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Friday, August 15, 2025

Climate change in the Arctic

From Wikipedia, the free encyclopedia

Due to climate change in the Arctic, this polar region is expected to become "profoundly different" by 2050. The speed of change is "among the highest in the world", with warming occurring at 3-4 times faster than the global average. This warming has already resulted in the profound Arctic sea ice decline, the accelerating melting of the Greenland ice sheet and the thawing of the permafrost landscape. These ongoing transformations are expected to be irreversible for centuries or even millennia.

Natural life in the Arctic is affected greatly. As the tundra warms, its soil becomes more hospitable to earthworms and larger plants, and the boreal forests spread to the north - yet this also makes the landscape more prone to wildfires, which take longer to recover from than in the other regions. Beavers also take advantage of this warming to colonize the Arctic rivers, and their dams contributing to methane emissions due to the increase in stagnant waters. The Arctic Ocean has experienced a large increase in the marine primary production as warmer waters and less shade from sea ice benefit phytoplankton. At the same time, it is already less alkaline than the rest of the global ocean, so ocean acidification caused by the increasing CO2 concentrations is more severe, threatening some forms of zooplankton such as pteropods.

The Arctic Ocean is expected to see its first ice-free events in the near future - most likely before 2050, and potentially in the late 2020s or early 2030s. This would have no precedent in the last 700,000 years. Some sea ice regrows every Arctic winter, but such events are expected to occur more and more frequently as the warming increases. This has great implications for the fauna species which are dependent on sea ice, such as polar bears. For humans, trade routes across the ocean will become more convenient. Yet, multiple countries have infrastructure in the Arctic which is worth billions of dollars, and it is threatened with collapse as the underlying permafrost thaws. The Arctic's indigenous people have a long relationship with its icy conditions, and face the loss of their cultural heritage.

Further, there are numerous implications which go beyond the Arctic region. Sea ice loss not only enhances warming in the Arctic but also adds to global temperature increase through the ice-albedo feedback. Permafrost thaw results in emissions of CO2 and methane that are comparable to those of major countries. Greenland melting is a significant contributor to global sea level rise. If the warming exceeds - or thereabouts, there is a significant risk of the entire ice sheet being lost over an estimated 10,000 years, adding up to global sea levels. Warming in the Arctic may affect the stability of the jet stream, and thus the extreme weather events in midlatitude regions, but there is only "low confidence" in that hypothesis.

Impacts on the physical environment

Warming

The image above shows where average air temperatures (October 2010 – September 2011) were up to 2 degrees Celsius above (red) or below (blue) the long-term average (1981–2010).

The period of 1995–2005 was the warmest decade in the Arctic since at least the 17th century, with temperatures 2 °C (3.6 °F) above the 1951–1990 average. Alaska and western Canada's temperature rose by 3 to 4 °C (5.40 to 7.20 °F) during that period. 2013 research has shown that temperatures in the region haven't been as high as they currently are since at least 44,000 years ago and perhaps as long as 120,000 years ago. Since 2013, Arctic annual mean surface air temperature (SAT) has been at least 1 °C (1.8 °F) warmer than the 1981-2010 mean.

In 2016, there were extreme anomalies from January to February with the temperature in the Arctic being estimated to be between 4–5.8 °C (7.2–10.4 °F) more than it was between 1981 and 2010. In 2020, mean SAT was 1.9 °C (3.4 °F) warmer than the 1981–2010 average. On 20 June 2020, for the first time, a temperature measurement was made inside the Arctic Circle of 38 °C, more than 100 °F. This kind of weather was expected in the region only by 2100. In March, April and May the average temperature in the Arctic was 10 °C (18.0 °F) higher than normal. This heat wave, without human – induced warming, could happen only one time in 80,000 years, according to an attribution study published in July 2020. It is the strongest link of a weather event to anthropogenic climate change that had been ever found, for now.

Arctic amplification

Potential regional warming caused by the loss of all land ice outside of East Antarctica, and by the disappearance of Arctic sea ice every year starting from June. While plausible, consistent sea ice loss would likely require relatively high warming, and the loss of all ice in Greenland would require multiple millennia.

Snow– and ice–albedo feedback have a substantial effect on regional temperatures. In particular, the presence of ice cover and sea ice makes the North Pole and the South Pole colder than they would have been without it. Consequently, recent Arctic sea ice decline is one of the primary factors behind the Arctic warming nearly four times faster than the global average since 1979 (the year when continuous satellite readings of the Arctic sea ice began), in a phenomenon known as Arctic amplification.

Modelling studies show that strong Arctic amplification only occurs during the months when significant sea ice loss occurs, and that it largely disappears when the simulated ice cover is held fixed. Conversely, the high stability of ice cover in Antarctica, where the thickness of the East Antarctic ice sheet allows it to rise nearly 4 km above the sea level, means that this continent has experienced very little net warming over the past seven decades, most of which was concentrated in West Antarctica. Ice loss in the Antarctic and its contribution to sea level rise is instead driven overwhelmingly by the warming of the Southern Ocean, which had absorbed 35–43% of the total heat taken up by all oceans between 1970 and 2017.

Ice–albedo feedback also has a smaller, but still notable effect on the global temperatures. Arctic sea ice decline between 1979 and 2011 is estimated to have been responsible for 0.21 watts per square meter (W/m2) of radiative forcing, which is equivalent to a quarter of radiative forcing from CO2 increases over the same period. When compared to cumulative increases in greenhouse gas radiative forcing since the start of the Industrial Revolution, it is equivalent to the estimated 2019 radiative forcing from nitrous oxide (0.21 W/m2), nearly half of 2019 radiative forcing from methane (0.54 W/m2) and 10% of the cumulative CO2 increase (2.16 W/m2). Between 1992 and 2015, this effect was partly offset by the growth in sea ice cover around Antarctica, which produced cooling of about 0.06 W/m2 per decade. However, Antarctic sea ice had also begun to decline afterwards, and the combined role of changes in ice cover between 1992 and 2018 is equivalent to 10% of all the anthropogenic greenhouse gas emissions.
The dark ocean surface reflects only 6 percent of incoming solar radiation, while sea ice reflects 50 to 70 percent.

The Arctic was historically described as warming twice as fast as the global average, but this estimate was based on older observations which missed the more recent acceleration. By 2021, enough data was available to show that the Arctic had warmed three times as fast as the globe - 3.1°C between 1971 and 2019, as opposed to the global warming of 1°C over the same period. Moreover, this estimate defines the Arctic as everything above 60th parallel north, or a full third of the Northern Hemisphere: in 2021–2022, it was found that since 1979, the warming within the Arctic Circle itself (above the 66th parallel) has been nearly four times faster than the global average. Within the Arctic Circle itself, even greater Arctic amplification occurs in the Barents Sea area, with hotspots around West Spitsbergen Current: weather stations located on its path record decadal warming up to seven times faster than the global average. This has fuelled concerns that unlike the rest of the Arctic sea ice, ice cover in the Barents Sea may permanently disappear even around 1.5 degrees of global warming.

The acceleration of Arctic amplification has not been linear: a 2022 analysis found that it occurred in two sharp steps, with the former around 1986, and the latter after 2000. The first acceleration is attributed to the increase in anthropogenic radiative forcing in the region, which is in turn likely connected to the reductions in stratospheric sulfur aerosols pollution in Europe in the 1980s in order to combat acid rain. Since sulphate aerosols have a cooling effect, their absence is likely to have increased Arctic temperatures by up to 0.5 degrees Celsius. The second acceleration has no known cause, which is why it did not show up in any climate models. It is likely to be an example of multi-decadal natural variability, like the suggested link between Arctic temperatures and Atlantic Multi-decadal Oscillation (AMO), in which case it can be expected to reverse in the future. However, even the first increase in Arctic amplification was only accurately simulated by a fraction of the current CMIP6 models. Recent studies show the Arctic has warmed nearly four times faster than the global average since 1979, with areas like the Barents Sea experiencing rates up to seven times higher, highlighting the urgent need to address polar climate change.

Precipitation

An observed impact of climate change is a strong increase in the number of lightnings in the Arctic. Lightnings increase the risk for wildfires. Some research suggests that globally, a warming greater than 1.5 °C (2.7 °F) over the preindustrial level could change the type of precipitation in the Arctic from snow to rain in summer and autumn.

Cryosphere loss

On average, climate change has lowered the thickness of land ice with every year, and reduced the extent of sea ice cover.

Sea ice

1870–2009 Northern Hemisphere sea ice extent in million square kilometers. Blue shading indicates the pre-satellite era; data then is less reliable.

Sea ice in the Arctic region has declined in recent decades in area and volume due to climate change. It has been melting more in summer than it refreezes in winter. Global warming, caused by greenhouse gas forcing is responsible for the decline in Arctic sea ice. The decline of sea ice in the Arctic has been accelerating during the early twenty-first century, with a decline rate of 4.7% per decade (it has declined over 50% since the first satellite records). Summertime sea ice will likely cease to exist sometime during the 21st century.

The region is at its warmest in at least 4,000 years. Furthermore, the Arctic-wide melt season has lengthened at a rate of five days per decade (from 1979 to 2013), dominated by a later autumn freeze-up. The IPCC Sixth Assessment Report (2021) stated that Arctic sea ice area will likely drop below 1 million km2 in at least some Septembers before 2050. In September 2020, the US National Snow and Ice Data Center reported that the Arctic sea ice in 2020 had melted to an extent of 3.74 million km2, its second-smallest extent since records began in 1979. Earth lost 28 trillion tonnes of ice between 1994 and 2017, with Arctic sea ice accounting for 7.6 trillion tonnes of this loss. The rate of ice loss has risen by 57% since the 1990s.

Greenland ice sheet

2023 projections of how much the Greenland ice sheet may shrink from its present extent by the year 2300 under the worst possible climate change scenario (upper half) and of how much faster its remaining ice will be flowing in that case (lower half)

The Greenland ice sheet is an ice sheet which forms the second largest body of ice in the world. It is an average of 1.67 km (1.0 mi) thick and over 3 km (1.9 mi) thick at its maximum. It is almost 2,900 kilometres (1,800 mi) long in a north–south direction, with a maximum width of 1,100 kilometres (680 mi) at a latitude of 77°N, near its northern edge. The ice sheet covers 1,710,000 square kilometres (660,000 sq mi), around 80% of the surface of Greenland, or about 12% of the area of the Antarctic ice sheet. The term 'Greenland ice sheet' is often shortened to GIS or GrIS in scientific literature.

Greenland has had major glaciers and ice caps for at least 18 million years, but a single ice sheet first covered most of the island some 2.6 million years ago. Since then, it has both grown and contracted significantly. The oldest known ice on Greenland is about 1 million years old. Due to anthropogenic greenhouse gas emissions, the ice sheet is now the warmest it has been in the past 1000 years, and is losing ice at the fastest rate in at least the past 12,000 years.

Every summer, parts of the surface melt and ice cliffs calve into the sea. Normally the ice sheet would be replenished by winter snowfall, but due to global warming the ice sheet is melting two to five times faster than before 1850, and snowfall has not kept up since 1996. If the Paris Agreement goal of staying below 2 °C (3.6 °F) is achieved, melting of Greenland ice alone would still add around 6 cm (2+12 in) to global sea level rise by the end of the century. If there are no reductions in emissions, melting would add around 13 cm (5 in) by 2100, with a worst-case of about 33 cm (13 in). For comparison, melting has so far contributed 1.4 cm (12 in) since 1972, while sea level rise from all sources was 15–25 cm (6–10 in) between 1901 and 2018.

Lakes

A January 2025 study published in the Proceedings of the National Academy of Sciences reported an "abrupt, coherent, climate-driven transformation" from "blue" (more transparent) to "brown" (less transparent) states of lakes in Greenland after a season of both record heat and rainfall drove a state change in these systems. This change was said to alter "numerous physical, chemical, and biological lake features", and the state changes were said to be unprecedented.

Biological environment

Impacts on Arctic flora

Western Hemisphere Arctic Vegetation Index Trend
Eastern Hemisphere Vegetation Index Trend

Climate change is expected to have a strong effect on the Arctic's flora, some of which is already being seen. NASA and NOAA have continuously monitored Arctic vegetation with satellite instruments such as Moderate Resolution Imaging Spectroradiometer (MODIS) and Advanced very-high-resolution radiometer (AVHRR). Their data allows scientists to calculate so-called "Arctic greening" and "Arctic browning". From 1985 to 2016, greening has occurred in 37.3% of all sites sampled in the tundra, whereas browning was observed only in 4.7% of the sites - typically the ones that were still experiencing cooling and drying, as opposed to warming and wettening for the rest.

This expansion of vegetation in the Arctic is not equivalent across types of vegetation. A major trend has been from shrub-type plants taking over areas previously dominated by moss and lichens. This change contributes to the consideration that the tundra biome is currently experiencing the most rapid change of any terrestrial biomes on the planet. The direct impact on mosses and lichens is unclear as there exist very few studies at species level, but climate change is more likely to cause increased fluctuation and more frequent extreme events. While shrubs may increase in range and biomass, warming may also cause a decline in cushion plants such as moss campion, and since cushion plants act as facilitator species across trophic levels and fill important ecological niches in several environments, this could cause cascading effects in these ecosystems that could severely affect the way in which they function and are structured.

The expansion of these shrubs can also have strong effects on other important ecological dynamics, such as the albedo effect. These shrubs change the winter surface of the tundra from undisturbed, uniform snow to mixed surface with protruding branches disrupting the snow cover, this type of snow cover has a lower albedo effect, with reductions of up to 55%, which contributes to a positive feedback loop on regional and global climate warming. This reduction of the albedo effect means that more radiation is absorbed by plants, and thus, surface temperatures increase, which could disrupt current surface-atmosphere energy exchanges and affect thermal regimes of permafrost. Carbon cycling is also being affected by these changes in vegetation, as parts of the tundra increase their shrub cover, they behave more like boreal forests in terms of carbon cycling. This is speeding up the carbon cycle, as warmer temperatures lead to increased permafrost thawing and carbon release, but also carbon capturing from plants that have increased growth. It is not certain whether this balance will go in one direction or the other, but studies have found that it is more likely that this will eventually lead to increased CO2 in the atmosphere.

However, boreal forests, particularly those in North America, showed a different response to warming. Many boreal forests greened, but the trend was not as strong as it was for tundra of the circumpolar Arctic, mostly characterized by shrub expansion and increased growth. In North America, some boreal forests actually experienced browning over the study period. Droughts, increased forest fire activity, animal behavior, industrial pollution, and a number of other factors may have contributed to browning.

Impacts on terrestrial fauna

Projected change in polar bear habitat from 2001–2010 to 2041–2050

Arctic warming negatively affects the foraging and breeding ecology of native Arctic mammals, such as Arctic foxes or Arctic reindeer. In July 2019, 200 Svalbard reindeer were found starved to death apparently due to low precipitation related to climate change. This was only one episode in the long-term decline of the species. United States Geological Survey research suggests that the shrinkage of Arctic sea ice would eventually extirpate polar bears from Alaska, but leave some of their habitat in the Canadian Arctic Archipelago and areas off the northern Greenland coast.

As the pure Arctic climate is gradually replaced by the subarctic climate, animals adapted to those conditions spread to the north. For instance, beavers have been actively colonizing Arctic regions, and as they create dams, they flood areas which used to be permafrost, contributing to its thaw and methane emissions from it. These colonizing species can outright replace native species, and they may also interbreed with their southern relations, like in the case of the Grizzly–polar bear hybrid. This usually has the effect of reducing the genetic diversity of the genus. Infectious diseases, such as brucellosis or phocine distemper virus, may spread to populations previously separated by the cold, or, in case of the marine mammals, the sea ice.

Marine ecosystems

The observed increase in phytoplankton biomass in the Arctic since 1998

The reduction of sea ice has brought more sunlight to the phytoplankton and increased the annual marine primary production in the Arctic by over 30% between 1998 and 2020. As the result, the Arctic Ocean became a stronger carbon sink over this period; yet, it still accounts for only 5% to 14% of the total ocean carbon sink, although it is expected to play a larger role in the future. By 2100, phytoplankton biomass in the Arctic Ocean is generally expected to increase by ~20% relative to 2000 under the low-emission scenario, and by 30-40% under the high-emission scenario.

Atlantic cod have been able to move deeper into the Arctic due to the warming waters, while the Polar cod and local marine mammals have been losing habitat. Many copepod species appear to be declining, which is also likely to reduce the numbers of fish which prey on them, such as walleye pollock or the arrowtooth flounder. This also affects Arctic shorebirds. For instance, around 9000 puffins and other shorebirds in Alaska died of starvation in 2016, because too many fish have moved to the north. While the shorebirds also appear to nest more successfully due to the observed warming, this benefit may be more than offset by phenological mismatch between shorebirds' and other species' life cycles. Marine mammals such as ringed seals and walruses are also being negatively affected by the warming.

Greenhouse gas emissions from the Arctic

In 2024, the Arctic has transformed from a carbon sink to a carbon source due to the impacts of climate change, mainly rising temperatures and wildfires.

Permafrost thaw

Permafrost thaw ponds on Baffin Island

Permafrost is an important component of hydrological systems and ecosystems within the Arctic landscape. In the Northern Hemisphere the terrestrial permafrost domain comprises around 18 million km2. Within this permafrost region, the total soil organic carbon (SOC) stock is estimated to be 1,460-1,600 Pg (where 1 Pg = 1 billion tons), which constitutes double the amount of carbon currently contained in the atmosphere.

In 2023, Woodwell Climate Research Center received a $5 million grant and fellowship from Google.org, the philanthropic arm of Google, to develop an open-access resource that will use satellite data and artificial intelligence in order to track Arctic permafrost thaw in near real-time.

As recent warming deepens the active layer subject to permafrost thaw, this exposes formerly stored carbon to biogenic processes which facilitate its entrance into the atmosphere as carbon dioxide and methane. Because carbon emissions from permafrost thaw contribute to the same warming which facilitates the thaw, it is a well-known example of a positive climate change feedback. Permafrost thaw is sometimes included as one of the major tipping points in the climate system due to the exhibition of local thresholds and its effective irreversibility. However, while there are self-perpetuating processes that apply on the local or regional scale, it is debated as to whether it meets the strict definition of a global tipping point as in aggregate permafrost thaw is gradual with warming.

In the northern circumpolar region, permafrost contains organic matter equivalent to 1400–1650 billion tons of pure carbon, which was built up over thousands of years. This amount equals almost half of all organic material in all soils, and it is about twice the carbon content of the atmosphere, or around four times larger than the human emissions of carbon between the start of the Industrial Revolution and 2011. Further, most of this carbon (~1,035 billion tons) is stored in what is defined as the near-surface permafrost, no deeper than 3 metres (9.8 ft) below the surface. However, only a fraction of this stored carbon is expected to enter the atmosphere. In general, the volume of permafrost in the upper 3 m of ground is expected to decrease by about 25% per 1 °C (1.8 °F) of global warming, yet even under the RCP8.5 scenario associated with over 4 °C (7.2 °F) of global warming by the end of the 21st century, about 5% to 15% of permafrost carbon is expected to be lost "over decades and centuries".
Nine probable scenarios of greenhouse gas emissions from permafrost thaw during the 21st century, which show a limited, moderate and intense CO2 and CH4 emission response to low, medium and high-emission Representative Concentration Pathways. The vertical bar uses emissions of selected large countries as a comparison: the right-hand side of the scale shows their cumulative emissions since the start of the Industrial Revolution, while the left-hand side shows each country's cumulative emissions for the rest of the 21st century if they remained unchanged from their 2019 levels.

Altogether, it is expected that cumulative greenhouse gas emissions from permafrost thaw will be smaller than the cumulative anthropogenic emissions, yet still substantial on a global scale, with some experts comparing them to emissions caused by deforestation. The IPCC Sixth Assessment Report estimates that carbon dioxide and methane released from permafrost could amount to the equivalent of 14–175 billion tonnes of carbon dioxide per 1 °C (1.8 °F) of warming. For comparison, by 2019, annual anthropogenic emissions of carbon dioxide alone stood around 40 billion tonnes. A major review published in the year 2022 concluded that if the goal of preventing 2 °C (3.6 °F) of warming was realized, then the average annual permafrost emissions throughout the 21st century would be equivalent to the year 2019 annual emissions of Russia. Under RCP4.5, a scenario considered close to the current trajectory and where the warming stays slightly below 3 °C (5.4 °F), annual permafrost emissions would be comparable to year 2019 emissions of Western Europe or the United States, while under the scenario of high global warming and worst-case permafrost feedback response, they would approach year 2019 emissions of China.

Fewer studies have attempted to describe the impact directly in terms of warming. A 2018 paper estimated that if global warming was limited to 2 °C (3.6 °F), gradual permafrost thaw would add around 0.09 °C (0.16 °F) to global temperatures by 2100, while a 2022 review concluded that every 1 °C (1.8 °F) of global warming would cause 0.04 °C (0.072 °F) and 0.11 °C (0.20 °F) from abrupt thaw by the year 2100 and 2300. Around 4 °C (7.2 °F) of global warming, abrupt (around 50 years) and widespread collapse of permafrost areas could occur, resulting in an additional warming of 0.2–0.4 °C (0.36–0.72 °F).

Black carbon

Black carbon emissions from fire and human activities around the Arctic in the year 2012, as measured from a research station in Abisko

Black carbon deposits (from the combustion of heavy fuel oil (HFO) of Arctic shipping) absorb solar radiation in the atmosphere and strongly reduce the albedo when deposited on snow and ice, thus accelerating the effect of the melting of snow and sea ice. A 2013 study quantified that gas flaring at petroleum extraction sites contributed over 40% of the black carbon deposited in the Arctic 2019 research attributed the majority (56%) of Arctic surface black carbon to emissions from Russia, followed by European emissions, and Asia also being a large source. In 2015, research suggested that reducing black carbon emissions and short-lived greenhouse gases by roughly 60 percent by 2050 could cool the Arctic up to 0.2 °C. However, a 2019 study indicates that "Black carbon emissions will continuously rise due to increased shipping activities", specifically fishing vessels.

The number of wildfires in the Arctic Circle has increased. In 2020, Arctic wildfire CO2 emissions broke a new record, peaking at 244 megatonnes of carbon dioxide emitted.  This is due to the burning of peatlands, carbon-rich soils that originate from the accumulation of waterlogged plants which are mostly found at Arctic latitudes. These peatlands are becoming more likely to burn as temperatures increase, but their own burning and releasing of CO2 contributes to their own likelihood of burning in a positive feedback loop. The smoke from wildfires defined as "brown carbon" also increases arctic warming, with its warming effect is around 30% that of black carbon. As wildfires increases with warming this creates a positive feedback loop.

Methane clathrate deposits

Methane clathrate is released as gas into the surrounding water column or soils when ambient temperature increases.
The clathrate gun hypothesis is a proposed explanation for the periods of rapid warming during the Quaternary. The hypothesis is that changes in fluxes in upper intermediate waters in the ocean caused temperature fluctuations that alternately accumulated and occasionally released methane clathrate on upper continental slopes. This would have had an immediate impact on the global temperature, as methane is a much more powerful greenhouse gas than carbon dioxide. Despite its atmospheric lifetime of around 12 years, methane's global warming potential is 72 times greater than that of carbon dioxide over 20 years, and 25 times over 100 years (33 when accounting for aerosol interactions). It is further proposed that these warming events caused the Bond cycles and individual interstadial events, such as the Dansgaard–Oeschger interstadials.
In 2018, a perspective piece devoted to tipping points in the climate system suggested that the climate change contribution from methane hydrates would be "negligible" by the end of the century, but could amount to 0.4–0.5 °C (0.72–0.90 °F) on the millennial timescales. In 2021, the IPCC Sixth Assessment Report no longer included methane hydrates in the list of potential tipping points, and says that "it is very unlikely that CH4 emissions from clathrates will substantially warm the climate system over the next few centuries." The report had also linked terrestrial hydrate deposits to gas emission craters discovered in the Yamal Peninsula in Siberia, Russia beginning in July 2014, but noted that since terrestrial gas hydrates predominantly form at a depth below 200 meters, a substantial response within the next few centuries can be ruled out. Likewise, a 2022 assessment of tipping points described methane hydrates as a "threshold-free feedback" rather than a tipping point.

Effects on other parts of the world

On ocean circulation

Modelled 21st century warming under the "intermediate" global warming scenario (top). The potential collapse of the subpolar gyre in this scenario (middle). The collapse of the entire Atlantic Meriditional Overturning Circulation (bottom).
The Atlantic meridional overturning circulation (AMOC) is the main ocean current system in the Atlantic Ocean. It is a component of Earth's ocean circulation system and plays an important role in the climate system. The AMOC includes Atlantic currents at the surface and at great depths that are driven by changes in weather, temperature and salinity. Those currents comprise half of the global thermohaline circulation that includes the flow of major ocean currents, the other half being the Southern Ocean overturning circulation.
 
The AMOC has not always existed; for much of Earth's history, overturning circulation in the northern hemisphere occurred in the North Pacific. Paleoclimate evidence shows the shift of overturning circulation from the Pacific to the Atlantic occurred 34 million years ago at the Eocene-Oligocene transition, when the Arctic-Atlantic gateway had closed. This closure fundamentally changed the thermohaline circulation structure; some researchers have suggested climate change may eventually reverse this shift and re-establish the Pacific circulation after the AMOC shuts down. Climate change affects the AMOC by making surface water warmer as a consequence of Earth's energy imbalance and by making surface water less saline due to the addition of large quantities of fresh water from melting ice – mainly from Greenland – and through increasing precipitation over the North Atlantic. Both of these causes would increase the difference between the surface and deep layers, thus making the upwelling and downwelling that drives the circulation more difficult.
 
Severe weakening of the AMOC may lead to a collapse of the circulation, which would not be easily reversible and thus constitutes one of the tipping points in the climate system. A collapse would substantially lower the average temperature and amount of rain and snowfall in Europe. It may also raise the frequency of extreme weather events and have other severe effects.

In 2021, the IPCC Sixth Assessment Report again said the AMOC is "very likely" to decline within the 21st century and that there was a "high confidence" changes to it would be reversible within centuries if warming was reversed. Unlike the Fifth Assessment Report, it had only "medium confidence" rather than "high confidence" in the AMOC avoiding a collapse before the end of the 21st century. This reduction in confidence was likely influenced by several review studies that draw attention to the circulation stability bias within general circulation models, and simplified ocean-modelling studies suggesting the AMOC may be more vulnerable to abrupt change than larger-scale models suggest.

The synthesis report of the IPCC Sixth Assessment Report summarized the scientific consensus as follows: "The Atlantic Meridional Overturning Circulation is very likely to weaken over the 21st century for all considered scenarios (high confidence), however an abrupt collapse is not expected before 2100 (medium confidence). If such a low probability event were to occur, it would very likely cause abrupt shifts in regional weather patterns and water cycle, such as a southward shift in the tropical rain belt, and large impacts on ecosystems and human activities."

On mid-latitude weather

Since the early 2000s, climate models have consistently identified that global warming will gradually push jet streams poleward. In 2008, this was confirmed by observational evidence, which proved that from 1979 to 2001, the northern jet stream moved northward at an average rate of 2.01 kilometres (1.25 mi) per year, with a similar trend in the southern hemisphere jet stream. Climate scientists have hypothesized that the jet stream will also gradually weaken as a result of global warming. Trends such as Arctic sea ice decline, reduced snow cover, evapotranspiration patterns, and other weather anomalies have caused the Arctic to heat up faster than other parts of the globe, in what is known as the Arctic amplification. In 2021–2022, it was found that since 1979, the warming within the Arctic Circle has been nearly four times faster than the global average, and some hotspots in the Barents Sea area warmed up to seven times faster than the global average. While the Arctic remains one of the coldest places on Earth today, the temperature gradient between it and the warmer parts of the globe will continue to diminish with every decade of global warming as the result of this amplification. If this gradient has a strong influence on the jet stream, then it will eventually become weaker and more variable in its course, which would allow more cold air from the polar vortex to leak mid-latitudes and slow the progression of Rossby waves, leading to more persistent and more extreme weather.

The hypothesis above is closely associated with Jennifer Francis, who had first proposed it in a 2012 paper co-authored by Stephen J. Vavrus. While some paleoclimate reconstructions have suggested that the polar vortex becomes more variable and causes more unstable weather during periods of warming back in 1997, this was contradicted by climate modelling, with PMIP2 simulations finding in 2010 that the Arctic Oscillation (AO) was much weaker and more negative during the Last Glacial Maximum, and suggesting that warmer periods have stronger positive phase AO, and thus less frequent leaks of the polar vortex air. However, a 2012 review in the Journal of the Atmospheric Sciences noted that "there [has been] a significant change in the vortex mean state over the twenty-first century, resulting in a weaker, more disturbed vortex.", which contradicted the modelling results but fit the Francis-Vavrus hypothesis. Additionally, a 2013 study noted that the then-current CMIP5 tended to strongly underestimate winter blocking trends, and other 2012 research had suggested a connection between declining Arctic sea ice and heavy snowfall during midlatitude winters.

However, because the specific observations are considered short-term observations, there is considerable uncertainty in the conclusions. Climatology observations require several decades to definitively distinguish various forms of natural variability from climate trends. This point was stressed by reviews in 2013 and in 2017. A study in 2014 concluded that Arctic amplification significantly decreased cold-season temperature variability over the northern hemisphere in recent decades. Cold Arctic air intrudes into the warmer lower latitudes more rapidly today during autumn and winter, a trend projected to continue in the future except during summer, thus calling into question whether winters will bring more cold extremes. A 2019 analysis of a data set collected from 35 182 weather stations worldwide, including 9116 whose records go beyond 50 years, found a sharp decrease in northern midlatitude cold waves since the 1980s.

Moreover, a range of long-term observational data collected during the 2010s and published in 2020 suggests that the intensification of Arctic amplification since the early 2010s was not linked to significant changes on mid-latitude atmospheric patterns. State-of-the-art modelling research of PAMIP (Polar Amplification Model Intercomparison Project) improved upon the 2010 findings of PMIP2; it found that sea ice decline would weaken the jet stream and increase the probability of atmospheric blocking, but the connection was very minor, and typically insignificant next to interannual variability. In 2022, a follow-up study found that while the PAMIP average had likely underestimated the weakening caused by sea ice decline by 1.2 to 3 times, even the corrected connection still amounts to only 10% of the jet stream's natural variability.

Impacts on people

Territorial claims

Growing evidence that global warming is shrinking polar ice has added to the urgency of several nations' Arctic territorial claims in hopes of establishing resource development and new shipping lanes, in addition to protecting sovereign rights.

As ice sea coverage decreases more and more, year on year, Arctic countries (Russia, Canada, Finland, Iceland, Norway, Sweden, the United States and Denmark representing Greenland) are making moves on the geopolitical stage to ensure access to potential new shipping lanes, oil and gas reserves, leading to overlapping claims across the region.

There is more activity in terms of maritime boundaries between countries, where overlapping claims for internal waters, territorial seas and particularly Exclusive Economic Zones (EEZs) can cause frictions between nations. Currently, official maritime borders have an unclaimed triangle of international waters lying between them, that is at the centerpoint of international disputes.

This unclaimed land can be obtainable by submitting a claim to the United Nations Convention on the Law of the Sea, these claims can be based on geological evidence that continental shelves extend beyond their current maritime borders and into international waters.

Some overlapping claims are still pending resolution by international bodies, such as a large portion containing the north pole that is both claimed by Denmark and Russia, with some parts of it also contested by Canada. Another example is that of the Northwest Passage, globally recognized as international waters, but technically in Canadian waters. This has led to Canada wanting to limit the number of ships that can go through for environmental reasons but the United States disputes that they have the authority to do so, favouring unlimited passage of vessels.

The Transpolar Sea Route is a future Arctic shipping lane running from the Atlantic Ocean to the Pacific Ocean across the center of the Arctic Ocean. The route is also sometimes called Trans-Arctic Route. In contrast to the Northeast Passage (including the Northern Sea Route) and the North-West Passage it largely avoids the territorial waters of Arctic states and lies in international high seas.

Governments and private industry have shown a growing interest in the Arctic. Major new shipping lanes are opening up: the northern sea route had 34 passages in 2011 while the Northwest Passage had 22 traverses, more than any time in history. Shipping companies may benefit from the shortened distance of these northern routes. Access to natural resources will increase, including valuable minerals and offshore oil and gas. Finding and controlling these resources will be difficult with the continually moving ice. Tourism may also increase as less sea ice will improve safety and accessibility to the Arctic.

The melting of Arctic ice caps is likely to increase traffic in and the commercial viability of the Northern Sea Route. One study, for instance, projects, "remarkable shifts in trade flows between Asia and Europe, diversion of trade within Europe, heavy shipping traffic in the Arctic and a substantial drop in Suez traffic. Projected shifts in trade also imply substantial pressure on an already threatened Arctic ecosystem."

Infrastructure

Map of likely risk to infrastructure from permafrost thaw expected to occur by 2050.

As of 2021, there are 1162 settlements located directly atop the Arctic permafrost, which host an estimated 5 million people. By 2050, permafrost layer below 42% of these settlements is expected to thaw, affecting all their inhabitants (currently 3.3 million people). Consequently, a wide range of infrastructure in permafrost areas is threatened by the thaw. By 2050, it's estimated that nearly 70% of global infrastructure located in the permafrost areas would be at high risk of permafrost thaw, including 30–50% of "critical" infrastructure. The associated costs could reach tens of billions of dollars by the second half of the century. Reducing greenhouse gas emissions in line with the Paris Agreement is projected to stabilize the risk after mid-century; otherwise, it'll continue to worsen.

In Alaska alone, damages to infrastructure by the end of the century would amount to $4.6 billion (at 2015 dollar value) if RCP8.5, the high-emission climate change scenario, were realized. Over half stems from the damage to buildings ($2.8 billion), but there's also damage to roads ($700 million), railroads ($620 million), airports ($360 million) and pipelines ($170 million). Similar estimates were done for RCP4.5, a less intense scenario which leads to around 2.5 °C (4.5 °F) by 2100, a level of warming similar to the current projections. In that case, total damages from permafrost thaw are reduced to $3 billion, while damages to roads and railroads are lessened by approximately two-thirds (from $700 and $620 million to $190 and $220 million) and damages to pipelines are reduced more than ten-fold, from $170 million to $16 million. Unlike the other costs stemming from climate change in Alaska, such as damages from increased precipitation and flooding, climate change adaptation is not a viable way to reduce damages from permafrost thaw, as it would cost more than the damage incurred under either scenario.

In Canada, Northwest Territories have a population of only 45,000 people in 33 communities, yet permafrost thaw is expected to cost them $1.3 billion over 75 years, or around $51 million a year. In 2006, the cost of adapting Inuvialuit homes to permafrost thaw was estimated at $208/m2 if they were built at pile foundations, and $1,000/m2 if they didn't. At the time, the average area of a residential building in the territory was around 100 m2. Thaw-induced damage is also unlikely to be covered by home insurance, and to address this reality, territorial government currently funds Contributing Assistance for Repairs and Enhancements (CARE) and Securing Assistance for Emergencies (SAFE) programs, which provide long- and short-term forgivable loans to help homeowners adapt. It is possible that in the future, mandatory relocation would instead take place as the cheaper option. However, it would effectively tear the local Inuit away from their ancestral homelands. Right now, their average personal income is only half that of the median NWT resident, meaning that adaptation costs are already disproportionate for them.

By 2022, up to 80% of buildings in some Northern Russia cities had already experienced damage. By 2050, the damage to residential infrastructure may reach $15 billion, while total public infrastructure damages could amount to 132 billion. This includes oil and gas extraction facilities, of which 45% are believed to be at risk.

Toxic pollution

Graphical representation of leaks from various toxic hazards caused by the thaw of formerly stable permafrost.

For much of the 20th century, it was believed that permafrost would "indefinitely" preserve anything buried there, and this made deep permafrost areas popular locations for hazardous waste disposal. In places like Canada's Prudhoe Bay oil field, procedures were developed documenting the "appropriate" way to inject waste beneath the permafrost. This means that as of 2023, there are ~4500 industrial facilities in the Arctic permafrost areas which either actively process or store hazardous chemicals. Additionally, there are between 13,000 and 20,000 sites which have been heavily contaminated, 70% of them in Russia, and their pollution is currently trapped in the permafrost.

About a fifth of both the industrial and the polluted sites (1000 and 2200–4800) are expected to start thawing in the future even if the warming does not increase from its 2020 levels. Only about 3% more sites would start thawing between now and 2050 under the climate change scenario consistent with the Paris Agreement goals, RCP2.6, but by 2100, about 1100 more industrial facilities and 3500 to 5200 contaminated sites are expected to start thawing even then. Under the very high emission scenario RCP8.5, 46% of industrial and contaminated sites would start thawing by 2050, and virtually all of them would be affected by the thaw by 2100.

Organochlorines and other persistent organic pollutants are of a particular concern, due to their potential to repeatedly reach local communities after their re-release through biomagnification in fish. At worst, future generations born in the Arctic would enter life with weakened immune systems due to pollutants accumulating across generations.

Distribution of toxic substances currently located at various permafrost sites in Alaska, by sector. The number of fish skeletons represents the toxicity of each substance.

A notable example of pollution risks associated with permafrost was the 2020 Norilsk oil spill, caused by the collapse of diesel fuel storage tank at Norilsk-Taimyr Energy's thermal power plant No. 3. It spilled 6,000 tonnes of fuel into the land and 15,000 into the water, polluting Ambarnaya, Daldykan and many smaller rivers on Taimyr Peninsula, even reaching lake Pyasino, which is a crucial water source in the area. State of emergency at the federal level was declared. The event has been described as the second-largest oil spill in modern Russian history.

Another issue associated with permafrost thaw is the release of natural mercury deposits. An estimated 800,000 tons of mercury are frozen in the permafrost soil. According to observations, around 70% of it is simply taken up by vegetation after the thaw. However, if the warming continues under RCP8.5, then permafrost emissions of mercury into the atmosphere would match the current global emissions from all human activities by 2200. Mercury-rich soils also pose a much greater threat to humans and the environment if they thaw near rivers. Under RCP8.5, enough mercury will enter the Yukon River basin by 2050 to make its fish unsafe to eat under the EPA guidelines. By 2100, mercury concentrations in the river will double. In contrast, even if mitigation is limited to RCP4.5 scenario, mercury levels will increase by about 14% by 2100, and will not breach the EPA guidelines even by 2300.
The impact of meltwater from Greenland goes beyond nutrient transport. For instance, meltwater also contains dissolved organic carbon, which comes from the microbial activity on the ice sheet's surface, and, to a lesser extent, from the remnants of ancient soil and vegetation beneath the ice. There is about 0.5-27 billion tonnes of pure carbon underneath the entire ice sheet, and much less within it. This is much less than the 1400–1650 billion tonnes contained within the Arctic permafrost, or the annual anthropogenic emissions of around 40 billion tonnes of CO2.) Yet, the release of this carbon through meltwater can still act as a climate change feedback if it increases overall carbon dioxide emissions.

Impacts on indigenous peoples

As climate change speeds up, it is having more and more of a direct impact on societies around the world. This is particularly true of people that live in the Arctic, where increases in temperature are occurring at faster rates than at other latitudes in the world, and where traditional ways of living, deeply connected with the natural arctic environment are at particular risk of environmental disruption caused by these changes.

The warming of the atmosphere and ecological changes that come alongside it presents challenges to local communities such as the Inuit. Hunting, which is a major way of survival for some small communities, will be changed with increasing temperatures. The reduction of sea ice will cause certain species populations to decline or even become extinct. Inuit communities are deeply reliant on seal hunting, which is dependent on sea ice flats, where seals are hunted.

Unsuspected changes in river and snow conditions will cause herds of animals, including reindeer, to change migration patterns, calving grounds, and forage availability. In good years, some communities are fully employed by the commercial harvest of certain animals. The harvest of different animals fluctuates each year and with the rise of temperatures it is likely to continue changing and creating issues for Inuit hunters, as unpredictability and disruption of ecological cycles further complicate life in these communities, which already face significant problems, such as Inuit communities being the poorest and most unemployed of North America.

Other forms of transportation in the Arctic have seen negative impacts from the current warming, with some transportation routes and pipelines on land being disrupted by the melting of ice. Many Arctic communities rely on frozen roadways to transport supplies and travel from area to area. The changing landscape and unpredictability of weather is creating new challenges in the Arctic. Researchers have documented historical and current trails created by the Inuit in the Pan Inuit Trails Atlas, finding that the change in sea ice formation and breakup has resulted in changes to the routes of trails created by the Inuit.

Adaptation

Research

Individual countries within the Arctic zone, Canada, Denmark (Greenland), Finland, Iceland, Norway, Russia, Sweden, and the United States (Alaska) conduct independent research through a variety of organizations and agencies, public and private, such as Russia's Arctic and Antarctic Research Institute. Countries who do not have Arctic claims, but are close neighbors, conduct Arctic research as well, such as the Chinese Arctic and Antarctic Administration (CAA). The United States's National Oceanic and Atmospheric Administration (NOAA) produces an Arctic Report Card annually, containing peer-reviewed information on recent observations of environmental conditions in the Arctic relative to historical records. International cooperative research between nations has also become increasingly important:

The 2021 Arctic Monitoring and Assessment Programme (AMAP) report by an international team of more than 60 experts, scientists, and indigenous knowledge keepers from Arctic communities, was prepared from 2019 to 2021. It is a follow-up report of the 2017 assessment, "Snow, Water, Ice and Permafrost in the Arctic" (SWIPA). The 2021 IPCC AR6 WG1 Technical Report confirmed that "[o]bserved and projected warming" were ""strongest in the Arctic". According to an 11 August 2022 article published in Nature, there have been numerous reports that the Arctic is warming from twice to three times as fast as the global average since 1979, but the co-authors cautioned that the recent report of the "four-fold Arctic warming ratio" was potentially an "extremely unlikely event". The annual mean Arctic Amplification (AA) index had "reached values exceeding four" from c. 2002 through 2022, according to a July 2022 article in Geophysical Research Letters.

The 14 December 2021 16th Arctic Report Card produced by the United States's National Oceanic and Atmospheric Administration (NOAA) and released annually, examined the "interconnected physical, ecological and human components" of the circumpolar Arctic.[218][47] The report said that the 12 months between October 2020 and September 2021 were the "seventh warmest over Arctic land since the record began in 1900".[218] The 2017 report said that the melting ice in the warming Arctic was unprecedented in the past 1500 years.[208][209] NOAA's State of the Arctic Reports, starting in 2006, updates some of the records of the original 2004 and 2005 Arctic Climate Impact Assessment (ACIA) reports by the intergovernmental Arctic Council and the non-governmental International Arctic Science Committee.[219]

A 2022 United Nations Environment Programme (UNEP) report "Spreading Like Wildfire: The Rising Threat Of Extraordinary Landscape Fires" said that smoke from wildfires around the world created a positive feedback loop that is a contributing factor to Arctic melting. The 2020 Siberian heatwave was "associated with extensive burning in the Arctic Circle". Report authors said that this extreme heat event was the first to demonstrate that it would have been "almost impossible" without anthropogenic emissions and climate change.

Ozone depletion

From Wikipedia, the free encyclopedia
Global monthly average total ozone amount

Ozone depletion consists of two related events observed since the late 1970s: a lowered total amount of ozone in Earth's upper atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone layer) around Earth's polar regions. The latter phenomenon is referred to as the ozone hole. There are also springtime polar tropospheric ozone depletion events in addition to these stratospheric events.

The main causes of ozone depletion and the ozone hole are manufactured chemicals, especially manufactured halocarbon refrigerants, solvents, propellants, and foam-blowing agents (chlorofluorocarbons (CFCs), HCFCs, halons), referred to as ozone-depleting substances (ODS). These compounds are transported into the stratosphere by turbulent mixing after being emitted from the surface, mixing much faster than the molecules can settle. Once in the stratosphere, they release atoms from the halogen group through photodissociation, which catalyze the breakdown of ozone (O3) into oxygen (O2). Both types of ozone depletion were observed to increase as emissions of halocarbons increased.

Ozone depletion and the ozone hole have generated worldwide concern over increased cancer risks and other negative effects. The ozone layer prevents harmful wavelengths of ultraviolet (UVB) light from passing through the Earth's atmosphere. These wavelengths cause skin cancer, sunburn, permanent blindness, and cataracts, which were projected to increase dramatically as a result of thinning ozone, as well as harming plants and animals. These concerns led to the adoption of the Montreal Protocol in 1987, which bans the production of CFCs, halons, and other ozone-depleting chemicals. Over time, scientists have developed new refrigerants with lower global warming potential (GWP) to replace older ones. For example, in new automobiles, R-1234yf systems are now common, being chosen over refrigerants with much higher GWP such as R-134a and R-12.

The ban came into effect in 1989. Ozone levels stabilized by the mid-1990s and began to recover in the 2000s, as the shifting of the jet stream in the southern hemisphere towards the south pole has stopped and might even be reversing. Recovery was projected to continue over the next century, with the ozone hole expected to reach pre-1980 levels by around 2075. In 2019, NASA reported that the ozone hole was the smallest ever since it was first discovered in 1982. The UN now projects that under the current regulations the ozone layer will completely regenerate by 2045. The Montreal Protocol is considered the most successful international environmental agreement to date.

Ozone cycle overview

The ozone cycle

Three forms (or allotropes) of oxygen are involved in the ozone-oxygen cycle: oxygen atoms (O or atomic oxygen), oxygen gas (O
2
or diatomic oxygen), and ozone gas (O
3
or triatomic oxygen). Ozone is formed in the stratosphere when oxygen gas molecules photodissociate after absorbing UVC photons. This converts a single O
2
into two atomic oxygen radicals. The atomic oxygen radicals then combine with separate O
2
molecules to create two O
3
molecules. These ozone molecules absorb UVB light, following which ozone splits into a molecule of O
2
and an oxygen atom. The oxygen atom then joins up with an oxygen molecule to regenerate ozone. This is a continuing process that terminates when an oxygen atom recombines with an ozone molecule to make two O
2
molecules. It is worth noting that ozone is the only atmospheric gas that absorbs UVB light.

O + O
3
→ 2 O
2
The distribution of atmospheric ozone in partial pressure as a function of altitude
Levels of ozone at various altitudes (DU/km) and absorption of different bands of ultraviolet radiation: In essence, all UVC is absorbed by diatomic oxygen (100–200 nm) or by ozone (triatomic oxygen) (200–280 nm) in the atmosphere. The ozone layer also absorbs most UVB. In contrast, UVA is hardly absorbed and most of it reaches the ground. Consequently UVA makes up almost all the UV light that penetrates the Earth's atmosphere.

The total amount of ozone in the stratosphere is determined by a balance between photochemical production and recombination.

Ozone can be destroyed by a number of free radical catalysts; the most important are the hydroxyl radical (OH·), nitric oxide radical (NO·), chlorine radical (Cl·) and bromine radical (Br·). The dot is a notation to indicate that each species has an unpaired electron and is thus extremely reactive. The effectiveness of different halogens and pseudohalogens as catalysts for ozone destruction varies, in part due to differing routes to regenerate the original radical after reacting with ozone or dioxygen.

While all of the relevant radicals have both natural and man-made sources, human activity has impacted some more than others. As of 2020, most of the OH· and NO· in the stratosphere is naturally occurring, but human activity has drastically increased the levels of chlorine and bromine. These elements are found in stable organic compounds, especially chlorofluorocarbons, which can travel to the stratosphere without being destroyed in the troposphere due to their low reactivity. Once in the stratosphere, the Cl and Br atoms are released from the parent compounds by the action of ultraviolet light, e.g.

CFCl
3
+ electromagnetic radiation → Cl· + ·CFCl
2

Ozone is a highly reactive molecule that easily reduces to the more stable oxygen form with the assistance of a catalyst. Cl and Br atoms destroy ozone molecules through a variety of catalytic cycles. In the simplest example of such a cycle, a chlorine atom reacts with an ozone molecule (O
3
), taking an oxygen atom to form chlorine monoxide (ClO) and leaving an oxygen molecule (O
2
). The ClO can react with a second molecule of ozone, releasing the chlorine atom and yielding two molecules of oxygen. The chemical shorthand for these gas-phase reactions is:

  • Cl· + O
    3
    → ClO + O
    2

    A chlorine atom removes an oxygen atom from an ozone molecule to make a ClO molecule
  • ClO + O
    3
    → Cl· + 2 O
    2

    This ClO can also remove an oxygen atom from another ozone molecule; the chlorine is free to repeat this two-step cycle

The overall effect is a decrease in the amount of ozone, though the rate of these processes can be decreased by the effects of null cycles. More complicated mechanisms have also been discovered that lead to ozone destruction in the lower stratosphere.

A single chlorine atom would continuously destroy ozone (thus a catalyst) for up to two years (the time scale for transport back down to the troposphere) except for reactions that remove it from this cycle by forming reservoir species such as hydrogen chloride (HCl) and chlorine nitrate (ClONO
2
). Bromine is even more efficient than chlorine at destroying ozone on a per-atom basis, but there is much less bromine in the atmosphere at present. Both chlorine and bromine contribute significantly to overall ozone depletion. Laboratory studies have also shown that fluorine and iodine atoms participate in analogous catalytic cycles. However, fluorine atoms react rapidly with water vapour, methane and hydrogen to form strongly bound hydrogen fluoride (HF) in the Earth's stratosphere, while organic molecules containing iodine react so rapidly in the lower atmosphere that they do not reach the stratosphere in significant quantities.

A single chlorine atom is able to react with an average of 100,000 ozone molecules before it is removed from the catalytic cycle. This fact plus the amount of chlorine released into the atmosphere yearly by chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) demonstrates the danger of CFCs and HCFCs to the environment.

Observations on ozone layer depletion

Lowest value of ozone measured by TOMS each year in the ozone hole

The ozone hole is usually measured by reduction in the total column ozone above a point on the Earth's surface. This is normally expressed in Dobson units; abbreviated as "DU". The most prominent decrease in ozone has been in the lower stratosphere. Marked decreases in column ozone in the Antarctic spring and early summer compared to the early 1970s and before have been observed using instruments such as the Total Ozone Mapping Spectrometer (TOMS).

Reductions of up to 70 percent in the ozone column observed in the austral (southern hemispheric) spring over Antarctica and first reported in 1985 (Farman et al.) are continuing. Antarctic total column ozone in September and October have continued to be 40–50 percent lower than pre-ozone-hole values since the 1990s. A gradual trend toward "healing" was reported in 2016. In 2017, NASA announced that the ozone hole was the weakest since 1988 because of warm stratospheric conditions. It is expected to recover around 2070.

The amount lost is more variable year-to-year in the Arctic than in the Antarctic. The greatest Arctic declines are in the winter and spring, reaching up to 30 percent when the stratosphere is coldest.

Reactions that take place on polar stratospheric clouds (PSCs) play an important role in enhancing ozone depletion. PSCs form more readily in the extreme cold of the Arctic and Antarctic stratosphere. This is why ozone holes first formed, and are deeper, over Antarctica. Early models failed to take PSCs into account and predicted a gradual global depletion, which is why the sudden Antarctic ozone hole was such a surprise to many scientists.

It is more accurate to speak of ozone depletion in middle latitudes rather than holes. Total column ozone declined below pre-1980 values between 1980 and 1996 for mid-latitudes. In the northern mid-latitudes, it then increased from the minimum value by about two percent from 1996 to 2009 as regulations took effect and the amount of chlorine in the stratosphere decreased. In the Southern Hemisphere's mid-latitudes, total ozone remained constant over that time period. There are no significant trends in the tropics, largely because halogen-containing compounds have not had time to break down and release chlorine and bromine atoms at tropical latitudes.

Large volcanic eruptions have been shown to have substantial albeit uneven ozone-depleting effects, as observed with the 1991 eruption of Mt. Pinatubo in the Philippines.

Ozone depletion also explains much of the observed reduction in stratospheric and upper tropospheric temperatures. The source of the warmth of the stratosphere is the absorption of UV radiation by ozone, hence reduced ozone leads to cooling. Some stratospheric cooling is also predicted from increases in greenhouse gases such as CO
2
and CFCs themselves; however, the ozone-induced cooling appears to be dominant.

Predictions of ozone levels remain difficult, but the precision of models' predictions of observed values and the agreement among different modeling techniques have increased steadily. The World Meteorological Organization Global Ozone Research and Monitoring Project—Report No. 44 is strongly in favor of the Montreal Protocol, but notes that a UNEP 1994 Assessment overestimated ozone loss for the 1994–1997 period.

Compounds in the atmosphere

Chlorofluorocarbons (CFCs) and other halogenated ozone-depleting substances (ODS) are mainly responsible for man-made chemical ozone depletion. The total amount of effective halogens (chlorine and bromine) in the stratosphere can be calculated and are known as the equivalent effective stratospheric chlorine (EESC).

CFCs as refrigerants were invented by Thomas Midgley Jr. in the 1930s. They were used in air conditioning and cooling units, as aerosol spray propellants prior to the 1970s, and in the cleaning processes of delicate electronic equipment. They also occur as by-products of some chemical processes. No significant natural sources have ever been identified for these compounds—their presence in the atmosphere is due almost entirely to human manufacture. As mentioned above, when such ozone-depleting chemicals reach the stratosphere, they are dissociated by ultraviolet light to release chlorine atoms. The chlorine atoms act as a catalyst, and each can break down tens of thousands of ozone molecules before being removed from the stratosphere. Given the longevity of CFC molecules, recovery times are measured in decades. It is calculated that a CFC molecule takes an average of about five to seven years to go from the ground level up to the upper atmosphere, and it can stay there for about a century, destroying up to one hundred thousand ozone molecules during that time.

1,1,1-Trichloro-2,2,2-trifluoroethane, also known as CFC-113a, is one of four man-made chemicals newly discovered in the atmosphere by a team at the University of East Anglia. CFC-113a is the only known CFC whose abundance in the atmosphere is still growing. Its source remains a mystery, but illegal manufacturing is suspected by some. CFC-113a seems to have been accumulating unabated since 1960. Between 2012 and 2017, concentrations of the gas jumped by 40 percent.

A study by an international team of researchers published in Nature found that since 2013 emissions that are predominately from north-eastern China have released large quantities of the banned chemical Chlorofluorocarbon-11 (CFC-11) into the atmosphere. Scientists estimate that without action, these CFC-11 emissions will delay the recovery of the planet's ozone hole by a decade.

Aluminum oxide

Satellites burning up upon re-entry into Earth's atmosphere produce aluminum oxide (Al2O3) nanoparticles that endure in the atmosphere for decades. Estimates for 2022 alone were ~17 metric tons (~30 kg of nanoparticles per ~250 kg satellite). Increasing populations of satellite constellations can eventually lead to significant ozone depletion.

Very short-lived substances (VSLS)

"Very short-lived substances" are a class of ozone-depleting chemicals, allowed by the Montreal Protocol, that degrade in under 6 months. 90% are naturally produced, for example bromine-based chemicals generated by seaweed and phytoplankton, but 10% are manmade, for example dichloromethane.

Computer modeling

Scientists have attributed ozone depletion to the increase of man-made (anthropogenic) halogen compounds from CFCs by combining observational data with computer models. These complex chemistry transport models (e.g. SLIMCAT, CLaMS—Chemical Lagrangian Model of the Stratosphere) work by combining measurements of chemicals and meteorological fields with chemical reaction rate constants. They identify key chemical reactions and transport processes that bring CFC photolysis products into contact with ozone.

Ozone hole and its causes

Ozone hole in North America during 1984 (abnormally warm, reducing ozone depletion) and 1997 (abnormally cold, resulting in increased seasonal depletion). Source: NASA

The Antarctic ozone hole is an area of the Antarctic stratosphere in which the recent ozone levels have dropped to as low as 33 percent of their pre-1975 values. The ozone hole occurs during the Antarctic spring, from September to early December, as strong westerly winds start to circulate around the continent and create an atmospheric container. Within this polar vortex, over 50 percent of the lower stratospheric ozone is destroyed during the Antarctic spring.

As explained above, the primary cause of ozone depletion is the presence of chlorine-containing source gases (primarily CFCs and related halocarbons). In the presence of UV light, these gases dissociate, releasing chlorine atoms, which then go on to catalyze ozone destruction. The Cl-catalyzed ozone depletion can take place in the gas phase, but it is substantially enhanced in the presence of polar stratospheric clouds (PSCs).

These polar stratospheric clouds form during winter, in the extreme cold. Polar winters are dark, consisting of three months without solar radiation (sunlight). The lack of sunlight contributes to a decrease in temperature and the polar vortex traps and chills the air. Temperatures are around or below −80 °C. These low temperatures form cloud particles. There are three types of PSC clouds—nitric acid trihydrate clouds, slowly cooling water-ice clouds, and rapid cooling water-ice (nacreous) clouds—provide surfaces for chemical reactions whose products will, in the spring lead to ozone destruction.

The photochemical processes involved are complex but well understood. The key observation is that, ordinarily, most of the chlorine in the stratosphere resides in "reservoir" compounds, primarily chlorine nitrate (ClONO
2
) as well as stable end products such as HCl. The formation of end products essentially removes Cl from the ozone depletion process. Reservoir compounds sequester Cl, which can later be made available via absorption of light at wavelengths shorter than 400 nm. During the Antarctic winter and spring, reactions on the surface of the polar stratospheric cloud particles convert these "reservoir" compounds into reactive free radicals (Cl and ClO). Denitrification is the process by which the clouds remove NO
2
from the stratosphere by converting it to nitric acid in PSC particles, which then are lost by sedimentation. This prevents newly formed ClO from being converted back into ClONO
2
.

The role of sunlight in ozone depletion is the reason why the Antarctic ozone depletion is greatest during spring. During winter, even though PSCs are at their most abundant, there is no light over the pole to drive chemical reactions. During the spring, however, sunlight returns and provides energy to drive photochemical reactions and melt the polar stratospheric clouds, releasing considerable ClO, which drives the hole mechanism. Further warming temperatures near the end of spring break up the vortex around mid-December. As warm, ozone and NO
2
-rich air flows in from lower latitudes, the PSCs are destroyed, the enhanced ozone depletion process shuts down, and the ozone hole closes.

Most of the ozone that is destroyed is in the lower stratosphere, in contrast to the much smaller ozone depletion through homogeneous gas-phase reactions, which occurs primarily in the upper stratosphere.

Effects

Since the ozone layer absorbs UVB ultraviolet light from the sun, ozone layer depletion increases surface UVB levels (all else equal), which could lead to damage, including an increase in skin cancer. This was the reason for the Montreal Protocol. Although decreases in stratospheric ozone are well-tied to CFCs and increases in surface UVB, there is no direct observational evidence linking ozone depletion to higher incidence of skin cancer and eye damage in human beings. This is partly because UVA, which has also been implicated in some forms of skin cancer, is not absorbed by ozone, and because it is nearly impossible to control statistics for lifestyle changes over time. Ozone depletion may also influence wind patterns.

Increased UV

Ozone, while a minority constituent in Earth's atmosphere, is responsible for most of the absorption of UVB radiation. The amount of UVB radiation that penetrates through the ozone layer decreases exponentially with the slant-path thickness and density of the layer. When stratospheric ozone levels decrease, higher levels of UVB reach the Earth's surface. UV-driven phenolic formation in tree rings has dated the start of ozone depletion in northern latitudes to the late 1700s.

In October 2008, the Ecuadorian Space Agency published a report called HIPERION. The study used ground instruments in Ecuador and the last 28 years' data from 12 satellites of several countries, and found that the UV radiation reaching equatorial latitudes was far greater than expected, with the UV Index climbing as high as 24 in Quito; the WHO considers 11 as an extreme index and a great risk to health. The report concluded that depleted ozone levels around the mid-latitudes of the planet are already endangering large populations in these areas. Later, the CONIDA, the Peruvian Space Agency, published its own study, which yielded almost the same findings as the Ecuadorian study.

Biological effects

The main public concern regarding the ozone hole has been the effects of increased surface UV radiation on human health. So far, ozone depletion in most locations has been typically a few percent and, as noted above, no direct evidence of health damage is available in most latitudes. If the high levels of depletion seen in the ozone hole were to be common across the globe, the effects could be substantially more dramatic. As the ozone hole over Antarctica has in some instances grown so large as to affect parts of Australia, New Zealand, Chile, Argentina, and South Africa, environmentalists have been concerned that the increase in surface UV could be significant. Excessive ultraviolet radiation (UVR) has reducing effects on the rates of photosynthesis and growth of benthic diatom communities (microalgae species that increase water quality and are pollution resistant) that are present in shallow freshwater. Ozone depletion not only affects human health but also has a profound impact on biodiversity. It damages plants and trees at the cellular level, affecting their growth, vitality, photosynthesis, water balance, and defense mechanisms against pests and diseases. This sets off a cascade of ecological impacts, harming soil microbes, insects, wildlife, and entire ecosystems.

Ozone depletion would magnify all of the effects of UV on human health, both positive (including production of vitamin D) and negative (including sunburn, skin cancer, and cataracts). In addition, increased surface UV leads to increased tropospheric ozone, which is a health risk to humans.

Basal and squamous cell carcinomas

The most common forms of skin cancer in humans, basal and squamous cell carcinomas, have been strongly linked to UV-B exposure. The mechanism by which UVB induces these cancers is well understood—absorption of UV-B radiation causes the pyrimidine bases in the DNA molecule to form dimers, resulting in transcription errors when the DNA replicates. These cancers are relatively mild and rarely fatal, although the treatment of squamous cell carcinoma sometimes requires extensive reconstructive surgery. By combining epidemiological data with results of animal studies, scientists have estimated that every one percent decrease in long-term stratospheric ozone would increase the incidence of these cancers by 2%.

Melanoma

Another form of skin cancer, Melanoma, is much less common but far more dangerous, being lethal in about 15–20 percent of the cases diagnosed. The relationship between melanoma and ultraviolet exposure is not yet fully understood, but it appears that both UV-B and UV-A are involved. Because of this uncertainty, it is difficult to estimate the effect of ozone depletion on melanoma incidence. One study showed that a 10 percent increase in UV-B radiation was associated with a 19 percent increase in melanomas for men and 16 percent for women. A study of people in Punta Arenas, at the southern tip of Chile, showed a 56 percent increase in melanoma and a 46 percent increase in non-melanoma skin cancer over a period of seven years, along with decreased ozone and increased UVB levels.

Cortical cataracts

Epidemiological studies suggest an association between ocular cortical cataracts and UV-B exposure, using crude approximations of exposure and various cataract assessment techniques. A detailed assessment of ocular exposure to UV-B was carried out in a study on Chesapeake Bay Watermen, where increases in average annual ocular exposure were associated with increasing risk of cortical opacity. In this highly exposed group of predominantly white males, the evidence linking cortical opacities to sunlight exposure was the strongest to date. Based on these results, ozone depletion is predicted to cause hundreds of thousands of additional cataracts by 2050.

Increased tropospheric ozone

Increased surface UV leads to increased tropospheric ozone. Ground-level ozone is generally recognized to be a health risk, as ozone is toxic due to its strong oxidant properties. The risks are particularly high for young children, the elderly, and those with asthma or other respiratory difficulties. At this time, ozone at ground level is produced mainly by the action of UV radiation on combustion gases from vehicle exhausts.

Increased production of vitamin D

Vitamin D is produced in the skin by ultraviolet light. Thus, higher UVB exposure raises human vitamin D in those deficient in it. Recent research (primarily since the Montreal Protocol) shows that many humans have less than optimal vitamin D levels. In particular, in the U.S. population, the lowest quarter of vitamin D (<17.8 ng/ml) were found using information from the National Health and Nutrition Examination Survey to be associated with an increase in all-cause mortality in the general population. While blood level of vitamin D in excess of 100 ng/ml appear to raise blood calcium excessively and to be associated with higher mortality, the body has mechanisms that prevent sunlight from producing vitamin D in excess of the body's requirements.

Effects on animals

A November 2011 report by scientists at the Institute of Zoology in London, England found that whales off the coast of California have shown a sharp rise in sun damage, and these scientists "fear that the thinning ozone layer is to blame". The study photographed and took skin biopsies from over 150 whales in the Gulf of California and found "widespread evidence of epidermal damage commonly associated with acute and severe sunburn", having cells that form when the DNA is damaged by UV radiation. The findings suggest "rising UV levels as a result of ozone depletion are to blame for the observed skin damage, in the same way that human skin cancer rates have been on the increase in recent decades." Apart from whales many other animals such as dogs, cats, sheep and terrestrial ecosystems also suffer the negative effects of increased UV-B radiations.

Effects on crops

An increase of UV radiation would be expected to affect crops. A number of economically important species of plants, such as rice, depend on cyanobacteria residing on their roots for the retention of nitrogen. Cyanobacteria are sensitive to UV radiation and would be affected by its increase. "Despite mechanisms to reduce or repair the effects of increased ultraviolet radiation, plants have a limited ability to adapt to increased levels of UVB, therefore plant growth can be directly affected by UVB radiation."

Effects on plant life

Over the years, the Arctic ozone layer has depleted severely. As a consequence species that live above the snow cover or in areas where snow has melted abundantly, due to hot temperatures, are negatively impacted due to UV radiation that reaches the ground. Depletion of the ozone layer and allowing excess UVB radiation would initially be assumed to increase damage to plant DNA. Reports have found that when plants are exposed to UVB radiation similar to stratospheric ozone depletion, there was no significant change in plant height or leaf mass, but showed a response in shoot biomass and leaf area with a small decrease. However, UVB radiation has been shown to decrease quantum yield of photosystem II. UVB damage only occurs under extreme exposure, and most plants also have UVB absorbing flavonoids which allow them to acclimatize to the radiation present. Plants experience different levels of UV radiation throughout the day. It is known that they are able to shift the levels and types of UV sunscreens (i.e. flavonoids), that they contain, throughout the day. This allows them to increase their protection against UV radiation. Plants that have been affected by radiation throughout development are more affected by the inability to intercept light with a larger leaf area than having photosynthetic systems compromised. Damage from UVB radiation is more likely to be significant on species interactions than on plants themselves.

Another significant impact of ozone depletion on plant life is the stress experienced by plants when exposed to UV radiation. This can cause a decrease in plant growth and an increase in oxidative stress, due to the production of nitric oxide and hydrogen peroxide. In areas where substantial ozone depletion has occurred, increased UV-B radiation reduces terrestrial plant productivity (and likewise carbon sequestration) by about 6%.

Moreover, if plants are exposed to high levels of UV radiation, it can elicit the production of harmful volatile organic compounds, like isoprenes. The emission of isoprenes into the air, by plants, can severely impact the environment by adding to air pollution and increasing the amount of carbon in the atmosphere, ultimately contributing to climate change.

Public policy

NASA projections of stratospheric ozone concentrations if chlorofluorocarbons had not been banned

The full extent of the damage that CFCs have caused to the ozone layer is not known and will not be known for decades; however, marked decreases in column ozone have already been observed. The Montreal and Vienna conventions were installed long before a scientific consensus was established or important uncertainties in the science field were being resolved. The ozone case was understood comparably well by lay persons as e.g. Ozone shield or ozone hole were useful "easy-to-understand bridging metaphors". Americans voluntarily switched away from aerosol sprays, resulting in a 50 percent sales loss even before legislation was enforced.

After a 1976 report by the United States National Academy of Sciences concluded that credible scientific evidence supported the ozone depletion hypothesis a few countries, including the United States, Canada, Sweden, Denmark, and Norway, moved to eliminate the use of CFCs in aerosol spray cans. At the time this was widely regarded as a first step towards a more comprehensive regulation policy, but progress in this direction slowed in subsequent years, due to a combination of political factors (continued resistance from the halocarbon industry and a general change in attitude towards environmental regulation during the first two years of the Reagan administration) and scientific developments (subsequent National Academy assessments that indicated that the first estimates of the magnitude of ozone depletion had been overly large).

A critical DuPont manufacturing patent for Freon was set to expire in 1979. The United States banned the use of CFCs in aerosol cans in 1978. The European Community rejected proposals to ban CFCs in aerosol sprays, and in the U.S., CFCs continued to be used as refrigerants and for cleaning circuit boards. Worldwide CFC production fell sharply after the U.S. aerosol ban, but by 1986 had returned nearly to its 1976 level. In 1993, DuPont Canada closed its CFC facility.

The U.S. government's attitude began to change again in 1983, when William Ruckelshaus replaced Anne M. Burford as Administrator of the United States Environmental Protection Agency (EPA). Under Ruckelshaus and his successor, Lee Thomas, the EPA pushed for an international approach to halocarbon regulations. In 1985 twenty nations, including most of the major CFC producers, signed the Vienna Convention for the Protection of the Ozone Layer, which established a framework for negotiating international regulations on ozone-depleting substances. That same year, the discovery of the Antarctic ozone hole was announced, causing a revival in public attention to the issue.

In 1987, representatives from 43 nations signed the Montreal Protocol. Meanwhile, the halocarbon industry shifted its position and started supporting a protocol to limit CFC production. However, this shift was uneven with DuPont acting more quickly than its European counterparts. DuPont may have feared court action related to increased skin cancer, especially as the EPA had published a study in 1986 claiming that an additional 40 million cases and 800,000 cancer deaths were to be expected in the U.S. in the next 88 years. The EU shifted its position as well after Germany gave up its defence of the CFC industry and started supporting moves towards regulation. Government and industry in France and the UK tried to defend their CFC producing industries even after the Montreal Protocol had been signed.

At Montreal, the participants agreed to freeze production of CFCs at 1986 levels and to reduce production by 50 percent by 1999. After a series of scientific expeditions to the Antarctic produced convincing evidence that the ozone hole was indeed caused by chlorine and bromine from manmade organohalogens, the Montreal Protocol was strengthened at a 1990 meeting in London. The participants agreed to phase out CFCs and halons entirely (aside from a very small amount marked for certain "essential" uses, such as asthma inhalers) by 2000 in non-Article 5 countries and by 2010 in Article 5 (less developed) signatories. At a 1992 meeting in Copenhagen, Denmark, the phase-out date was moved up to 1996. At the same meeting, methyl bromide (MeBr), a fumigant used primarily in agricultural production, was added to the list of controlled substances. For all substances controlled under the protocol, phaseout schedules were delayed for less developed ('Article 5(1)') countries, and phaseout in these countries was supported by transfers of expertise, technology, and money from non-Article 5(1) Parties to the Protocol. Additionally, exemptions from the agreed schedules could be applied for under the Essential Use Exemption (EUE) process for substances other than methyl bromide and under the Critical Use Exemption (CUE) process for methyl bromide.

Civil society, including especially non-governmental organizations (NGOs), played critical roles at all stages of policy development leading to the Vienna Conference, the Montreal Protocol, and in assessing compliance afterwards. The major companies claimed that no alternatives to HFC existed. An ozone-safe hydrocarbon refrigerant was developed at a technological institute in Hamburg, Germany, consisting of a mixture of the hydrocarbon gases propane and butane, and in 1992 came to the attention of the NGO Greenpeace. Greenpeace called it "Greenfreeze". The NGO then worked successfully first with a small and struggling company to market an appliance beginning in Europe, then Asia and later Latin America, receiving a 1997 UNEP award. By 1995, Germany had made CFC refrigerators illegal. Since 2004, corporations like Coca-Cola, Carlsberg, and IKEA formed a coalition to promote the ozone-safe Greenfreeze units. Production spread to companies like Electrolux, Bosch, and LG, with sales reaching some 300 million refrigerators by 2008. In Latin America, a domestic Argentinian company began Greenfreeze production in 2003, while the giant Bosch in Brazil began a year later. By 2013 it was being used by some 700 million refrigerators, making up about 40 percent of the market.

In the U.S., however, change has been much slower. To some extent, CFCs were being replaced by the less damaging hydrochlorofluorocarbons (HCFCs), although concerns remain regarding HCFCs also. In some applications, hydrofluorocarbons (HFCs) were being used to replace CFCs. HFCs, which contain no chlorine or bromine, do not contribute to ozone depletion although they are potent greenhouse gases. The best known of these compounds is probably HFC-134a (R-134a), which in the United States has largely replaced CFC-12 (R-12) in automobile air conditioners. In laboratory analytics (a former "essential" use) the ozone depleting substances can be replaced with other solvents. Chemical companies like Du Pont, whose representatives disparaged Greenfreeze as "that German technology," maneuvered the EPA to block the technology in the U.S. until 2011. Ben & Jerry's of Unilever and General Electric, spurred by Greenpeace, had expressed formal interest in 2008 which figured in the EPA's final approval.

The EU recast its Ozone Regulation in 2009. The law bans ozone-depleting substances with the goal of protecting the ozone layer. The list of ODS that are subject to the regulation is the same as those under the Montreal Protocol, with some additions.

More recently, policy experts have advocated for efforts to link ozone protection efforts to climate protection efforts. Many ODS are also greenhouse gases, some thousands of times more powerful agents of radiative forcing than carbon dioxide over the short and medium term. Thus policies protecting the ozone layer have had benefits in mitigating climate change. The reduction of the radiative forcing due to ODS probably masked the true level of climate change effects of other greenhouse gases, and was responsible for the "slow down" of global warming from the mid-90s. Policy decisions in one arena affect the costs and effectiveness of environmental improvements in the other.

ODS requirements in the marine industry

The IMO has amended MARPOL Annex VI Regulation 12 regarding ozone depleting substances. As from July 1, 2010, all vessels where MARPOL Annex VI is applicable should have a list of equipment using ozone depleting substances. The list should include the name of ODS, type and location of equipment, quantity in kg and date. All changes since that date should be recorded in an ODS Record book on board recording all intended or unintended releases to the atmosphere. Furthermore, new ODS supply or landing to shore facilities should be recorded as well.

Prospects of ozone depletion

Ozone levels stabilized in the 1990s following the Montreal Protocol, and have started to recover. They are projected to reach pre-1980 levels before 2075.
Ozone-depleting gas trends

Since the adoption and strengthening of the Montreal Protocol has led to reductions in the emissions of CFCs, atmospheric concentrations of the most-significant compounds have been declining. These substances are being gradually removed from the atmosphere; since peaking in 1994, the Effective Equivalent Chlorine (EECl) level in the atmosphere had dropped about 10 percent by 2008. The decrease in ozone-depleting chemicals has also been significantly affected by a decrease in bromine-containing chemicals. The data suggest that substantial natural sources exist for atmospheric methyl bromide (CH
3
Br
). The phase-out of CFCs means that nitrous oxide (N
2
O
), which is not covered by the Montreal Protocol, has become the most highly emitted ozone-depleting substance and is expected to remain so throughout the 21st century.

According to the IPCC Sixth Assessment Report, global stratospheric ozone levels experienced rapid decline in the 1970s and 1980s and have since been increasing, but have not reached preindustrial levels. Although considerable variability is expected from year to year, including in polar regions where depletion is largest, the ozone layer is expected to continue recovering in coming decades due to declining ozone-depleting substance concentrations, assuming full compliance with the Montreal Protocol.

The Antarctic ozone hole is expected to continue for decades. Ozone concentrations in the lower stratosphere over Antarctica increased by 5–10 percent by 2020 and will return to pre-1980 levels by about 2060–2075. This is 10–25 years later than predicted in earlier assessments, because of revised estimates of atmospheric concentrations of ozone-depleting substances, including a larger predicted future usage in developing countries. Another factor that may prolong ozone depletion is the drawdown of nitrogen oxides from above the stratosphere due to changing wind patterns. A gradual trend toward "healing" was reported in 2016. In 2019, the ozone hole was at its smallest in the previous thirty years, due to the warmer polar stratosphere weakening the polar vortex. In September 2023, the Antarctic ozone hole was one of the largest on record, at 26 million square kilometers. The anomalously large ozone loss may have been a result of the 2022 Tonga volcanic eruption. According to a 2023 United Nations assessment, the ozone layer is on track to recover to 1980 levels by around 2066 over Antarctica, by 2045 over the Arctic, and by 2040 for the rest of the world, assuming current regulations remain in place.

Research history

The basic physical and chemical processes that lead to the formation of an ozone layer in the Earth's stratosphere were discovered by Sydney Chapman in 1930. Short-wavelength UV radiation splits an oxygen (O
2
) molecule into two oxygen (O) atoms, which then combine with other oxygen molecules to form ozone. Ozone is removed when an oxygen atom and an ozone molecule "recombine" to form two oxygen molecules, i.e. O + O
3
→ 2O
2
. In the 1950s, David Bates and Marcel Nicolet presented evidence that various free radicals, in particular hydroxyl (OH) and nitric oxide (NO), could catalyze this recombination reaction, reducing the overall amount of ozone. These free radicals were known to be present in the stratosphere, and so were regarded as part of the natural balance—it was estimated that in their absence, the ozone layer would be about twice as thick as it currently is.

In 1970 Paul Crutzen pointed out that emissions of nitrous oxide (N
2
O
), a stable, long-lived gas produced by soil bacteria, from the Earth's surface could affect the amount of nitric oxide (NO) in the stratosphere. Crutzen showed that nitrous oxide lives long enough to reach the stratosphere, where it is converted into NO. Crutzen then noted that increasing use of fertilizers might have led to an increase in nitrous oxide emissions over the natural background, which would in turn result in an increase in the amount of NO in the stratosphere. Thus human activity could affect the stratospheric ozone layer. In the following year, Crutzen and (independently) Harold Johnston suggested that NO emissions from supersonic passenger aircraft, which would fly in the lower stratosphere, could also deplete the ozone layer. However, more recent analysis in 1995 by David W. Fahey, an atmospheric scientist at the National Oceanic and Atmospheric Administration, found that the drop in ozone would be from 1–2 percent if a fleet of 500 supersonic passenger aircraft were operated. This, Fahey expressed, would not be a showstopper for advanced supersonic passenger aircraft development.

Rowland–Molina hypothesis

In 1974 Frank Sherwood Rowland, Chemistry Professor at the University of California at Irvine, and his postdoctoral associate Mario J. Molina suggested that long-lived organic halogen compounds, such as CFCs, might behave in a similar fashion as Crutzen had proposed for nitrous oxide. James Lovelock had recently discovered, during a cruise in the South Atlantic in 1971, that almost all of the CFC compounds manufactured since their invention in 1930 were still present in the atmosphere. Molina and Rowland concluded that, like N
2
O
, the CFCs would reach the stratosphere where they would be dissociated by UV light, releasing chlorine atoms. A year earlier, Richard Stolarski and Ralph Cicerone at the University of Michigan had shown that Cl is even more efficient than NO at catalyzing the destruction of ozone. Similar conclusions were reached by Michael McElroy and Steven Wofsy at Harvard University. Neither group, however, had realized that CFCs were a potentially large source of stratospheric chlorine—instead, they had been investigating the possible effects of HCl emissions from the Space Shuttle, which are very much smaller.

The Rowland–Molina hypothesis was strongly disputed by representatives of the aerosol and halocarbon industries. The Chair of the Board of DuPont was quoted as saying that ozone depletion theory is "a science fiction tale ... a load of rubbish ... utter nonsense". Robert Abplanalp, the President of Precision Valve Corporation (and inventor of the first practical aerosol spray can valve), wrote to the Chancellor of UC Irvine to complain about Rowland's public statements. Nevertheless, within three years most of the basic assumptions made by Rowland and Molina were confirmed by laboratory measurements and by direct observation in the stratosphere. The concentrations of the source gases (CFCs and related compounds) and the chlorine reservoir species (HCl and ClONO
2
) were measured throughout the stratosphere, and demonstrated that CFCs were indeed the major source of stratospheric chlorine, and that nearly all of the CFCs emitted would eventually reach the stratosphere. Even more convincing was the measurement, by James G. Anderson and collaborators, of chlorine monoxide (ClO) in the stratosphere. ClO is produced by the reaction of Cl with ozone—its observation thus demonstrated that Cl radicals not only were present in the stratosphere but also were actually involved in destroying ozone. McElroy and Wofsy extended the work of Rowland and Molina by showing that bromine atoms were even more effective catalysts for ozone loss than chlorine atoms and argued that the brominated organic compounds known as halons, widely used in fire extinguishers, were a potentially large source of stratospheric bromine. In 1976 the United States National Academy of Sciences released a report concluding that the ozone depletion hypothesis was strongly supported by the scientific evidence. In response the United States, Canada and Norway banned the use of CFCs in aerosol spray cans in 1978. Early estimates were that, if CFC production continued at 1977 levels, the total atmospheric ozone would after a century or so reach a steady state, 15 to 18 percent below normal levels. By 1984, when better evidence on the speed of critical reactions was available, this estimate was changed to 5 to 9 percent steady-state depletion.

Crutzen, Molina, and Rowland were awarded the 1995 Nobel Prize in Chemistry for their work on stratospheric ozone.

Antarctic ozone hole

The discovery of the Antarctic "ozone hole" by British Antarctic Survey scientists Farman, Gardiner and Shanklin (first reported in a paper in Nature in May 1985) came as a shock to the scientific community, because the observed decline in polar ozone was far larger than had been anticipated. Satellite measurements (TOMS onboard Nimbus 7) showing massive depletion of ozone around the south pole were becoming available at the same time. However, these were initially rejected as unreasonable by data quality control algorithms (they were filtered out as errors since the values were unexpectedly low); the ozone hole was detected only in satellite data when the raw data was reprocessed following evidence of ozone depletion in in situ observations. When the software was rerun without the flags, the ozone hole was seen as far back as 1976.

Susan Solomon, an atmospheric chemist at the National Oceanic and Atmospheric Administration (NOAA), proposed that chemical reactions on polar stratospheric clouds (PSCs) in the cold Antarctic stratosphere caused a massive, though localized and seasonal, increase in the amount of chlorine present in active, ozone-destroying forms. The polar stratospheric clouds in Antarctica are only formed at very low temperatures, as low as −80 °C, and early spring conditions. In such conditions the ice crystals of the cloud provide a suitable surface for conversion of unreactive chlorine compounds into reactive chlorine compounds, which can easily deplete ozone.

Moreover, the polar vortex formed over Antarctica is very tight and the reaction occurring on the surface of the cloud crystals is far different from when it occurs in atmosphere. These conditions have led to ozone hole formation in Antarctica. This hypothesis was decisively confirmed, first by laboratory measurements and subsequently by direct measurements, from the ground and from high-altitude airplanes, of very high concentrations of chlorine monoxide (ClO) in the Antarctic stratosphere.

Alternative hypotheses, which had attributed the ozone hole to variations in solar UV radiation or to changes in atmospheric circulation patterns, were also tested and shown to be untenable.

Meanwhile, analysis of ozone measurements from the worldwide network of ground-based Dobson spectrophotometers led an international panel to conclude that the ozone layer was in fact being depleted, at all latitudes outside of the tropics. These trends were confirmed by satellite measurements. As a consequence, the major halocarbon-producing nations agreed to phase out production of CFCs, halons, and related compounds, a process that was completed in 1996.

Since 1981 the United Nations Environment Programme, under the auspices of the World Meteorological Organization, has sponsored a series of technical reports on the Scientific Assessment of Ozone Depletion, based on satellite measurements. The 2007 report showed that the hole in the ozone layer was recovering and the smallest it had been for about a decade.

A 2010 report found, "Over the past decade, global ozone and ozone in the Arctic and Antarctic regions is no longer decreasing but is not yet increasing. The ozone layer outside the Polar regions is projected to recover to its pre-1980 levels some time before the middle of this century. In contrast, the springtime ozone hole over the Antarctic is expected to recover much later."

In 2012, NOAA and NASA reported "Warmer air temperatures high above the Antarctic led to the second smallest season ozone hole in 20 years averaging 17.9 million square kilometres. The hole reached its maximum size for the season on Sept 22, stretching to 21.2 million square kilometres." A gradual trend toward "healing" was reported in 2016 and then in 2017. It is reported that the recovery signal is evident even in the ozone loss saturation altitudes.

The hole in the Earth's ozone layer over the South Pole has affected atmospheric circulation in the Southern Hemisphere all the way to the equator. The ozone hole has influenced atmospheric circulation all the way to the tropics and increased rainfall at low, subtropical latitudes in the Southern Hemisphere.

Arctic ozone "mini-hole"

On March 3, 2005, the journal Nature published an article linking 2004's unusually large Arctic ozone hole to solar wind activity.

On March 15, 2011, a record ozone layer loss was observed, with about half of the ozone present over the Arctic having been destroyed. The change was attributed to increasingly cold winters in the Arctic stratosphere at an altitude of approximately 20 km (12 mi), a change associated with global warming in a relationship that is still under investigation. By March 25, the ozone loss had become the largest compared to that observed in all previous winters with the possibility that it would become an ozone hole. This would require that the quantities of ozone to fall below 200 Dobson units, from the 250 recorded over central Siberia. It is predicted that the thinning layer would affect parts of Scandinavia and Eastern Europe on March 30–31.

On October 2, 2011, a study was published in the journal Nature, which said that between December 2010 and March 2011 up to 80 percent of the ozone in the atmosphere at about 20 kilometres (12 mi) above the surface was destroyed. The level of ozone depletion was severe enough that scientists said it could be compared to the ozone hole that forms over Antarctica every winter. According to the study, "for the first time, sufficient loss occurred to reasonably be described as an Arctic ozone hole." The study analyzed data from the Aura and CALIPSO satellites, and determined that the larger-than-normal ozone loss was due to an unusually long period of cold weather in the Arctic, some 30 days more than typical, which allowed for more ozone-destroying chlorine compounds to be created. According to Lamont Poole, a co-author of the study, cloud and aerosol particles on which the chlorine compounds are found "were abundant in the Arctic until mid March 2011—much later than usual—with average amounts at some altitudes similar to those observed in the Antarctic, and dramatically larger than the near-zero values seen in March in most Arctic winters".

In 2013, researchers analyzed the data and found the 2010–2011 Arctic event did not reach the ozone depletion levels to classify as a true hole. A hole in the ozone is generally classified as 220 Dobson units or lower; the Arctic hole did not approach that low level. It has since been classified as a "mini-hole."

Following the ozone depletion in 1997 and 2011, a 90% drop in ozone was measured by weather balloons over the Arctic in March 2020, as they normally recorded 3.5 parts per million of ozone, compared to only around 0.3 parts per million lastly, due to the coldest temperatures ever recorded since 1979, and a strong polar vortex which allowed chemicals, including chlorine and bromine, to reduce ozone.

A rare hole, the result of unusually low temperatures in the atmosphere above the North Pole, was studied in 2020.

Tibet ozone hole

As winters that are colder are more affected, at times there is an ozone hole over Tibet. In 2006, a 2.5 million square kilometer ozone hole was detected over Tibet. Again in 2011, an ozone hole appeared over mountainous regions of Tibet, Xinjiang, Qinghai and the Hindu Kush, along with an unprecedented hole over the Arctic, though the Tibet one was far less intense than the ones over the Arctic or Antarctic.

Potential depletion by storm clouds

Research in 2012 showed that the same process that produces the ozone hole over Antarctica, occurs over summer storm clouds in the United States, and thus may be destroying ozone there as well.

Ozone hole over tropics

Physicist Qing-Bin Lu, of the University of Waterloo, claimed to have discovered a large, all-season ozone hole in the lower stratosphere over the tropics in July 2022. However, other researchers in the field refuted this claim, stating that the research was riddled with "serious errors and unsubstantiated assertions." According to Dr Paul Young, a lead author of the 2022 WMO/UNEP Scientific Assessment of Ozone Depletion, "The author's identification of a 'tropical ozone hole' is down to him looking at percentage changes in ozone, rather than absolute changes, with the latter being much more relevant for damaging UV reaching the surface." Specifically, Lu's work defines "ozone hole" as "an area with O3 loss in percent larger than 25%, with respect to the undisturbed O3 value when there were no significant CFCs in the stratosphere (~ in the 1960s)" instead of the general definition of 220 Dobson units or lower. Dr Marta Abalos Alvarez has added "Ozone depletion in the tropics is nothing new and is mainly due to the acceleration of the Brewer-Dobson circulation."

Depletion caused by wildfire smoke

Analyzing the atmospheric impacts of the 2019–2020 Australian bushfire season, scientists led by MIT researcher Susan Solomon found the smoke destroyed 3–5% of ozone in affected areas of the Southern Hemisphere. Smoke particles absorb hydrogen chloride and act as a catalyst to create chlorine radicals that destroy ozone.

Ozone depletion and global warming

Among others, Robert Watson had a role in the science assessment and in the regulation efforts of ozone depletion and global warming. Prior to the 1980s, the EU, NASA, NAS, UNEP, WMO and the British government had dissenting scientific reports and Watson played a role in the process of unified assessments. Based on the experience with the ozone case, the IPCC started to work on a unified reporting and science assessment to reach a consensus to provide the IPCC Summary for Policymakers.

There are various areas of linkage between ozone depletion and global warming science:

Radiative forcing from various greenhouse gases and other sources
  • The same CO
    2
    radiative forcing that produces global warming is expected to cool the stratosphere. This cooling, in turn, is expected to produce a relative increase in ozone (O
    3
    ) depletion in polar areas and the frequency of ozone holes.
  • Conversely, ozone depletion represents a radiative forcing of the climate system. There are two opposing effects: Reduced ozone causes the stratosphere to absorb less solar radiation, thus cooling the stratosphere while warming the troposphere; the resulting colder stratosphere emits less long-wave radiation downward, thus cooling the troposphere. Overall, the cooling dominates; the IPCC concludes "observed stratospheric O
    3
    losses over the past two decades have caused a negative forcing of the surface-troposphere system
    " of about −0.15 ± 0.10 watts per square meter (W/m2).
  • One of the strongest predictions of the greenhouse effect is that the stratosphere will cool. Although this cooling has been observed, it is not trivial to separate the effects of changes in the concentration of greenhouse gases and ozone depletion since both will lead to cooling. However, this can be done by numerical stratospheric modeling. Results from the National Oceanic and Atmospheric Administration's Geophysical Fluid Dynamics Laboratory show that above 20 km (12 mi), the greenhouse gases dominate the cooling.
  • Ozone depleting chemicals are also often greenhouse gases. The increases in concentrations of these chemicals have produced 0.34 ± 0.03 W/m2 of radiative forcing, corresponding to about 14 percent of the total radiative forcing from increases in the concentrations of well-mixed greenhouse gases.
  • The long term modeling of the process, its measurement, study, design of theories and testing take decades to document, gain wide acceptance, and ultimately become the dominant paradigm. Several theories about the destruction of ozone were hypothesized in the 1980s, published in the late 1990s, and are now being investigated. Dr Drew Schindell, and Dr Paul Newman, NASA Goddard, proposed a theory in the late 1990s, using computational modeling methods to model ozone destruction, that accounted for 78 percent of the ozone destroyed. Further refinement of that model accounted for 89 percent of the ozone destroyed, but pushed back the estimated recovery of the ozone hole from 75 years to 150 years. (An important part of that model is the lack of stratospheric flight due to depletion of fossil fuels.)

In 2019, NASA reported that there was no significant relation between size of the ozone hole and climate change.

Misconceptions

CFC weight

Since CFC molecules are heavier than air (nitrogen or oxygen), it is commonly believed that the CFC molecules cannot reach the stratosphere in significant amounts. However, atmospheric gases are not sorted by weight at these altitudes; the forces of wind can fully mix the gases in the atmosphere. Some of the heavier CFCs are not evenly distributed.

Percentage of human-made chlorine

Sources of stratospheric chlorine

Another misconception is that natural sources of chlorine are several times larger than human-made ones. While this statement is true for tropospheric chlorine, that is irrelevant to ozone depletion, which is only affected by stratospheric chlorine. Chlorine from ocean spray is soluble and thus is washed by rainfall before it reaches the stratosphere. CFCs, in contrast, are insoluble and long-lived, allowing them to reach the stratosphere. In the lower atmosphere, there is much more chlorine from CFCs and related haloalkanes than there is in HCl from salt spray, and in the stratosphere halocarbons are dominant. Only methyl chloride, which is one of these halocarbons, has a mainly natural source, and it is responsible for about 20 percent of the chlorine in the stratosphere; the remaining 80 percent comes from human-made sources.

Very violent volcanic eruptions can inject HCl into the stratosphere, but researchers have shown that the contribution is not significant compared to that from CFCs. A similar erroneous assertion is that soluble halogen compounds from the volcanic plume of Mount Erebus on Ross Island, Antarctica are a major contributor to the Antarctic ozone hole.

Nevertheless, a 2015 study showed that the role of Mount Erebus volcano in the Antarctic ozone depletion was probably underestimated. Based on the NCEP/NCAR reanalysis data over the last 35 years and by using the NOAA HYSPLIT trajectory model, researchers showed that gas emissions from the volcano (including hydrogen chloride (HCl)) can reach the Antarctic stratosphere via high-latitude cyclones and then the polar vortex. Depending on the level of its volcanic activity, the additional annual HCl mass entering the stratosphere from Erebus varies from 1.0 to 14.3 kt.

First observation

G.M.B. Dobson mentioned that when springtime ozone levels in the Antarctic over Halley Bay were first measured in 1956, he was surprised to find that they were only about 320 DU, about 150 DU below typical spring Arctic levels of around 450 DU. What Dobson observed was not an ozone hole but in fact a typical annual maximum Antarctic ozone concentration: actual ozone hole values are in the 150–100 DU range. While Arctic ozone concentrations vary on a smooth annual cycle from around 300 to 450 DU, peaking in the northern hemisphere spring, Antarctic concentrations drop sharply in the southern hemisphere spring from highs of around 300 DU to much lower values. Peak values are not reached again until December.

Location of hole

Some people thought that the ozone hole should be above the sources of CFCs. However, CFCs are well mixed globally in the troposphere and stratosphere. The reason for occurrence of the ozone hole above Antarctica is not because there are more CFCs concentrated but because the low temperatures help form polar stratospheric clouds. In fact, there are findings of significant and localized "ozone holes" above other parts of the Earth, such as above Central Asia.

Awareness campaigns

Public misconceptions and misunderstandings of complex issues like ozone depletion are common. The limited scientific knowledge of the public led to confusion about global warming or the perception of global warming as a subset of the "ozone hole". In the beginning, classical green NGOs refrained from using CFC depletion for campaigning, as they assumed the topic was too complicated. They became active much later, e.g. in Greenpeace's support for a CFC-free refrigerator produced by the former East German company VEB dkk Scharfenstein.

The metaphors used in the CFC discussion (ozone shield, ozone hole) are not "exact" in the scientific sense. The "ozone hole" is more of a depression, less "a hole in the windshield". The ozone does not disappear through the layer, nor is there a uniform "thinning" of the ozone layer. However, they resonated better with non-scientists and their concerns. The ozone hole was seen as a "hot issue" and imminent risk as laypeople feared severe personal consequences such as skin cancer, cataracts, damage to plants, and reduction of plankton populations in the ocean's photic zone. Not only on the policy level, ozone regulation compared to climate change fared much better in public opinion. Americans voluntarily switched away from aerosol sprays before legislation was enforced, while climate change failed to achieve comparable concern and public action. The sudden identification in 1985 that there was a substantial "hole" was widely reported in the press. The especially rapid ozone depletion in Antarctica had previously been dismissed as a measurement error. Scientific consensus was established after regulation.

While the Antarctic ozone hole has a relatively small effect on global ozone, the hole has generated a great deal of public interest because:

  • Many have worried that ozone holes might start appearing over other areas of the globe, though to date the only other large-scale depletion is a smaller ozone "dimple" observed during the Arctic spring around the North Pole. Ozone at middle latitudes has declined, but by a much smaller extent (a decrease of about 4–5 percent).
  • If stratospheric conditions become more severe (cooler temperatures, more clouds, more active chlorine), global ozone may decrease at a greater pace. Standard global warming theory predicts that the stratosphere will cool.
  • When the Antarctic ozone hole breaks up each year, the ozone-depleted air drifts into nearby regions. Decreases in the ozone level of up to 10 percent have been reported in New Zealand in the month following the breakup of the Antarctic ozone hole, with ultraviolet-B radiation intensities increasing by more than 15 percent since the 1970s.

World Ozone Day

In 1994, the United Nations General Assembly voted to designate September 16 as the International Day for the Preservation of the Ozone Layer, or "World Ozone Day". The designation commemorates the signing of the Montreal Protocol on that date in 1987.

Spatial ability

From Wikipedia, the free encyclopedia https://en.wikipedia.org/wiki/Spatial_ability Space Engineer...