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Thursday, January 11, 2024

History of gunpowder

From Wikipedia, the free encyclopedia
Earliest known written formula for gunpowder, from the Wujing Zongyao of 1044 AD.

Gunpowder is the first explosive to have been developed. Popularly listed as one of the "Four Great Inventions" of China, it was invented during the late Tang dynasty (9th century) while the earliest recorded chemical formula for gunpowder dates to the Song dynasty (11th century). Knowledge of gunpowder spread rapidly throughout Asia and Europe, possibly as a result of the Mongol conquests during the 13th century, with written formulas for it appearing in the Middle East between 1240 and 1280 in a treatise by Hasan al-Rammah, and in Europe by 1267 in the Opus Majus by Roger Bacon. It was employed in warfare to some effect from at least the 10th century in weapons such as fire arrows, bombs, and the fire lance before the appearance of the gun in the 13th century. While the fire lance was eventually supplanted by the gun, other gunpowder weapons such as rockets and fire arrows continued to see use in China, Korea, India, and this eventually led to its use in the Middle East, Europe, and Africa. Bombs too never ceased to develop and continued to progress into the modern day as grenades, mines, and other explosive implements. Gunpowder has also been used for non-military purposes such as fireworks for entertainment, or in explosives for mining and tunneling.

The evolution of guns led to the development of large artillery pieces, popularly known as bombards, during the 15th century, pioneered by states such as the Duchy of Burgundy. Firearms came to dominate early modern warfare in Europe by the 17th century. The gradual improvement of cannons firing heavier rounds for a greater impact against fortifications led to the invention of the star fort and the bastion in the Western world, where traditional city walls and castles were no longer suitable for defense. The use of gunpowder technology also spread throughout the Islamic world and to India, Korea, and Japan. The so-called Gunpowder Empires of the early modern period consisted of the Mughal Empire, Safavid Empire, and Ottoman Empire.

The use of gunpowder in warfare during the course of the 19th century diminished due to the invention of smokeless powder. Gunpowder is often referred to today as "black powder" to distinguish it from the propellant used in contemporary firearms.

Chinese beginnings

A fire arrow using a bag of gunpowder as incendiary. As depicted in the Huolongjing (c. 1390).
Depiction of fire arrows known as "divine engine arrows" (shen ji jian 神機箭) from the Wubei Zhi (1621).
The 'divine flying fire crow' (shen huo fei ya), an aerodynamic winged rocket bomb from the Huolongjing

Gunpowder formula

Gunpowder was invented in China sometime during the first millennium AD. The earliest possible reference to gunpowder appeared in 142 AD during the Eastern Han dynasty when the alchemist Wei Boyang, also known as the "father of alchemy", wrote about a substance with gunpowder-like properties. He described a mixture of three powders that would "fly and dance" violently in his Cantong qi, otherwise known as the Book of the Kinship of Three, a Taoist text on the subject of alchemy. At this time, saltpeter was produced in Hanzhong, but would shift to Gansu and Sichuan later on. Wei Boyang is considered to be a semi-legendary figure meant to represent a "collective unity", and the Cantong qi was probably written in stages from the Han dynasty to 450 AD.

While it was almost certainly not their intention to create a weapon of war, Taoist alchemists continued to play a major role in gunpowder development due to their experiments with sulfur and saltpeter involved in searching for eternal life and ways to transmute one material into another. Historian Peter Lorge notes that despite the early association of gunpowder with Taoism, this may be a quirk of historiography and a result of the better preservation of texts associated with Taoism, rather than being a subject limited to only Taoists. The Taoist quest for the elixir of life attracted many powerful patrons, one of whom was Emperor Wu of Han. One of the resulting alchemical experiments involved heating 10% sulfur and 75% saltpeter to transform them.

The next reference to gunpowder occurred in the year 300 during the Jin dynasty (266–420). A Taoist philosopher by the name of Ge Hong wrote down the ingredients of gunpowder in his surviving works, collectively known as the Baopuzi ("The Master Who Embraces Simplicity"). The "Inner Chapters" (neipian) on Taoism contains records of his experiments to create gold with heated saltpeter, pine resin, and charcoal among other carbon materials, resulting in a purple powder and arsenic vapours. In 492, Taoist alchemists noted that saltpeter, one of the most important ingredients in gunpowder, burns with a purple flame, allowing for practical efforts at purifying the substance. During the Tang dynasty, alchemists used saltpeter in processing the "four yellow drugs" (sulfur, realgar, orpiment, arsenic trisulfide).

The first confirmed reference to what can be considered gunpowder in China occurred more than three hundred years later during the Tang dynasty, first in a formula contained in the Taishang Shengzu Jindan Mijue (太上聖祖金丹秘訣) in 808, and then about 50 years later in a Taoist text known as the Zhenyuan miaodao yaolüe (真元妙道要略). The first formula was a combination of six parts sulfur to six parts saltpeter to one part birthwort herb. The Taoist text warned against an assortment of dangerous formulas, one of which corresponds with gunpowder: "Some have heated together sulfur, realgar (arsenic disulfide), and saltpeter with honey; smoke [and flames] result, so that their hands and faces have been burnt, and even the whole house burned down." Alchemists called this discovery fire medicine ("huoyao" 火藥), and the term has continued to refer to gunpowder in China into the present day, a reminder of its heritage as a side result in the search for longevity increasing drugs. A book published in 1185 called Gui Dong (The Control of Spirits) also contains a story about a Tang dynasty alchemist whose furnace exploded, but it is not known if this was caused by gunpowder.

The earliest surviving chemical formula of gunpowder dates to 1044 in the form of the military manual Wujing Zongyao, also known in English as the Complete Essentials for the Military Classics, which contains a collection of entries on Chinese weaponry. However the 1044 edition has since been lost and the only currently extant copy is dated to 1510 during the Ming dynasty. The Wujing Zongyao served as a repository of antiquated or fanciful weaponry, and this applied to gunpowder as well, suggesting that it had already been weaponized long before the invention of what would today be considered conventional firearms. These types of gunpowder weapons styles an assortment of odd names such as "flying incendiary club for subjugating demons", "caltrop fire ball", "ten-thousand fire flying sand magic bomb", "big bees nest", "burning heaven fierce fire unstoppable bomb", "fire bricks" which released "flying swallows", "flying rats", "fire birds", and "fire oxen". Eventually they gave way and coalesced into a smaller number of dominant weapon types, notably gunpowder arrows, bombs, and guns. This was most likely because some weapons were deemed too onerous or ineffective to deploy.

Fire arrows

The early gunpowder formula contained too little saltpeter (about 50%) to be explosive, but the mixture was highly flammable, and contemporary weapons reflected this in their deployment as mainly shock and incendiary weapons. One of the first, if not the first of these weapons was the fire arrow. The first possible reference to the use of fire arrows was by the Southern Wu in 904 during the siege of Yuzhang. An officer under Yang Xingmi by the name of Zheng Fan (鄭璠) ordered his troops to "shoot off a machine to let fire and burn the Longsha Gate", after which he and his troops dashed over the fire into the city and captured it, and he was promoted to Prime Minister Inspectorate for his efforts and the burns his body endured. A later account of this event corroborated with the report and explained that "by let fire (飛火) is meant things like firebombs and fire arrows." Arrows carrying gunpowder were possibly the most applicable form of gunpowder weaponry at the time. Early gunpowder may have only produced an effective flame when exposed to oxygen, thus the rush of air around the arrow in flight would have provided a suitably ample supply of reactants for the reaction.

Rockets

The first fire arrows were arrows strapped with gunpowder incendiaries but they eventually became gunpowder propelled projectiles (rockets). It's not certain when this happened. According to the History of Song, in 969 two Song generals, Yue Yifang and Feng Jisheng (馮繼升), invented a variant fire arrow which used gunpowder tubes as propellants. These fire arrows were shown to the emperor in 970 when the head of a weapons manufacturing bureau sent Feng Jisheng to demonstrate the gunpowder arrow design, for which he was heavily rewarded. However Joseph Needham argues that rockets could not have existed before the 12th century, since the gunpowder formulas listed in the Wujing Zongyao are not suitable as rocket propellant. According to Stephen G. Haw, there is only slight evidence that rockets existed prior to 1200 and it is more likely they were not produced or used for warfare until the latter half of the 13th century. Rockets are recorded to have been used by the Song navy in a military exercise dated to 1245. Internal-combustion rocket propulsion is mentioned in a reference to 1264, recording that the 'ground-rat,' a type of firework, had frightened the Empress-Mother Gongsheng at a feast held in her honor by her son the Emperor Lizong.

In 975, the state of Wuyue sent to the Song dynasty a unit of soldiers skilled in the handling of fire arrows and in the same year, the Song used fire arrows to destroy the fleet of Southern Tang. In 994, the Liao dynasty attacked the Song and laid siege to Zitong with 100,000 troops. They were repelled with the aid of fire arrows. In 1000 a soldier by the name of Tang Fu (唐福) also demonstrated his own designs of gunpowder arrows, gunpowder pots (a proto-bomb which spews fire), and gunpowder caltrops, for which he was richly rewarded as well.

The imperial court took great interest in the progress of gunpowder developments and actively encouraged as well as disseminated military technology. For example, in 1002 a local militia man named Shi Pu (石普) showed his own versions of fireballs and gunpowder arrows to imperial officials. They were so astounded that the emperor and court decreed that a team would be assembled to print the plans and instructions for the new designs to promulgate throughout the realm. The Song court's policy of rewarding military innovators was reported to have "brought about a great number of cases of people presenting technology and techniques" (器械法式) according to the official History of Song. Production of gunpowder and fire arrows heavily increased in the 11th century as the court centralized the production process, constructing large gunpowder production facilities, hiring artisans, carpenters, and tanners for the military production complex in the capital of Kaifeng. One surviving source circa 1023 lists all the artisans working in Kaifeng while another notes that in 1083 the imperial court sent 100,000 gunpowder arrows to one garrison and 250,000 to another.

Evidence of gunpowder in the Liao dynasty and Western Xia is much sparser than in Song, but some evidence such as the Song decree of 1073 that all subjects were henceforth forbidden from trading sulfur and saltpeter across the Liao border, suggests that the Liao were aware of gunpowder developments to the south and coveted gunpowder ingredients of their own.

Explosives

An illustration of a thunderclap bomb as depicted in the 1044 text Wujing Zongyao. The top item is a through awl and the bottom one is a hook awl, used to ignite the projectile before it was hurled.
A later fire lance shooting a blast of flame with lead pellets as co-viative projectiles. The 'phalanx-charging fire-gourd' (chong zhen huo hu-lu 衝陣火葫蘆) forgoes the spearhead and relies solely on the force of gunpowder and projectiles. As depicted in the Huolongjing, a 14th-century military treatise.

Gunpowder bombs had been mentioned since the 11th century. In 1000 AD, a soldier by the name of Tang Fu (唐福) demonstrated a design of gunpowder pots (a proto-bomb which spews fire) and gunpowder caltrops, for which he was richly rewarded. In the same year, Xu Dong wrote that trebuchets used bombs that were like "flying fire", suggesting that they were incendiaries. In the military text Wujing Zongyao of 1044, bombs such as the "ten-thousand fire flying sand magic bomb", "burning heaven fierce fire unstoppable bomb", and "thunderclap bomb" (pilipao) were mentioned. However detailed accounts of their use did not appear until the 12th century.

The Jurchen people of Manchuria united under Wanyan Aguda and established the Jin dynasty in 1115. Allying with the Song, they rose rapidly to the forefront of East Asian powers and defeated the Liao dynasty in a shockingly short span of time, destroying the 150-year balance of power between the Song, Liao, and Western Xia. Remnants of the Liao fled to the west and became known as the Qara Khitai, or Western Liao to the Chinese. In the east, the fragile Song-Jin alliance dissolved once the Jin saw how badly the Song army had performed against Liao forces. Realizing the weakness of Song, the Jin grew tired of waiting and captured all five of the Liao capitals themselves. They proceeded to make war on Song, initiating the Jin-Song Wars.

For the first time, two major powers would have access to equally formidable gunpowder weapons. Initially the Jin expected their campaign in the south to proceed smoothly given how poorly the Song had fared against the Liao. However they were met with stout resistance upon besieging Kaifeng in 1126 and faced the usual array of gunpowder arrows and fire bombs, but also a weapon called the "thunderclap bomb" (霹靂炮), which one witness wrote, "At night the thunderclap bombs were used, hitting the lines of the enemy well, and throwing them into great confusion. Many fled, screaming in fright." The thunderclap bomb was previously mentioned in the Wujing Zongyao, but this was the first recorded instance of its use. Its description in the text reads thus:

The thunderclap bomb contains a length of two or three internodes of dry bamboo with a diameter of 1.5 in. There must be no cracks, and the septa are to be retained to avoid any leakage. Thirty pieces of thin broken porcelain the size of iron coins are mixed with 3 or 4 lb of gunpowder, and packed around the bamboo tube. The tube is wrapped within the ball, but with about an inch or so protruding at each end. A (gun)powder mixture is then applied all over the outer surface of the ball.

Jin troops withdrew with a ransom of Song silk and treasure but returned several months later with their own gunpowder bombs manufactured by captured Song artisans. According to historian Wang Zhaochun, the account of this battle provided the "earliest truly detailed descriptions of the use of gunpowder weapons in warfare." Records show that the Jin used gunpowder arrows and trebuchets to hurl gunpowder bombs while the Song responded with gunpowder arrows, fire bombs, thunderclap bombs, and a new addition called the "molten metal bomb" (金汁炮). As the Jin account describes, when they attacked the city's Xuanhua Gate, their "fire bombs fell like rain, and their arrows were so numerous as to be uncountable." The Jin captured Kaifeng despite the appearance of the molten metal bomb and secured another 20,000 fire arrows for their arsenal.

The molten metal bomb appeared again in 1129 when Song general Li Yanxian (李彥仙) clashed with Jin forces while defending a strategic pass. The Jin assault lasted day and night without respite, using siege carts, fire carts, and sky bridges, but each assault was met with Song soldiers who "resisted at each occasion, and also used molten metal bombs. Wherever the gunpowder touched, everything would disintegrate without a trace."

Fire lance

First illustration of a fire lance and lobbed bomb, mid-10th Century, from Dunhuang, Buddhist silk banner painting from the Five Dynasties and Ten Kingdoms period

The Song relocated their capital to Hangzhou and the Jin followed. The fighting that ensued would see the first proto-gun, the fire lance, in action – with earliest confirmed employment by Song dynasty forces against the Jin in 1132 during the siege of De'an (modern Anlu, Hubei), Most Chinese scholars reject the appearance of the fire lance prior to the Jin-Song wars, but its first appearance in art with a silk banner painting from Dunhuang dates to the Five Dynasties and Ten Kingdoms period in the mid-10th century.

The siege of De'an marks an important transition and landmark in the history of gunpowder weapons as the fire medicine of the fire lances were described using a new word: "fire bomb medicine" (火炮藥), rather than simply "fire medicine." This could imply the use of a new more potent formula, or simply an acknowledgement of the specialized military application of gunpowder. Peter Lorge suggests that this "bomb powder" may have been corned, making it distinct from normal gunpowder. Evidence of gunpowder firecrackers also points to their appearance at roughly around the same time fire medicine was making its transition in the literary imagination.

Fire lances continued to be used as anti-personnel weapons into the Ming dynasty, and were even attached to battle carts on one situation in 1163. Song commander Wei Sheng constructed several hundred of these carts known as "at-your-desire-war-carts" (如意戰車), which contained fire lances protruding from protective covering on the sides. They were used to defend mobile trebuchets that hurled fire bombs. They were used as cavalry weapons by the 13th century.

Naval bombs

Gunpowder technology also spread to naval warfare and in 1129 Song decreed that all warships were to be fitted with trebuchets for hurling gunpowder bombs. Older gunpowder weapons such as fire arrows were also used. In 1159 a Song fleet of 120 ships caught a Jin fleet at anchor near Shijiu Island (石臼島) off the shore of Shandong peninsula. The Song commander "ordered that gunpowder arrows be shot from all sides, and wherever they struck, flames and smoke rose up in swirls, setting fire to several hundred vessels." Song forces took another victory in 1161 when Song paddle boats ambushed a Jin transport fleet, launched thunderclap bombs, and drowned the Jin force in the Yangtze.

The men inside them paddled fast on the treadmills, and the ships glided forwards as though they were flying, yet no one was visible on board. The enemy thought that they were made of paper. Then all of a sudden a thunderclap bomb was let off: It was made with paper (carton) and filled with lime and sulphur. (Launched from trebuchets) these thunderclap bombs came dropping down from the air, and upon meeting the water exploded with a noise like thunder, the sulphur bursting into flames. The carton case rebounded and broke, scattering the lime to form a smoky fog which blinded the eyes of men and horses so that they could see nothing. Our ships then went forward to attack theirs, and their men and horses were all drowned, so that they were utterly defeated.

— Hai Qiu Fu

According to a minor military official by the name of Zhao Wannian (趙萬年), thunderclap bombs were used again to great effect by the Song during the Jin siege of Xiangyang in 1206–1207. Both sides had gunpowder weapons, but the Jin troops only used gunpowder arrows for destroying the city's moored vessels. The Song used fire arrows, fire bombs, and thunderclap bombs. Fire arrows and bombs were used to destroy Jin trebuchets. The thunderclap bombs were used on Jin soldiers themselves, causing foot soldiers and horsemen to panic and retreat. "We beat our drums and yelled from atop the city wall, and simultaneously fired our thunderclap missiles out from the city walls. The enemy cavalry was terrified and ran away." The Jin were forced to retreat and make camp by the riverside. In a rare occurrence, the Song made a successful offensive on Jin forces and conducted a night assault using boats. They were loaded with gunpowder arrows, thunderclap bombs, a thousand crossbowmen, five hundred infantry, and a hundred drummers. Jin troops were surprised in their encampment while asleep by loud drumming, followed by an onslaught of crossbow bolts, and then thunderclap bombs, which caused a panic of such magnitude that they were unable to even saddle themselves and trampled over each other trying to get away. Two to three thousand Jin troops were slaughtered along with eight to nine hundred horses.

Hard-shell explosives

The introduction of the iron bomb was significant to the history of gunpowder weaponry. Traditionally the inspiration for the development of the iron bomb is ascribed to the tale of a fox hunter named Iron Li. According to the story, around the year 1189 Iron Li developed a new method for hunting foxes which used a ceramic explosive to scare foxes into his nets. The explosive consisted of a ceramic bottle with a mouth, stuffed with gunpowder, and attached with a fuse. Explosive and net were placed at strategic points of places such as watering holes frequented by foxes, and when they got near enough, Iron Li would light the fuse, causing the ceramic bottle to explode and scaring the frightened foxes right into his nets. While a fanciful tale, it's not exactly certain why this would cause the development of the iron bomb, given the explosive was made using ceramics, and other materials such as bamboo or even leather would have done the same job, assuming they made a loud enough noise. Nonetheless, the iron bomb made its first appearance in 1221 at the siege of Qizhou (in modern Hubei), and this time it would be the Jin who possessed the technological advantage. The Song commander Zhao Yurong (趙與褣) survived and was able to relay his account for posterity.

Qizhou was a major fortress city situated near the Yangtze and a 25 thousand strong Jin army advanced on it in 1221. News of the approaching army reached Zhao Yurong in Qizhou, and despite being outnumbered nearly eight to one, he decided to hold the city. Qizhou's arsenal consisted of some three thousand thunderclap bombs, twenty thousand "great leather bombs" (皮大炮), and thousands of gunpowder arrows and gunpowder crossbow bolts. While the formula for gunpowder had become potent enough to consider the Song bombs to be true explosives, they were unable to match the explosive power of the Jin iron bombs. Yurong describes the uneven exchange thus, "The barbaric enemy attacked the Northwest Tower with an unceasing flow of catapult projectiles from thirteen catapults. Each catapult shot was followed by an iron fire bomb [catapult shot], whose sound was like thunder. That day, the city soldiers in facing the catapult shots showed great courage as they maneuvered [our own] catapults, hindered by injuries from the iron fire bombs. Their heads, their eyes, their cheeks were exploded to bits, and only one half [of the face] was left." Jin artillerists were able to successfully target the command center itself: "The enemy fired off catapult stones ... nonstop day and night, and the magistrate's headquarters [帳] at the eastern gate, as well as my own quarters ..., were hit by the most iron fire bombs, to the point that they struck even on top of [my] sleeping quarters and [I] nearly perished! Some said there was a traitor. If not, how would they have known the way to strike at both of these places?"

Zhao was able to examine the new iron bombs himself and described thus, "In shape they are like gourds, but with a small mouth. They are made with pig iron, about two inches thick, and they cause the city's walls to shake." Houses were blown apart, towers battered, and defenders blasted from their placements. Within four weeks all four gates were under heavy bombardment. Finally the Jin made a frontal assault on the walls and scaled them, after which followed a merciless hunt for soldiers, officers, and officials of every level. Zhao managed an escape by clambering over the battlement and making a hasty retreat across the river, but his family remained in the city. Upon returning at a later date to search the ruins, he found that the "bones and skeletons were so mixed up that there was no way to tell who was who."

Hand cannon

Bronze cannon with inscription dated the 3rd year of the Zhiyuan era (1332) of the Yuan Dynasty (1271–1368); it was discovered at the Yunju Temple of Fangshan District, Beijing in 1935.
Cannon with trunnions, Yuan Dynasty (1271–1368).
Hand cannon from the Yuan Dynasty (1271–1368).

The early fire lance, considered to be the ancestor of firearms, is not considered a true gun because it did not include projectiles, whereas a gun by definition uses "the explosive force of the gunpowder to propel a projectile from a tube: cannons, muskets, and pistols are typical examples.". Even later on when shrapnel such as ceramics and bits of iron were added to the fire lance, these didn't occlude the barrel, and were only swept along with the discharge rather than making use of windage, and so are referred to as "co-viatives."

In 1259 a type of "fire-emitting lance" (tuhuoqiang 突火槍) made an appearance and according to the History of Song: "It is made from a large bamboo tube, and inside is stuffed a pellet wad (子窠). Once the fire goes off it completely spews the rear pellet wad forth, and the sound is like a bomb that can be heard for five hundred or more paces." The pellet wad mentioned is possibly the first true bullet in recorded history depending on how bullet is defined, as it did occlude the barrel, unlike previous co-viatives used in the fire lance. Fire lances transformed from the "bamboo- (or wood- or paper-) barreled firearm to the metal-barreled firearm" to better withstand the explosive pressure of gunpowder. From there it branched off into several different gunpowder weapons known as "eruptors" in the late 12th and early 13th centuries, with different functions such as the "filling-the-sky erupting tube" which spewed out poisonous gas and porcelain shards, the "orifice-penetrating flying sand magic mist tube" (鑽穴飛砂神霧筒) which spewed forth sand and poisonous chemicals into orifices, and the more conventional "phalanx-charging fire gourd" which shot out lead pellets.

The earliest artistic depiction of what might be a hand cannon – a rock sculpture found among the Dazu Rock Carvings – is dated to 1128, much earlier than any recorded or precisely dated archaeological samples, so it is possible that the concept of a cannon-like firearm has existed since the 12th century. This has been challenged by others such as Liu Xu, Cheng Dong, and Benjamin Avichai Katz Sinvany. According to Liu, the weight of the cannon would have been too much for one person to hold, especially with just one arm, and points out that fire lances were being used a decade later at De'an. Cheng Dong believes that the figure depicted is actually a wind spirit letting air out of a bag rather than a cannon emitting a blast. Stephen Haw also considered the possibility that the item in question was a bag of air but concludes that it is a cannon because it was grouped with other weapon wielding sculptures. Sinvany believes in the wind bag interpretation and that the cannonball indentation was added later on.

Archaeological samples of the gun, specifically the hand cannon (huochong), have been dated starting from the 13th century. The oldest extant gun whose dating is unequivocal is the Xanadu Gun because it contains an inscription describing its date of manufacture corresponding to 1298. It is so called because it was discovered in the ruins of Xanadu, the Mongol summer palace in Inner Mongolia. The Xanadu Gun is 34.7 cm in length and weighs 6.2 kg. The design of the gun includes axial holes in its rear which some speculate could have been used in a mounting mechanism. Like most early guns it is small, weighing just over six kilograms and thirty-five centimeters in length. Although the Xanadu Gun is the most precisely dated gun from the 13th century, other extant samples with approximate dating likely predate it. The Heilongjiang hand cannon is dated a decade earlier to 1288, but the dating method is based on contextual evidence; the gun bears no inscription or era date. According to the History of Yuan, in 1287, a group of soldiers equipped with hand cannons led by the Jurchen commander Li Ting (李庭) attacked the rebel prince Nayan's camp. The History reports that the hand cannons not only "caused great damage," but also caused "such confusion that the enemy soldiers attacked and killed each other." The hand cannons were used again in the beginning of 1288. Li Ting's "gun-soldiers" or chongzu (銃卒) were able to carry the hand cannons "on their backs". The passage on the 1288 battle is also the first to coin the name chong () for metal-barrel firearms. Chong was used instead of the earlier and more ambiguous term huo tong (fire tube; 火筒), which may refer to the tubes of fire lances, proto-cannons, or signal flares.

Another specimen, the Wuwei Bronze Cannon, was discovered in 1980 and may possibly be the oldest as well as largest cannon of the 13th century: a 100 centimeter 108 kilogram bronze cannon discovered in a cellar in Wuwei, Gansu containing no inscription, but has been dated by historians to the late Western Xia period between 1214 and 1227. The gun contained an iron ball about nine centimeters in diameter, which is smaller than the muzzle diameter at twelve centimeters, and 0.1 kilograms of gunpowder in it when discovered, meaning that the projectile might have been another co-viative. Ben Sinvany and Dang Shoushan believe that the ball used to be much larger prior to its highly corroded state at the time of discovery. While large in size, the weapon is noticeably more primitive than later Yuan dynasty guns, and is unevenly cast. A similar weapon was discovered not far from the discovery site in 1997, but much smaller in size at only 1.5 kg. Chen Bingying disputes this however, and argues there were no guns before 1259, while Dang Shoushan believes the Western Xia guns point to the appearance of guns by 1220, and Stephen Haw goes even further by stating that guns were developed as early as 1200. Sinologist Joseph Needham and renaissance siege expert Thomas Arnold provide a more conservative estimate of around 1280 for the appearance of the "true" cannon.

Whether or not any of these are correct, it seems likely that the gun was born sometime during the 13th century.

Use by the Mongols

Three hollow pottery caltrops speculated to have been filled with gunpowder. 13th – 14th century, possibly Yuan dynasty (1206–1368).
Ming dynasty exploding pottery caltrops. From Jizhou District, Tianjin.
A 'magic fire meteor going against the wind' bomb as depicted in the Huolongjing.
A 'bone-burning and bruising fire-oil magic bomb' (lan gu huo you shen pao 爛骨火油神砲) fragmentation bomb from the Huolongjing. It is composed of a cast iron casing, iron pellets coated in tung oil, urine, sal ammoniac, feces, and scallion juice. In the middle is a gunpowder stick.
Stoneware bombs, known in Japanese as Tetsuhau (iron bomb), or in Chinese as Zhentianlei (thunder crash bomb), excavated from the Takashima shipwreck, October 2011, dated to the Mongol invasions of Japan (1271–1284).

The Mongols and their rise in world history as well as conflicts with both the Jin and Song played a key role in the evolution of gunpowder technology. Mongol aptitude in incorporating foreign experts extended to the Chinese, who provided artisans that followed Mongol armies willingly and unwillingly far into the west and even east, to Japan. Unfortunately textual evidence for this is scant as the Mongols left few documents. This lack of primary source documents has caused some historians and scholars such as Kate Raphael to doubt the Mongol's role in disseminating gunpowder throughout Eurasia. On the opposite side stand historians such as Tonio Andrade and Stephen Haw, who believe that the Mongol Empire not only used gunpowder weapons but deserves the moniker "the first gunpowder empire."

Conquest of the Jin dynasty

The first concerted Mongol invasion of Jin occurred in 1211 and total conquest was not accomplished until 1234. In 1232 the Mongols besieged the Jin capital of Kaifeng and deployed gunpowder weapons along with other more conventional siege techniques such as building stockades, watchtowers, trenches, guardhouses, and forcing Chinese captives to haul supplies and fill moats. Jin scholar Liu Qi (劉祈) recounts in his memoir, "the attack against the city walls grew increasingly intense, and bombs rained down as [the enemy] advanced." The Jin defenders also deployed gunpowder bombs as well as fire arrows (huo jian 火箭) launched using a type of early solid-propellant rocket. Of the bombs, Liu Qi writes, "From within the walls the defenders responded with a gunpowder bomb called the heaven-shaking-thunder bomb (震天雷). Whenever the [Mongol] troops encountered one, several men at a time would be turned into ashes."

A more fact based and clear description of the bomb exists in the History of Jin: "The heaven-shaking-thunder bomb is an iron vessel filled with gunpowder. When lighted with fire and shot off, it goes off like a crash of thunder that can be heard for a hundred li [thirty miles], burning an expanse of land more than half a mu [所爇圍半畝之上, a mu is a sixth of an acre], and the fire can even penetrate iron armor." A Ming official named He Mengchuan would encounter an old cache of these bombs three centuries later in the Xi'an area: "When I went on official business to Shaanxi Province, I saw on top of Xi'an's city walls an old stockpile of iron bombs. They were called 'heaven-shaking-thunder' bombs, and they were like an enclosed rice bowl with a hole at the top, just big enough to put your finger in. The troops said they hadn't been used for a very long time." Furthermore, he wrote, "When the powder goes off, the bomb rips open, and the iron pieces fly in all directions. That is how it is able to kill people and horses from far away."

Heaven-shaking-thunder bombs, also known as thunder crash bombs, were used prior to the siege in 1231 when a Jin general made use of them in destroying a Mongol warship. The Jin general named Wanyan Eke had lost the defense of Hezhong to the Mongols and fled on ships with 3,000 of his men. The Mongols pursued them with their ships until the Jin broke through by using thunder crash bombs that caused flashes and flames. However during the siege the Mongols responded by protecting themselves with elaborate screens of thick cowhide. This was effective enough for workers to get right up to the walls to undermine their foundations and excavate protective niches. Jin defenders countered by tying iron cords and attaching them to heaven-shaking-thunder bombs, which were lowered down the walls until they reached the place where the miners worked. The protective leather screens were unable to withstand the explosion, and were penetrated, killing the excavators.

Another weapon the Jin employed was an improved version of the fire lance called the flying fire lance. The History of Jin provides a detailed description: "To make the lance, use chi-huang paper, sixteen layers of it for the tube, and make it a bit longer than two feet. Stuff it with willow charcoal, iron fragments, magnet ends, sulfur, white arsenic [probably an error that should mean saltpeter], and other ingredients, and put a fuse to the end. Each troop has hanging on him a little iron pot to keep fire [probably hot coals], and when it's time to do battle, the flames shoot out the front of the lance more than ten feet, and when the gunpowder is depleted, the tube isn't destroyed." While Mongol soldiers typically held a view of disdain toward most Jin weapons, apparently they greatly feared the flying fire lance and heaven-shaking-thunder bomb. Kaifeng managed to hold out for a year before the Jin emperor fled and the city capitulated. In some cases Jin troops still fought with some success, scoring isolated victories such as when a Jin commander led 450 fire lancers against a Mongol encampment, which was "completely routed, and three thousand five hundred were drowned." Even after the Jin emperor committed suicide in 1234, one loyalist gathered all the metal he could find in the city he was defending, even gold and silver, and made explosives to lob against the Mongols, but the momentum of the Mongol Empire could not be stopped. By 1234, both the Western Xia and Jin dynasty had been conquered.

Conquest of the Song dynasty

The Mongol war machine moved south and in 1237 attacked the Song city of Anfeng (modern Shouxian, Anhui) "using gunpowder bombs [huo pao] to burn the [defensive] towers." These bombs were apparently quite large. "Several hundred men hurled one bomb, and if it hit the tower it would immediately smash it to pieces." The Song defenders under commander Du Gao (杜杲) rebuilt the towers and retaliated with their own bombs, which they called the "Elipao," after a famous local pear, probably in reference to the shape of the weapon. Perhaps as another point of military interest, the account of this battle also mentions that the Anfeng defenders were equipped with a type of small arrow to shoot through eye slits of Mongol armor, as normal arrows were too thick to penetrate.

By the mid 13th century, gunpowder weapons had become central to the Song war effort. In 1257 the Song official Li Zengbo was dispatched to inspect frontier city arsenals. Li considered an ideal city arsenal to include several hundred thousand iron bombshells, and also its own production facility to produce at least a couple thousand a month. The results of his tour of the border were severely disappointing and in one arsenal he found "no more than 85 iron bomb-shells, large and small, 95 fire-arrows, and 105 fire-lances. This is not sufficient for a mere hundred men, let alone a thousand, to use against an attack by the ... barbarians. The government supposedly wants to make preparations for the defense of its fortified cities, and to furnish them with military supplies against the enemy (yet this is all they give us). What chilling indifference!" Fortunately for the Song, Möngke Khan died in 1259 and the war would not continue until 1269 under the leadership of Kublai Khan, but when it did the Mongols came in full force.

Blocking the Mongols' passage south of the Yangtze were the twin fortress cities of Xiangyang and Fancheng. What resulted was one of the longest sieges the world had ever known, lasting from 1268 to 1273. In 1273 the Mongols enlisted the expertise of two Muslim engineers, one from Persia and one from Syria, who helped in the construction of counterweight trebuchets. These new siege weapons had the capability of throwing larger missiles further than the previous traction trebuchets. One account records, "when the machinery went off the noise shook heaven and earth; every thing that [the missile] hit was broken and destroyed." The fortress city of Xiangyang fell in 1273.

The next major battle to feature gunpowder weapons was during a campaign led by the Mongol general Bayan, who commanded an army of around two hundred thousand, consisting of mostly Chinese soldiers. It was probably the largest army the Mongols had ever used. Such an army was still unable to successfully storm Song city walls, as seen in the 1274 Siege of Shayang. Thus Bayan waited for the wind to change to a northerly course before ordering his artillerists to begin bombarding the city with molten metal bombs, which caused such a fire that "the buildings were burned up and the smoke and flames rose up to heaven." Shayang was captured and its inhabitants massacred.

Gunpowder bombs were used again in the 1275 Siege of Changzhou in the latter stages of the Mongol-Song Wars. Upon arriving at the city, Bayan gave the inhabitants an ultimatum: "if you ... resist us ... we shall drain your carcasses of blood and use them for pillows." This didn't work and the city resisted anyway, so the Mongol army bombarded them with fire bombs before storming the walls, after which followed an immense slaughter claiming the lives of a quarter million. The war lasted for only another four years during which some remnants of the Song held up last desperate defenses. In 1277, 250 defenders under Lou Qianxia conducted a suicide bombing and set off a huge iron bomb when it became clear defeat was imminent. Of this, the History of Song writes, "the noise was like a tremendous thunderclap, shaking the walls and ground, and the smoke filled up the heavens outside. Many of the troops [outside] were startled to death. When the fire was extinguished they went in to see. There were just ashes, not a trace left." So came an end to the Mongol-Song Wars, which saw the deployment of all the gunpowder weapons available to both sides at the time, which for the most part meant gunpowder arrows, bombs, and lances, but in retrospect, another development would overshadow them all, the birth of the gun.

In 1280, a large store of gunpowder at Weiyang in Yangzhou accidentally caught fire, producing such a massive explosion that a team of inspectors at the site a week later deduced that some 100 guards had been killed instantly, with wooden beams and pillars blown sky high and landing at a distance of over 10 li (~2 mi. or ~3 km) away from the explosion, creating a crater more than ten feet deep.

By the time of Jiao Yu and his Huolongjing (a book that describes military applications of gunpowder in great detail) in the mid 14th century, the explosive potential of gunpowder was perfected, as the level of nitrate in gunpowder formulas had risen from a range of 12% to 91%, with at least 6 different formulas in use that are considered to have maximum explosive potential for gunpowder. By that time, the Chinese had discovered how to create explosive round shot by packing their hollow shells with this nitrate-enhanced gunpowder.

Invasions of Europe and Japan

Gunpowder may have been used during the Mongol invasions of Europe. "Fire catapults", "pao", and "naphtha-shooters" are mentioned in some sources. However, according to Timothy May, "there is no concrete evidence that the Mongols used gunpowder weapons on a regular basis outside of China."

Shortly after the Mongol invasions of Japan (1274–1281), the Japanese produced a scroll painting depicting a bomb. Called tetsuhau in Japanese, the bomb is speculated to have been the Chinese thunder crash bomb. Japanese descriptions of the invasions also talk of iron and bamboo pao causing "light and fire" and emitting 2–3,000 iron bullets. The Nihon Kokujokushi, written around 1300, mentions huo tong (fire tubes) at the Battle of Tsushima in 1274 and the second coastal assault led by Holdon in 1281. The Hachiman Gudoukun of 1360 mentions iron pao "which caused a flash of light and a loud noise when fired." The [[Taihe[ki]] of 1370 mentions "iron pao shaped like a bell."

The commanding general kept his position on high ground, and directed the various detachments as need be with signals from hand-drums. But whenever the (Mongol) soldiers took to flight, they sent iron bomb-shells (tetsuho) flying against us, which made our side dizzy and confused. Our soldiers were frightened out of their wits by the thundering explosions; their eyes were blinded, their ears deafened, so that they could hardly distinguish east from west. According to our manner of fighting, we must first call out by name someone from the enemy ranks, and then attack in single combat. But they (the Mongols) took no notice at all of such conventions; they rushed forward all together in a mass, grappling with any individuals they could catch and killing them.

— Hachiman Gudoukun
The samurai Takezaki Suenaga facing Mongol and Korean arrows and bombs.

Historiography of gunpowder and gun transmission

Battle of Ain Jalut, 1260

According to historian Tonio Andrade, "Scholars today overwhelmingly concur that the gun was invented in China," however multiple independent gunpowder and gun invention theories continue to exist today, advocating for European, Islamic, or Indian origins. Opponents of Chinese invention and transmission criticize the vagueness of Chinese records on specific gunpowder usage in weaponry, the possible lack of gunpowder in incendiary weapons as described by Chinese documents, the weakness of Chinese firearms, the lack of evidence of guns between Europe and China before 1326, and emphasize the appearance of earlier or superior gunpowder weapons. For example, Stephen Morillo, Jeremy Black, and Paul Lococo's War in World History argues that "the sources are not entirely clear about Chinese use of gunpowder in guns. There are references to bamboo and iron cannons, or perhaps proto-cannons, but these seem to have been small, unreliable, handheld weapons in this period. The Chinese do seem to have invented guns independently of the Europeans, at least in principle; but, in terms of effective cannon, the edge goes to Europe." Independent invention theories include examples such as the attribution of gunpowder to Berthold Schwarz (Black Berthold), the usage of cannons by Mamluks at the Battle of Ain Jalut in 1260, and descriptions of gunpowder and firearms to various Sanskrit texts. The problem with all theories of non-Chinese invention boils down to lack of evidence and dating. It's not certain who exactly Berthold Schwarz was since there are no contemporary records of him. According to J.R. Partington, Black Berthold is a purely legendary figure invented for the purpose of providing a German origin for gunpowder and cannon. The source for Mamluk usage of cannons in the Battle of Ain Jalut is a text dated to the late 14th century. The dating of the cited Sanskrit texts is often dubious at best, with one example, Sukraniti, containing descriptions of a musket and a cart-drawn gun.

Proponents of Chinese invention and transmission point out the acute dearth of any significant evidence of evolution or experimentation with gunpowder or gunpowder weapons leading up to the gun outside of China. Gunpowder appeared in Europe primed for military usage as an explosive and propellant, bypassing a process which took centuries of Chinese experimentation with gunpowder weaponry to reach, making a nearly instantaneous and seamless transition into firearm warfare, as its name suggests. Furthermore, early European gunpowder recipes shared identical defects with Chinese recipes such as the inclusion of the poisons sal ammoniac and arsenic, which provide no benefit to gunpowder. Bert S. Hall explains this phenomenon in his Weapons and Warfare in Renaissance Europe: Gunpowder, Technology, and Tactics by drawing upon the gunpowder transmission theory, explaining that "gunpowder came [to Europe], not as an ancient mystery, but as a well-developed modern technology, in a manner very much like twentieth-century 'technology-transfer' projects." In a similar vein, Peter Lorge supposes that the Europeans experienced gunpowder "free from preconceived notions of what could be done," in contrast to China, "where a wide range of formulas and a broad variety of weapons demonstrated the full range of possibilities and limitations of the technologies involved." There is also the vestige of Chinese influence on Muslim terminology of key gunpowder related items such as saltpeter, which has been described as either Chinese snow or salt, fireworks which were called Chinese flowers, and rockets which were called Chinese arrows. Moreover, Europeans in particular experienced great difficulty in obtaining saltpeter, a primary ingredient of gunpowder which was relatively scarce in Europe compared to China, and had to be obtained from "distant lands or extracted at high cost from soil rich in dung and urine." Thomas Arnold believes that the similarities between early European cannons and contemporary Chinese models suggests a direct transmission of cannon making knowledge from China rather than a home grown development.

Spread throughout Eurasia and Africa

Arabic illustration showing a gunpowder arrow on the left, fireworks in the middle, and a midfa (fire lance or hand cannon) on the right, from Rzevuski MS, c. 1320–1350

Middle East

Arabic illustration showing soldiers holding a fire tube on the left, a naphtha flask/bomb and midfa (fire lance or hand cannon) on the right, and a rider holding gunpowder cartridges in the middle, from Rzevuski MS, c. 1320–1350

The Muslim world acquired the gunpowder formula some time after 1240, but before 1280, by which time Hasan al-Rammah had written, in Arabic, recipes for gunpowder, instructions for the purification of saltpeter, and descriptions of gunpowder incendiaries. Early Muslim sources suggest that knowledge of gunpowder was acquired from China and may have been introduced by invading Mongols. This is implied by al-Rammah's usage of "terms that suggested he derived his knowledge from Chinese sources." Early Arab texts on gunpowder refer to saltpeter as "Chinese snow" (Arabic: ثلج الصين thalj al-ṣīn), fireworks as "Chinese flowers" and rockets as "Chinese arrows" (sahm al-Khitai). Similarly, the Persians called saltpeter "Chinese salt" or "salt from Chinese salt marshes" (namak shūra chīnī Persian: نمک شوره چيني). Fireworks listed by al-Rammah include "wheels of China" and "flowers of China".

The gunpowder formula of al-Rammah has a saltpeter content of 68% to 75%, which is more explosive than is necessary for rockets, however no explosives are mentioned. Al-Rammah's text, The Book of Military Horsemanship and Ingenious War Devices (Kitab al-Furusiya wa'l-Munasab al-Harbiya), does however mention fuses, incendiary bombs, naphtha pots, fire lances, and an illustration and description of the earliest torpedo. The torpedo was called the "egg which moves itself and burns." Two iron sheets were fastened together and tightened using felt. The flattened pear shaped vessel was filled with gunpowder, metal filings, "good mixtures," two rods, and a large rocket for propulsion. Judging by the illustration, it was evidently supposed to glide across the water.

Hasan al-Rammah was the first Muslim to describe the purification of saltpeter using the chemical processes of solution and crystallization. This was the first clear method for the purification of saltpeter.

According to Joseph Needham, fire lances were used in battles between the Muslims and Mongols in 1299 and 1303.

The earliest surviving documentary evidence for cannons in the Islamic world is from an Arabic manuscript dated to the early 14th century. The author's name is uncertain but may have been Shams al-Din Muhammad, who died in 1350. Dating from around 1320–1350, the illustrations show gunpowder weapons such as gunpowder arrows, bombs, fire tubes, and fire lances or proto-guns. The manuscript describes a type of gunpowder weapon called a midfa which uses gunpowder to shoot projectiles out of a tube at the end of a stock. Some consider this to be a cannon while others do not. The problem with identifying cannons in early 14th century Arabic texts is the term midfa, which appears from 1342 to 1352 but cannot be proven to be true hand-guns or bombards. Contemporary accounts of a metal-barrel cannon in the Islamic world do not occur until 1365. Needham believes that in its original form the term midfa refers to the tube or cylinder of a naphtha projector (flamethrower), then after the invention of gunpowder it meant the tube of fire lances, and eventually it applied to the cylinder of hand-gun and cannon.

Description of the drug (mixture) to be introduced in the madfa'a (cannon) with its proportions: barud, ten; charcoal two drachmes, sulphur one and a half drachmes. Reduce the whole into a thin powder and fill with it one third of the madfa'a. Do not put more because it might explode. This is why you should go to the turner and ask him to make a wooden madfa'a whose size must be in proportion with its muzzle. Introduce the mixture (drug) strongly; add the bunduk (balls) or the arrow and put fire to the priming. The madfa'a length must be in proportion with the hole. If the madfa'a was deeper than the muzzle's width, this would be a defect. Take care of the gunners. Be careful

— Rzevuski MS, possibly written by Shams al-Din Muhammad, c. 1320–1350

According to Paul E. J. Hammer, the Mamluks certainly used cannons by 1342. According to J. Lavin, cannons were used by Moors at the siege of Algeciras in 1343. A metal cannon firing an iron ball was described by Shihab al-Din Abu al-Abbas al-Qalqashandi between 1365 and 1376.

Europe

Recipes for gunpowder (pulveres pixidum) in a manuscript dated c. 1400 (GNM 3227a fol. 6rĎ).
European tiller gun lighted by a hot iron rod being fired from a stand, manuscript by Konrad Kyeser: Bellifortis. c. 1402–1404
Swiss soldier firing a hand cannon late 14th, 15th centuries, illustration produced in 1874.

A common theory of how gunpowder came to Europe is that it made its way along the Silk Road through the Middle East. Another is that it was brought to Europe during the Mongol invasion in the first half of the 13th century. Some sources claim that Chinese firearms and gunpowder weapons may have been deployed by Mongols against European forces at the Battle of Mohi in 1241. It may also have been due to subsequent diplomatic and military contacts. Some authors have speculated that William of Rubruck, who served as an ambassador to the Mongols from 1253 to 1255, was a possible intermediary in the transmission of gunpowder. His travels were recorded by Roger Bacon, who was the first European to mention gunpowder, but the records of William's journey do not contain any mention of gunpowder.

The earliest European references to gunpowder are found in Roger Bacon's Opus Majus from 1267, in which he mentions a firecracker toy found in various parts of the world. The passage reads: "We have an example of these things (that act on the senses) in [the sound and fire of] that children's toy which is made in many [diverse] parts of the world; i.e., a device no bigger than one's thumb. From the violence of that salt called saltpeter [together with sulfur and willow charcoal, combined into a powder] so horrible a sound is made by the bursting of a thing so small, no more than a bit of parchment [containing it], that we find [the ear assaulted by a noise] exceeding the roar of strong thunder, and a flash brighter than the most brilliant lightning." In the early 20th century, British artillery officer Henry William Lovett Hime proposed that another work tentatively attributed to Bacon, Epistola de Secretis Operibus Artis et Naturae, et de Nullitate Magiae contained an encrypted formula for gunpowder. This claim has been disputed by historians of science including Lynn Thorndike, John Maxson Stillman and George Sarton and by Bacon's editor Robert Steele, both in terms of authenticity of the work, and with respect to the decryption method. In any case, the formula claimed to have been decrypted (7:5:5 saltpeter:charcoal:sulfur) is not useful for firearms use or even firecrackers, burning slowly and producing mostly smoke. However, if Bacon's recipe is taken as measurements by volume rather than weight, a far more potent and serviceable explosive powder is created suitable for firing hand-cannons, albeit less consistent due to the inherent inaccuracies of measurements by volume. One example of this composition resulted in 100 parts saltpeter, 27 parts charcoal, and 45 parts sulfur, by weight.

The oldest written recipes for gunpowder in Europe were recorded under the name Marcus Graecus or Mark the Greek between 1280 and 1300 in the Liber Ignium, or Book of Fires. One recipe for "flying fire" (ignis volatilis) involves saltpeter, sulfur, and colophonium, which, when inserted into a reed or hollow wood, "flies away suddenly and burns up everything." Another recipe, for artificial "thunder", specifies a mixture of one pound native sulfur, two pounds linden or willow charcoal, and six pounds of saltpeter. Another specifies a 1:3:9 ratio. The text is likely a translation from Arabic through a Spanish intermediary due to the terminology used and recipes for items found in 12th century Arabic texts.

The earliest known European depiction of a gun appeared in 1326 in a manuscript by Walter de Milemete, although not necessarily drawn by him, known as De Nobilitatibus, sapientii et prudentiis regum (Concerning the Majesty, Wisdom, and Prudence of Kings), which displays a gun with a large arrow emerging from it and its user lowering a long stick to ignite the gun through the touchole. In the same year, another similar illustration showed a darker gun being set off by a group of knights, which also featured in another work of de Milemete's, De secretis secretorum Aristotelis. On 11 February of that same year, the Signoria of Florence appointed two officers to obtain canones de mettallo and ammunition for the town's defense. In the following year a document from the Turin area recorded a certain amount was paid "for the making of a certain instrument or device made by Friar Marcello for the projection of pellets of lead." The bronze vase-shaped gun from Mantua, unfortunately disappeared in 1849, but of which we have drawings and measurements taken in 1786, dates back to 1322. It was 16.4 cm long, weighed about 5 kg and had a caliber of 5.5 cm.

The 1320s seem to have been the takeoff point for guns in Europe according to most modern military historians. Scholars suggest that the lack of gunpowder weapons in a well-traveled Venetian's catalogue for a new crusade in 1321 implies that guns were unknown in Europe up until this point. From the 1320s guns spread rapidly across Europe. The French raiding party that sacked and burned Southampton in 1338 brought with them a ribaudequin and 48 bolts (but only 3 pounds of gunpowder). By 1341 the town of Lille had a "tonnoire master," and a tonnoire was an arrow-hurling gun. In 1345, two iron cannons were present in Toulouse. In 1346 Aix-la-Chapelle too possessed iron cannons which shot arrows (busa ferrea ad sagittandum tonitrum). The Battle of Crécy in 1346 was one of the first in Europe where cannons were used. By 1350 Petrarch wrote that the presence of cannons on the battlefield was 'as common and familiar as other kinds of arms'.

Around the late 14th century European and Ottoman guns began to deviate in purpose and design from guns in China, changing from small anti-personnel and incendiary devices to the larger artillery pieces most people imagine today when using the word "cannon." If the 1320s can be considered the arrival of the gun on the European scene, then the end of the 14th century may very well be the departure point from the trajectory of gun development in China. In the last quarter of the 14th century, European guns grew larger and began to blast down fortifications.

Southeast Asia

A double barrelled cetbang on a carriage, with swivel yoke, c. 1522. The mouth of the cannon is in the shape of Javanese Nāga.

In Southeast Asia, cannons were used by the Ayutthaya Kingdom in 1352 during its invasion of the Khmer Empire. Within a decade large quantities of gunpowder could be found in the Khmer Empire. By the end of the century firearms were also used by the Trần dynasty in Đại Việt.

The Mongol invasion of Java in 1293 brought gunpowder technology to the Nusantara archipelago in the form of cannon (Chinese: 炮—Pào). The knowledge of making gunpowder-based weapon has been known after the failed Mongol invasion of Java. The predecessor of firearms, the pole gun (bedil tombak), was recorded as being used in Java by 1413, while the knowledge of making "true" firearms came much later, after the middle of 15th century. It was brought by the Muslim traders from West Asia, most probably the Arabs. The precise year of introduction is unknown, but it may be safely concluded to be no earlier than 1460.

Portuguese influence to local weaponry after the capture of Malacca (1511) resulted in a new type of hybrid tradition matchlock firearm, the istinggar. Saltpeter harvesting was recorded by Dutch and German travelers as being common in even the smallest villages and was collected from the decomposition process of large dung hills specifically piled for this purpose. The Dutch punishment for possession of non-permitted gunpowder appears to have been amputation. Ownership and manufacture of gunpowder was later prohibited by the colonial Dutch occupiers. According to colonel McKenzie quoted in the book The History of Java (1817) by Thomas Stamford Raffles, the purest sulfur was supplied from a crater from a mountain near the straits of Bali.

India

Gunpowder technology is believed to have arrived in India by the mid-14th century, but could have been introduced much earlier by the Mongols, who had conquered both China and some borderlands of India, perhaps as early as the mid-13th century. The unification of a large single Mongol Empire resulted in the free transmission of Chinese technology into Mongol conquered parts of India. Regardless, it is believed that the Mongols used Chinese gunpowder weapons during their invasions of India. It was written in the Tarikh-i Firishta (1606–1607) that the envoy of the Mongol ruler Hulegu Khan was presented with a dazzling pyrotechnics display upon his arrival in Delhi in 1258. The first gunpowder device, as opposed to naphtha-based pyrotechnics, introduced to India from China in the second half of the 13th century, was a rocket called the "hawai" (also called "ban"). The rocket was used as an instrument of war from the second half of the 14th century onward, and the Delhi sultanate as well as the Bahmani Sultanate made good use of them. As a part of an embassy to India by Timurid leader Shah Rukh (1405–1447), 'Abd al-Razzaq mentioned naphtha-throwers mounted on elephants and a variety of pyrotechnics put on display. Roger Pauly has written that "while gunpowder was primarily a Chinese innovation," the saltpeter that led to the invention of gunpowder may have arrived from India, although it is also likely that it originated indigenously in China.

Firearms known as top-o-tufak also existed in the Vijayanagara Empire of Southern India by as early as 1366. In 1368–1369, the Bahmani Sultanate may have used firearms against Vijayanagara, but these weapons could have been pyrotechnics as well. By 1442 guns had a clearly felt presence in India as attested to by historical records. From then on the employment of gunpowder warfare in India was prevalent, with events such as the siege of Belgaum in 1473 by Muhammad Shah III. Muslim and Hindu states in the south were advanced in artillery compared to the Delhi rulers of this period because of their contact with the outside world, especially Turkey, through the sea route. The south Indian kingdoms imported their gunners (topci) and artillery from Turkey and the Arab countries, with whom they had developed good relations.

Korea

A hwacha manual from the Gukjo orye seorye (1474)

Korea had already come into possession of cannons by 1373, when a Korean mission was sent to China requesting gunpowder supplies for the artillery on their ships. However Korea did not natively produce gunpowder until the years 1374–76. In the 14th century a Korean scholar named Choe Museon discovered a way to produce it after visiting China and bribing a merchant by the name of Li Yuan for the gunpowder formula. In 1377 he figured out how to extract potassium nitrate from the soil and subsequently invented the juhwa, Korea's first rocket, and further developments led to the birth of singijeons, Korean arrow rockets. Korea also began producing cannons in 1377. The multiple rocket launcher known as hwacha ("fire cart" 火車) was developed from the juhwa and singijeon in Korea by 1409 during the Joseon Dynasty. Its inventors include Yi Do (이도, not to be mistaken for Sejong the Great) and Choi Hae-san (최해산, son of Choe Museon). However the first hwachas did not fire rockets, but used mounted bronze guns that shot iron-fletched darts. Rocket launching hwachas were developed in 1451 under the decree of King Munjong and his younger brother Pe. ImYung (Yi Gu, 임영대군 이구). This "Munjong Hwacha" is the well-known type today, and could fire 100 rocket arrows or 200 small Chongtong bullets at one time with changeable modules. At the time, 50 units were deployed in Hanseong (present-day Seoul), and another 80 on the northern border. By the end of 1451, hundreds of hwachas were deployed throughout Korea.

Naval gunpowder weapons also appeared and were rapidly adopted by Korean ships for conflicts against Japanese pirates in 1380 and 1383. By 1410, 160 Korean ships were reported to have equipped artillery of some sort. Mortars firing thunder-crash bombs are known to have been used, and four types of cannons are mentioned: chonja (heaven), chija (earth), hyonja (black), and hwangja (yellow), but their specifications are unknown. These cannons typically shot wooden arrows tipped with iron, the longest of which were nine feet long, but stone and iron balls were sometimes used as well.

Japan

Firearms seem to have been known in Japan around 1270 as proto-cannons invented in China, which the Japanese called teppō (鉄砲 lit. "iron cannon"). Gunpowder weaponry exchange between China and Japan was slow and only a small number of hand guns ever reached Japan. However Japanese samurai used Fire lances in 15th-century. The first recorded appearance of the Fire lances in Japan was in 1409. The use of gunpowder bombs in the style of Chinese explosives is known to have occurred in Japan from at least the mid-15th century onward. The first recorded appearance of the cannon in Japan was in 1510 when a Buddhist monk presented Hōjō Ujitsuna with a teppō iron cannon that he had acquired during his travels in China. Firearms saw very little use in Japan until Portuguese matchlocks were introduced in 1543. During the Japanese invasions of Korea (1592–1598), the forces of Toyotomi Hideyoshi effectively used matchlock firearms against the Korean forces of Joseon, although they would ultimately be defeated and forced to withdraw from the Korean peninsula.

Africa

In Africa, the Adal Empire and the Abyssinian Empire both deployed gunpowder weapons during the Adal-Abyssinian War. Imported from Arabia, and the wider Islamic world, the Adalites, led by Ahmed ibn Ibrahim al-Ghazi, were the first African power to introduce cannon warfare to the African continent. Later on as the Portuguese Empire entered the war it would supply and train the Abyssinians with cannon and muskets, while the Ottoman Empire sent soldiers and cannon to back Adal. The conflict proved, through their use on both sides, the value of firearms such as the matchlock musket, cannon, and the arquebus over traditional weapons.

Ernest Gellner in his book 'Nations and Nationalism' argues that the centralizing potential of the gun and the book, enabled both the Somali people and the Amhara people to dominate the political history of a vast area in Africa, despite neither of them being numerically predominant.

"In the Horn of Africa both the Amharas and the Somalis possessed both gun and Book (not the same Book, but rival and different editions), and neither bothered greatly with the wheel. Each of these ethnic groups was aided in its use of these two pieces of cultural equipment by its link to other members of the wider religious civilization which habitually used them, and were willing to replenish their stock." – Ernest Gellner

Transition to early modern warfare

Early Ming firearms

Ming artillerymen from a mural in Yanqing District, Beijing.
Iron cannons, Ming dynasty
Defensive wall of Prince Qin Mansion, western section.

Gun development and proliferation in China continued under the Ming dynasty. The success of its founder Zhu Yuanzhang, who declared his reign to be the era of Hongwu, or "Great Martiality," has often been attributed to his effective use of guns.

Most early Ming guns weighed two to three kilograms while guns considered "large" at the time weighed around only seventy-five kilograms. Ming sources suggest guns such as these shot stones and iron balls, but were primarily used against men rather than for causing structural damage to ships or walls. Accuracy was low and they were limited to a range of only 50 paces or so.

Despite the relatively small size of early Ming guns, some elements of gunpowder weapon design followed world trends. The growing length to muzzle bore ratio matched the rate at which European guns were developing up until the 1450s. The practice of corning gunpowder had been developed by 1370 for the purpose of increasing explosive power in land mines, and was arguably used in guns as well according to one record of a fire-tube shooting a projectile 457 meters, which was probably only possible at the time with the usage of corned powder. Around the same year Ming guns transitioned from using stone shots to iron ammunition, which has greater density and increased firearm power. Aside from firearms, the Ming pioneered in the usage of rocket launchers known as "wasp nests", which it manufactured for the army in 1380 and was used by the general Li Jinglong in 1400 against Zhu Di, the future Yongle Emperor.

The peak of Chinese cannon development prior to the incorporation of European weaponry in the 16th century is exemplified by the muzzle loading wrought iron "great general cannon" (大將軍炮) which weighed up to 360 kilograms and could fire a 4.8 kilogram lead ball. Its heavier variant, the "great divine cannon" (大神銃), could weigh up to 600 kilograms and was capable of firing several iron balls and upward of a hundred iron shots at once. The great general and divine cannons were the last indigenous Chinese cannon designs prior to the incorporation of European models in the 16th century.

The lack of larger siege weapons in China unlike the rest of the world where cannons grew larger and more potent has been attributed to the immense thickness of traditional Chinese walls, which Tonio Andrade suggests provided no incentive for creating larger cannons, since even industrial artillery had trouble overcoming them. Asianist Kenneth Chase also argues that larger guns were not particularly useful against China's traditional enemies: horse nomads.

Big guns

The development of large artillery pieces began by Burgundy. Originally a minor power, the duchy grew to become one of the most powerful states in 14th-century Europe, and a great innovator in siege warfare. The Duke of Burgundy, Philip the Bold (1363–1404), based his power on the effective use of big guns and promoted research and development in all aspects of gunpowder weaponry technology. Philip established manufacturers and employed more cannon casters than any European power before him.

Whereas most European guns before 1370 weighed about 20 to 40 lbs (9–14 kg), the French siege of Château de Saint-Sauveur-le-Vicomte in 1375 during the Hundred Years War saw the use of guns weighing over a ton (900 kg), firing stone balls weighing over 100 lbs (45 kg). Philip used large guns to help the French capture the fortress of Odruik in 1377. These guns fired projectiles far larger than any that had been used before, with seven guns that could shoot projectiles as heavy as 90 kilograms. The cannons smashed the city walls, inaugurating a new era of artillery warfare and Burgundy's territories rapidly expanded.

Europe entered an arms race to build ever larger artillery pieces. By the early 15th century both French and English armies were equipped with larger pieces known as bombards, weighing up to 5 tons (4,535 kg) and firing balls weighing up to 300 lbs (136 kg). The artillery trains used by Henry V of England in the 1415 Siege of Harfleur and 1419 Siege of Rouen proved effective in breaching French fortifications, while artillery contributed to the victories of French forces under Joan of Arc in the Loire Campaign (1429).

These weapons were transformational for European warfare. A hundred years earlier the Frenchman Pierre Dubois wrote that a "castle can hardly be taken within a year, and even if it does fall, it means more expenses for the king's purse and for his subjects than the conquest is worth," but by the 15th century European walls fell with the utmost regularity.

The Ottoman Empire was also developing their own artillery pieces. Mehmed the Conqueror (1432–1481) was determined to procure large cannons for the purpose of conquering Constantinople. Hungarian Urban produced for him a six-meter (20-foot) long cannon, which required hundreds of pounds of gunpowder to fire; during the actual siege of Constantinople the gun proved to be somewhat underwhelming. However, dozens of other large cannons bombarded Constantinople's walls in their weakest sections for 55 days, and despite a fierce defense, the city's fortifications were overwhelmed.

Changes to fortifications

17th-century map of the city of Palmanova, Italy, an example of a Venetian star fort
Chinese angled bastion fort, 1638

As a response to gunpowder artillery, European fortifications began displaying architectural principles such as lower and thicker walls in the mid-1400s. Cannon towers were built with artillery rooms where cannons could discharge fire from slits in the walls. However this proved problematic as the slow rate of fire, reverberating concussions, and noxious fumes produced greatly hindered defenders. Gun towers also limited the size and number of cannon placements because the rooms could only be built so big. Notable surviving artillery towers include a seven layer defensive structure built in 1480 at Fougères in Brittany, and a four layer tower built in 1479 at Querfurth in Saxony.

The star fort, also known as the bastion fort, tracé à l'italienne, or renaissance fortress, was a style of fortification that became popular in Europe during the 16th century. The bastion and star fort was developed in Italy, where the Florentine engineer Giuliano da Sangallo (1445–1516) compiled a comprehensive defensive plan using the geometric bastion and full tracé à l'italienne that became widespread in Europe.

The main distinguishing features of the star fort were its angle bastions, each placed to support their neighbor with lethal crossfire, covering all angles, making them extremely difficult to engage with and attack. Angle bastions consisted of two faces and two flanks. Artillery positions positioned at the flanks could fire parallel into the opposite bastion's line of fire, thus providing two lines of cover fire against an armed assault on the wall, and preventing mining parties from finding refuge. Meanwhile, artillery positioned on the bastion platform could fire frontally from the two faces, also providing overlapping fire with the opposite bastion. Overlapping mutually supporting defensive fire was the greatest advantage enjoyed by the star fort. As a result, sieges lasted longer and became more difficult affairs. By the 1530s the bastion fort had become the dominant defensive structure in Italy.

Outside Europe, the star fort became an "engine of European expansion", and acted as a force multiplier so that small European garrisons could hold out against numerically superior forces. Wherever star forts were erected the natives experienced great difficulty in uprooting European invaders.

In China, Sun Yuanhua advocated for the construction of angled bastion forts in his Xifashenji so that their cannons could better support each other. The officials Han Yun and Han Lin noted that cannons on square forts could not support each side as well as bastion forts. Their efforts to construct bastion forts and their results were inconclusive. Ma Weicheng built two bastion forts in his home county, which helped fend off a Qing incursion in 1638. By 1641, there were ten bastion forts in the county. Before bastion forts could be spread any further, the Ming dynasty fell in 1644, and they were largely forgotten as the Qing dynasty was on the offensive most of the time and had no use for them.

Classical cannon

Gun development and design in Europe reached its "classic" form in the 1480s – longer, lighter, more efficient, and more accurate compared to its predecessors only three decades prior. The design persisted, and cannons of the 1480s show little difference and surprising similarity with cannons three centuries later in the 1750s. This 300-year period during which the classic cannon dominated gives it its moniker.

The early classical European guns are exemplified by two cannons from 1488 now preserved in a plaza in Neuchâtel, Switzerland. The Neuchâtel guns are 224 centimeters long, with a bore of 6.2 centimeters and the other is slightly longer, 252 centimeters, with the same bore size. They are differentiated from older firearms by an assortment of improvements. Their longer length-to-bore ratio imparts more energy into the shot, enabling the projectile to shoot further. Not only longer, they were also lighter as the barrel walls were made thinner to allow for faster dissipation of heat. They also no longer needed the help of a wooden plug to load since they offered a tighter fit between projectile and barrel, further increasing the accuracy of gunpowder warfare – and were deadlier due to developments such as gunpowder corning and iron shot. When these guns reached China in the 1510s, the Chinese were highly impressed by them, primarily for their longer and thinner barrels.

The two primary theories for the appearance of the classic gun involve the development of gunpowder corning and a new method for casting guns.

The corning hypothesis stipulates that the longer barrels came about as a reaction to the development of corned gunpowder. Not only did "corned" powder keep better, because of its reduced surface area, but gunners also found that it was more powerful and easier to load into guns. Prior to corning, gunpowder would also frequently demix into its constitutive components and was therefore unreliable. The faster gunpowder reaction was suitable for smaller guns, since large ones had a tendency to crack, and the more controlled reaction allowed large guns to have longer, thinner walls. However, the corning hypothesis has been argued against on two grounds: One, the powder makers were probably more worried about spoilage than the effect of corned gunpowder on guns; and two, corning as a practice had existed in China (for explosives) since the 1370s.

The second theory is that the key to developing the classic gun may have been a new method of gun casting, muzzle side up. Smith observes: "The surviving pieces of ordnance from earlier in the 15th century are big pieces with large bore sizes. They do not look like the long thin gun.… Essentially they are parallel-sided tubes with flat ends. The explanation is, probably, that they were cast muzzle down in the traditional bell-founding method whereas the long thin guns were cast muzzle up.… Perhaps this marks the real 'revolution' in artillery. Once the technique of casting muzzle up with the attendant advantages, and it is not clear what those are at present, had been mastered by cannon founders, the way was open for the development of the 'classic' form of artillery." However, Smith himself states that it is not clear what advantages this technique would have conferred, despite its widespread adoption.

Iron and bronze

Across the 15th and 16th centuries there were primarily two different types of manufactured cannons. The wrought iron cannon and the cast-bronze cannon. Wrought iron guns were structurally composed of two layers: an inner tube of iron staves held together in a tight fit by an outer case of iron hoops. Bronze cannons on the other hand were cast in one piece similar to bells. The technique used in casting bronze cannons was so similar to the bell that the two were often looked upon as a connected enterprise.

Both iron and bronze cannons had their advantages and disadvantages. Forged iron cannons were up to ten times cheaper, but more unstable due to their piece built nature. Even without use, iron cannons were liable to rust away, while bronze cannons did not. Another reason for the dominance of bronze cannons was their aesthetic appeal. Because cannons were so important as displays of power and prestige, rulers liked to commission bronze cannons, which could be sculpted into fanciful designs containing artistic motifs or symbols. It was for all these reasons that the cast-bronze cannon became the preferred type by the late 1400s.

Some cannons cast in China during the 1370s may have been of steel rather than iron.

Composite metal

Composite iron/bronze cannons were far less common, but were produced in substantial numbers during the Ming and Qing dynasties. The resulting bronze-iron composite cannons were superior to iron or bronze cannons in many respects. They were lighter, stronger, longer lasting, and able to withstand more intensive explosive pressure. Chinese artisans also experimented with other variants such as cannons featuring wrought iron cores with cast iron exteriors. While inferior to their bronze-iron counterparts, these were considerably cheaper and more durable than standard iron cannons. Both types were met with success and were considered "among the best in the world" during the 17th century. The Chinese composite metal casting technique was effective enough that Portuguese imperial officials sought to employ Chinese gunsmiths for their cannon foundries in Goa, so that they could impart their methods for Portuguese weapons manufacturing. The Gujarats experimented with the same concept in 1545, the English at least by 1580, and Hollanders in 1629. However the effort required to produce these weapons prevented them from mass production. The Europeans essentially treated them as experimental products, resulting in very few surviving pieces today. Of the currently known extant composite metal cannons, there are 2 English, 2 Dutch, 12 Gujarati, and 48 from the Ming-Qing period.

Arquebus and musket

Two soldiers on the left using arquebuses, 1470.
A serpentine matchlock mechanism.
Musketeer from Jacob van Gheyn's Wapenhandelingen van Roers, Musquetten ende Spiesen, (1608).

The arquebus was a firearm that appeared in Europe and the Ottoman Empire in the early 15th century. Its name is derived from the German word Hakenbüchse. Although the term arquebus was applied to many different forms of firearms from the 15th to 17th centuries, it was originally used to describe "a hand-gun with a hook-like projection or lug on its under surface, useful for steadying it against battlements or other objects when firing." These "hook guns" were in their earliest forms defensive weapons mounted on German city walls in the early 1400s, but by the late 1400s had transitioned into handheld firearms, with heavier variants known as "muskets" that were fired from resting Y-shaped supports appearing by the early 1500s.

The musket was able to penetrate all forms of armor available at the time, making armor obsolete, and as a consequence the heavy musket as well. Although there is relatively little to no difference in design between arquebus and musket except in size and strength, it was the term musket which remained in use up into the 1800s. It may not be completely inaccurate to suggest that the musket was in its fabrication simply a larger arquebus. At least on one occasion the musket and arquebus have been used interchangeably to refer to the same weapon, and even referred to as an "arquebus musket." A Habsburg commander in the mid-1560s once referred to muskets as "double arquebuses." The definition of arquebus and similar firearms is therefore quite convoluted as the term has been applied to different sorts of firearms as well as acquiring several names like hackbut, harquebus, schiopo, sclopus, tüfenk, tofak, matchlock, and firelock. Some say that the hackbut was a forerunner of the arquebus.

The dating of the matchlock firing mechanism's first appearance is disputed. The first references to the use of what may have been arquebuses (tüfek) by the Janissary corps of the Ottoman army date them from 1394 to 1465. However it's unclear whether these were arquebuses or small cannons as late as 1444, but the fact that they were listed separate from cannons in mid-15th century inventories suggest they were handheld firearms. In Europe, a shoulder stock, probably inspired by the crossbow stock, was added to the arquebus around 1470 and the appearance of the matchlock mechanism is dated to a little before 1475. The matchlock arquebus was the first firearm equipped with a trigger mechanism. It is also considered to be the first portable shoulder-arms firearm.

Matchlock became a common term for the arquebus after it was added to the firearm. Prior to the appearance of the matchlock, handguns were fired from the chest, tucked under one arm, while the other arm maneuvered a hot pricker to the touch hole to ignite the gunpowder. The matchlock changed this by adding a firing mechanism consisting of two parts, the match, and the lock. The lock mechanism held within a clamp a two to three feet long length of smoldering rope soaked in saltpeter, which was the match. Connected to the lock lever was a trigger, which lowered the match into a priming pan when pulled, igniting the priming powder, causing a flash to travel through the touch hole, also igniting the gunpowder within the barrel, and propelling the bullet out the muzzle.

While matchlocks provided a crucial advantage by allowing the user to aim the firearm using both hands, it was also awkward to use. To avoid accidentally igniting the gunpowder the match had to be detached while loading the gun. In some instances the match would also go out, so both ends of the match were kept lit. This proved cumbersome to maneuver as both hands were required to hold the match during removal, one end in each hand. The procedure was so complex that a 1607 drill manual published by Jacob de Gheyn in the Netherlands listed 28 steps just to fire and load the gun. In 1584 the Ming general Qi Jiguang composed an 11 step song to practice the procedure in rhythm: "One, clean the gun. Two pour the powder. Three tamp the powder down. Four drop the pellet. Five drive the pellet down. Six put in paper (stopper). Seven drive the paper down. Eight open the flashpan cover. Nine pour in the flash powder. Ten close the flashpan, and clamp the fuse. Eleven, listen for the signal, then open the flashpan cover. Aiming at the enemy, raise your gun and fire." Reloading a gun during the 16th century took anywhere from between 20 seconds to a minute under the most ideal conditions.

The arquebus is considered to be the first portable "shoulder" arms firearm. Arquebuses were used as early as 1472 by the Spanish and Portuguese at Zamora. Likewise, the Castilians used arquebuses as well in 1476. In 1496 Philip Monch of the Palatinate composed an illustrated Buch der Strynt un(d) Buchsse(n) on guns and "harquebuses." The Mamluks in particular were conservatively against the incorporation of gunpowder weapons. When faced with cannons and arquebuses wielded by the Ottomans they criticized them thus, "God curse the man who invented them, and God curse the man who fires on Muslims with them." Insults were also levied against the Ottomans for having "brought with you this contrivance artfully devised by the Christians of Europe when they were incapable of meeting the Muslim armies on the battlefield." Similarly, musketeers and musket-wielding infantrymen were despised in society by the feudal knights, even until the time of Don Quixote author Miguel de Cervantes (1547–1616). Eventually the Mamluks under Qaitbay were ordered in 1489 to train in the use of al-bunduq al-rasas (arquebuses). However, in 1514 an Ottoman army of 12,000 soldiers wielding arquebuses still managed to rout a much larger Mamluk force. The arquebus had become a common infantry weapon by the 16th century due to its relative cheapness – a helmet, breastplate and pike cost about three and a quarter ducats while an arquebus only a little over one ducat. Another advantage of arquebuses over other equipment and weapons was its short training period. While a bow potentially took years to master, an effective arquebusier could be trained in just two weeks. According to a 1571 report by Vincentio d'Alessandri, Persian arms including arquebuses "were superior and better tempered than those of any other nation."

In the early 1500s a larger arquebus known as the musket appeared. The heavy musket, while being rather awkward to handle, requiring a fork rest to fire properly, had the advantage of being able to penetrate the best armor within a range of 180 meters, regular armor at 365 meters, and an unarmed man at 548 meters. However, both the musket and arquebus were effectively limited to a range of only 90 to 185 meters regardless of armor since they were incredibly inaccurate. According to some sources, a smoothbore musket was completely incapable of hitting a man sized target past the 73-meter mark. While rifled guns did exist at this time in the form of grooves cut into the interior of a barrel, these were considered specialist weapons and limited in number. In some aspects this made the smoothbore musket an inferior weapon compared to the bow. The average Mamluk archer for example was capable of hitting targets only 68 meters far away but could keep up a pace of six to eight shots per minute. In comparison, sixteenth-century matchlocks fired off one shot every several minutes, and much less when taking into consideration misfires and malfunctions which occurred up to half the time. This is not to say that firearms of the 16th century were inferior to the bow and arrow, for it could better penetrate armor and required less training, but the disadvantages of the musket were very real, and it would not be until the 1590s that archers were for the most part phased out of European warfare. This was possibly a consequence of the increased effectiveness of musket warfare due to the rise of volley fire in Europe as first applied by the Dutch. At this time gunners in European armies reached as high as 40 percent of infantry forces.

As the virtues of the musket became apparent it was quickly adopted throughout Eurasia so that by 1560 even in China generals were giving praise to the new weapon. Qi Jiguang, a noted partisan of the musket, gave a eulogy on the effectiveness of the gun in 1560:

It is unlike any other of the many types of fire weapons. In strength it can pierce armor. In accuracy it can strike the center of targets, even to the point of hitting the eye of a coin [i.e., shooting right through a coin], and not just for exceptional shooters.… The arquebus [鳥銃] is such a powerful weapon and is so accurate that even bow and arrow cannot match it, and … nothing is so strong as to be able to defend against it.

— Jixiao Xinshu

Other East Asian powers such as Đại Việt also adopted the matchlock musket in quick order. Đại Việt in particular was considered by the Ming to have produced the most advanced matchlocks in the world during the 17th century, surpassing even Ottoman, Japanese, and European firearms. European observers of the Trịnh–Nguyễn War also corroborated with the Ming in the proficiency of matchlock making by the Vietnamese. The Vietnamese matchlock was said to have been able to pierce several layers of iron armour, kill two to five men in one shot, yet also fire quietly for a weapon of its caliber.

Gunpowder Empires

An illustration by Byam Shaw from the book The Adventures of Akbar by Flora Annie Steel. It depicts artillerymen.

The Gunpowder Empires generally refer to the Islamic Ottoman, Safavid and Mughal empires. The phrase was first coined by Marshall Hodgson in the title of Book 5 ("The Second Flowering: The Empires of Gunpowder Times") of his highly influential three-volume work, The Venture of Islam (1974).

Hogdson applied the term "gunpowder empire" to three Islamic political entities he identified as separate from the unstable, geographically limited confederations of Turkic clans that prevailed in post-Mongol times. He called them "military patronage states of the Later Middle Period," which possessed three defining characteristics: first, a legitimization of independent dynastic law; second, the conception of the whole state as a single military force; third, the attempt to explain all economic and high cultural resources as appanages of the chief military families. Connecting these empires were their traditions which grew "out of Mongol notions of greatness," but "[s]uch notions could fully mature and create stable bureaucratic empires only after gunpowder weapons and their specialized technology attained a primary place in military life."

William H. McNeill further expanded on the concept of gunpowder empires by arguing that such states "were able to monopolize the new artillery, central authorities were able to unite larger territories into new, or newly consolidated, empires."

In 2011 Douglas E. Streusand criticized the Hodgson-McNeill Gunpowder-Empire hypothesis, calling it into disfavor as a neither "adequate [n]or accurate" explanation, although the term remains in use. The main problem he saw with the Hodgson-McNeill theory is that the acquisition of firearms does not seem to have preceded the initial acquisition of territory constituting the imperial critical mass of any of the three early modern Islamic empires, except in the case of the Mughals. Moreover, it seems that the commitment to military autocratic rule pre-dated the acquisition of gunpowder weapons in all three cases.

Whether or not gunpowder was inherently linked to the existence of any of these three empires, it cannot be questioned that each of the three acquired artillery and firearms early in their history and made such weapons an integral part of their military tactics.

Ottoman Empire

It's not certain when the Ottomans started using firearms, however it's argued that they had been using cannons since the Battles of Kosovo (1389) and Nukap (1396) and most certainly by the 1420s. Some argue that field guns only entered service shortly after the Battle of Varna (1444) and more certainly used in the Second Battle of Kosovo (1448). Firearms, (especially grenades) were used in the 1683 siege of Vienna The arquebus reached them around 1425.

India and the Mughal Empire

An illustration from the Akbarnama written by Abu'l-Fazl ibn Mubarak (1551–1602) depicts a gun in Akbar's court (bottom center).

In India, guns made of bronze were recovered from Calicut (1504) and Diu (1533). By the 17th century, Indians were manufacturing a diverse variety of firearms; large guns in particular, became visible in Tanjore, Dacca, Bijapur and Murshidabad. Gujarāt supplied Europe saltpeter for use in gunpowder warfare during the 17th century. Bengal and Mālwa participated in saltpeter production. The Dutch, French, Portuguese, and English used Chāpra as a center of saltpeter refining.

Fathullah Shirazi (c. 1582), who worked for Akbar the Great as a mechanical engineer, developed an early multi gun shot. Shirazi's rapid-firing gun had multiple gun barrels that fired hand cannons loaded with gunpowder.

Mysorean rockets were an Indian military weapon, the first iron-cased rockets successfully deployed for military use. The Mysorean army, under Hyder Ali and his son Tipu Sultan, used the rockets effectively against the British East India Company during the 1780s and 1790s.

The Indian war rockets were formidable weapons before such rockets were used in Europe. They had bam-boo rods, a rocket-body lashed to the rod, and iron points. They were directed at the target and fired by lighting the fuse, but the trajectory was rather erratic. The use of mines and counter-mines with explosive charges of gunpowder is mentioned for the times of Akbar and Jahāngir.

Civil engineering

Canals

Gunpowder was used for hydraulic engineering in China by 1541. Gunpowder blasting followed by dredging of the detritus was a technique which Chen Mu employed to improve the Grand Canal at the waterway where it crossed the Yellow River. In Europe, gunpowder was used in the construction of the Canal du Midi in Southern France. It was completed in 1681 and linked the Mediterranean sea with the Atlantic with 240 km of canal and 100 locks. Another noteworthy consumer of black powder was the Erie Canal in New York, which was 585 km long and took eight years to complete, starting in 1817.

Mining

Before gunpowder was applied to civil engineering, there were two ways to break up large rocks, by hard labor or by heating with large fires followed by rapid quenching. The earliest record for the use of gunpowder in mines comes from Hungary in 1627. It was introduced to Britain in 1638 by German miners, after which records are numerous. Until the invention of the safety fuse by William Bickford in 1831, the practice was extremely dangerous. Another reason for danger were the dense fumes given off and the risk of igniting flammable gas when used in coal mines.

Tunnel construction

Gunpowder was also extensively used in railway construction. At first railways followed the contours of the land, or crossed low ground by means of bridges and viaducts, but later railways made extensive use of cuttings and tunnels. One 2400-ft stretch of the 5.4 mi Box Tunnel on the Great Western Railway line between London and Bristol consumed a ton of gunpowder per week for over two years. The 12.9 km long Mont Cenis Tunnel was completed in 13 years starting in 1857 but, even with black powder, progress was only 25 cm a day until the invention of pneumatic drills sped up the work.

United States

Revolutionary War

During the American Revolutionary War, a number of caves were mined for saltpeter to make gunpowder when supplies from Europe were embargoed. Abigail Adams reputedly also made gunpowder at her family farm in Massachusetts.

The New York Committee of Safety produced some essays on making gunpowder that were printed in 1776.

Civil War

During the American Civil War, British India was the main source for saltpeter for the manufacture of gunpowder for the Union armies. This supply was threatened by the British government during the Trent Affair, when Union naval forces stopped a British ship, the RMS Trent, and removed two Confederate diplomats. The British government responded in part by halting all exports of saltpeter to the United States, threatening their gunpowder manufacturing resources. Shortly thereafter, the situation was resolved and the Confederate diplomats were released.

The Union Navy blockaded the southern Confederate States, which reduced the amount of gunpowder that could be imported from overseas. The Confederate Nitre and Mining Bureau was formed to produce gunpowder for the army and the navy from domestic resources. Nitre is the English spelling of "Niter". While carbon and sulfur were readily available throughout the south, potassium nitrate was often produced from the Calcium nitrate found in cave dirt, tobacco barn floors and barn stalls other places. A number of caves were mined, and the men and boys who worked in the caves were called "peter monkey", somewhat in imitation of the naval term "powder monkey" that was used for the boys who brought up charges of gunpowder on gunboats.

On 13 November 1862, the Confederate government advertised in the Charleston Daily Courier for 20 or 30 "able bodied Negro men" to work in the new nitre beds at Ashley Ferry, S.C. The nitre beds were large rectangles of rotted manure and straw, moistened weekly with urine, "dung water", and liquid from privies, cesspools and drains, and turned over regularly. The process was designed to yield saltpeter, an ingredient of gunpowder, which the Confederate army needed during the Civil War. The South was so desperate for saltpeter for gunpowder that one Alabama official reportedly placed a newspaper ad asking that the contents of chamber pots be saved for collection. In the winter of 1863, scores of enslaved people were set to work extracting it from a huge cave in Barstow County, Ga., where they labored by torchlight in grim conditions, hauling out and processing the so-called "peter dirt",. In South Carolina, in April 1864, the Confederate government hired 31 enslaved people to work at the Ashley Ferry Nitre Works.

Decline

The latter half of the 19th century saw the invention of nitroglycerin, nitrocellulose and smokeless powders which soon replaced traditional gunpowder in most civil and military applications.

Smokeless powder

From Wikipedia, the free encyclopedia
https://en.wikipedia.org/wiki/Smokeless_powder
Finnish smokeless powder

Smokeless powder, also referred to as gunpowder, is a type of propellant used in firearms and artillery that produces less smoke and less fouling when fired compared to black powder. The combustion products are mainly gaseous, compared to around 55% solid products (mostly potassium carbonate, potassium sulfate, and potassium sulfide) for black powder. In addition, smokeless powder does not leave the thick, heavy fouling of hygroscopic material associated with black powder that causes rusting of the barrel.

Despite its name, smokeless powder is not completely free of smoke; while there may be little noticeable smoke from small-arms ammunition, smoke from artillery fire can be substantial.

Invented in 1884 by Paul Vieille, the most common formulations are based on nitrocellulose, but the term was also used to describe various picrate mixtures with nitrate, chlorate, or dichromate oxidizers during the late 19th century, before the advantages of nitrocellulose became evident.

Smokeless powders are typically classified as division 1.3 explosives under the UN Recommendations on the Transport of Dangerous Goods – Model Regulations, regional regulations (such as ADR) and national regulations. However, they are used as solid propellants; in normal use, they undergo deflagration rather than detonation.

Smokeless powder made autoloading firearms with many moving parts feasible (which would otherwise jam or seize under heavy black powder fouling). Smokeless powder allowed the development of modern semi- and fully automatic firearms and lighter breeches and barrels for artillery.

History

Before the widespread introduction of smokeless powder the use of gunpowder or black powder caused many problems on the battlefield. Military commanders since the Napoleonic Wars reported difficulty with giving orders on a battlefield obscured by the smoke of firing. Visual signals could not be seen through the thick smoke from the gunpowder used by the guns. Unless there was a strong wind, after a few shots, soldiers using gunpowder ammunition would have their view obscured by a huge cloud of smoke. Snipers or other concealed shooters were given away by a cloud of smoke over the firing position. Gunpowder produces lower pressures and is about one third as powerful as smokeless powder. Gunpowder is also hygroscopic (i.e., it attracts moisture from the air), making cleaning mandatory after every use. Likewise, gunpowder's tendency to produce severe fouling causes actions to jam and often makes reloading difficult.

Nitroglycerine and guncotton

Nitroglycerine was synthesized by the Italian chemist Ascanio Sobrero in 1847. It was subsequently developed and manufactured by Alfred Nobel as an industrial explosive, but even then it was unsuitable as a propellant: despite its energetic and smokeless qualities, it detonates instead of deflagrating smoothly, making it more liable to shatter a gun, rather than propel a projectile out of it. Nitroglycerine is also highly shock-sensitive, making it unfit to be carried in battlefield conditions.

A major step forward was the invention of guncotton, a nitrocellulose-based material, by German chemist Christian Friedrich Schönbein in 1846. He promoted its use as a blasting explosive and sold manufacturing rights to the Austrian Empire. Guncotton was more powerful than gunpowder, but at the same time was once again somewhat more unstable. John Taylor obtained an English patent for guncotton; and John Hall & Sons began manufacture in Faversham.

English interest languished after an explosion destroyed the Faversham factory in 1847. Austrian Baron Wilhelm Lenk von Wolfsberg built two guncotton plants producing artillery propellent, but it too was dangerous under field conditions, and guns that could fire thousands of rounds using black powder would reach the end of their service life after only a few hundred shots with the more powerful guncotton. Small arms could not withstand the pressures generated by guncotton.

After one of the Austrian factories blew up in 1862, Thomas Prentice & Company began manufacturing guncotton in Stowmarket in 1863; and British War Office chemist Sir Frederick Abel began thorough research at Waltham Abbey Royal Gunpowder Mills leading to a manufacturing process that eliminated the impurities in nitrocellulose making it safer to produce and a stable product safer to handle. Abel patented this process in 1865 when the second Austrian guncotton factory exploded. After the Stowmarket factory exploded in 1871, Waltham Abbey began production of guncotton for torpedo and mine warheads.

Improvements

An extruded stick powder

In 1863, Prussian artillery captain Johann F. E. Schultze patented a small-arms propellant of nitrated hardwood impregnated with saltpeter or barium nitrate. Prentice received an 1866 patent for a sporting powder of nitrated paper manufactured at Stowmarket, but ballistic uniformity suffered as the paper absorbed atmospheric moisture. In 1871, Frederick Volkmann received an Austrian patent for a colloided version of Schultze powder called Collodin, which he manufactured near Vienna for use in sporting firearms. Austrian patents were not published at the time, and the Austrian Empire considered the operation a violation of the government monopoly on explosives manufacture and closed the Volkmann factory in 1875.

In 1882, the Explosives Company at Stowmarket patented an improved formulation of nitrated cotton gelatinised by ether-alcohol with nitrates of potassium and barium. These propellants were suitable for shotguns but not rifles, because rifling results in resistance to a smooth expansion of the gas, which is reduced in smoothbore shotguns.

In 1884, Paul Vieille invented a smokeless powder called Poudre B (short for poudre blanche, white powder, as distinguished from black powder) made from 68.2% insoluble nitrocellulose, 29.8% soluble nitrocellulose gelatinized with ether and 2% paraffin. This was adopted for the Lebel rifle chambered in 8×50mmR Lebel. It was passed through rollers to form paper thin sheets, which were cut into flakes of the desired size. The resulting propellant, known as pyrocellulose, contains somewhat less nitrogen than guncotton and is less volatile. A particularly good feature of the propellant is that it will not detonate unless it is compressed, making it very safe to handle under normal conditions. Vieille's powder revolutionized the effectiveness of small guns because it gave off almost no smoke and was three times more powerful than black powder. Higher muzzle velocity meant a flatter trajectory and less wind drift and bullet drop, making 1,000 m (1,094 yd) shots practicable. Since less powder was needed to propel a bullet, the cartridge could be made smaller and lighter. This allowed troops to carry more ammunition for the same weight. Also, it would burn even when wet. Black powder ammunition had to be kept dry and was almost always stored and transported in watertight cartridges. Other European countries swiftly followed and started using their own versions of Poudre B, the first being Germany and Austria, which introduced new weapons in 1888. Subsequently, Poudre B was modified several times with various compounds being added and removed. Krupp began adding diphenylamine as a stabilizer in 1888.

Meanwhile, in 1887, Alfred Nobel obtained an English patent for a smokeless gunpowder he called Ballistite. In this propellant the fibrous structure of cotton (nitro-cellulose) was destroyed by a nitroglycerine solution instead of a solvent. In England in 1889, a similar powder was patented by Hiram Maxim, and in the United States in 1890 by Hudson Maxim. Ballistite was patented in the United States in 1891. The Germans adopted ballistite for naval use in 1898, calling it WPC/98. The Italians adopted it as filite, in cord instead of flake form, but realising its drawbacks changed to a formulation with nitroglycerine they called solenite. In 1891 the Russians tasked the chemist Mendeleev with finding a suitable propellant. He created nitrocellulose gelatinised by ether-alcohol, which produced more nitrogen and more uniform colloidal structure than the French use of nitro-cottons in Poudre B. He called it pyrocollodion.

Close-up of Cordite filaments in a .303 British rifle cartridge (manufactured in 1964)

Britain conducted trials on all the various types of propellant brought to their attention, but were dissatisfied with them all and sought something superior to all existing types. In 1889, Sir Frederick Abel, James Dewar and Dr W Kellner patented (Nos 5614 and 11,664 in the names of Abel and Dewar) a new formulation that was manufactured at the Royal Gunpowder Factory at Waltham Abbey. It entered British service in 1891 as Cordite Mark 1. Its main composition was 58% nitroglycerine, 37% guncotton and 3% mineral jelly. A modified version, Cordite MD, entered service in 1901, with the guncotton percentage increased to 65% and nitroglycerine reduced to 30%. This change reduced the combustion temperature and hence erosion and barrel wear. Cordite's advantages over gunpowder were reduced maximum pressure in the chamber (hence lighter breeches, etc.) but longer high pressure. Cordite could be made in any desired shape or size. The creation of cordite led to a lengthy court battle between Nobel, Maxim, and another inventor over alleged British patent infringement.

The Anglo-American Explosives Company began manufacturing its shotgun powder in Oakland, New Jersey in 1890. DuPont began producing guncotton at Carneys Point Township, New Jersey in 1891. Charles E. Munroe of the Naval Torpedo Station in Newport, Rhode Island patented a formulation of guncotton colloided with nitrobenzene, called Indurite, in 1891. Several United States firms began producing smokeless powder when Winchester Repeating Arms Company started loading sporting cartridges with Explosives Company powder in 1893. California Powder Works began producing a mixture of nitroglycerine and nitrocellulose with ammonium picrate as Peyton Powder, Leonard Smokeless Powder Company began producing nitroglycerine–nitrocellulose Ruby powders, Laflin & Rand negotiated a license to produce Ballistite, and DuPont started producing smokeless shotgun powder. The United States Army evaluated 25 varieties of smokeless powder and selected Ruby and Peyton Powders as the most suitable for use in the Krag–Jørgensen service rifle. Ruby was preferred, because tin-plating was required to protect brass cartridge cases from picric acid in the Peyton Powder. Rather than paying the required royalties for Ballistite, Laflin & Rand financed Leonard's reorganization as the American Smokeless Powder Company. United States Army Lieutenant Whistler assisted American Smokeless Powder Company factory superintendent Aspinwall in formulating an improved powder named W.A. for their efforts. W.A. smokeless powder was the standard for United States military service rifles from 1897 until 1908.

In 1897, United States Navy Lieutenant John Bernadou patented a nitrocellulose powder colloided with ether-alcohol. The Navy licensed or sold patents for this formulation to DuPont and the California Powder Works while retaining manufacturing rights for the Naval Powder Factory, Indian Head, Maryland constructed in 1900. The United States Army adopted the Navy single-base formulation in 1908 and began manufacture at Picatinny Arsenal. By that time Laflin & Rand had taken over the American Powder Company to protect their investment, and Laflin & Rand had been purchased by DuPont in 1902. Upon securing a 99-year lease of the Explosives Company in 1903, DuPont enjoyed use of all significant smokeless powder patents in the United States, and was able to optimize production of smokeless powder. When government anti-trust action forced divestiture in 1912, DuPont retained the nitrocellulose smokeless powder formulations used by the United States military and released the double-base formulations used in sporting ammunition to the reorganized Hercules Powder Company. These newer and more powerful propellants were more stable and thus safer to handle than Poudre B.

Characteristics

Macro shot of Hodgdon H110 pistol powder, small black and greenish beads against a white background.
Hodgdon H110 smokeless pistol powder

The properties of the propellant are greatly influenced by the size and shape of its pieces. The specific surface area of the propellant influences the speed of burning, and the size and shape of the particles determine the specific surface area. By manipulation of the shape it is possible to influence the burning rate and hence the rate at which pressure builds during combustion. Smokeless powder burns only on the surfaces of the pieces. Larger pieces burn more slowly, and the burn rate is further controlled by flame-deterrent coatings that retard burning slightly. The intent is to regulate the burn rate so that a more or less constant pressure is exerted on the propelled projectile as long as it is in the barrel so as to obtain the highest velocity. The perforations stabilize the burn rate because as the outside burns inward (thus shrinking the burning surface area) the inside is burning outward (thus increasing the burning surface area, but faster, so as to fill up the increasing volume of barrel presented by the departing projectile). Fast-burning pistol powders are made by extruding shapes with more area such as flakes or by flattening the spherical granules. Drying is usually performed under a vacuum. The solvents are condensed and recycled. The granules are also coated with graphite to prevent static electricity sparks from causing undesired ignitions.

Smokeless powder does not leave the thick, heavy fouling of hygroscopic material associated with black powder that causes rusting of the barrel (though some primer compounds can leave hygroscopic salts that have a similar effect; non-corrosive primer compounds were introduced in the 1920s).

Faster-burning propellants generate higher temperatures and higher pressures, however they also increase wear on gun barrels.

Nitrocellulose deteriorates with time, yielding acidic byproducts. Those byproducts catalyze the further deterioration, increasing its rate. The released heat, in case of bulk storage of the powder, or too large blocks of solid propellant, can cause self-ignition of the material. Single-base nitrocellulose propellants are hygroscopic and most susceptible to degradation; double-base and triple-base propellants tend to deteriorate more slowly. To neutralize the decomposition products, which could otherwise cause corrosion of metals of the cartridges and gun barrels, calcium carbonate is added to some formulations.

To prevent buildup of the deterioration products, stabilizers are added. Diphenylamine is one of the most common stabilizers used. Nitrated analogs of diphenylamine formed in the process of stabilizing decomposing powder are sometimes used as stabilizers themselves. The stabilizers are added in the amount of 0.5–2% of the total amount of the formulation; higher amounts tend to degrade its ballistic properties. The amount of the stabilizer is depleted with time. Propellants in storage should be periodically tested for the amount of stabilizer remaining, as its depletion may lead to auto-ignition of the propellant.

Composition

Propellants using nitrocellulose (detonation velocity 7,300 m/s (23,950 ft/s), RE factor 1.10) (typically an ether-alcohol colloid of nitrocellulose) as the sole explosive propellant ingredient are described as single-base powder.

Propellants mixtures containing nitrocellulose and nitroglycerin (detonation velocity 7,700 m/s (25,260 ft/s), RE factor 1.54) as explosive propellant ingredients are known as double-base powder. Alternatively diethylene glycol dinitrate (detonation velocity 6,610 m/s (21,690 ft/s), RE factor 1.17) can be used as a nitroglycerin replacement when reduced flame temperatures without sacrificing chamber pressure are of importance. Reduction of flame temperature significantly reduces barrel erosion and hence wear.

During the 1930s, triple-base propellant containing nitrocellulose, nitroglycerin or diethylene glycol dinitrate, and a substantial quantity of nitroguanidine (detonation velocity 8,200 m/s (26,900 ft/s), RE factor 0.95) as explosive propellant ingredients was developed. These "cold propellant" mixtures have reduced flash and flame temperature without sacrificing chamber pressure compared to single- and double-base propellants, albeit at the cost of more smoke. In practice, triple base propellants are reserved mainly for large caliber ammunition such as used in (naval) artillery and tank guns, which suffer from bore erosion the most. During World War II, it had some use by British artillery. After that war it became the standard propellant in all British large caliber ammunition designs except small-arms. Most western nations, except the United States, followed a similar path.

In the late 20th century new propellant formulations started to appear. These are based on nitroguanidine and high explosives of the RDX type (detonation velocity 8,750 m/s (28,710 ft/s), RE factor 1.60).

Detonation velocities are of limited value in assessing the reaction rates of nitrocellulose propellants formulated to avoid detonation. Although the slower reaction is often described as burning because of similar gaseous end products at elevated temperatures, the decomposition differs from combustion in an oxygen atmosphere. Conversion of nitrocellulose propellants to high-pressure gas proceeds from the exposed surface to the interior of each solid particle in accordance with Piobert's law. Studies of solid single- and double-base propellant reactions suggest reaction rate is controlled by heat transfer through the temperature gradient across a series of zones or phases as the reaction proceeds from the surface into the solid. The deepest portion of the solid experiencing heat transfer melts and begins phase transition from solid to gas in a foam zone. The gaseous propellant decomposes into simpler molecules in a surrounding fizz zone. Energy is released in a luminous outer flame zone where the simpler gas molecules react to form conventional combustion products like steam and carbon monoxide. The foam zone acts as an insulator slowing the rate of heat transfer from the flame zone into the unreacted solid. Reaction rates vary with pressure; because the foam allows less effective heat transfer at low pressure, with greater heat transfer as higher pressures compress the gas volume of that foam. Propellants designed for a minimum heat transfer pressure may fail to sustain the flame zone at lower pressures.

The energetic components used in smokeless propellants include nitrocellulose (the most common), nitroglycerin, nitroguanidine, DINA (bis-nitroxyethylnitramine; diethanolamine dinitrate, DEADN; DHE), Fivonite (2,2,5,5-tetramethylol-cyclopentanone tetranitrate, CyP), DGN (diethylene glycol dinitrate), and acetyl cellulose.

Deterrents (or moderants) are used to slow the burning rate. Deterrents include centralites (symmetrical diphenyl urea—primarily diethyl or dimethyl), dibutyl phthalate, dinitrotoluene (toxic and carcinogenic), akardite (asymmetrical diphenyl urea), ortho-Tolyl urethane, and polyester adipate. Camphor was formerly used but is now obsolete.

Stabilizers prevent or slow down self-decomposition. These include diphenylamine, petroleum jelly, calcium carbonate, magnesium oxide, sodium bicarbonate, and beta-Naphthol methyl ether Obsolete stabilizers include amyl alcohol and aniline.

Decoppering additives hinder the buildup of copper residues from the gun barrel rifling. These include tin metal and compounds (e.g., tin dioxide), and bismuth metal and compounds (e.g., bismuth trioxide, bismuth subcarbonate, bismuth nitrate, bismuth antimonide); the bismuth compounds are favored as copper dissolves in molten bismuth, forming brittle and easily removable alloy. Lead foil and lead compounds have been phased out due to toxicity.

Wear reduction materials including wax, talc and titanium dioxide are added to lower the wear of the gun barrel liners. Large guns use polyurethane jackets over the powder bags.

Other additives include ethyl acetate (a solvent for manufacture of spherical powder), rosin (a surfactant to hold the grain shape of spherical powder) and graphite (a lubricant to cover the grains and prevent them from sticking together, and to dissipate static electricity).

Flash reduction

Flash reducers dim muzzle flash, the light emitted in the vicinity of the muzzle by the hot propellant gases and the chemical reactions that follow as the gases mix with the surrounding air. Before projectiles exit, a slight pre-flash may occur from gases leaking past the projectiles. Following muzzle exit, the heat of gases is usually sufficient to emit visible radiation: the primary flash. The gases expand but as they pass through the Mach disc, they are re-compressed to produce an intermediate flash. Hot, combustible gases (e.g. hydrogen and carbon-monoxide) may follow when they mix with oxygen in the surrounding air to produce the secondary flash, the brightest. The secondary flash does not usually occur with small arms.

Nitrocellulose contains insufficient oxygen to completely oxidize its carbon and hydrogen. The oxygen deficit is increased by addition of graphite and organic stabilizers. Products of combustion within the gun barrel include flammable gasses like hydrogen and carbon monoxide. At high temperature, these flammable gasses will ignite when turbulently mixed with atmospheric oxygen beyond the muzzle of the gun. During night engagements, the flash produced by ignition can reveal the location of the gun to enemy forces and cause temporary night-blindness among the gun crew by photo-bleaching visual purple.

Flash suppressors are commonly used on small arms to reduce the flash signature, but this approach is not practical for artillery. Artillery muzzle flash up to 150 feet (46 m) from the muzzle has been observed, and can be reflected off clouds and be visible for distances up to 30 miles (48 km). For artillery, the most effective method is a propellant that produces a large proportion of inert nitrogen at relatively low temperatures that dilutes the combustible gases. Triple based propellants are used for this because of the nitrogen in the nitroguanidine.

Flash reducers include potassium chloride, potassium nitrate, potassium sulfate, and potassium bitartrate (potassium hydrogen tartrate: a byproduct of wine production formerly used by French artillery). Before the use of triple based propellants, the usual method of flash reduction was to add inorganic salts like potassium chloride so their specific heat capacity might reduce the temperature of combustion gasses and their finely divided particulate smoke might block visible wavelengths of radiant energy of combustion.

All flash reducers have a disadvantage: the production of smoke.

Manufacturing

Ammunition handloading powders

Smokeless powder may be corned into small spherical balls or extruded into cylinders or strips with many cross-sectional shapes (strips with various rectangular proportions, single or multi-hole cylinders, slotted cylinders) using solvents such as ether. These extrusions can be cut into short ("flakes") or long pieces ("cords" many inches long). Cannon powder has the largest pieces.

The United States Navy manufactured single-base tubular powder for naval artillery at Indian Head, Maryland, beginning in 1900. Similar procedures were used for United States Army production at Picatinny Arsenal beginning in 1907 and for manufacture of smaller grained Improved Military Rifle (IMR) powders after 1914. Short-fiber cotton linter was boiled in a solution of sodium hydroxide to remove vegetable waxes, and then dried before conversion to nitrocellulose by mixing with concentrated nitric and sulfuric acids. Nitrocellulose still resembles fibrous cotton at this point in the manufacturing process, and was typically identified as pyrocellulose because it would spontaneously ignite in air until unreacted acid was removed. The term guncotton was also used; although some references identify guncotton as a more extensively nitrated and refined product used in torpedo and mine warheads prior to use of TNT.

Unreacted acid was removed from pyrocellulose pulp by a multistage draining and water washing process similar to that used in paper mills during production of chemical woodpulp. Pressurized alcohol removed remaining water from drained pyrocellulose prior to mixing with ether and diphenylamine. The mixture was then fed through a press extruding a long tubular cord form to be cut into grains of the desired length.

Alcohol and ether were then evaporated from "green" powder grains to a remaining solvent concentration between 3 percent for rifle powders and 7 percent for large artillery powder grains. Burning rate is inversely proportional to solvent concentration. Grains were coated with electrically conductive graphite to minimize generation of static electricity during subsequent blending. "Lots" containing more than ten tonnes of powder grains were mixed through a tower arrangement of blending hoppers to minimize ballistic differences. Each blended lot was then subjected to testing to determine the correct loading charge for the desired performance.

Military quantities of old smokeless powder were sometimes reworked into new lots of propellants. Through the 1920s Fred Olsen worked at Picatinny Arsenal experimenting with ways to salvage tons of single-base cannon powder manufactured for World War I. Olsen was employed by Western Cartridge Company in 1929 and developed a process for manufacturing spherical smokeless powder by 1933. Reworked powder or washed pyrocellulose can be dissolved in ethyl acetate containing small quantities of desired stabilizers and other additives. The resultant syrup, combined with water and surfactants, can be heated and agitated in a pressurized container until the syrup forms an emulsion of small spherical globules of the desired size. Ethyl acetate distills off as pressure is slowly reduced to leave small spheres of nitrocellulose and additives. The spheres can be subsequently modified by adding nitroglycerine to increase energy, flattening between rollers to a uniform minimum dimension, coating with phthalate deterrents to retard ignition, and/or glazing with graphite to improve flow characteristics during blending.

Modern smokeless powder is produced in the United States by St. Marks Powder, Inc. owned by General Dynamics.

Gunpowder empires

From Wikipedia, the free encyclopedia
https://en.wikipedia.org/wiki/Gunpowder_empires

Gunpowder empires
1556–1736
Gunpowder empires near the end of the 17th century
StatusEmpires
Religion
Sunni Islam (Hanafi majority),
Shia Islam (only Safavid)
Membership
Historical eraEarly modern
Mughal Army artillerymen during the reign of Akbar.
A mufti sprinkling cannon with rose water

The gunpowder empires, or Islamic gunpowder empires, is a collective term coined by Marshall G. S. Hodgson and William H. McNeill at the University of Chicago, referring to three early modern Muslim empires: the Ottoman Empire, Safavid Empire and the Mughal Empire, in the period they flourished from mid-16th to the early 18th century. These three empires were among the most stable empires of the early modern period, leading to commercial expansion, and patronage of culture, while their political and legal institutions were consolidated with an increasing degree of centralization. They stretched from Central Europe and North Africa in the west to Bengal and Arakan in the east. Hodgson's colleague William H. McNeill expanded on the history of gunpowder use across multiple civilizations including East Asian, South Asian and European powers in his "The Age of Gunpowder Empires". Vast amounts of territory were conquered by the gunpowder empires with the use and development of the newly invented firearms, especially cannon and small arms, in the course of imperial expansion. Like in Europe, the introduction of gunpowder weapons prompted changes such as the rise of centralized monarchical states.

According to G. S. Hodgson, in the gunpowder empires these changes went well beyond military organisation. The Mughals, based in the Indian subcontinent, inherited in part the Timurid Renaissance, and are recognised for their lavish architecture and for having heralded in Bengal an era of what some describe as proto-industrialization. The Safavids created an efficient and modern state administration for Iran and sponsored major developments in the fine arts. The sultans of the Ottoman Empire, also known as the Kaysar-i Rûm, controlled the holy cities of Mecca and Medina, and hence were the recognised Caliphs of Islam; their powers, wealth, architecture, and various contributions significantly influenced the course of Islamic world history. Hodgson's colleague William H. McNeill expanded on the history of gunpowder use across multiple civilizations including East Asian, European, and South Asian powers in his 1993 work The Age of Gunpowder Empires.

The Hodgson–McNeill concept

The phrase was coined by Marshall G. S. Hodgson and his colleague William H. McNeill at the University of Chicago. Hodgson used the phrase in the title of Book 5 ("The Second Flowering: The Empires of Gunpowder Times") of his highly influential three-volume work, The Venture of Islam (1974). Hodgson saw gunpowder weapons as the key to the "military patronage states of the Later Middle Period" which replaced the unstable, geographically limited confederations of Turkic clans that prevailed in post-Mongol times. Hodgson defined a "military patronage state" as one having three characteristics:

first, a legitimization of independent dynastic law; second, the conception of the whole state as a single military force; third, the attempt to explain all economic and high cultural resources as appanages of the chief military families.

Such states grew "out of Mongol notions of greatness", but "[s]uch notions could fully mature and create stable bureaucratic empires only after gunpowder weapons and their specialized technology attained a primary place in military life."

McNeill argued that whenever such states "were able to monopolize the new artillery, central authorities were able to unite larger territories into new, or newly consolidated, empires." Monopolization was key. Although Europe pioneered the development of new artillery in the fifteenth century, no state monopolized it. Gun-casting know-how had been concentrated in the Low Countries near the mouths of the Scheldt and Rhine rivers. France and the Habsburgs divided those territories among themselves, resulting in an arms standoff. By contrast, such monopolies allowed states to create militarized empires in Western Asia, Russia, and India, and "in a considerably modified fashion" in China, Korea, and Japan.

Recent views on the concept

More recently, the Hodgson–McNeill "gunpowder empire" hypothesis has been called into disfavour as a neither "adequate [n]or accurate" explanation, although the term remains in use. Reasons other than (or in addition to) military technology have been offered for the nearly simultaneous rise of three centralized military empires in contiguous areas dominated by decentralized Turkic tribes. One explanation, called "Confessionalization" by historians of fifteenth century Europe, invokes examination of how the relation of church and state "mediated through confessional statements and church ordinances" lead to the origins of absolutist polities. Douglas Streusand uses the Safavids as an example:

The Safavids from the beginning imposed a new religious identity on their general population; they did not seek to develop a national or linguistic identity, but their policy had that effect.

One problem of the Hodgson–McNeill theory is that the acquisition of firearms does not seem to have preceded the initial acquisition of territory constituting the imperial critical mass of any of the three early modern Islamic empires, except in the case of the Mughal empire. Moreover, it seems that the commitment to military autocratic rule pre-dated the acquisition of gunpowder weapons in all three cases. Nor does it seem to be the case that the acquisition of gunpowder weapons and their integration into the military was influenced by which variety of Islam the particular empire promoted. Whether or not gunpowder was inherently linked to the existence of any of these three empires, it cannot be questioned that each of the three acquired artillery and firearms early in their history and made such weapons an integral part of their military tactics.

Michael Axworthy has pointed out that the label is misleading in the case of the Safavids, as unlike contemporary European armies, the Safavid military mostly used swords, lances, and bows well into the mid-18th century. It was not until the rule of Nader Shah's Afsharid dynasty that the majority of Iran's troops would be equipped with firearms for the first time.

Gunpowder empires of the Muslim world

Ottoman Empire

The bronze Dardanelles Gun on display at Fort Nelson in Hampshire. Similar cannons were used by the Ottoman Turks in the siege of Constantinople in 1453.

The first of the three empires to acquire gunpowder weapons was the Ottoman Empire. By the 14th century, the Ottomans had adopted gunpowder artillery. The adoption of the gunpowder weapons by the Ottomans was so rapid that they "preceded both their European and Middle Eastern adversaries in establishing centralized and permanent troops specialized in the manufacturing and handling of firearms." But it was their use of artillery that shocked their adversaries and impelled the other two Islamic empires to accelerate their weapons programs. The Ottomans had artillery at least by the reign of Bayezid I and used them in the sieges of Constantinople in 1399 and 1402. They finally proved their worth as siege engines in the successful siege of Salonica in 1430. The Ottomans employed Middle-Eastern as well as European foundries to cast their cannons, and by the siege of Constantinople in 1453, they had large enough cannons to batter the walls of the city, to the surprise of the defenders.

The Ottoman military's regularized use of firearms proceeded ahead of the pace of their European counterparts. The Janissaries had been an infantry bodyguard using bows and arrows. During the rule of Sultan Mehmed II they were drilled with firearms and became "perhaps the first standing infantry force equipped with firearms in the world." The Janissaries are thus considered the first modern standing armies. The combination of artillery and Janissary firepower proved decisive at Varna in 1444 against a force of Crusaders, Başkent in 1473 against the Aq Qoyunlu, and Mohács in 1526 against Hungary. But the battle which convinced the Safavids and the Mughals of the efficacy of gunpowder was Chaldiran.

The matchlock arquebus began to be used by the Janissary corps by the 1440s. The musket later appeared in the Ottoman Empire by 1465. Damascus steel was later used in the production of firearms such as the musket from the 16th century. At the Battle of Mohács in 1526, the Janissaries equipped with 2000 tüfenks (usually translated as musket) "formed nine consecutive rows and they fired their weapons row by row," in a "kneeling or standing position without the need for additional support or rest." The Chinese later adopted the Ottoman kneeling position for firing. In 1598, Chinese writer Zhao Shizhen described Turkish muskets as being superior to European muskets. The Chinese Wu Pei Chih (1621) later described Turkish muskets that used a rack-and-pinion mechanism, which was not known to have been used in any European or Chinese firearms at the time.

The Dardanelles Gun was designed and cast in bronze in 1464 by Munir Ali. The Dardanelles Gun was still present for duty more than 340 years later in 1807, when a Royal Navy force appeared and commenced the Dardanelles Operation. Turkish forces loaded the ancient relics with propellant and projectiles, then fired them at the British ships. The British squadron suffered 28 casualties from this bombardment.

Persian Musketeer in time of Abbas I by Habib-Allah Mashadi after Falsafi (Berlin Museum of Islamic Art).

At Chaldiran, the Ottomans met the Safavids in battle for the first time. Sultan Selim I moved east with his field artillery in 1514 to confront what he perceived as a Shia threat instigated by Shah Ismail in favor of Selim's rivals. Ismail staked his reputation as a divinely-favored ruler on an open cavalry charge against a fixed Ottoman position. The Ottomans deployed their cannons between the carts that carried them, which also provided cover for the armed Janissaries. The result of the charge was devastating losses to the Safavid cavalry. The defeat was so thorough that the Ottoman forces were able to move on and briefly occupy the Safavid capital, Tabriz. Only the limited campaign radius of the Ottoman army prevented it from holding the city and ending the Safavid rule.

Safavid Empire

Although the Chaldiran defeat brought an end to Ismail's territorial expansion program, the shah nonetheless took immediate steps to protect against the real threat from the Ottoman sultanate by arming his troops with gunpowder weapons. Within two years of Chaldiran, Ismail had a corps of musketeers (tofangchi) numbering 8,000, and by 1521, possibly 20,000. After Abbas the Great reformed the army (around 1598), the Safavid forces had an artillery corps of 500 cannons as well as 12,000 musketeers.

The Safavids first put their gunpowder arms to good use against the Uzbeks, who had invaded eastern Persia during the civil war that followed the death of Ismail I. The young shah Tahmasp I headed an army to relieve Herat and encountered the Uzbeks on 24 September 1528 at Jam, where the Safavids decisively beat the Uzbeks. The shah's army deployed cannons (swivel guns on wagons) in the center protected by wagons with cavalry on both flanks. Mughal emperor Babur described the formation at Jam as "in the Anatolian fashion." The several thousand gun-bearing infantry also massed in the center as did the Janissaries of the Ottoman army. Although the Uzbek cavalry engaged and turned the Safavid army on both flanks, the Safavid center held (because it was not directly engaged by the Uzbeks). Rallying under Tahmasp's personal leadership, the infantry of the center engaged and scattered the Uzbek center and secured the field.

Mughal Empire

Mughal matchlock.

By the time he was invited by the Lodi governor of Lahore Daulat Khan to support his rebellion against Lodi Sultan Ibrahim Khan, Babur was familiar with gunpowder firearms and field artillery and a method for deploying them. Babur had employed Ottoman expert Ustad Ali Quli, who showed Babur the standard Ottoman formation—artillery and firearm-equipped infantry protected by wagons in the center, and mounted archers on both wings. Babur used this formation at the First Battle of Panipat in 1526, where the Afghan and Rajput forces loyal to the Delhi sultanate, though superior in numbers but without the gunpowder weapons, were defeated. The decisive victory of the Timurid forces is one reason opponents rarely met Mughal princes in pitched battle over the course of the empire's history. The reigns of Akbar The Great, Shah Jahan and Aurangzeb have been described as a major height of Indian history. By the time of Aurangzeb, the Mughal army was predominantly composed of Indian Muslims, with tribal elements like the Sadaat-e-Bara forming the vanguard of the Mughal cavalry. The Mughal Empire became a powerful geopolitical entity with at times, 24.2% of the world population. The Mughals inherited elements of Persian culture and art, as did the Ottomans and Safavids. Indian Muslims maintained the dominance of artillery in India, and even after the fall of the Mughal empire, various non-Muslim Indian kingdoms continued to recruit Hindustani Muslims as artillery officers in their armies.

Mughal musketeer

Gunpowder empires of East Asia

The three Islamic gunpowder empires are known for their quickly gained success in dominating the battle fields using their newly acquired firearms and techniques. East Asian powers and their military success are commonly overlooked in this subject due to the success of not only the Islamic empires, but also European empires. The success and innovation of gunpowder combat in East Asia, however, are worth mentioning in the same context as that of the Islamic gunpowder empires for their military advancements.

China

The first firearms originated in 10th-century China, and there were various ways that more modern forms of small firearms came to China. During the golden age of East Asian Piracy between the 1540s and 1560s, it was most likely that through their battles and other encounters with these pirates, the Ming dynasty forces inevitably got hold of the weapons and copied them. It was also likely that a powerful mariner Wang Zhi, who controlled thousands of armed men eventually surrendered to the Ming in 1558 and they replicated his weapons. This particular account on arquebus technology was the first to spark the interest of Ming officials for the Chinese to broaden their use of these weapons.

Turkish arquebuses may have reached China before Portuguese ones. In Zhao Shizhen's book of 1598, the Shenqipu, there were illustrations of Ottoman Turkish musketmen with detailed illustrations of their muskets, alongside European musketeers with detailed illustrations of their muskets. There was also illustration and description of how the Chinese had adopted the Ottoman kneeling position in firing. Zhao Shizhen described the Turkish muskets as being superior to the European muskets. The Wu Pei Chih (1621) later described Turkish muskets that used a rack-and-pinion mechanism, which was not known to have been used in any European or Chinese firearms at the time.

The Chinese intensively practiced tactical strategies based on firearm use which resulted in military success. Qi Jiguang, a revered Ming military leader, drilled his soldiers to extremes so that their performance in battle would be successful. In addition, Qi Jiguang also used innovative battle techniques like the volley, counter march, dividing into teams, and even encouraged having a flexible formation to adapt to the battle field.

During the Sino-Dutch War beginning in 1661, Southern Ming commander Zheng Chenggong (Koxinga) used similar tactics to Qi Jiguang effectively in battle. The Chinese were able to defeat Dutch forces through their strict adherence to discipline and their ability to stay in formation. Ultimately, it was their technique and training that defeated the Dutch weapons.

A soldier from the Qianlong era, holding an arquebus.

In 1631, "Heavy Troops" that could build and operate European-style cannon, The imported cannons in the Qing dynasty had a high reputation such as 'Great General in Red'. The Manchu elite did not concern themselves directly with guns and their production, preferring instead to delegate the task to Han-Chinese craftsmen, who produced for the Qing a similar composite metal cannon known as the "Shenwei grand general." Cannons and muskets are also widely used in wars known as 'Ten Great Campaigns'. However, after the Qing gained hegemony over East Asia in the mid-18th century, the practice of casting composite metal cannons fell into disuse until the dynasty faced external threats once again in the Opium War of 1840, at which point smoothbore cannons were already starting to become obsolete as a result of rifled barrels.

Japan

The Japanese adopted the use of the Portuguese arquebus in the middle of the 16th century. Multiple accounts have said that Portuguese men working for Chinese pirates ended up in Japan by chance and impressed the local ruler with the weapons. Soon after, the Japanese started mass-producing the Portuguese style weapon for themselves. In other accounts, this firearm technology may have trickled in to Japan as early as 1540 from the constant in and out flow of Japanese mercenaries who could have picked up firearms in their travels. Soon, Japanese soldiers carrying firearms would greatly outnumber those with other weapons.

Tonio Andrade cited that the Military Revolution Model that gave the Europeans so much military success included the use of superior drilling techniques. The drilling technique he was speaking of was the musketeer volley technique. The volley technique was said to have been invented by Japanese Warlord Oda Nobunaga. He used the same technique that Japanese archers used, but the effect that the technique had to allow soldiers to reload at the same time others could fire was devastating to their enemies.

Korea

Koreans had been using Chinese and self made firearms as early as the late 14th century. They were also quite adept and innovative with their strategies on the battlefield. In fact, there were accounts of Koreans using a type of volley technique in 1447. But the Imjin War between the Japanese against the Koreans and the Ming starting in 1592 and ending in 1598 would change Joseon Korean's perspective on warfare. While it was a devastating defeat to the Koreans, this war forced the Koreans to realize that they needed to adopt the use of the musket as well as Japanese and Chinese methods. The Koreans quickly issued the musket as the base of their military tactic, and their musketeers became more than 50 percent of the military by 1594. They trained using manuals based on Qi Jiguang's techniques such as the volley, while incorporating their own methods too. These events marked the beginning of a Korean military revolution in which the Koreans could combat their enemies using modern equipment and methods of warfare.

There were many instances where the Korean military used their new techniques effectively. In 1619, the Koreans aided the Ming against the Manchus, a great military force. While the Koreans and Ming lost, a Korean unit did exhibit their techniques successful in battle. Then, in 1627 and 1636, the Koreans faced the Manchus alone, again showing their competency in battle by using their musket tactics. Again, they lost in battle to the Manchus in both battles. In 1654 and 1658, the Koreans aided the Qing in battle against the Russians for control over land in Manchuria. In these instances, the Koreans showed their superior tactics and were the reason for the Russians' defeat.

Vietnam

Comparatively little attention has been made to the use and innovation of gunpowder in the expansion of Vietnam. There is, in fact, a widespread belief that the Vietnamese introduced firearms to China, although other scholars disagree. Regardless, the use of gunpowder technology has left an undeniable mark in Vietnamese history, allowing the "southward march" and significant expansion of Vietnamese territory.

Gunpowder in Europe

Europeans are said to have pushed gunpowder technology to its limits, improving the formulas that existed and devising new uses of the substance after it was introduced to Europe via the Silk Road in the thirteenth century. Europeans were improving gunpowder a century after the first gun was invented in China.

Official name Silk Roads: the Routes Network of Chang'an-Tianshan Type Cultural Criteria ii, iii, iv, vi Designated 2014 (38th session) Reference no. 1442 Region Asia-Pacific
Silk Roads: the Routes Network of Chang'an-Tianshan.
Roger Bacon

Roger Bacon, a renowned early European alchemist (1214 – 1292), set forth the marvels of the world; key among them was the ingredients of gunpowder. With these ingredients available, European scientists, inventors and alchemists went on to create corned gunpowder, which had a different refinement process. It entailed adding a wet substance to the gunpowder and then drying it as a mixture. With this improved gunpowder technology, German friar Berthold Schwarz invented the first European cannon in 1353. Due to constant warfare, europe saw an exponential growth innovation of gunpowder firearms, making it the most advanced in the whole world. Europeans improved the gunpowder firearms which had been made in China and the Middle East, creating much stronger and more durable rifles using advanced European metalworking techniques. They learned how to calculate the amount of force exerted by the gas contained in a gun's chamber, which led to guns with the power to fire greater distances.

Improved gunpowder from Europe later, in 1520, reached China on a Portuguese ship, though Turkish arquebuses may have reached China before Portuguese ones. The Ottomans and Portuguese introduced the cannon, improved rifles and other advancements to China, hundreds of years after gunpowder's original invention in China, bringing gunpowder's journey through Asia full circle.

In Fiction

Harry Turtledove wrote "Gunpowder Empire", an alternative history novel whose premise is that, had the Roman Empire survived until the invention of gunpower, it might have become a "Gunpowder Empire" similar to the above and survived into the 21st Century.

Inequality (mathematics)

From Wikipedia, the free encyclopedia https://en.wikipedia.org/wiki/Inequality...