Search This Blog

Friday, August 26, 2022

Politics of climate change

From Wikipedia, the free encyclopedia
 
Heads of delegations at the 2015 United Nations Paris conference.

The politics of climate change results from different perspectives on how to respond to climate change. Global warming is driven largely by the emissions of greenhouse gases due to human economic activity, especially the burning of fossil fuels, certain industries like cement and steel production, and land use for agriculture and forestry. Since the Industrial Revolution, fossil fuels have provided the main source of energy for economic and technological development. The centrality of fossil fuels and other carbon-intensive industries has resulted in much resistance to climate friendly policy, despite widespread scientific consensus that such policy is necessary.

Climate change first emerged as a political issue in the 1970s. Efforts to mitigate climate change have been prominent on the international political agenda since the 1990s, and are also increasingly addressed at national and local level. Climate change is a complex global problem. Greenhouse gas (GHG) emissions contribute to global warming across the world, regardless of where the emissions originate. Yet the impact of global warming varies widely depending on how vulnerable a location or economy is to its effects. Global warming is on the whole having negative impact, which is predicted to worsen as heating increases. Ability to benefit from both fossil fuels and renewable energy sources vary substantially from nation to nation.

Different responsibilities, benefits and climate related threats faced by the world's nations contributed to early climate change conferences producing little beyond general statements of intent to address the problem, and non-binding commitments from the developed countries to reduce emissions. In the 21st century, there has been increased attention to mechanisms like climate finance in order for vulnerable nations to adapt to climate change. In some nations and local jurisdictions, climate friendly policies have been adopted that go well beyond what was committed to at international level. Yet local reductions in GHG emission that such policies achieve will not slow global warming unless the overall volume of GHG emission declines across the planet.

Since entering the 2020s, the feasibility of replacing energy from fossil fuel with renewable energy sources significantly increased, with some countries now generating almost all their electricity from renewables. Public awareness of the climate change threat has risen, in larger part due to social movement led by youth and visibility of the impacts of climate change, such as extreme weather events and flooding caused by sea level rise. Many surveys show a growing proportion of voters support tackling climate change as a high priority, making it easier for politicians to commit to policies that include climate action. The COVID-19 pandemic and economic recession lead to widespread calls for a "green recovery", with some political contexts like the European Union successfully integrating climate action into policy change. Outright climate change denial had become a much less influential force by 2019, where opposition has pivoted to strategies of encouraging delay or inaction.

Effects of climate change

Global heating is driven by human emissions of greenhouse gases (GHG). As of 2021, average temperatures have already risen about 1.2 °C above pre-industrial levels. This rise has already contributed to the extinction of numerous plants and animals and to many thousands of human deaths. At the 2015 Paris conference, nations agreed to make efforts to keep further rises well below 2 °C, and to try to limit them to 1.5 °C. Specific actions to achieve this have not yet been decided. With existing policies and commitments, global warming is projected to reach about 3 °C by 2100. The impact of global warming could be worsened by the possible triggering of irreversible climate tipping points.

In the worst case, feedback from mutually reinforcing cascading tipping points could lead to runaway climate change beyond human ability to control; though this is considered highly unlikely. Considerable economic disruption is predicted even if political agreement is strong enough to achieve the RCP 2.6 pathway, which is likely to keep warming between 1.5 °C and 2 °C. Among the risks of 2 °C warming are sea level rises that could devastate various Island nations, along with vulnerable countries and regions with much low-lying land, such as Bangladesh or Florida. A 3 °C rise would sharply increase occurrences of deadly wet-bulb temperatures, potentially leading to the deaths of tens of millions of people who live in the tropics, unless they are able to migrate or seek shelter in reliably air conditioned areas.

History

The history of climate change policy and politics refers to the continuing history of political actions, policies, trends, controversies and activist efforts as they pertain to the issue of global warming and other environmental anomalies. Dryzek, Norgaard, and Schlosberg suggest that critical reflection on the history of climate policy is necessary because it provides 'ways to think about one of the most difficult issues we human beings have brought upon ourselves in our short life on the planet’.

Climate change emerged as a political issue in the 1970s, where activist and formal efforts were taken to ensure environmental crises were addressed on a global scale. International policy regarding climate change has focused on cooperation and the establishment of international guidelines to address global warming. The United Nations Framework Convention on Climate Change (UNFCCC) is a largely accepted international agreement that has continuously developed to meet new challenges.

Domestic policy on climate change has focused on both establishing internal measures to reduce greenhouse gas emissions and incorporating international guidelines into domestic law.

In the late 20th and 21st century, climate change policy moved away from attempts to mitigate the impact of global warming and towards adapting to unavoidable changes to the human environment. There has also been a shift towards vulnerability based policy for those most impacted by environmental anomalies. Over the history of climate policy, concerns have been raised about the treatment of developing nations and a lack of gender specific action.

Policy debate

Like all policy debates, the political debate on climate change is fundamentally about action. Various distinct arguments underpin the politics of climate change - such as different assessments of the urgency of the threat, and on the feasibility, advantages and disadvantages of various responses. But essentially, these all relate to potential responses to climate change. To date, a consensual agreement on a credible climate-change framework internationally is still in the works.

The statements that form political arguments can be divided into two types: positive and normative statements. Positive statements can generally be clarified or refuted by careful definition of terms, and scientific evidence. Whereas normative statements about what one "ought" to do often relate at least partly to morality, and are essentially a matter of judgement. Experience has indicated that better progress is often made at debates if participants attempt to disentangle the positive and normative parts of their arguments, reaching agreement on the positive statements first. In the early stages of a debate, the normative positions of participants can be strongly influenced by perceptions of the best interests of whatever constituency they represent. In achieving exceptional progress at the 2015 Paris conference, Christiana Figueres and others noted it was helpful that key participants were able to move beyond a competitive mindset concerning competing interests, to normative statements that reflected a shared abundance based collaborative mindset.

Actions in response to climate change can be divided into three classes: mitigation – actions to reduce greenhouse gas emissions, adaptation – actions to defend against the negative results of global warming, and climate engineering – direct human intervention in the climate, aimed at reducing average global temperature.

Most 20th century international debate on climate change focused almost entirely on mitigation. It was sometimes considered defeatist to pay much attention to adaptation. Also, compared to mitigation, adaptation is more a local matter, with different parts of the world facing vastly different threats and opportunities from climate change. By the early 21st century, while mitigation still receives most attention in political debates, it is no longer the sole focus. Some degree of adaptation is now widely considered essential, and is discussed internationally at least at high level, though which specific actions to take remain mostly a local matter. A commitment to provide $100 billion per year worth of funding to developing countries was made at the 2009 Copenhagen Summit. At Paris, it was clarified that allocation of the funding should involve a balanced split between adaptation and mitigation, though as of December 2020, not all funding had been provided, and what had been delivered was going mainly to mitigation projects. By 2019, possibilities for geoengineering were also increasingly being discussed, and were expected to become more prominent in future debates.

Political debate concerning which specific courses of action for achieving effective mitigation tends to vary depending on the scale of governance concerned. Different considerations apply for international debate, compared with national and municipal level discussion. In the 1990s, when climate change first became prominent on the political agenda, there was optimism that the problem could be successfully tackled. The then recent signing of the 1987 Montreal Protocol to protect the ozone layer had indicated that the world was able to act collectively to address a threat warned about by scientists, even when it was not yet causing significant harm to humans. Yet by the early 2000s, GHG emissions had continued to rise, with little sign of agreement to penalise emitters or reward climate friendly behaviour. It had become clear that achieving global agreement for effective action to limit global warming would be much more challenging. Some politicians, such as Arnold Schwarzenegger with his slogan "terminate pollution", say that activists should generate optimism by focusing on the health co-benefits of climate action.

Multilateral

Global carbon dioxide emissions by jurisdiction (as of 2015)

Climate change became a fixture on the global political agenda in the early 1990s, with United Nations Climate Change conferences set to run yearly. These annual events are also called Conferences of the Parties (COPs). Major landmark COPs were the 1997 Kyoto Protocol, the 2009 Copenhagen Summit and the 2015 Paris conference. Kyoto was initially considered promising, yet by the early 2000s its results had proved disappointing. Copenhagen saw a major attempt to move beyond Kyoto with a much stronger package of commitments, yet largely failed. Paris was widely considered successful, yet how effective it will be at reducing long term global warming remains to be seen.

At international level, there are three broad approaches to emissions reduction that nations can attempt to negotiate. Firstly, the adoption of emissions reductions targets. Secondly, setting a carbon price. Lastly, creating largely voluntary set of processes to encourage emission reduction, which include the sharing of information and progress reviews. These approaches are largely complementary, though at various conferences much of the focus has often been on a single approach. Until about 2010, international negotiations focused largely on emissions targets. The success of the Montreal treaty in reducing emissions that damaged the ozone layer suggested that targets could be effective. Yet in the case of greenhouse gas reductions, targets have not in general led to substantial cuts in emissions. Ambitious targets have usually not been met. Attempts to impose severe penalties that would incentivise more determined efforts to meet challenging targets, have always been blocked by at least one or two nations.

In the 21st century, there is widespread agreement that a carbon price is the most effective way to reduce emissions, at least in theory. Generally though, nations have been reluctant to adopt a high carbon price, or in most cases any price at all. One of the main reasons for this reluctance is the problem of carbon leakage – the phenomena where activities producing GHG emissions are moved out of the jurisdiction that imposes the carbon price thus depriving the jurisdiction of jobs & revenue, and to no benefit, as the emissions will be released elsewhere. Nonetheless, the percentage of the worlds' emissions that are covered by a carbon price rose from 5% in 2005, to 15% by 2019, and should reach over 40% once China's carbon price comes fully into force. Existing carbon price regimes have been implemented mostly independently by the European Union, nations and sub national jurisdictions acting autonomously.

The largely voluntary pledge and review system where states make their own plans for emissions reduction was introduced in 1991, but abandoned before the 1997 Kyoto treaty, where the focus was on securing agreement for "top down" emissions targets. The approach was revived at Copenhagen, and gained further prominence with the 2015 Paris Agreement, though pledges came to be called nationally determined contributions (NDCs). These are meant to be re-submitted in enhanced form every 5 years. How effective this approach is remains to be seen. Some countries submitted elevated NDCs in 2021, around the time of the Glasgow conference. Accounting rules for carbon trading were agreed at the 2021 Glasgow COP meeting.

Regional, National and sub national

The Climate Change Performance Index ranks countries by greenhouse gas emissions (40% of score), renewable energy (20%), energy use (20%), and climate policy (20%).
  High
  Medium
  Low
  Very Low

Policies to reduce GHG emissions are set by either national or sub national jurisdictions, or at regional level in the case of the European Union. Much of the emission reduction policies that have been put into place have been beyond those required by international agreements. Examples include the introduction of a carbon price by some individual US states, or Costa Rica reaching 99% electrical power generation by renewables in the 2010s.

Actual decisions to reduce emissions or deploy clean technologies are mostly not made by governments themselves, but by individuals, businesses and other organisations. Yet it is national and local governments that set policies to encourage climate friendly activity. Broadly these policies can be divided into four types: firstly, the implementation of a carbon price mechanism and other financial incentives; secondly prescriptive regulations, for example mandating that a certain percentage of electricity generation must be from renewables; thirdly, direct government spending on climate friendly activity or research; and fourthly, approaches based on information sharing, education and encouraging voluntary climate friendly behaviour. Local politics is sometimes combined with air pollution, for example the politics of creating low emission zones in cities may also aim to reduce carbon emissions from road transport.

Non-governmental actors

Individuals, businesses and NGOs can affect the politics of climate change both directly and indirectly. Mechanisms include individual rhetoric, aggregate expression of opinion by means of polls, and mass protests. Historically, a significant proportion of these protests have been against climate friendly policies. Since the 2000 UK fuel protests there have been dozens of protests across the world against fuel taxes or the ending of fuel subsidies. Since 2019 and the advent of the school strike and Extinction Rebellion, pro climate protests have become more prominent. Indirect channels for apolitical actors to effect the politics of climate change include funding or working on green technologies, and the fossil fuel divestment movement.

Special interests and lobbying by non-country actors

Global warming has attracted the attention of left-wing groups, as here with the Democratic Socialists of America.

There are numerous special interest groups, organizations, and corporations who have public and private positions on the multifaceted topic of global warming. The following is a partial list of the types of special interest parties that have shown an interest in the politics of global warming:

  • Fossil fuel companies: Traditional fossil fuel corporations stand to lose from stricter global warming regulations, though there are exceptions. The fact fossil fuel companies are engaged in energy trading might mean that their participation in trading schemes and other such mechanisms could give them a unique advantage, so it is unclear whether every traditional fossil fuel companies would always be against stricter global warming policies. As an example, Enron, a traditional gas pipeline company with a large trading desk heavily lobbied the United States government to regulate CO2: they thought that they would dominate the energy industry if they could be at the center of energy trading.
  • Farmers and agribusiness are an important lobby but vary in their views on effects of climate change on agriculture and greenhouse gas emissions from agriculture and, for example, the role of the EU Common Agricultural Policy.
  • Financial Institutions: Financial institutions generally support policies against global warming, particularly the implementation of carbon trading schemes and the creation of market mechanisms that associate a price with carbon. These new markets require trading infrastructures, which banking institutions can provide. Financial institutions are also well positioned to invest, trade and develop various financial instruments that they could profit from through speculative positions on carbon prices and the use of brokerage and other financial functions like insurance and derivative instruments.
  • Environmental groups: Environmental advocacy groups generally favor strict restrictions on CO2 emissions. Environmental groups, as activists, engage in raising awareness.
  • Renewable energy and energy efficiency companies: companies in wind, solar and energy efficiency generally support stricter global warming policies. They expect their share of the energy market to expand as fossil fuels are made more expensive through trading schemes or taxes.
  • Nuclear power companies: support and benefit from carbon pricing or subsidies of low-carbon energy production, as nuclear power produces minimal greenhouse gas emissions.
  • Electricity distribution companies: may lose from solar panels but benefit from electric vehicles.
  • Traditional retailers and marketers: traditional retailers, marketers, and the general corporations respond by adopting policies that resonate with their customers. If "being green" provides customer appeal, then they could undertake modest programs to please and better align with their customers. However, since the general corporation does not make a profit from their particular position, it is unlikely that they would strongly lobby either for or against a stricter global warming policy position.
  • Medics: often say that climate change and air pollution can be tackled together and so save millions of lives.
  • Information and communications technology companies: say their products help others combat climate change, tend to benefit from reductions in travel, and many purchase green electricity.

The various interested parties sometimes align with one another to reinforce their message, for example electricity companies fund the purchase of electric school buses to benefit medics by reducing the load on the health service whilst at the same time selling more electricity. Sometimes industries will fund specialty nonprofit organizations to raise awareness and lobby on their behest.

Collective action

Current climate politics are influenced by a number of social and political movements focused on different parts of building political will for climate action. This includes the climate justice movement, youth climate movement and movements to divest from fossil fuel industries.

Divestment movement

As of 2021, 1,300 institutions possessing 14.6 trillion dollars divested from the fossil fuel industry.

Fossil fuel divestment or fossil fuel divestment and investment in climate solutions is an attempt to reduce climate change by exerting social, political, and economic pressure for the institutional divestment of assets including stocks, bonds, and other financial instruments connected to companies involved in extracting fossil fuels.

Fossil fuel divestment campaigns emerged on campuses in the United States in 2011 with students urging their administrations to turn endowment investments in the fossil fuel industry into investments in clean energy and communities most impacted by climate change. In 2012, Unity College in Maine became the first institution of higher learning to divest its endowment from fossil fuels.

By 2015, fossil fuel divestment was reportedly the fastest growing divestment movement in history. In October 2021, a total of 1,485 institutions representing $39.2 trillion in assets worldwide had begun or committed to a divestment from fossil fuels.

Youth movement

Maximum number of school strikers per country:
  <1000 
  1000
  10000
  100000
  1000000+


School Strike for Climate (Swedish: Skolstrejk för klimatet), also known variously as Fridays for Future (FFF), Youth for Climate, Climate Strike or Youth Strike for Climate, is an international movement of school students who skip Friday classes to participate in demonstrations to demand action from political leaders to prevent climate change and for the fossil fuel industry to transition to renewable energy.

Publicity and widespread organising began after Swedish pupil Greta Thunberg staged a protest in August 2018 outside of the Swedish Riksdag (parliament), holding a sign that read "Skolstrejk för klimatet" ("School strike for climate").

A global strike on 15 March 2019 gathered more than one million strikers in 2,200 strikes organised in 125 countries. On 24 May 2019, in the second global strike, 1,600 protests across 150 countries drew hundreds of thousands of strikers. The May protests were timed to coincide with the 2019 European Parliament election.

The 2019 Global Week for Future was a series of 4,500 strikes across over 150 countries, focused around Friday 20 September and Friday 27 September. Likely the largest climate strikes in world history, the 20 September strikes gathered roughly 4 million protesters, many of them schoolchildren, including 1.4 million in Germany. On 27 September, an estimated two million people participated in demonstrations worldwide, including over one million protesters in Italy and several hundred thousand protesters in Canada.

Current outlook

Historical political attempts to agree on policies to limit global warming have largely failed. Commentators have expressed optimism that the 2020s can be more successful, due to various recent developments and opportunities that were not present during earlier periods. Other commentators have expressed warnings that there is now very little time to act in order to have any chance of keeping warming below 1.5 °C, or even to have a good chance of keeping global heating under 2 °C.

Opportunities

In the late 2010s, various developments conducive to climate friendly politics saw commentators express optimism that the 2020s might see good progress in addressing the threat of global heating.

Tipping point in public opinion

Greta Thunberg. Her Fridays for future movement has been influential in raising public awareness of the threat from global warming.

The year 2019 has been described as "the year the world woke up to climate change", driven by factors such growing recognition of the global warming threat resulting from recent extreme weather events, the Greta effect and the IPPC 1.5 °C report

In 2019, the secretary general of OPEC recognised the school strike movement as the greatest threat faced by the fossil fuel industry. According to Christiana Figueres, once about 3.5% of a population start participating in non violent protest, they are always successful in sparking political change, with the success of Greta Thunberg's Fridays for Future movement suggesting that reaching this threshold may be obtainable.

Reduced influence of climate change denial

By 2019, outright climate change denial had become a much less influential force than it had been in previous years. Reasons for this include the increasing frequency of extreme weather events, more effective communication on the part of climate scientists, and the Greta effect. As an example, in 2019 the Cato Institute closed down its climate shop.

Growth of renewable energy

Renewable energy is an inexhaustible source of naturally replenishing energy. The major renewable energy sources are wind, hydropower, solar, geothermal, and biomass. In 2020, renewable energy generated 29% of world electricity.

In the wake of the Paris Agreement, 168 countries have adopted national renewable energy targets and 115 counties as well, have national renewable energy targets. There are many different efforts used by these countries to help include renewable energy investments such as 102 countries have implemented tax credits, 101 countries include some sort of public investment, and 100 countries currently use tax reductions. The largest CO2 emitters tend to be industrialized countries like the US, China, UK, and India. These countries aren't implementing enough industrial policies (188) compared to deployment policies (more than 1,000). It's clear that these policies must be created in a way where they build upon each other, so they are most effective.

A group of women world leaders at the COP26 in Glasgow.

In November 2021, the 26th United Nation Conference of the Parties (COP26) took place in Glasgow, Scotland. Almost 200 nations agreed to accelerate the fight against climate change and commit to more effective climate pledges. Some of the new pledges included reforms on methane gas pollution, deforestation, and coal financing. Surprisingly, the US and China (the two largest carbon emitters) also both agreed to work together on efforts to prevent global warming from surpassing 1.5 degrees Celsius. Some scientists, politicians, and activist are arguing that enough hasn't been done at this summit and that we will still reach that 1.5 degree tipping point. An Independent report by Climate Action Tracker said the commitments were “lip service” and “we will emit roughly twice as much in 2030 as required for 1.5 degrees.”

As of 2020, the feasibility of replacing energy from fossil fuel with nuclear and especially renewable energy has much increased, with dozens of countries now generating more than half of their electricity from renewable sources.

Green recovery

Green recovery packages are proposed environmental, regulatory and fiscal reforms to build prosperity in the wake of an economic crisis, like the COVID-19 pandemic or the Global Financial Crisis. They pertain to fiscal measures that intend to recover economic growth while also positively benefitting the environment, including measures for renewable energy, efficient energy use, nature based solutions, sustainable transport, green innovation and green jobs, amongst others.

For green recovery in response to the COVID-19 pandemic, support has come from multiple political parties, governments, activists and academia across the European Union, the United Kingdom, the United States, and other countries. Following similar measures in response to the Global Financial Crisis, a key part of the packages is to ensure that actions to combat recession also combat climate change, including the reduction of coal, oil, and gas use, clean transport, renewable energy, eco-friendly buildings, and sustainable corporate or financial practices. These initiatives are supported by the United Nations and the Organisation for Economic Co-operation and Development. Several global initiatives have provided live tracking of national fiscal responses, including the Global Recovery Observatory (from Oxford University, the United Nations, and the IMF), the Energy Policy Tracker (from a consortium of six organisations), and the OECD's Green Recovery Tracker. The Global Recovery Observatory includes ~8,000 policies in 88 countries compared to ~1,700 for Energy Policy Tracker in 35 countries, and 1,500 in 44 countries for the OECD.

Dilineating between rescue and recovery investment, an Oxford University March 2021 analysis found that 18% of recovery investment and 2.5% of total spending had been green. In July 2021, the International Energy Agency supported that analysis, noting that only around 2% of economic bailout money worldwide was going to clean energy. According to a 2022 analysis of the $14tn that G20 countries have spent as economic stimulus, only about 6% of pandemic recovery spending has been allocated to areas that will also cut greenhouse-gas emissions, including electrifying vehicles, making buildings more energy efficient and installing renewables.

Challenges

Despite various promising conditions, commentators tend to warn that several difficult challenges remain, which need to be overcome if climate change politics is to result in a substantial reduction of greenhouse gas emissions. For example increasing tax on meat can be politically difficult.

Urgency

As of 2021, CO2 levels have already increased by about 50% since the pre-industrial era, with billions of tons more being released each year. Global warming has already passed the point where it is beginning to have a catastrophic impact in some localities. So major policy changes need to be implemented very soon if the risk of escalating environmental impact is to be avoided.

Centrality of fossil fuel

Energy from fossil fuels remains central to the worlds economy, accounting for about 80% of its energy generation as of 2019. Suddenly removing fossil fuel subsidies from consumers has often been found to cause riots. While clean energy can sometimes be cheaper, provisioning large amounts of renewable energy in a short period of time tends to be challenging. According to a 2021 report by the International Energy Agency, energy related CO2 emissions from fossil fuels are set to rise in 2021 by 4.8%. This would be the second highest rise ever, expected to be driven largely by increased burning of coal. In 2022 the European Central Bank argued that high energy prices were accelerating the energy transition away from fossil fuel, but that governments should take steps to prevent energy poverty without hindering the move to low carbon energy.

Inactivism

While outright denial of climate change is much less prevalent in the 2020s compared to the preceding decades, many arguments continue to be made against taking action to limit GHG emissions. Such arguments include the view that there are better ways to spend available funds (such as adaptation), that it would be better to wait until new technology is developed as that would make mitigation cheaper, that technology and innovation will render climate change moot or resolve certain aspects, and that the future negative effects of climate change should be heavily discounted compared to current needs.

Fossil fuel lobby and political spending

The largest oil and gas corporations that comprise Big Oil and their industry lobbyist arm, the American Petroleum Institute (API), spend large amounts of money on lobbying and political campaigns, and employ hundreds of lobbyists, to obstruct and delay government action to address climate change. The fossil fuel lobby has considerable clout in Washington, D.C. and in other political centers, including the European Union and the United Kingdom. Fossil fuel industry interests spend many times as much on advancing their agenda in the halls of power than do ordinary citizens and environmental activists, with the former spending $2 billion in the years 2000–2016 on climate change lobbying in the United States. The five largest Big Oil corporations spent hundreds of millions of euros to lobby for its agenda in Brussels. Big Oil companies often adopt "sustainability principles" that are at odds with the policy agenda their lobbyists advocate, which often entails sewing doubt about the reality and impacts of climate change and forestalling government efforts to address them. API launched a public relations disinformation campaign with the aim of creating doubt in the public mind so that “climate change becomes a non-issue." This industry also spends lavishly on American political campaigns, with approximately 2/3 of its political contributions over the past several decades fueling Republican Party politicians, and outspending many fold political contributions from renewable energy advocates. Fossil fuel industry political contributions reward politicians who vote against environmental protections. According to a study published by the Proceedings of the National Academy of Sciences of the United States of America, as voting by a member of United States Congress turned more anti-environment, as measured by his/her voting record as scored by the League of Conservation Voters (LCV), the fossil fuel industry contributions that this member of Congress received increased. On average, a 10% decrease in the LCV score was correlated with an increase of $1,700 in campaign contributions from the fossil fuel industry for the campaign following the Congressional term.

Suppression of climate science

Big Oil companies, starting as early as the 1970s, suppressed their own scientists' reports of major climate impacts of the combustion of fossil fuels. ExxonMobil launched a corporate propaganda campaign promoting false information about the issue of climate change, a tactic that has been compared to Big Tobacco's public relations efforts to hoodwink the public about the dangers of smoking. Fossil fuel industry-funded think tanks harassed climate scientists who were publicly discussing the dire threat of climate change. As early as the 1980s when larger segments of the American public began to become aware of the climate change issue, the administrations of some United States presidents scorned scientists who spoke publicly of the threat fossil fuels posed for the climate. Other U.S. administrations have silenced climate scientists and muzzled government whistleblowers. Political appointees at a number of federal agencies prevented scientists from reporting their findings regarding aspects of the climate crisis, changed data modeling to arrive at conclusions they had set out a prior to prove, and shut out the input of career scientists of the agencies.

Targeting of climate activists

Climate and environmental activists, including, increasingly, those defending woodlands against the logging industry, have been killed in several countries, such as Colombia, Brazil and the Philippines. The perpetrators of most such killings have not been punished. A record number of such killings was recorded for the year 2019. Indigenous environmental activists are disproportionately targeted, comprising as many as 40% of fatalities worldwide. Domestic intelligence services of several governments, such as those of the U.S. government, have targeted environmental activists and climate change organizations as "domestic terrorists," surveilling them, investigating them, questioning them, and placing them on national "watchlists" that could make it more difficult for them to board airplanes and could instigate local law enforcement monitoring. Other U.S. tactics have included preventing media coverage of American citizen assemblies and protests against climate change, and partnering with private security companies to monitor activists.

Doomism

In the context of climate change politics, doomism refers to pessimistic narratives that claim that it is now too late to do anything about climate change. Doomism can include exaggeration of the probability of cascading climate tipping points, and their likelihood in triggering runaway global heating beyond human ability to control, even if humanity was able to immediately stop all burning of fossil fuels. In the US, polls found that for people who did not support further action to limit global warming, a belief that it is too late to do so was given as a more common reason than skepticism about man made climate change.

Lack of compromise

Several climate friendly policies have been blocked in the legislative process by environmental and/or left leaning pressure groups and parties. For example, in 2009, the Australian green party voted against the Carbon Pollution Reduction Scheme, as they felt it did not impose a high enough carbon price. In the US, the Sierra Club helped defeat a 2016 climate tax bill which they saw as lacking in social justice. Some of the attempts to impose a carbon price in US states have been blocked by left wing politicians because they were to be implemented by a cap and trade mechanism, rather than a tax.

Multi-sector governance

The issue of climate change usually fits into various sectors, which means that the integration of climate change policies into other policy areas is frequently called for. Thus the problem is difficult, as it needs to be addressed at multiple scales with diverse actors involved in the complex governance process.

Maladaptation

Successful adaptation to climate change requires balancing competing economic, social, and political interests. In the absence of such balancing, harmful unintended consequences can undo the benefits of adaptation initiatives. For example, efforts to protect coral reefs in Tanzania forced local villagers to shift from traditional fishing activities to farming that produced higher greenhouse gas emissions.

Technology

The promise of technology is seen as both a threat and a potential boon. New technologies can open up possibilities for new and more effective climate policies. Most models that indicate a path to limiting warming to 2 °C have a big role for carbon dioxide removal, one of the two main forms of climate engineering. Commentators from across the political spectrum tend to welcome CO2 removal. But some are sceptical that it will be ever be able to remove enough CO2 to slow global warming without there also being rapid cuts in emissions, and they warn that too much optimism about such technology may make it harder for mitigation policies to be enacted.

There is a somewhat opposite view towards the other main form of climate engineering, solar radiation management. At least with the sulphur based aerosol variant, there is broad agreement that it would be effective in bringing down average global temperatures. Yet the prospect is considered unwelcome by many climate scientists. They warn that side effects would include possible reductions in agricultural yields due to reduced sunlight and rainfall, and possible localised temperature rises and other weather disruptions. According to Michael Mann, the prospect of using solar management to reduce temperatures is another argument used to reduce willingness to enact emissions reduction policy.

Just transition

Economic disruption due to phaseout of carbon-intensive activities, such as coal mining, cattle farming or bottom trawling, can be politically sensitive due to the high political profile of coal miners, farmers and fishers in some countries. Many labor and environmental groups advocate for a just transition that minimizes the harm and maximizes the benefits associated with climate-related changes to society, for example by providing job training.

Different responses on the political spectrum

In the United States, Democrats (blue) and Republicans (red) have long differed in views of the importance of addressing climate change, with the gap widening in the late 2010s mainly through Democrats' share increasing by more than 30 points.
 
The sharp divide over the existence of and responsibility for global warming and climate change falls largely along political lines. Overall, 60% of Americans surveyed said oil and gas companies were "completely or mostly responsible" for climate change.
 
Opinion about human causation of climate change increased substantially with education among Democrats, but not among Republicans. Conversely, opinions favoring becoming carbon neutral declined substantially with age among Republicans, but not among Democrats.

Climate friendly policies are generally supported across the political spectrum. Though there have been many exceptions among voters and politicians leaning towards the right, and even politicians on the left have rarely made addressing climate change a top priority. Some nations and individuals are unwilling to reduce greenhouse gas emissions or enforce laws because in doing so, they would only suffer in paying the full price of abatement. In the 20th century, right wing politicians led much significant action against climate change, both internationally and domestically, with Richard Nixon and Margaret Thatcher being prominent examples. Yet by the 1990s, especially in some English speaking countries and most especially in the US, the issue began to be polarised. Right wing media started arguing that climate change was being invented or at least exaggerated by the left to justify an expansion in the size of government. As of 2020, some right wing governments have enacted increased climate friendly policies. Various surveys indicated a slight trend for even U.S. right wing voters to become less sceptical of global warming, and groups like American Conservation Coalition indicate young Republican voters embrace climate as a central policy field. Though in the view of Anatol Lieven, for some right wing US voters, being sceptical of climate change has become part of their identity, so their position on the matter can not easily be shifted by rational argument.

A 2014 study from the University of Dortmund concluded that countries with centre and left-wing governments had higher emission reductions than right-wing governments in OECD countries for the time period 1992–2008. Historically, nationalist governments have been among the worst performers in enacting policies. Though according to Lieven, as climate change is increasingly seen as a threat to the ongoing existence of nation states, nationalism is likely to become one of the most effective forces to drive determined mitigation efforts. The growing trend to securitize the climate change threat may be especially effective for increasing support among nationalist and conservatives.

Relationship to climate science

Global warming has attracted the attention of central bank governors, as here with Mark Carney, appointed UN envoy for climate action in 2019.

In the scientific literature, there is an overwhelming consensus that global surface temperatures have increased in recent decades and that the trend is caused primarily by human-induced emissions of greenhouse gases.

The politicization of science in the sense of a manipulation of science for political gains is a part of the political process. It is part of the controversies about intelligent design (compare the Wedge strategy) or Merchants of Doubt, scientists that are under suspicion to willingly obscure findings. e.g. about issues like tobacco smoke, ozone depletion, global warming or acid rain. However, e.g. in case of ozone depletion, global regulation based on the Montreal Protocol was successful, in a climate of high uncertainty and against strong resistance while in case of climate change, the Kyoto Protocol failed.

While the IPCC process tries to find and orchestrate the findings of global climate change research to shape a worldwide consensus on the matter it has itself been the object of a strong politicization. Anthropogenic climate change evolved from a mere science issue to a top global policy topic.

The IPCC process having built a broad science consensus does not stop governments following different, if not opposing goals. In case of the ozone depletion challenge, global regulation was already being put into place before a scientific consensus was established. So a linear model of policy-making, based on a the more knowledge we have, the better the political response will be view is not necessarily accurate. Instead knowledge policy, successfully managing knowledge and uncertainties as a foundation for political decision making; requires a better understanding of the relation between science, public (lack of) understanding and policy.

Most of the policy debate concerning climate change mitigation has been framed by projections for the twenty-first century. Academics have criticised this as short term thinking, as decisions made in the next few decades will have environmental consequences that will last for many millennia.

It has been estimated that only 0.12% of all funding for climate-related research is spent on the social science of climate change mitigation. Vastly more funding is spent on natural science studies of climate change and considerable sums are also spent on studies of the impact of and adaptation to climate change. It has been argued that this is a misallocation of resources, as the most urgent puzzle at the current juncture is to work out how to change human behavior to mitigate climate change, whereas the natural science of climate change is already well established and there will be decades and centuries to handle adaptation.

Hydrogen production

From Wikipedia, the free encyclopedia
https://en.wikipedia.org/wiki/Hydrogen_production

Hydrogen production is the family of industrial methods for generating hydrogen gas. As of 2020, the majority of hydrogen (∼95%) is produced from fossil fuels by steam reforming of natural gas and other light hydrocarbons, partial oxidation of heavier hydrocarbons, and coal gasification. Other methods of hydrogen production include biomass gasification, zero-CO2-emission methane pyrolysis, and electrolysis of water. The latter processes, methane pyrolysis as well as water electrolysis can be done directly with any source of electricity, such as solar power.

The production of hydrogen plays a key role in any industrialized society, since hydrogen is required for many essential chemical processes. In 2020, roughly 87 million tons of hydrogen was produced worldwide for various uses, such as oil refining, and in the production of ammonia (NH3) (through the Haber process) and methanol (CH3OH) (through reduction of carbon monoxide [CO]), and also as a fuel in transportation. The global hydrogen generation market was valued at US$135.94 billion in 2021, and expected to grow to US$219.2 billion by 2030, with a compound annual growth rate (CAGR) of 5.4% from 2021 to 2030.

Methods of hydrogen production

Gasification

There are four main sources for the commercial production of hydrogen: natural gas, oil, coal, and electrolysis; which account for 48%, 30%, 18% and 4% of the world's hydrogen production respectively. Fossil fuels are the dominant source of industrial hydrogen. Carbon dioxide can be separated from natural gas with a 70–85% efficiency for hydrogen production and from other hydrocarbons to varying degrees of efficiency. Specifically, bulk hydrogen is usually produced by the steam reforming of methane or natural gas.

Steam methane reforming

Steam methane reforming (SMR) is a method of producing hydrogen from natural gas, which is mostly methane (CH4). It is currently the cheapest source of industrial hydrogen. Nearly 50% of the world's hydrogen is being produced by this method. The process consists of heating the gas to between 700–1,100 °C (1,292–2,012 °F) in the presence of steam and a nickel catalyst. The resulting endothermic reaction breaks up the methane molecules and forms carbon monoxide and molecular hydrogen (H2). The carbon monoxide gas can then be passed with steam over iron oxide or other oxides and undergo a water-gas shift reaction to obtain further quantities of H2. The downside to this process is that its byproducts are major atmospheric release of CO2, CO and other greenhouse gases. Depending on the quality of the feedstock (natural gas, rich gases, naphtha, etc.), one ton of hydrogen produced will also produce 9 to 12 tons of CO2, a greenhouse gas that may be captured.

Illustrating inputs and outputs of steam reforming of natural gas, a process to produce hydrogen and CO2 greenhouse gas that may be captured with CCS

For this process, high temperature steam (H2O) reacts with methane (CH4) in an endothermic reaction to yield syngas.

CH4 + H2O → CO + 3 H2

In a second stage, additional hydrogen is generated through the lower-temperature, exothermic, water-gas shift reaction, performed at about 360 °C (680 °F):

CO + H2O → CO2 + H2

Essentially, the oxygen (O) atom is stripped from the additional water (steam) to oxidize CO to CO2. This oxidation also provides energy to maintain the reaction. Additional heat required to drive the process is generally supplied by burning some portion of the methane.

Other production methods from fossil fuels

Methane pyrolysis

Illustrating inputs and outputs of methane pyrolysis, an efficient one-step process to produce hydrogen and no greenhouse gas

Pyrolysis of methane is a hydrogen production process from natural gas. Hydrogen separation occurs in one step via flow through a molten metal catalyst in a "bubble column". It is a "no-greenhouse-gas" approach for potentially low-cost hydrogen production being measured for its capability to scale up and for operation at scale. The process is conducted at higher temperatures (1065 °C or 1950 °F). Other forms of methane pyrolysis, such as the thermo-catalytic decomposition of methane, however, are able to operate at a reduced temperature between 600 °C - 1000 °C depending on the chosen catalyst.

CH
4
(g) → C(s) + 2 H
2
(g) ΔH° = 74.8 kJ/mol

The industrial quality solid carbon can then be sold as manufacturing feedstock or landfilled, it is not released into the atmosphere and does not pollute groundwater in landfills.

Partial oxidation

Hydrogen production from heavy hydrocarbons, which are unsuitable for catalytic steam reforming, is achieved by partial oxidation. A fuel-air or fuel-oxygen mixture is partially combusted, resulting in a hydrogen- and carbon monoxide-rich syngas. More hydrogen and carbon dioxide are then obtained from carbon monoxide (and water) via the water-gas shift reaction. Carbon dioxide can be co-fed to lower the hydrogen to carbon monoxide ratio.

The partial oxidation reaction occurs when a substoichiometric fuel-air mixture or fuel-oxygen is partially combusted in a reformer or partial oxidation reactor. A distinction is made between thermal partial oxidation (TPOX) and catalytic partial oxidation (CPOX). The chemical reaction takes the general form:

CnHm + n/2 O2n CO + m/2 H2

Idealized examples for heating oil and coal, assuming compositions C12H24 and C24H12 respectively, are as follows:

C12H24 + 6 O2 → 12 CO + 12 H2
C24H12 + 12 O2 → 24 CO + 6 H2

Plasma reforming

The Kværner process or Kvaerner carbon black & hydrogen process (CB&H) is a plasma reforming method, developed in the 1980s by a Norwegian company of the same name, for the production of hydrogen and carbon black from liquid hydrocarbons (CnHm). Of the available energy of the feed, approximately 48% is contained in the hydrogen, 40% is contained in activated carbon and 10% in superheated steam. CO2 is not produced in the process.

A variation of this process is presented in 2009 using, plasma arc waste disposal technology for the production of hydrogen, heat and carbon from methane and natural gas in a plasma converter.

From coal

For the production of hydrogen from coal, coal gasification is used. The process of coal gasification uses steam and oxygen to break molecular bonds in coal and form a gaseous mixture of hydrogen and carbon monoxide. Carbon dioxide and pollutants may be more easily removed from gas obtained from coal gasification versus coal combustion. Another method for conversion is low-temperature and high-temperature coal carbonization.

Coke oven gas made from pyrolysis (oxygen free heating) of coal has about 60% hydrogen, the rest being methane, carbon monoxide, carbon dioxide, ammonia, molecular nitrogen, and hydrogen sulfide (H2S). Hydrogen can be separated from other impurities by the pressure-swing adsorption process. Japanese steel companies have carried out production of hydrogen by this method.

From petroleum coke

Petroleum coke can also be converted to hydrogen-rich syngas via coal gasification. The produced syngas consists mainly of hydrogen, carbon monoxide and H2S from the sulfur in the coke feed. Gasification is an option for producing hydrogen from almost any carbon source.

From water

Methods to produce hydrogen without the use of fossil fuels involve the process of water splitting, or splitting the water molecule (H2O) into its components oxygen and hydrogen. When the source of energy for water splitting is renewable or low-carbon, the hydrogen produced is sometimes referred to as green hydrogen. The conversion can be accomplished in several ways, but all methods are generally more expensive than fossil-fuel based production methods.

Electrolysis

Hydrogen production via Electrolysis graphic
Illustrating inputs and outputs of electrolysis of water, for production of hydrogen and no greenhouse gas

Around 8 GW of electrolysis capacity is installed worldwide in 2020, accounting for around 4% of global hydrogen production.

Electrolysis consists of using electricity to split water into hydrogen and oxygen. Electrolysis of water is 70–80% efficient (a 20–30% conversion loss) while steam reforming of natural gas has a thermal efficiency between 70–85%. The electrical efficiency of electrolysis is expected to reach 82–86% before 2030, while also maintaining durability as progress in this area continues apace.

Water electrolysis can operate between 50–80 °C (122–176 °F), while steam methane reforming requires temperatures between 700–1,100 °C (1,292–2,012 °F). The difference between the two methods is the primary energy used; either electricity (for electrolysis) or natural gas (for steam methane reforming). Due to their use of water, a readily available resource, electrolysis and similar water-splitting methods have attracted the interest of the scientific community. With the objective of reducing the cost of hydrogen production, renewable sources of energy have been targeted to allow electrolysis.

There are three main types of electrolytic cells, solid oxide electrolyser cells (SOECs), polymer electrolyte membrane cells (PEM) and alkaline electrolysis cells (AECs). Traditionally, alkaline electrolysers are cheaper in terms of investment (they generally use nickel catalysts), but less-efficient; PEM electrolysers, conversely, are more expensive (they generally use expensive platinum group metal catalysts) but are more efficient and can operate at higher current densities, and can therefore be possibly cheaper if the hydrogen production is large enough.

SOECs operate at high temperatures, typically around 800 °C (1,470 °F). At these high temperatures, a significant amount of the energy required can be provided as thermal energy (heat), and as such is termed high-temperature electrolysis. The heat energy can be provided from a number of different sources, including waste industrial heat, nuclear power stations or concentrated solar thermal plants. This has the potential to reduce the overall cost of the hydrogen produced by reducing the amount of electrical energy required for electrolysis. PEM electrolysis cells typically operate below 100 °C (212 °F). These cells have the advantage of being comparatively simple and can be designed to accept widely varying voltage inputs, which makes them ideal for use with renewable sources of energy such as photovoltaic solar panels. AECs optimally operate at high concentrations of electrolyte (KOH or potassium carbonate) and at high temperatures, often near 200 °C (392 °F).

Industrial output and efficiency

Efficiency of modern hydrogen generators is measured by energy consumed per standard volume of hydrogen (MJ/m3), assuming standard temperature and pressure of the H2. The lower the energy used by a generator, the higher would be its efficiency; a 100%-efficient electrolyser would consume 39.4 kilowatt-hours per kilogram (142 MJ/kg) of hydrogen, 12,749 joules per litre (12.75 MJ/m3). Practical electrolysis typically uses a rotating electrolyser, where centrifugal force helps separate gas bubbles from water. Such an electrolyser at 15 bar pressure may consume 50 kilowatt-hours per kilogram (180 MJ/kg), and a further 15 kilowatt-hours (54 MJ) if the hydrogen is compressed for use in hydrogen cars.

Conventional alkaline electrolysis has an efficiency of about 70%, however advanced alkaline water electrolyser with efficiency of up to 82% are available. Accounting for the use of the higher heat value (because inefficiency via heat can be redirected back into the system to create the steam required by the catalyst), average working efficiencies for PEM electrolysis are around 80%, or 82% using the most modern alkaline electrolysers.

PEM efficiency is expected to increase to approximately 86% before 2030. Theoretical efficiency for PEM electrolysers is predicted up to 94%.

H2 production cost ($-gge untaxed) at varying natural gas prices

As of 2020, the cost of hydrogen by electrolysis is around $3–8/kg. Considering the industrial production of hydrogen, and using current best processes for water electrolysis (PEM or alkaline electrolysis) which have an effective electrical efficiency of 70–82%, producing 1 kg of hydrogen (which has a specific energy of 143 MJ/kg or about 40 kWh/kg) requires 50–55 kWh of electricity. At an electricity cost of $0.06/kWh, as set out in the Department of Energy hydrogen production targets for 2015, the hydrogen cost is $3/kg. The US DOE target price for hydrogen in 2020 is $2.30/kg, requiring an electricity cost of $0.037/kWh, which is achievable given recent PPA tenders for wind and solar in many regions. The report by IRENA.ORG is an extensive factual report of present day industrial hydrogen production consuming about 53 to 70 kWh per kg could go down to about 45 kWh/kg H2. The thermodynamic energy required for hydrogen by electrolysis translates to 33 kWh/kg, which is higher than steam reforming with carbon capture and higher than methane pyrolysis. One of the advantages of electrolysis over hydrogen from steam methane reforming (SMR) is that the hydrogen can be produced on-site, meaning that the costly process of delivery via truck or pipeline is avoided.

Steam methane reforming is between $1–3/kg on average. This makes production of hydrogen via electrolysis cost competitive in many regions already, as outlined by Nel Hydrogen and others, including an article by the IEA examining the conditions which could lead to a competitive advantage for electrolysis.

Chemically assisted electrolysis

In addition to reduce the voltage required for electrolysis via the increasing of the temperature of the electrolysis cell it is also possible to electrochemically consume the oxygen produced in an electrolyser by introducing a fuel (such as carbon/coal, methanol, ethanol, formic acid, glycerol, etc.) into the oxygen side of the reactor. This reduces the required electrical energy and has the potential to reduce the cost of hydrogen to less than 40~60% with the remaining energy provided in this manner. In addition, carbon/hydrocarbon assisted water electrolysis (CAWE) has the potential to offer a less energy intensive, cleaner method of using chemical energy in various sources of carbon, such as low-rank and high sulfur coals, biomass, alcohols and methane (Natural Gas), where pure CO2 produced can be easily sequestered without the need for separation.

Radiolysis

Nuclear radiation can break water bonds through radiolysis. In the Mponeng gold mine, South Africa, researchers found bacteria in a naturally occurring high radiation zone. The bacterial community which was dominated by a new phylotype of Desulfotomaculum, was feeding on primarily radiolytically produced hydrogen.

Thermolysis

Water spontaneously dissociates at around 2500 °C, but this thermolysis occurs at temperatures too high for usual process piping and equipment resulting in a rather low commercialization potential.

Thermochemical cycle

Thermochemical cycles combine solely heat sources (thermo) with chemical reactions to split water into its hydrogen and oxygen components. The term cycle is used because aside from water, hydrogen and oxygen, the chemical compounds used in these processes are continuously recycled. If electricity is partially used as an input, the resulting thermochemical cycle is defined as a hybrid one.

The sulfur-iodine cycle (S-I cycle) is a thermochemical cycle processes which generates hydrogen from water with an efficiency of approximately 50%. The sulfur and iodine used in the process are recovered and reused, and not consumed by the process. The cycle can be performed with any source of very high temperatures, approximately 950 °C, such as by Concentrating solar power systems (CSP) and is regarded as being well suited to the production of hydrogen by high-temperature nuclear reactors, and as such, is being studied in the High-temperature engineering test reactor in Japan. There are other hybrid cycles that use both high temperatures and some electricity, such as the Copper–chlorine cycle, it is classified as a hybrid thermochemical cycle because it uses an electrochemical reaction in one of the reaction steps, it operates at 530 °C and has an efficiency of 43 percent.

Ferrosilicon method

Ferrosilicon is used by the military to quickly produce hydrogen for balloons. The chemical reaction uses sodium hydroxide, ferrosilicon, and water. The generator is small enough to fit a truck and requires only a small amount of electric power, the materials are stable and not combustible, and they do not generate hydrogen until mixed. The method has been in use since World War I. A heavy steel pressure vessel is filled with sodium hydroxide and ferrosilicon, closed, and a controlled amount of water is added; the dissolving of the hydroxide heats the mixture to about 93 °C and starts the reaction; sodium silicate, hydrogen and steam are produced.

Photobiological water splitting

An algae bioreactor for hydrogen production.
 

Biological hydrogen can be produced in an algae bioreactor. In the late 1990s it was discovered that if the algae are deprived of sulfur it will switch from the production of oxygen, i.e. normal photosynthesis, to the production of hydrogen. It seems that the production is now economically feasible by surpassing the 7–10 percent energy efficiency (the conversion of sunlight into hydrogen) barrier with a hydrogen production rate of 10–12 ml per liter culture per hour.

Photocatalytic water splitting

The conversion of solar energy to hydrogen by means of water splitting process is one of the most interesting ways to achieve clean and renewable energy systems. However, if this process is assisted by photocatalysts suspended directly in water instead of using photovoltaic and an electrolytic system the reaction is in just one step, it can be made more efficient.

Biohydrogen routes

Biomass and waste streams can in principle be converted into biohydrogen with biomass gasification, steam reforming, or biological conversion like biocatalysed electrolysis or fermentative hydrogen production.

Among hydrogen production methods such as steam methane reforming, thermal cracking, coal and biomass gasification and pyrolysis, electrolysis, and photolysis, biological ones are more eco-friendly and less energy intensive. In addition, a wide variety of waste and low-value materials such as agricultural biomass as renewable sources can be utilized to produce hydrogen via biochemical pathways. Nevertheless, at present hydrogen is produced mainly from fossil fuels, in particular, natural gas which are non-renewable sources. Hydrogen is not only the cleanest fuel but also widely used in a number of industries, especially fertilizer, petrochemical and food ones. This makes it logical to investigate alternative sources for hydrogen production. The main biochemical technologies to produce hydrogen are dark and photo fermentation processes. In dark fermentation, carbohydrates are converted to hydrogen by fermentative microorganisms including strict anaerobe and facultative anaerobe bacteria. A theoretical maximum of 4 mol H2/mol glucose can be produced and, besides hydrogen, sugars are converted to volatile fatty acids (VFAs) and alcohols as by-products during this process. Photo fermentative bacteria are able to generate hydrogen from VFAs. Hence, metabolites formed in dark fermentation can be used as feedstock in photo fermentation to enhance the overall yield of hydrogen.

Fermentative hydrogen production

Biohydrogen can be produced in bioreactors. The process involves bacteria consuming hydrocarbons and producing hydrogen and CO2. The CO2 and hydrogen can be separated.

Fermentative hydrogen production is the fermentative conversion of organic substrate to biohydrogen manifested by a diverse group of bacteria using multi enzyme systems involving three steps similar to anaerobic conversion. Dark fermentation reactions do not require light energy, so they are capable of constantly producing hydrogen from organic compounds throughout the day and night. Photofermentation differs from dark fermentation because it only proceeds in the presence of light. For example, photo-fermentation with Rhodobacter sphaeroides SH2C can be employed to convert small molecular fatty acids into hydrogen.

Fermentative hydrogen production can be done using direct biophotolysis by green algae, indirect biophotolysis by cyanobacteria, photo-fermentation by anaerobic photosynthetic bacteria and dark fermentation by anaerobic fermentative bacteria. For example, studies on hydrogen production using H. salinarium, an anaerobic photosynthetic bacteria, coupled to a hydrogenase donor like E. coli, are reported in literature. Enterobacter aerogenes is another hydrogen producer.

Enzymatic hydrogen generation

Diverse enzymatic pathways have been designed to generate hydrogen from sugars.

Biocatalysed electrolysis

A microbial electrolysis cell
 

Besides dark fermentation, electrohydrogenesis (electrolysis using microbes) is another possibility. Using microbial fuel cells, wastewater or plants can be used to generate power. Biocatalysed electrolysis should not be confused with biological hydrogen production, as the latter only uses algae and with the latter, the algae itself generates the hydrogen instantly, where with biocatalysed electrolysis, this happens after running through the microbial fuel cell and a variety of aquatic plants can be used. These include reed sweetgrass, cordgrass, rice, tomatoes, lupines and algae.

Nano-galvanic aluminum-based powder developed by the U.S. Army Research Laboratory

Nanogalvanic aluminum alloy powder

An aluminum alloy powder invented by the U.S. Army Research Laboratory in 2017 was shown to be capable of producing hydrogen gas upon contact with water or any liquid containing water due to its unique nanoscale galvanic microstructure. It reportedly generates hydrogen at 100 percent of the theoretical yield without the need for any catalysts, chemicals, or externally supplied power.

Environmental impact

As of 2020, most hydrogen is produced from fossil fuels, resulting in carbon dioxide emissions. This is often referred to as grey hydrogen when emissions are released to the atmosphere, and blue hydrogen when emissions are captured through carbon capture and storage (CCS). Blue hydrogen has been estimated to have a greenhouse gas footprint 20% greater than burning gas or coal for heat and 60% greater when compared to burning diesel for heat, assuming US up- and mid-stream methane leakage rates and production via steam methane reformers (SMR) retrofitted with carbon dioxide capture. The use of autothermal reformers (ATR) with integrated capture of carbon dioxide allow higher capture rates at satisfactory energy efficiencies and life cycle assessments have shown lower greenhouse gas emissions for such plants compared to SMRs with carbon dioxide capture. Application of ATR technology with integrated capture of carbon dioxide in Europe has been assessed to have a lower greenhouse gas footprint than burning natural gas, e.g. for the H21 project with a reported reduction of 68% due to a reduced carbon dioxide intensity of natural gas combined with a more suitable reactor type for capture of carbon dioxide.

Hydrogen produced using the newer, non-polluting technology methane pyrolysis is often referred to as turquoise hydrogen. High quality hydrogen is produced directly from natural gas and the associated non-polluting solid carbon is not released into the atmosphere and can then be sold for industrial use or stored in landfill.

Hydrogen produced from renewable energy sources is often referred to as green hydrogen. There are two practical ways of producing hydrogen from renewable energy sources. One is to use power to gas, in which electric power is used to produce hydrogen from electrolysis of water, and the other is to use landfill gas to produce hydrogen in a steam reformer. Hydrogen fuel, when produced by renewable sources of energy like wind or solar power, is a renewable fuel. Hydrogen produced from nuclear energy via electrolysis is sometimes viewed as a subset of green hydrogen, but can also be referred to as pink hydrogen. The Oskarshamn Nuclear Power Plant made an agreement in January 2022 to supply commercial pink hydrogen in the order of kilograms per day.

As of 2020, estimated costs of production are $1–1.80/kg for grey hydrogen and blue hydrogen, and $2.50–6.80 for green hydrogen.

Use of hydrogen

Hydrogen is used for the conversion of heavy petroleum fractions into lighter ones via hydrocracking. It is also used in other processes including the aromatization process, hydrodesulfurization and the production of ammonia via the Haber process, the primary industrial method for the production of synthetic nitrogen fertilizer for growing 47 percent of food worldwide.

Hydrogen may be used in fuel cells for local electricity generation or potentially as a transportation fuel.

Hydrogen is produced as a by-product of industrial chlorine production by electrolysis. Although requiring expensive technologies, hydrogen can be cooled, compressed and purified for use in other processes on site or sold to a customer via pipeline, cylinders or trucks. The discovery and development of less expensive methods of production of bulk hydrogen is relevant to the establishment of a hydrogen economy.

Atomic bombings of Hiroshima and Nagasaki

From Wikipedia, the free encyclopedia https://en.wikipedia.org/wiki/Atomic_bombings_of_Hiroshima_and_Nagasaki   ...