
  • Pedotransfer function
  • Soil mechanics and engineering
• Soil hydrology, hydropedology

Fields of application in soil science

• Climate change
• Ecosystem studies
• Pedotransfer function
• Soil fertility / Nutrient management
• Soil management
• Soil survey
• Standard methods of analysis
• Watershed and wetland studies

Related disciplines

• Agricultural sciences
  • Agricultural soil science
  • Agrophysics science
  • Irrigation management
• Anthropology
  • archaeological stratigraphy
• Environmental science
  • Landscape ecology
• Physical geography
  • Geomorphology
• Geology
  • Biogeochemistry
  • Geomicrobiology
• Hydrology
  • Hydrogeology
• Waste management
• Wetland science

Depression storage capacity

Depression storage capacity, in soil science, is the ability of a particular area of land to retain water in its pits and depressions, thus preventing it from flowing. Depression storage capacity, along with infiltration capacity, is one of the main factors involved in Horton overland flow, whereby water volume surpasses both infiltration and depression storage capacity and begins to flow horizontally across land, possibly leading to flooding and soil erosion. The study of land's depression storage capacity is important in the fields of geology, ecology, and especially hydrology.

Industrial ecology

From Wikipedia, the free encyclopedia

Industrial ecology (IE) is the study of material and energy flows through industrial systems. The global industrial economy can be modelled as a network of industrial processes that extract resources from the Earth and transform those resources into commodities which can be bought and sold to meet the needs of humanity. Industrial ecology seeks to quantify the material flows and document the industrial processes that make modern society function. Industrial ecologists are often concerned with the impacts that industrial activities have on the environment, with use of the planet's supply of natural resources, and with problems of waste disposal. Industrial ecology is a young but growing multidisciplinary field of research which combines aspects of engineering, economics, sociology, toxicology and the natural sciences.

 

Industrial ecology has been defined as a "systems-based, multidisciplinary discourse that seeks to understand emergent behaviour of complex integrated human/natural systems".^[1] The field approaches issues of sustainability by examining problems from multiple perspectives, usually involving aspects of sociology, the environment, economy and technology. The name comes from the idea that the analogy of natural systems should be used as an aid in understanding how to design sustainable industrial systems.

Overview

Example of Industrial Symbiosis. Waste steam from a waste incinerator (right) is piped to an ethanol plant (left) where it is used as in input to their production process.

Industrial ecology is concerned with the shifting of industrial process from linear (open loop) systems, in which resource and capital investments move through the system to become waste, to a closed loop system where wastes can become inputs for new processes.

Much of the research focuses on the following areas:

• material and energy flow studies ("industrial metabolism")
• dematerialization and decarbonization
• technological change and the environment
• life-cycle planning, design and assessment
• design for the environment ("eco-design")
• extended producer responsibility ("product stewardship")
• eco-industrial parks ("industrial symbiosis")
• product-oriented environmental policy
• eco-efficiency

Industrial ecology seeks to understand the way in which industrial systems (for example a factory, an ecoregion, or national or global economy) interact with the biosphere. Natural ecosystems provide a metaphor for understanding how different parts of industrial systems interact with one another, in an "ecosystem" based on resources and infrastructural capital rather than on natural capital. It seeks to exploit the idea that natural systems do not have waste in them to inspire sustainable design.

Along with more general energy conservation and material conservation goals, and redefining commodity markets and product stewardship relations strictly as a service economy, industrial ecology is one of the four objectives of Natural Capitalism. This strategy discourages forms of amoral purchasing arising from ignorance of what goes on at a distance and implies a political economy that values natural capital highly and relies on more instructional capital to design and maintain each unique industrial ecology.

History

View of Kalundborg Eco-industrial Park

Industrial ecology was popularized in 1989 in a Scientific American article by Robert Frosch and Nicholas E. Gallopoulos. Frosch and Gallopoulos' vision was "why would not our industrial system behave like an ecosystem, where the wastes of a species may be resource to another species? Why would not the outputs of an industry be the inputs of another, thus reducing use of raw materials, pollution, and saving on waste treatment?" A notable example resides in a Danish industrial park in the city of Kalundborg. Here several linkages of byproducts and waste heat can be found between numerous entities such as a large power plant, an oil refinery, a pharmaceutical plant, a plasterboard factory, an enzyme manufacturer, a waste company and the city itself. Another example is the Rantasalmi EIP in Rantasalmi, Finland. While this country has had previous organically formed EIP's, the park at Rantasalmi is Finland's first planned EIP.

The scientific field Industrial Ecology has grown quickly in recent years. The Journal of Industrial Ecology (since 1997), the International Society for Industrial Ecology (since 2001), and the journal Progress in Industrial Ecology (since 2004) give Industrial Ecology a strong and dynamic position in the international scientific community. Industrial Ecology principles are also emerging in various policy realms such as the concept of the Circular Economy that is being promoted in China. Although the definition of the Circular Economy has yet to be formalized, generally the focus is on strategies such as creating a circular flow of materials, and cascading energy flows. An example of this would be using waste heat from one process to run another process that requires a lower temperature. The hope is that strategy such as this will create a more efficient economy with fewer pollutants and other unwanted by-products.

Principles

One of the central principles of Industrial Ecology is the view that societal and technological systems are bounded within the biosphere, and do not exist outside it. Ecology is used as a metaphor due to the observation that natural systems reuse materials and have a largely closed loop cycling of nutrients. Industrial Ecology approaches problems with the hypothesis that by using similar principles as natural systems, industrial systems can be improved to reduce their impact on the natural environment as well. The table shows the general metaphor. 

Biosphere	Technosphere
Environment Organism Natural Product Natural Selection Ecosystem Ecological Niche Anabolism / Catabolism Mutation and Selection Succession Adaptation Food Web	Market Company Industrial Product Competition Eco-Industrial Park Market Niche Manufacturing / Waste Management Design for Environment Economic Growth Innovation Product Life Cycle

IE examines societal issues and their relationship with both technical systems and the environment. Through this holistic view , IE recognizes that solving problems must involve understanding the connections that exist between these systems, various aspects cannot be viewed in isolation. Often changes in one part of the overall system can propagate and cause changes in another part. Thus, you can only understand a problem if you look at its parts in relation to the whole. Based on this framework, IE looks at environmental issues with a systems thinking approach. A good IE example with these societal impacts can be found at the Blue Lagoon in Iceland. The Lagoon uses super-heated water from a local geothermal power plant to fill mineral-rich basins that have become recreational healing centers. In this sense the industrial process of energy production uses its wastewater to provide a crucial resource for the dependent recreational industry.

Take a city for instance. A city can be divided into commercial areas, residential areas, offices, services, infrastructures, and so forth. These are all sub-systems of the 'big city’ system. Problems can emerge in one sub-system, but the solution has to be global. Let’s say the price of housing is rising dramatically because there is too high a demand for housing. One solution would be to build new houses, but this will lead to more people living in the city, leading to the need for more infrastructure like roads, schools, more supermarkets, etc. This system is a simplified interpretation of reality whose behaviors can be ‘predicted’. 

In many cases, the systems IE deals with are complex systems. Complexity makes it difficult to understand the behavior of the system and may lead to rebound effects. Due to unforeseen behavioral change of users or consumers, a measure taken to improve environmental performance does not lead to any improvement or may even worsen the situation.

Moreover, life cycle thinking is also a very important principle in industrial ecology. It implies that all environmental impacts caused by a product, system, or project during its life cycle are taken into account. In this context life cycle includes

• Raw material extraction
• Material processing
• Manufacture
• Use
• Maintenance
• Disposal

The transport necessary between these stages is also taken into account as well as, if relevant, extra stages such as reuse, remanufacture, and recycle. Adopting a life cycle approach is essential to avoid shifting environmental impacts from one life cycle stage to another. This is commonly referred to as problem shifting. For instance, during the re-design of a product, one can choose to reduce its weight, thereby decreasing use of resources. However, it is possible that the lighter materials used in the new product will be more difficult to dispose of. The environmental impacts of the product gained during the extraction phase are shifted to the disposal phase. Overall environmental improvements are thus null. 

A final important principle of IE is its integrated approach or multidisciplinarity. IE takes into account three different disciplines: social sciences (including economics), technical sciences and environmental sciences. The challenge is to merge them into a single approach.

Examples

The Kalundborg industrial park is located in Denmark. This industrial park is special because companies reuse each other's waste (which then becomes by-products). For example, the Energy E2 Asnæs Power Station produces gypsum as a by-product of the electricity generation process; this gypsum becomes a resource for the BPB Gyproc A/S which produces plasterboards. This is one example of a system inspired by the biosphere-technosphere metaphor: in ecosystems, the waste from one organism is used as inputs to other organisms; in industrial systems, waste from a company is used as a resource by others. 

Apart from the direct benefit of incorporating waste into the loop, the use of an eco-industrial park can be a means of making renewable energy generating plants, like Solar PV, more economical and environmentally friendly. In essence, this assists the growth of the renewable energy industry and the environmental benefits that come with replacing fossil-fuels.

Additional examples of industrial ecology include:

• Substituting the fly ash byproduct of coal burning practices for cement in concrete production
• Using second generation biofuels. An example of this is converting grease or cooking oil to biodiesels to fuel vehicles.
• South Africa's National Cleaner Production Center (NCPC) was created in order to make the region's industries more efficient in terms of materials. Results of the use of sustainable methods will include lowered energy costs and improved waste management. The program assesses existing companies to implement change.

Tools

People	Planet	Profit	Modeling
Stakeholder analysis Strength Weakness Opportunities Threats Analysis (SWOT Analysis) Ecolabelling ISO 14000 Environmental management system (EMS) Integrated chain management (ICM) Technology assessment	Environmental impact assessment (EIA) Input-output analysis (IOA) Life-cycle assessment (LCA) Material flow analysis (MFA) Substance flow analysis (SFA) MET Matrix	Cost benefit analysis (CBA) Full cost accounting (FCA) Life cycle costing (LCC)	Stock and flow analysis Agent based modeling

Future directions

The ecosystem metaphor popularized by Frosch and Gallopoulos has been a valuable creative tool for helping researchers look for novel solutions to difficult problems. Recently, it has been pointed out that this metaphor is based largely on a model of classical ecology, and that advancements in understanding ecology based on complexity science have been made by researchers such as C. S. Holling, James J. Kay, and further advanced in terms of contemporary ecology by others. For industrial ecology, this may mean a shift from a more mechanistic view of systems, to one where sustainability is viewed as an emergent property of a complex system. To explore this further, several researchers are working with agent based modeling techniques.

Exergy analysis is performed in the field of industrial ecology to use energy more efficiently. The term exergy was coined by Zoran Rant in 1956, but the concept was developed by J. Willard Gibbs. In recent decades, utilization of exergy has spread outside physics and engineering to the fields of industrial ecology, ecological economics, systems ecology, and energetics.

Other examples

Another great example of industrial ecology both in practice and in potential is the Burnside Cleaner Production Centre in Burnside, Nova Scotia. They play a role in facilitating the 'greening' of over 1200 businesses that are located in Burnside, Eastern Canada's largest industrial park. The creation of waste exchange is a big part of what they work towards, which will promote strong industrial ecology relationships.