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Monday, January 31, 2022

Landfill

From Wikipedia, the free encyclopedia

A landfill in Poland

A landfill site, also known as a tip, dump, rubbish dump, garbage dump, or dumping ground, is a site for the disposal of waste materials. Landfill is the oldest and most common form of waste disposal, although the systematic burial of the waste with daily, intermediate and final covers only began in the 1940s. In the past, refuse was simply left in piles or thrown into pits; in archeology this is known as a midden.

Some landfill sites are used for waste management purposes, such as temporary storage, consolidation and transfer, or for various stages of processing waste material, such as sorting, treatment, or recycling. Unless they are stabilized, landfills may undergo severe shaking or soil liquefaction of the ground during an earthquake. Once full the area over a landfill site may be reclaimed for other uses.

Operations

One of several landfills used by Dryden, Ontario, Canada

Operators of well-run landfills for non-hazardous waste meet predefined specifications by applying techniques to:

  1. confine waste to as small an area as possible
  2. compact waste to reduce volume

They can also cover waste (usually daily) with layers of soil or other types of material such as woodchips and fine particles.

During landfill operations, a scale or weighbridge may weigh waste collection vehicles on arrival and personnel may inspect loads for wastes that do not accord with the landfill's waste-acceptance criteria. Afterward, the waste collection vehicles use the existing road network on their way to the tipping face or working front, where they unload their contents. After loads are deposited, compactors or bulldozers can spread and compact the waste on the working face. Before leaving the landfill boundaries, the waste collection vehicles may pass through a wheel-cleaning facility. If necessary, they return to the weighbridge for re-weighing without their load. The weighing process can assemble statistics on the daily incoming waste tonnage, which databases can retain for record keeping. In addition to trucks, some landfills may have equipment to handle railroad containers. The use of "rail-haul" permits landfills to be located at more remote sites, without the problems associated with many truck trips.

Typically, in the working face, the compacted waste is covered with soil or alternative materials daily. Alternative waste-cover materials include chipped wood or other "green waste", several sprayed-on foam products, chemically "fixed" bio-solids, and temporary blankets. Blankets can be lifted into place at night and then removed the following day prior to waste placement. The space that is occupied daily by the compacted waste and the cover material is called a daily cell. Waste compaction is critical to extending the life of the landfill. Factors such as waste compressibility, waste-layer thickness and the number of passes of the compactor over the waste affect the waste densities.

Sanitary landfill life cycle

The term landfill is usually shorthand for a municipal landfill or sanitary landfill. These facilities were first introduced early in the 20th century, but gained wide use in the 1960s and 1970s, in an effort to eliminate open dumps and other "unsanitary" waste disposal practices. The sanitary landfill is an engineered facility that separates and confines waste. Sanitary landfills are intended as biological reactors (bioreactors) in which microbes will break down complex organic waste into simpler, less toxic compounds over time. These reactors must be designed and operated according to regulatory standards and guidelines (See environmental engineering).

Usually, aerobic decomposition is the first stage by which wastes are broken down in a landfill. These are followed by four stages of anaerobic degradation. Usually, solid organic material in solid phase decays rapidly as larger organic molecules degrade into smaller molecules. These smaller organic molecules begin to dissolve and move to the liquid phase, followed by hydrolysis of these organic molecules, and the hydrolyzed compounds then undergo transformation and volatilization as carbon dioxide (CO2) and methane (CH4), with rest of the waste remaining in solid and liquid phases.

During the early phases, little material volume reaches the leachate, as the biodegradable organic matter of the waste undergoes a rapid decrease in volume. Meanwhile, the leachate's chemical oxygen demand increases with increasing concentrations of the more recalcitrant compounds compared to the more reactive compounds in the leachate. Successful conversion and stabilization of the waste depend on how well microbial populations function in syntrophy, i.e. an interaction of different populations to provide each other's nutritional needs.

The life cycle of a municipal landfill undergoes five distinct phases.

Initial adjustment (Phase I)

As the waste is placed in the landfill, the void spaces contain high volumes of molecular oxygen (O2). With added and compacted wastes, the O2 content of the landfill bioreactor strata gradually decreases. Microbial populations grow, density increases. Aerobic biodegradation dominates, i.e. the primary electron acceptor is O2.

Transition (Phase II)

The O2 is rapidly degraded by the existing microbial populations. The decreasing O2 leads to less aerobic and more anaerobic conditions in the layers. The primary electron acceptors during transition are nitrates and sulphates since O2 is rapidly displaced by CO2 in the effluent gas.

Acid formation (Phase III)

Hydrolysis of the biodegradable fraction of the solid waste begins in the acid formation phase, which leads to rapid accumulation of volatile fatty acids (VFAs) in the leachate. The increased organic acid content decreases the leachate pH from approximately 7.5 to 5.6. During this phase, the decomposition intermediate compounds like the VFAs contribute much chemical oxygen demand (COD). Long-chain volatile organic acids (VOAs) are converted to acetic acid (C2H4O2), CO2, and hydrogen gas (H2). High concentrations of VFAs increase both the biochemical oxygen demand (BOD) and VOA concentrations, which initiates H2 production by fermentative bacteria, which stimulates the growth of H2-oxidizing bacteria. The H2 generation phase is relatively short because it is complete by the end of the acid formation phase. The increase in the biomass of acidogenic bacteria increases the amount of degradation of the waste material and consuming nutrients. Metals, which are generally more water-soluble at lower pH, may become more mobile during this phase, leading to increasing metal concentrations in the leachate.

Methane fermentation (Phase IV)

The acid formation phase intermediary products (e.g., acetic, propionic, and butyric acids) are converted to CH4 and CO2 by methanogenic microorganisms. As VFAs are metabolized by the methanogens, the landfill water pH returns to neutrality. The leachate's organic strength, expressed as oxygen demand, decreases at a rapid rate with increases in CH4 and CO2 gas production. This is the longest decomposition phase.

Final maturation and stabilization (Phase V)

The rate of microbiological activity slows during the last phase of waste decomposition as the supply of nutrients limits the chemical reactions, e.g. as bioavailable phosphorus becomes increasingly scarce. CH4 production almost completely disappears, with O2 and oxidized species gradually reappearing in the gas wells as O2 permeates downwardly from the troposphere. This transforms the oxidation–reduction potential (ORP) in the leachate toward oxidative processes. The residual organic materials may incrementally be converted to the gas phase, and as organic matter is composted; i.e. the organic matter is converted to humic-like compounds.

Social and environmental impact

Landfill operation in Hawaii. Note that the area being filled is a single, well-defined "cell" and that a protective landfill liner is in place (exposed on the left) to prevent contamination by leachates migrating downward through the underlying geological formation.

Landfills have the potential to cause a number of issues. Infrastructure disruption, such as damage to access roads by heavy vehicles, may occur. Pollution of local roads and watercourses from wheels on vehicles when they leave the landfill can be significant and can be mitigated by wheel washing systems. Pollution of the local environment, such as contamination of groundwater or aquifers or soil contamination may occur, as well.

Leachate

When precipitation falls on open landfills, water percolates through the garbage and becomes contaminated with suspended and dissolved material, forming leachate. If this is not contained it can contaminate groundwater. All modern landfill sites use a combination of impermeable liners several metres thick, geologically stable sites and collection systems to contain and capture this leachate. It can then be treated and evaporated. Once a landfill site is full, it is sealed off to prevent precipitation ingress and new leachate formation. However, liners must have a lifespan, be it several hundred years or more. Eventually, any landfill liner could leak, so the ground around landfills must be tested for leachate to prevent pollutants from contaminating groundwater.

Decomposition gases

Rotting food and other decaying organic waste create decomposition gases, especially CO2 and CH4 from aerobic and anaerobic decomposition, respectively. Both processes occur simultaneously in different parts of a landfill. In addition to available O2, the fraction of gas constituents will vary, depending on the age of landfill, type of waste, moisture content and other factors. For example, the maximum amount of landfill gas produced can be illustrated a simplified net reaction of diethyl oxalate that accounts for these simultaneous reactions:

4 C6H10O4 + 6 H2O → 13 CH4 + 11 CO2.

On average, about half of the volumetric concentration of landfill gas is CH4 and slightly less than half is CO2. The gas also contains about 5% molecular nitrogen (N2), less than 1% hydrogen sulfide (H2S), and a low concentration of non-methane organic compounds (NMOC), about 2700 ppmv.

Waste disposal in Athens, Greece

Landfill gases can seep out of the landfill and into the surrounding air and soil. Methane is a greenhouse gas, and is flammable and potentially explosive at certain concentrations, which makes it perfect for burning to generate electricity cleanly. Since decomposing plant matter and food waste only release carbon that has been captured from the atmosphere through photosynthesis, no new carbon enters the carbon cycle and the atmospheric concentration of CO2 is not affected. Carbon dioxide traps heat in the atmosphere, contributing to climate change. In properly managed landfills, gas is collected and flared or recovered for landfill gas utilization.

Vectors

Poorly run landfills may become nuisances because of vectors such as rats and flies which can spread infectious diseases. The occurrence of such vectors can be mitigated through the use of daily cover.

Other nuisances

A group of wild elephants interacting with a trash dump in Sri Lanka

Other potential issues include wildlife disruption due to occupation of habitat and animal health disruption caused by consuming waste from landfills, dust, odor, noise pollution, and reduced local property values.

Landfill gas

Gases are produced in landfills due to the anaerobic digestion by microbes. In a properly managed landfill this gas is collected and used. Its uses range from simple flaring to the landfill gas utilization and generation of electricity. Landfill gas monitoring alerts workers to the presence of a build-up of gases to a harmful level. In some countries, landfill gas recovery is extensive; in the United States, for example, more than 850 landfills have active landfill gas recovery systems.

A gas flare produced by a landfill in Lake County, Ohio

Regional practice

A landfill in Perth, Western Australia
 
South East New Territories Landfill, Hong Kong

Canada

Landfills in Canada are regulated by provincial environmental agencies and environmental protection legislation. Older facilities tend to fall under current standards and are monitored for leaching. Some former locations have been converted to parkland.

European Union

In the European Union, individual states are obliged to enact legislation to comply with the requirements and obligations of the European Landfill Directive.

The majority of EU member states have laws banning or severely restricting the disposal of household trash via landfills.

India

Landfilling is currently the major method of municipal waste disposal in India. India also has Asia's largest dumping ground in Deonar, Mumbai. However issues frequently arise due alarming growth rate of landfills and poor management by authorities. On and under surface fires have been commonly seen in the Indian landfills over the last few years.

United Kingdom

Landfilling practices in the UK have had to change in recent years to meet the challenges of the European Landfill Directive. The UK now imposes landfill tax upon biodegradable waste which is put into landfills. In addition to this the Landfill Allowance Trading Scheme has been established for local authorities to trade landfill quotas in England. A different system operates in Wales where authorities cannot 'trade' amongst themselves, but have allowances known as the Landfill Allowance Scheme.

United States

U.S. landfills are regulated by each state's environmental agency, which establishes minimum guidelines; however, none of these standards may fall below those set by the United States Environmental Protection Agency (EPA).

Permitting a landfill generally takes between five and seven years, costs millions of dollars and requires rigorous siting, engineering and environmental studies and demonstrations to ensure local environmental and safety concerns are satisfied.

Types

Microbial topics

The status of a landfill's microbial community may determine its digestive efficiency.

Bacteria that digest plastic have been found in landfills.

Reclaiming materials

One can treat landfills as a viable and abundant source of materials and energy. In third-world countries, waste pickers often scavenge for still-usable materials. In commercial contexts, companies have also discovered landfill sites, and many have begun harvesting materials and energy. Well-known examples include gas-recovery facilities. Other commercial facilities include waste incinerators which have built-in material recovery. This material recovery is possible through the use of filters (electro filter, active-carbon and potassium filter, quench, HCl-washer, SO2-washer, bottom ash-grating, etc.).

Alternatives

In addition to waste reduction and recycling strategies, there are various alternatives to landfills, including waste-to-energy incineration, anaerobic digestion, composting, mechanical biological treatment, pyrolysis and plasma arc gasification. Depending on local economics and incentives, these can be made more financially attractive than landfills.

Restrictions

Countries including Germany, Austria, Sweden, Denmark, Belgium, the Netherlands, and Switzerland, have banned the disposal of untreated waste in landfills. In these countries, only certain hazardous wastes, fly ashes from incineration or the stabilized output of mechanical biological treatment plants may still be deposited.

Soil contamination

From Wikipedia, the free encyclopedia
 
Excavation showing soil contamination at a disused gasworks in England.

Soil contamination, soil pollution, or land pollution as a part of land degradation is caused by the presence of xenobiotic (human-made) chemicals or other alteration in the natural soil environment. It is typically caused by industrial activity, agricultural chemicals or improper disposal of waste. The most common chemicals involved are petroleum hydrocarbons, polynuclear aromatic hydrocarbons (such as naphthalene and benzo(a)pyrene), solvents, pesticides, lead, and other heavy metals. Contamination is correlated with the degree of industrialization and intensity of chemical substance. The concern over soil contamination stems primarily from health risks, from direct contact with the contaminated soil, vapour from the contaminants, or from secondary contamination of water supplies within and underlying the soil. Mapping of contaminated soil sites and the resulting cleanups are time-consuming and expensive tasks, and require expertise in geology, hydrology, chemistry, computer modeling, and GIS in Environmental Contamination, as well as an appreciation of the history of industrial chemistry.

In North America and Western Europe the extent of contaminated land is best known, with many of countries in these areas having a legal framework to identify and deal with this environmental problem. Developing countries tend to be less tightly regulated despite some of them having undergone significant industrialization.

Causes

Soil pollution can be caused by the following (non-exhaustive list)

The most common chemicals involved are petroleum hydrocarbons, solvents, pesticides, lead, and other heavy metals.

Any activity that leads to other forms of soil degradation (erosion, compaction, etc.) may indirectly worsen the contamination effects in that soil remediation becomes more tedious.

Historical deposition of coal ash used for residential, commercial, and industrial heating, as well as for industrial processes such as ore smelting, were a common source of contamination in areas that were industrialized before about 1960. Coal naturally concentrates lead and zinc during its formation, as well as other heavy metals to a lesser degree. When the coal is burned, most of these metals become concentrated in the ash (the principal exception being mercury). Coal ash and slag may contain sufficient lead to qualify as a "characteristic hazardous waste", defined in the US as containing more than 5 mg/l of extractable lead using the TCLP procedure. In addition to lead, coal ash typically contains variable but significant concentrations of polynuclear aromatic hydrocarbons (PAHs; e.g., benzo(a)anthracene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, indeno(cd)pyrene, phenanthrene, anthracene, and others). These PAHs are known human carcinogens and the acceptable concentrations of them in soil are typically around 1 mg/kg. Coal ash and slag can be recognised by the presence of off-white grains in soil, gray heterogeneous soil, or (coal slag) bubbly, vesicular pebble-sized grains.

Treated sewage sludge, known in the industry as biosolids, has become controversial as a "fertilizer". As it is the byproduct of sewage treatment, it generally contains more contaminants such as organisms, pesticides, and heavy metals than other soil.

In the European Union, the Urban Waste Water Treatment Directive allows sewage sludge to be sprayed onto land. The volume is expected to double to 185,000 tons of dry solids in 2005. This has good agricultural properties due to the high nitrogen and phosphate content. In 1990/1991, 13% wet weight was sprayed onto 0.13% of the land; however, this is expected to rise 15 fold by 2005. Advocates say there is a need to control this so that pathogenic microorganisms do not get into water courses and to ensure that there is no accumulation of heavy metals in the top soil.

Pesticides and herbicides

A pesticide is a substance used to kill a pest. A pesticide may be a chemical substance, biological agent (such as a virus or bacteria), antimicrobial, disinfectant or device used against any pest. Pests include insects, plant pathogens, weeds, mollusks, birds, mammals, fish, nematodes (roundworms) and microbes that compete with humans for food, destroy property, spread or are a vector for disease or cause a nuisance. Although there are benefits to the use of pesticides, there are also drawbacks, such as potential toxicity to humans and other organisms.

Herbicides are used to kill weeds, especially on pavements and railways. They are similar to auxins and most are biodegradable by soil bacteria. However, one group derived from trinitrotoluene (2:4 D and 2:4:5 T) have the impurity dioxin, which is very toxic and causes fatality even in low concentrations. Another herbicide is Paraquat. It is highly toxic but it rapidly degrades in soil due to the action of bacteria and does not kill soil fauna.

Insecticides are used to rid farms of pests which damage crops. The insects damage not only standing crops but also stored ones and in the tropics it is reckoned that one third of the total production is lost during food storage. As with fungicides, the first insecticides used in the nineteenth century were inorganic e.g. Paris Green and other compounds of arsenic. Nicotine has also been used since the late eighteenth century.

There are now two main groups of synthetic insecticides –

1. Organochlorines include DDT, Aldrin, Dieldrin and BHC. They are cheap to produce, potent and persistent. DDT was used on a massive scale from the 1930s, with a peak of 72,000 tonnes used 1970. Then usage fell as the harmful environmental effects were realized. It was found worldwide in fish and birds and was even discovered in the snow in the Antarctic. It is only slightly soluble in water but is very soluble in the bloodstream. It affects the nervous and endocrine systems and causes the eggshells of birds to lack calcium causing them to be easily breakable. It is thought to be responsible for the decline of the numbers of birds of prey like ospreys and peregrine falcons in the 1950s – they are now recovering. As well as increased concentration via the food chain, it is known to enter via permeable membranes, so fish get it through their gills. As it has low water solubility, it tends to stay at the water surface, so organisms that live there are most affected. DDT found in fish that formed part of the human food chain caused concern, but the levels found in the liver, kidney and brain tissues was less than 1 ppm and in fat was 10 ppm, which was below the level likely to cause harm. However, DDT was banned in the UK and the United States to stop the further buildup of it in the food chain. U.S. manufacturers continued to sell DDT to developing countries, who could not afford the expensive replacement chemicals and who did not have such stringent regulations governing the use of pesticides.

2. Organophosphates, e.g. parathion, methyl parathion and about 40 other insecticides are available nationally. Parathion is highly toxic, methyl-parathion is less so and Malathion is generally considered safe as it has low toxicity and is rapidly broken down in the mammalian liver. This group works by preventing normal nerve transmission as cholinesterase is prevented from breaking down the transmitter substance acetylcholine, resulting in uncontrolled muscle movements.

Agents of war

The disposal of munitions, and a lack of care in manufacture of munitions caused by the urgency of production, can contaminate soil for extended periods. There is little published evidence on this type of contamination largely because of restrictions placed by governments of many countries on the publication of material related to war effort. However, mustard gas stored during World War II has contaminated some sites for up to 50 years and the testing of Anthrax as a potential biological weapon contaminated the whole island of Gruinard.

Health effects

Contaminated or polluted soil directly affects human health through direct contact with soil or via inhalation of soil contaminants which have vaporized; potentially greater threats are posed by the infiltration of soil contamination into groundwater aquifers used for human consumption, sometimes in areas apparently far removed from any apparent source of above ground contamination. This tends to result in the development of pollution-related diseases.

Health consequences from exposure to soil contamination vary greatly depending on pollutant type, pathway of attack and vulnerability of the exposed population. Chronic exposure to chromium, lead and other metals, petroleum, solvents, and many pesticide and herbicide formulations can be carcinogenic, can cause congenital disorders, or can cause other chronic health conditions. Industrial or man-made concentrations of naturally occurring substances, such as nitrate and ammonia associated with livestock manure from agricultural operations, have also been identified as health hazards in soil and groundwater.

Chronic exposure to benzene at sufficient concentrations is known to be associated with higher incidence of leukemia. Mercury and cyclodienes are known to induce higher incidences of kidney damage and some irreversible diseases. PCBs and cyclodienes are linked to liver toxicity. Organophosphates and carbonates can induce a chain of responses leading to neuromuscular blockage. Many chlorinated solvents induce liver changes, kidney changes and depression of the central nervous system. There is an entire spectrum of further health effects such as headache, nausea, fatigue, eye irritation and skin rash for the above cited and other chemicals. At sufficient dosages a large number of soil contaminants can cause death by exposure via direct contact, inhalation or ingestion of contaminants in groundwater contaminated through soil.

The Scottish Government has commissioned the Institute of Occupational Medicine to undertake a review of methods to assess risk to human health from contaminated land. The overall aim of the project is to work up guidance that should be useful to Scottish Local Authorities in assessing whether sites represent a significant possibility of significant harm (SPOSH) to human health. It is envisaged that the output of the project will be a short document providing high level guidance on health risk assessment with reference to existing published guidance and methodologies that have been identified as being particularly relevant and helpful. The project will examine how policy guidelines have been developed for determining the acceptability of risks to human health and propose an approach for assessing what constitutes unacceptable risk in line with the criteria for SPOSH as defined in the legislation and the Scottish Statutory Guidance.

Ecosystem effects

Not unexpectedly, soil contaminants can have significant deleterious consequences for ecosystems. There are radical soil chemistry changes which can arise from the presence of many hazardous chemicals even at low concentration of the contaminant species. These changes can manifest in the alteration of metabolism of endemic microorganisms and arthropods resident in a given soil environment. The result can be virtual eradication of some of the primary food chain, which in turn could have major consequences for predator or consumer species. Even if the chemical effect on lower life forms is small, the lower pyramid levels of the food chain may ingest alien chemicals, which normally become more concentrated for each consuming rung of the food chain. Many of these effects are now well known, such as the concentration of persistent DDT materials for avian consumers, leading to weakening of egg shells, increased chick mortality and potential extinction of species.

Effects occur to agricultural lands which have certain types of soil contamination. Contaminants typically alter plant metabolism, often causing a reduction in crop yields. This has a secondary effect upon soil conservation, since the languishing crops cannot shield the Earth's soil from erosion. Some of these chemical contaminants have long half-lives and in other cases derivative chemicals are formed from decay of primary soil contaminants.

Cleanup options

Cleanup or environmental remediation is analyzed by environmental scientists who utilize field measurement of soil chemicals and also apply computer models (GIS in Environmental Contamination) for analyzing transport and fate of soil chemicals. Various technologies have been developed for remediation of oil-contaminated soil and sediments.  There are several principal strategies for remediation:

  • Excavate soil and take it to a disposal site away from ready pathways for human or sensitive ecosystem contact. This technique also applies to dredging of bay muds containing toxins.
  • Aeration of soils at the contaminated site (with attendant risk of creating air pollution)
  • Thermal remediation by introduction of heat to raise subsurface temperatures sufficiently high to volatize chemical contaminants out of the soil for vapor extraction. Technologies include ISTD, electrical resistance heating (ERH), and ET-DSP.
  • Bioremediation, involving microbial digestion of certain organic chemicals. Techniques used in bioremediation include landfarming, biostimulation and bioaugmentating soil biota with commercially available microflora.
  • Extraction of groundwater or soil vapor with an active electromechanical system, with subsequent stripping of the contaminants from the extract.
  • Containment of the soil contaminants (such as by capping or paving over in place).
  • Phytoremediation, or using plants (such as willow) to extract heavy metals.
  • Mycoremediation, or using fungus to metabolize contaminants and accumulate heavy metals.
  • Remediation of oil contaminated sediments with self-collapsing air microbubbles.
  • Surfactant leaching

By country

Various national standards for concentrations of particular contaminants include the United States EPA Region 9 Preliminary Remediation Goals (U.S. PRGs), the U.S. EPA Region 3 Risk Based Concentrations (U.S. EPA RBCs) and National Environment Protection Council of Australia Guideline on Investigation Levels in Soil and Groundwater.

People's Republic of China

The immense and sustained growth of the People's Republic of China since the 1970s has exacted a price from the land in increased soil pollution. The Ministry of Ecology and Environment believes it to be a threat to the environment, to food safety and to sustainable agriculture. According to a scientific sampling, 150 million mu (100,000 square kilometres) of China's cultivated land have been polluted, with contaminated water being used to irrigate a further 32.5 million mu (21,670 square kilometres) and another 2 million mu (1,300 square kilometres) covered or destroyed by solid waste. In total, the area accounts for one-tenth of China's cultivatable land, and is mostly in economically developed areas. An estimated 12 million tonnes of grain are contaminated by heavy metals every year, causing direct losses of 20 billion yuan ($2.57 billion USD).

European Union

According to the received data from Member states, in the European Union the number of estimated potential contaminated sites is more than 2.5 million and the identified contaminated sites around 342 thousand. Municipal and industrial wastes contribute most to soil contamination (38%), followed by the industrial/commercial sector (34%). Mineral oil and heavy metals are the main contaminants contributing around 60% to soil contamination. In terms of budget, the management of contaminated sites is estimated to cost around 6 billion Euros (€) annually.

United Kingdom

Generic guidance commonly used in the United Kingdom are the Soil Guideline Values published by the Department for Environment, Food and Rural Affairs (DEFRA) and the Environment Agency. These are screening values that demonstrate the minimal acceptable level of a substance. Above this there can be no assurances in terms of significant risk of harm to human health. These have been derived using the Contaminated Land Exposure Assessment Model (CLEA UK). Certain input parameters such as Health Criteria Values, age and land use are fed into CLEA UK to obtain a probabilistic output.

Guidance by the Inter Departmental Committee for the Redevelopment of Contaminated Land (ICRCL) has been formally withdrawn by DEFRA, for use as a prescriptive document to determine the potential need for remediation or further assessment.

The CLEA model published by DEFRA and the Environment Agency (EA) in March 2002 sets a framework for the appropriate assessment of risks to human health from contaminated land, as required by Part IIA of the Environmental Protection Act 1990. As part of this framework, generic Soil Guideline Values (SGVs) have currently been derived for ten contaminants to be used as "intervention values". These values should not be considered as remedial targets but values above which further detailed assessment should be considered; see Dutch standards.

Three sets of CLEA SGVs have been produced for three different land uses, namely

  • residential (with and without plant uptake)
  • allotments
  • commercial/industrial

It is intended that the SGVs replace the former ICRCL values. The CLEA SGVs relate to assessing chronic (long term) risks to human health and do not apply to the protection of ground workers during construction, or other potential receptors such as groundwater, buildings, plants or other ecosystems. The CLEA SGVs are not directly applicable to a site completely covered in hardstanding, as there is no direct exposure route to contaminated soils.

To date, the first ten of fifty-five contaminant SGVs have been published, for the following: arsenic, cadmium, chromium, lead, inorganic mercury, nickel, selenium ethyl benzene, phenol and toluene. Draft SGVs for benzene, naphthalene and xylene have been produced but their publication is on hold. Toxicological data (Tox) has been published for each of these contaminants as well as for benzo[a]pyrene, benzene, dioxins, furans and dioxin-like PCBs, naphthalene, vinyl chloride, 1,1,2,2 tetrachloroethane and 1,1,1,2 tetrachloroethane, 1,1,1 trichloroethane, tetrachloroethene, carbon tetrachloride, 1,2-dichloroethane, trichloroethene and xylene. The SGVs for ethyl benzene, phenol and toluene are dependent on the soil organic matter (SOM) content (which can be calculated from the total organic carbon (TOC) content). As an initial screen the SGVs for 1% SOM are considered to be appropriate.

Canada

As of February 2021, there are a total of 2,500 plus contaminated sites in Canada. One infamous contaminated sited is located near a nickel-copper smelting site in Sudbury, Ontario. A study investigating the heavy metal pollution in the vicinity of the smelter reveals that elevated levels of nickel and copper were found in the soil; values going as high as 5,104ppm Ni, and 2,892 ppm Cu within a 1.1km range of the smelter location. Other metals were also found in the soil; such metals include iron, cobalt, and silver. Furthermore, upon examining the different vegetation surrounding the smelter it was evident that they too had been affected; the results show that the plants contained nickel, copper and aluminium as a result of soil contamination. 

India

In March 2009, the issue of Uranium poisoning in Punjab attracted press coverage. It was alleged to be caused by fly ash ponds of thermal power stations, which reportedly lead to severe birth defects in children in the Faridkot and Bhatinda districts of Punjab. The news reports claimed the uranium levels were more than 60 times the maximum safe limit. In 2012, the Government of India confirmed that the ground water in Malwa belt of Punjab has uranium metal that is 50% above the trace limits set by the United Nations' World Health Organization (WHO). Scientific studies, based on over 1000 samples from various sampling points, could not trace the source to fly ash and any sources from thermal power plants or industry as originally alleged. The study also revealed that the uranium concentration in ground water of Malwa district is not 60 times the WHO limits, but only 50% above the WHO limit in 3 locations. This highest concentration found in samples was less than those found naturally in ground waters currently used for human purposes elsewhere, such as Finland. Research is underway to identify natural or other sources for the uranium.

History of measurement

From Wikipedia, the free encyclopedia
https://en.wikipedia.org/wiki/History_of_measurement 
 
Detail of a cubit rod in the Museo Egizio of Turin

The earliest recorded systems of weights and measures originate in the 3rd or 4th millennium BC. Even the very earliest civilizations needed measurement for purposes of agriculture, construction and trade. Early standard units might only have applied to a single community or small region, with every area developing its own standards for lengths, areas, volumes and masses. Often such systems were closely tied to one field of use, so that volume measures used, for example, for dry grains were unrelated to those for liquids, with neither bearing any particular relationship to units of length used for measuring cloth or land. With development of manufacturing technologies, and the growing importance of trade between communities and ultimately across the Earth, standardized weights and measures became critical. Starting in the 18th century, modernized, simplified and uniform systems of weights and measures were developed, with the fundamental units defined by ever more precise methods in the science of metrology. The discovery and application of electricity was one factor motivating the development of standardized internationally applicable units.

Sources of information

The comparison of the dimensions of buildings with the descriptions of contemporary writers is another source of information. An interesting example of this is the comparison of the dimensions of the Greek Parthenon with the description given by Plutarch from which a fairly accurate idea of the size of the Attic foot is obtained. Because of the comparative volume of artifacts and documentation, we know much more about the state-sanctioned measures of large, advanced societies than we do about those of smaller societies or about the informal measures that often coexisted with official ones throughout history. In some cases, we have only plausible theories and we must sometimes select the interpretation to be given to the evidence.

It is possible to group official measurement systems for large societies into historical systems that are relatively stable over time, including: the Babylonian system, the Egyptian system, the Phileterian system of the Ptolemaic age, the Olympic system of Greece, the Roman system, the British system, and the metric system.

Earliest known measurement systems

The earliest known uniform systems of weights and measures seem all to have been created at some time in the 4th and 3rd millennia BC among the ancient peoples of Egypt, Mesopotamia and the Indus Valley, and perhaps also Elam (in Iran) as well.

Early Babylonian and Egyptian records and the Hebrew Bible indicate that length was first measured with the forearm, hand, or finger and that time was measured by the periods of the sun, moon, and other heavenly bodies. When it was necessary to compare the capacities of containers such as gourds or clay or metal vessels, they were filled with plant seeds which were then counted to measure the volumes. When means for weighing were invented, seeds and stones served as standards. For instance, the carat, still used as a unit for gems, was derived from the carob seed.

History of units

Units of length

The Egyptian cubit, the Indus Valley units of length referred to above and the Mesopotamian cubit were used in the 3rd millennium BC and are the earliest known units used by ancient peoples to measure length. The units of length used in ancient India included the dhanus, or dhanush (bow), the krosa (cry, or cow-call) and the yojana (stage).

The common cubit was the length of the forearm from the elbow to the tip of the middle finger. It was divided into the span of the hand or the length between the tip of little finger to the tip of the thumb (one-half cubit), the palm or width of the hand (one sixth), and the digit or width of the middle finger (one twenty-fourth). The Royal Cubit, which was a standard cubit enhanced by an extra palm—thus 7 palms or 28 digits long—was used in constructing buildings and monuments and in surveying in ancient Egypt. The inch, foot, and yard evolved from these units through a complicated transformation not yet fully understood. Some believe they evolved from cubic measures; others believe they were simple proportions or multiples of the cubit. In whichever case, the Greeks and Romans inherited the foot from the Egyptians. The Roman foot (~296 mm) was divided into both 12 unciae (inches) (~24.7 mm) and 16 digits (~18.5 mm). The Romans also introduced the mille passus (1000 paces) or double steps, the pace being equal to five Roman feet (~1480 mm). The Roman mile of 5000 feet (1480 m) was introduced into England during the occupation. Queen Elizabeth I (reigned from 1558 to 1603) changed, by statute, the mile to 5280 feet (~1609 m) or 8 furlongs, a furlong being 40 rod (unit)s (~201 m) of 5.5 yards (~5.03 m) each.

The introduction of the yard (0.9144 m) as a unit of length came later, but its origin is not definitely known. Some believe the origin was the double cubit, others believe that it originated from cubic measure. Whatever its origin, the early yard was divided by the binary method into 2, 4, 8, and 16 parts called the half-yard, span, finger, and nail. The association of the yard with the "gird" or circumference of a person's waist or with the distance from the tip of the nose to the end of the thumb of King Henry I (reigned 1100–1135) are probably standardizing actions, since several yards were in use in Britain. There were also Rods, Poles and Perches for measurements of length. The following table lists the equivalents.

components unit
12 lines 1 inch
12 inches 1 foot
3 feet 1 yard
1760 yards 1 mile
36 inches 1 yard
440 yards quarter-mile
880 yards half-mile
100 links 1 chain
10 chains 1 furlong
8 furlongs 1 mile
4 inches 1 hand
22 yards 1 chain
5.5 yards 1 rod, pole or perch
4 poles 1 chain
40 poles 1 furlong

Units of mass

The grain was the earliest unit of mass and is the smallest unit in the apothecary, avoirdupois, Tower, and troy systems. The early unit was a grain of wheat or barleycorn used to weigh the precious metals silver and gold. Larger units preserved in stone standards were developed that were used as both units of mass and of monetary currency. The pound was derived from the mina (unit) used by ancient civilizations. A smaller unit was the shekel, and a larger unit was the talent. The magnitude of these units varied from place to place. The Babylonians and Sumerians had a system in which there were 60 shekels in a mina and 60 minas in a talent. The Roman talent consisted of 100 libra (pound) which were smaller in magnitude than the mina. The troy pound (~373.2 g) used in England and the United States for monetary purposes, like the Roman pound, was divided into 12 ounces, but the Roman uncia (ounce) was smaller. The carat is a unit for measuring gemstones that had its origin in the carob seed, which later was standardized at 1/144 ounce and then 0.2 gram.

Goods of commerce were originally traded by number or volume. When weighing of goods began, units of mass based on a volume of grain or water were developed. The diverse magnitudes of units having the same name, which still appear today in our dry and liquid measures, could have arisen from the various commodities traded. The larger avoirdupois pound for goods of commerce might have been based on volume of water which has a higher bulk density than grain.

The stone, quarter, hundredweight, and ton were larger units of mass used in Britain. Today only the stone continues in customary use for measuring personal body weight. The present stone is 14 pounds (~6.35 kg), but an earlier unit appears to have been 16 pounds (~7.25 kg). The other units were multiples of 2, 8, and 160 times the stone, or 28, 112, and 2240 pounds (~12.7 kg, 50.8 kg, 1016 kg), respectively. The hundredweight was approximately equal to two talents. The ton of 2240 pounds is called the "long ton". The "short ton" is equal to 2000 pounds (~907 kg). A tonne (t) is equal to 1000 kg.

Units of time and angle

The division of the circle into 360 degrees and the day into hours, minutes, and seconds can be traced to the Babylonians who had sexagesimal system of numbers. The 360 degrees may have been related to a year of 360 days. Many other systems of measurement divided the day differently -- counting hours, decimal time, etc. Other calendars divided the year differently.

Forerunners of the metric system

Decimal numbers are an essential part of the metric system, with only one base unit and multiples created on the decimal base, the figures remain the same. This simplifies calculations. Although the Indians used decimal numbers for mathematical computations, it was Simon Stevin who in 1585 first advocated the use of decimal numbers for everyday purposes in his booklet De Thiende (old Dutch for 'the tenth'). He also declared that it would only be a matter of time before decimal numbers were used for currencies and measurements. His notation for decimal fractions was clumsy, but this was overcome with the introduction of the decimal point, generally attributed to Bartholomaeus Pitiscus who used this notation in his trigonometrical tables (1595).

In 1670, Gabriel Mouton published a proposal that was in essence similar to Wilkins' proposal, except that his base unit of length would have been 1/1000 of a minute of arc (about 1.852 m) of geographical latitude. He proposed calling this unit the virga. Rather than using different names for each unit of length, he proposed a series of names that had prefixes, rather like the prefixes found in SI.

In 1790, Thomas Jefferson submitted a report to the United States Congress in which he proposed the adoption of a decimal system of coinage and of weights and measures. He proposed calling his base unit of length a "foot" which he suggested should be either 310 or 13 of the length of a pendulum that had a period of one second – that is 310 or 13 of the "standard" proposed by Wilkins over a century previously. This would have equated to 11.755 English inches (29.8 cm) or 13.06 English inches (33.1 cm). Like Wilkins, the names that he proposed for multiples and subunits of his base units of measure were the names of units of measure that were in use at the time. The great interest in geodesy during this era, and the measurement system ideas that developed, influenced how the continental US was surveyed and parceled. The story of how Jefferson's full vision for the new measurement system came close to displacing the Gunter chain and the traditional acre, but ended up not doing so, is explored in Andro Linklater's Measuring America.

Metric conversion

The metric system was first described in 1668 and officially adopted by France in 1799. Over nineteenth and twentieth centuries, it became the dominant system worldwide, although several countries, including the United States, China, and the United Kingdom continue to use their customary units. Among the numerous customary systems, many have been adapted to become an integer multiple of a related metric unit: The Scandinavian mile is now defined as 10 km, the Chinese jin is now defined as 0.5 kg, and the Dutch ons is now defined as 100 g.

Streaming algorithm

From Wikipedia, the free encyclopedia https://en.wikipedia.org/wiki/Streaming_algorithm ...