Search This Blog

Monday, August 18, 2025

Energy storage

From Wikipedia, the free encyclopedia
The Llyn Stwlan dam of the Ffestiniog Pumped-Storage Scheme in Wales. The lower power station has four water turbines which can generate a total of 360 MW of electricity for several hours, an example of artificial energy storage and conversion.

Energy storage is the capture of energy produced at one time for use at a later time to reduce imbalances between energy demand and energy production. A device that stores energy is generally called an accumulator or battery. Energy comes in multiple forms including radiation, chemical, gravitational potential, electrical potential, electricity, elevated temperature, latent heat and kinetic. Energy storage involves converting energy from forms that are difficult to store to more conveniently or economically storable forms.

Some technologies provide short-term energy storage, while others can endure for much longer. Bulk energy storage is currently dominated by hydroelectric dams, both conventional as well as pumped. Grid energy storage is a collection of methods used for energy storage on a large scale within an electrical power grid.

Common examples of energy storage are the rechargeable battery, which stores chemical energy readily convertible to electricity to operate a mobile phone; the hydroelectric dam, which stores energy in a reservoir as gravitational potential energy; and ice storage tanks, which store ice frozen by cheaper energy at night to meet peak daytime demand for cooling. Fossil fuels such as coal and gasoline store ancient energy derived from sunlight by organisms that later died, became buried and over time were then converted into these fuels. Food (which is made by the same process as fossil fuels) is a form of energy stored in chemical form.

History

In the 20th century grid, electrical power was largely generated by burning fossil fuel. When less power was required, less fuel was burned. Hydropower, a mechanical energy storage method, is the most widely adopted mechanical energy storage, and has been in use for centuries. Large hydropower dams have been energy storage sites for more than one hundred years. Concerns with air pollution, energy imports, and global warming have spawned the growth of renewable energy such as solar and wind power. Wind power is uncontrolled and may be generating at a time when no additional power is needed. Solar power varies with cloud cover and at best is only available during daylight hours, while demand often peaks after sunset (see duck curve). Interest in storing power from these intermittent sources grows as the renewable energy industry begins to generate a larger fraction of overall energy consumption. In 2023 BloombergNEF forecast total energy storage deployments to grow at a compound annual growth rate of 27 percent through 2030.

Off grid electrical use was a niche market in the 20th century, but in the 21st century, it has expanded. Portable devices are in use all over the world. Solar panels are now common in the rural settings worldwide. Access to electricity is now a question of economics and financial viability, and not solely on technical aspects. Electric vehicles are gradually replacing combustion-engine vehicles. However, powering long-distance transportation without burning fuel remains in development.

Methods

Comparison of various energy storage technologies

Outline

The following list includes a variety of types of energy storage:

Mechanical

Energy from sunlight or other renewable sources is converted to potential energy for storage in devices such as electric batteries. The stored potential energy is later converted to electricity that is added to the power grid, even when the original energy source is not available. In pumped hydro systems, energy from the source is used to lift water upward against the force of gravity, giving it potential energy that is later converted to electricity provided to the power grid.

Energy can be stored in water pumped to a higher elevation using pumped storage methods or by moving solid matter to higher locations (gravity batteries). Other commercial mechanical methods include compressing air and flywheels that convert electric energy into internal energy or kinetic energy and then back again when electrical demand peaks.

Hydroelectricity

Hydroelectric dams with reservoirs can be operated to provide electricity at times of peak demand. Water is stored in the reservoir during periods of low demand and released when demand is high. The net effect is similar to pumped storage, but without the pumping loss.

While a hydroelectric dam does not directly store energy from other generating units, it behaves equivalently by lowering output in periods of excess electricity from other sources. In this mode, dams are one of the most efficient forms of energy storage, because only the timing of its generation changes. Hydroelectric turbines have a start-up time on the order of a few minutes.

Pumped hydro

The Sir Adam Beck Generating Complex at Niagara Falls, Canada, which includes a large pumped storage hydroelectricity reservoir to provide an extra 174 MW of electricity during periods of peak demand

Worldwide, pumped-storage hydroelectricity (PSH) is the largest-capacity form of active grid energy storage available, and, as of March 2012, the Electric Power Research Institute (EPRI) reports that PSH accounts for more than 99% of bulk storage capacity worldwide, representing around 127,000 MW.  PSH energy efficiency varies in practice between 70% and 80%, with claims of up to 87%.

At times of low electrical demand, excess generation capacity is used to pump water from a lower source into a higher reservoir. When demand grows, water is released back into a lower reservoir (or waterway or body of water) through a turbine, generating electricity. Reversible turbine-generator assemblies act as both a pump and turbine (usually a Francis turbine design). Nearly all facilities use the height difference between two water bodies. Pure pumped-storage plants shift the water between reservoirs, while the "pump-back" approach is a combination of pumped storage and conventional hydroelectric plants that use natural stream-flow.

Compressed air

A compressed air locomotive used inside a mine between 1928 and 1961

Compressed-air energy storage (CAES) uses surplus energy to compress air for subsequent electricity generation. Small-scale systems have long been used in such applications as propulsion of mine locomotives. The compressed air is stored in an underground reservoir, such as a salt dome.

Compressed-air energy storage (CAES) plants can bridge the gap between production volatility and load. CAES storage addresses the energy needs of consumers by effectively providing readily available energy to meet demand. Renewable energy sources like wind and solar energy vary. So at times when they provide little power, they need to be supplemented with other forms of energy to meet energy demand. Compressed-air energy storage plants can take in the surplus energy output of renewable energy sources during times of energy over-production. This stored energy can be used at a later time when demand for electricity increases or energy resource availability decreases.

Compression of air creates heat; the air is warmer after compression. Expansion requires heat. If no extra heat is added, the air will be much colder after expansion. If the heat generated during compression can be stored and used during expansion, efficiency improves considerably. A CAES system can deal with the heat in three ways. Air storage can be adiabatic, diabatic, or isothermal. Another approach uses compressed air to power vehicles.

Flywheel

The main components of a typical flywheel
A Flybrid Kinetic Energy Recovery System flywheel. Built for use on Formula 1 racing cars, it is employed to recover and reuse kinetic energy captured during braking.

Flywheel energy storage (FES) works by accelerating a rotor (a flywheel) to a very high speed, holding energy as rotational energy. When energy is added the rotational speed of the flywheel increases, and when energy is extracted, the speed declines, due to conservation of energy.

Most FES systems use electricity to accelerate and decelerate the flywheel, but devices that directly use mechanical energy are under consideration.

FES systems have rotors made of high strength carbon-fiber composites, suspended by magnetic bearings and spinning at speeds from 20,000 to over 50,000 revolutions per minute (rpm) in a vacuum enclosure. Such flywheels can reach maximum speed ("charge") in a matter of minutes. The flywheel system is connected to a combination electric motor/generator.

FES systems have relatively long lifetimes (lasting decades with little or no maintenance; full-cycle lifetimes quoted for flywheels range from in excess of 105, up to 107, cycles of use), high specific energy (100–130 W·h/kg, or 360–500 kJ/kg) and power density.

Solid mass gravitational

Changing the altitude of solid masses can store or release energy via an elevating system driven by an electric motor/generator. Studies suggest energy can begin to be released with as little as 1 second warning, making the method a useful supplemental feed into an electricity grid to balance load surges.

Efficiencies can be as high as 85% recovery of stored energy.

This can be achieved by siting the masses inside old vertical mine shafts or in specially constructed towers where the heavy weights are winched up to store energy and allowed a controlled descent to release it. At 2020 a prototype vertical store is being built in Edinburgh, Scotland.

Potential energy storage or gravity energy storage was under active development in 2013 in association with the California Independent System Operator. It examined the movement of earth-filled hopper rail cars driven by electric locomotives from lower to higher elevations.

Other proposed methods include:-

  • using rails, cranes, or elevators to move weights up and down;
  • using high-altitude solar-powered balloon platforms supporting winches to raise and lower solid masses slung underneath them,
  • using winches supported by an ocean barge to take advantage of a 4 km (13,000 ft) elevation difference between the sea surface and the seabed,
District heating accumulation tower from Theiss near Krems an der Donau in Lower Austria with a thermal capacity of 2 GWh

Thermal

Thermal energy storage (TES) is the temporary storage or removal of heat.

Sensible heat thermal

Sensible heat storage take advantage of sensible heat in a material to store energy.

Seasonal thermal energy storage (STES) allows heat or cold to be used months after it was collected from waste energy or natural sources. The material can be stored in contained aquifers, clusters of boreholes in geological substrates such as sand or crystalline bedrock, in lined pits filled with gravel and water, or water-filled mines. Seasonal thermal energy storage (STES) projects often have paybacks in four to six years. An example is Drake Landing Solar Community in Canada, for which 97% of the year-round heat is provided by solar-thermal collectors on garage roofs, enabled by a borehole thermal energy store (BTES). In Braedstrup, Denmark, the community's solar district heating system also uses STES, at a temperature of 65 °C (149 °F). A heat pump, which runs only while surplus wind power is available. It is used to raise the temperature to 80 °C (176 °F) for distribution. When wind energy is not available, a gas-fired boiler is used. Twenty percent of Braedstrup's heat is solar.

Latent heat thermal (LHTES)

Latent heat thermal energy storage systems work by transferring heat to or from a material to change its phase. A phase-change is the melting, solidifying, vaporizing or liquifying. Such a material is called a phase change material (PCM). Materials used in LHTESs often have a high latent heat so that at their specific temperature, the phase change absorbs a large amount of energy, much more than sensible heat.

A steam accumulator is a type of LHTES where the phase change is between liquid and gas and uses the latent heat of vaporization of water. Ice storage air conditioning systems use off-peak electricity to store cold by freezing water into ice. The stored cold in ice releases during melting process and can be used for cooling at peak hours.

Cryogenic thermal energy storage

Air can be liquefied by cooling using electricity and stored as a cryogen with existing technologies. The liquid air can then be expanded through a turbine and the energy recovered as electricity. The system was demonstrated at a pilot plant in the UK in 2012. In 2019, Highview announced plans to build a 50 MW in the North of England and northern Vermont, with the proposed facility able to store five to eight hours of energy, for a 250–400 MWh storage capacity.

Carnot battery

Electrical energy can be stored thermally by resistive heating or heat pumps, and the stored heat can be converted back to electricity via Rankine cycle or Brayton cycle. This technology has been studied to retrofit coal-fired power plants into fossil-fuel free generation systems. Coal-fired boilers are replaced by high-temperature heat storage charged by excess electricity from renewable energy sources. In 2020, German Aerospace Center started to construct the world's first large-scale Carnot battery system, which has 1,000  MWh storage capacity.

Electrochemical

Rechargeable battery

A rechargeable battery bank used as an uninterruptible power supply in a data center

A rechargeable battery comprises one or more electrochemical cells. It is known as a 'secondary cell' because its electrochemical reactions are electrically reversible. Rechargeable batteries come in many shapes and sizes, ranging from button cells to megawatt grid systems.

Rechargeable batteries have lower total cost of use and environmental impact than non-rechargeable (disposable) batteries. Some rechargeable battery types are available in the same form factors as disposables. Rechargeable batteries have higher initial cost but can be recharged very cheaply and used many times.

Common rechargeable battery chemistries include:

  • Lead–acid battery: Lead acid batteries hold the largest market share of electric storage products. A single cell produces about 2V when charged. In the charged state the metallic lead negative electrode and the lead sulfate positive electrode are immersed in a dilute sulfuric acid (H2SO4) electrolyte. In the discharge process electrons are pushed out of the cell as lead sulfate is formed at the negative electrode while the electrolyte is reduced to water.
    • Lead–acid battery technology has been developed extensively. Upkeep requires minimal labor and its cost is low. The battery's available energy capacity is subject to a quick discharge resulting in a low life span and low energy density.
  • Nickel–cadmium battery (NiCd): Uses nickel oxide hydroxide and metallic cadmium as electrodes. Cadmium is a toxic element, and was banned for most uses by the European Union in 2004. Nickel–cadmium batteries have been almost completely replaced by nickel–metal hydride (NiMH) batteries.
  • Nickel–metal hydride battery (NiMH): First commercial types were available in 1989. These are now a common consumer and industrial type. The battery has a hydrogen-absorbing alloy for the negative electrode instead of cadmium.
  • Lithium-ion battery: The choice in many consumer electronics and have one of the best energy-to-mass ratios and a very slow self-discharge when not in use.
  • Lithium-ion polymer battery: These batteries are light in weight and can be made in any shape desired.
  • Aluminium-sulfur battery with rock salt crystals as electrolyte: aluminium and sulfur are Earth-abundant materials and are much cheaper than traditional Lithium.
Flow battery

A flow battery works by passing a solution over a membrane where ions are exchanged to charge or discharge the cell. Cell voltage is chemically determined by the Nernst equation and ranges, in practical applications, from 1.0 V to 2.2 V. Storage capacity depends on the volume of solution. A flow battery is technically akin both to a fuel cell and an electrochemical accumulator cell. Commercial applications are for long half-cycle storage such as backup grid power.

Supercapacitor

One of a fleet of electric capabuses powered by supercapacitors, at a quick-charge station-bus stop, in service during Expo 2010 Shanghai China. Charging rails can be seen suspended over the bus.

Supercapacitors, also called electric double-layer capacitors (EDLC) or ultracapacitors, are a family of electrochemical capacitors that do not have conventional solid dielectrics. Capacitance is determined by two storage principles, double-layer capacitance and pseudocapacitance.

Supercapacitors bridge the gap between conventional capacitors and rechargeable batteries. They store the most energy per unit volume or mass (energy density) among capacitors. They support up to 10,000 farads/1.2 Volt, up to 10,000 times that of electrolytic capacitors, but deliver or accept less than half as much power per unit time (power density).

While supercapacitors have specific energy and energy densities that are approximately 10% of batteries, their power density is generally 10 to 100 times greater. This results in much shorter charge/discharge cycles. Also, they tolerate many more charge-discharge cycles than batteries.

Supercapacitors have many applications, including:

  • Low supply current for memory backup in static random-access memory (SRAM)
  • Power for cars, buses, trains, cranes and elevators, including energy recovery from braking, short-term energy storage and burst-mode power delivery

Chemical

Power-to-gas

The new technology helps reduce greenhouse gases and operating costs at two existing peaker plants in Norwalk and Rancho Cucamonga. The 10-megawatt battery storage system, combined with the gas turbine, allows the peaker plant to more quickly respond to changing energy needs, thus increasing the reliability of the electrical grid.

Power-to-gas is the conversion of electricity to a gaseous fuel such as hydrogen or methane. The three commercial methods use electricity to reduce water into hydrogen and oxygen by means of electrolysis.

In the first method, hydrogen is injected into the natural gas grid or is used for transportation. The second method is to combine the hydrogen with carbon dioxide to produce methane using a methanation reaction such as the Sabatier reaction, or biological methanation, resulting in an extra energy conversion loss of 8%. The methane may then be fed into the natural gas grid. The third method uses the output gas of a wood gas generator or a biogas plant, after the biogas upgrader is mixed with the hydrogen from the electrolyzer, to upgrade the quality of the biogas.

Hydrogen

The element hydrogen can be a form of stored energy. Hydrogen can produce electricity via a hydrogen fuel cell.

At penetrations below 20% of the grid demand, renewables do not severely change the economics; but beyond about 20% of the total demand, external storage becomes important. If these sources are used to make ionic hydrogen, they can be freely expanded. A 5-year community-based pilot program using wind turbines and hydrogen generators began in 2007 in the remote community of Ramea, Newfoundland and Labrador. A similar project began in 2004 on Utsira, a small Norwegian island.

Energy losses involved in the hydrogen storage cycle come from the electrolysis of water, liquification or compression of the hydrogen and conversion to electricity.

Hydrogen can also be produced from aluminum and water by stripping aluminum's naturally occurring aluminum oxide barrier and introducing it to water. This method is beneficial because recycled aluminum cans can be used to generate hydrogen; however, systems to harness this option have not been commercially developed and are much more complex than electrolysis systems. Common methods to strip the oxide layer include caustic catalysts such as sodium hydroxide and alloys with gallium, mercury and other metals.

Underground hydrogen storage is the practice of hydrogen storage in caverns, salt domes and depleted oil and gas fields. Large quantities of gaseous hydrogen have been stored in caverns by Imperial Chemical Industries for many years without any difficulties. The European Hyunder project indicated in 2013 that storage of wind and solar energy using underground hydrogen would require 85 caverns.

Powerpaste is a magnesium and hydrogen -based fluid gel that releases hydrogen when reacting with water. It was invented, patented and is being developed by the Fraunhofer Institute for Manufacturing Technology and Advanced Materials (IFAM) of the Fraunhofer-Gesellschaft. Powerpaste is made by combining magnesium powder with hydrogen to form magnesium hydride in a process conducted at 350 °C and five to six times atmospheric pressure. An ester and a metal salt are then added to make the finished product. Fraunhofer states that they are building a production plant slated to start production in 2021, which will produce 4 tons of Powerpaste annually. Fraunhofer has patented their invention in the United States and EU. Fraunhofer claims that Powerpaste is able to store hydrogen energy at 10 times the energy density of a lithium battery of a similar dimension and is safe and convenient for automotive situations.

Methane

Methane is the simplest hydrocarbon with the molecular formula CH4. Methane is more easily stored and transported than hydrogen. Storage and combustion infrastructure (pipelines, gasometers, power plants) are mature.

Synthetic natural gas (syngas or SNG) can be created in a multi-step process, starting with hydrogen and oxygen. Hydrogen is then reacted with carbon dioxide in a Sabatier process, producing methane and water. Methane can be stored and later used to produce electricity. The resulting water is recycled, reducing the need for water. In the electrolysis stage, oxygen is stored for methane combustion in a pure oxygen environment at an adjacent power plant, eliminating nitrogen oxides.

Methane combustion produces carbon dioxide (CO2) and water. The carbon dioxide can be recycled to boost the Sabatier process and water can be recycled for further electrolysis. Methane production, storage and combustion recycles the reaction products.

The CO2 has economic value as a component of an energy storage vector, not a cost as in carbon capture and storage.

Power-to-liquid

Power-to-liquid is similar to power to gas except that the hydrogen is converted into liquids such as methanol or ammonia. These are easier to handle than gases, and require fewer safety precautions than hydrogen. They can be used for transportation, including aircraft, but also for industrial purposes or in the power sector.

Biofuels

Various biofuels such as biodiesel, vegetable oil, alcohol fuels, or biomass can replace fossil fuels. Various chemical processes can convert the carbon and hydrogen in coal, natural gas, plant and animal biomass and organic wastes into short hydrocarbons suitable as replacements for existing hydrocarbon fuels. Examples are Fischer–Tropsch diesel, methanol, dimethyl ether and syngas. This diesel source was used extensively in World War II in Germany, which faced limited access to crude oil supplies. South Africa produces most of the country's diesel from coal for similar reasons. A long term oil price above US$35/bbl may make such large scale synthetic liquid fuels economical.

Power-to-Solid

Similar to power-to-liquid and power-to-gas concepts, energy may be stored in solid materials, for example in metals such as Iron, Aluminium and non-metallic materials such as Sulfur. Energy in the form of electricity or solar heat is stored chemically and can be released on-demand. Historically, solid energy carriers have been long used in Fireworks and Rockets.

Aluminum

Aluminum has been proposed as an energy store by a number of researchers. Its electrochemical equivalent (8.04 Ah/cm3) is nearly four times greater than that of lithium (2.06 Ah/cm3). Energy can be extracted from aluminum by reacting it with water to generate hydrogen. However, it must first be stripped of its natural oxide layer, a process which requires pulverization, chemical reactions with caustic substances, or alloys. The byproduct of the reaction to create hydrogen is aluminum oxide, which can be recycled into aluminum with the Hall–Héroult process, making the reaction theoretically renewable. If the Hall-Héroult Process is run using solar or wind power, aluminum could be used to store the energy produced at higher efficiency than direct solar electrolysis.

Boron, silicon, and zinc

Boronsilicon, and zinc have been proposed as energy storage solutions.

Other chemical

The organic compound norbornadiene converts to quadricyclane upon exposure to light, storing solar energy as the energy of chemical bonds. A working system has been developed in Sweden as a molecular solar thermal system.

Electrical methods

Capacitor

This mylar-film, oil-filled capacitor has very low inductance and low resistance, to provide the high-power (70 megawatts) and the very high speed (1.2 microsecond) discharges needed to operate a dye laser.

A capacitor (originally known as a 'condenser') is a passive two-terminal electrical component used to store energy electrostatically. Practical capacitors vary widely, but all contain at least two electrical conductors (plates) separated by a dielectric (i.e., insulator). A capacitor can store electric energy when disconnected from its charging circuit, so it can be used like a temporary battery, or like other types of rechargeable energy storage system. Capacitors are commonly used in electronic devices to maintain power supply while batteries change. (This prevents loss of information in volatile memory.) Conventional capacitors provide less than 360 joules per kilogram, while a conventional alkaline battery has a density of 590 kJ/kg.

Capacitors store energy in an electrostatic field between their plates. Given a potential difference across the conductors (e.g., when a capacitor is attached across a battery), an electric field develops across the dielectric, causing positive charge (+Q) to collect on one plate and negative charge (-Q) to collect on the other plate. If a battery is attached to a capacitor for a sufficient amount of time, no current can flow through the capacitor. However, if an accelerating or alternating voltage is applied across the leads of the capacitor, a displacement current can flow. Besides capacitor plates, charge can also be stored in a dielectric layer.

Capacitance is greater given a narrower separation between conductors and when the conductors have a larger surface area. In practice, the dielectric between the plates emits a small amount of leakage current and has an electric field strength limit, known as the breakdown voltage. However, the effect of recovery of a dielectric after a high-voltage breakdown holds promise for a new generation of self-healing capacitors. The conductors and leads introduce undesired inductance and resistance.

Research is assessing the quantum effects of nanoscale capacitors for digital quantum batteries.

Superconducting magnetics

Superconducting magnetic energy storage (SMES) systems store energy in a magnetic field created by the flow of direct current in a superconducting coil that has been cooled to a temperature below its superconducting critical temperature. A typical SMES system includes a superconducting coil, power conditioning system and refrigerator. Once the superconducting coil is charged, the current does not decay and the magnetic energy can be stored indefinitely.

The stored energy can be released to the network by discharging the coil. The associated inverter/rectifier accounts for about 2–3% energy loss in each direction. SMES loses the least amount of electricity in the energy storage process compared to other methods of storing energy. SMES systems offer round-trip efficiency greater than 95%.

Due to the energy requirements of refrigeration and the cost of superconducting wire, SMES is used for short duration storage such as improving power quality. It also has applications in grid balancing.

Applications

Mills

The classic application before the Industrial Revolution was the control of waterways to drive water mills for processing grain or powering machinery. Complex systems of reservoirs and dams were constructed to store and release water (and the potential energy it contained) when required.

Homes

Home energy storage is expected to become increasingly common given the growing importance of distributed generation of renewable energies (especially photovoltaics) and the important share of energy consumption in buildings. To exceed a self-sufficiency of 40% in a household equipped with photovoltaics, energy storage is needed. Multiple manufacturers produce rechargeable battery systems for storing energy, generally to hold surplus energy from home solar or wind generation. Today, for home energy storage, Li-ion batteries are preferable to lead-acid ones given their similar cost but much better performance.

Tesla Motors produces two models of the Tesla Powerwall. One is a 10 kWh weekly cycle version for backup applications and the other is a 7 kWh version for daily cycle applications. In 2016, a limited version of the Tesla Powerpack 2 cost $398(US)/kWh to store electricity worth 12.5 cents/kWh (US average grid price) making a positive return on investment doubtful unless electricity prices are higher than 30 cents/kWh.

RoseWater Energy produces two models of the "Energy & Storage System", the HUB 120 and SB20. Both versions provide 28.8 kWh of output, enabling it to run larger houses or light commercial premises, and protecting custom installations. The system provides five key elements into one system, including providing a clean 60 Hz Sine wave, zero transfer time, industrial-grade surge protection, renewable energy grid sell-back (optional), and battery backup.

Enphase Energy announced an integrated system that allows home users to store, monitor and manage electricity. The system stores 1.2 kWh of energy and 275W/500W power output.

Storing wind or solar energy using thermal energy storage though less flexible, is considerably cheaper than batteries. A simple 52-gallon electric water heater can store roughly 12 kWh of energy for supplementing hot water or space heating.

For purely financial purposes in areas where net metering is available, home generated electricity may be sold to the grid through a grid-tie inverter without the use of batteries for storage.

Grid electricity and power stations

Renewable energy

Construction of the Salt Tanks which provide efficient thermal energy storage so that electricity can be generated after the sun goes down, and output can be scheduled to meet demand. The 280 MW Solana Generating Station is designed to provide six hours of storage. This allows the plant to generate about 38% of its rated capacity over the course of a year.
The 150 MW Andasol solar power station in Spain is a parabolic trough solar thermal power plant that stores energy in tanks of molten salt so that it can continue generating electricity when the sun is not shining.

The largest source and the greatest store of renewable energy is provided by hydroelectric dams. A large reservoir behind a dam can store enough water to average the annual flow of a river between dry and wet seasons, and a very large reservoir can store enough water to average the flow of a river between dry and wet years. While a hydroelectric dam does not directly store energy from intermittent sources, it does balance the grid by lowering its output and retaining its water when power is generated by solar or wind. If wind or solar generation exceeds the region's hydroelectric capacity, then some additional source of energy is needed.

Many renewable energy sources (notably solar and wind) produce variable power. Storage systems can level out the imbalances between supply and demand that this causes. Electricity must be used as it is generated or converted immediately into storable forms.

The main method of electrical grid storage is pumped-storage hydroelectricity. Areas of the world such as Norway, Wales, Japan and the US have used elevated geographic features for reservoirs, using electrically powered pumps to fill them. When needed, the water passes through generators and converts the gravitational potential of the falling water into electricity. Pumped storage in Norway, which gets almost all its electricity from hydro, has currently a capacity of 1.4 GW but since the total installed capacity is nearly 32 GW and 75% of that is regulable, it can be expanded significantly.

Some forms of storage that produce electricity include pumped-storage hydroelectric dams, rechargeable batteries, thermal storage including molten salts which can efficiently store and release very large quantities of heat energy, and compressed air energy storage, flywheels, cryogenic systems and superconducting magnetic coils.

Surplus power can also be converted into methane (Sabatier process) with stockage in the natural gas network.

In 2011, the Bonneville Power Administration in the northwestern United States created an experimental program to absorb excess wind and hydro power generated at night or during stormy periods that are accompanied by high winds. Under central control, home appliances absorb surplus energy by heating ceramic bricks in special space heaters to hundreds of degrees and by boosting the temperature of modified hot water heater tanks. After charging, the appliances provide home heating and hot water as needed. The experimental system was created as a result of a severe 2010 storm that overproduced renewable energy to the extent that all conventional power sources were shut down, or in the case of a nuclear power plant, reduced to its lowest possible operating level, leaving a large area running almost completely on renewable energy.

Another advanced method used at the former Solar Two project in the United States and the Solar Tres Power Tower in Spain uses molten salt to store thermal energy captured from the sun and then convert it and dispatch it as electrical power. The system pumps molten salt through a tower or other special conduits to be heated by the sun. Insulated tanks store the solution. Electricity is produced by turning water to steam that is fed to turbines.

Since the early 21st century batteries have been applied to utility scale load-leveling and frequency regulation capabilities.

In vehicle-to-grid storage, electric vehicles that are plugged into the energy grid can deliver stored electrical energy from their batteries into the grid when needed.

Air conditioning

Thermal energy storage (TES) can be used for air conditioning. It is most widely used for cooling single large buildings and/or groups of smaller buildings. Commercial air conditioning systems are the biggest contributors to peak electrical loads. In 2009, thermal storage was used in over 3,300 buildings in over 35 countries. It works by chilling material at night and using the chilled material for cooling during the hotter daytime periods.

The most popular technique is ice storage, which requires less space than water and is cheaper than fuel cells or flywheels. In this application, a standard chiller runs at night to produce an ice pile. Water circulates through the pile during the day to chill water that would normally be the chiller's daytime output.

A partial storage system minimizes capital investment by running the chillers nearly 24 hours a day. At night, they produce ice for storage and during the day they chill water. Water circulating through the melting ice augments the production of chilled water. Such a system makes ice for 16 to 18 hours a day and melts ice for six hours a day. Capital expenditures are reduced because the chillers can be just 40% – 50% of the size needed for a conventional, no-storage design. Storage sufficient to store half a day's available heat is usually adequate.

A full storage system shuts off the chillers during peak load hours. Capital costs are higher, as such a system requires larger chillers and a larger ice storage system.

This ice is produced when electrical utility rates are lower. Off-peak cooling systems can lower energy costs. The U.S. Green Building Council has developed the Leadership in Energy and Environmental Design (LEED) program to encourage the design of reduced-environmental impact buildings. Off-peak cooling may help toward LEED Certification.

Thermal storage for heating is less common than for cooling. An example of thermal storage is storing solar heat to be used for heating at night.

Latent heat can also be stored in technical phase change materials (PCMs). These can be encapsulated in wall and ceiling panels, to moderate room temperatures.

Transport

Liquid hydrocarbon fuels are the most commonly used forms of energy storage for use in transportation, followed by a growing use of Battery Electric Vehicles and Hybrid Electric Vehicles. Other energy carriers such as hydrogen can be used to avoid producing greenhouse gases.

Public transport systems like trams and trolleybuses require electricity, but due to their variability in movement, a steady supply of electricity via renewable energy is challenging. Photovoltaic systems installed on the roofs of buildings can be used to power public transportation systems during periods in which there is increased demand for electricity and access to other forms of energy are not readily available. Upcoming transitions in the transportation system also include e.g. ferries and airplanes, where electric power supply is investigated as an interesting alternative.

Electronics

Capacitors are widely used in electronic circuits for blocking direct current while allowing alternating current to pass. In analog filter networks, they smooth the output of power supplies. In resonant circuits they tune radios to particular frequencies. In electric power transmission systems they stabilize voltage and power flow.

Use cases

The United States Department of Energy International Energy Storage Database (IESDB), is a free-access database of energy storage projects and policies funded by the United States Department of Energy Office of Electricity and Sandia National Labs.

Capacity

Storage capacity is the amount of energy extracted from an energy storage device or system; usually measured in joules or kilowatt-hours and their multiples, it may be given in number of hours of electricity production at power plant nameplate capacity; when storage is of primary type (i.e., thermal or pumped-water), output is sourced only with the power plant embedded storage system.

Economics

The economics of energy storage strictly depends on the reserve service requested, and several uncertainty factors affect the profitability of energy storage. Therefore, not every storage method is technically and economically suitable for the storage of several MWh, and the optimal size of the energy storage is market and location dependent.

Moreover, ESS are affected by several risks, e.g.:

  • Techno-economic risks, which are related to the specific technology;
  • Market risks, which are the factors that affect the electricity supply system;
  • Regulation and policy risks.

Therefore, traditional techniques based on deterministic Discounted Cash Flow (DCF) for the investment appraisal are not fully adequate to evaluate these risks and uncertainties and the investor's flexibility to deal with them. Hence, the literature recommends to assess the value of risks and uncertainties through the Real Option Analysis (ROA), which is a valuable method in uncertain contexts.

The economic valuation of large-scale applications (including pumped hydro storage and compressed air) considers benefits including: curtailment avoidance, grid congestion avoidance, price arbitrage and carbon-free energy delivery. In one technical assessment by the Carnegie Mellon Electricity Industry Centre, economic goals could be met using batteries if their capital cost was $30 to $50 per kilowatt-hour.

A metric of energy efficiency of storage is energy storage on energy invested (ESOI), which is the amount of energy that can be stored by a technology, divided by the amount of energy required to build that technology. The higher the ESOI, the better the storage technology is energetically. For lithium-ion batteries this is around 10, and for lead acid batteries it is about 2. Other forms of storage such as pumped hydroelectric storage generally have higher ESOI, such as 210.

Pumped-storage hydroelectricity is by far the largest storage technology used globally. However, the usage of conventional pumped-hydro storage is limited because it requires terrain with elevation differences and also has a very high land use for relatively small power. In locations without suitable natural geography, underground pumped-hydro storage could also be used. High costs and limited life still make batteries a "weak substitute" for dispatchable power sources, and are unable to cover for variable renewable power gaps lasting for days, weeks or months. In grid models with high VRE share, the excessive cost of storage tends to dominate the costs of the whole grid — for example, in California alone 80% share of VRE would require 9.6 TWh of storage but 100% would require 36.3 TWh. As of 2018 the state only had 150 GWh of storage, primarily in pumped storage and a small fraction in batteries. According to another study, supplying 80% of US demand from VRE would require a smart grid covering the whole country or battery storage capable to supply the whole system for 12 hours, both at cost estimated at $2.5 trillion. Similarly, several studies have found that relying only on VRE and energy storage would cost about 30–50% more than a comparable system that combines VRE with nuclear plants or plants with carbon capture and storage instead of energy storage.

Research

Germany

In 2013, the German government allocated €200M (approximately US$270M) for research, and another €50M to subsidize battery storage in residential rooftop solar panels, according to a representative of the German Energy Storage Association.

Siemens AG commissioned a production-research plant to open in 2015 at the Zentrum für Sonnenenergie und Wasserstoff (ZSW, the German Center for Solar Energy and Hydrogen Research in the State of Baden-Württemberg), a university/industry collaboration in Stuttgart, Ulm and Widderstall, staffed by approximately 350 scientists, researchers, engineers, and technicians. The plant develops new near-production manufacturing materials and processes (NPMM&P) using a computerized Supervisory Control and Data Acquisition (SCADA) system. It aims to enable the expansion of rechargeable battery production with increased quality and lower cost.

From 2023 onwards, a new project by the German Research Foundation focuses on molecular photoswitches to store solar thermal energy. The spokesperson of these so-called molecular solar thermal (MOST) systems is Prof. Dr. Hermann A. Wegner.

United States

In 2014, research and test centers opened to evaluate energy storage technologies. Among them was the Advanced Systems Test Laboratory at the University of Wisconsin at Madison in Wisconsin State, which partnered with battery manufacturer Johnson Controls. The laboratory was created as part of the university's newly opened Wisconsin Energy Institute. Their goals include the evaluation of state-of-the-art and next generation electric vehicle batteries, including their use as grid supplements.

The State of New York unveiled its New York Battery and Energy Storage Technology (NY-BEST) Test and Commercialization Center at Eastman Business Park in Rochester, New York, at a cost of $23 million for its almost 1,700 m2 laboratory. The center includes the Center for Future Energy Systems, a collaboration between Cornell University of Ithaca, New York and the Rensselaer Polytechnic Institute in Troy, New York. NY-BEST tests, validates and independently certifies diverse forms of energy storage intended for commercial use.

On September 27, 2017, Senators Al Franken of Minnesota and Martin Heinrich of New Mexico introduced Advancing Grid Storage Act (AGSA), which would devote more than $1 billion in research, technical assistance and grants to encourage energy storage in the United States.

In grid models with high VRE share, the excessive cost of storage tends to dominate the costs of the whole grid – for example, in California alone 80% share of VRE would require 9.6 TWh of storage but 100% would require 36.3 TWh. According to another study, supplying 80% of US demand from VRE would require a smart grid covering the whole country or battery storage capable to supply the whole system for 12 hours, both at cost estimated at $2.5 trillion.

United Kingdom

In the United Kingdom, some 14 industry and government agencies allied with seven British universities in May 2014 to create the SUPERGEN Energy Storage Hub in order to assist in the coordination of energy storage technology research and development.

Nitrous oxide

From Wikipedia, the free encyclopedia

Nitrous oxide (dinitrogen oxide or dinitrogen monoxide), commonly known as laughing gas, nitrous, or factitious air, among others,[4] is a chemical compound, an oxide of nitrogen with the formula N
2
O
. At room temperature, it is a colourless non-flammable gas, and has a slightly sweet scent and taste.[4] At elevated temperatures, nitrous oxide is a powerful oxidiser similar to molecular oxygen.

Nitrous oxide has significant medical uses, especially in surgery and dentistry, for its anaesthetic and pain-reducing effects, and it is on the World Health Organization's List of Essential Medicines. Its colloquial name, "laughing gas", coined by Humphry Davy, describes the euphoric effects upon inhaling it, which cause it to be used as a recreational drug inducing a brief "high". When abused chronically, it may cause neurological damage through inactivation of vitamin B12. It is also used as an oxidiser in rocket propellants and motor racing fuels, and as a frothing gas for whipped cream.

Nitrous oxide is also an atmospheric pollutant, with a concentration of 333 parts per billion (ppb) in 2020, increasing at 1 ppb annually. It is a major scavenger of stratospheric ozone, with an impact comparable to that of CFCs. About 40% of human-caused emissions are from agriculture, as nitrogen fertilisers are digested into nitrous oxide by soil micro-organisms. As the third most important greenhouse gas, nitrous oxide substantially contributes to global warming. Reduction of emissions is an important goal in the politics of climate change.

Discovery and early use

The gas was first synthesised in 1772 by English natural philosopher and chemist Joseph Priestley who called it dephlogisticated nitrous air (see phlogiston theory) or inflammable nitrous air. Priestley published his discovery in the book Experiments and Observations on Different Kinds of Air (1775), where he described how to produce the preparation of "nitrous air diminished", by heating iron filings dampened with nitric acid.

"Living Made Easy": A satirical print from 1830 depicting Humphry Davy administering a dose of laughing gas to a woman

The first important use of nitrous oxide was made possible by Thomas Beddoes and James Watt, who worked together to publish the book Considerations on the Medical Use and on the Production of Factitious Airs (1794). This book was important for two reasons. First, James Watt had invented a novel machine to produce "factitious airs" (including nitrous oxide) and a novel "breathing apparatus" to inhale the gas. Second, the book also presented the new medical theories by Thomas Beddoes, that tuberculosis and other lung diseases could be treated by inhalation of "Factitious Airs".

Sir Humphry Davy's Researches chemical and philosophical: chiefly concerning nitrous oxide (1800), pages 556 and 557 (right), outlining potential anaesthetic properties of nitrous oxide in relieving pain during surgery

The machine to produce "Factitious Airs" had three parts: a furnace to burn the needed material, a vessel with water where the produced gas passed through in a spiral pipe (for impurities to be "washed off"), and finally the gas cylinder with a gasometer where the gas produced, "air", could be tapped into portable air bags (made of airtight oily silk). The breathing apparatus consisted of one of the portable air bags connected with a tube to a mouthpiece. With this new equipment being engineered and produced by 1794, the way was paved for clinical trials, which began in 1798 when Thomas Beddoes established the "Pneumatic Institution for Relieving Diseases by Medical Airs" in Hotwells (Bristol). In the basement of the building, a large-scale machine was producing the gases under the supervision of a young Humphry Davy, who was encouraged to experiment with new gases for patients to inhale. The first important work of Davy was examination of the nitrous oxide, and the publication of his results in the book: Researches, Chemical and Philosophical (1800). In that publication, Davy notes the analgesic effect of nitrous oxide at page 465 and its potential to be used for surgical operations at page 556. Davy coined the name "laughing gas" for nitrous oxide.

Despite Davy's discovery that inhalation of nitrous oxide could relieve a conscious person from pain, another 44 years elapsed before doctors attempted to use it for anaesthesia. The use of nitrous oxide as a recreational drug at "laughing gas parties", primarily arranged for the British upper class, became an immediate success beginning in 1799. While the effects of the gas generally make the user appear stuporous, dreamy and sedated, some people also "get the giggles" in a state of euphoria, and frequently erupt in laughter.

One of the earliest commercial producers in the U.S. was George Poe, cousin of the poet Edgar Allan Poe, who also was the first to liquefy the gas.

The first time nitrous oxide was used as an anaesthetic drug in the treatment of a patient was when dentist Horace Wells, with assistance by Gardner Quincy Colton and John Mankey Riggs, demonstrated insensitivity to pain from a dental extraction on 11 December 1844. In the following weeks, Wells treated the first 12 to 15 patients with nitrous oxide in Hartford, Connecticut, and, according to his own record, only failed in two cases. In spite of these convincing results having been reported by Wells to the medical society in Boston in December 1844, this new method was not immediately adopted by other dentists. The reason for this was most likely that Wells, in January 1845 at his first public demonstration to the medical faculty in Boston, had been partly unsuccessful, leaving his colleagues doubtful regarding its efficacy and safety. The method did not come into general use until 1863, when Gardner Quincy Colton successfully started to use it in all his "Colton Dental Association" clinics, that he had just established in New Haven and New York City. Over the following three years, Colton and his associates successfully administered nitrous oxide to more than 25,000 patients. Today, nitrous oxide is used in dentistry as an anxiolytic, as an adjunct to local anaesthetic.

Nitrous oxide was not found to be a strong enough anaesthetic for use in major surgery in hospital settings. Instead, diethyl ether, being a stronger and more potent anaesthetic, was demonstrated and accepted for use in October 1846, along with chloroform in 1847. When Joseph Thomas Clover invented the "gas-ether inhaler" in 1876, it became a common practice at hospitals to initiate all anaesthetic treatments with a mild flow of nitrous oxide, and then gradually increase the anaesthesia with the stronger ether or chloroform. Clover's gas-ether inhaler was designed to supply the patient with nitrous oxide and ether at the same time, with the exact mixture being controlled by the operator of the device. It remained in use by many hospitals until the 1930s. Although hospitals today use a more advanced anaesthetic machine, these machines still use the same principle launched with Clover's gas-ether inhaler, to initiate the anaesthesia with nitrous oxide, before the administration of a more powerful anaesthetic.

Colton's popularisation of nitrous oxide led to its adoption by a number of less than reputable quacksalvers, who touted it as a cure for consumption, scrofula, catarrh and other diseases of the blood, throat and lungs. Nitrous oxide treatment was administered and licensed as a patent medicine by the likes of C. L. Blood and Jerome Harris in Boston and Charles E. Barney of Chicago.

Chemical properties and reactions

Nitrous oxide is a colourless gas with a faint, sweet odour.

Nitrous oxide supports combustion by releasing the dipolar bonded oxygen radical, and can thus relight a glowing splint.

N
2
O
is inert at room temperature and has few reactions. At elevated temperatures, its reactivity increases. For example, nitrous oxide reacts with NaNH
2
at 187 °C (369 °F) to give NaN
3
:

2 NaNH2 + N2O → NaN3 + NaOH + NH3

This reaction is the route adopted by the commercial chemical industry to produce azide salts, which are used as detonators.

Mechanism of action

The pharmacological mechanism of action of inhaled N
2
O
is not fully known. However, it has been shown to directly modulate a broad range of ligand-gated ion channels, which likely plays a major role. It moderately blocks NMDAR and β2-subunit-containing nACh channels, weakly inhibits AMPA, kainate, GABAC and 5-HT3 receptors, and slightly potentiates GABAA and glycine receptors. It also has been shown to activate two-pore-domain K+
channels
. While N
2
O
affects several ion channels, its anaesthetic, hallucinogenic and euphoriant effects are likely caused mainly via inhibition of NMDA receptor-mediated currents. In addition to its effects on ion channels, N
2
O
may act similarly to nitric oxide (NO) in the central nervous system. Nitrous oxide is 30 to 40 times more soluble than nitrogen.

The effects of inhaling sub-anaesthetic doses of nitrous oxide may vary unpredictably with settings and individual differences; however, Jay (2008) suggests that it reliably induces the following states and sensations:

  • Intoxication
  • Euphoria/dysphoria
  • Spatial disorientation
  • Temporal disorientation
  • Reduced pain sensitivity

A minority of users also experience uncontrolled vocalisations and muscular spasms. These effects generally disappear minutes after removal of the nitrous oxide source.

Anxiolytic effect

In behavioural tests of anxiety, a low dose of N
2
O
is an effective anxiolytic. This anti-anxiety effect is associated with enhanced activity of GABAA receptors, as it is partially reversed by benzodiazepine receptor antagonists. Mirroring this, animals that have developed tolerance to the anxiolytic effects of benzodiazepines are partially tolerant to N
2
O
. Indeed, in humans given 30% N
2
O
, benzodiazepine receptor antagonists reduced the subjective reports of feeling "high", but did not alter psychomotor performance.

Analgesic effect

The analgesic effects of N
2
O
are linked to the interaction between the endogenous opioid system and the descending noradrenergic system. When animals are given morphine chronically, they develop tolerance to its pain-killing effects, and this also renders the animals tolerant to the analgesic effects of N
2
O
. Administration of antibodies that bind and block the activity of some endogenous opioids (not β-endorphin) also block the antinociceptive effects of N
2
O
. Drugs that inhibit the breakdown of endogenous opioids also potentiate the antinociceptive effects of N
2
O
. Several experiments have shown that opioid receptor antagonists applied directly to the brain block the antinociceptive effects of N
2
O
, but these drugs have no effect when injected into the spinal cord.

Apart from an indirect action, nitrous oxide, like morphine also interacts directly with the endogenous opioid system by binding at opioid receptor binding sites.

Conversely, α2-adrenoceptor antagonists block the pain-reducing effects of N
2
O
when given directly to the spinal cord, but not when applied directly to the brain. Indeed, α2B-adrenoceptor knockout mice or animals depleted in norepinephrine are nearly completely resistant to the antinociceptive effects of N
2
O
. Apparently N
2
O
-induced release of endogenous opioids causes disinhibition of brainstem noradrenergic neurons, which release norepinephrine into the spinal cord and inhibit pain signalling. Exactly how N
2
O
causes the release of endogenous opioid peptides remains uncertain.

Production

Various methods of producing nitrous oxide are used.

Industrial methods

Nitrous oxide production

Nitrous oxide is prepared on an industrial scale by carefully heating ammonium nitrate at about 250 °C, which decomposes into nitrous oxide and water vapour.

NH4NO3 → 2 H2O + N2O

The addition of various phosphate salts favours formation of a purer gas at slightly lower temperatures. This reaction may be difficult to control, resulting in detonation.

Laboratory methods

The decomposition of ammonium nitrate is also a common laboratory method for preparing the gas. Equivalently, it can be obtained by heating a mixture of sodium nitrate and ammonium sulfate:

2 NaNO3 + (NH4)2SO4 → Na2SO4 + 2 N2O + 4 H2O

Another method involves the reaction of urea, nitric acid and sulfuric acid:

2 (NH2)2CO + 2 HNO3 + H2SO4 → 2 N2O + 2 CO2 + (NH4)2SO4 + 2 H2O

Direct oxidation of ammonia with a manganese dioxide-bismuth oxide catalyst has been reported: cf. Ostwald process.

2 NH3 + 2 O2 → N2O + 3 H2O

Hydroxylammonium chloride reacts with sodium nitrite to give nitrous oxide. If the nitrite is added to the hydroxylamine solution, the only remaining by-product is salt water. If the hydroxylamine solution is added to the nitrite solution (nitrite is in excess), however, then toxic higher oxides of nitrogen also are formed:

NH3OHCl + NaNO2 → N2O + NaCl + 2 H2O

Treating HNO
3
with SnCl
2
and HCl also has been demonstrated:

2 HNO3 + 8 HCl + 4 SnCl2 → 5 H2O + 4 SnCl4 + N2O

Hyponitrous acid decomposes to N2O and water with a half-life of 16 days at 25 °C at pH 1–3.

H2N2O2 → H2O + N2O

Atmospheric occurrence

Nitrous oxide (N2O) measured by the Advanced Global Atmospheric Gases Experiment (AGAGE) in the lower atmosphere (troposphere) at stations around the world. Abundances are given as pollution free monthly mean mole fractions in parts-per-billion.
Nitrous oxide atmospheric concentration since 1978
Annual growth rate of atmospheric nitrous oxide since 2000
Earth's nitrous oxide budget from the Global Carbon Project (2020)

Nitrous oxide is a minor component of Earth's atmosphere and is an active part of the planetary nitrogen cycle. Based on analysis of air samples gathered from sites around the world, its concentration surpassed 330 ppb in 2017. The growth rate of about 1 ppb per year has also accelerated during recent decades. Nitrous oxide's atmospheric abundance has grown more than 20% from a base level of about 270 ppb in 1750. Important atmospheric properties of N
2
O
are summarized in the following table:

Property Value
Ozone depletion potential (ODP) 0.017 (CCl3F = 1)
Global warming potential (GWP: 100-year) 273 (CO2 = 1)
Atmospheric lifetime 116 ± 9 years

In 2022 the IPCC reported that: "The human perturbation of the natural nitrogen cycle through the use of synthetic fertilizers and manure, as well as nitrogen deposition resulting from land-based agriculture and fossil fuel burning has been the largest driver of the increase in atmospheric N2O of 31.0 ± 0.5 ppb (10%) between 1980 and 2019."

Emissions by source

17.0 (12.2 to 23.5) million tonnes total annual average nitrogen in N
2
O
was emitted in 2007–2016. About 40% of N
2
O
emissions are from humans and the rest are part of the natural nitrogen cycle. The N
2
O
emitted each year by humans has a greenhouse effect equivalent to about 3 billion tonnes of carbon dioxide: for comparison humans emitted 37 billion tonnes of actual carbon dioxide in 2019, and methane equivalent to 9 billion tonnes of carbon dioxide.

Most of the N
2
O
emitted into the atmosphere, from natural and anthropogenic sources, is produced by microorganisms such as denitrifying bacteria and fungi in soils and oceans. Soils under natural vegetation are an important source of nitrous oxide, accounting for 60% of all naturally produced emissions. Other natural sources include the oceans (35%) and atmospheric chemical reactions (5%). Wetlands can also be emitters of nitrous oxide. Emissions from thawing permafrost may be significant, but as of 2022 this is not certain.

The main components of anthropogenic emissions are fertilised agricultural soils and livestock manure (42%), runoff and leaching of fertilisers (25%), biomass burning (10%), fossil fuel combustion and industrial processes (10%), biological degradation of other nitrogen-containing atmospheric emissions (9%) and human sewage (5%). Agriculture enhances nitrous oxide production through soil cultivation, the use of nitrogen fertilisers and animal waste handling. These activities stimulate naturally occurring bacteria to produce more nitrous oxide. Nitrous oxide emissions from soil can be challenging to measure as they vary markedly over time and space, and the majority of a year's emissions may occur when conditions are favorable during "hot moments" and/or at favorable locations known as "hotspots".

Among industrial emissions, the production of nitric acid and adipic acid are the largest sources of nitrous oxide emissions. The adipic acid emissions specifically arise from the degradation of the nitrolic acid intermediate derived from the nitration of cyclohexanone.

Biological processes

Microbial processes that generate nitrous oxide may be classified as nitrification and denitrification. Specifically, they include:

  • aerobic autotrophic nitrification, the stepwise oxidation of ammonia (NH
    3
    ) to nitrite (NO
    2
    ) and to nitrate (NO
    3
    )
  • anaerobic heterotrophic denitrification, the stepwise reduction of NO
    3
    to NO
    2
    , nitric oxide (NO), N
    2
    O
    and ultimately N
    2
    , where facultative anaerobe bacteria use NO
    3
    as an electron acceptor in the respiration of organic material in the condition of insufficient oxygen (O
    2
    )
  • nitrifier denitrification, which is carried out by autotrophic NH
    3
    -oxidising bacteria and the pathway whereby ammonia (NH
    3
    ) is oxidised to nitrite (NO
    2
    ), followed by the reduction of NO
    2
    to nitric oxide (NO), N
    2
    O
    and molecular nitrogen (N
    2
    )
  • heterotrophic nitrification
  • aerobic denitrification by the same heterotrophic nitrifiers
  • fungal denitrification
  • non-biological chemodenitrification

These processes are affected by soil chemical and physical properties such as the availability of mineral nitrogen and organic matter, acidity and soil type, as well as climate-related factors such as soil temperature and water content.

The emission of the gas to the atmosphere is limited greatly by its consumption inside the cells, by a process catalysed by the enzyme nitrous oxide reductase.

Uses

Rocket motors

Nitrous oxide may be used as an oxidiser in a rocket motor. Compared to other oxidisers, it is much less toxic and more stable at room temperature, making it easier to store and safer to carry on a flight. Its high density and low storage pressure (when maintained at low temperatures) make it highly competitive with stored high-pressure gas systems.

In a 1914 patent, American rocket pioneer Robert Goddard suggested nitrous oxide and gasoline as possible propellants for a liquid-fuelled rocket. Nitrous oxide has been the oxidiser of choice in several hybrid rocket designs (using solid fuel with a liquid or gaseous oxidiser). The combination of nitrous oxide with hydroxyl-terminated polybutadiene fuel has been used by SpaceShipOne and others. It also is notably used in amateur and high power rocketry with various plastics as the fuel.

Nitrous oxide may also be used as a monopropellant. In the presence of a heated catalyst at a temperature of 577 °C (1,071 °F), N
2
O
decomposes exothermically into nitrogen and oxygen. Because of the large heat release, the catalytic action rapidly becomes secondary, as thermal autodecomposition becomes dominant. In a vacuum thruster, this may provide a monopropellant specific impulse (Isp) up to 180 s. While noticeably less than the Isp available from hydrazine thrusters (monopropellant, or bipropellant with dinitrogen tetroxide), the decreased toxicity makes nitrous oxide a worthwhile option.

The ignition of nitrous oxide depends critically on pressure. It deflagrates at approximately 600 °C (1,112 °F) at a pressure of 309 psi (21 atmospheres). At 600 psi, the required ignition energy is only 6 joules, whereas at 130 psi a 2,500-joule ignition energy input is insufficient.

Internal combustion engine

In vehicle racing, nitrous oxide (often called "nitrous") increases engine power by providing more oxygen during combustion, thus allowing the engine to burn more fuel. It is an oxidising agent roughly equivalent to hydrogen peroxide, and much stronger than molecular oxygen. Nitrous oxide is not flammable at low pressure/temperature, but at about 300 °C (572 °F), its breakdown delivers more oxygen than atmospheric air. It often is mixed with another fuel that is easier to deflagrate.

Nitrous oxide is stored as a compressed liquid. In an engine intake manifold, the evaporation and expansion of the liquid causes a large drop in intake charge temperature, resulting in a denser charge and allowing more air/fuel mixture to enter the cylinder. Sometimes nitrous oxide is injected into (or prior to) the intake manifold, whereas other systems directly inject it just before the cylinder (direct port injection).

The technique was used during World War II by Luftwaffe aircraft with the GM-1 system to boost the power output of aircraft engines. Originally meant to provide the Luftwaffe standard aircraft with superior high-altitude performance, technological considerations limited its use to extremely high altitudes. Accordingly, it was only used by specialised planes such as high-altitude reconnaissance aircraft, high-speed bombers and high-altitude interceptor aircraft. It sometimes could be found on Luftwaffe aircraft also fitted with another engine-boost system, MW 50, a form of water injection for aviation engines that used methanol for its boost capabilities.

One of the major problems of nitrous oxide oxidant in a reciprocating engine is excessive power: if the mechanical structure of the engine is not properly reinforced, it may be severely damaged or destroyed. It is important with nitrous oxide augmentation of petrol engines to maintain proper and evenly spread operating temperatures and fuel levels to prevent pre-ignition (also called detonation or spark knock). However, most problems associated with nitrous oxide come not from excessive power but from excessive pressure, since the gas builds up a much denser charge in the cylinder. The increased pressure and temperature can melt, crack, or warp the piston, valve, and cylinder head.

Automotive-grade liquid nitrous oxide differs slightly from medical-grade. A small amount of sulfur dioxide (SO
2
) is added to prevent substance abuse.

Aerosol propellant for food

Food-grade N
2
O
whipped-cream chargers

The gas is approved for use as a food additive (E number: E942), specifically as an aerosol spray propellant. It is commonly used in aerosol whipped cream canisters and cooking sprays.

The gas is extremely soluble in fatty compounds. In pressurised aerosol whipped cream, it is dissolved in the fatty cream until it leaves the can, when it becomes gaseous and thus creates foam. This produces whipped cream four times the volume of the liquid, whereas whipping air into cream only produces twice the volume. Unlike air, nitrous oxide inhibits rancidification of the butterfat. Carbon dioxide cannot be used for whipped cream because it is acidic in water, which would curdle the cream and give it a seltzer-like "sparkle".

Extra-frothed whipped cream produced with nitrous oxide is unstable, and will return to liquid within half an hour to one hour. Thus, it is not suitable for decorating food that will not be served immediately.

In December 2016, there was a shortage of aerosol whipped cream in the United States, with canned whipped cream use at its peak during the Christmas and holiday season, due to an explosion at the Air Liquide nitrous oxide facility in Florida in late August. The company prioritized the remaining supply of nitrous oxide to medical customers rather than to food manufacturing.

Also, cooking spray, made from various oils with lecithin emulsifier, may use nitrous oxide propellant, or alternatively food-grade alcohol or propane.

Medical

Medical-grade N
2
O
tanks used in dentistry

Nitrous oxide has been used in dentistry and surgery, as an anaesthetic and analgesic, since 1844. In the early days, the gas was administered through simple inhalers consisting of a breathing bag made of rubber cloth. Today, the gas is administered in hospitals by means of an automated relative analgesia machine, with an anaesthetic vaporiser and a medical ventilator, that delivers a precisely dosed and breath-actuated flow of nitrous oxide mixed with oxygen in a 2:1 ratio.

Nitrous oxide is a weak general anaesthetic, and so is generally not used alone in general anaesthesia, but used as a carrier gas (mixed with oxygen) for more powerful general anaesthetic drugs such as sevoflurane or desflurane. It has a minimum alveolar concentration of 105% and a blood/gas partition coefficient of 0.46. The use of nitrous oxide in anaesthesia can increase the risk of postoperative nausea and vomiting.

Dentists use a simpler machine which only delivers an N
2
O
/O
2
mixture for the patient to inhale while conscious but must still be a recognised purpose designed dedicated relative analgesic flowmeter with a minimum 30% of oxygen at all times and a maximum upper limit of 70% nitrous oxide. The patient is kept conscious throughout the procedure, and retains adequate mental faculties to respond to questions and instructions from the dentist.

Inhalation of nitrous oxide is used frequently to relieve pain associated with childbirth, trauma, oral surgery and acute coronary syndrome (including heart attacks). Its use during labour has been shown to be a safe and effective aid for birthing women. Its use for acute coronary syndrome is of unknown benefit.

In Canada and the UK, Entonox and Nitronox are used commonly by ambulance crews (including unregistered practitioners) as rapid and highly effective analgesic gas.

Fifty percent nitrous oxide can be considered for use by trained non-professional first aid responders in prehospital settings, given the relative ease and safety of administering 50% nitrous oxide as an analgesic. The rapid reversibility of its effect would also prevent it from precluding diagnosis.

Recreational

Aquatint depiction of a laughing gas party in the nineteenth century, by Thomas Rowlandson
Street sign indicating ban of nitrous oxide use near the Poelestraat in Groningen
Whippit remnants (the small steel canisters) of recreational drug use, the Netherlands, 2017

Recreational inhalation of nitrous oxide, to induce euphoria and slight hallucinations, began with the British upper class in 1799 in gatherings known as "laughing gas parties".

From the 19th century, the widespread availability of the gas for medical and culinary purposes allowed for recreational use to greatly expand globally. In the UK as of 2014, nitrous oxide was estimated to be used by almost half a million young people at nightspots, festivals and parties.

Widespread recreational use of the drug throughout the UK was featured in the 2017 Vice documentary Inside The Laughing Gas Black Market, in which journalist Matt Shea met with dealers of the drug who stole it from hospitals.

A significant issue cited in London's press is the effect of nitrous oxide canister littering, which is highly visible and causes significant complaints from communities.

Prior to 8 November 2023 in the UK, nitrous oxide was subject to the Psychoactive Substances Act 2016, making it illegal to produce, supply, import or export nitrous oxide for recreational use. The updated law prohibited possession of nitrous oxide, classifying it as a Class C drug under the Misuse of Drugs Act 1971.

While nitrous oxide is understood by most recreational users to give a "safe high", many are unaware that excessive consumption may cause neurological harm which, if left untreated, can cause permanent neurological damage. In Australia, recreation use became a public health concern following a rise in reports of neurotoxicity and emergency room admissions. In the state of South Australia, legislation was passed in 2020 to restrict canister sales.

In 2024, under the street name "Galaxy Gas", nitrous oxide has exploded in popularity among young people for recreational use. Most of the popularity has been fostered through TikTok.

Safety

Nitrous oxide is a significant occupational hazard for surgeons, dentists and nurses. Because the gas is minimally metabolised in humans (with a rate of 0.004%), it retains its potency when exhaled into the room by the patient, and can intoxicate the clinic staff if the room is poorly ventilated, with potential chronic exposure. A continuous-flow fresh-air ventilation system or N
2
O
scavenger system may be needed to prevent waste-gas buildup. The National Institute for Occupational Safety and Health recommends that workers' exposure to nitrous oxide should be controlled during the administration of anaesthetic gas in medical, dental and veterinary operators. It set a recommended exposure limit (REL) of 25 ppm (46 mg/m3) to escaped anaesthetic.

Exposure to nitrous oxide causes short-term impairment of cognition, audiovisual acuity, and manual dexterity, as well as spatial and temporal disorientation, putting the user at risk of accidental injury.

Nitrous oxide is neurotoxic, and medium or long-term habitual consumption of significant quantities can cause neurological harm with the potential for permanent damage if left untreated. It is believed that, like other NMDA receptor antagonists, N
2
O
produces Olney's lesions in rodents upon prolonged (several hour) exposure. However, because it is normally expelled from the body rapidly, it is less likely to be neurotoxic than other NMDAR antagonists. In rodents, short-term exposure results in only mild injury that is rapidly reversible, and neuronal death occurs only after constant and sustained exposure. Nitrous oxide may also cause neurotoxicity after extended exposure because of hypoxia. This is especially true of non-medical formulations such as whipped-cream chargers ("whippits" or "nangs"), which contain no oxygen gas.

In reports to poison control centers, heavy users (≥400 g or ≥200 L of N2O gas in one session) or frequent users (regular, i.e., daily or weekly) have developed signs of peripheral neuropathy: ataxia (gait abnormalities) or paresthesia (perception of sensations such as tingling, numbness, or prickling, mostly in the extremities). Such early signs of neurological damage indicate chronic toxicity.

Nitrous oxide might have therapeutic use in treating stroke. In a rodent model, nitrous oxide at 75% by volume reduced ischemia-induced neuronal death induced by occlusion of the middle cerebral artery, and decreased NMDA-induced Ca2+ influx in neuronal cell cultures, a cause of excitotoxicity.

Occupational exposure to ambient nitrous oxide has been associated with DNA damage, due to interruptions in DNA synthesis. This correlation is dose-dependent and does not appear to extend to casual recreational use; however, further research is needed to confirm the level of exposure needed to cause damage.

Inhalation of pure nitrous oxide causes oxygen deprivation, resulting in low blood pressure, fainting, and even heart attacks. This can occur if the user inhales large quantities continuously, as with a strap-on mask connected to a gas canister or other inhalation system, or prolonged breath-holding.

Long-term exposure to nitrous oxide may cause vitamin B12 deficiency. This can cause serious neurotoxicity if the user has preexisting vitamin B12 deficiency. It inactivates the cobalamin form of vitamin B12 by oxidation. Symptoms of vitamin B12 deficiency, including sensory neuropathy, myelopathy and encephalopathy, may occur within days or weeks of exposure to nitrous oxide anaesthesia in people with subclinical vitamin B12 deficiency. Symptoms are treated with high doses of vitamin B12, but recovery can be slow and incomplete. People with normal vitamin B12 levels have stores to make the effects of nitrous oxide insignificant, unless exposure is repeated and prolonged (nitrous oxide abuse). Vitamin B12 levels should be checked in people with risk factors for vitamin B12 deficiency prior to using nitrous oxide anaesthesia.

Several experimental studies in rats indicate that chronic exposure of pregnant females to nitrous oxide may have adverse effects on the developing fetus.

At room temperature (20 °C [68 °F]) the saturated vapour pressure is 50.525 bar, rising up to 72.45 bar at 36.4 °C (97.5 °F)—the critical temperature. The pressure curve is thus unusually sensitive to temperature. As with many strong oxidisers, contamination of parts with fuels have been implicated in rocketry accidents, where small quantities of nitrous/fuel mixtures explode due to "water hammer"-like effects (sometimes called "dieseling"—heating due to adiabatic compression of gases can reach decomposition temperatures). Some common building materials such as stainless steel and aluminium can act as fuels with strong oxidisers such as nitrous oxide, as can contaminants that may ignite due to adiabatic compression. There also have been incidents where nitrous oxide decomposition in plumbing has led to the explosion of large tanks.

Environmental impact

Global accounting of N
2
O
sources and sinks over the decade ending 2016 indicates that about 40% of the average 17 TgN/yr (teragrams, or million metric tons, of nitrogen per year) of emissions originated from human activity, and shows that emissions growth chiefly came from expanding agriculture.

Trends in the atmospheric abundance of long-lived greenhouse gases

Nitrous oxide has significant global warming potential as a greenhouse gas. On a per-molecule basis, considered over a 100-year period, nitrous oxide has 265 times the atmospheric heat-trapping ability of carbon dioxide (CO
2
). However, because of its low concentration (less than 1/1,000 of that of CO
2
), its contribution to the greenhouse effect is less than one third that of carbon dioxide, and also less than methane. On the other hand, since about 40% of the N
2
O
entering the atmosphere is the result of human activity, control of nitrous oxide is part of efforts to curb greenhouse gas emissions.

Most human caused nitrous oxide released into the atmosphere is a greenhouse gas emission from agriculture, when farmers add nitrogen-based fertilizers onto the fields, and through the breakdown of animal manure. Reduction of emissions can be a hot topic in the politics of climate change.

Nitrous oxide is also released as a by-product of burning fossil fuel, though the amount released depends on which fuel was used. It is also emitted through the manufacture of nitric acid, which is used in the synthesis of nitrogen fertilizers. The production of adipic acid, a precursor to nylon and other synthetic clothing fibres, also releases nitrous oxide.

A rise in atmospheric nitrous oxide concentrations has been implicated as a possible contributor to the extremely intense global warming during the Cenomanian-Turonian boundary event.

Nitrous oxide has also been implicated in thinning the ozone layer. A 2009 study suggested that N
2
O
emission was the single most important ozone-depleting emission and it was expected to remain the largest throughout the 21st century.

Legality

In India transfer of nitrous oxide from bulk cylinders to smaller, more transportable E-type, 1,590-litre-capacity tanks is legal when intended for medical anaesthesia.

The New Zealand Ministry of Health has warned that nitrous oxide is a prescription medicine whose sale or possession without a prescription is an offense under the Medicines Act. This would seemingly prohibit all non-medicinal uses of nitrous oxide, although it is implied that only recreational use will be targeted.

In August 2015, the Council of the London Borough of Lambeth (UK) banned the use of the drug for recreational purposes, making offenders liable to an on-the-spot fine of up to £1,000. In September 2023, the UK Government announced that nitrous oxide would be made illegal by the end of the year as a class C drug, with possession potentially carrying up to a two-year prison sentence or an unlimited fine.

Possession of nitrous oxide is legal under United States federal law and is not subject to DEA purview. It is, however, regulated by the Food and Drug Administration under the Food Drug and Cosmetics Act; prosecution is possible under its "misbranding" clauses, prohibiting the sale or distribution of nitrous oxide for the purpose of human consumption without a proper medical license. Many states have laws regulating the possession, sale and distribution of nitrous oxide. Such laws usually ban distribution to minors or limit the amount that may be sold without special license. For example, in California, possession for recreational use is prohibited and qualifies as a misdemeanor.

Linear no-threshold model

From Wikipedia, the free encyclopedia   https://en.wikipedia.org/wiki/L...